Abstract: An solid oxide fuel cell stack having a metallic layer and a glass layer, and a method for preventing or reducing a chemical reaction between a metallic layer and a glass layer are disclosed. The solid oxide fuel cell stack has a barrier layer disposed between the metallic layer and the glass layer. The barrier layer includes alumina and a phosphate. The phosphate includes an aluminum dihydrogen phosphate, an aluminum-containing phosphate, a phosphate of an element of the metallic layer, a phosphate of an element of the glass layer, or combinations thereof. The method includes disposing a barrier layer between the metallic layer and the glass layer.

Abstract: A molding material in a powder-fixing lamination method includes an aggregate and a powdery precursor of a binder that binds the aggregate mutually. The aggregate is a casting sand, and the powdery precursor contains a hardening component and a hardening accelerating component. A molded product is manufactured using the molding material.

Abstract: The present disclosure relates to a medical cement composition containing calcium silicate in an amount of less than 20 wt % of a total weight of the composition, with a lithium salt being added thereto. The medical cement composition of the present disclosure has a low compressive strength of 12 MPa or less, after being hardened, for easy removal, excellent stability in storage, and high bioactivity.

Abstract: A method of curing a low Ca/Mg cement composition is described that includes providing a predetermined quantity of the low Ca/Mg cement composition in uncured form; and reacting the uncured low Ca/Mg cement composition with a reagent chemical for a time sufficient to cure said cementitious material, wherein said reagent chemical is a compound synthesized from CO2 and comprises dicarboxylic acids, tricarboxylic acids, or alpha-hydroxycarboxylic acids.

Abstract: A medical use honeycomb structure having a plurality of through-holes extending in one direction, wherein an outer peripheral section of the medical use honeycomb structure has a through-hole groove formed by incomplete side walls of the through-hole, and a through-hole inlet adjacent to the through-hole groove.

Abstract: A solid oxide fuel cell stack having a metallic layer and a glass layer, and a method for preventing or reducing a chemical reaction between the metallic layer and the glass layer are disclosed. The solid oxide fuel cell stack has a barrier layer disposed between the metallic layer and the glass layer. The barrier layer includes alumina and a phosphate. The phosphate includes an aluminum dihydrogen phosphate, an aluminum-containing phosphate, a phosphate of an element of the metallic layer, a phosphate of an element of the glass layer, or combinations thereof. The method includes disposing a barrier layer between the metallic layer and the glass layer.

Abstract: The present disclosure relates generally to building materials, such as building boards, having improved strength and reduced shrinkage. More particularly, the present disclosure provides building compositions comprising Struvite-K (KMgPO4.6H2O), Syngenite (K2Ca(SO4)2.H2O), and one or more silicate additives suitable for use in building materials.

Abstract: The present invention is a system for repairing asphalt. The system includes a discrete quantity of an asphalt repair composition located within a container and an induction heater. The composition is a combination of an asphalt binder, aggregate particles, and induction particles. The average diameter of the induction particles ranges from approximately 10% above to approximately 10% below an average diameter of the aggregate particles used in the composition. The induction heater heats the composition within the container by generating a magnetic field that penetrates the container. The magnetic field creates eddy currents in the induction particles. These eddy currents in turn heat the composition. Because the induction particles are distributed throughout the composition, the composition heats rapidly.

Abstract: An inorganic, non-Portland cement-based construction material is provided. The material may include blast furnace slag material, volcano rock flour, alkali-based powder, and sand. Other materials having various ratios may also be included.

Abstract: The present invention relates to an aqueous composition based on phosphates, aluminum ions and other metal ions, in particular manganese ions and zinc ions, as well as silicates, siloxanes or silanes, for providing anticorrosive coatings on metal surfaces, in particular for the electrical insulation of grain-oriented electrical steel strip. For the desired functionality, the compositions according to the invention contain the constituents mentioned in a prescribed ratio to one another. The invention also relates to a method for coating the surface of a metallic workpiece by using the aqueous compositions, wherein the method produces outstanding results, in particular on grain-oriented electrical steel strip, with regard to corrosion protection and adherence.

