Organic Silicon Material Containing Patents (Class 106/490)
  • Patent number: 11952465
    Abstract: Amino-functionalized linear and cyclic oligosiloxanes, which have at least two silicon and two oxygen atoms as well as an organoamino group and methods for making the oligosiloxanes are disclosed. Methods for depositing silicon and oxygen containing films using the organoamino-functionalized linear and cyclic oligosiloxanes are also disclosed.
    Type: Grant
    Filed: September 29, 2020
    Date of Patent: April 9, 2024
    Assignee: VERSUM MATERIALS US, LLC
    Inventors: Manchao Xiao, Matthew R. MacDonald, Xinjian Lei, Meiliang Wang
  • Patent number: 11851554
    Abstract: Disclosed is a rubber composition including a copolymer including polyethylene, ?-olefin, and non-conjugated polyene; natural rubber; a filler; and a coupling agent, a vehicle part including the same, and a vehicle including the same. The rubber bushing composition includes the components uniformly dispersed such that compatibility and physical properties thereof can be improved. Further, a product (e.g., vehicle part) obtained from the rubber bushing composition can have superior heat resistance, fatigue resistance, and compression set resistance.
    Type: Grant
    Filed: September 2, 2022
    Date of Patent: December 26, 2023
    Assignees: Hyundai Motor Company, Kia Corporation
    Inventors: Sung Hyun Lee, Heon Seob Jung
  • Patent number: 11830533
    Abstract: [Solving Means] A method of producing a magnetic powder includes: coating a surface of each of silica-coated precursor particles with at least one type of coating agent of a metal chloride or a sulfate; and firing the precursor particles coated with the coating agent.
    Type: Grant
    Filed: March 27, 2019
    Date of Patent: November 28, 2023
    Assignee: Sony Corporation
    Inventors: Natsuki Toyosawa, Norikatsu Fujisawa, Yuta Akimoto, Satoru Abe, Masaru Terakawa, Katsunori Maeshima, Atsushi Muramatu, Masafumi Nakaya
  • Patent number: 11649367
    Abstract: There are disclosed aqueous pigment dispersions containing dispersant-improving-agents, and methods of preparing and using the same.
    Type: Grant
    Filed: September 21, 2022
    Date of Patent: May 16, 2023
    Assignee: LANDA LABS (2012) LTD.
    Inventors: Galia Golodetz, Benzion Landa, Sagi Abramovich, Dan Avital, Jose Kuperwasser, Omer Ashkenazi
  • Patent number: 11603470
    Abstract: A method for manufacturing granulated silica. The method includes granulating silica powders each having a primary particle size of 5 to 50 nm by use of water, and hydrophobizing each surface of the silica powders with a silicon atom-containing hydrophobizing agent before or simultaneously with the granulation step.
    Type: Grant
    Filed: June 19, 2020
    Date of Patent: March 14, 2023
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Masanobu Nishimine, Tomoya Ogata, Daichi Todoroki, Tsutomu Nakamura, Susumu Ueno
  • Patent number: 11590474
    Abstract: A stable, solid, externally dry particulate system for controlling humidity to a selected range comprising a hydrophobic silica component and a hydrophilic silica component where the hydrophobic component comprises about 4 to 10 wt. % hydrophobic nano silica particles and from about 96 to 90 wt. % of a mixture of a saturated solution of at least one soluble solid and undissolved at least one soluble solid, and the hydrophilic micro silica component comprises from about 20 to 40 wt. % hydrophilic silica particles and about 80 to 60 wt.% of the mixture of the saturated solution of at least one soluble solid and the undissolved at least one soluble solid. The saturated solution is made of at least one soluble solid dissolved into a polar liquid and has an equilibrium relative humidity when a saturated solution in the polar liquid.
    Type: Grant
    Filed: August 14, 2020
    Date of Patent: February 28, 2023
    Assignee: JEA Holdings, LLC
    Inventor: Jeffrey W. Akers
  • Patent number: 11578217
    Abstract: A water based paint that can be used to form a superhydrophobic coating includes a fluorinated particulate filler, a water soluble or water suspendable resin, and an aqueous solvent. The superhydrophobic paint can be applied to a surface where the loss of the solvent results in a superhydrophobic coating.
