Organic Silicon Material Containing Patents (Class 106/490)
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Patent number: 12234361Abstract: The present disclosure relates to a combined treatment method for surface modification of fumed silica, which comprises the following steps: (1) two sets of modification devices are used to jointly treat fumed silica; the fumed silica is modified with a modifier in the reaction furnace of each set of modification devices to obtain two groups of modified fumed silica and exhaust gas respectively; (2) the exhaust gas obtained in step (1) is separated respectively to obtain unreacted modifier and by-products, and the obtained by-products are input into the reaction furnace of the other set of modification devices as reaction assistants to participate in the modification reaction; and the obtained unreacted modifiers are returned to the reaction furnace of the original modification device for repeated use.Type: GrantFiled: August 9, 2022Date of Patent: February 25, 2025Assignees: GUANGZHOU HUIFU RESEARCH INSTITUTE CO., LTD., HUBEI HUIFU NANOMATERIAL CO., LTD.Inventors: Xianjian Duan, Chunlei Wu, Yuelin Wang, Shiyu Xu, Chenggang Wang
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Patent number: 12173127Abstract: Described herein are composite materials composed of ceramic particles coated with a surfactant incorporated within a polymer matrix, methods of making same, filaments composed of the same, and articles printed using the filaments. The composite materials and articles described herein have desirable electronic and thermal properties for use in radio frequency (RF) and millimeter wave devices and demonstrate reliable performance at elevated humidity levels.Type: GrantFiled: August 6, 2020Date of Patent: December 24, 2024Assignee: UNIVERSITY OF SOUTH FLORIDAInventors: Jing Wang, Vishvajitsinh Kosamiya
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Patent number: 12145852Abstract: The purpose of the present invention is to provide: silica particles of which the maximum particle diameter can be minimized and which can achieve proper fluidability that cannot be achieved by the conventional techniques; and silica spherical particles which, when used as a filler for a heat-dissipating sheet, can achieve excellent heat conductivity and flexibility. Silica spherical particles characterized in that, when particles each having a size of 5 ?m or more and imaged by an optical measurement are observed, the particle diameter of each of the particles, which is determined from the image, satisfies the following requirements. Requirements: D99?29 ?m, and 10 ?m?Dmode<D99, and D99/Dmode?1.5, and Dmode?20 ?m.Type: GrantFiled: November 13, 2019Date of Patent: November 19, 2024Assignee: NIPPON STEEL CHEMICAL & MATERIAL CO., LTD.Inventors: Katsumasa Yagi, Dota Saito, Mutsuhito Tanaka, Masanori Ae, Hiroyuki Deai
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Patent number: 12129393Abstract: The present invention relates to a composition comprising a binder comprising one or more siloxane polymers, silicone resins, silicone based elastomers, and mixtures thereof, wherein said binder optionally comprises one or more cross-linker components comprising a silane and/or a siloxane containing silicon-bonded hydrolysable groups; and a hydrophilic powder and/or gel selected from one or more amorphous, porous hydrophilic silica (s) having a thermal conductivity at 20° C. and atmospheric pressure of 0.001 to 0.15 W/m·K and a surface area (SBET) of between 200 and 1500 m2/g, one or more hydrophilic aerogel (s) and mixtures thereof, wherein the binder is a solution, an emulsion, or a dispersion in water. The invention also relates to the use of the composition as or in thermally or acoustically insulating materials and to coated substrates, products and articles made by using the composition.Type: GrantFiled: January 23, 2019Date of Patent: October 29, 2024Assignees: DOW SILICONES CORPORATION, WORLEE-CHEMIE GMBHInventors: Thorsten Adebahr, Joachim Müller, David Pierre
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Patent number: 12030810Abstract: The present invention relates to a thermal insulating composition, containing 5 to 60% by weight of a hydrophobized granular material comprising fumed silica and at least one IR-opacifier, and 40 to 95% by weight of an inorganic and/or an organic binder, whereby the hydrophobized granular material has a content of free hydroxyl groups of no greater than 0.12 mmol/g, as determined by the reaction with lithium aluminium hydride.Type: GrantFiled: July 8, 2019Date of Patent: July 9, 2024Assignee: Evonik Operations GmbHInventors: Matthias Geisler, Maria Nargiello, Bettina Gerharz-Kalte, Björn Lazar, Uwe Numrich, Ulrich Boes, Bob Tse-Weng Lin, Craig Biesiada