Abstract: A composition and process for the manufacture thereof for use in a hybrid building material comprising at least in part Syngenite (K2Ca(SO4)2.H2O) and Struvite-K (KMgPO4·6H2O). Specified constituents, including magnesium oxide (MgO), monopotassium phosphate (MKP) and stucco (calcium sulfate hemihydrate) are mixed in predetermined ratios and the reaction proceeds through multiple phases reactions which at times are proceeding simultaneously and in parallel and reaction may even compete with each other for reagents if the Struvite-K reaction is not buffered to slow down the reaction rate). A number of variable factors, such as water temperature, pH mixing times and rates, have been found to affect resultant reaction products. Preferred ratios of chemical constituents and manufacturing parameters, including predetermined and specified ratios of Struvite-K and Syngenite may be provided for specified purposes, optimized in respect of stoichiometry to reduce the combined heat of formation to non-destructive levels.

Abstract: An object is to provide a method for manufacturing a calcium carbonate block of no less than 0.1 cm in diameter and thickness, not including any impurities, and able to be employed as a raw material of an artificial bone that requires biosafety: the method includes: (a) shaping a calcium hydroxide block; (b) being exposed to carbon dioxide; and (c) immersing in a carbonate ion containing solution.

Abstract: A surface treatment composition including polymeric complex nanoparticles used in a hydrophobic agent and siloxane complex nanoparticles used in a suspending agent thereof. The composition of the present invention is a solution comprising a plurality of components. The primary components are an acid mixture and a base mixture that are combined together in a manner to be described herein to produce a two-part liquid solution. The two parts, are combined together prior to application to a surface and allowed to cure on the surface.

Abstract: A coating system for coating inorganic substrates with a wide range of functional materials without having to use the usually necessary high temperatures includes an aqueous solution as component K1, which aqueous solution contains at least Al(H2PO4)3 and Al(NaHPO4)3 in the following fractions on an oxide basis and in mass percent with respect to the total mass of the solution: P2O5=25.0 to 37.0, Al2O3=5.8 to 9.0, Na2O=0.1 to 2.0, and H2O=54.0 to 66.0, and which includes an additional component K2 having the constituents magnesium oxide, silicate, and borate, which are contained in K2 in the following fractions on an oxide basis and in mass percent with respect to the total mass of component K2: MgO=70.0 to 95.0, SiO2=1.0 to 19.0, and B2O3=1.0 to 3.0, wherein there is a reactivity of the magnesium oxide of 40 to 400 seconds in the citric acid test and the loss on ignition of component K2 is 0 to 3.0.

Abstract: A refurbishment process for a volumetric screw compressor of the ‘oil-free’ type, which comprises a male rotor and a female rotor, is described. The process comprises visually checking the wear condition of the rotors, treating their surface for removing the previous coating, and applying a new coating on the surface. The composition of the coating applied on the surface of the rotors consists of the following materials: Material Amount (g) Polytetrafluoroethylene 750 ÷ 850 (954G 303 C Teflon, DuPont) Amorphous graphite powder 300 ÷ 400 Thinner for spray cleaning apparatuses 200 ÷ 270 (8595 thinner, DuPont) Methyl ethyl ketone (MEK) 170 ÷ 220 Cellosolve acetate coating additive 200 ÷ 300 (Syn Fac 800 resin).

Abstract: Magnesium phosphate cement binder systems and method for providing magnesium phosphate cements are described. In an embodiment, a magnesium phosphate cement binder system may include magnesium oxide that has been calcined at a temperature of between about 900° F. to about 1800° F. The magnesium phosphate cement binder system may also include a phosphate material. Other formulations, compositions, and methods are also described.

Abstract: The present invention relates to a binder composition comprising (i) a phospho-magnesium cement; (ii) a boron source; (iii) a lithium salt; and (iv) water and to its preparation method. The present invention also relates to the use of such a binder for confining wastes and notably nuclear wastes containing aluminum metal.

