Abstract: A method of solidifying and detoxifying a soil, incinerated ash and coal ash to yield a solidified substance detoxified to a level complying with the environmental standards and a method of detoxifying polluted water containing dioxins and polluted water containing PCB are provided. First solidifying and detoxifying agent contains light burnt magnesite as component (1) and chrysolite powder as component (2), in which a ratio by weight of the component (1) and the component (2) is 1:5 to 5:1, preferably 1:3 to 3:1, more preferably 1:2 to 2:1 and is the solidifying and detoxifying agent applied to one kind selected from soil, incinerated ash and coal ash as well as polluted water containing dioxins and polluted water containing PCB. Other solidifying and detoxifying agent further contains as an additional component a fused phosphate fertilizer and titanium dioxide powder as well as anhydrous gypsum powder, light burnt dolomite and/or calcined lime powder.

Abstract: A sealant having a specific gravity in the range of from about 0.7 to about 1.6 for heavy oil and/or coal bed methane fields is disclosed. The sealant has a binder including an oxide or hydroxide of Al or of Fe and a phosphoric acid solution. The binder may have MgO or an oxide of Fe and/or an acid phosphate. The binder is present from about 20 to about 50% by weight of the sealant with a lightweight additive present in the range of from about 1 to about 10% by weight of said sealant, a filler, and water sufficient to provide chemically bound water present in the range of from about 9 to about 36% by weight of the sealant when set. A porous ceramic is also disclosed.

Abstract: A hydraulic cement based on calcium phosphate for surgical use comprising A) a first component comprising powder particles of calcium phosphate; and B) a second component comprising water. The calcium phosphate comprises anhydrous, amorphous calcium phosphate (ACP) and the ACP is obtained by milling a calcium phosphate synthesized above 500° C. The cement according to the invention has the advantage of being very fast setting compared to prior art calcium phosphate cements. The setting reaction is finished much faster although the initial part of the reaction proceeds at the same speed as with known cements.

Abstract: A method is provided for making inexpensive synthetic inorganic resins that are stable, mix easily with water and may be conveniently diluted to form an easy-to-use paste for commercial applications. The method uses environmentally friendly techniques to provide improved efficiencies in the commercial production of these resins. The resins are produced by the partial reaction of phosphoric acid with sparsely-soluble oxides, or sparsely-soluble oxide minerals, that are added to the phosphoric acid under controlled conditions. In certain specific embodiments, methods are provided for modifying synthetic inorganic resins so as to produce rapid-setting phosphate cements and ceramics having high flexural strength. Unique synthetic inorganic resin formulations are also disclosed.

Abstract: A cementitious composition being a mixture of mono ammonium hydrogen phosphate, magnesium oxide, silicate fibers and water. For the dry components, approximately 40 to 90 wt. percent magnesium oxide, approximately 30 to 5 wt. percent mono ammonium hydrogen phosphate and approximately 30 to 5 wt. percent silicate fibers are mixed.

Abstract: A self-foaming bone cement is described herein. In one variation, the bone cements include a self setting calcium phosphate cement formulation which when cured, forms macroscopic pores of varying sizes and densities with sufficient surface area to provide substantial regions for bone turnover.

Abstract: The bone repair material comprises the following components: A) a first granular component with a diameter larger than 20 ?m chosen from the group of: calcium phosphate, calcium pyrophosphate, or calcium sulfate dihydrate; B) a second component chosen from the group of apatite powder with a particle diameter smaller than 1 ?m, (preferably smaller than 100 nm); and B) a third component comprising water or an aqueous solution, whereby C) the volume fraction of the second and third component represents at least 35 volume-% of the total bone repair material.

Abstract: This invention relates to a cement, which comprises in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive.

Abstract: A hydraulic cement for biomedical applications. The cement sets in-situ, hardening when exposed to water to produce nano-dispersed composite of calcium-silicate-hydrate gel mixed with hydroxyapatite. In comparison with prior cements, the composition provides high biocompatibility, high bioactivity and high biomechanical strength, due to the composite structure of the calcium silicate hydrate reinforced with co-precipitated particles of hydroxyapatite. Biocompatibility is also increased due to an absence of aluminum and magnesium in the composition. The cement is suitable for variety of applications, including dental implants, bone fixation, and bone repair.