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Patent number: 11987501Abstract: An aqueous hydrophobic silica dispersion includes a hydrophilic particulate silica, a hydrophobic particulate silica having a methanol number of at least 60, and a dispersant having at least one cationic or cationizable group and an HLB ratio of 2 to 20.Type: GrantFiled: January 24, 2019Date of Patent: May 21, 2024Assignee: Cabot CorporationInventors: Lang H. Nguyen, Kavita K. Pai, Steven Jacobs, Tianqi Liu, Melissa J. Monello, Angelica M. Sanchez Garcia, Zhangliang Gui, Takashi Umehara
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Patent number: 11952465Abstract: Amino-functionalized linear and cyclic oligosiloxanes, which have at least two silicon and two oxygen atoms as well as an organoamino group and methods for making the oligosiloxanes are disclosed. Methods for depositing silicon and oxygen containing films using the organoamino-functionalized linear and cyclic oligosiloxanes are also disclosed.Type: GrantFiled: September 29, 2020Date of Patent: April 9, 2024Assignee: VERSUM MATERIALS US, LLCInventors: Manchao Xiao, Matthew R. MacDonald, Xinjian Lei, Meiliang Wang
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Patent number: 11851554Abstract: Disclosed is a rubber composition including a copolymer including polyethylene, ?-olefin, and non-conjugated polyene; natural rubber; a filler; and a coupling agent, a vehicle part including the same, and a vehicle including the same. The rubber bushing composition includes the components uniformly dispersed such that compatibility and physical properties thereof can be improved. Further, a product (e.g., vehicle part) obtained from the rubber bushing composition can have superior heat resistance, fatigue resistance, and compression set resistance.Type: GrantFiled: September 2, 2022Date of Patent: December 26, 2023Assignees: Hyundai Motor Company, Kia CorporationInventors: Sung Hyun Lee, Heon Seob Jung
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Patent number: 11830533Abstract: [Solving Means] A method of producing a magnetic powder includes: coating a surface of each of silica-coated precursor particles with at least one type of coating agent of a metal chloride or a sulfate; and firing the precursor particles coated with the coating agent.Type: GrantFiled: March 27, 2019Date of Patent: November 28, 2023Assignee: Sony CorporationInventors: Natsuki Toyosawa, Norikatsu Fujisawa, Yuta Akimoto, Satoru Abe, Masaru Terakawa, Katsunori Maeshima, Atsushi Muramatu, Masafumi Nakaya
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Patent number: 11649367Abstract: There are disclosed aqueous pigment dispersions containing dispersant-improving-agents, and methods of preparing and using the same.Type: GrantFiled: September 21, 2022Date of Patent: May 16, 2023Assignee: LANDA LABS (2012) LTD.Inventors: Galia Golodetz, Benzion Landa, Sagi Abramovich, Dan Avital, Jose Kuperwasser, Omer Ashkenazi
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Patent number: 11603470Abstract: A method for manufacturing granulated silica. The method includes granulating silica powders each having a primary particle size of 5 to 50 nm by use of water, and hydrophobizing each surface of the silica powders with a silicon atom-containing hydrophobizing agent before or simultaneously with the granulation step.Type: GrantFiled: June 19, 2020Date of Patent: March 14, 2023Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masanobu Nishimine, Tomoya Ogata, Daichi Todoroki, Tsutomu Nakamura, Susumu Ueno
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Patent number: 11590474Abstract: A stable, solid, externally dry particulate system for controlling humidity to a selected range comprising a hydrophobic silica component and a hydrophilic silica component where the hydrophobic component comprises about 4 to 10 wt. % hydrophobic nano silica particles and from about 96 to 90 wt. % of a mixture of a saturated solution of at least one soluble solid and undissolved at least one soluble solid, and the hydrophilic micro silica component comprises from about 20 to 40 wt. % hydrophilic silica particles and about 80 to 60 wt.% of the mixture of the saturated solution of at least one soluble solid and the undissolved at least one soluble solid. The saturated solution is made of at least one soluble solid dissolved into a polar liquid and has an equilibrium relative humidity when a saturated solution in the polar liquid.Type: GrantFiled: August 14, 2020Date of Patent: February 28, 2023Assignee: JEA Holdings, LLCInventor: Jeffrey W. Akers
