Bismuth, Vanadium, Molybdenum, Or Tungsten Compound Containing (bi, V, Mo, Or W) Patents (Class 106/479)
  • Patent number: 10858728
    Abstract: A phase-transition type vanadium oxide material and a preparation method therefor. The preparation method includes the following steps: providing a vanadium oxide base material, and implanting gaseous ions into the vanadium oxide base material, to obtain a phase-transition type vanadium oxide material having a preset phase-transition temperature. Subsequently, optionally, further annealing may be performed to adjust a bubble generation status in vanadium oxide after the gaseous ions are implanted, to further adjust the stress and strain and the phase-transition temperature. The method for preparing a phase-transition type vanadium oxide material consistent with the present invention has simple steps, desirable process reproducibility, high flexibility, and the phase-transition temperature of vanadium oxide can be continuously adjusted by changing an implantation dosage of the gaseous ions.
    Type: Grant
    Filed: January 6, 2016
    Date of Patent: December 8, 2020
    Assignee: SHANGHAI INSTITUTE OF MICROSYSTEM AND INFORMATION TECHNOLOGY, CHINESE ACADEMY OF SCIENCE
    Inventors: Xin Ou, Qi Jia, Kai Huang, Xi Wang
  • Patent number: 10717664
    Abstract: The invention provides a process for the preparation of bismuth oxyhalide, comprising a precipitation of bismuth oxyhalide in an acidic aqueous medium in the presence of a reducing agent. Also provided are bismuth oxyhalide compounds doped with elemental bismuth Bi(0). The use of Bi(0) doped bismuth oxyhalide as photocatalysts in water purification is also described.
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: July 21, 2020
    Assignee: YISSUM RESEARCH DEVELOPMENT COMPANY OF THE HEBREW UNIVERSITY OF JERUSALEM LTD.
    Inventors: Yoel Sasson, Hani Gnayem
  • Patent number: 10447325
    Abstract: A metallic shell, a method for manufacturing the metallic shell and a mobile terminal including the metallic shell are provided. The metallic shell includes a body and an insulator. The body has a slot. The insulator is formed in the slot and includes an insulating material. The insulating material includes a plastic material, a first coating and a second coating. The first coating is configured to color the plastic material to make the insulator exhibit a same color as that of the body. The second coating is configured to improve luster of the plastic material to make the insulator exhibit a same metallic luster as that of the body.
    Type: Grant
    Filed: October 30, 2017
    Date of Patent: October 15, 2019
    Assignee: GUANGDONG OPPO MOBILE TELECOMMUNICATIONS CORP., LTD.
    Inventor: Zhengnan Jiang
  • Patent number: 10183280
    Abstract: The present invention relates to the photocatalyst field, and discloses a photocatalyst for removing hydroxypropyl guar gum in flow-back fluid of fracturing liquid, and a preparation method and the use of the photocatalyst, wherein, the photocatalyst is expressed by Bi5O7Br0.5I0.5, in a powder form in 12-15 nm particle size, with 285-300 m2/g specific surface area. The photocatalyst has improved response to visible light, has greater specific surface area, and has very high activity in removal of hydroxypropyl guar gum in flow-back fluid of fracturing liquid. In addition, the photocatalyst can be prepared with a simple preparation method under mild conditions, and can be used to remove hydroxypropyl guar gum in flow-back fluid of fracturing liquid.
    Type: Grant
    Filed: July 26, 2018
    Date of Patent: January 22, 2019
    Assignee: Southwest Petroleum University
    Inventors: Yang Bai, Ying Zhou, Liqun Ye, Xian Shi, Yaqin Hu
  • Patent number: 9868860
    Abstract: A bismuth vanadate pigment is provided which pigment is doped with a combination of Mg, Al and P and optionally an element E, wherein the molar ratios of the Bi, V, Mg, Al, P and E correspond to a formula Bi Mga Alb Ec Vd Pe Of??(I) wherein E is selected from the group consisting of Be, Ca, Sr, Ba, Zr, Mo, Ce and a combination thereof; 0.001?a?0.2; 0.001?b?0.2; 0?c?1.7; 0.5?d?2.3; 0.001?e?0.5; and f denotes the number of oxygen atoms for satisfying the valence requirements of the cations. The pigment may be used as colorant in various applications, especially in coloring high molecular weight organic material, for example, coating compositions, paints, printing inks, liquid inks, plastics, films, fibers, or glazes for ceramics or glass.
