Soil Or Inorganic Silicon Compound Containing, E.g., Granite, Chrysotile, Asbestos, Etc. Patents (Class 106/466)
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Patent number: 10538679Abstract: Provided is a phosphor, which is excited by a wide band of visible light, capable of emitting near-infrared light of high intensity. The phosphor comprises a crystal phase represented by a formula (1): MCuSi2O6 (where M comprises one or more of Ba, Sr and Ca), and a crystal phase represented by a formula (2): MCuSi4O10 (where M comprises one or more of Ba, Sr and Ca), wherein a ratio ? of a diffraction peak intensity of MCuSi4O10 with respect to a diffraction peak intensity of MCuSi2O6 in an X-ray diffraction (XRD) pattern obtained by powder XRD measurement using CuK? rays is 0<??0.50.Type: GrantFiled: February 10, 2016Date of Patent: January 21, 2020Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Jun-ichi Itoh, Ikuhiro Ozawa, Takayoshi Mori
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Patent number: 10196317Abstract: An alkali metal ion source with a moderate rate of release of the ion (e.g. potassium) is formed by a method that includes: 1) combining an particulate ore that contains at least one of an alkali metal ion-bearing framework silicate (e.g. syenite ore) with at least one of an oxide and hydroxide of at least one of an alkali metal and alkaline earth metal such as calcium hydroxide; 2) milling the mixture of these two components optionally, with water, optionally, milling the dry components separately and blended thereafter, optionally, with water; 3) forming a mixture by adding water to the solid mixture after milling, if water was not added before milling; 4) exposing the mixture to an elevated temperature and pressure to form a gel that includes silica and the alkali metal of the framework silicate.Type: GrantFiled: April 27, 2016Date of Patent: February 5, 2019Assignee: Massachusetts Institute of TechnologyInventors: Taisiya Skorina, Antoine Allanore
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Patent number: 9713827Abstract: The present invention relates to a device for decontaminating surfaces such as a wall, a floor, or a ceiling of a building, or the like, having one or more toxic products, such as, asbestos, lead (Pb), PCBs (polychlorinated biphenyls), polycyclic aromatic hydrocarbons (PAHs), or radioactive products. The device includes at least one hydroblasting head fed by a high pressure unit and connected to a vacuum source comprising a low pressure source connected to a cyclone head mounted on a container which collects water containing toxic products and residues of the support. A filtration system having a filtering press is provided. The filtering press is fed with water containing toxic products collected in the container and whose output feeds a buffer tank wherein the water from the filtration comprises particles less than or equal to 5 ?m. Another objective of the invention concerns a method for decontaminating surfaces.Type: GrantFiled: March 10, 2014Date of Patent: July 25, 2017Assignee: PERI-BATInventors: Jean-Pierre Bonneau, Cedric Bonneau, Michael Bonneau, Vincent Bonneau
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Patent number: 8871863Abstract: A method for producing a thermoplastic polymeric matrix includes adding a suspension containing a silicate compound and/or barium sulfate either before or during the polymerization of the polymerizable polymeric matrix; various articles are obtained by forming this polymeric matrix, such as yarns, fibers, filaments, films and molded articles.Type: GrantFiled: July 20, 2009Date of Patent: October 28, 2014Assignee: Rhodia Poliamida e Especialidades LTDAInventors: Daniel Hideki Di Petta, Karla Krivtzoff Laguens, Leo Ricardo Bedore Dos Santos, Tarcis Cordeiro Bastos, Thomas Canova
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Patent number: 8808447Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.Type: GrantFiled: March 8, 2012Date of Patent: August 19, 2014Assignee: CQV Co., Ltd.Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
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Publication number: 20140178813Abstract: A method for manufacturing a fatty acid metal salt particle includes forming a coating layer including a fatty acid metal salt on a surface of a core material particle in supercritical carbon dioxide.Type: ApplicationFiled: June 6, 2013Publication date: June 26, 2014Inventors: Hiroyoshi OKUNO, Junichi TOMONAGA, Takeshi IWANAGA, Shunsuke NOZAKI, Hideaki YOSHIKAWA