Abstract: The invention is related to a premixed putty calcium phosphate composition comprising at least two calcium phosphate minerals, at least one reaction retarding agent, at least one binding agent, at least one sodium phosphate, and at least one nonaqueous extender, wherein one of said at least two calcium phosphate minerals contains a stabilizing agent.

Abstract: This invention relates to a cement, which comprises in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive.

Abstract: Ceramic precursor compositions and chemically bonded ceramic (CBC) materials, especially Ca-based, and a composite biomaterial suitable for orthopaedic applications. The CBC-system includes a binding phase (chemical cement) and additional phases with specified chemistry imparting to the biomaterial the ability of initial strength followed by interaction with the body tissue including body liquid, to form a resorbable or partly resorbable biomaterial. The ceramic precursor composition includes at least one silicate with Ca as the main cation with a resorption rate less or equal to that of the bone in-growth rate. The silicate will form the binding phase of the cured material. Implants and surface coated devices are also disclosed. The cured material exhibits a compressive strength exceeding 100 MPa.

Abstract: A method of servicing a wellbore comprising placing in the wellbore a cement composition comprising light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set. A method of cementing comprising preparing a cement composition comprising a light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set.

Abstract: A road and repair system and/or method using one or more components including a plurality of magnetite concentrate particles, at least one acidic activator including phosphate anions, and a plurality of reactive aggregate particles including iron.

Abstract: A cement powder is disclosed that contains reactive tricalcium phosphate nanoparticles and other ingredients required to form a cementous material. Methods of making the reactive tricalcium phosphate nanoparticles, the cement powder, the cement paste, and cured cement are also provided, as are methods and articles for using the cement.

Abstract: A wellbore may be cemented by preparing a cementitious composition comprising water, a metal oxide or hydroxide compound, a phosphate compound, a borate compound, and a sugar, followed by displacing the cementitious composition into the wellbore. The metal oxide or hydroxide compound reacts with the phosphate compound in the wellbore to set into a hard mass. The synergistic effect of the borate compound and the sugar may increase a thickening time of the cementitious composition to in a range of from about 2 hours to about 11 hours at ambient temperatures in the wellbore. As such, the thickening time is sufficient to allow the cementitious composition to be placed in its desired location in the wellbore before setting.

Abstract: A self-foaming bone cement is described herein. In one variation, the bone cements include a self setting calcium phosphate cement formulation which when cured, forms macroscopic pores of varying sizes and densities with sufficient surface area to provide substantial regions for bone turnover.

Abstract: A plurality of shaped particles that comprises at least one shaped early mechanically strong particle, the plurality of particles comprising a plurality of settable compounds, the shaped early mechanically strong particles being solid, porous, hollow, or a combination thereof, and being at least one of round and elongated.

Abstract: A cementitious material is provided that includes a phosphate based component and an alkali earth component. The alkali earth ion component has as a majority source a calcium aluminate calcium ion source of dodeca-calcium hepta-aluminate, or tricalcium aluminate. Magnesium oxide that has been fused and crushed to a size of less than 200 microns, alone or in combination with the calcium aluminate calcium ion source is also provided as the alkali earth ion component. When the phosphate based component and alkali earth ion components are combined in appropriate proportions, a rigid structure is obtained. A cementitious material formulation is also provided having an aqueous acidic phosphate solution as a part B and an alkali earth ion source as a part A that includes calcium aluminate, magnesium oxide or a combination thereof. Other additives include strength enhancing insoluble phosphate additive, an impurity metal reaction suppressant, tackifiers, anti-foaming agents, and the like.

Abstract: Calcium-strontium-hydroxyphosphate (strontium-apatite-) cement preparations are described, comprising a powder mixture, which contains molar quantities of the components calcium (Ca), strontium (Sr) and phosphate (P) in the mixture in the ranges 1.00<Ca/P?1.50 and 0<Sr/P<1.5, together with an alkali salt or an ammonium salt of phosphoric acid, and with water and/or an aqueous solution. The powder mixture particularly contains, as the Ca-component, Ca3(PO4)2 (TCP), and as the Sr-component SrHPO4 and/or Sr3(PO4)2 and optionally additional SrCO3. As the aqueous mixing solution for the formation of the strontium-apatite cement, an aqueous solution of an alkali salt or an ammonium salt of the phosphoric acid is suitable.

Abstract: A chemically bonded biomaterial element composed of an inorganic cement, exhibiting minimal dimensional changes upon hardening and long-time use, improved mechanical properties and improved translucency. An algorithm to describe the micro-structure is expressed as ? = d * ( 1 - V F ) ( V F ) where ? is the distance between filler particles of mean size d, and VF is the volume content of non-reacted cement and added filler, and where ??10 ?m. The invention also relates to a device in connection with the preparation of a chemically bonded biomaterial element according to the invention.

Abstract: The invention provides a set gypsum-containing product having increased resistance to permanent deformation and a method for preparing it comprising forming a mixture of a calcium sulfate material, water, and an appropriate amount of one or more enhancing materials chosen from condensed phosphoric acids, each of which comprises 2 or more phosphoric acid units; and salts or ions of condensed phosphates, each of which comprises 2 or more phosphate units. The mixture is then maintained under conditions sufficient for the calcium sulfate material to form a set gypsum material.

Abstract: Composite materials made from reactive compounds such as oxides are disclosed. The materials comprise a reaction producing of metal oxide, phosphate and reactive residual materials. The metal oxide may comprise MgO, CaO, ZnO, TiO2 or the like. The phosphate may comprise mono-potassium phosphate, mono-ammonium phosphate, mono-sodium phosphate or the like. The reactive residual material may be ash, phosphate clay, phosphate residual slurry, mining waste or the like. The composite materials may be used for many applications including rapid repair materials, pre-cast structures, in-situ structures, mixes and coatings.

Abstract: Of the many methods and compositions provided herein, one method comprises providing a cement composition, wherein the cement composition comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into at least a portion of the subterranean formation; and allowing the cement composition to at least partially set therein. Another method provided herein comprises providing a cement composition that comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into a void located in a pipe string; and allowing the cement composition to at least partially set therein.

Abstract: A method of making a rapid setting composition for cement boards is disclosed. Compositions including portland cement, fly ash, gypsum, alkanolamine and phosphate are disclosed. A synergistic interaction between the alkanolamine and phosphate increases the effectiveness of accelerating reactions thus allowing for quick setting and increased early-age compressive strength compositions.

Abstract: A calcium phosphate composition comprising at least one calcium phosphate mineral, at least one reaction retarding agent, at least one biding agent, and at least one sodium phosphate compound.

Abstract: The present invention provides foamed cement compositions with improved mechanical properties and methods of cementing in subterranean formations, particularly in conjunction with subterranean well operations. The foamed cement compositions comprise carbon fibers, a hydraulic cement material, sufficient water to form a slurry, an expanding additive, and optionally other ingredients including a weighting agent, a retarding or accelerating agent, or the like.

Abstract: A sealant for an oil or geothermal well capable of setting within about 3 to about 6 hours at temperatures less than about 250° F. for shallow wells less than about 10,000 feet and deep wells greater than about 10,000 feet having MgO present in the range of from about 9.9 to about 14.5%, KH2PO4 present in the range of from about 29.7 to about 27.2%, class C fly ash present in the range of from about 19.8 to about 36.3%, class F fly ash present in the range of from about 19.8 to about 0%, boric acid or borax present in the range of from about 0.39 to about 1.45%, and water present in the range of from about 20.3 to about 21.86% by weight of the sealant. A method of sealing wells is disclosed as are compositions for very high temperature wells is disclosed as is a composition for treating oil field wastes.

Abstract: This invention relates to a cement, which comprises in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive.

Abstract: The photocatalytic granular mixture for mortar and concrete includes a photocatalyst in the form of at least two granular classes with different B.E.T. specific surfaces. It has a photocatalytic activity greater than that of a monodisperse photocatalyst with a single range of B.E.T. specific surface, and thus permits, in association with a conventional hydraulic binder, to obtain construction and repair materials whose aptitude for self cleaning, for the reduction of odors, and for the depollution of ambient air, is considerably improved.

Abstract: Compositions useful in the prevention and treatment of osteoporosis and for bone and fracture repair. Slow-releasing calcium phosphate-based materials are disclosed, incorporating Mg, Zn, F and carbonate, which will promote bone formation and inhibit bone resorption and thus be agents for the cited uses.

Abstract: The invention is related to a rapid setting calcium phosphate cement comprising a powdered first component comprising stabilized dicalcium phosphate dihydrous containing from about 10 ppm to about 60 ppm of magnesium, a powdered second component comprising a calcium phosphate mineral other than said stabilized dicalcium phosphate dihydrous, and a liquid third component comprising water.

Abstract: The invention concerns injectable bone filling cements, in particular hydraulic calcium phosphate cements, the latter being prepared from at least two initial liquid or pasty constituents comprising each a species reactive in solution or in suspension, the solidification process being initiated when said constituents are being mixed.

Abstract: A kit for preparing a hardenable cementitious composition includes a pre-proportioned cementitious material component and at least one pre-formulated and pre-proportioned liquid additive component, wherein the cementitious material and liquid components are mixed with together to prepare a cementitious material that possesses end application properties. Also disclosed is a method for preparing a hardenable cementitious composition using the kit and a method for repairing a flas in a cementitious structure using the hardenable cementitious composition.

Abstract: A structural material of a polystyrene base and the reaction product of the polystyrene base and a solid phosphate ceramic is applied as a slurry which includes one or more of a metal oxide or a metal hydroxide with a source of phosphate to produce a phosphate ceramic and a poly (acrylic acid or acrylate) or combinations or salts thereof and polystyrene or MgO applied to the polystyrene base and allowed to cure so that the dried aqueous slurry chemically bonds to the polystyrene base. A method is also disclosed of applying the slurry to the polystyrene base.

Abstract: A hydraulic cement is based on calcium phosphate for surgical use, and includes three components. The first component includes ?-tricalcium phosphate powder particles. The second, component includes calcium sulphate dehydrate. The third component includes water. Furthermore the hydraulic cement does not contain more calcium sulfate hemihydrate (CSH) than 10% of the total amount of the calcium sulphate dihydrate (CSD).

Abstract: The invention describes a method of preparing macroporous calcium phosphate granules with NaCl porogen technique, wherein a calcium phosphate self-setting cement powder is mixed with 30 to 80 wt % NaCl. The calcium phosphate granules comprise macro- and micropores communicating with one another substantially throughout the body with a porosity of 40% or more and having the same mineral as those of human bones. Said granules are used as a substitute or repairing material for bone, carrier material for drug delivery and gradual release system.

Abstract: A composition and method for producing interconnective macroporous, resorbable and injectable calcium phosphate-based cements (MICPCs). The composition of the invention sets to poorly crystalline apatitic calcium phosphate after mixing a powder component and an aqueous solution. The multiphasic calcium phosphate components in the cement resorb at different rates allowing the timely replacement by new bone. The interconnected macroporosity in the cement allows for vascularization, entrapment of growth factors, cell colonization and tissue ingrowth. This MICPC can be used for dental and medical applications relating to bone repair, augmentation, reconstruction, regeneration, and osteoporosis treatment, and also for drug delivery, and as scaffolds for tissue engineering.

Abstract: A structural material of a polystyrene base and the reaction product of the polystyrene base and a solid phosphate ceramic. The ceramic is applied as a slurry which includes one or more of a metal oxide or a metal hydroxide with a source of phosphate to produce a phosphate ceramic and a poly (acrylic acid or acrylate) or combinations or salts thereof and polystyrene or MgO applied to the polystyrene base and allowed to cure so that the dried aqueous slurry chemically bonds to the polystyrene base. A method is also disclosed of applying the slurry to the polystyrene base.

Abstract: The present invention relates to refractory composition consisting essentially of 40-90 dry weight % of amorphous silica aggregates, up to 40 dry weight % of alumina based compounds 10-15 dry weight % of clay, 0.2-2.0 dry weight % of a chemical binder and further containing 2 to 8% of water. These compositions are particularly useful for the repair of coke oven damaged wall in a gunning process.

Abstract: In order to produce a dental cast product having the flat surface, by blending a dispersant with a phosphate-based investing material to improve the dispersability of an aggregate powder and a binder powder so as to prevent a agglomeration of the aggregate powder and the binder powder thereby forming a wall surface of an cavity in a mold to be flat, and also to make more various kinds of powders available for the aggregate powder without restriction to quartz, cristobalite and tridymite, the phosphate-based dental investing material comprising a mixed powder including an aggregate powder and a phosphate-based binder powder, and a liquid, with an alkaline metal salt of phosphoric acid being added to at least one of the mixed powder and the liquid.

Abstract: A self-foaming bone cement is described herein. In one variation, the bone cements include a self setting calcium phosphate cement formulation which when cured, forms macroscopic pores of varying sizes and densities with sufficient surface area to provide substantial regions for bone turnover.

Abstract: A bone or dental implant material in the form of a paste includes a mixture of calcium phosphate and/or calcium-containing powders and a solution that is (1) an acidic calcium phosphate solution saturated with respect to one or more calcium phosphate compounds, (2) a concentrated acid solution, or (3) salt solutions with a cationic component other than calcium. The paste is stable, resistant to washout and will form hydroxyapatite and harden relatively rapidly to a cement.

Abstract: A fast-setting, bioresorbable calcium phosphate cement is prepared by a process which can be carried out with a heat treatment up to 1000° C. on a mixture of a wetting solution and a calcium phosphate powder having a Ca to P molar ratio of 0.5-2.5. The wetting solution suitable for use in the process of the present invention includes water, an organic solvent, an acidic and basic solution. A setting solution for mixing with the heated powder to form the fast-setting, bioresorbable calcium phosphate cement may be water, an acidic or basic solution according to the process of the present invention.

Abstract: A cementitious material is provided that includes a phosphate based component and an alkali earth component. The alkali earth ion component has as a majority source a calcium aluminate calcium ion source of dodeca-calcium hepta-aluminate, or tricalcium aluminate. Magnesium oxide that has been fused and crushed to a size of less than 200 microns, alone or in combination with the calcium aluminate calcium ion source is also provided as the alkali earth ion component. When the phosphate based component and alkali earth ion components are combined in appropriate proportions, a rigid structure is obtained. A cementitious material formulation is also provided having an aqueous acidic phosphate solution as a part B and an alkali earth ion source as a part A that includes calcium aluminate, magnesium oxide or a combination thereof. Other additives include strength enhancing insoluble phosphate additive, an impurity metal reaction suppressant, tackifiers, anti-foaming agents, and the like.

Abstract: Calcium-strontium-hydroxyphosphate (strontium-apatite-) cement preparations are described, comprising a powder mixture, which contains molar quantities of the components calcium (Ca), strontium (Sr) and phosphate (P) in the mixture in the ranges 1.00<Ca/P?1.50 and 0<Sr/P<1.5, together with an alkali salt or an ammonium salt of phosphoric acid, and with water and/or an aqueous solution. The powder mixture particularly contains, as the Ca-component, Ca3(PO4)2 (TCP), and as the Sr-component SrHPO4 and/or Sr3(PO4)2 and optionally additional SrCO3. As the aqueous mixing solution for the formation of the strontium-apatite cement, an aqueous solution of an alkali salt or an ammonium salt of the phosphoric acid is suitable.

Abstract: A method for increasing working time/setting time of monolithic tetracalcium phosphate (TTCP) cement paste formed by mixing a TTCP powder with an aqueous solution, which includes heating the TTCP powder, prior to the mixing, so that the TTCP powder is maintained at a temperature of 50-350° C. for a period of time which is greater than one minute, and that a TTCP cement paste formed by mixing the resulting heated TTCP powder with the aqueous solution has a prolonged working time in comparison with that formed by mixing TTCP powder that has not been subjected to such heating with the aqueous solution.

Abstract: A fast-setting, bioresorbable calcium phosphate cement is prepared by a process which can be carried out with a heat treatment up to 1000° C. on a mixture of a wetting solution and a calcium phosphate powder having a Ca to P molar ratio of 0.5-2.5. The wetting solution suitable for use in the process of the present invention includes water, an organic solvent, an acidic and basic solution. A setting solution for mixing with the heated powder to form the fast-setting, bioresorbable calcium phosphate cement may be water, an acidic or basic solution according to the process of the present invention.

Abstract: A calcium phosphate cement suitable for use in dental and bone prosthesis is disclosed, which include calcium phosphate particles having a diameter of 0.05 to 100 microns, wherein said calcium phosphate particles on their surfaces have whiskers or fine crystals having a width ranging from 1 to 100 nm and a length ranging from 1 to 1000 nm.

Abstract: Inorganic resin compositions comprising, in combination, an aqueous solution of metal phosphate, an oxy-boron compound, a wollastonite compound and other optional additives, inorganic composite articles and products reinforced by fillers and fibers including glass fibers obtained from these compositions and processes for preparing said products.