    Type: Grant
    Filed: February 28, 2018
    Date of Patent: February 14, 2023
    Assignee: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, Incorporated
    Inventors: Wolfgang M. Sigmund, Yung-Chieh Hung, Neil Macinnes
  • Patent number: 11220434
    Abstract: The present invention relates to a method of preparing ultra-pure silicon carbide in which a super-porous spherical silica aerogel is used as a silica raw material. By preparing the silica aerogel particles using low-cost water glass, a reaction area with respect to a carbon raw material is increased to enable low-temperature synthesis of silicon carbide, the size and shape of silicon carbide powder may be uniformly controlled to prepare ultra-pure silicon carbide, and economic efficiency and productivity of the silicon carbide synthesis may be improved. Thus, it is expected that the silicon carbide powder prepared by the preparation method of the present invention may be provided as an optimized raw material for the preparation of silicon carbide sintered body and single crystal (ingot).
    Type: Grant
    Filed: October 24, 2017
    Date of Patent: January 11, 2022
    Assignees: LG Chem, Ltd., Inha University Research And Business Foundation
    Inventors: Young Hun Kim, Je Kyun Lee, Hae Jin Hwang, Kyoung Jin Lee
  • Patent number: 11034586
    Abstract: A method of preparing hydrophobic porous silica includes reacting a porous silica particle containing a hydrophilic group in a solvent with an organosilane compound under a basic catalyst to form a mixture, drying the mixture comprising the porous silica particle in a vacuum, and condensation reacting the hydrophilic group of the porous silica particle with the organosilane compound on the surface of the porous silica particle to modify the surface of the porous silica particle to be hydrophobic.
    Type: Grant
    Filed: August 28, 2019
    Date of Patent: June 15, 2021
    Assignee: Research & Business Foundation Sungkyunkwan University
    Inventors: Jae Young Choi, Su Dong Chae, Jang Ho Park, Sung Ho Lee
  • Patent number: 11001714
    Abstract: A production method for an electronic material filler includes: a preparation step of preparing a silica particle material produced by a dry method; and a first surface treatment step of performing surface treatment on the silica particle material with a silane compound having a vinyl group, a phenyl group, a phenylamino group, an alkyl group having four or more carbon atoms, a methacryl group, or an epoxy group, to obtain a first surface treatment-processed particle material. After the silica particle material is produced by the dry method, the silica particle material is not brought into contact with liquid water, and has a particle diameter of 100 nm to 600 nm or a specific surface area of 5 m2/g to 35 m2/g.
    Type: Grant
    Filed: December 16, 2019
    Date of Patent: May 11, 2021
    Assignee: ADMATECHS CO., LTD.
    Inventors: Yusuke Watanabe, Nobutaka Tomita, Yoshiaki Kato
  • Patent number: 10822458
    Abstract: Amino-functionalized linear and cyclic oligosiloxanes, which have at least two silicon and two oxygen atoms as well as an organoamino group and methods for making the oligosiloxanes are disclosed. Methods for depositing silicon and oxygen containing films using the organoamino-functionalized linear and cyclic oligosiloxanes are also disclosed.
    Type: Grant
    Filed: January 30, 2018
    Date of Patent: November 3, 2020
    Assignee: Versum Materials US, LLC
    Inventors: Manchao Xiao, Matthew R. MacDonald, Xinjian Lei, Meiliang Wang
  • Patent number: 10601046
    Abstract: Lithium titanate, Li4Ti5O12, particles containing surface hydroxyl groups are susceptible to unwanted gas generation (such as hydrogen) in the presence of water contamination when the particles are used as active anode electrode material in lithium-ion cells operating with an anhydrous liquid electrolyte. In accordance with this disclosure, the hydroxyl groups on the surfaces of the particles are reacted with one of a group of selected agents containing organic alkoxy groups to form hydrophobic moieties on the surfaces of the particles which effectively block water molecules from the surfaces of lithium titanate particles in the anode of the cell.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: March 24, 2020
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Zhiqiang Yu, Haijing Liu
  • Patent number: 10472483
    Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.
    Type: Grant
    Filed: December 25, 2015
    Date of Patent: November 12, 2019
    Assignee: NITTO DENKO CORPORATION
    Inventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
  • Patent number: 10435531
    Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.