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Publication number: 20140033954Abstract: An activator composition, in particular suitable for activating latent hydraulic and/or pozzolanic materials in binder compositions, includes: a first component A, including an alkali metal salt and/or an earth alkali metal salt; a second component B, including a metal sulfate; optionally, a third component C, suitable for accelerating the hardening of a hydraulic binder material; and optionally, a filler material; with at least the components A, B and C, if present, being chemically different.Type: ApplicationFiled: March 22, 2012Publication date: February 6, 2014Applicant: SIKA TECHNOLOGY AGInventors: Robert Flatt, Christophe Guyot, Pascal Bailleul
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Publication number: 20130340650Abstract: Plant and process for cement clinker production includes preheating a raw meal, a calcination step where the raw meal is brought to a temperature of about 800-850° C. to substantially decompose its mineral constituents into their oxides, and a sintering step where the load is brought to a temperature of 1300 to 1450° C. to form Ca2SiO4 (or (CaO)2.SiO2), to further decompose calcium carbonate and partially melt the load to form Ca3.SiO5 (or (CaO)3.SiO2) in a rotarykiln, followed by cooling the resulting clinker, and optionally milling it, wherein untreated oil sludge is supplied into an injection zone of the calcination zone operated at a material temperature of approx. 800-850° C., the injection zone including the bottom discharge of the lowest cyclone stages and/or of the precalciner, if appropriate, the feed-in slope of the rotary kiln and the gas phase over the mineral bed at the material inlet end of the rotary kiln.Type: ApplicationFiled: June 20, 2013Publication date: December 26, 2013Inventors: Christian Meyers, Hans Ericsson
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Publication number: 20130180431Abstract: Embodiments are presented herein that provide a filler that is a combination of zeolite and hydrated lime. Addition of this filler to asphalt is more beneficial than addition of either zeolite or hydrated lime alone. The beneficial properties of zeolite include a controlled release of moisture that aids mixture workability and the ability of the asphalt to effectively coat the aggregate particles. The mixture of zeolite and hydrated lime is easier to handle and integrate into a process than use of either compound alone, and it offers a number of other benefits.Type: ApplicationFiled: July 19, 2012Publication date: July 18, 2013Inventors: Edward A. Myszak, JR., Flavio Ernesto Ribeiro, Dallas N. Little
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Publication number: 20130035399Abstract: The subject matter of the present invention is marked inorganic additives, a method for their production and also their use.Type: ApplicationFiled: September 21, 2012Publication date: February 7, 2013Applicant: SACHTLEBEN CHEMIE GMBHInventor: SACHTLEBEN CHEMIE GMBH
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Patent number: 8362132Abstract: Aqueous coating composition having a PVC from 78 to 85% and free of non-fugitive coalescing solvent, comprising, based on the total volume solids of the dry coating unless otherwise stated, a) opacifying pigment particles comprising from 3 to 10% titanium dioxide and from 0 to 20% of hollow polymeric particles; b) non-opacifying extender particles comprising calcium magnesium carbonate and/or calcium carbonate and/or nepheline syenite and/or kaolin; c) polymer binder particles of calculated Fox Tg of from 5 to 25° C. having an acid value of from 15 to 65 mg KOH/g of polymer; d) dispersant having weight average molecular weight of at least 3500 Daltons, and wherein the dispersant demand of a mixture of the opacifying pigment particles, other than the hollow polymeric particles, of a) and the extender particles of b) is greater than 0.35 wt %, calculated on the weight of the titanium dioxide and extender particles; e) fugitive coalescing solvent.Type: GrantFiled: April 21, 2011Date of Patent: January 29, 2013Assignee: Akzo Nobel Coatings International B.V.Inventors: Stephen Arthur Wheeler, Richard Barcock, Colin Pearce, Gary Jefferson, Anthony David Woods, Simon Nicholas Emmett, Javier Perez-Amoros
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Publication number: 20120312194Abstract: A method for producing a reaction product including at least one synthetic formulation that carbonates sufficiently, said method comprising: providing a first raw material, having a first concentration of M; providing a second raw material, having a second concentration of Me; and mixing the first raw material and the second raw material to produce a reaction product that includes at least one synthetic formulation having the general formula MaMebOc, MaMeb(OH)d, MaMebOc(OH)d or MaMebO(OH)d.(H2O)e, wherein M comprises at least one metal that can react to form a carbonate and Me is at least one element that can form an oxide during the carbonation reaction, wherein the at least one synthetic formulation is capable of undergoing a carbonation reaction, and wherein the at least one synthetic formulation is capable of undergoing volume change during the carbonation reaction.Type: ApplicationFiled: June 7, 2012Publication date: December 13, 2012Applicant: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEYInventors: Richard E. RIMAN, Thomas E. NYE, Vahit ATAKAN, Cekdar VAKIFAHMETOGLU, Qinghua LI, Ling TANG