Abstract: The present invention relates to a method of preparing a composite biomaterial, essentially consisting of collagen in combination with granules of hydroxyapatite/?-tricalcium phosphate (HA/?-TCP), to be used in maxillofacial surgery, dentistry, aesthetic surgery and particularly in orthopedic surgery; the invention also relates to the biomaterial obtained by means of this method.

Abstract: The invention provides a composite of ?-calcium sulfate (CS) hemihydrate/amorphous calcium phosphate (?-CSH/ACP), comprising ?-CSH and ACP at a weight ratio of about 10:90 to about 90:10. Particularly, the composite of the invention has a resorption period of 3-6 months. The invention also provides a one-pot process for producing ?-CSH/ACP composite of the invention. The one-pot process of the invention can produce ?-CSH and ACP in a single process and easily obtain ?-CSH/ACP composite.

Abstract: Methods and a kit. A cement forming method includes nucleating an acidic metallophosphate reaction mixture with first particles, resulting in forming a settable metallophosphate cement from the acidic metallophosphate reaction mixture. The first particles include a first metal oxide. Each particle of the first particles independently have a particle size in a range from about 15 microns to about 450 microns. A method for applying cement includes seeding a solution with particles, resulting in forming a settable cement from the solution. The particles have a size in a range from about 15 microns to about 450 microns. The solution includes a first metal oxide reacting with phosphate. The settable cement is applied to a substrate. A cement application kit is also described.

Abstract: A composition and process for the manufacture thereof for use in a hybrid building material comprising at least in part Syngenite (K2Ca(SO4)2.H2O) and Struvite-K (KMgPO4.6H2O). Specified constituents, including magnesium oxide (MgO), monopotassium phosphate (MKP) and stucco (calcium sulfate hemihydrate) are mixed in predetermined ratios and the reaction proceeds through multiple phases reactions which at times are proceeding simultaneously and in parallel and reaction may even compete with each other for reagents if the Struvite-K reaction is not buffered to slow down the reaction rate). A number of variable factors, such as water temperature, pH mixing times and rates, have been found to affect resultant reaction products. Preferred ratios of chemical constituents and manufacturing parameters, including predetermined and specified ratios of Struvite-K and Syngenite may be provided for specified purposes, optimized in respect of stoichiometry to reduce the combined heat of formation to non-destructive levels.

Abstract: The present invention relates to a gallium-doped phosphocalcic compound of formula (I): Ca(10.5-1.5x)Gax(PO4)7??(I) wherein 0<x<1 and the salts, hydrates and mixtures thereof. The invention further relates to a solid state process and a process in solution for the manufacture of such compounds and the use thereof for the preparation of a biomaterial, in particular a self-setting calcium-phosphate cement (CPC).

Abstract: The present invention relates to a galliated calcium-phosphate biomaterial comprising a gallium-doped phosphocalcic compound of formula (I): Ca(10.5-1.5x)Gax(PO4)7??(I) wherein 0<x<1 and the salts, hydrates and mixtures thereof and/or a calcium deficient apatite structure with in particular a (Ca+Ga)/P molar ratio in the range of 1.3 to 1.67, and a gallium content up to 4.5% by weight. It also relates to processes of preparation of such materials and uses thereof, in particular as dental or bony implants. It further relates to a kit comprising a galliated calcium-phosphate biomaterial in combination with a fluid component. It finally relates to methods of use of the galliated calcium-phosphate biomaterial, notably for III) ions increase radio-opacity after bone implantation and can be released for inhibiting bone resorption.

Abstract: There is provide a solid cement reactant comprising a dehydrated magnesium phosphate, and/or an amorphous or partially amorphous magnesium phosphate, and/or Farringtonite.

Abstract: Disclosed and described are multi-component inorganic phosphate formulations of acidic phosphate components and basic oxide/hydroxide components. Also disclosed are high solids, atomizable compositions of same, suitable for spray coating.

