Organic Silicon Material Containing Patents (Class 106/490)
  • Patent number: 8197591
    Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: June 12, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt
  • Patent number: 8152916
    Abstract: The invention relates to a hydrophobic fumed silica which is obtained by grinding a fumed silica which, as a result of silanization, has octylsilyl groups fixed on the surface, to a process for preparing it, and to coating formulations comprising this silica.
    Type: Grant
    Filed: May 6, 2008
    Date of Patent: April 10, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Juergen Meyer, Andreas Garbatscheck, Guenther Michael, Vlasta Valter
  • Patent number: 8129021
    Abstract: Effect pigments with a platelet-shaped substrate provided on at least one side with at least one coating of semitransparent metal and/or at least one high-index coating having a refractive index ?2.0. The platelet-shaped substrate includes at least one mixed inorganic/organic phase. Also, a method of producing effect pigments including the following steps: a) combining at least one organic network former, at least one reactive organic component, at least one inorganic network former and/or nanoscale inorganic particles and a liquid phase to form a reaction composition, b) applying the reaction composition to a sheetlike base, c) forming a solidified mixed inorganic/organic phase, d) converting the mixed inorganic/organic phase into platelet-shaped substrates, and e) coating the platelet-shaped substrates with at least one coating of semitransparent metal and/or at least one high-index coating having a refractive index ?2.0.
    Type: Grant
    Filed: June 16, 2008
    Date of Patent: March 6, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt, Dirk Schumacher
  • Patent number: 8110037
    Abstract: Methods, treatment compositions and treatment systems are disclosed for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles, which provide a substantially transparent coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated surface or treated article bearing a receptive surface.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: February 7, 2012
    Assignee: The Clorox Company
    Inventors: Jodi Lynn Russell, Felix Müller, Danielle Coutts, Ashot K. Serobian, Patrick Winter, Nicholas Pivonka
  • Patent number: 8092587
    Abstract: The invention relates to stabilized dispersions of precipitated silicon dioxide, to a process for production thereof and to the use thereof, especially for production of paper coatings for glossy photo paper for inkjet printing.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: January 10, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Florian Zschunke, Burkhard Standke, Stefan Scharfe, Christoph Batz-Sohn, Heinz Lach, Andrea Heuschen, Juergen Behnisch, Markus Ruf, Guenter Stein, Tobias Banert
  • Patent number: 8034173
    Abstract: A method for processing compositions, compositions obtained by such a process and methods of use are disclosed for forming a detachable and renewable protective coating which is substantially transparent. The inventive process compositions are produced by making a highly concentrated dispersion of hydrophobically modified silica particles in the presence of an optional, yet preferable, disilazane derivative under high shear conditions. These process compositions are intended to be further diluted to final treatment compositions, optionally while adding other functional ingredients.
    Type: Grant
    Filed: October 31, 2005
    Date of Patent: October 11, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Thomas Dietz, Felix Müller, Maria R. Nargiello, Jodi Lynn Russell, Ashot K. Serobian, Patrick Winter
  • Publication number: 20110204283
    Abstract: The invention provides fumed silica comprising aggregates that have an aggregate size and a surface area that satisfy particular formulas relating aggregate size to surface area, as well as aggregates that exhibit particular viscosity, power law exponent index, and/or elastic modulus characteristics when dispersed in liquid media. The invention also provides processes of preparing such fumed silica by combining a silica precursor with a stream of combustible gas, combusting the stream, and producing a stream of combusted gas and fumed silica particles, wherein dopants are introduced, the time/temperature profile, or history, of the stream of combusted gas and fumed silica particles is adjusted to allow for post-quench aggregate growth, and/or additional silica precursor is introduced into the stream of combusted gas.
    Type: Application
    Filed: March 4, 2011
    Publication date: August 25, 2011
    Applicant: Cabot Corporation
    Inventors: Sheldon B. Davis, Angelica M. Sanchez Garcia, David Matheu, Yakov E. Kutsovsky
  • Patent number: 7981211
    Abstract: Surface-modified, fumed silica having the data: BET surface area, m2/g: 25-400; Average primary particle size, nm: 5-50; pH: 3-10; Carbon content, % by weight: 0.1-10; Potassium content (calculated as potassium oxide), % by weight: 0.000001-40; is prepared by subjecting a fumed silica to surface modification in the presence of potassium compounds. It can be used in LSR silicone rubber compositions as a filler.