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Publication number: 20120136093Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.Type: ApplicationFiled: January 16, 2012Publication date: May 31, 2012Applicants: THE TEXAS A & M UNIVERSITY, DOW GLOBAL TECHNOLOGIES LLCInventors: Luyi Sun, Woong Jae Boo, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Publication number: 20120107512Abstract: The invention relates to a binder for binding RBSC (reaction-bonded silicon carbide), which is used to prepare RBSC assembly, wherein it includes a sintered body obtained by sintering a mixed powder of at least one substance selected from the group having Al, Ti, Fe, Mg, Cu and Ge, and silicon, or a powder obtained by milling the sintered body; and with regard to the mixing ratio of the mixed powder, the maximum amount of silicon is an amount rendering the complete melting temperature of phase in phase diagram of the mixed powder to be at most 1400° C., and the minimum amount of silicon is a larger value of either 50 at % or the minimum amount of silicon in silicon+liquid phase zone of the phase diagram, and a method of binding RBSC using the same.Type: ApplicationFiled: December 23, 2011Publication date: May 3, 2012Applicant: SKC Solmics co.,LtdInventors: Sung-sic HWANG, Soo-hwan An, Seok-ho Jang, Hyung-woo Jun, Ho-chan Lee, Kwang-il Ju
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Publication number: 20110203486Abstract: A process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound, said reaction being effected in the presence of a water-soluble dispersant having at least one polyalkyleneglycol structural unit with a functional group at one end of the polyalkyleneglycol, being able to interact as an anchor group with the surface of cement particles, the hardening accelerator composition and its use.Type: ApplicationFiled: February 25, 2011Publication date: August 25, 2011Inventors: Luc NICOLEAU, Gerhard ALBRECHT
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Publication number: 20110190443Abstract: A method for producing a thermoplastic polymeric matrix includes adding a suspension containing a silicate compound and/or barium sulfate either before or during the polymerization of the polymerizable polymeric matrix; various articles are obtained by forming this polymeric matrix, such as yarns, fibers, filaments, films and molded articles.Type: ApplicationFiled: July 20, 2009Publication date: August 4, 2011Applicant: RHODIA POLIAMIDA ESPECIALIDADES LTDAInventors: Daniel Hideki Di Petta, Karla Krivtzoff Laguens, Leo Ricardo Bedore Dos Santos, Tarcis Corderio Bastos, Thomas Canova
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Patent number: 7776232Abstract: A powdery white vulcanization promoter composition which is excellent in storage stability, the resistance of blends thereof with rubbers or the like to heat build-up, and design; and rubber compositions containing the same. Specifically, a vulcanization promoter composition which comprises a modified calcium carbonate (A) surface-treated with a fatty acid or a resin acid and a silicic acid, an inorganic filler (B) exhibiting an oil absorption of as high as 50 to 300 ml/100 g, and a vulcanization promoter component (C) liquid at ordinary temperatures, characterized in that the (A):(B) mixing ratio is within the range of 30:70 to 95:5 and the content of (C) is 30 to 80 wt % based on the whole of the promoter composition.Type: GrantFiled: August 31, 2005Date of Patent: August 17, 2010Assignee: Shiraishi Kogyo Kaisha, Ltd.Inventors: Takashi Korenaga, Takashi Deguchi, Shoichi Tsutsui
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Publication number: 20100063183Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer. The first step is to disperse a water dispersible filler material in a liquid comprising water to form a dispersion. The second step is to replace at least a portion of the water of the liquid with an organic solvent to form the filler composition, the water concentration of the liquid of the filler composition being less than six percent by weight, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step.Type: ApplicationFiled: November 16, 2007Publication date: March 11, 2010Inventors: Luyi Sun, Jae Boo Woong, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Patent number: 7611815Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.Type: GrantFiled: July 15, 2003Date of Patent: November 3, 2009Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