    Type: Grant
    Filed: December 25, 2015
    Date of Patent: October 8, 2019
    Assignee: NITTO DENKO CORPORATION
    Inventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
  • Patent number: 10385179
    Abstract: The present invention provides, for example, a silicone porous body having a porous structure with less cracks and a high proportion of void space as well as having a strength. The silicone porous body of the present invention includes silicon compound microporous particles, wherein the silicon compound microporous particles are chemically bonded by catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The silicone porous body can be produced, for example, by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products, for example.
    Type: Grant
    Filed: December 25, 2015
    Date of Patent: August 20, 2019
    Assignee: NITTO DENKO CORPORATION
    Inventors: Hiromoto Haruta, Kozo Nakamura, Kazuki Uwada, Hiroyuki Takemoto, Nao Murakami, Daisuke Hattori
  • Patent number: 10294111
    Abstract: The present invention relates to a method of preparing a high hydrophobic silica aerogel having a low tap density and a hydrophobic silica aerogel prepared thereby. The method of preparing a hydrophobic silica aerogel according to the present invention may have good productivity and economic efficiency, because preparation time is reduced by simultaneously performing surface modification and solvent substitution in a single step, and may control a degree of hydrophobicity of the prepared silica aerogel by controlling a surface modification reaction by including a step of adding ammonium hydroxide. Thus, a hydrophobic silica aerogel having excellent physical properties, such as tap density and specific surface area, as well as high hydrophobicity obtained by controlling the degree of hydrophobicity may be prepared.
    Type: Grant
    Filed: November 4, 2016
    Date of Patent: May 21, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Young Hun Kim, Jin Hee Oh, Je Kyun Lee
  • Patent number: 10297698
    Abstract: There is provided a coating composition comprising nonspherical nanoparticles; spherical nanoparticles; optionally hydrophilic groups and optional an surfactant; and a liquid medium comprising water and no greater than 30 wt % organic solvent, if present, based on the total weight of liquid medium, where at least a portion of the nonspherical nanoparticles or at least a portion of the spherical nanoparticles comprises functional groups attached to their surface through chemical bonds, wherein the functional groups comprise at least one group selected from the group consisting of epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto group, or combinations thereof. There is also provided a method for modifying a substrate surface using the coating composition and articles made therefrom.
    Type: Grant
    Filed: March 23, 2018
    Date of Patent: May 21, 2019
    Assignee: 3M Innovative Properties Company
    Inventors: Yiwen Chu, Zhigang Yu, Naiyong Jing, Rui Pan
  • Patent number: 10273400
    Abstract: Insulating packer fluids containing colloidal silica inorganic additives may be used in methods that reduce convective currents in a packer fluid. In other aspects, packer fluids containing colloidal silica inorganic additives may be used in methods of insulating production wells and methods for stimulating production of hydrocarbons.
    Type: Grant
    Filed: November 29, 2013
    Date of Patent: April 30, 2019
    Assignee: M-I L.L.C.
    Inventors: Changping Sui, Balakrishnan Panamarathupalayam, Hui Joyce Zhang, William E. Foxenberg
  • Patent number: 10030124
    Abstract: A method for manufacturing a modified silica product includes admixing a mercapto silane and a silica to form a hydrophobated silica, and treating the hydrophobated silica with an oxidizing agent. Likewise, a method for manufacturing a silica masterbatch with the modified silica product includes the admixing a mercapto silane solution and a silica slurry to form a hydrophobated silica slurry, and then treating the hydrophobated silica slurry with an oxidizing agent to form a modified silica slurry. The modified silica slurry is blended with a rubber latex, which is then coagulated to form the silica masterbatch. Rubber formulations and articles manufactured with one of the modified silica product and the silica masterbatch are also disclosed.
    Type: Grant
    Filed: June 29, 2015
    Date of Patent: July 24, 2018
    Assignee: Cooper Tire & Rubber Company
    Inventors: Howard Colvin, Peter John Wallen
  • Patent number: 9878496
    Abstract: The invention is a package (1) for stereolithography comprising a container (2) filled with stereolithography resin (3), provided with an access opening (4), and a mixer element (5) arranged in a removable manner in the container (2) and provided with at least one magnet (6).
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: January 30, 2018
    Assignee: DWS S.R.L.