    Type: Grant
    Filed: September 11, 2007
    Date of Patent: July 19, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Juergen Meyer, Mario Scholz
  • Patent number: 7972431
    Abstract: Surface-modified silicas Surface-modified, highly structured, potassium oxide-doped silicas, characterized by BET surface area, m2/g: 25-400 average primary particle size, nm: 5-50 pH: 3-10 carbon content, % by weight: 0.1-10 potassium oxide content, % by weight: 0.000001-40 are prepared by subjecting a potassium oxide-doped silica to surface modification. It can be used as a filler in silicone rubber compositions.
    Type: Grant
    Filed: September 11, 2007
    Date of Patent: July 5, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Juergen Meyer, Mario Scholz, Kai Schumacher
  • Patent number: 7955430
    Abstract: A coating material comprising a binding agent and at least one filler including particles having a size and/or surface roughness of about 100 ?m or less, and a photocatalytically active agent. The binding agent may be at least partially decomposed by a photocatalytic action, and a microstructured, self-cleaning surface may be formed.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: June 7, 2011
    Assignee: STO AG
    Inventor: Peter Grochal
  • Patent number: 7938902
    Abstract: Cationically stablished aqueous silica dispersion, method for its production and its use. A method is described for the production of cationically stabilised silica in which silica is cationically stabilised in the form of an aqueous dispersion or a powder by mixing with an acid aminosilane solution. A cationically stabilised silica powder may be obtained by removing the solvent. The cationically stabilised silica dispersion obtained is highly storage stable. Mixing with organic binding agents such as PVA is possible without a significant increase in viscosity. The dispersions are particularly suitable for coating slips for printing media, such as inkjet paper, but also for the surface treatment of substrates, e.g. for the hard coating of plastics, or in parting compounds or abrasives and polishing agents.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: May 10, 2011
    Assignee: Buhler Partec GmbH
    Inventors: Klaus Steingröver, Frank Tabellion, Steffen Pilotek
  • Patent number: 7901731
    Abstract: Methods, treatment compositions and treatment systems are disclosed for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles, which provide a substantially transparent coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated surface or treated article bearing a receptive surface.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: March 8, 2011
    Assignee: The Clorox Company
    Inventors: Jodi Lynn Russell, Felix Muller, Danielle Coutts, Ashot K. Serobian, Patrick Winter, Nicholas Pivonka
  • Patent number: 7897648
    Abstract: This invention relates to silica aerogels and to a method for their preparation from rice husk. Rice husk is very rich in silica, and its ash can contain up to 92-97% of amorphous silica. The rice husk ash is prepared by burning the rice husk on a heating plate with excess air until the white ash is obtained. Silica from rice ash husk is in a very active form and has been found to be a very potential starting material for silica aerogels.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: March 1, 2011
    Assignee: Universiti Teknologi Malaysia
    Inventor: Hamdan Halimaton
  • Patent number: 7828889
    Abstract: Methods, treatment compositions and treatment systems are disclosed for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles, which provide a substantially transparent coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated surface or treated article bearing a receptive surface.
    Type: Grant
    Filed: October 31, 2005
    Date of Patent: November 9, 2010
    Assignee: The Clorox Company
    Inventors: Jodi Lynn Russell, Felix Müller, Danielle Coutts, Ashot K. Serobian, Patrick Winter, Nicholas Pivonka
  • Publication number: 20100261823
    Abstract: Flakes comprising pyrogenically prepared silicon dioxide were rendered water repellent after compacting. They can be used in natural rubber and synthetic rubber production.