    Type: Grant
    Filed: July 22, 2014
    Date of Patent: January 16, 2018
    Assignee: BASF SE
    Inventors: Emily Mbayisi Mutambi, Aron Wosylus, Christof Kujat, Georg Josef Döring, Philipp Raff
  • Patent number: 9017475
    Abstract: An object of the present invention is to provide a metal pigment composition having the characteristics that aging stability is excellent, reductions of brightness, masking and flip flop appearance are little, and storage stability is excellent. The present invention is directed to a metal pigment composition containing a metal pigment treated with at least one of organic molybdenum compounds, or a metal pigment composition containing a metal pigment treated with at least one of organic molybdenum compounds, and at least one agent selected from the groups consisting of an anti-oxidizing agent, an anti-reducing agent and a photostabilizer.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: April 28, 2015
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Kazuko Nakajima, Shigeki Katsuta
  • Publication number: 20150105497
    Abstract: An inorganic filler coated with molybdenum compound used as an additive is added into a resin mixture in an amount of 20 to 80 wt % of the resin mixture, resulted in that printed circuit boards if made from a laminate or a prepreg containing the resin mixture have properties of a low coefficient of thermal expansion, good heat tolerance and excellent drilling processability.
    Type: Application
    Filed: October 1, 2014
    Publication date: April 16, 2015
    Inventors: Dein-Run FUNG, Te-Chao LIAO, Hao-Sheng CHEN, Chun-Lai CHEN
  • Patent number: 8968462
    Abstract: The subject matter of the invention relates to aqueous pigment preparations containing (A) 30 to 75% by weight of at least one inorganic white or colored pigment or a mixture of different inorganic white or colored pigments, (B) 0.01 to 15% by weight of at least one fatty acid ethanol amide ethoxylate of the formula (I), in which R1 is a linear or branched alkyl radical or alkenyl radical with 7 to 21 carbon atoms, and n is a whole number from 2 to 40, (C) 0.01 to 5% by weight of at least one amine of the formula (II), in which R2 is a linear or branched alkyl radical or alkenyl radical with 8 to 22 carbon atoms, identical to or different from R1, A represents an iminopropyl group —NH—CH2—CH2—CH2—, an oxyethyl group —O—CH2—CH2— or an oxypropyl group —O—CH2—CH(CH3)—CH2—, and a is a whole number from 0 to 5, wherein the compound of the formula (II); can be present in the form of an ammonium salt, and (E) water.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: March 3, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Hendrik Ahrens
  • Patent number: 8926870
    Abstract: Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.
    Type: Grant
    Filed: January 29, 2013
    Date of Patent: January 6, 2015
    Assignee: Sandia Corporation
    Inventors: James L. Krumhansl, Tina M. Nenoff
  • Publication number: 20140308489
    Abstract: The present invention provides a novel surface-treated molybdenum compound powder and provides a prepreg, a laminate, a metal foil laminate, a printed wiring board, and the like that have a low thermal expansion coefficient in the planar direction, and excellent drillability, heat resistance, and flame retardancy. The surface-treated molybdenum compound powder of the present invention has at least part of the surface thereof coated with an inorganic oxide, and this is used as a filler.
    Type: Application
    Filed: September 12, 2012
    Publication date: October 16, 2014
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Tetsuro Miyahira, Yoshihiro Kato, Takaaki Ogashiwa, Hiroshi Takahashi
  • Publication number: 20140290530
    Abstract: The present disclosure provides a metal compound. The metal compound is represented by a formula (I): Cu2A?B2-?O4-? (I). A contains at least one element selected from the groups 6 and 8 of the periodic table. B contains at least one element selected from the group 13 of the periodic table, 0<?<2, and 0<?<1.5. Polymer article containing the metal compound and method for preparing the polymer article as well as selective metallization of a surface of the polymer article are also provided. In addition, the present disclosure provides an ink composition and the selective metallization for a surface of the insulative substrate using the ink composition.