    Inventor: Sergio Zenere
  • Patent number: 9862614
    Abstract: Provided is a method for preparing a hydrophobic silica aerogel by using a Soxhlet extraction, and a hydrophobic silica aerogel prepared by using the method. Since the preparation method according to the present invention may simultaneously perform washing and drying of a hydrophobic silica wet gel as well as solvent substitution and may remove an extraction solvent without an additional separation process, a hydrophobic silica aerogel having low tap density and high specific surface area may be easily prepared.
    Type: Grant
    Filed: February 4, 2015
    Date of Patent: January 9, 2018
    Assignee: LG CHEM, LTD.
    Inventors: Kyoung Shil Oh, Jin Hee Oh, Ye Hon Kim, Dong Hyun Cho, Mi Ri Kim, Sung Min Yu, Je Kyun Lee
  • Patent number: 9834684
    Abstract: Natural amorphous silica filler products featuring high brightness, low oil absorption, fine particle size, and low crystalline silica content are described. Methods for making, using, and measuring the properties of the natural amorphous silica filler products are also described. The natural amorphous silica filler products described herein may be useful in a variety of products including, but not limited to, polymers, sealants, paints, caulks, latex, architectural coatings, industrial coatings, pozzolan, glass catalysts, ceramic glazes, and anti-blocking applications.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: December 5, 2017
    Assignee: Imerys Filtration Minerals, Inc.
    Inventors: Bo Wang, Michael Greene, Rajendra Kashinath Singh
  • Patent number: 9783658
    Abstract: A silica-containing rubber mixture is produced from a rubber, a sulphur-containing alkoxysilane, a crosslinking agent, a silica-containing filler, and 0.1 to 15 parts by weight, based on 100 parts by weight of the rubber, of a silicon-free polysulphide additive of the formula (I) A-S-(S)x-S-B where x is 0-4, and A and B are the same or different, are alkyl or aryl, and contain at last one oxygen, which may be in the form of a carboxyl group.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: October 10, 2017
    Assignee: LANXESS Deutschland GmbH
    Inventors: Melanie Wiedemeier, Hermann-Josef Weidenhaupt, Ulrich Feldhues, Irene Moll
  • Patent number: 9567229
    Abstract: Fumed silica having a BET surface area of 200±15 m2/g, a grindometer value of less than 30 ?m and a median value by PCS of 65 to 85 nm is prepared by grinding a fumed silica having a surface area of 200±25 m2/g, and silicone rubber containing this silica.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: February 14, 2017
    Assignee: EVONIK DEGUSSA GMBH
    Inventors: Jürgen Meyer, Mario Scholz, Matthias Rochnia
  • Patent number: 9562158
    Abstract: A silicone rubber-based hardening composition includes a linear organopolysiloxane having a vinyl group (A), an organohydrogen polysiloxane (B), and a silica filler (C) of which surface is treated with a silane coupling agent having a trimethylsilyl group. The linear organopolysiloxane having a vinyl group (A) includes a first linear organopolysiloxane having a vinyl group (A1), and a second linear organopolysiloxane having a vinyl group (A2).
    Type: Grant
    Filed: October 9, 2015
    Date of Patent: February 7, 2017
    Assignee: SUMITOMO BAKELITE COMPANY LIMITED
    Inventors: Jun Okada, Kazunobu Senoo
  • Patent number: 9551107
    Abstract: Compositions comprising a liquid and fumed silica may be applied to fabric and other textile materials as a sealant, e.g., to protect against damage or deterioration. The composition may comprise liquid droplets at least partially or completely surrounded by fumed silica. The liquid may comprise water and one or more polymers, such as anionic polymers, anionic copolymers, fluoropolymers, fluorocopolymers, acrylic polymers, and/or acrylic copolymers. Methods of treating a textile surface with the composition may include depositing the composition on the surface and brushing the particles against the surface, for example. The composition may be in the form of a powder, such that the particles remain intact on the surface upon deposition and release liquid onto the surface upon brushing, for example.
    Type: Grant
    Filed: November 9, 2015
    Date of Patent: January 24, 2017
    Assignee: CAL-TEX PROTECTIVE COATINGS, INC.