    Type: Application
    Filed: November 18, 2008
    Publication date: October 14, 2010
    Applicant: Evonik Degussa GmbH
    Inventors: Florian Felix Kneisel, Ralph Hofmann
  • Patent number: 7811540
    Abstract: The invention provides a method of preparing hydrophobic silica particles comprising (a) providing an aqueous colloidal silica dispersion comprising about 5-70 wt. % of silica particles having an average overall particle size of about 10-1000 nm, wherein the silica particles comprise surface silanol groups, (b) combining the silica dispersion with about 3-75 ?mole/m2 (based on the BET surface area of the silica) of a silyl amine treating agent and optionally with other ingredients to provide a reaction mixture, wherein the reaction mixture has a pH of about 7 or more, and comprises no more than about 50 wt. % of an organic solvent, and (c) drying the dispersion to provide hydrophobic silica particles. The invention further provides a method of preparing a toner composition comprising combining the hydrophobic silica particles as recited above with toner particles to provide a toner composition.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: October 12, 2010
    Assignee: Cabot Corporation
    Inventor: Curtis E. Adams
  • Patent number: 7790232
    Abstract: Process for the preparation and the deposition of vitreous films on substrates comprising: the dissolution of one or more metal alkoxides in aprotic solvent, the hydrolysis of the resulting solution, the eventual removal of the formed alcohol, the deposition of the resulting sol on the substrate surface of interest and the final drying of the film.
    Type: Grant
    Filed: July 7, 2003
    Date of Patent: September 7, 2010
    Assignee: Degussa Novara Technology S.p.A.
    Inventors: Fulvio Costa, Lorenzo Costa
  • Patent number: 7772290
    Abstract: A method to prepare multi-phobic effects nanosized-structure film and its application are described, which features nanosized silica, titanium oxide and zinc oxide compounded materials of previous size 3-100 nm are in-situ combined with substrate through fluorocarbon surfactants and perfluoro alkyl filming substance under specific conditions to form a nanosized-structure film. The reaction between fluorocarbon surfactants and hydroxyl groups on surfaces of nanosized particles renders the modified nanosized particle and nanosized film having extremely high chemical stability, resistance, and the capacity to repel and disperse water, oil, bacteria, organic dust, gas, electricity, magnetism and light (i.e., multi-phobic effects). This technology may be widely used in surface modification of fabric, chemical fiber, cotton, wool, glass product, brick-stone concrete and wood wall.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: August 10, 2010
    Inventors: Ho Cheong Poon, Jing Chun Liu, Fugao Chen
  • Patent number: 7737187
    Abstract: A process for producing an inorganic oxide organosol that has good dispersibility and low viscosity, has excellent transparency, and shows good compatibility with resin solutions, and includes the steps (A) and (B) of: (A) adding silicon alkoxide having two or more alkoxy groups bonded to a silicon atom or having one or more hydroxy groups bonded to a silicon atom and one or more alkoxy groups bonded to a silicon atom to a hydrophilic inorganic oxide sol containing a hydrophilic solvent having a boiling point (1 atm) of 100° C. or less in an amount of 25 to 100% by weight in a dispersion medium to treat surface of the inorganic oxide particles in the sol; and (B) replacing the dispersion medium of the surface treated inorganic oxide sol obtained in step (A) with a non-alcoholic organic solvent in the presence of a primary alcohol having 3 to 12 carbon atoms.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: June 15, 2010
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Keiko Yoshitake, Yoshinari Koyama, Naohiko Suemura
  • Patent number: 7722714
    Abstract: Dispersion of fumed silica comprising a silanized, structurally modified silica and a solvent. It is used for producing coating materials.
    Type: Grant
    Filed: April 5, 2007
    Date of Patent: May 25, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Günther Michael, Jürgen Meyer, Thorsten Ladwig, Pedro Cavaleiro
  • Patent number: 7700669
    Abstract: Silicas modified with groups of the general formula (I) RaSiR1bOc—??(I) where at least one of R or R1 is a >C3 hydrocarbon radical are useful in preparing stable dispersions of basic substances, the silica permitting a decrease in the shear viscosity h for a storage time of 1 week at room temperature (25° C.) to not more than 50% of the initial viscosity value, the viscosity being measured by means of cone/plate geometry with a shearing gap of 105 ?m and a shear rate of 0.5 s?1 at 25° C.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: April 20, 2010
    Assignee: Wacker Chemie AG
    Inventors: Torsten Gottschalk-Gaudig, Michael Dreyer
  • Patent number: 7658793
    Abstract: The invention relates to a pigment preparation based on at least one inorganic pigment and at least one organic pigment, and to a method for producing one such pigment preparation. Said pigment preparation contains particles wherein fine organic pigment particles are combined with inorganic pigment particles, said particles also being provided with an organic macromolecular coating. The inventive pigment preparation is produced by wet-grinding the inorganic and organic pigments, optionally adding other constituents, in the presence of a surface-active substance in the form of a macromolecular organic compound.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: February 9, 2010
    Assignee: Heubach GmbH
    Inventors: Rainer Heubach, Yvonne Brussaard, Hugo Brussaard
  • Patent number: 7642199
    Abstract: A method of producing a silica or silica-like coating by forming a precursor formulation from oligomeric organosilicate. The precursor formulation is coated on a substrate as a continuous liquid phase. The precursor formulation is then cured in an ammoniacal atmosphere to produce a continuous, interconnected, nano-porous silica network.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: January 5, 2010
    Assignee: Xerocoat Inc.