    Type: Application
    Filed: April 1, 2014
    Publication date: October 2, 2014
    Applicants: BYD COMPANY LIMITED, SHENZHEN BYD AUTO R&D COMPANY LIMITED
    Inventors: Qing GONG, Wei ZHOU, Bifeng MAO, Weifeng MIAO
  • Publication number: 20140261085
    Abstract: A compound or a pigment comprising a compound where there is simultaneous substitution of more or more elements onto both the A and B sites of a pyrochlore lattice or a lattice related to a pyrochlore. The pigment comprises a compound with the formula of AyA?y?BxB?x?Zp. Elements A and A? have a valence of 1, 2, or 3; and are selected from the elements of groups 1, 2, 12, 13, 14, 15, and the first row of transition metals, excluding H, Pb, Cd, Hg, N, As, and Tl. Elements B and B? have a valence of 3, 4, 5, or 6; and are selected from the elements of the first, second, or third row of transition metals, groups 13, 14, and 15, excluding V, C, Pb, and Tl. Element Z is selected from O, F, N, a chalcogen, S, Se, hydroxide ion, and mixtures thereof.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: The Shepherd Color Company
    Inventors: Simon K. Boocock, Andrew E. Smith, Miroslav Trojan
  • Publication number: 20140076201
    Abstract: A coated metal pigment that has excellent passivation, dispersion and adhesion properties, a method for producing the coated metal pigment and a coating composition that includes the coated metal pigment are described.
    Type: Application
    Filed: September 14, 2012
    Publication date: March 20, 2014
    Applicant: SILBERLINE MANUFACTURING CO. INC.
    Inventors: Anand SUNDARARAMAN, Yungwan KWAK, Craig KEEMER, John BUCHALA, Mary Kate THOMAS, Chang XU, Parfait Jean Marie LIKIBI
  • Publication number: 20140057112
    Abstract: Pigment compositions are described that advantageously increase total solar reflectance. Also described are methods of making pigment compositions. The pigment compositions can contain copper oxide; copper antimony oxides, copper bismuth oxides, or combinations thereof; and alkaline earth metal oxides, early-transition metal oxides, post-transition metal oxides, metalloid (semi-metal) oxides, rare-earth metal oxides, or combinations thereof.
    Type: Application
    Filed: May 9, 2012
    Publication date: February 27, 2014
    Applicant: FERRO CORPORATION
    Inventor: Wei Lang
  • Publication number: 20140031455
    Abstract: The present invention relates to a method for producing a compound that comprises a pseudolaminar silicate of natural origin, which is at least one clay of the paligorskite-sepiolite group, characterized in that said method comprises the following steps: defibrillating the microfibre bundles of the at least one clay in water; dispersing the defibrillated clay in an organic or inorganic liquid solvent until a stable gel is formed; adding to the dispersion at least one clay-surface-modifying agent; removing the solvent from the dispersion by means of a solid-liquid separation process and/or drying process; and deagglomerating the final compound until a powdered product is obtained. A further object of the present invention is the compound that can be obtained using said method, as well as the use of the compound as an additive or filler in composite polymeric materials in order to enhance the properties thereof, the composite polymeric material likewise being encompassed within the present invention.
    Type: Application
    Filed: January 30, 2012
    Publication date: January 30, 2014
    Inventors: Julio Santarén Romé, Eduardo Aguilar Diez, Antonio Esteban Cubillo, Antonio Álvarez Berenguer, Esperanza Benito Cano, Nuria García García, Julio Guzmán Perote, Pilar Tiemblo Magro
  • Publication number: 20130101813
    Abstract: Provided is a metallic-pigment composition which is usable in coating compositions or ink compositions, in particular, in water-based coating compositions or aqueous inks, and which gives coating compositions having excellent storage stability. The metallic-pigment composition gives a coating film having excellent performances with respect to brightness, hiding properties, flip-flop feeling, etc., causes no colorant or organic-pigment discoloration, and has excellent adhesion and chemical resistance. The metallic-pigment composition comprises one or more mixed-coordination-type heteropolyanion compounds, a hydrolyzate of a silicon compound and/or a condensate thereof, and metal particles.
    Type: Application
    Filed: April 26, 2011
    Publication date: April 25, 2013
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Kazuko Nakajima, Kaoru Ueyanagi
  • Patent number: 8409343
    Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.
    Type: Grant
    Filed: January 21, 2009
    Date of Patent: April 2, 2013
    Assignee: Mayan Pigments, Inc.
    Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
  • Publication number: 20120296025
    Abstract: The invention provides a treated powder having improved loose bulk density comprising a silanized inorganic powder treated with a long chain fatty acid or salts thereof, wherein the amount of the long chain fatty acid is about 0.25% to about 2 wt %, based on the total weight of the treated powder.
    Type: Application
    Filed: July 27, 2012
    Publication date: November 22, 2012
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Timothy Allan Bell, Joy Sawyer Bloom
  • Patent number: 8303706
    Abstract: The present invention provides a non-toxic yellow inorganic pigment consist of samarium and molybdenum oxides which may be used as additives to plastics, glasses, ceramics and paints. The samarium molybdenum yellow pigment preferably comprise Sm6MoO12 having a cubic crystal structure. Inorganic pigments according to the invention are formed by mixing stoichiometric amounts of (NH4)6Mo7O24.4H2O and Sm2O3; ball milled and calcined 1500-1650 C for 10-12 h in air atmosphere. The well ground calcined powders were used for characterization of the pigments. The phase purity and optical properties of the prepared pigments were investigated. A further aspect of the present invention is to provide of colouring a substrate. The method includes the steps of providing a substrate, and adding a samarium molybdate yellow pigment to the substrate. The samarium molybdate yellow pigment may be dispersed in the substrate or coated on the substrate.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: November 6, 2012
    Assignee: Council of Scientific & Industrial Research
    Inventor: Mundlapudi Lakshmipathi Reddy
  • Patent number: 8268202
    Abstract: Disclosed are potassium cesium tungsten bronze solid solution particles of the formula KxCsyWOz, where x+y?1 and 2?z?3. The particles are for instance micron or nano scaled particles. Also disclosed are organic or inorganic compositions comprising an organic or inorganic substrate and incorporated therein the present potassium cesium tungsten bronze solid solution particles. The substrates are for instance plastics, coatings, inks, adhesives, ceramics or glass. Also disclosed is a method for the preparation of the present potassium cesium tungsten bronze solid solution particles, which method comprises mixing a suitable tungsten source with a salt of potassium and a salt of cesium to form a powder mixture and exposing the powder mixture to a plasma torch under a reducing atmosphere. The present tungsten bronze particles are suitable NIR absorbers and heat shielding additives.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE
    Inventors: Marc Andrew Mamak, Urs Lehmann, Urs Leo Stadler, Ralf Stefan Knischka
  • Publication number: 20120216717
    Abstract: This disclosure relates to inorganic particles, typically inorganic metal oxide or mixed metal oxide particles, and more typically titanium dioxide (TiO2) particles, comprising at least about 0.002% of tungsten, based on the total weight of the inorganic particles, wherein inorganic particles have a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. These titanium dioxide particles comprising tungsten may further comprise alumina.
    Type: Application
    Filed: November 9, 2010
    Publication date: August 30, 2012
    Applicant: E. I. DUPONT DE NEMOURS AND COMPANY
    Inventors: John Davis Bolt, Eugene Michael McCarron, III, Charles David Musick
  • Publication number: 20120160130
    Abstract: A tinting system for producing a defined number of shades of a paint ready for use characterized by: (a) a dye set, (b) a color identification means, and (c) plurality of metering means for accommodating a shade component, and a brightening component. Each metering means being designed to manually meter the respective dye component and to exactly reproduce the number of shades defined by the color identification means.
    Type: Application
    Filed: June 1, 2010
    Publication date: June 28, 2012
    Applicant: HEUBACH GMBH
    Inventor: Rainer Heubach
  • Publication number: 20120110921
    Abstract: The present invention relates to sintered abrasive grit agglomerates based on aluminum oxide, having homogeneously distributed nanoscale pores in the range of 100-300 nm, with a pore volume of at least 15%. The average diameter of primary particles of the aluminum oxide primary particles is less than 5 ?m, wherein said primary particles are connected to each other without additional adhesive agent.