    Inventors: Rande Hawkinson, Thomas Engelken, John E. Blount, Darin Klaehn
  • Patent number: 9534122
    Abstract: Provided are surface-treated fine particles which, when added to coatings for the production of films, exhibit excellent reactivity with respect to organosilicon compounds and resins that are matrix components of the coating films, and thereby allow the films to exhibit excellent performance. Oligomer-modified fine particles include inorganic oxide fine particles having a surface modified with an oligomer, the oligomer being derived from a metal alkoxide represented by Formula (1): RnM1(OR?)z-n (1) wherein M1: one or more elements selected from Si, Ti, Zr and Al; R and R?: one or more groups selected from alkyl groups of 1 to 8 carbon atoms, aryl groups and vinyl groups; n: an integer of from 0 to (z?2); and z: the valence of M1. The oligomer has a polymerization degree of 3 or more. The oligomer has a weight average molecular weight in the range of 1000 to 10000.
    Type: Grant
    Filed: December 21, 2012
    Date of Patent: January 3, 2017
    Assignee: JGC Catalysts and Chemicals Ltd.
    Inventors: Yoichi Ishihara, Toshiharu Hirai
  • Patent number: 9463997
    Abstract: A composite oxide particle prepared from raw materials comprising: (1) a finely powdered silica having a BET specific surface area of 50 m2/g or greater or an alkoxysilane, and (2) a liquid metal alkoxide other than an alkoxysilane or a nano order metal oxide powder other than finely powdered silica, one of components (1) and (2) being a solid oxide and the other being a liquid alkoxide, wherein the composite oxide particle is prepared by mixing or kneading the raw materials to obtain a sol or gel-like substance, sintering the sol or gel-like substance at a temperature of 300° C. or higher to form a glass-like substance, and then crushing the glass-like substance is provided. Also, a resin composition containing the composite oxide particle, and a reflector for a light-emitting semiconductor device formed using the resin composition are provided.
    Type: Grant
    Filed: August 6, 2014
    Date of Patent: October 11, 2016
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Shiobara, Yoshihiro Tsutsumi
  • Patent number: 9410077
    Abstract: A method for preparing an ultra-light-weight (ULW) proppant usable in the oil and gas industry. The method uses silane coupling agent and organic acid to modify silica fume (SF) to obtain modified SF that is lipophilic and hydrophobic. The modified SF is used as inorganic phase, and the polymerizable monomer is used as organic phase, and the organic-inorganic composite microspheres are obtained through suspension polymerization. The ULW proppant is obtained by drying, screening, and pre-oxidization of the composite microsphere. The ULW proppant has a density of about 1.109 g/cm3-1.278 g/cm3, which is close to that of water, a crushing rate of <5% at 52 Mpa, and a crushing rate of <7% at 69 Mpa. In the oil and gas industry application, water or salt water can be used to replace the high viscose guanidine gum as carrier, thus reduced cost of fracturing, and reduced environment pollution.
    Type: Grant
    Filed: August 13, 2015
    Date of Patent: August 9, 2016
    Assignee: CHINA UNIVERSITY OF GEOSIENCES (WUHAN)
    Inventors: Chunjie Yan, Yixia Wang, Tao Chen, Yonghan Zhang, Yuting Chen, Luru Jing
  • Patent number: 9163135
    Abstract: A composition includes an elastomer and a ketoximo silane or a ketoxime additive.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: October 20, 2015
    Assignee: Bridgestone Corporation
    Inventors: Chenchy J. Lin, Yaohong Chen, Atsushi Fukushima, William L. Hergenrother, Terrence E. Hogan
  • Patent number: 8980960