Abstract: The present invention provides a bone cement formula having a powder component and a setting liquid component, wherein the powder component includes a calcium sulfate source and a calcium phosphate source with a weight ratio of the calcium sulfate source less than 65%, based on the total weight of the calcium sulfate source and the calcium phosphate source, and the setting liquid component comprises ammonium ion (NH4+) in a concentration of about 0.5 M to 4 M, wherein the calcium phosphate source includes tetracalcium phosphate (TTCP) and dicalcium phosphate in a molar ratio of TTCP to dicalcium phosphate of about 0.5 to about 2.5, and the calcium sulfate source is calcium sulfate hemihydrate (CSH), calcium sulfate dehydrate (CSD), or anhydrous calcium sulfate.

Abstract: Methods are provided for producing compositions, e.g. pastes or clays, which rapidly set into high-strength calcium phosphate products. In the subject methods, dry reactants that include calcium and phosphate sources, as well as a monovalent cation dihydrogen phosphate salt, are combined with a setting fluid and the combined reactants are mixed to produce the settable composition. A feature of the invention is that cements rapidly set into high strength product compositions. Also provided are the compositions themselves as well as kits for preparing the same. The subject methods and compositions produced thereby find use in a variety of applications, including hard tissue repair applications.

Abstract: The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200° C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

Abstract: A calcium phosphate cement composition kit comprising (A) a powdery agent comprising 100 parts by mass of calcium phosphate powder, and 5-50 parts by mass of a powdery apatite/collagen composite, and (B) an aqueous blending liquid; a paste-like mixture being obtained by blending the powdery agent with the aqueous blending liquid, in such a proportion that the aqueous blending liquid is 15-50 parts by mass per the total amount (100 parts by mass) of the calcium phosphate powder and the powdery apatite/collagen composite, and filled in a predetermined prosthetic site in a human body to form a hardened calcium phosphate/collagen composite.

Abstract: Calcium-strontium-hydroxyphosphate (strontium-apatite-) cement preparations are described, comprising a powder mixture, which contains molar quantities of the components calcium (Ca), strontium (Sr) and phosphate (P) in the mixture in the ranges 1.00<Ca/P?1.50 and 0<Sr/P<1.5, together with an alkali salt or an ammonium salt of phosphoric acid, and with water and/or an aqueous solution. The powder mixture particularly contains, as the Ca-component, Ca3(PO4)2 (TCP), and as the Sr-component SrHPO4 and/or Sr3(PO4)2 and optionally additional SrCO3. As the aqueous mixing solution for the formation of the strontium-apatite cement, an aqueous solution of an alkali salt or an ammonium salt of the phosphoric acid is suitable.

Abstract: Non-aqueous hydraulic cement compositions comprise a non-aqueous mixture of a powder composition and a non-aqueous water-miscible liquid. In one embodiment, powder composition is a Brushite or Monetite-forming calcium phosphate powder composition. In another embodiment, the powder composition comprises porous ?-tricalcium phosphate (?-TCP) granules and at least one additional calcium phosphate powder. In another embodiment, the powder composition comprises calcium silicate powder. In a further embodiment, the powder composition comprises calcium aluminate powder. In another embodiment, the powder composition is a cement composition and comprises nanopowders having a grain size of less than 1 micron. Hardened cements are formed from such hydraulic cement compositions, and methods of producing hardened cements, kits, and articles of manufacture employ such hydraulic cement compositions.

Abstract: A composition for binding environmentally-harmful substances in solid or semi-liquid state contains caustic magnesium oxide, non-ferrous metal salts as a hardener, non-ferrous metal oxides catalyzing formation of radial crystalline structures, and optionally water and other additives. A method of stabilization of environmentally-harmful substances binds these substances in the solid state or semi-liquid state in the composition containing caustic magnesium oxide, wherein the environmentally-harmful substances are supplemented by the composition containing caustic magnesium oxide, non-ferrous metal salts as hardener, non-ferrous metal oxides catalyzing formation of radial crystalline structures, and optionally water and other additives. A form of paste is obtained, followed by leaving the mixture for solidification and stabilization of the product.