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Patent number: 11578217Abstract: A water based paint that can be used to form a superhydrophobic coating includes a fluorinated particulate filler, a water soluble or water suspendable resin, and an aqueous solvent. The superhydrophobic paint can be applied to a surface where the loss of the solvent results in a superhydrophobic coating.Type: GrantFiled: February 28, 2018Date of Patent: February 14, 2023Assignee: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, IncorporatedInventors: Wolfgang M. Sigmund, Yung-Chieh Hung, Neil Macinnes
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Silicon carbide powder and method of preparing the same using a hydrophobic spherical silica aerogel
Patent number: 11220434Abstract: The present invention relates to a method of preparing ultra-pure silicon carbide in which a super-porous spherical silica aerogel is used as a silica raw material. By preparing the silica aerogel particles using low-cost water glass, a reaction area with respect to a carbon raw material is increased to enable low-temperature synthesis of silicon carbide, the size and shape of silicon carbide powder may be uniformly controlled to prepare ultra-pure silicon carbide, and economic efficiency and productivity of the silicon carbide synthesis may be improved. Thus, it is expected that the silicon carbide powder prepared by the preparation method of the present invention may be provided as an optimized raw material for the preparation of silicon carbide sintered body and single crystal (ingot).Type: GrantFiled: October 24, 2017Date of Patent: January 11, 2022Assignees: LG Chem, Ltd., Inha University Research And Business FoundationInventors: Young Hun Kim, Je Kyun Lee, Hae Jin Hwang, Kyoung Jin Lee -
Patent number: 11034586Abstract: A method of preparing hydrophobic porous silica includes reacting a porous silica particle containing a hydrophilic group in a solvent with an organosilane compound under a basic catalyst to form a mixture, drying the mixture comprising the porous silica particle in a vacuum, and condensation reacting the hydrophilic group of the porous silica particle with the organosilane compound on the surface of the porous silica particle to modify the surface of the porous silica particle to be hydrophobic.Type: GrantFiled: August 28, 2019Date of Patent: June 15, 2021Assignee: Research & Business Foundation Sungkyunkwan UniversityInventors: Jae Young Choi, Su Dong Chae, Jang Ho Park, Sung Ho Lee
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Patent number: 11001714Abstract: A production method for an electronic material filler includes: a preparation step of preparing a silica particle material produced by a dry method; and a first surface treatment step of performing surface treatment on the silica particle material with a silane compound having a vinyl group, a phenyl group, a phenylamino group, an alkyl group having four or more carbon atoms, a methacryl group, or an epoxy group, to obtain a first surface treatment-processed particle material. After the silica particle material is produced by the dry method, the silica particle material is not brought into contact with liquid water, and has a particle diameter of 100 nm to 600 nm or a specific surface area of 5 m2/g to 35 m2/g.Type: GrantFiled: December 16, 2019Date of Patent: May 11, 2021Assignee: ADMATECHS CO., LTD.Inventors: Yusuke Watanabe, Nobutaka Tomita, Yoshiaki Kato
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Patent number: 10822458Abstract: Amino-functionalized linear and cyclic oligosiloxanes, which have at least two silicon and two oxygen atoms as well as an organoamino group and methods for making the oligosiloxanes are disclosed. Methods for depositing silicon and oxygen containing films using the organoamino-functionalized linear and cyclic oligosiloxanes are also disclosed.Type: GrantFiled: January 30, 2018Date of Patent: November 3, 2020Assignee: Versum Materials US, LLCInventors: Manchao Xiao, Matthew R. MacDonald, Xinjian Lei, Meiliang Wang