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Publication number: 20090260541Abstract: An ultra-fine powder formed from a naturally occurring mineral or rock material and having a controlled or “engineered” particle size distribution (PSD) to match the infrared spectra with a maximum particle size in the range of 14-17 microns measured as either D99, or preferably D95, and a minimum particle size D5 in the range of 4-7 microns. Preferably the maximum particle size is about 15 microns, the minimum particle size is about 5 microns and the D50 particle size is about 8-10 microns with the moisture content of the particle size “engineered” powder being less than about 0.20 percent by weight and preferably about 0.05 to 0.08 percent by weight of the powder. This specially “engineered” ultra-fine powder is used to reduce the thermicity of thermal film to a value less than about 20%.Type: ApplicationFiled: September 25, 2008Publication date: October 22, 2009Inventors: David D. Kragten, Christy Karr, JR., Scott VanRemortel, Robert Ratcliff, Ibezim Anazia, Louis M. Schlesinger
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Patent number: 7601213Abstract: The present invention relates to a pigment and a coating composition comprising such a pigment, wherein it is contemplated that a coating composition containing such pigment is capable of inhibiting corrosion of a substrate to which it is applied. In one embodiment, the pigment comprises a filler having calcium borate, calcium molybdate, and calcium phosphate deposited on the surface of the filler. In an exemplary embodiment, the filler is calcium carbonate.Type: GrantFiled: December 5, 2008Date of Patent: October 13, 2009Assignee: The Sherwin-Williams CompanyInventors: Charles H. Simpson, Michael W. Peck, Lisa M. Wright
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Patent number: 7563316Abstract: The invention relates to a method for producing a coloured sand composition containing a large number of silica sand grains with outer coatings of colour pigments, wherein the method comprises the following steps: mixing caustic soda and water in a predetermined ratio, preferably of 1:2, to form a dilute caustic soda; mixing boric acid in a predetermined concentration with the dilute caustic soda to form a boric acid/caustic soda solution; mixing a binder with the boric acid/caustic soda solution in a predetermined ratio to form a coating mixture; coating the silica sand grains coated with the colour pigments with the coating mixture by adding the coating mixture to the silica sand grains, and indirectly heating the silica sand grains coated with the coating mixture in a system which is spatially sealed from the heating source by means of separate chambers for the heating process and the heating source. A coloured sand composition is also described.Type: GrantFiled: July 28, 2004Date of Patent: July 21, 2009Assignee: Bene-Fit GmbHInventors: Reinhard Kräuter, Michael Flierl
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Publication number: 20090169499Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: ApplicationFiled: February 26, 2009Publication date: July 2, 2009Inventors: Patrice Bujard, Holger Leybach
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Publication number: 20090004390Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
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Publication number: 20080300442Abstract: Compositions and methods for producing a manufactured product, a method for making a liquid absorbent, and processes for disposal of flammable liquids with a flue gas desulfurization by-product. The compositions for the manufactured products combine a binder and the by-product. The composition contains a greater percentage by weight of the by-product than the binder. The methods for producing manufactured products include dewatering the gypsum-depleted waste stream to reduce a water content, and forming the manufactured product. The method for making a liquid absorbent includes dewatering, granulating, drying, heating, and packaging a granulated gypsum-depleted composition as the liquid absorbent. The processes for disposal of flammable liquids include distributing a by-product into contact with flammable liquid, absorbing the liquid, transporting, and igniting the flammable liquid. The artificial soils are a combination of by-product and animal waste.Type: ApplicationFiled: May 30, 2008Publication date: December 4, 2008Applicant: UTTER TECHNOLOGY, LLCInventor: Terry D. Utter
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Patent number: 7455726Abstract: The present invention relates to photostabilised effect pigments in which one or more calcined and vanadium-containing oxide layers, alone or mixed with sulfates, borates or phosphates, have been applied to a substrate, to a process for the preparation thereof, and to the use thereof in plastics, paints, coatings, printing inks, cosmetics, films, in security printing, for laser marking, in thermal protection or for colouring seed.Type: GrantFiled: April 27, 2004Date of Patent: November 25, 2008Assignee: Merck Patent GmbHInventors: Ulrich Schoenefeld, Padma Kaviratna