Abstract: Rapid setting high strength calcium phosphate cements and methods of using the same are provided. Aspects of the cements include fine and coarse calcium phosphate particulate reactants and a cyclodextrin which, upon combination with a setting fluid, produce a flowable composition that rapidly sets into a high strength product. The flowable compositions find use in a variety of different applications, including the repair of hard tissue defects, e.g., bone defects such as fractures.

Abstract: A mixture for making a high strength phosphate cement includes monopotassium phosphate, a Group IIA metal oxide in amounts of about 20 to about 100 parts per 100 parts of the monopotassium phosphate and monocalcium orthophosphate in amounts of from about 3 to about 30 parts per 100 parts of the monopotassium phosphate. Products made from the phosphate cement have a pH of less than about 9 and the product develops a compressive strength greater than 2000 psi in 24 hours.

Abstract: A cement mix for preparation of a magnesium silico-phosphate cement (MSPC) with an altered hardening rate is provided. The cement mix comprises on the order of 1% of an [MF6]n? salt or acid. Upon addition of water, the mix produces a final set cement that has similar physical properties to those of a cement prepared from a mix lacking the additive, but with a significantly altered setting time. In some embodiments of the invention, the additive is provided in the form of a coating for the MgO component of the mix. In preferred embodiments, H2TiF6, Na2TiF6 and/or K2TiF6 are used as retarders, while K3AlF6 is used as an accelerant. Other embodiments use M?nMF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: The present invention relates to a gallium-doped phosphocalcic compound of formula (I): Ca(10.5-1.5x)Gax(PO4)7??(I) wherein 0<x<1 and the salts, hydrates and mixtures thereof. The invention further relates to a solid state process and a process in solution for the manufacture of such compounds and the use thereof for the preparation of a biomaterial, in particular a self-setting calcium-phosphate cement (CPC).

Abstract: Inorganic-organic composite articles and methods for producing them using inorganic acidic/alkaline precursor components as inorganic adhesives is provided. Articles prepared therefrom provide improved flexibility, zero flame spread, no release of volatile organic compounds, and low carbon foot print.

Abstract: A kneadable and moldable bone-replacement material includes a mixture of calcium-containing ceramic particles and a hydrogel or a substance which can be swelled into a hydrogel. The ceramic particles are of fully synthetic origin and the individual ceramic particles have a structure which is at least partially cohesive and porous. In addition, the majority of the ceramic particles have a non-spheric shape.

Abstract: A non-aqueous hydraulic cement composition comprises a non-aqueous mixture of (a) ?-tricalcium phosphate powder, (b) monocalcium phosphate powder, and (c) non-aqueous water-miscible liquid, wherein (i) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 200-600 ?m and the powder (weight) to liquid (volume) ratio is about 2.5-5.5, (ii) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 1-400 ?m and the powder (weight) to liquid (volume) ratio is about 2-5, or (iii) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 1-600 ?m and the powder (weight) to liquid (volume) ratio is about 2.5-5.5. Methods, hardened cements, articles of manufacture and kits employ such compositions.

Abstract: Disclosed are dual-phase cement precursor systems and associated methods and kits. The cement precursor systems comprises at least first and second phases each containing a calcium phosphate compound. When mixed, the first and second cement precursor phases form a biocompatible cement. The disclosed systems include an organic acid in an amount effective to enhance the working time of the cement precursor composition, and also include a setting accelerator. In some embodiments, one or more of the calcium phosphate compounds is provided in the form of particles with a nonmonomial particle sized distribution.

Abstract: The invention relates to a preparation for a magnesium ammonium phosphate cement. There is provided a preparation comprising (a) a magnesium calcium phosphate of the formula MgxCay(PO4)2Oz, wherein x+y?4, x>1, y>0, z=x+y?3 and z?0; (b) an ammonium salt; and (c) water; wherein the ammonium salt and the water can be present partially or completely as an aqueous solution of the ammonium salt.