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Patent number: 10601046Abstract: Lithium titanate, Li4Ti5O12, particles containing surface hydroxyl groups are susceptible to unwanted gas generation (such as hydrogen) in the presence of water contamination when the particles are used as active anode electrode material in lithium-ion cells operating with an anhydrous liquid electrolyte. In accordance with this disclosure, the hydroxyl groups on the surfaces of the particles are reacted with one of a group of selected agents containing organic alkoxy groups to form hydrophobic moieties on the surfaces of the particles which effectively block water molecules from the surfaces of lithium titanate particles in the anode of the cell.Type: GrantFiled: October 7, 2015Date of Patent: March 24, 2020Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Zhiqiang Yu, Haijing Liu
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Patent number: 10472483Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.Type: GrantFiled: December 25, 2015Date of Patent: November 12, 2019Assignee: NITTO DENKO CORPORATIONInventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
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Patent number: 10435531Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.Type: GrantFiled: December 25, 2015Date of Patent: October 8, 2019Assignee: NITTO DENKO CORPORATIONInventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
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Patent number: 10385179Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.Type: GrantFiled: December 25, 2015Date of Patent: August 20, 2019Assignee: NITTO DENKO CORPORATIONInventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
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Patent number: 10294111Abstract: The present invention relates to a method of preparing a high hydrophobic silica aerogel having a low tap density and a hydrophobic silica aerogel prepared thereby. The method of preparing a hydrophobic silica aerogel according to the present invention may have good productivity and economic efficiency, because preparation time is reduced by simultaneously performing surface modification and solvent substitution in a single step, and may control a degree of hydrophobicity of the prepared silica aerogel by controlling a surface modification reaction by including a step of adding ammonium hydroxide. Thus, a hydrophobic silica aerogel having excellent physical properties, such as tap density and specific surface area, as well as high hydrophobicity obtained by controlling the degree of hydrophobicity may be prepared.Type: GrantFiled: November 4, 2016Date of Patent: May 21, 2019Assignee: LG CHEM, LTD.Inventors: Young Hun Kim, Jin Hee Oh, Je Kyun Lee
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Patent number: 10297698Abstract: There is provided a coating composition comprising nonspherical nanoparticles; spherical nanoparticles; optionally hydrophilic groups and optional an surfactant; and a liquid medium comprising water and no greater than 30 wt % organic solvent, if present, based on the total weight of liquid medium, where at least a portion of the nonspherical nanoparticles or at least a portion of the spherical nanoparticles comprises functional groups attached to their surface through chemical bonds, wherein the functional groups comprise at least one group selected from the group consisting of epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto group, or combinations thereof. There is also provided a method for modifying a substrate surface using the coating composition and articles made therefrom.Type: GrantFiled: March 23, 2018Date of Patent: May 21, 2019Assignee: 3M Innovative Properties CompanyInventors: Yiwen Chu, Zhigang Yu, Naiyong Jing, Rui Pan
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Patent number: 10273400Abstract: Insulating packer fluids containing colloidal silica inorganic additives may be used in methods that reduce convective currents in a packer fluid. In other aspects, packer fluids containing colloidal silica inorganic additives may be used in methods of insulating production wells and methods for stimulating production of hydrocarbons.Type: GrantFiled: November 29, 2013Date of Patent: April 30, 2019Assignee: M-I L.L.C.Inventors: Changping Sui, Balakrishnan Panamarathupalayam, Hui Joyce Zhang, William E. Foxenberg
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Patent number: 10030124Abstract: A method for manufacturing a modified silica product includes admixing a mercapto silane and a silica to form a hydrophobated silica, and treating the hydrophobated silica with an oxidizing agent. Likewise, a method for manufacturing a silica masterbatch with the modified silica product includes the admixing a mercapto silane solution and a silica slurry to form a hydrophobated silica slurry, and then treating the hydrophobated silica slurry with an oxidizing agent to form a modified silica slurry. The modified silica slurry is blended with a rubber latex, which is then coagulated to form the silica masterbatch. Rubber formulations and articles manufactured with one of the modified silica product and the silica masterbatch are also disclosed.Type: GrantFiled: June 29, 2015Date of Patent: July 24, 2018Assignee: Cooper Tire & Rubber CompanyInventors: Howard Colvin, Peter John Wallen