    Type: Application
    Filed: July 21, 2009
    Publication date: May 10, 2012
    Applicant: Center for Abrasives and Refractories Research & Development C.A.R.R.D. GmbH
    Inventors: Maria Christina DiDavide, Reiner Kunz
  • Publication number: 20120100769
    Abstract: The present invention proposes the development of inorganic green pigment, having a general formula, RE2MoO6 (where RE is mixed rare earth metal and Mo is molybdenum metal) comprising mixed rare earth elements having atomic number in the range of 57 to 66 and having a composition of at least lanthanum in the range of 43-45% w/w, neodymium in the range of 33-35% w/w, praseodymium in the range of 9-10% w/w, samarium in the range of 4-5% w/w and other rare earths to a maximum of 5% w/w and molybdenum. The colorant can be prepared in a convenient and inexpensive method utilizing the solid state route by calcining the mixed rare earth carbonate and ammonium molybdate at a temperature range of 900-1100° C. for 3-6 h at a heating rate of 10° C./min followed by grinding. The well ground calcined powders were used for characterization of the pigments. The phase purity and optical properties of the prepared pigments were investigated.
    Type: Application
    Filed: March 29, 2010
    Publication date: April 26, 2012
    Inventor: Mundlapudi Lakshmipathi Reddy
  • Publication number: 20120017807
    Abstract: The present invention provides a non-toxic yellow inorganic pigment consist of samarium and molybdenum oxides which may be used as additives to plastics, glasses, ceramics and paints. The samarium molybdenum yellow pigment preferably comprise Sm6MoO12 having a cubic crystal structure. Inorganic pigments according to the invention are formed by mixing stoichiometric amounts of (NH4)6Mo7O24.4H2O and Sm2O3; ball milled and calcined 1500-1650 C for 10-12 h in air atmosphere. The well ground calcined powders were used for characterization of the pigments. The phase purity and optical properties of the prepared pigments were investigated. A further aspect of the present invention is to provide of colouring a substrate. The method includes the steps of providing a substrate, and adding a samarium molybdate yellow pigment to the substrate. The samarium molybdate yellow pigment may be dispersed in the substrate or coated on the substrate.
    Type: Application
    Filed: September 30, 2009
    Publication date: January 26, 2012
    Inventor: Mundlapudi Lakshmipathi Reddy
  • Publication number: 20120016058
    Abstract: Manganese vanadium tantalum oxide that can be represented by the formula MnxVyTazOw, where 1?x?3, 0.001?y?3, 0.001?z?2, and w=7, and alternately, x=1.25?x?2.45, 0.1?y?2.39, 0.2?z?1.9, and w=7, methods of producing MnxVyTazOw, a pigment coated with MnxVyTazOw and a chalcogenide glass layer, and a method of producing the coated pigment are described. The disclosed manganese vanadium tantalum oxide has superior near-infrared reflective properties. The disclosed methods of producing the manganese vanadium tantalum oxide provide products with superior phase purity, appearance and performance and take health and safety into consideration. The construction of the disclosed coated pigment combines the reflective properties of the substrate with the near-infrared reflective properties of MnxVyTazOw, while the chalcogenide glass layer provides aesthetic appeal. The disclosed method of producing the coated pigment involves physical vapor deposition of MnxVyTazOw, and the chalcogenide glass layer.
    Type: Application
    Filed: July 15, 2010
    Publication date: January 19, 2012
    Applicant: SILBERLINE MANUFACTURING COMPANY, INC.
    Inventors: Stewart James WARRENDER, Hai Hui LIN, Parfait Jean Marie LIKIBI, Rajasekar PITCHIMANI, Devidas Balu RASKAR, David ALDOUS
  • Patent number: 8083847
    Abstract: To provide an infrared-shielding body sufficiently transmitting visible rays, having no half-mirror shaped appearance, requiring no large-scale apparatus when forming a film on a substrate, efficiently shutting invisible near-infrared rays with wavelength range of 780 nm or more, while eliminating a heat treatment at high temperature after film formation, and having a spectral characteristic such as transparency with no change of color tone. The starting material, which is a mixture containing a predetermined amount of a tungsten compound, is heated at 550° C. in a reductive atmosphere for 1 hour, then cooled to room temperature once in an argon atmosphere, thus producing powder of W18O49. Then, the powder, the solvent, and the dispersant are mixed, then subjected to dispersion treatment to obtain a dispersion solution. The dispersion solution and a UV-curable hardcoat resin are mixed to obtain a solution of fine particle dispersion of infrared-shielding material.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: December 27, 2011
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Hiromitsu Takeda, Kenji Adachi
  • Publication number: 20110250341
    Abstract: A silica containing composition is disclosed. The silica composition comprising a compound having the following formula (SiO2)x(OH)yMzOaF: wherein M optionally exists and said M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01-100%; and wherein the molar ratio of y/x is equal to 0.01-0.5, the molar ratio of x/z is equal to 0.1-300, and the molar ratio of a/z is dependent on the nature of the metal oxide formed.