Abstract: Embodiments of the present invention provide cellular phosphate bodies formed using specialized steps to ensure a specific strength range, and specifically a compressive strength less than 100 pounds per square inch. Further embodiments relate to uses for various phosphate ceramics as vehicle arresting systems.

Abstract: Methods for preparing a tricalcium phosphate coarse particle composition are provided. Aspects of the methods include converting an initial tricalcium phosphate particulate composition to hydroxyapatite, sintering the resultant hydroxyapatite to produce a second tricalcium phosphate composition and then mechanically manipulating the second tricalcium phosphate composition to produce a tricalcium phosphate coarse particle composition. The subject methods and compositions produced thereby find use in a variety of applications.

Abstract: Bone graft compositions for repairing bone defects, which are characterized by a chemical composition of cementitious, non-cementitious, highly-resorbable and poorly-resorbable particulate substances, and further characterized by a specific particle size distribution that includes two or more different ranges of particle size, are disclosed. Further disclosed are articles of manufacturing and unit dosage forms containing the bone graft compositions, methods of repairing bone defects utilizing the bone graft compositions, and processes of preparing the same. Also provided are applicators for applying flowable mixtures formed by mixing a dry composition and a liquid carrier, which are particularly useful for preparing and applying bone graft compositions, as well as methods of using same.

Abstract: Methods and compositions for producing flowable compositions, e.g. pastes, that set into calcium phosphate products are provided. In the subject methods, dry reactants that include a calcium source and a phosphate source are combined with a setting fluid to produce the flowable composition. A feature of the subject methods is that the dry reactants include a particulate calcium and/or phosphate reactant having a mean particle size of less than about 8 ?m and narrow size distribution. Also provided are the compositions themselves as well as kits for use in practicing the subject methods. The subject methods and compositions produced thereby find use in a variety of applications, including the repair of hard tissue defects, e.g., bone defects.

Abstract: Waste storage vessels formed from a composition including calcium silicate, magnesium or calcium oxides and an acid phosphate are provided. The composition may also include fly ash or kaolin with or without the calcium silicate.

Abstract: A non-aqueous hydraulic cement composition comprises a non-aqueous mixture of (a) ?-tricalcium phosphate powder, (b) monocalcium phosphate comprising monocalcium phosphate anhydrous (MCPA), monocalcium phosphate monohydrate (MCPM), or a combination thereof, and (c) non-aqueous water-miscible liquid, wherein a 0.1 g/ml saturated aqueous solution of the monocalcium phosphate has a pH less than 3.0. Methods of producing a hardened cement, hardened cements, kits, and articles of manufacture employ such compositions.

Abstract: A non-aqueous hydraulic cement composition comprises a non-aqueous mixture of (a) ?-tricalcium phosphate powder, (b) monocalcium phosphate powder, and (c) non-aqueous water-miscible liquid, wherein (i) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 200-600 ?m and the powder (weight) to liquid (volume) ratio is about 2.5-5.5, (ii) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 1-400 ?m and the powder (weight) to liquid (volume) ratio is about 2-5, or (iii) at least about 90% of the monocalcium phosphate powder has a grain size in a range of about 1-600 ?m and the powder (weight) to liquid (volume) ratio is about 2.5-5.5. Methods, hardened cements, articles of manufacture and kits employ such compositions.

Abstract: A method is provided for advantageously altering the rate of hardening of a magnesium silico-phosphate cement (MSPC). Addition of on the order of 1% of an [MF6]n? salt or acid to an MSPC, obtained by adding the salt or acid either directly to the dry mix or to the water used to effect hydraulic hardening of the cement, significantly alters the hardening rate without adversely affecting the physical properties of the final set cement. In preferred embodiments, Na2TiF6 and/or K2TiF6 are used as retardants, while K3AlF6 is used as an accelerant. Other embodiments use M?n-MF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), Si (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: A hybrid magnesium cement composition formed of an A-side and a B-side. The A-side having an A1-component including a light-burn grade magnesium-containing material, and an A2-component including a non-metallic oxide salt. A B-side having a metal silicate polymer is included.