Cement Clinker Preparation Patents (Class 106/693)
  • Patent number: 6752865
    Abstract: The present invention describes a process for manufacture of high iron hydraulic cement clinker in production of cement and cementation binder for application in construction activity and in metallurgical industry for sintering of iron ore fines and making cold bonded briquettes and pellets. The process is cost effective and flexible for utilization of wide varieties of raw material consisting of lime and iron in production of high iron cements for different applications.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: June 22, 2004
    Assignee: Council of Scientific and Industrial Research
    Inventors: Bansidhar Nayak, Vibhuti Narayan Misra
  • Patent number: 6730159
    Abstract: A clinker-type hydraulic binder obtained by burning comprising a magnesia spinel mineralogical phase and at least a calcium aluminate mineralogical phase, with a lime content less than 15% of the binder by dry weight. The magnesia spinel represents between 68% and 81% by dry weight of the binder and preferably the calcium aluminates consist essentially of CA and CA2, with C═CaO and A═Al2O3. The invention also concerns the use of such a binder for making a refractory concrete and a method for making such a binder. The invention is useful for making steel ladles (1), preferably for their wear lining.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: May 4, 2004
    Assignee: Lafarge Aluminates
    Inventors: Jean-Pierre Falaschi, Hervé Fryda, Jean-Pierre Letourneux, Christopher Parr, Bruno Touzo, Michel Vialle
  • Patent number: 6695910
    Abstract: The lightly colored sulfoaluminous clinker contains: more than 55% by weight of calcium sulfoaluminate phase (C4A3S), more than 10% by weight of belite phase (C2S), less than 10% by weight of anhydrite (C{overscore (S)}), and contains practically no ferrite phase, nor a gehlenite phase (C2AS), nor free lime. It is prepared by a process of roasting carried out at temperatures comprised between about 1250° C. and 1350° C. It can be used for a wide range of applications by combining it with a source of calcium sulfate and/or Portland cement, to obtain binders having specific properties (color, setup time, mechanical strength, expansion or contraction . . . ).
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: February 24, 2004
    Assignee: Ciments Francais
    Inventors: Bruno Classen, Pierre Colombet
  • Patent number: 6689207
    Abstract: The concentration d3 is alumina AL2O3, —A—, and the concentration d4 in lime CaO, —C—, in the initial mixture are such that d3/d4 ranges between 1.15 and 1.40. Grinding produces a cement with a size distribution as represented in a Rosin Rammler diagram has a gradient ranging between 0.75 and 0.90.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: February 10, 2004
    Assignee: LafargeSaluminates
    Inventors: Bruno Espinosa, Thomas Bier
  • Patent number: 6602343
    Abstract: The present invention refers to a hydraulic binder made from Portland clinker containing calcium fluoroaluminate 11CaO.7Al2O3.CaF2, to which sodium aluminate, lime, and optionally, sodium bicarbonate are added. The added lime has not undergone the formation process of clinker. The cement mix that can be obtained with this binder has a very short hardening time, scarcely influenced by temperature variations during laying operations.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: August 5, 2003
    Assignee: Italcementi S.p.A.
    Inventors: Umberto Costa, Lorenzo Barcella
  • Patent number: 6537365
    Abstract: Cement clinker, characterized in that it comprises Al2O3 and Fe2O3 wherein the mass ratio of Al2O3/Fe2O3 is 0.05-0.62, and alkali components and C2S wherein the content Y (mass %) of alkali components and the content X (mass %) of C2S satisfy the formula: 0.0025X+0.1≦Y≦0.01X+0.8. The production of the clinker allows the incorporation of alkali components into cement with an advantageous effect of enhancement of the hydration of belite and also with suppression of the lowering of flowability, which leads to the reuse of wastes containing alkali components as a cement raw material.
    Type: Grant
    Filed: October 8, 2001
    Date of Patent: March 25, 2003
    Assignee: Sumitomo Osaka Cement Co., Ltd.