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Patent number: 9878496Abstract: The invention is a package (1) for stereolithography comprising a container (2) filled with stereolithography resin (3), provided with an access opening (4), and a mixer element (5) arranged in a removable manner in the container (2) and provided with at least one magnet (6).Type: GrantFiled: July 25, 2013Date of Patent: January 30, 2018Assignee: DWS S.R.L.Inventor: Sergio Zenere
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Patent number: 9862614Abstract: Provided is a method for preparing a hydrophobic silica aerogel by using a Soxhlet extraction, and a hydrophobic silica aerogel prepared by using the method. Since the preparation method according to the present invention may simultaneously perform washing and drying of a hydrophobic silica wet gel as well as solvent substitution and may remove an extraction solvent without an additional separation process, a hydrophobic silica aerogel having low tap density and high specific surface area may be easily prepared.Type: GrantFiled: February 4, 2015Date of Patent: January 9, 2018Assignee: LG CHEM, LTD.Inventors: Kyoung Shil Oh, Jin Hee Oh, Ye Hon Kim, Dong Hyun Cho, Mi Ri Kim, Sung Min Yu, Je Kyun Lee
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Patent number: 9834684Abstract: Natural amorphous silica filler products featuring high brightness, low oil absorption, fine particle size, and low crystalline silica content are described. Methods for making, using, and measuring the properties of the natural amorphous silica filler products are also described. The natural amorphous silica filler products described herein may be useful in a variety of products including, but not limited to, polymers, sealants, paints, caulks, latex, architectural coatings, industrial coatings, pozzolan, glass catalysts, ceramic glazes, and anti-blocking applications.Type: GrantFiled: March 9, 2010Date of Patent: December 5, 2017Assignee: Imerys Filtration Minerals, Inc.Inventors: Bo Wang, Michael Greene, Rajendra Kashinath Singh
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Patent number: 9783658Abstract: A silica-containing rubber mixture is produced from a rubber, a sulphur-containing alkoxysilane, a crosslinking agent, a silica-containing filler, and 0.1 to 15 parts by weight, based on 100 parts by weight of the rubber, of a silicon-free polysulphide additive of the formula (I) A-S-(S)x-S-B where x is 0-4, and A and B are the same or different, are alkyl or aryl, and contain at last one oxygen, which may be in the form of a carboxyl group.Type: GrantFiled: April 27, 2012Date of Patent: October 10, 2017Assignee: LANXESS Deutschland GmbHInventors: Melanie Wiedemeier, Hermann-Josef Weidenhaupt, Ulrich Feldhues, Irene Moll
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Patent number: 9567229Abstract: Fumed silica having a BET surface area of 200±15 m2/g, a grindometer value of less than 30 ?m and a median value by PCS of 65 to 85 nm is prepared by grinding a fumed silica having a surface area of 200±25 m2/g, and silicone rubber containing this silica.Type: GrantFiled: February 19, 2014Date of Patent: February 14, 2017Assignee: EVONIK DEGUSSA GMBHInventors: Jürgen Meyer, Mario Scholz, Matthias Rochnia
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Patent number: 9562158Abstract: A silicone rubber-based hardening composition includes a linear organopolysiloxane having a vinyl group (A), an organohydrogen polysiloxane (B), and a silica filler (C) of which surface is treated with a silane coupling agent having a trimethylsilyl group. The linear organopolysiloxane having a vinyl group (A) includes a first linear organopolysiloxane having a vinyl group (A1), and a second linear organopolysiloxane having a vinyl group (A2).Type: GrantFiled: October 9, 2015Date of Patent: February 7, 2017Assignee: SUMITOMO BAKELITE COMPANY LIMITEDInventors: Jun Okada, Kazunobu Senoo
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Patent number: 9551107Abstract: Compositions comprising a liquid and fumed silica may be applied to fabric and other textile materials as a sealant, e.g., to protect against damage or deterioration. The composition may comprise liquid droplets at least partially or completely surrounded by fumed silica. The liquid may comprise water and one or more polymers, such as anionic polymers, anionic copolymers, fluoropolymers, fluorocopolymers, acrylic polymers, and/or acrylic copolymers. Methods of treating a textile surface with the composition may include depositing the composition on the surface and brushing the particles against the surface, for example. The composition may be in the form of a powder, such that the particles remain intact on the surface upon deposition and release liquid onto the surface upon brushing, for example.Type: GrantFiled: November 9, 2015Date of Patent: January 24, 2017Assignee: CAL-TEX PROTECTIVE COATINGS, INC.Inventors: Rande Hawkinson, Thomas Engelken, John E. Blount, Darin Klaehn
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Patent number: 9534122Abstract: Provided are surface-treated fine particles which, when added to coatings for the production of films, exhibit excellent reactivity with respect to organosilicon compounds and resins that are matrix components of the coating films, and thereby allow the films to exhibit excellent performance. Oligomer-modified fine particles include inorganic oxide fine particles having a surface modified with an oligomer, the oligomer being derived from a metal alkoxide represented by Formula (1): RnM1(OR?)z-n (1) wherein M1: one or more elements selected from Si, Ti, Zr and Al; R and R?: one or more groups selected from alkyl groups of 1 to 8 carbon atoms, aryl groups and vinyl groups; n: an integer of from 0 to (z?2); and z: the valence of M1. The oligomer has a polymerization degree of 3 or more. The oligomer has a weight average molecular weight in the range of 1000 to 10000.Type: GrantFiled: December 21, 2012Date of Patent: January 3, 2017Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Yoichi Ishihara, Toshiharu Hirai
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Patent number: 9463997Abstract: A composite oxide particle prepared from raw materials comprising: (1) a finely powdered silica having a BET specific surface area of 50 m2/g or greater or an alkoxysilane, and (2) a liquid metal alkoxide other than an alkoxysilane or a nano order metal oxide powder other than finely powdered silica, one of components (1) and (2) being a solid oxide and the other being a liquid alkoxide, wherein the composite oxide particle is prepared by mixing or kneading the raw materials to obtain a sol or gel-like substance, sintering the sol or gel-like substance at a temperature of 300° C. or higher to form a glass-like substance, and then crushing the glass-like substance is provided. Also, a resin composition containing the composite oxide particle, and a reflector for a light-emitting semiconductor device formed using the resin composition are provided.Type: GrantFiled: August 6, 2014Date of Patent: October 11, 2016Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Toshio Shiobara, Yoshihiro Tsutsumi
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Patent number: 9410077Abstract: A method for preparing an ultra-light-weight (ULW) proppant usable in the oil and gas industry. The method uses silane coupling agent and organic acid to modify silica fume (SF) to obtain modified SF that is lipophilic and hydrophobic. The modified SF is used as inorganic phase, and the polymerizable monomer is used as organic phase, and the organic-inorganic composite microspheres are obtained through suspension polymerization. The ULW proppant is obtained by drying, screening, and pre-oxidization of the composite microsphere. The ULW proppant has a density of about 1.109 g/cm3-1.278 g/cm3, which is close to that of water, a crushing rate of <5% at 52 Mpa, and a crushing rate of <7% at 69 Mpa. In the oil and gas industry application, water or salt water can be used to replace the high viscose guanidine gum as carrier, thus reduced cost of fracturing, and reduced environment pollution.Type: GrantFiled: August 13, 2015Date of Patent: August 9, 2016Assignee: CHINA UNIVERSITY OF GEOSIENCES (WUHAN)Inventors: Chunjie Yan, Yixia Wang, Tao Chen, Yonghan Zhang, Yuting Chen, Luru Jing
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Patent number: 9163135Abstract: A composition includes an elastomer and a ketoximo silane or a ketoxime additive.Type: GrantFiled: August 31, 2011Date of Patent: October 20, 2015Assignee: Bridgestone CorporationInventors: Chenchy J. Lin, Yaohong Chen, Atsushi Fukushima, William L. Hergenrother, Terrence E. Hogan