    Inventors: Paul Meredith, Michael Harvey
  • Patent number: 7625445
    Abstract: An aggregate for making a molded article and a method of making the aggregate is disclosed. The aggregate consists of an acrylate based resin matrix and anti abrasive particles chiefly quartz particles having a size of between 0.1 mm and 1.2 mm, at least 30 percent of the anti abrasive particles being broken particles having irregular shape with sharp edges silanized and non-silanized. The aggregate includes fine powders, cross linking agent and Peroxides. The molded article made from the aggregate has anti-abrasive properties and “look and feel” of natural material.
    Type: Grant
    Filed: September 13, 2004
    Date of Patent: December 1, 2009
    Inventors: Chirag Parekh, Ashwin Parekh
  • Patent number: 7611815
    Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: November 3, 2009
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
  • Patent number: 7612137
    Abstract: The invention relates to surface-modified silica gels, to a process for preparing them, and to their use as matting agents in coating materials. As a result of the nature of the surface modification, the viscosity of 2-component coating materials is increased only slightly, or not at all, after the matting agent has been added.
    Type: Grant
    Filed: May 19, 2005
    Date of Patent: November 3, 2009
    Assignee: Degussa AG
    Inventors: Ulrich Brinkmann, Christian Götz, Hans-Dieter Christian
  • Patent number: 7569107
    Abstract: The present invention is related to treated filler and processes for producing said treated filler. Untreated filler slurry can be treated with a treating material and, optionally, a coupling material and then subjected to conventional drying method(s), to produce the treated filler of the invention. Treated filler has a wide variety of applications including but not limited to battery separators and rubber compositions such as tires.
    Type: Grant
    Filed: May 26, 2006
    Date of Patent: August 4, 2009
    Assignee: PPG Industries Ohio, Inc.
    Inventors: James L. Boyer, Charles R. Coleman, Timothy A. Okel, Narayan K. Raman
  • Patent number: 7563317
    Abstract: Silanised, structurally modified silicas, characterised by groups fixed on the surface, the groups being alkylsilyl (SiCnH2n+1, with n=2-18). They are produced in that pyrogenically produced silicas are treated with the silanising agent and structurally modified. They are used to improve scratch resistance in lacquers.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: July 21, 2009
    Assignee: Degussa AG
    Inventors: Jürgen Meyer, Stephanie Frahn, Manfred Ettlinger
  • Publication number: 20090071368
    Abstract: The invention relates to a process for the dispersion of fine-particle surface-modified inorganic powders in liquid media, with use of siloxanes. A process for the preparation of a dispersion of inorganic particles in a liquid medium is described, in which inorganic particles which have been surface-modified so that they have at least one organic group on the surface are mixed in a liquid medium with an organosiloxane, where at least one organic group of the organosiloxane corresponds to the at least one organic group on the surface of the inorganic particles.
    Type: Application
    Filed: September 17, 2008
    Publication date: March 19, 2009
    Applicant: Buhler PARTEC GmbH
    Inventors: Klaus Steingrover, Frank Tabellion, Steffen Pilotek, Michael Khim
  • Publication number: 20090076194
    Abstract: Hydrophobic pyrogenic silica doped with potassium by means of aerosol is prepared by reacting a pyrogenic silica doped with potassium by means of aerosol with a surface-modifying agent. It can be used as a filler in silicone rubber.