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Publication number: 20080216714Abstract: A filler material that includes a metal fluoride compound which is coated with silica. The filler material can be used in various types of covering agents.Type: ApplicationFiled: May 23, 2008Publication date: September 11, 2008Inventors: CHRIS CAPOBIANCO, SCOTT VANREMORTEL, THOMAS A. GALLO
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Publication number: 20080216713Abstract: A filler material that includes a metal fluoride compound which is coated with silica. The filler material can be used in various types of covering agents.Type: ApplicationFiled: May 22, 2008Publication date: September 11, 2008Inventors: Chris Capobianco, Scott VanRemortel, Thomas A. Gallo
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Patent number: 6793720Abstract: A solid marking composition comprises a solid matrix containing at least one type of optically variable interference pigment flakes. The solid marking composition provides a document or article with a copy and counterfeit protection feature, and is preferably used in a writing instrument for applying hand-written anti-counterfeit markings and signatures.Type: GrantFiled: September 26, 2002Date of Patent: September 21, 2004Assignee: SICPA Holding S.A.Inventors: Edgar Müller, Olivier Rozumek
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Publication number: 20040139890Abstract: A composite pigment is provided with the composite pigment including a dense inorganic material and silica. The pigment composition is characterized by a CTAB surface area of greater than about 20 m2/g; a BET surface area of greater than about 15 m2/g; and a density of greater than about 2.5 g/cm3.Type: ApplicationFiled: January 17, 2003Publication date: July 22, 2004Inventors: Fitzgerald Alphanso Sinclair, Mark Edward Wozniak, Louis Frank Gatti, William C. Fultz
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Patent number: 6706785Abstract: Platelet-shaped substrates that are coated with metal oxides and that are useful in the laser marking of plastics are disclosed. The platelet-shaped substrates may be employed as an additive to plastic for laser marking of a wide variety of plastics and for use with a number of different laser types.Type: GrantFiled: February 18, 2000Date of Patent: March 16, 2004Assignee: Rona/EMI Industries, Inc.Inventor: Guoyi Fu
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Patent number: 6610136Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.Type: GrantFiled: March 21, 2002Date of Patent: August 26, 2003Assignee: Thiele Kaolin CompanyInventors: Prakash B. Malla, Siva Devisetti
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Patent number: 6602341Abstract: A method of treating a kaolinitic clay which is intended for use as an ingredient in a ceramic composition which method comprises the steps of: (a) mixing with the kaolinitic clay from 0.1% to 15.0% by weight, based on the dry weight of the kaolinitic clay, of a smectite clay; and (b) subjecting a mass in a moist plastic state of the clay mixture formed in step (a) to mechanical working under conditions such that there is dissipated in the moist plastic mass at least 5 kJ of energy per kilogram of clay mixture on a dry weight basis.Type: GrantFiled: January 2, 2002Date of Patent: August 5, 2003Assignee: Imerys Minerals LimitedInventor: Christopher Stirling Hogg
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Publication number: 20030101908Abstract: Organic and inorganic composite pigments have an average particle diameter of 0.01 to 10.Type: ApplicationFiled: June 11, 2002Publication date: June 5, 2003Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
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Publication number: 20030056693Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.Type: ApplicationFiled: June 4, 2002Publication date: March 27, 2003Inventors: Kazuyuki Hayashi, Hiroko Morii, Keisuke Iwasaki
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Patent number: 6444025Abstract: Zirconium-containing, red-tinged bismuth vanadate pigments of general formula I, BiVbOx.Cac(MoO4)d.ZreSifOy.Fz I wherein the variables have the following meanings: b 0.8 to 1.5; c 0 to 0.3; d 0 to 0.3; e 0.01 to 0.3; f 0 to 0.3; x (3/2+5b/2); y (2e+2 f); z 0.001 to 0.5, and a process for the preparation thereof and the use thereof in pigmenting high molecular weight organic materials such as surface-coatings, plastics and printing inks.Type: GrantFiled: March 12, 2001Date of Patent: September 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Leonardus Johannes Hubertus Erkens, Gregor Schmitt, Hendrikus Maria Anna Hamers, Johannes Maria Martinus Luijten, Jozef Gertruda Emanuel Mains, Helena Francisca Maria Schulpen-Vleugels