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Patent number: 8980960Abstract: Process for preparing a dispersion comprising silicon dioxide particles and cationizing agents, by dispersing 50 to 75 parts by weight of water, 25 to 50 parts by weight of silicon dioxide particles having a BET surface area of 30 to 500 m2/g and 100 to 300 ?g of cationizing agent per square meter of the BET surface area of the silicon dioxide particles, wherein the cationizing agent is obtainable by reacting at least one haloalkyl-functional alkoxysilane, hydrolysis products, condensation products and/or mixtures thereof with at least one aminoalcohol and water; and optionally removing the resulting hydrolysis alcohol from the reaction mixture. Also the process for preparing the dispersion, wherein the cationizing agent comprises one or more quaternary, aminoalcohol-functional, organosilicon compounds of formula III and/or condensation products thereof, wherein Ru and Rv are independently C2-4 alkyl group, m is 2-5 and n is 2-5.Type: GrantFiled: May 23, 2011Date of Patent: March 17, 2015Assignee: Evonik Degussa GmbHInventors: Stefan Scharfe, Andrea Heuschen, Christoph Batz-Sohn, Burkhard Standke, Christian Wassmer, Heinz Lach
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Patent number: 8974590Abstract: Methods, treatment compositions and treatment systems for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles. The process provides a coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated receptive surface. The methods, treatment compositions and treatment systems are useful in providing detachable coatings and treated articles featuring surface protective benefits including dirt- and water-repellency, self-cleaning with water, and easier cleaning benefits when applied to a variety of automotive and home surfaces, both interior and exterior.Type: GrantFiled: January 4, 2012Date of Patent: March 10, 2015Assignee: The Armor ALL/STP Products CompanyInventors: Jodi Lynn Russell, Felix Müller, Danielle Coutts, Ashot K. Serobian, Patrick Winter, Nicholas Pivonka
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Patent number: 8933164Abstract: A dispersion, comprising 0.1 to 25% by weight hydrophobized silica, 8 to 90 wt % of at least one alcohol selected from the group consisting of ethanol, 1-propanol and 2-propanol, 7 to 89 wt % of water, 0 to 30% by weight solvent immiscible with water, and 0.04 to 5 wt % of at least one carboxyvinyl polymer present in neutralized form, can be applied to a surface using a non-drip application method and, by modifying the surface with hydrophobized silica, imparts water-repelling and self-cleaning properties to the surface.Type: GrantFiled: March 16, 2010Date of Patent: January 13, 2015Assignee: Evonik Degussa GmbHInventors: Jörg Peggau, Harald Jakob, Wolfgang Lortz
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Publication number: 20140377524Abstract: An inorganic filler including a closed pore having a content of 1 to 30 vol. %, an insulation layer including the same, and a substrate using the insulation layer. With the insulation layer using the inorganic filler prepared so as to include a closed pore corresponding to a change rate in volume, the closed pore may offset change in volume in the inorganic filler and release stress, thereby improving a coefficient of thermal expansion according to change in temperature of the insulation layer.Type: ApplicationFiled: October 9, 2013Publication date: December 25, 2014Applicant: Samsung Electro-Mechanics Co., Ltd.Inventors: Ye Jun PARK, Byung Kun Kim, Jung Wook Seo
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Patent number: 8747541Abstract: Dispersion obtainable by reacting a) in 50 to 75 parts by weight of water b) 25 to 50 parts by weight of silica particles having a BET surface area of 30 to 500 m2/g and c) 100 to 300 ?g/m2 BET surface area of the silica particles from b) parts by weight of one or more aminofunctional, organosilicon compounds, the aminofunctional, organosilicon compound being a quaternary, aminofunctional, organosilicon compound which is obtainable by reacting at least one haloalkylfunctional silane as component A with a tertiary amine as component B in the presence of a defined amount of water and at least partly removing the resulting hydrolysis alcohol from the system.Type: GrantFiled: March 24, 2010Date of Patent: June 10, 2014Assignee: Evonik Degussa GmbHInventors: Stefan Scharfe, Christoph Batz-Sohn, Heinz Lach, Andrea Heuschen, Burkhard Standke, Christian Wassmer