    Type: Application
    Filed: October 29, 2005
    Publication date: March 19, 2009
    Inventors: Jurgen Meyer, Mario Scholz
  • Patent number: 7503970
    Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: March 17, 2009
    Assignee: Croda International PLC
    Inventors: Graham Paul Dransfield, Susan Cutter, Phillip Laurence Lyth
  • Patent number: 7470725
    Abstract: The present invention relates to novel, organically modified aerogels, uses thereof, and a process for producing them in which a) a hydrogel is introduced as an initial charge, b) the hydrogel obtained in step a) is subjected to surface modification, and c) the surface-modified gel obtained in step b) is dried. The present invention additionally relates to novel, organically modified wet gels, to a process for producing them, and to their use.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: December 30, 2008
    Assignee: Cabot Corporation
    Inventors: Fritz Schwertfeger, Dierk Frank
  • Publication number: 20080295736
    Abstract: The invention relates to a pearl pigment, and the preparing method of the same comprises: coating metal oxides on a sheet-like substrate, and coating metal phosphites (aluminum phosphite or zinc phosphite) on it, and then treating by hydrolysable silane coupling agent. The pearl pigment obtained highly improves its stability and its aging resistance when used for external outsides.
    Type: Application
    Filed: September 21, 2005
    Publication date: December 4, 2008
    Inventors: Yizhong Lin, Wensong Jin
  • Patent number: 7393407
    Abstract: The present invention relates to a slurry containing water, amorphous silica panicles having a particle size less than 1 micron and silica flour with a particle size between 2-200 microns. In order to stablize the slurry, the slurry contains a polysaccharide. The invention further relates to a method for the production of a slurry containing water, amorphous silica having a particle size below 1 micron, and silica flour with a particle size between 2-200 microns, where a polysaccharide is added to a slurry of water and amorphous silica, whereafter the silica flour is mixed into the slurry of amorphous silica.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: July 1, 2008
    Assignee: Elkem ASA
    Inventors: Eldar O Dingsoyr, Magne Dastol, Cor Oldenziel, Bjorn Vassoy
  • Publication number: 20080053336
    Abstract: The present invention concerns aqueous coating systems, providing an aqueous coating composition which comprises water, a film-forming component and at least one inorganic pigment surface treated with one or more organosilicon compounds from the alkyltrialkoxysilanes, the dialkyldialkoxysilanes and mixtures, oligomers, and copolymers of the alkyltrialkoxysilanes and dialkyldialkoxysilanes, wherein the alkyl groups contain from three to six carbon atoms and optionally contain an oxygen atom or contain fluorine and/or chlorine heteroatoms. By controlling and limiting the amounts used of these organosilicon surface treatments, the dispersibility of a conventionally hydrophilic inorganic pigment such as titanium dioxide is not materially adversely affected, but improvements are at the same time afforded in terms of the compatibility of the pigment with the film-forming component, as demonstrated by improved tint strength and gloss properties in a paint composition.
    Type: Application
    Filed: September 6, 2006
    Publication date: March 6, 2008
    Inventors: Daniel H. Craig, Jeffrey D. Elliott, Michael E. Kidder, George A. Perakis, Harmon E. Ray, Mark D. Westmeyer
  • Patent number: 7300510
    Abstract: Goniochromatic luster pigments comprising at least one dielectric low-refractive interference-colored layer which includes a polar organic solvent which can interact with the layer material via functional groups.
    Type: Grant
    Filed: May 8, 2003
    Date of Patent: November 27, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Seeger, Norbert Mronga, Rainer Henning, Raimund Schmid
  • Publication number: 20070244223
    Abstract: Silicas modified with groups of the general formula (I) RaSiR1bOc— ??(I) where at least one of R or R1 is a >C3 hydrocarbon radical are useful in preparing stable dispersions of basic substances, the silica permitting a decrease in the shear viscosity h for a storage time of 1 week at room temperature (25° C.) to not more than 50% of the initial viscosity value, the viscosity being measured by means of cone/plate geometry with a shearing gap of 105 ?m and a shear rate of 0.5 s?1 at 25° C.