    Type: Application
    Filed: April 8, 2010
    Publication date: October 13, 2011
    Inventors: Bruce A. Keiser, Nicholas S. Ergang, Richard Mimna
  • Publication number: 20110212832
    Abstract: In one embodiment, an aqueous dispersion liquid contains at least one particles selected from tungsten oxide particles and tungsten oxide composite particles. A mean primary particle diameter (D50) of the particles is in the range of 1 nm to 400 nm. In the aqueous dispersion liquid, concentration of the particles is in the range of 0.1 mass % to 40 mass %, and pH is in the range of 1.5 to 6.5. The aqueous dispersion liquid excels in dispersibility of particles and capable of maintaining good liquidity for a long period.
    Type: Application
    Filed: September 2, 2010
    Publication date: September 1, 2011
    Inventors: Kayo Nakano, Akira Sato, Yasuhiro Shirakawa, Keiichi Fuse, Shinya Kasamatsu, Akito Sasaki
  • Patent number: 7998266
    Abstract: This invention provides a colored metallic pigment, which can develop a variety of colors and varied interference colors while maintaining good lightfastness, weatherfastness and hiding power, a process for producing the same, a coating composition containing the colored metallic pigment and capable of providing a coating film having excellent finished appearance, and a cosmetic preparation containing the colored metallic pigment, having excellent hiding power, and capable of providing sharp hue. The colored metallic pigment comprises at least a metallic pigment, an amorphous silicon oxide film layer provided on the surface of the metallic pigment, a metal layer provided on the surface of the amorphous silicon oxide film layer, and metallic particles provided on the surface of the metal layer. The metallic particles are provided so as to directly cover a part of the surface of the metal layer.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: August 16, 2011
    Assignee: Toyo Aluminium Kabushiki Kaisha
    Inventors: Taro Morimitsu, Takayuki Nakao, Yoshiki Hashizume, Hideaki Minamiyama, Masakazu Nakamura
  • Patent number: 7955430
    Abstract: A coating material comprising a binding agent and at least one filler including particles having a size and/or surface roughness of about 100 ?m or less, and a photocatalytically active agent. The binding agent may be at least partially decomposed by a photocatalytic action, and a microstructured, self-cleaning surface may be formed.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: June 7, 2011
    Assignee: STO AG
    Inventor: Peter Grochal
  • Patent number: 7931746
    Abstract: The present invention is directed to pigment compositions with the formula BiwMnxCoyCuzO40, wherein w is between 7 and 9, x is between 3 and 13, y is between 2 and 13, z is between 0.5 and 7 and the sum of w, x, y and z is 26. The invention also is directed to thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: April 26, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson, Veda L. Evans
  • Publication number: 20110057156
    Abstract: The present invention relates to a method for producing delaminated/exfoliated non-ionic inorganic materials, to such materials and their use as additives.
    Type: Application
    Filed: October 10, 2008
    Publication date: March 10, 2011
    Applicant: DET SELVEJENDE INSTITUT CISMI (FOND)
    Inventor: Kjeld Schaumburg
  • Patent number: 7887849
    Abstract: The invention relates to a pigment mixture consisting of at least two constituents, constituent A being uncoated, monocoated or multicoated glass lamellae, and constituent B being nacreous pigments based on phyllosilicates, SiO2 lamellae, Fe2O3 lamellae or Al2O3 lamellae. The invention also relates to the use of said pigment mixture, inter alia, in paints, dyes, especially printing inks, plastics, powder paints, pastes and cosmetic formulations.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: February 15, 2011
    Assignee: Merck Patent GmbH
    Inventors: Dieter Heinz, Ralf Anselmann, Klaus Boehm, Sabine Schoen
  • Publication number: 20100298482
    Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.
    Type: Application
    Filed: January 21, 2009
    Publication date: November 25, 2010
    Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
  • Patent number: 7837782
    Abstract: The present invention provides yellow inorganic pigments comprising praseodymium, oxides of transition metals selected from molybdenum, titanium, zirconium and combinations thereof, essentially molybdenum, optionally with alkaline earth metal (A) and the said yellow inorganic pigment has a general formula APr2MoTmxO6+? or Pr2MoTmxO6+? (Tm=Ti or Zr, x=0 or 1, and wherein ? has a value commensurate with the value of x and sufficient to satisfy the valencies of the formula). High purity chemicals such as MgCO3, CaCO3, SrCO3, BaCO3, TiO2, ZrO2, (NH4)6Mo7O24.4H2O and Pr6O11 are weighted in the stoichiometric ratio, ball milled and calcined in the range 900°-1200° C. for 3-12 hrs in air.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: November 23, 2010
    Assignee: Council of Scientific and Industrial Research
    Inventors: Padala Prabhakar Rao, Mundlapudi Lakshmipathi Reddy
  • Publication number: 20100291014
    Abstract: Disclosed are pigment mixtures containing at least two components, where component A contains bismuth oxychloride (BiOCl) or boron nitride (BN) and component B contains synthetic flakes treated with at least one metal soap or mineral flakes treated with at least one metal soap and to the use thereof especially in cosmetic formulations.
    Type: Application
    Filed: May 13, 2010
    Publication date: November 18, 2010
    Applicant: MERCK Patent Gesselschaft
    Inventors: Mark Tellefsen, Qinyun Peng
  • Patent number: 7833331
    Abstract: Corrosion-inhibiting pigments based on cobalt are described that contain a trivalent or tetravalent cobalt/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent cobalt ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent cobalt during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Cobalt/valence stabilizer combinations are chosen based on the well-founded principles of cobalt coordination chemistry. Many cobalt-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: November 16, 2010
    Assignee: University of Dayton
    Inventors: Jeffrey Allen Sturgill, Andrew Wells Phelps, Joseph Thomas Swartzbaugh
  • Patent number: 7811376
    Abstract: An aqueous pigment preparation containing: (A) at least one organic and/or inorganic pigment; (B) at least one water-soluble or water-dispersible non-ionic oligoester or polyester, which is obtained by the polycondensation of dicarboxylic acid and glycol components, said oligoester or polyester comprising I) one or more aromatic dicarboxylic acids, their esters or anhydrides, II) C2-C8 alkenediols, III) poly (C1-C4-alkene)glycols and/or methylpoly(C2-C4 alkene)glycols, IV) optional water-soluble addition products of alkene oxide on C1-C24 alcohols, C6-C18 alkylphenols or on C8-C24 alkylamines and V) one or more optional polyols; (C) optional additional dispersants and surfactants that are conventionally used to produce aqueous pigment dispersions; (D) optional additional additives that are conventionally used to produce aqueous pigment dispersions; and (E) water.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: October 12, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Bjoern Fechner, Frank-Peter Lang, Alexander Lerch, Uwe Bechtold, Hendrik Ahrens
  • Publication number: 20100255047
    Abstract: The present invention relates to effect pigments based on thin glass flakes and to a method for the production of such pigments. The resulting pigment can be used in any application for which pearlescent pigments have been heretofore used such as, for example, in plastics, paints, inks, cosmetic formulations, coatings including solvent or waterborne automotive paint systems, powder coatings, inks and agriculture foils.
    Type: Application
    Filed: June 16, 2010
    Publication date: October 7, 2010
    Inventors: Ralf ANSELMANN, Klaus Ambrosius, Marcus Mathias
  • Patent number: 7806976
    Abstract: There is provided an aluminum pigment including an aluminum particle having a film formed on a surface thereof, wherein the film contains a metallic amine salt and the metallic amine salt is represented by the compositional formula RmHnN+?O—M(?O)2—OH (wherein M represents a metal element, R represents a hydrocarbon chain optionally having a substituent, m represents an integer of 1 or more, and n represents an integer satisfying n=4?m).
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: October 5, 2010
    Assignee: Toyo Aluminium Kabushiki Kaisha
    Inventor: Takayuki Nakao
  • Publication number: 20100227181
    Abstract: A bright pigment 100 includes: a flaky substrate 10; a first layer 20 that is formed on the flaky substrate 10 and that contains one selected from the group consisting of titanium dioxide, silver and a silver alloy as its main component; and a second layer 30 that is formed so that the first layer 20 is interposed between the flaky substrate 10 and the second layer 30 and that contains the hydroxide or hydrated oxide of neodymium.
    Type: Application
    Filed: October 17, 2008
    Publication date: September 9, 2010
    Applicant: NIPPON SHEET GLASS COMPANY, LIMITED
    Inventor: Takeaki Kitamura
  • Patent number: 7789958
    Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.
    Type: Grant
    Filed: January 4, 2007
    Date of Patent: September 7, 2010
    Assignee: University of Dayton
    Inventors: Jeffrey A. Sturgill, Andrew Wells Phelps, Joseph T. Swartzbaugh
  • Publication number: 20100210450
    Abstract: Nanoparticles comprising tungsten, methods of manufacturing nanoparticles comprising tungsten, and applications of nanoparticles comprising tungsten, such as electronics, optical devices, photonics, reagents for fine chemical synthesis, pigments, and catalysts are provided.
    Type: Application
    Filed: April 27, 2010
    Publication date: August 19, 2010
    Applicant: PPG INDUSTRIES OHIO, INC.
    Inventor: Tapesh Yadav
  • Patent number: 7767018
    Abstract: Disclosed is a metal pigment composition which can be used in an aqueous coating and shows excellent storage stability of a coating agent, and which is reduced in the deterioration of glossiness, hiding power, flip-flop property and the like when formed into a coating film. Specifically disclosed is a metal pigment composition which is treated with at least one amine salt of a heteropoly acid. The heteroatom constituting the heteropoly acid is at least one element selected from the elements belonging to Groups III, IV and V. The polyatom constituting the heteropoly acid is a transition metal. The amount of the amine salt of the heteropoly acid is preferably 0.01 to 10 parts by weight relative to 100 parts by weight of a metal pigment. The metal pigment is preferably an aluminum flake.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: August 3, 2010
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Kazuko Nakajima, Shigeki Katsuta
  • Publication number: 20100175587
    Abstract: The present invention relates to interference pigments based on coated flake-form substrates which are distinguished by the fact in that they comprise (A) a layer of SiO2 having a layer thickness of 5-350 nm, (B) a high-refractive-index coating having a refractive index n of >1.8 and/or (C) an interference system consisting of alternating high- and low-refractive-index layers and optionally (D) an outer protective layer, and to the use thereof in paints, coatings, automotive paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tent awnings, as absorbers in the laser marking of paper and plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, and for the preparation of pigment preparations and dry preparations.
    Type: Application
    Filed: March 22, 2010
    Publication date: July 15, 2010
    Inventors: Reinhold Rueger, Klaus Ambrosius, Marcus Mathias, Helge Bettina Kniess
  • Patent number: 7749321
    Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: July 6, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jerome D. Smith, Pedro A. Jimenez, Tony Jackson
  • Publication number: 20100154680
    Abstract: The present invention relates to pigment granules which contain inorganic filter aids and a process for the production thereof and their use for colouring lime- and/or cement-bound building materials, asphalt, paints, finishes, paper or plastics.
    Type: Application
    Filed: August 20, 2009
    Publication date: June 24, 2010
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: Holger Friedrich, Herbert Kunstmann, Krzysztof Chlopek, Jüergen Kischkewitz
  • Publication number: 20100092700
    Abstract: The invention provides a laser marking additive comprising mixed oxides of tin and a transition metal. Methods of making and using the additive are also provided.
    Type: Application
    Filed: October 15, 2008
    Publication date: April 15, 2010
    Inventors: James CARROLL, Steven Alan JONES, William LOUCKA
  • Patent number: 7662227
    Abstract: The present invention relates to compounds on apatite basis, having the general formula M5 (A04)3X wherein X is situated in the hexagonal channels of the apatite structure and includes Cu-atoms, processes for the preparation thereof as well as applications of these compounds. The compounds presented herein are particularly useful as pigments.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: February 16, 2010
    Assignee: Max-Planck-Gesellschaft zur Forderung der Wissenschaften e.V.
    Inventors: Pavel E. Kazin, Andrei S. Karpov, Martin Jansen