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Patent number: 6440209Abstract: Composite pigments comprising particles of silicate or oxide minerals having deposited thereon a multiplicity of particles of a metal carbonate as a result of in-situ precipitation.Type: GrantFiled: February 9, 2000Date of Patent: August 27, 2002Assignee: Engelhard CorpoartionInventors: S. A. Ravishankar, Ernest M. Finch, Richard R. Berube
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Patent number: 6267811Abstract: An aqueous talc slurry that exhibits minimal foaming comprises talc pigment, a carboxymethyl cellulose (CMC) wetting agent having a molecular weight of between 50,000 and 150,000, an ionic polyacrylate dispersing agent, and has a solids content of between 55% and 65%. The slurry has an entrained air content of less than about 1% as measured after at least several minutes of low shear agitation. A method of preparing a talc slurry that exhibits minimal foaming comprises the sequential steps of mixing CMC wetting agent with water, adding an ionic polyacrylate dispersing agent, and dispersing talc to result in a solids content of between 55% and 65%. The resultant slurry has an entrained air content of less than 1% as measured after at least 30 minutes of low shear mixing. An aqueous talc slurry containing a small amount of xanthan gum stabilizing agent is stable for prolonged periods.Type: GrantFiled: December 21, 1998Date of Patent: July 31, 2001Assignee: Stora Enso North America Corp.Inventor: Suresh B. Cherukuri
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Patent number: 6242098Abstract: A method for producing a mineral filler and pozzolan product from fly ash is provided in which fly ash is dry processed in an air classifier to obtain a fine fraction having an average particle size of from about 0.1 to 5 microns and a coarse fraction having an average particle size of from about 6 to 20 microns. The fine fraction is then preferably passed through a magnetic separator to remove ferrous iron oxides and may optionally be treated with a surface modifier to form a mineral filler. The coarse fraction is preferably passed through a 100 mesh screen to form a pozzolan product.Type: GrantFiled: July 19, 1999Date of Patent: June 5, 2001Assignee: Mineral Resources Technologies, LLCInventors: Robert William Styron, Kamal Seyi Abiodun
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Patent number: 6139616Abstract: The present invention relates to an anti-corrosive pigment composition, characterized by comprising, as main components, white anti-corrosive pigment and an inorganic anion exchanger represented by the following formula (1):(3-4)[M.sub.1 ]O.Al.sub.2 O.sub.3.[M.sub.2 ]X.sub.2/m .multidot.nH.sub.2 O(1)(wherein, M.sub.1 and M.sub.2 are at least one selected from Ca.sup.2+ or Zn.sup.2+, X represents at least one anion selected from NO.sub.2.sup.-, NO.sub.3.sup.- or MoO.sub.4.sup.2-, m represents a valency of the anion, and n is 20 or less).Type: GrantFiled: March 30, 1999Date of Patent: October 31, 2000Assignees: Nippon Chemical Industrial Co., LTD, Toho Ganryo Kogyo Co., Ltd.Inventors: Takahiro Nagayama, Minoru Yokoyama
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Patent number: 6139960Abstract: A method for producing a mineral filler from fly ash is provided in which fly ash is dry processed in an air classifier to obtain a fine fraction having an average particle size of from about 0.1 to 5 microns. The fine fraction is then preferably passed through a magnetic separator to remove ferrous iron oxides and may optionally be treated with a surface modifier. The resulting processed fly ash may be used in a wide variety of filler applications.Type: GrantFiled: February 17, 1999Date of Patent: October 31, 2000Assignee: Mineral Resource Technologies, LLCInventors: Robert William Styron, Kamal Seyi Abiodun
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Patent number: 6139610Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides.Type: GrantFiled: June 3, 1999Date of Patent: October 31, 2000Assignee: Wayne Pigment Corp.Inventor: John Sinko
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Patent number: 6083317Abstract: An improved form of calcium carbonate which is acid resistant to enable its use as a filler material in the making of neutral to weakly acidic paper, and a process for producing this acid-resistant calcium carbonate is provided. This acid-resistant calcium carbonate composition comprises calcium carbonate and at least about 0.1% to about 25% based on the dry weight of the calcium carbonate, of sodium silicate, together with at least 0.1% to about 25 percent, based on the dry weight of the calcium carbonate, of a weak acid, such as phosphoric acid, formic acid, fluoroboric acid, polyacrylic acid, or alum, or a mixture of weak acids, such as phosphoric acid and polyacrylic acid.Type: GrantFiled: November 5, 1996Date of Patent: July 4, 2000Assignee: Imerys Pigments, Inc.Inventors: Kevin J. Snowden, Kuan-Ting Wu, Jose M. Rodriguez
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Patent number: 6074474Abstract: A multi-component pigment slurry which comprises at least 50% solids. The slurry is formulated to be admixed into paint and coating compositions to promote TiO.sub.2 extension. The slurry includes a structured pigment, a coarse particle size pigment, and a fine particle size pigment. The structured pigment comprises about 20% to about 55% of the slurry by dry weight and has a median particle size diameter of about 0.7.mu. to about 6.0.mu.. The coarse particle size pigment preferably comprises about 20% to about 60% by weight of the slurry and has a median particle size diameter of about 3.0.mu. to about 10.0.mu.. The fine particle size pigment preferably comprises up to about 50% by dry weight of the slurry and has a median particle size diameter of about 0.2.mu. to about 1.0.mu..Type: GrantFiled: April 17, 1998Date of Patent: June 13, 2000Assignee: J.M. Huber CorporationInventors: Thad T. Broome, Mark E. Wozniak, James Ray Lamb
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Patent number: 6007616Abstract: Disclosed is a system of natural colours consisting of thousands of coloured powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colours cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colours. The powders of this system are obtained by mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to colour materials and, more especially those used in the construction and architectural fields.Type: GrantFiled: October 8, 1996Date of Patent: December 28, 1999Inventor: Paulette Tourangeau
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Patent number: 5997626Abstract: A method for reducing the abrasion of a silica-containing calcined kaolin pigment by the controlled leaching of silica from the pigment, preferably by the use of a caustic solution to dissolve the silica out of the calcined kaolin. In another aspect of the invention, the brightness, opacity, or both of a calcined kaolin is increased by increasing the fineness of the kaolin feed supplied to the calciner. The combination of these methods results in the production of a calcined kaolin with low abrasion and high brightness and opacity. Another aspect of the invention concerns an improved method of filtration of dilatent materials such as the leached calcined clay.Type: GrantFiled: May 1, 1998Date of Patent: December 7, 1999Assignee: Engelhard CorporationInventors: Joseph H. Z. Wu, Michael G. Londo, Mitchell J. Willis, Rene S. Guermonprez, Tracey A. Burbank
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Patent number: 5958125Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.Type: GrantFiled: July 5, 1996Date of Patent: September 28, 1999Inventors: Raimund Schmid, Norbert Mronga
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Patent number: 5931998Abstract: Disclosed is a system of natural colors consisting of thousands of colored powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colors cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colors. The powders of this system are obtained by mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to color materials and, more especially those used in the construction and architectural fields.Type: GrantFiled: October 8, 1996Date of Patent: August 3, 1999Inventor: Paulette Tourangeau
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Patent number: 5908499Abstract: Disclosed is a system of natural colors consisting of thousands of colored powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colors cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colors. The powders of this system are obtained by a combination of two mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to color materials and, more especially those used in the construction and architectural fields.Type: GrantFiled: October 8, 1996Date of Patent: June 1, 1999Inventor: Paulette Tourangeau
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Patent number: 5897698Abstract: An aqueous, non-settling, universal nacreous pigment dispersion that can be used in dispensing machines for the custom mixing of retail and trade sales of alkyd or solvent-thinned and water-based surface coatings employs a synthetic silicate, sodium lithium magnesium silicate, as the suspending agent. Also disclosed are methods for preparing the dispersion which incorporates one or more carriers, humectants, surfactants and other optional conventional additives.Type: GrantFiled: October 18, 1996Date of Patent: April 27, 1999Assignee: Huls America Inc.Inventor: Thomas M. Bellas