    Type: Application
    Filed: March 29, 2007
    Publication date: October 18, 2007
    Applicant: WACKER CHEMIE AG
    Inventors: Torsten Gottschalk-Gaudig, Michael Dreyer
  • Patent number: 7238387
    Abstract: Hydrophobic inorganic fine particles characterized by being a mixture of at least small-particle-diameter inorganic fine particles having an average primary particle diameter of 5 to 25 nm and having a maximum peak particle diameter of 20 nm or less and large-particle-diameter inorganic fine particles having an average primary particle diameter which is 1.5 to 100 times the average primary particle diameter of the small-particle-diameter inorganic fine particles; the mixture being a mixture having been treated in the same treating tank to subject both the small-particle-diameter inorganic fine particles and large-particle-diameter inorganic fine particles simultaneously to hydrophobic treatment.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: July 3, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshihiro Ogawa, Takashige Kasuya, Kaori Hiratsuka
  • Patent number: 7220449
    Abstract: The invention relates to hydrophobicized precipitated silicas that possess an extremely high whiteness and extremely low moisture absorption. The hydrophobic precipitated silicas are prepared, inter alia, by coating with silicone oil and oxidative heat treatment.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: May 22, 2007
    Assignee: Degussa AG
    Inventors: Uwe Schachtely, Christian Panz, Ralf Schmoll
  • Patent number: 7208038
    Abstract: Silane-modified biopolymeric, biooligomeric, oxidic or siliceous filler obtainable by reacting at least one biopolymeric, biooligomeric, oxidic or siliceous filler in a compressed gas with at least one silane. The silane-modified biopolymeric, biooligomeric, oxidic or siliceous fillers are used in rubber compounds.
    Type: Grant
    Filed: March 3, 2005
    Date of Patent: April 24, 2007
    Assignee: Degussa AG
    Inventors: Karsten Korth, Hans-Detlef Luginsland, Andre Hasse, Ingo Kiefer, Juergen Heidlas
  • Patent number: 7186440
    Abstract: A process for producing a hydrophobic silica powder, comprises the steps for hydrophobic treatment of: adding to a silica sol in mixed solvent having a silica concentration of 5 to 50 mass % obtained by mixing an aqueous silica sol containing hydrophilic colloidal silica having a specific surface area of 5.5 to 550 m2/g with a hydrophilic organic solvent in a mass ratio of 0.12 to 2.5 based on water in the aqueous silica sol, a disilazane compound of formula (1) (R13Si)2NH ??(1) wherein each R1 is C1-6alkyl group or phenyl group that is selected independently of one another, in an amount of 0.1 to 20 mmol per surface area 100 m2 of the hydrophilic colloidal silica, to obtain a mixture of the silica sol in mixed solvent and the disilazane compound; and heating the mixture at a temperature of 50 to 100° C. for aging it to obtain a slurry dispersion of hydrophobic treated colloidal silica. The process provides a hydrophobic silica powder through a simple hydrophobic treatment step.