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Publication number: 20140102334Abstract: Surface-modified, structurally modified fumed silicas are surface-modified with N-containing silicon compounds.Type: ApplicationFiled: December 23, 2013Publication date: April 17, 2014Applicant: Evonik Degussa GmbHInventors: Mario SCHOLZ, Juergen Meyer
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Publication number: 20140102332Abstract: Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.Type: ApplicationFiled: September 18, 2013Publication date: April 17, 2014Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Bok Ryul YOO, Joon Soo HAN, Dong Euy JUNG
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Patent number: 8617306Abstract: The present invention relates to hetero-coagulated silica-alumina mixed oxide compositions that have a sharp refractive index and narrow refractive index dispersion between about 1.46 and 1.60.Type: GrantFiled: June 24, 2011Date of Patent: December 31, 2013Assignee: Transparent Materials, LLCInventors: Patrick M. Lambert, Joseph F. Bringley
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Patent number: 8614256Abstract: A hydrophobic precipitated silica having a BET of less than 110 m2/g, a CTAB of less than 150 m2/g, a BET/CTAB ratio of less than 3, a carbon content of greater than 3.1%, a pH of 9.7 to 10.5, a DBP of less than 230 g/(100 g), and a methanol wettability of more than 50%. The hydrophobic precipitated silica is used in compositions including defoamers, silicone rubber and HTV crosslinkable silicone rubber compositions. The hydrophobic precipitated silica is also useful as a flow assistant and carrier or anti-blocking agent.Type: GrantFiled: February 1, 2011Date of Patent: December 24, 2013Assignee: Evonik Degussa GmbHInventors: Christian Panz, Rene Allerdisse, Helga Obladen, Mario Loebbus, Anja Lukas, Roland Bergmann, Karl Meier
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Patent number: 8568524Abstract: Provided are compositions comprising stamp sand granules embedded in asphalt, where the stamp sand granules comprise a silane coating. Additionally provided are methods of making a silane-coated stamp sand, the methods comprising combining stamp sand granules and a silane solution to form a mixture and drying the mixture. Additionally provided are methods of covering a surface, the methods comprising combining silane-coated particles and asphalt to provide a mixture and distributing the mixture on the surface.Type: GrantFiled: March 25, 2011Date of Patent: October 29, 2013Assignee: Michigan Technology UniversityInventors: Bowen Li, Ralph Hodek, Domenic Popko, Jiann-Yang Hwang
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Patent number: 8513333Abstract: The invention relates to particles which have been functionalised by means of an inertised reactive group, i.e. by means of specific reversibly blocked isocyanate groups, and whose inertization can be reversed by means of an external influence.Type: GrantFiled: April 8, 2009Date of Patent: August 20, 2013Assignee: Merck Patent GmbHInventors: Matthias Koch, Jens Pradella
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Patent number: 8455165Abstract: This invention provides metal oxide particles surface-treated with a cyclic silazane and a hydrophobicity-imparting agent, methods of making such, and toner compositions comprising the same.Type: GrantFiled: July 6, 2007Date of Patent: June 4, 2013Assignee: Cabot CorporationInventors: Dmitry Fomitchev, Hairuo Tu
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Publication number: 20130079445Abstract: The present invention is directed to a process for producing treated filler including (a) treating a slurry of untreated filler which has not been previously dried, with a treating composition including an organosilane material of specified structure (I); and (b) drying the treated filler slurry. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: ApplicationFiled: September 20, 2012Publication date: March 28, 2013Inventors: Justin J. Martin, Timothy A. Okel, Raphael O. Kollah
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Patent number: 8388859Abstract: A composition comprising a blocked and/or unblocked isocyanate compound and surface-modified nanoscale solid particles that comprise on the surface thereof organic radicals which comprise groups with an active hydrogen or precursors of such groups.Type: GrantFiled: December 5, 2005Date of Patent: March 5, 2013Assignee: Leibniz-Institut fuer Neue Materialien Gemeinnuetzige GmbHInventors: Carsten Becker-Willinger, Martin Kluke, Helmut Schmidt