    Inventors: Tatsuo Ikabata, Tatsushi Akiyama, Kazuhiro Kano
  • Patent number: 6447597
    Abstract: An additive, a mixture incorporating the additive and a method of formulating a mortar incorporating the additive. The additive is based on calcium sulfoaluminate composed of C3AH6 and CAH10 where C=calcium oxide, A=aluminum oxide and H=water. The admixture includes gypsum and calcium hydroxide. The calcium aluminum hydrates are obtained by hydration of high alumina cement particles to eliminate any lack of hydration in the core of the particle. The method involves the preparation of such particles and the mix incorporates the particles to produce a homogeneously hydrated cement additive.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: September 10, 2002
    Assignee: National Research Council
    Inventors: Wellington L. Repette, Noel P. Mailvaganam
  • Patent number: 6406534
    Abstract: Clinkered materials containing high concentrations of {(C,K,N,M)4 (A,F,Mn,P,T,S)3 Cl,{overscore (S)})}(crystal X), and {C2S)3 (C{overscore (S)})3Ca(f,Cl)2} or C9S3{overscore (S)}3Ca(f,cl)2 (crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O5, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: June 18, 2002
    Inventor: Hassan Kunbargi
  • Patent number: 6238633
    Abstract: A non-metallic product (NMP) substantially free of metallic aluminum and aluminum nitride which is utilized for making calcium aluminate.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: May 29, 2001
    Assignee: Aluminum Waste Technology, Inc.
    Inventors: John W. Pickens, Edward L. Morris
  • Patent number: 6190449
    Abstract: The method comprises the steps of: preparing a belitic crude cement, neutralizing waste sulfurous acids by means of at least clay-calcareous fines which are thus transformed into artificial gypsum, and adding said artificial gypsum to the belitic crude cement.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: February 20, 2001
    Assignee: Carrieres du Boulonnais
    Inventor: Guy Beauvent
  • Patent number: 6149724
    Abstract: A method of manufacturing cements based on calcium sulfoaluminate by forming a clinker through calcining a selection of typical cement precursor raw materials to temperatures of more than 1200.degree. C. in an industrial kiln, preferably with a preheater (typically of the cascading cyclone type) and precalciner, selected in such a manner that the clinker thus produced has a high content of calcium sulfoaluminate, tricalcium silicate and dicalcium silicate with no other calcium aluminates and, preferably during or prior to the grinding thereof, adding to the clinker thus produced (with the above recited basic components), effective amounts of calcium oxide or hydroxide and calcium sulfate, in order to activate said clinker. Upon said grinding, a temperature of about 100 to 125.degree. C.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: November 21, 2000
    Assignee: Cemex, S.A. de C.V.
    Inventors: Ramon Poo Ulibarri, Waltter Lopez Gonzalez, Jose Torres
  • Patent number: 6113684
    Abstract: Clinkered materials containing high concentrations of {(C,K,N,M).sub.4 (A,F,Mn,P,T,S).sub.3 Cl,S)}(crystal X), and {C.sub.2 S).sub.3 (CS).sub.3 C(f,Cl)} or C.sub.10 S.sub.3 S.sub.3 (f,cl) (crystal Y), and/or {C.sub.5 S.sub.2 S) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al.sub.2 O.sub.3, Fe.sub.2 O.sub.3, TiO.sub.2, Mn.sub.2 O.sub.5, SiO.sub.2, SO.sub.3, Na.sub.2 O, K.sub.2 O, P.sub.2 O.sub.5 and F, respectively designated C, M, A, F, T, Mn, S, S, N, K, P and f, and heating said mixture to an elevated temperature between 900.degree. C. and 1,200.degree. C.; before determining average amount of crystals X, Y, and Z.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: September 5, 2000
    Inventor: Hassan Kunbargi
  • Patent number: 6005057
    Abstract: A cement clinker grinding aid which comprises a styrene-maleic anhydride copolymer (SMA) superplasticiser. The SMA is preferably a type with polyoxyalkylene-based side chains. Use of the grinding aid renders the grinding process more efficient and improves the performance of cementitous compositions in which the cement thus ground is used.
    Type: Grant
    Filed: January 30, 1997
    Date of Patent: December 21, 1999
    Assignee: MBT Holding AG
    Inventor: Bayhass El-Jazairi
  • Patent number: 5741357
    Abstract: A hydraulic cement composition is disclosed which utilizes as part of an expansive component novel coated particles of high alumina cement. The particles have a core of substantially unhydrated high alumina cement and an outer layer of hydration products of the core, which outer layer delays the reaction of the particles with other materials in the composition. By varying the nature and relative amounts of the coated particles the amount the cement composition may expand and the setting time of the cement may be varied. The coated particles may be formed by partial hydration, drying and grinding of a mixture of high alumina cement powder alone with water.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: April 21, 1998
    Inventor: Shamim A. Sheikh
  • Patent number: 5624489
    Abstract: Additives for high alumina cement compositions are proposed. The additives are effective to reduce or prevent the deleterious conversion of hexagonal calcium aluminate hydrates to cubic hydrogarnet in the high alumina cement compositions. The additives comprise 80-99 wt. % of a siliceous pozzolan and 1-20 wt. % of an inorganic sodium or potassium salt.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: April 29, 1997
    Assignee: National Research Council of Canada
    Inventors: Yan Fu, Jian Ding, James J. Beaudoin
  • Patent number: 5549745
    Abstract: An essentially non-slumping, high density, low moisture and low cement castable composition, consisting of a tempered, pumpable first component containing the castable solids and consisting essentially of a refractory aggregate, a calcium-aluminate cement, a flow aid, a deflocculating agent, and water, the water being present in the lowest amount sufficient to achieve a pumpable consistency of the tempered first component, and a flocculating agent as a second component to be added to said first component at time of installation in an amount sufficient to give the castable a dried bulk density of at least about 120 pcf.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: August 27, 1996
    Assignee: Indresco Inc.