    Type: Grant
    Filed: June 30, 2006
    Date of Patent: March 6, 2007
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Keiko Yoshitake, Hirokazu Kato
  • Patent number: 7160375
    Abstract: An aqueous glittering color material composition of the present invention is an aqueous glittering color material composition comprising a glittering pigment having a water repellent particle surface and it includes the following ingredients. The aqueous glittering color material composition of the present invention is used for an ink for writing instruments, for cosmetics, and the like. (a) As said glittering pigment, a metal coated glass flake pigment having a particle surface with water repellent treatment with a titanate or a silane coupling agent. (b) A colorant, and (c) A fixing resin.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: January 9, 2007
    Assignee: Sakura Color Products Corporation
    Inventor: Yuki Yamamoto
  • Patent number: 7144628
    Abstract: Spherical silica-titania-based fine particles surface-treated with silane are provided. The fine particles have a titanium atom content of 0.001 to 5% by weight, a frictional electrification with iron powder of ?100 to ?300 ?C/g, a bulk density of 0.2 to 0.4 g/ml, and a particle diameter of 0.01 to 5 ?m. The particles are useful as a material for an external additive for an electrostatically charged image developing toner. The toner is unlikely to cause degeneration or scratching of organic photoreceptors, displays excellent dispersibility and favorable flowability and consequently does not cause adhesion to the photoreceptor.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: December 5, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaaki Yamaya
  • Patent number: 7144930
    Abstract: Functionalized, structurally modified silicas with 3-methacryloxypropylsilyl and/or glycidyloxypropylsilyl groups on the surface are prepared by mixing the silicas with the silane and heat-treating, destructuring and grinding the mixture. The silicas are employed in radiation-curing coatings.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: December 5, 2006
    Assignee: Degussa AG
    Inventors: Jürgen Meyer, Manfred Ettlinger, Stephanie Frahn
  • Patent number: 7083888
    Abstract: An external additive for electrostatically charged image developing toner is provided. The additive includes spherical hydrophobic fine silica particles having primary particles with a particle diameter of from 0.01 to 5 ?m and having been treated with a compound selected from the group consisting of a quaternary ammonium salt compound, a fluoroalkyl-group- or fluoroalkenyl-group- containing betaine compound and a silicone oil. The fine silica particles fulfill conditions (i) and (ii), as described in the disclosure. The external additive does not react or has no interaction with an organic photoreceptor and therefore change in quality does not occur or the photoreceptor is not scraped. Furthermore, it has a good flowability and therefore adhesion of a toner to the photoreceptor does not occur.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: August 1, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaki Tanaka
  • Patent number: 7074457
    Abstract: A hydrophobic precipitated silica is prepared by a process comprising: a) preparing a mixture of an organopolysiloxane derivative and a precipitated silica; b) conditioning the mixture obtained at a temperature ranging from 10 to 150° C. for a period ranging from 0.5 to 72 h, and c) conducting oxidative heat treatment under fluid conditions at a temperature more than 300° C. with an oxidizing gas.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: July 11, 2006
    Assignee: Degussa AG
    Inventors: Christian Panz, Karl Meier, Ralf Stoffels, Helga Obladen, Ralf Schmoll
  • Patent number: 7022375
    Abstract: The invention relates to hydrophobicized precipitated silicas that possess an extremely high whiteness and extremely low moisture absorption. The hydrophobic precipitated silicas are prepared, inter alia, by coating with silicone oil and oxidative heat treatment.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: April 4, 2006
    Assignee: Degussa AG
    Inventors: Uwe Schachtely, Christian Panz, Ralf Schmoll
  • Patent number: 6921781
    Abstract: The present invention provides a process, which includes: coating at least a portion of a surface of at least one silica particle with at least one wax, wherein the coating is carried out in at least one gas at a temperature above the melting point of the wax and below the decomposition temperature of the wax, to obtain at least one wax-coated silica particle. Other embodiments of the present invention provides processes for impregnating the silica particle with wax and uses of the wax-coated or wax-impregnated particles.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: July 26, 2005
    Assignee: Degussa AG
    Inventors: Juergen Schubert, Klaus-Dieter Hellwig, Michael Pickel, Hans-Dieter Puetz
  • Patent number: 6899951
    Abstract: The present invention provides a hydrophobic precipitated silica having the following properties: carbon content 1.0-8.0% methanol wettability ?20-55% reflectance >94% BET/CTAB ratio ??1 DBP absorption <250 g/100 g BET surface area ?50-110 m2/g CTAB surface area 100-150 m2/g Sears number <13. The present invention also provides methods for making and using the hydrophobic precipitated silica and articles and compositions which include the same.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: May 31, 2005
    Assignee: Degussa AG
    Inventors: Christian Panz, Ralf Schmoll, Michael Kempf, Mario Scholz
  • Patent number: RE41858
    Abstract: A pearlescent pigment based on a metal oxide-coated, platelet-shaped substrate and a top layer on the metal oxide layer, where the top layer comprises silicon dioxide, at least one further metal hydroxide or metal oxide hydrate and at least one organic coupling reagent. The further metal hydroxides or metal oxide hydrates are hydroxides or oxide hydrates of cerium, aluminum or zirconium, or mixtures thereof. The coupling reagents employed are organofunctional silanes, zirconium aluminates or metal acid esters.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: October 26, 2010
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Joachim Duschek, Ralf Glausch