    Abstract: Process for preparing a dispersion comprising silicon dioxide particles and cationizing agents, by dispersing 50 to 75 parts by weight of water, 25 to 50 parts by weight of silicon dioxide particles having a BET surface area of 30 to 500 m2/g and 100 to 300 ?g of cationizing agent per square meter of the BET surface area of the silicon dioxide particles, wherein the cationizing agent is obtainable by reacting at least one haloalkyl-functional alkoxysilane, hydrolysis products, condensation products and/or mixtures thereof with at least one aminoalcohol and water; and optionally removing the resulting hydrolysis alcohol from the reaction mixture. Also the process for preparing the dispersion, wherein the cationizing agent comprises one or more quaternary, aminoalcohol-functional, organosilicon compounds of formula III and/or condensation products thereof, wherein Ru and Rv are independently C2-4 alkyl group, m is 2-5 and n is 2-5.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: March 17, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Stefan Scharfe, Andrea Heuschen, Christoph Batz-Sohn, Burkhard Standke, Christian Wassmer, Heinz Lach
  • Patent number: 8974590
    Abstract: Methods, treatment compositions and treatment systems for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles. The process provides a coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated receptive surface. The methods, treatment compositions and treatment systems are useful in providing detachable coatings and treated articles featuring surface protective benefits including dirt- and water-repellency, self-cleaning with water, and easier cleaning benefits when applied to a variety of automotive and home surfaces, both interior and exterior.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: March 10, 2015
    Assignee: The Armor ALL/STP Products Company
    Inventors: Jodi Lynn Russell, Felix Müller, Danielle Coutts, Ashot K. Serobian, Patrick Winter, Nicholas Pivonka
  • Patent number: 8933164
    Abstract: A dispersion, comprising 0.1 to 25% by weight hydrophobized silica, 8 to 90 wt % of at least one alcohol selected from the group consisting of ethanol, 1-propanol and 2-propanol, 7 to 89 wt % of water, 0 to 30% by weight solvent immiscible with water, and 0.04 to 5 wt % of at least one carboxyvinyl polymer present in neutralized form, can be applied to a surface using a non-drip application method and, by modifying the surface with hydrophobized silica, imparts water-repelling and self-cleaning properties to the surface.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: January 13, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Jörg Peggau, Harald Jakob, Wolfgang Lortz
  • Publication number: 20140377524
    Abstract: An inorganic filler including a closed pore having a content of 1 to 30 vol. %, an insulation layer including the same, and a substrate using the insulation layer. With the insulation layer using the inorganic filler prepared so as to include a closed pore corresponding to a change rate in volume, the closed pore may offset change in volume in the inorganic filler and release stress, thereby improving a coefficient of thermal expansion according to change in temperature of the insulation layer.
    Type: Application
    Filed: October 9, 2013
    Publication date: December 25, 2014
    Applicant: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Ye Jun PARK, Byung Kun Kim, Jung Wook Seo
  • Patent number: 8747541
    Abstract: Dispersion obtainable by reacting a) in 50 to 75 parts by weight of water b) 25 to 50 parts by weight of silica particles having a BET surface area of 30 to 500 m2/g and c) 100 to 300 ?g/m2 BET surface area of the silica particles from b) parts by weight of one or more aminofunctional, organosilicon compounds, the aminofunctional, organosilicon compound being a quaternary, aminofunctional, organosilicon compound which is obtainable by reacting at least one haloalkylfunctional silane as component A with a tertiary amine as component B in the presence of a defined amount of water and at least partly removing the resulting hydrolysis alcohol from the system.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: June 10, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Stefan Scharfe, Christoph Batz-Sohn, Heinz Lach, Andrea Heuschen, Burkhard Standke, Christian Wassmer
  • Publication number: 20140102332
    Abstract: Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.
    Type: Application
    Filed: September 18, 2013
    Publication date: April 17, 2014
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Bok Ryul YOO, Joon Soo HAN, Dong Euy JUNG
  • Publication number: 20140102334
    Abstract: Surface-modified, structurally modified fumed silicas are surface-modified with N-containing silicon compounds.