    Inventors: Mark C. Langenohl, Gustav G. Hughes
  • Patent number: 5527387
    Abstract: A design optimization process used to determine the proportions of sand, cement, coarse aggregate, water, fly ash, water reducers, air entraining agents and fillers needed to produce a concrete mixture that has desired strength and slump properties and a minimal cost. The optimization process comprises a combination of models that accurately reflect the properties of a concrete mixture based on the properties of its individual components. The process is further capable of optimizing the durability of the cementitious mixture and of accurately calculating the expected yield of the mixture.
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: June 18, 1996
    Assignee: E. Khashoggi Industries
    Inventors: Per J. Andersen, Simon K. Hodson
  • Patent number: 5512523
    Abstract: A monolithic refractory powder mixture containing from 2 to 3 wt % of spheroidized refractory particles having a mean particle size of at most 30 .mu.m of at least one member selected from the group consisting of alumina cement, alumina, titania, bauxite, diaspore, mullite, aluminous shale, chamotte, pyrophyllite, sillimanite, andrewsite, silica rock, chromite, spinel, magnesia, zirconia, zircon, chromia, silicon nitride, aluminum nitride, silicon carbide, boron carbide, zirconium boride and titanium boride, and having a cone flow value of at least 180 mm when a refractory mixture having the powder mixture kneaded by an addition of 6 parts by weight of water per 100 parts by weight of the powder mixture, is cast into a cone-shaped mold with a dimension of 70 mm.o slashed.-100 mm.o slashed..times.60 mm and left to stand for 60 seconds without exerting vibration after removing the cone-shaped mold.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: April 30, 1996
    Assignee: Asahi Glass Company Ltd.
    Inventors: Yasushi Ono, Satoshi Sakamoto, Yutaka Murata, Tetsuo Kaji, Yasuhiko Endo
  • Patent number: 5073197
    Abstract: The advantages of high alumina cement (early strength, resistance to sulphate attack) are preserved and its disadvantage (weakens with age) is solved by mixing it 50:50 with silica fume, gasifier slag, fly ash or other pozzolanic or latently hydraulic material. This encourages formation of gehlenite octahydrate in preference to the harmful `conversion` (weakening) reaction.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: December 17, 1991
    Assignee: National Research Development Corporation
    Inventors: Amalendu J. Majumdar, Bahadur Singh
  • Patent number: 5071484
    Abstract: A cementitious composition capable of forming an early high strength cement when admixed with a liquid comprising a cementitious material of a specific chemical composition, surface area, and particle size distribution, the method of making such cementitious composition, and cements comprising said composition.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: December 10, 1991
    Assignee: Capitol Aggregates, Inc.
    Inventors: Wesley E. Bonifay, John G. Wheeler, Jose G. Garcia
  • Patent number: 4957556
    Abstract: Methods for forming very early setting, ultra high strength cements and the cements so produced are claimed. The methods comprise forming a mixture of raw materials containing SiO.sub.2, Al.sub.2 O.sub.3, CaO, Fe.sub.2 O.sub.3, and SO.sub.3, respectively designated S, A, C, F, and S such that the overall molar ratio of A/F exceeds approximately 0.64 and the overall molar ratio of S/A+F is between approximately 0.35 and 0.25. This mixture is heated to n elevated temperature between 1,000.degree. C. and 1,200.degree. C. for a sufficient period of time to produce a clinker containing high concentrations of C.sub.4 A.sub.3 S. The average amount of C.sub.4 A.sub.3 S is then determined and a final mixture is formed utilizing the high C.sub.4 A.sub.3 S clinker, C containing hydraulic or portland type cement and soluble CS anhydride to produce a final cement mixture having a C.sub.4 A.sub.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: September 18, 1990
    Inventor: Hassan Kunbargi