Bismuth, Vanadium, Molybdenum, Or Tungsten Compound Containing (bi, V, Mo, Or W) Patents (Class 106/479)
  • Patent number: 6602339
    Abstract: An aluminum pigment excellent in water resistance useful in water-based metallic paints, water-based metallic inks and the like, is provided. The pigment is excellent in water resistance and has a coating derived from peroxo-polymolibdate represented by the compositional formula: MoO3.mH2O2.nH2O or MoO3-m(O2)m.nH2O where Mo is molybdenum, O is oxygen, 0≦m≦1 and 1≦n≦2 and also includes at least one amine selected from alkylamine, allylamine, arylamine, alkanolamine or alkoxylamine.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: August 5, 2003
    Assignee: Toyo Aluminium Kabushiki Kaisha
    Inventors: Yoshiki Hashizume, Takayuki Nakao
  • Patent number: 6596073
    Abstract: The invention relates to a solid pigment composition comprising a) at least one pigment, b) at least one compound selected from the group consisting of b0) a phenol-styrene-polyglycol ether or an ionically modified phenol-styrene-polyglycol ether, b1) a condensation product prepared from b1A) sulphonated aromatics b1B) aldehydes and/or ketones and b1C) optionally one or more compounds selected from the group of unsulphonated aromatics, urea and urea derivatives, and b2) phosphoric acid, phosphonic acid and derivatives thereof, and c) at least one organic thickener.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: July 22, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roger Nyssen, Josef Witt
  • Patent number: 6582506
    Abstract: Pigment flakes having cores preferably composed of resins, polymers, thermoplastics, and/or thermosets with colorant (pigment and/or dyes) deposited thereon, coating applications thereof, and a method for making pigment flakes which includes providing a core material, compounding the core material, processing the core material into uniform forms such as films, wires, thread with rectangular cross sections and bead strings, providing colorant material, vaporizing the colorant material, exposing a surface of core material to the vaporized colorant material to form a layer of colorant on thereon, and fracturing the resultant colorant layered core material into flakes.
    Type: Grant
    Filed: May 25, 2001
    Date of Patent: June 24, 2003
    Assignee: Hampden Papers, Inc.
    Inventor: Michael E. Archambeault
  • Patent number: 6582507
    Abstract: A bismuth oxychloride effect pigment has a zinc oxide or microfine titanium dioxide particulate at about the surface of the crystals of the bismuth oxychloride. The pigment is prepared by, for instance, growing the bismuth oxychloride crystals, and adding the particulate before the hydrolysis is complete.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: June 24, 2003
    Assignee: Engelhard Corporation
    Inventors: Paul B. Cao, Michael Venturini
  • Patent number: 6582814
    Abstract: Rare earth-transition metal oxides are used as pigments. The rare earth-transition metal oxide pigments are preferably of the formula (RexTm)Oy, where Re is at least one rare earth element, Tm is at least one transition metal, x ranges from 0.08 to 12, and y ranges from x+1 to 2x+2. The pigments are useful as colorants, and possess good stability.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: June 24, 2003
    Assignee: DMC2 Degussa Metals Catalysts Cerdec AG
    Inventors: Daniel R. Swiler, Terry J. Detrie, Enos A. Axtell, III
  • Patent number: 6579357
    Abstract: A bismuth oxychloride effect pigment exhibiting improved light stability has a discontinuous coating of hydrous iron oxide on the crystals of the bismuth oxychloride. The pigment is prepared by growing the bismuth oxychloride crystals, adding a hydrolyzable iron salt thereto and then hydrolyzing the iron salt.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: June 17, 2003
    Assignee: Engelhard Corporation
    Inventor: Paul Cao
  • Patent number: 6572695
    Abstract: A bismuth oxychloride effect pigment has a carbon black particulate at about the surface of the crystals of the bismuth oxychloride. The pigment is prepared by, for instance, growing the bismuth oxychloride crystals, and adding the particulate before the hydrolysis is complete.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: June 3, 2003
    Assignee: Engelhard Corporation
    Inventor: Paul B. Cao
  • Publication number: 20030097965
    Abstract: The present invention relates to coloured interference pigments based on multicoated, platelet-shaped substrates, which are distinguished in that they comprise
    Type: Application
    Filed: October 24, 2002
    Publication date: May 29, 2003
    Applicant: Merck Patent GmbH
    Inventors: Lilia Heider, Manuela Loch, Nicole Schupp, Helge Kniess
  • Patent number: 6551397
    Abstract: The present invention relates to a pigment preparation comprising BiOCl pigments, one or more luster pigments and spherical particles, and to the use thereof in printing inks, security printing inks, surface coatings, paints, plastics and in cosmetic formulations.
    Type: Grant
    Filed: April 29, 2002
    Date of Patent: April 22, 2003
    Assignee: Merck Patent GmbH
    Inventors: Joachim Weitzel, Wolfgang Hechler
  • Patent number: 6547869
    Abstract: Described is a process for preparing a powder coating material, in which a mixture comprising binders, pigments and also, where appropriate, fillers, additives and cross linkers is extruded and then ground. The pigment fraction of this mixture at least in part comprises surface-modified effect pigment that has been coated with a low molecular mass polyethylene or polypropylene. Also, described is a powder coating material prepared by this process and the use of effect pigments coated with low molecular mass polyethylene or polypropylene to prepare powder coating materials.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: April 15, 2003
    Assignee: Merck Patent GmbH
    Inventor: Tobias Witt
  • Publication number: 20030039836
    Abstract: The invention relates to multilayered interference pigments which comprise a platelet-shaped substrate of silicon dioxide which is coated alternately with layers of light-transparent materials having refractive indices of n>1.8 and layers of light-transparent materials having refractive indices of n≦1.8, where the optical thickness of the platelet-shaped substrate and the optical thickness of the individual layers of light-transparent materials having refractive indices of n≦1.8 are the same.
    Type: Application
    Filed: August 2, 2002
    Publication date: February 27, 2003
    Applicant: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Helge Kniess, Peter Reynders
  • Patent number: 6508876
    Abstract: A colored interference pigment having a platelet-shaped layer as substrate, a coating of at least one metal oxide layer and, optionally, a further layer, at least two layers comprising or consisting of colorants.
    Type: Grant
    Filed: February 9, 2000
    Date of Patent: January 21, 2003
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bernhardt, Hans-Dieter Brückner, Karl Osterried, Reiner Vogt
  • Patent number: 6503468
    Abstract: A method of doping vanadium pentoxide with silver comprising the steps of: providing vanadium pentoxide gel providing stable colloidal silver and combining the vanadium pentoxide gel and the colloidal silver at room temperature for a period sufficient for vanadium (+5) to be electrochemically reduced to vanadium (+4) and for silver to be oxidized (+1).
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: January 7, 2003
    Assignee: Eastman Kodak Company
    Inventors: James R. Sandifer, David S. Uerz
  • Patent number: 6503310
    Abstract: Laser markable coatings include a marking pigment and a fixing material. The marking pigment may comprise titanium dioxide, zinc oxide, zinc sulfide or the like. The fixing material may comprise bismuth trioxide, antimony oxide and the like, and preferably has a melting temperature below 1,300° C. A preferred laser marking composition includes TiO2 and Bi2O3 in a weight ratio of about 1:1. After application to a substrate and laser irradiation, the fixing material stabilizes the resultant mark.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: January 7, 2003
    Assignee: DMC2 Degussa Metals Catalysts Cerdec AG
    Inventor: Robert Michael Sullivan
  • Patent number: 6503316
    Abstract: The present invention relates to additive, pigment or colorant materials which may be used for laser marking. The materials comprise oxides of bismuth and at least one additional metal. Preferred laser-markable bismuth-containing oxide compounds are of the formula BixMyOz, where M is at least one metal selected from Zn, Ti, Fe, Cu, Al, Zr, P, Sn, Sr, Si, Y, Nb, La, Ta, Pr, Ca, Mg, Mo, W, Sb, Cr, Ba and Ce, x is from about 0.3 to about 70, y is from about 0.05 to about 8, and z is from about 1 to about 100. The bismuth-containing material may be dispersed in a substrate which is subsequently irradiated by a laser to provide a contrasting mark in the irradiated region.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: January 7, 2003
    Assignee: DMC2 Degussa Metals Catalysts Cerdec AG
    Inventors: George Emil Sakoske, Joseph E. Sarver
  • Patent number: 6503304
    Abstract: A flowable and pumpable aqueous semifinished product of gassing stability for the production of paints and lacquers comprises water, a pre-stabilized metallic pigment and an anticorrosive pigment.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: January 7, 2003
    Assignee: ECKART-Werke Standard-Bronzepulver-Werke Carl Eckart GmbH & Co.
    Inventors: Andreas Korn, Robert Maul
  • Patent number: 6494943
    Abstract: Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C. for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: December 17, 2002
    Assignee: Cabot Corporation
    Inventors: Yuan Yu, Friedrich K. von Gottberg, Robert M. Amici, Paul S. Palumbo
  • Patent number: 6485557
    Abstract: Manganese vanadium oxides are used as pigments. The mnanganese vanadium oxide pigments are of the formula Mn2V2O7. The, pigments are useful as colorants, and also possess improved reflectance characteristics in the infrared region, thereby reducing IR-induced heat buildup.
    Type: Grant
    Filed: July 6, 2000
    Date of Patent: November 26, 2002
    Assignee: DMC
    Inventor: Daniel Russell Swiler
  • Patent number: 6478866
    Abstract: Aqueous pigment preparations containing a) at least one pigment, b) at least one condensation product based on A) suphonated aromatics, B) aldehydes and/or ketones and optionally C) one or several compounds selected from the group of non sulphonated aromatics, urea and urea derivatives, and c) at least one polyether polyol with a boiling point of above 150° C., at normal pressure. The inventive preparations are highly suitable for pigmenting natural or synthetic materials.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 12, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roger Nyssen, Wolfgang Zarges, Achim Brand, Thomas Roick, Hans Peter Geiger
  • Publication number: 20020157574
    Abstract: The present invention relates to a pigment preparation comprising BiOCl pigments, one or more luster pigments and spherical particles, and to the use thereof in printing inks, security printing inks, surface coatings, paints, plastics and in cosmetic formulations.
    Type: Application
    Filed: April 29, 2002
    Publication date: October 31, 2002
    Applicant: Merck Patent GmbH
    Inventors: Joachim Weitzel, Wolfgang Hechler
  • Patent number: 6472547
    Abstract: This invention provides a process for producing bismuth tertiary amyloxide which is a starting material for forming a ferroelectric film such as SrBi2Ta2O9 containing bismuth oxide, or an oxide superconductive film such as Bi2Sr2CaCu2O8, by the CVD method or sol-gel method. This process comprises reacting bismuth bromide with sodium tertiary amyloxide or potassium tertiaryamyloxide in a toluene solvent containing 5 to 30 weight % tetrahydrofuran, then separating a byproduct sodium bromide or potassium bromide by filtration and recovering bismuth tertiary amyloxide by distillation under reduced pressure.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: October 29, 2002
    Assignee: Kabushikikaisha Kojundokagaku Kenyusho
    Inventors: Satoru Morisawa, Masamichi Matsumoto, Hidekimi Kadokura
  • Patent number: 6464772
    Abstract: The present invention relates to very durable bismuth-based inorganic pigments with a light vivid yellow to orange color corresponding to the following general formula: BiV(1−n)XnO(4−3n) in which X is a halogen or a mixture of halogens and n can vary from 0 to 1. The invention also relates to the process for the manufacture of such pigments.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: October 15, 2002
    Assignee: Gebroeders Cappelle N.V.
    Inventors: Frank Vermoortele, Emile Joseph Buyse
  • Patent number: 6458197
    Abstract: The present invention relates to a pigment based on bismuth vanadate with a bright vivid yellow to orange color exhibiting improved resistance, in particular an improved resistance to heat, characterized in that it is coated with several layers of inorganic compounds in several successive stages, the last layer being based on a zinc and boron compound. The present invention also relates to the process for producing this pigment and to its application.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: October 1, 2002
    Assignee: Gebroeders Cappelle, N.V.
    Inventors: Frank Vermoortele, Emile Joseph Buyse
  • Patent number: 6444025
    Abstract: Zirconium-containing, red-tinged bismuth vanadate pigments of general formula I, BiVbOx.Cac(MoO4)d.ZreSifOy.Fz  I wherein the variables have the following meanings: b 0.8 to 1.5; c 0 to 0.3; d 0 to 0.3; e 0.01 to 0.3; f 0 to 0.3; x (3/2+5b/2); y (2e+2 f); z 0.001 to 0.5, and a process for the preparation thereof and the use thereof in pigmenting high molecular weight organic materials such as surface-coatings, plastics and printing inks.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: September 3, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Leonardus Johannes Hubertus Erkens, Gregor Schmitt, Hendrikus Maria Anna Hamers, Johannes Maria Martinus Luijten, Jozef Gertruda Emanuel Mains, Helena Francisca Maria Schulpen-Vleugels
  • Patent number: 6428615
    Abstract: Pigment preparations including as essential blending components A) an inorganic pigment from the group of the bismuth vanadate pigments and rutile pigments and B) a phosphate, are produced and used for coloring polymeric materials.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: August 6, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Hansulrich Reisacher, Oliver Seeger
  • Patent number: 6423131
    Abstract: Bismuth vanadate pigments comprising at least one coating containing calcium fluoride, bismuth oxyfluoride or a lanthanide fluoride or oxyfluoride or a mixture thereof are useful for coloring paints, printing inks and plastics.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: July 23, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Seeger, Hansulrich Reisacher, Norbert Mronga, Reinhard Zickgraf
  • Publication number: 20020056402
    Abstract: Bismuth vanadate pigments comprising at least one coating containing calcium fluoride, bismuth oxyfluoride or a lanthanide fluoride or oxyfluoride or a mixture thereof are useful for coloring paints, printing inks and plastics.
    Type: Application
    Filed: September 2, 1999
    Publication date: May 16, 2002
    Inventors: OLIVER SEEGER, HANSULRICH REISACHER, NORBERT MRONGA, REINHARD ZICKGRAF
  • Patent number: 6387498
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6383638
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: May 7, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6379449
    Abstract: Nitride or oxidenitride based red to yellow pigments, such as tantalum(V) nitride and oxidenitrides containing tantalum may be produced by passing ammonia over nitridable metal compounds, in particular oxide compounds, at 700 to 1250° C. According to the invention, nitriding proceeds in a rotary tube or fluidised bed reactor in the presence of an oxide from the series SiO2, ZrO2, GeO2, SnO2, TiO2 and HfO2 under conditions under which this oxide is substantially not nitrided.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: April 30, 2002
    Assignee: dmc
    Inventors: Martin Jansen, Eberhard Günther, Hans-Peter Letschert
  • Patent number: 6358307
    Abstract: Vanadium dioxide particles having formula V1−xMxO2, wherein 0≦x≧0.05 and M is a doping metal, and being characterized in that they have a particle size of less than 10 &mgr;m, a method for preparing same, and the use of said microparticles, in particular for surface coating, are disclosed.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: March 19, 2002
    Assignee: Les Peintures Jefco
    Inventors: Pierre Legrand, Jean-Raymond Gavarri, Jean-Christophe Valmalette, Gilbert Vacquier, Daniel Lefevre
  • Patent number: 6277187
    Abstract: A film for cutting off heat rays having a high transmittance and a low reflectivity of visible light, a low transmittance and a high reflectivity of near infrared radiation and a surface resistivity of at least about 106 ohms/square is formed from a coating liquid is a dispersion containing fine particles of borides having an average diameter not exceeding 100 nm. The liquid disperison is coated on a surface and heated. The dispersion may further contain fine particles of at least one ruthenium or iridium oxide having an average diameter not exceeding 100 nm.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: August 21, 2001
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Hiroko Kuno, Hiromitsu Takeda, Kenji Adachi
  • Publication number: 20010009130
    Abstract: A flowable and pumpable aqueous semifinished product of gassing stability for the production of paints and lacquers comprises water, a pre-stabilized metallic pigment and an anticorrosive pigment.
    Type: Application
    Filed: January 16, 2001
    Publication date: July 26, 2001
    Inventors: Andreas Korn, Robert Maul
  • Patent number: 6238471
    Abstract: Multilayer interference pigment having a blue mass tone, comprised of a platelet-shaped carrier material and a coating which is formed from (i) a first layer of a colorless, transparent metal oxide of high refractive index, (ii) a second layer of colorless, transparent metal oxide of low refractive index and (iii) a third, outer layer of cobalt aluminate, cobalt-containing glass, tungsten bronzes or cobalt oxide, it also being possible for the first and third layer to be swapped around.
    Type: Grant
    Filed: February 1, 1999
    Date of Patent: May 29, 2001
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Reiner Vogt, Hans-Dieter Brückner
  • Patent number: 6221147
    Abstract: Bismuth manganese oxide pigments are used as additives to various materials such as plastics, plastic or organic coating compositions, glass and ceramic coating compositions, and the like. The bismuth manganese oxide pigments preferably comprise Bi2Mn4O10 crystallized in the orthorhombic crystal structure. The pigments possess improved reflectance characteristics, particularly in the IR region, and may reduce IR-induced heat buildup.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: April 24, 2001
    Assignee: Cerdec Aktiengesellschaft Keramischre Farben
    Inventors: George Emil Sakoske, Joseph E. Sarver, Miroslav Novotny
  • Patent number: 6171383
    Abstract: Bismuth manganese oxide green pigments are used as additives to various materials such as plastics, plastic or organic coating compositions, glass and ceramic coating compositions, and the like. The green bismuth manganese oxide pigments preferably comprise Bi12MnO20 crystallized in the cubic crystal structure. The pigments possess improved reflectance characteristics, particularly in the IR region, and may reduce IR-induced heat buildup.
    Type: Grant
    Filed: November 17, 1999
    Date of Patent: January 9, 2001
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: George Emil Sakoske, Joseph E. Sarver
  • Patent number: 6156695
    Abstract: A hydrodenitrogenation catalyst is prepared by decomposing a nickel (ammonium) molybdotungstate precursor and sulfiding, either pre-use or in situ, the decomposition product.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: December 5, 2000
    Assignee: Exxon Research and Engineering Company
    Inventors: Stuart L. Soled, Sabato Miseo, Roman Krycak, Hilda Vroman, Teh C. Ho, Kenneth L. Riley
  • Patent number: 6132505
    Abstract: The present invention relates to inorganic pigment pellets for coloring building materials, lacquers and plastics and to a process for the production thereof and to the use thereof inter alia for the production of pastes, suspensions and emulsion paints.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: October 17, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Linde, Kai Butje, Manfred Eitel
  • Patent number: 6080232
    Abstract: The invention relates to spherical colored pigments having an average particle diameter of less than 10 .mu.m on the basis of an oxide, a mixed oxide or a silicate. The pigments are obtainable by means of spray-pyrolysis technology: a solution containing oxide-forming or silicate-forming metal compounds is converted into an aerosol and the latter is fed, preferably after predrying, to a pyrolysis reactor; the pigment is separated from the pyrolysis gas. The colored pigments according to the invention are suitable for the production of ceramic decorations and for the coloring of plastics, synthetic foils, fibers and also lacquers. By reason of the spherical shape, unusual technical application properties are achieved.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: June 27, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Jorg Sperlich, Ralph Brandes, Hauke Jacobsen, Stipan Katusic, Andreas Schulz
  • Patent number: 6080808
    Abstract: The molding composition contains, in a flowable binder, from 20 to 50% by vol., based on the total volume of the molding composition, of a powder comprising one or more metal oxides and, if desired, metal carbides and/or metal nitrides which cannot be reduced using hydrogen, where at least 65% by vol. of the powder has a maximum particle size of 0.5 .mu.m and the remainder of the powder has a maximum particle size of 1 .mu.m, and at least 90% by vol. of the powder comprises metal oxides which can be reduced using hydrogen. The metal oxides which can be reduced using hydrogen are Fe.sub.2 O.sub.3, FeO, Fe.sub.3 O.sub.4, NiO, CoO, Co.sub.3 O.sub.4, CuO, Cu.sub.2 O, Ag.sub.2 O, Bi.sub.2 O.sub.3, WO.sub.3, MoO.sub.3, SnO, SnO.sub.2, CdO, PbO, Pb.sub.3 O.sub.4, PbO.sub.2 or Cr.sub.2 O.sub.3, or mixtures thereof.
    Type: Grant
    Filed: January 5, 1998
    Date of Patent: June 27, 2000
    Assignee: BASF Aktiengesellschaft
    Inventor: Hans-Josef Sterzel
  • Patent number: 6068688
    Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: May 30, 2000
    Assignee: Cabot Corporation
    Inventors: Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
  • Patent number: 6063182
    Abstract: A stir-in pigment composition for coloring high-molecular-weight material, particularly coatings and ink systems, comprises 85 to 99.5 parts by weight of a pigment and 0.5 to 15 parts by weight of an additive comprising a vinylpyrrolidone polymer or copolymer. The stir-in pigment composition is in the form of microgranules and is obtainable by spray drying a high solids content aqueous pigment dispersion containing the pigment and the additive. The new pigment composition powders are easily handled, easily wetted and disperse rapidly to form homogeneous aqueous pigment dispersions which are practically free of larger pigment aggregates and can readily be incorporated into aqueous ink and paint systems as stir-in pigments without a dispersion step in a bead mill.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: May 16, 2000
    Assignee: Ciba Speciality Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 6036764
    Abstract: The present invention relates to a yellow pigment blend containing a) a yellow nickel titanate pigment, b) a yellow bismuth vanadate, and c) a yellow isoindolinone pigment, wherein a hardened pigmented article resulting from the blend is characterized according to the CIE tristimulus values system by having a value for Y of at least about 36, a value for x between 0.48 and 0.51 and a value for y between 0.44 and 0.47. The yellow pigment blend has very good heat resistance for hot melt application and very good lightfastness for long term durability.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: March 14, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Kim Diane Gooding, James Martin Delaney
  • Patent number: 6022404
    Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: February 8, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Manfred Ettlinger, Werner Hartmann, Dieter Kerner, Jurgen Meyer
  • Patent number: 5997627
    Abstract: The disclosure describes pigment compositions containing a small particle size porous filler and a pigment, and their use for preparing effect coating compositions which produce thin film finishes exhibiting strong lightness and color flop with a pronounced three dimensional effect. The thin film finishes are particularly interesting as automotive finishes.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: December 7, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5993523
    Abstract: Metal particles useful for coating compositions, particularly aqueous coating compositions, are produced by treating the metal particles with a molybdate pigment. The molybdate pigment reacts with the surface of the metal particles. The molybdate pigment may be a salt such as a molybdate, phosphomolybdate or silicomolybdate salt, and the salt may include a multivalent cation such as calcium, strontium, barium, magnesium, zinc and aluminum. The metal particles show improved resistance to attack by water.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: November 30, 1999
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: Craig B. Keemer, William G. Jenkins, H. Taylor Lamborn, Robert E. Souerwine
  • Patent number: 5976238
    Abstract: Pigment powder mixtures, consisting of0.999-0.5 part of C.I. Pigment Yellow 184, and0.001-0.5 part of an organic pigment selected from the group consisting of C.I. Pigment Orange 13, C.I. Pigment Orange 34, C.I. Pigment Orange 36, C.I. Pigment Orange 73, C.I. Pigment Red 170, C.I. Pigment Red 254, C.I. Pigment Red 255 and C.I. Pigment Red 264,or of0.99-0.5 part of C.I. Pigment Yellow 184, and0.01-0.5 part of an organic pigment selected from the group consisting of C.I. Pigment Yellow 83, C.I. Pigment Yellow 110 and C.I. Pigment Yellow 139.These pigment powder mixtures are distinguished, in particular in paints, by very high chroma.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: November 2, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Leonardus Johannes Hubertus Erkens, Gregor Schmitt, Hendrikus Maria Anna Hamers, Johannes Maria Martinus Luijten, Jozef Gertruda Emanuel Mains
  • Patent number: 5961710
    Abstract: The invention relates to granules of inorganic pigments, a process for their production using several auxiliary substances by compacting and their use in many technical fields.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: October 5, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Linde, Manfred Eitel, Olaf Schmidt-Park, Kai Butje
  • Patent number: 5958125
    Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: September 28, 1999
    Inventors: Raimund Schmid, Norbert Mronga
  • Patent number: 5958126
    Abstract: Bismuth vanadate pigments of the formula (Bi.sub.4 V.sub.2 O.sub.11).sub.1-x.(BiVO.sub.4).sub.x, where 0.ltoreq.x<0.9, further comprising from 0 to 0.5% by weight of phosphorus in the form of bismuth phosphate, are characterized by a CIELAB hue angle of from 64 to 91.degree., a chroma of from 72 to 95 and a lightness.gtoreq.62 (measuring angle 45.degree., standard illuminant D65).
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: September 28, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Jorg Adel, Boubacar Camara, Norbert Mronga