    Type: Application
    Filed: December 23, 2013
    Publication date: April 17, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Mario SCHOLZ, Juergen Meyer
  • Patent number: 8617306
    Abstract: The present invention relates to hetero-coagulated silica-alumina mixed oxide compositions that have a sharp refractive index and narrow refractive index dispersion between about 1.46 and 1.60.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: December 31, 2013
    Assignee: Transparent Materials, LLC
    Inventors: Patrick M. Lambert, Joseph F. Bringley
  • Patent number: 8614256
    Abstract: A hydrophobic precipitated silica having a BET of less than 110 m2/g, a CTAB of less than 150 m2/g, a BET/CTAB ratio of less than 3, a carbon content of greater than 3.1%, a pH of 9.7 to 10.5, a DBP of less than 230 g/(100 g), and a methanol wettability of more than 50%. The hydrophobic precipitated silica is used in compositions including defoamers, silicone rubber and HTV crosslinkable silicone rubber compositions. The hydrophobic precipitated silica is also useful as a flow assistant and carrier or anti-blocking agent.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: December 24, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Panz, Rene Allerdisse, Helga Obladen, Mario Loebbus, Anja Lukas, Roland Bergmann, Karl Meier
  • Patent number: 8568524
    Abstract: Provided are compositions comprising stamp sand granules embedded in asphalt, where the stamp sand granules comprise a silane coating. Additionally provided are methods of making a silane-coated stamp sand, the methods comprising combining stamp sand granules and a silane solution to form a mixture and drying the mixture. Additionally provided are methods of covering a surface, the methods comprising combining silane-coated particles and asphalt to provide a mixture and distributing the mixture on the surface.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: October 29, 2013
    Assignee: Michigan Technology University
    Inventors: Bowen Li, Ralph Hodek, Domenic Popko, Jiann-Yang Hwang
  • Patent number: 8513333
    Abstract: The invention relates to particles which have been functionalised by means of an inertised reactive group, i.e. by means of specific reversibly blocked isocyanate groups, and whose inertization can be reversed by means of an external influence.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: August 20, 2013
    Assignee: Merck Patent GmbH
    Inventors: Matthias Koch, Jens Pradella
  • Patent number: 8455165
    Abstract: This invention provides metal oxide particles surface-treated with a cyclic silazane and a hydrophobicity-imparting agent, methods of making such, and toner compositions comprising the same.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: June 4, 2013
    Assignee: Cabot Corporation
    Inventors: Dmitry Fomitchev, Hairuo Tu
  • Publication number: 20130079445
    Abstract: The present invention is directed to a process for producing treated filler including (a) treating a slurry of untreated filler which has not been previously dried, with a treating composition including an organosilane material of specified structure (I); and (b) drying the treated filler slurry. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 28, 2013
    Inventors: Justin J. Martin, Timothy A. Okel, Raphael O. Kollah
  • Patent number: 8388859
    Abstract: A composition comprising a blocked and/or unblocked isocyanate compound and surface-modified nanoscale solid particles that comprise on the surface thereof organic radicals which comprise groups with an active hydrogen or precursors of such groups.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: March 5, 2013
    Assignee: Leibniz-Institut fuer Neue Materialien Gemeinnuetzige GmbH
    Inventors: Carsten Becker-Willinger, Martin Kluke, Helmut Schmidt
  • Patent number: 8377194
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF.B. M comprises at least one metal or metalloid cation S is a sulfur-based species. F optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5. B is a hygroscopic solid at a water to solid molar ratio of 0.1-6 and preferably comprises at least one alkaline earth oxide or lanthanide oxide.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: February 19, 2013
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Ian Saratovsky, Hung-Ting Chen
  • Publication number: 20130036946
    Abstract: Methods of forming a silica-containing products are disclosed. One method comprises: (a) providing a silica containing precursor (SCP) contained in solution that has a pH less than or equal to a pH of 7; (b) optionally doping the SCP with one or more metal species; (d) adding an effective amount of salt to the solution so that the conductivity of the solution is greater than or equal to 4 mS; (e) optionally filtering and drying the SCP; and (f) optionally reacting the dried product from step e with a functional group.
    Type: Application
    Filed: October 7, 2011
    Publication date: February 14, 2013
    Inventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna, Brett Showalter, Ian Saratovsky, Hung-Ting Chen
  • Patent number: 8333835
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: December 18, 2012
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
  • Patent number: 8304077
    Abstract: Metallic effect pigments with a platelet-shaped metallic substrate. The pigments have at least one metal oxide layer.
    Type: Grant
    Filed: July 8, 2009
    Date of Patent: November 6, 2012
    Assignees: Eckart GmbH, BYK-Chemie GmbH
    Inventors: Alfred Bubat, Wolfgang Griesel, Phu Qui Nguyen, Hans-Jörg Kremitzl
  • Publication number: 20120233929
    Abstract: Presently described are methods of inhibiting water vapor adsorption of a powder and methods of storing a powder at increased humidity level. The methods comprise providing adding discrete hydrophobic nanoparticles to a plurality of particles.
    Type: Application
    Filed: November 29, 2010
    Publication date: September 20, 2012
    Inventors: Jimmie R. Baran, JR., Roxanne A. Boehmer
  • Patent number: 8268069
    Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: September 18, 2012
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias