Cement Clinker Preparation Patents (Class 106/693)
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Patent number: 11542206Abstract: A porous refractory cast material contains a closed refractory aggregate fraction having a minimum particle size and a maximum particle size; the ratio of maximum particle size to minimum particle size is 10:1 or less. This closed refractory aggregate fraction comprises all of the porous refractory cast material having a particle diameter greater than 0.1 mm. The porous refractory cast material also contains a binder phase containing refractory selected from calcium aluminate cement, alumina phosphate, hydratable alumina, colloidal silica and combinations thereof. Also disclosed is a metallurgical vessel with an interior lining incorporating the porous refractory cast material.Type: GrantFiled: April 4, 2018Date of Patent: January 3, 2023Assignee: Vesuvius USA CorporationInventors: Duane L. Debastiani, Xianxin Zhou
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Patent number: 11358900Abstract: The present invention relates to an aluminous cement.Type: GrantFiled: December 21, 2018Date of Patent: June 14, 2022Assignee: Calucem GmbHInventors: Günther Walenta, Ronny Kaden, Markus Schmid
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Patent number: 11208353Abstract: Disclosed is a calcium aluminate cement, including a calcium aluminate with a first crystallised mineralogical phase of calcium dialuminate CA2 including one calcium oxide CaO for two aluminium oxides Al2O3 and/or a second crystallised mineralogical phase of dicalcium alumina silicate C2AS including two calcium oxides CaO for one aluminium oxide Al2O3 and one silicon dioxide SiO2. The mass fraction of all of the first and second mineralogical phases in the calcium aluminate is greater than or equal to 80%.Type: GrantFiled: May 11, 2020Date of Patent: December 28, 2021Assignee: KERNEOSInventors: Bruno Espinosa, Mark Winslow Fitzgerald, Charles Walter Alt, Philippe Thouilleux, Ratana Soth, Michaël Lievin
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Patent number: 10647613Abstract: Disclosed is to a calcium aluminate cement, including a calcium aluminate with a first crystallised mineralogical phase of calcium dialuminate CA2 including one calcium oxide CaO for two aluminium oxides Al2O3 and/or a second crystallised mineralogical phase of dicalcium alumina silicate C2AS including two calcium oxides CaO for one aluminium oxide Al2O3 and one silicon dioxide SiO2. The mass fraction of all of the first and second mineralogical phases in the calcium aluminate is greater than or equal to 80%.Type: GrantFiled: July 27, 2016Date of Patent: May 12, 2020Assignee: KERNEOSInventors: Bruno Espinosa, Mark Winslow Fitzgerald, Charles Walter Alt, Philippe Thouilleux, Ratana Soth, Michael Lievin
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Patent number: 10000413Abstract: A clinker for use in cement manufacturing includes a cement clinker mixture having crystals of an element that is less electronegative than carbon and carbon bonded to at least a portion of the crystals.Type: GrantFiled: December 16, 2015Date of Patent: June 19, 2018Assignee: The United States of America as Represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Morgan Barrera Abney, James E. Alleman
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Patent number: 9765451Abstract: A functional polyester thread includes nanosized and surface treated pearlite, whose water absorbance, thermal and noise insulation, and antibacterial protection properties are improved in order to be used in industries like automotive, filter, textile and construction, etc. industries. A production method for polyester thread is also disclosed.Type: GrantFiled: May 16, 2014Date of Patent: September 19, 2017Inventors: Esra Karaca, Sunay Ömeroglu, Okan Akçam
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Patent number: 9533429Abstract: A method and system for system for rapidly determining the predicted strength of concrete prior to pouring the concrete is disclosed herein. The system and process provides for a database storing concrete family characteristics that may be updated as actual strength of poured concrete is determined. The process also allows construction workers to pour concrete with a keener knowledge of the resulting concrete strength.Type: GrantFiled: March 15, 2013Date of Patent: January 3, 2017Assignee: Command Alkon, Inc.Inventors: Robert W. Phares, Charlene Hohl
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Patent number: 9353002Abstract: Cement material, curable in the presence of water and including a hydraulic binder composition, which contains a mixture of hydraulic binders and a mixture of sulphate sources, wherein the hydraulic binder mixture includes: at least one hydraulic binder containing an alite-type mineralogical phase and at least one hydraulic binder containing an aluminate-type mineralogical phase, mainly consisting of ye'elimite (C4A3$) or a mixture of ye'elimite and calcium monoaluminate (CA), the mixture of sulphate sources containing at least one sulphate source with a solubility of <4 g·L?1, and at least one sulphate source with a solubility >4 g·L?1, the cement material optionally including mineral additions, fine granulates, large granulates and additives. The curable cement material is useful as a material capable of setting in cold weather, in particular a concrete, a mortar, a grout, a coating or a cement paste to be used at a temperature of ?10° C. to +5° C.Type: GrantFiled: December 16, 2013Date of Patent: May 31, 2016Assignee: CIMENTS FRANCAISInventor: Jean-Pierre Grelaud
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Patent number: 9034099Abstract: The present invention relates to a novel cement which makes possible the preparation of concrete, grout or mortar which is resistant to internal sulfate reactions and to external sulfate attacks, and also the use of this cement for the preparation of concrete, grout or mortar.Type: GrantFiled: November 24, 2011Date of Patent: May 19, 2015Assignee: VICATInventors: Laetitia Bessette, Francois Hue, Martine Pasquier
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Patent number: 8986444Abstract: A hybrid cement clinker incorporates specific ranges of clinker phases and falls within specific modulus values as set forth and described in this document.Type: GrantFiled: February 14, 2014Date of Patent: March 24, 2015Assignee: University of Kentucky Research FoundationInventors: Thomas Robl, Tristana Duvallet, Robert Rathbone, Yongmin Zhou
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Publication number: 20150053118Abstract: The present disclosure relates to a method for manufacturing cement clinker with waste concrete as a blending material, comprising the steps of: i) crushing waste concrete into granules with particle size less than or equal to 40 mm; ii) adding the granules obtained in step i) to a cement production plant and mixing the granules with clinker in said production plant, wherein said granules are activated by the residual heat of said clinker, and then mixed with said clinker to directly serve as a blending material, and thus said cement clinker is manufactured. The present disclosure further relates to a cement comprising the cement clinker manufactured by said method.Type: ApplicationFiled: November 14, 2013Publication date: February 26, 2015Inventor: Wuji Yin
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Publication number: 20140311386Abstract: A hybrid cement clinker incorporates specific ranges of clinker phases and falls within specific modulus values as set forth and described in this document.Type: ApplicationFiled: February 14, 2014Publication date: October 23, 2014Applicant: University of Kentucky Research FoundationInventors: Thomas Robl, Tristana Duvallet, Robert Rathbone, Yongmin Zhou
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Patent number: 8864902Abstract: A cement clinker which can be sintered at 1,300 to 1,400° C. which is lower than the conventional sintering temperature and develops excellent strength characteristics such as mortar compression strength. The cement clinker has a total content of C3A and C4AF calculated by Bogue's formulas of 22 mass % or more, a C3S content calculated by Bogue's formula of 60 mass % or more and an iron modulus (I.M.) of 1.3 or less, preferably 1.0 to 1.3. Since the total content of C3A and C4AF is 22 mass % or more, the cement clinker can be sintered at a low temperature and the reduction of strength when a cement composition is cured can be prevented by reducing the iron modulus of the cement clinker.Type: GrantFiled: April 17, 2012Date of Patent: October 21, 2014Assignee: Tokuyama CorporationInventors: Hiroshi Nagata, Akinori Nakamura, Hiroyoshi Kato, Takashi Chabayashi, Daihachi Kitayama
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Patent number: 8828136Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.Type: GrantFiled: March 25, 2014Date of Patent: September 9, 2014Assignee: PKL CorporationInventors: Edward K. Rice, Grant M. Kao, Eric P. Bescher
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Patent number: 8715411Abstract: A method for producing a clinker for cement, comprising grinding a raw flour comprising, especially, Al2O3, Fe2O3 and SO3 in contents such that the formula for calculating SO3 content of=0.261×Al2O3?0.638×Fe2O3+k, where 2.5<k<3.5, then by sintering flour in an overn wherein the temperature is between 1250° C. and 1350° C. and oxygen content is between 2.5% and 10% by volume.Type: GrantFiled: June 17, 2011Date of Patent: May 6, 2014Assignee: Cemex Research Group AGInventors: Juan Carlos Martinez, Norma Leticia Garza Gonzalez, Karla Serrano Gonzalez, Homero Ramirez Tovias
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Patent number: 8574359Abstract: The invention relates to a sulfo-aluminous clinker with optimal setting time and short term compressive strengths, comprising a mixture of the following phases: —calcium sulfoaluminate, or C4A3$, in amounts higher than 50% by weight of the mixture, —belite, or C25, in amounts between 2 and 23%, —3C25 3C$ CaX2, X being fluorine or chlorine, between 3 and 15% —C11A7CaX2, X being fluorine or chlorine, between 2 and 12%, both fluorine and chlorine being altogether present in the mixture, and phase C5S2$ being absent. The invention also relates to a method for preparing this sulfo-aluminous clinker, and hydraulic binders comprising this clinker.Type: GrantFiled: November 15, 2011Date of Patent: November 5, 2013Assignee: ItalcementiInventors: Maurizio Iler Marchi, Stefano Allevi
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Publication number: 20130233207Abstract: The invention relates to a sulfo-aluminous clinker with optimal setting time and short term compressive strengths, comprising a mixture of the following phases: calcium sulfoaluminate, or C4A3$, in amounts higher than 50% by weight of the mixture, belite, or C2S, in amounts between 2 and 23%, 3C2S 3C$ CaX2, X being fluorine or chlorine, between 3 and 15% C11A7CaX2, X being fluorine or chlorine, between 2 and 12%, both fluorine and chlorine being altogether present in the mixture, and phase C5S2$ being absent. The invention also relates to a method for preparing this sulfo-aluminous clinker, and hydraulic binders comprising this clinker.Type: ApplicationFiled: November 15, 2011Publication date: September 12, 2013Inventors: Maurizio Iler Marchi, Stefano Allevi
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Patent number: 8506701Abstract: The present invention provides the production of the hydraulic powder containing C3A in an amount of 0.5 to 9.5% by weight through a step of grinding a hydraulic compound in the presence of the alkanolamine having a freezing point of not higher than 0° C.Type: GrantFiled: July 14, 2011Date of Patent: August 13, 2013Assignee: Kao CorporationInventors: Keiichiro Sagawa, Masaaki Shimoda, Koji Nagasawa
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Publication number: 20130152825Abstract: A method for producing a clinker for cement, comprising grinding a raw flour comprising, especially, Al2O3, Fe2O3 and SO3 in contents such that the formula for calculating SO3 content of=0.261×Al2O3?0.638×Fe2O3+k, where 2.5<k<3.5, then by sintering flour in an overn wherein the temperature is between 1250° C. and 1350° C. and oxygen content is between 2.5% and 10% by volume.Type: ApplicationFiled: June 17, 2011Publication date: June 20, 2013Applicant: CEMEX RESEARCH GROUP AGInventors: Homero Ramirez Tovias, Juan Carlos Martinez, Norma Leticia Garza Gonzalez, Karla Serrano Gonzalez
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Patent number: 8425679Abstract: It is the object of the invention to provide a cement admixture, and a cement composition that can impart good enough rustproofness to reinforcing bars in hardened cement concrete, and can have resistance to penetration of chloride ions entering from the outside, prevent the hardened cement concrete from getting porous due to reduced leaching of Ca ions and have a self-recovery capability. The invention provides a cement admixture characterized by containing a calcium ferroaluminate compound comprising a CaO—Al2O3—Fe2O3 system, and having a Fe2O3 content of 0.5 to 15% by mass and a CaO.2Al2O3 structure with a CaO/Al2O3 molar ratio ranging from 0.15 to 0.7.Type: GrantFiled: November 25, 2010Date of Patent: April 23, 2013Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Taiichiro Mori, Kazuto Tabara, Kenji Yamamoto, Minoru Morioka, Takayuki Higuchi
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Patent number: 8317915Abstract: A composition includes at least, in % expressed by mass relative to the total mass of the composition, from 0.01 to 3% of polycarboxylic acid or salts thereof, the polycarboxylic acid including 2 to 4 carboxyl groups per molecule; and from 97 to 99.99% of a Belite-Calcium-Sulphoaluminate-Ferrite clinker (BCSAF clinker).Type: GrantFiled: July 20, 2010Date of Patent: November 27, 2012Assignee: LafargeInventors: Gunther Walenta, Ellis Gartner, Vincent Morin
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Patent number: 8268071Abstract: The invention relates to a novel sulfoaluminous clinker, to a method for preparing said clinker, and to the use of said clinker for preparing a hydraulic binder and subsequently grout, concrete, or mortar.Type: GrantFiled: January 28, 2010Date of Patent: September 18, 2012Assignee: VICATInventors: Michel Pasquier, Laury Barnes-Davin, Guy Beauvent
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Calcium Aluminate Clinker as a Refractory Aggregate with and without Barium Addition and Use Thereof
Publication number: 20120180703Abstract: The present invention provides for a refractory aggregate composition comprising an improved calcium aluminate clinker having the formula CnAx wherein C is calcium oxide and A is aluminum oxide, wherein n is an integer from about 1 to about 12, wherein x is an integer from about 1 to about 24, and wherein said clinker has from zero to less than about fifty weight percent C12A7, and including a source of barium that is substituted for calcium in said calcium aluminate clinker. Analogs, derivatives and hydrates of the improved calcium aluminate clinker are provided. A refractory composition and a sprayable refractory composition are disclosed comprising the improved calcium aluminate clinker. A method for improving the insulating character and/or penetration resistance of a liner in contact with molten aluminum in an aluminum manufacturing process or during aluminum transport is provided.Type: ApplicationFiled: January 25, 2012Publication date: July 19, 2012Inventor: Kenneth A. McGowan -
Publication number: 20120145043Abstract: “Green” cements, which can be carbon neutral or negative, can be prepared at lower temperatures (450° C.-500° C.) by utilizing feed compositions comprising (i) TiO2, TaOxNy, TiOxNy, RuO2, Pt, TaO, band gap materials, or a first mixture thereof; (ii) AI2O3; and (iii) Ca2SiO2, MgSiO2, MnSiO2, or a second mixture thereof; and spent wash with melanoidin as a binder.Type: ApplicationFiled: October 19, 2010Publication date: June 14, 2012Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLCInventor: Thevasahayam Arockiadoss
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Patent number: 8187374Abstract: The invention relates to a process for manufacturing clinker from a raw mix, implementing the following: preheating of the raw mix by combustion flue gases; precalcination of the raw mix; and calcination of the precalcined raw mix in a rotary kiln, in which process the precalcination and the calcination in the rotary kiln produce combustion flue gases that contain CO2, in which the combustion flue gases created by the precalcination undergo a CO2-removal treatment without said flue gases mixing with the combustion flue gases created by the calcination in the rotary kiln.Type: GrantFiled: October 22, 2007Date of Patent: May 29, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Erwin Penfornis, Guillaume De Smedt
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Patent number: 8177903Abstract: The present invention relates to a composition including at least a Portland clinker and a Belite-Calcium-Sulphoaluminate-Ferrite clinker (BCSAF).Type: GrantFiled: December 18, 2009Date of Patent: May 15, 2012Assignee: LafargeInventors: Günther Walenta, Cédric Comparet, Vincent Morin, Ellis Gartner
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Patent number: 8123854Abstract: A method of treating marine or river dredging sediments, especially harbour zone sediments, whose free water content is between 40% and 80% by weight, for the purpose of obtaining a solid material which is easy to handle, includes the following successive steps: mixing the sediments with a treatment composition including a sulphoaluminate binder and at least one other component selected from a sulphate source and a catalyst of the hydration reactions of the sulphoaluminate binder; a step of setting of the mixture, leading to a compact mixture having a free water content of less than 20% by weight; then fractionating the compact mixture. The sediment thus treated may be incorporated into concrete or mortar formulas, which then have leachable fractions of less than 1% by weight.Type: GrantFiled: September 29, 2009Date of Patent: February 28, 2012Assignee: Ciments FrancaisInventors: Pierre Cassat, Emmanuel Moudilou, Bruno le Rolland
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Publication number: 20120000395Abstract: In a method for producing photocatalytically active clinker, TiO2-containing materials are reacted to calcium titanates, particularly CaTiO3, with clinker raw meal or clinker raw mix.Type: ApplicationFiled: December 15, 2009Publication date: January 5, 2012Applicant: Holcim Technology Ltd.Inventors: Shreesh Anant Khadilkar, Manish Vasant Karandikar, Pradeep Gopal Lele
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Publication number: 20110308431Abstract: The invention relates to a novel sulfoaluminous clinker, to a method for preparing said clinker, and to the use of said clinker for preparing a hydraulic binder and subsequently grout, concrete, or mortar.Type: ApplicationFiled: January 28, 2010Publication date: December 22, 2011Applicant: VicatInventors: Michel Pasquier, Laury Barnes-Davin, Guy Beauvent
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Patent number: 7998267Abstract: A belite-calcium sulphoaluminate-ferrite (BCSAF) cement composition including: a BCSAF clinker which clinker has the following mineralogical composition, based on the total weight of the clinker: 5 to 25%, preferably 10 to 20%, of a calcium aluminoferrite phase having the general formula C2AxF(1?X), wherein X is from 0.2 to 0.8; 15 to 35% of a calcium sulphoaluminate phase; 40 to 75% of belite (C2S); from 0.01 to 10% in total of one or more minor phases selected from calcium sulphates, alkali metal sulphates, perovskite, calcium aluminates, gehlenite, free lime and periclase and/or a vitreous phase; and an alkanolamine.Type: GrantFiled: March 24, 2009Date of Patent: August 16, 2011Assignee: LAFARGEInventors: Ellis Gartner, Vincent Morin
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Publication number: 20110073013Abstract: The invention relates to a method for manufacturing a sulfoaluminous or belitic sulfoaluminous clinker from a raw mix formed from a mixture including minerals containing calcium, aluminum, silica, iron, and sulfur, preferably in sulfate form, and is characterized in that the method comprises the steps including: at least partially dehydrating and decarbonating the mixture through placement in a vertical kiln (1) comprising a substantially vertical chamber (2) wherein the mixture is heated, the chamber (2) of the vertical kiln (1) being supplied with hot gases the temperature of which is between 900 and 1150° C; extracting the dehydrated and decarbonated mixture from the vertical kiln (1) and conveying the same in a continuous kiln (4) comprising a furnace (5) and a transporting means (6) for transporting the mixture across the furnace (5); heating the mixture from the vertical kiln (1) by passing the mixture through the furnace (5) via the transporting means (6) such that a clinkerization of the mixture is obType: ApplicationFiled: March 12, 2009Publication date: March 31, 2011Applicant: VICATInventors: Yvan-Pierre Jacob, Jacques Croce, Guy Beauvent, Rene De La fouchardiere, Dominique Renie
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Publication number: 20110073014Abstract: A method and an apparatus for manufacturing of cement includes cement raw meal being preheated in a preheater, calcined in a calciner by contact with hot gases which are introduced into the calciner via a gas inlet and being diverted from the calciner via a gas outlet, and where calcined cement raw meal is diverted from the calciner, burned into cement clinker in a kiln and subsequently cooled in a clinker cooler. At least a portion of the calcined cement raw meal diverted from the calciner is heated further in a separate system to a temperature which exceeds the calcination temperature and is subsequently recirculated to the calciner. That at least a portion of the gases which are diverted via the gas outlet of the calciner is removed from the plant with a view to storage underground or other additional treatment.Type: ApplicationFiled: May 12, 2009Publication date: March 31, 2011Applicant: FLSMIDTH A/SInventor: Klaus Hjuler
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Publication number: 20110059316Abstract: A method of making cementitious particles using combustion synthesis is described. The method uses less energy and produces lower CO2 emissions than conventional processes. By controlling the process conditions, the morphology and the properties of the particles can be easily tuned for a variety of applications. A batch reactor and a continuous conveyor type reactor that can be used for the combustion synthesis with high viscosity raw materials are also described.Type: ApplicationFiled: May 27, 2010Publication date: March 10, 2011Applicant: SRIYA GREEN MATERIALS, INC.Inventors: Srinivas Kilambi, Krishnan Iyer, Karthik Gopalakrishnan, Ramesh Chembeti, Niraj Singh, Satish Reddy Dhumpala, Zijun Liu, Raman Kumar Gottumukkala, Subhadeep Mukherjee
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Publication number: 20110041736Abstract: A belite-calcium sulphoaluminate-ferrite (BCSAF) cement composition including: a BCSAF clinker which clinker has the following mineralogical composition, based on the total weight of the clinker: 5 to 25%, preferably 10 to 20%, of a calcium aluminoferrite phase having the general formula C2AxF(1?X), wherein X is from 0.2 to 0.8; 15 to 35% of a calcium sulphoaluminate phase; 40 to 75% of belite (C2S); from 0.01 to 10% in total of one or more minor phases selected from calcium sulphates, alkali metal sulphates, perovskite, calcium aluminates, gehlenite, free lime and periclase and/or a vitreous phase; and an alkanolamine.Type: ApplicationFiled: March 24, 2009Publication date: February 24, 2011Applicant: LAFARGEInventors: Ellis Gartner, Vincent Morin
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CALCIUM ALUMINATE CLINKER AS A REFRACTORY AGGREGATE WITH AND WITHOUT BARIUM ADDITION AND USE THEREOF
Publication number: 20110011213Abstract: The present invention provides for a refractory aggregate composition comprising an improved calcium aluminate clinker having the formula CnAx wherein C is calcium oxide and A is aluminum oxide, wherein n is an integer from about 1 to about 12, wherein x is an integer from about 1 to about 24, and wherein said clinker has from zero to less than about fifty weight percent C12A7. Analogs, derivatives and hydrates of the improved calcium aluminate clinker are provided. A refractory composition and a sprayable refractory composition are disclosed comprising the improved calcium aluminate clinker. A method for improving the insulating character and/or penetration resistance of a liner in contact with molten aluminum in an aluminum manufacturing process or during aluminum transport is provided.Type: ApplicationFiled: September 27, 2010Publication date: January 20, 2011Inventor: Kenneth A. McGowan -
Patent number: 7850776Abstract: A sulphoaluminate clinker includes as a phasic formulation, compared with the total weight of clinker: 5 to 25% of a calcium aluminoferrite phase with a formulation corresponding to the general formula C2AXF(1?X), with X comprised between 0.2 and 0.8; 15 to 35% of a calcium sulphoaluminate phase yee' limit (C4A3$); 40 to 75% belite (C2S); from 0.01 to 10% of one or several minor phases selected from the group consisting of calcium sulphates, alkali sulphates, perovskite, calcium aluminates, gehlenite, free lime and periclase, and/or a vitreous phase, and additives including at least sodium and boron present in the following quantities, by weight as compared to the total weight of the clinker: from 0.1 to 5% of sodium expressed as sodium oxide and from 0.2 to 3% of boron, expressed as boron oxide, the total content of said additives being less than or equal to 15%.Type: GrantFiled: June 29, 2009Date of Patent: December 14, 2010Assignee: LafargeInventors: Ellis Gartner, Guanshu Li
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Publication number: 20100282131Abstract: Method of improving the product properties of clinker in the firing of raw meal in a clinker or cement furnace in which at least part of the fuels used are low-heating-value or alternative fuels, waste products containing organic substances or low-heating-value or alternative fuels are subjected to thermal dissociation and reaction of the dissociation products using radiant energy. The product gas or synthesis gas formed in this way is fed to the burners of the main firing facility to increase the flame temperature.Type: ApplicationFiled: December 18, 2008Publication date: November 11, 2010Applicant: Holcim Technology Ltd.Inventors: Albert Obrist, Peter Von Zedtwitz, Christian Wieckert
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Publication number: 20100132590Abstract: A sulphoaluminate clinker includes as a phasic formulation, compared with the total weight of clinker: 5 to 25% of a calcium aluminoferrite phase with a formulation corresponding to the general formula C2AXF(1?X), with X comprised between 0.2 and 0.8; 15 to 35% of a calcium sulphoaluminate phase yee' limit (C4A3$); 40 to 75% belite (C2S); from 0.01 to 10% of one or several minor phases selected from the group consisting of calcium sulphates, alkali sulphates, perovskite, calcium aluminates, gehlenite, free lime and periclase, and/or a vitreous phase, and additives including at least sodium and boron present in the following quantities, by weight as compared to the total weight of the clinker: from 0.1 to 5% of sodium expressed as sodium oxide and from 0.2 to 3% of boron, expressed as boron oxide, the total content of said additives being less than or equal to 15%.Type: ApplicationFiled: June 29, 2009Publication date: June 3, 2010Applicant: LAFARGEInventors: Ellis Gartner, Guanshu Li
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Patent number: 7695559Abstract: A cement suspension includes the following, in relation to the cement material: water (22-35% by weight); acetic acid (1-10% by weight); plasticizer (up to 8% by weight); and dispersant agent (0-2% by weight), having an apparent viscosity of 0.5-2 Pa·s for the casting speed gradient. Pieces of cement that are prepared from the suspension and which can be used as electronic components are also disclosed.Type: GrantFiled: April 28, 2005Date of Patent: April 13, 2010Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Ecole Nationale Superieure de Ceramique Industrielle (ENSCI)Inventors: Thierry Chartier, Youssef El Hafiane, Agnes Smith, Jean-Pierre Bonnet
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Publication number: 20100000446Abstract: The invention relates to a process for manufacturing clinker from a raw mix, implementing the following: preheating of the raw mix by combustion flue gases; precalcination of the raw mix; and calcination of the precalcined raw mix in a rotary kiln, in which process the precalcination and the calcination in the rotary kiln produce combustion flue gases that contain CO2, in which the combustion flue gases created by the precalcination undergo a CO2-removal treatment without said flue gases mixing with the combustion flue gases created by the calcination in the rotary kiln.Type: ApplicationFiled: October 22, 2007Publication date: January 7, 2010Applicant: L'Air Liquide Soceiete Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Erwin Penfornis, Guillaume De Smedt
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Publication number: 20090071377Abstract: The present invention relates to a hydraulic binder for low-cement content concrete. The ground mineral portion of this cement comprises an under-calcinated alumina the BET specific surface of which ranges between 8 m2/g and 20 m2/g. Said binder enables to formulate a concrete the use properties of which remain stable and constant whatever the type of silica fume used, and capable of being used over a wide working temperature range for implementation. The invention also relates to a preparation for refractory concrete, a refractory concrete and a method for making a refractory concrete.Type: ApplicationFiled: March 5, 2007Publication date: March 19, 2009Applicant: KERNEOSInventors: Christoph Wohrmeyer, Fabien Simonin, Chris Parr, Eric Frier, Farida Ben Yahia
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Publication number: 20090064902Abstract: A grouting material which comprises an ultrafine particle material having a maximum particle size of 15 micrometer or less, containing 3 to 40% by mass of cement clinker, 60 to 97% by mass of and blast-furnace slag, 0.5 to 3 parts by mass of gypsum in terms of SO3 based on 100 parts by mass of the total amount of cement clinker and blast-furnace slag, and further comprises (i) 0.7 to 7 parts by mass of calcium-aluminate-based rapid-hardening admixture, (ii) 0.01 to 0.13 parts by mass of setting retarder, and (iii) 0.2 to 1.0 parts by mass of high-performance water-reducing agent, based on 100 parts by mass of the ultrafine particle material can maintain high injectability for long, and rapidly starts to set after injected to thereby exhibit a good short-term strength.Type: ApplicationFiled: February 8, 2007Publication date: March 12, 2009Applicant: NITTETSU CEMENT CO., LTD.Inventors: Takahiro Sato, Tomohiro Kanazawa, Tadashi Hayasaka, Ken Uoya, Akira Takami, Shin-ichiro Tada
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Patent number: 7445668Abstract: The invention relates to a hydraulic binder containing, in percentage by weight: from 1.1 to 9% of tricalcium aluminate from 1.5 to 13.5% of tetracalcium ferroaluminate from 0.5 to 1.5% of dodecacalcium heptaaluminate from 0.5 to 1.5% of tetracalcium trialuminate sulphate from 0 to 0.8% of dicalcium silicoaluminate from 5 to 70% of pozzolanic material(s) from 0 to 6% of calcium sulphate the remainder being composed of the non-aluminous constituents of at least one Portland-type clinker. It also relates to concretes or mortars prepared using a binder of this type.Type: GrantFiled: October 16, 2006Date of Patent: November 4, 2008Assignee: VICATInventor: Denis Sommain
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Patent number: 7351281Abstract: Powdered material, the binder phase of which mainly consists of a cement-based system, which powdered material has the capacity following saturation with a liquid reacting with the binder phase to hydrate to a chemically bonded ceramic material, preferably for dental purposes. According to the invention the powdered material has a composition and/or structure suitable for giving the ceramic material translucence in the hydrated state. The invention also relates to the ceramic material produced by hydration of the powdered material.Type: GrantFiled: August 21, 2002Date of Patent: April 1, 2008Assignee: Doxa AktiebolagInventors: Leif Hermansson, Lars Kraft, H{dot over (a)}kan Engqvist, Irmeli Hermansson, Nils-Otto Ahnfelt, Gunilla Gomez-Ortega
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Patent number: 7326290Abstract: The invention relates to a setting accelerator for a composition comprising Portland cement, in the form of a slurry comprising at least one calcium aluminate, 0.5 4%, preferably 0.6 2.3% of an aluminous cement setting inhibitor by weight in relation to the overall weight of the calcium alumnate, and an anti-sedimentation agent.Type: GrantFiled: December 24, 2003Date of Patent: February 5, 2008Assignee: KerneosInventors: Dominique Guinot, Eric Charpentier, Eric Frier
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Patent number: 7182137Abstract: Methods and compositions for wellbore treating fluids, especially cementitious compositions that include interground cement clinker and zeolite, with and without gypsum.Type: GrantFiled: September 13, 2004Date of Patent: February 27, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Glen C. Fyten, Karen Luke, Keith A. Rispler
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Patent number: 7150786Abstract: Clinkered materials containing high concentrations of {(C,K,N,M)4(A,F,Mn,P,T,S)3(cl,{overscore (S)})} (crystal X), and {(C2S)3(C{overscore (S)})3 Ca(f,cl) 2} or {(C2S)3(C{overscore (S)})3Ca(f,cl)2} (crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O3, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z.Type: GrantFiled: July 6, 2004Date of Patent: December 19, 2006Assignee: Ultimax CorporationInventor: Hassan Kunbargi
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Patent number: 6997984Abstract: A burned product containing 100 parts by weight of C2S, 10 to 100 parts by weight of C2AS, and 20 parts by weight or less of C3A; a cement admixture prepared by grinding the burned product; and a cement containing 100 parts by weight of ground portland cement clinker and 5 to 100 parts by weight of a ground product of the burned product.Type: GrantFiled: March 19, 2003Date of Patent: February 14, 2006Assignee: Taiheiyo Cement CorporationInventors: Daisuke Sawaki, Shuuichi Harasawa, Kenichi Honma, Makihiko Ichikawa
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Patent number: 6758896Abstract: Clinkered materials containing high concentrations of {(C,K,N,M)4 (A,F,Mn,P,T,S)3 Cl,{overscore (S)})}(crystal X), and {C2S)3(C{overscore (S)})3Ca(f,Cl)2} or C9S3{overscore (S)}3Ca(f,cl)2 crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O5, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z.Type: GrantFiled: July 18, 2001Date of Patent: July 6, 2004Inventor: Hassan Kunbargi
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Patent number: RE49415Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.Type: GrantFiled: March 6, 2019Date of Patent: February 14, 2023Assignee: ROMAN CEMENT, LLCInventors: John M. Guynn, Andrew S. Hansen