Aluminous Cement (e.g., High Alumina, Calcium Aluminate, Etc.) Patents (Class 106/692)
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Patent number: 11708305Abstract: This geopolymer molding production method comprises: a mixing step (S1) for mixing a first material containing aluminum and silicon with a hydrate of an alkali stimulant containing a hydrate of an alkaline hydroxide and/or a hydrate of an alkaline silicate; a compaction step (S2) for compacting the mixture obtained in the mixing step (S1) into a compacted mixture; and a curing step (S3) for curing the compacted mixture.Type: GrantFiled: January 30, 2018Date of Patent: July 25, 2023Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATIONInventors: Kanae Kawauchi, Hirofumi Okabe, Masaaki Kaneko, Chiaki Namiki, Tatsuaki Sato, Hideki Nakamura, Ryo Yamamoto, Fumi Takahashi
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Patent number: 11547981Abstract: A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising: a) Preparing a paste in a liquid diluent of hydroxide precursor particles and/or oxyhydroxide precursor particles of transition alumina particles, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 ?m, b) extruding the paste nozzle(s) to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface.Type: GrantFiled: May 28, 2019Date of Patent: January 10, 2023Inventors: Matthias Georg Schwab, Esther Groeneveld, Peter Berben, Harry Bouwman, Willem Dijkstra, Bart Michielsen, Jasper Lefevere
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Patent number: 11414346Abstract: A cement composition including a dry phase and a liquid phase. The dry phase includes an aluminosilicate source, including amorphous bagasse ash with a concentration between 40 wt. % and 100 wt. % of the weight of the dry phase. The liquid phase includes at least one of water and an alkaline activator solution. The alkaline activator solution includes at least one of an alkali metal stearate, an alkali metal silicate, and an alkali metal hydroxide.Type: GrantFiled: August 5, 2020Date of Patent: August 16, 2022Inventors: Amir Bahador Moradi Khou, Alireza Esparham
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Patent number: 11130711Abstract: The present invention relates to a dry refractory particulate composition comprising a zeolithic microstructure, to a green body and to a refractory lining formed therefrom, and to uses thereof.Type: GrantFiled: December 15, 2016Date of Patent: September 28, 2021Assignee: ImerTech SASInventors: Pierre Meunier, Nicolas Duvauchelle, Serge Martin-Calle, Jérome Soudier, Romain Techer
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Patent number: 10815157Abstract: Calcium carbonate which has an average particle size in the range of from 0.5 to 3 ?m is used in an inorganic mortar system for a chemical fastening of anchors and post-installed reinforcing bars in mineral substrates. The system includes a curable aluminous cement component A and an initiator component B for initiating the curing process. The component A includes at least one blocking agent selected from phosphoric acid, metaphosphoric acid, phosphorous acid and phosphonic acids, at least one plasticizer, and water. The component B includes an initiator, at least one retarder, at least one mineral filler, and water. Moreover, the calcium carbonate increases load values. Further, a method is used for a chemical fastening of anchors and post-installed reinforcing bars in mineral substrates, such as structures made of brickwork, concrete, pervious concrete or natural stone.Type: GrantFiled: April 3, 2018Date of Patent: October 27, 2020Assignee: Hilti AktiengesellschaftInventors: Anna Sharmak, Armin Pfeil, Friedlinde Götz-Neunhöffer, Daniel Jansen
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Patent number: 10815153Abstract: The present invention provides an apparatus and a method for producing cement through flue gas desulfurization, and specifically provides an apparatus and a method for simultaneously producing magnesium sulfate cement during a magnesium oxide based flue gas desulfurization process. The apparatus of the present invention includes a flue gas desulfurization equipment, a concentration equipment, a crystallization equipment, a centrifugation equipment, a drying equipment, a waste ash supplying equipment, a slag material supplying equipment, a mixing equipment, etc. By adopting the apparatus and method of the present invention, the problems in the present conventional cement production such as high energy cost, severe damage to the environment and so on can be solved, and the problems like high production cost of ordinary magnesium sulfate cement and high transportation cost of supplies thereby causing incapability in a large scale market spreading and application can also be solved.Type: GrantFiled: December 12, 2016Date of Patent: October 27, 2020Inventor: Shanghui Tong
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Patent number: 10414695Abstract: In a monolithic refractory, in terms of a proportion in 100 mass % of a refractory raw material having a grain size of 8 mm or smaller, an amount of CaXSr1?XAl2O4 (where, 0?X?0.5) is 0.5 mass % or more and 10 mass % or less, and a polyvalent metal salt of oxycarboxylic acid is 0.05 mass % or more and 1.0 mass % or less.Type: GrantFiled: September 29, 2016Date of Patent: September 17, 2019Assignee: NIPPON STEEL CORPORATIONInventors: Tsuyoshi Matsui, Koji Goda, Atsunori Koyama, Yoshitaka Sadatomi, Tsubasa Nakamichi
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Patent number: 10301217Abstract: Cementitious compositions and methods for producing the cementitious compositions are described herein. The methods can include mixing a compound of the general formula MaSibXcOd, MaSibXcOd(OH)e, MaSibXc(OH)e, or MaSibXc(OH)e.(H2O)f, wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater, with a rapid setting hydraulic cement to produce a cementitious mixture. The methods can further include hydrating the cementitious mixture and carbonating the cementitious mixture. Carbonating the cementitious mixture can occur simultaneously with hydrating the cementitious mixture or subsequent to hydrating the cementitious mixture. In some embodiments, the non-hydraulic cement can comprise wollastonite. The hydraulic cement can be in an amount of from 5 wt % to 80 wt % of the cementitious composition.Type: GrantFiled: December 23, 2014Date of Patent: May 28, 2019Assignee: BORAL IP HOLDINGS (AUSTRALIA) PTY LIMITEDInventors: Russell L. Hill, Amitabha Kumar
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Patent number: 10221098Abstract: Disclosed is an ultra-fast setting cement composition including at least amorphous calcium aluminate including by weight, as compared to amorphous calcium aluminate total weight, (a) from 35 to 55% of calcium oxide CaO (C), (b) from 19 to 55% of alumina Al2O3 (A), the C/A molar ratio being higher than or equal to 1.5, preferably higher than or equal to 1.7, characterized in that amorphous calcium aluminate is coated with a surface treatment including an organic compound having at least two hydrophilic functions and one hydrophobic chain. Also disclosed is a method to produce the cement composition, as well as to uses thereof.Type: GrantFiled: May 13, 2015Date of Patent: March 5, 2019Assignee: KERNEOSInventors: Jamel Mahiaoui, Jacques Estival, Jean-Noel Bousseau, Anais Martinet
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Patent number: 10196306Abstract: The present invention relates to an ultra-fast setting cement composition containing at least amorphous calcium aluminate including by weight, as compared to amorphous calcium aluminate total weight: (a) from 35 to 55% of calcium oxide CaO (C), (b) from 19 to 55% of alumina Al2O3 (A), the C/A molar ratio being higher than or equal to 1.5, (c) from 0 to 10% of silica SiO2, with the amorphous calcium aluminate including (d) from 5 to 16% of iron oxide Fe2O3. Also disclosed is a method to produce the cement composition, as well as to uses thereof.Type: GrantFiled: May 13, 2015Date of Patent: February 5, 2019Assignee: KERNEOSInventor: Bruno Touzo
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Patent number: 10112871Abstract: A building product is made from granular material and a binder that includes steel slag. A process for making the building product includes combining the granular material and the binder and then curing the combined granular material and binder with carbon dioxide. A building material includes a mixture of steel slag and a silica-rich material. The steel slag and silica-rich material is treated by heating. The silica-rich material may be waste glass and/or fly ash. A process for making the building material includes mixing the steel slag and silica-rich material and further heating the mixture.Type: GrantFiled: March 23, 2015Date of Patent: October 30, 2018Assignee: THE ROYAL INSTITUTION FOR THE ADVANCEMENT OF LEARNING/MCGILL UNIVERSITYInventors: Yixin Shao, Mehrdad Mahoutian, Zaid Ghouleh
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Patent number: 10023498Abstract: Compositions and methods for terminating water flow in a subterranean formation are described. The compositions include a calcium aluminate cement, a Portland cement, a non-aqueous carrier fluid, and a polyphosphate. The cement compositions, upon making contact with water, form a viscous gel that sets into a hardened mass with extraordinary compressive strengths in a short period of time.Type: GrantFiled: October 16, 2014Date of Patent: July 17, 2018Assignee: Halliburton Energy Services, IncInventors: Kyriacos Agapiou, Thomas J. Pisklak, Larry Eoff
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Patent number: 10011526Abstract: A hydraulic binder which includes a clinker with a specific shape, the clinker including as main phases, given as weight percentages relative to the total weight of the clinker: (i) 70 to 95% of a belite phase having a particle size such that the Dv50 ranges from 5 to 15 ?m; (ii) 5 to 30% of a calcium aluminoferrite phase; and (iii) less than 5% of minor phases; the clinker having an Al2O3/Fe2O3 weight ratio of less than 1.5; and the clinker including less than 5% of alite phase and less than 5% of calcium sulphoaluminate phase; and at least 0.5% dry weight of an activator made of calcium sulphate, as a weight percentage relative to the total weight of phases (i) to (iii).Type: GrantFiled: January 15, 2016Date of Patent: July 3, 2018Assignee: LAFARGEInventors: Pascal Bost, Alexander Pisch, Ellis Gartner, Vincent Morin, Isabelle Dubois-Brugger
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Patent number: 9994484Abstract: A method of making a rapid setting composition for cement boards is disclosed. Compositions including a hydraulic cement preferably portland cement, an alkali metal citrate such as tripotassium citrate, and a phosphate such as sodium trimetaphosphate, with optional gypsum, and no alkanolamine accelerant, and no fly ash based cement. An interaction between the alkali metal citrate and the phosphate increases the effectiveness of accelerating reactions of the portland cement without need for an alkanolamine accelerant, even in the presence of gypsum. This allows unexpected quick setting and increased early-age compressive strength without shrinkage in the cement board compositions.Type: GrantFiled: July 30, 2013Date of Patent: June 12, 2018Assignee: UNITED STATES GYPSYM COMPANYInventor: Marianela Perez-Pena
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Patent number: 9981252Abstract: A method for preparing a catalyst comprising (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.Type: GrantFiled: September 29, 2016Date of Patent: May 29, 2018Assignee: Johnson Matthey PLCInventors: Mikael Per Uno Carlsson, Jonathan Geoffrey Oliver, Mark Robert Feaviour, David James Birdsall, Samuel Arthur French
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Patent number: 9828298Abstract: Disclosed are cement compositions for applying to honeycomb bodies as a plugging cement composition, segment cement, or even as an after-applied artificial skin or coating. The cement compositions generally comprise an inorganic powder batch mixture; an organic binder; a liquid vehicle; and a gelled inorganic binder. Also disclosed are honeycomb bodies having the disclosed cement compositions applied thereto, and methods for making same.Type: GrantFiled: November 20, 2008Date of Patent: November 28, 2017Assignee: Corning IncorporatedInventors: Thomas James Deneka, Crystal Lynn Michels, Patrick David Tepesch, John Forrest Wight, Jr.
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Patent number: 9764365Abstract: A hydraulic binder based on a sulfoaluminate clinker including the mineralogical phases ye'elimite C4A3$, mayenite C12A7, free lime CaO, and optionally belite C2S, characterized in that, in the clinker, the mineralogical phases are 20% to 50% by weight of ye'elimite C4A3$ phase, 5% to 80% by weight of mayenite C12A7 phase, and 1% to 5% by weight of free lime CaO, the weight ratio between the mayenite C12A7 and ye'elimite C4A3$ phases being between 0.1 and 10. The binder can be used to treat polluted soils, in particular soils with a leachable fraction greater than 0.4% that contains predominantly anions and/or heavy metal cations by mixing the soil with the hydraulic binder, in soil/binder weight proportions of between 1 and 40 parts of binder for 100 parts of soil. It makes it possible to stabilize soils which are polluted or to stabilize soils before dumping.Type: GrantFiled: May 13, 2013Date of Patent: September 19, 2017Assignee: CIMENTS FRANCAISInventors: Emmanuel Moudilou, Cyril Guerandel, Bruno Le Rolland, Stephanie Delair
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Patent number: 9650294Abstract: This burned cement clinker is a burned cement clinker including at least one selected from the group consisting of fluorine, sulfur, chlorine and bromine, and at least one metallic element(s) selected from the group consisting of elements in groups 3 through 12 of the periodic table. Preferably, the amount of fluorine is within a range from 300 to 750 mg/kg, the amount of sulfur (expressed in terms of SO3) is within a range from 1.5 to 3.0% by mass, the amount of at least one chlorine equivalent(s) selected from the group consisting of chlorine and bromine is within a range from 150 to 350 mg/kg, and the amount of at least one metallic element selected from the group consisting of elements in groups 3 through 12 of the periodic table is within a range from 0.2 to 0.8% by mass.Type: GrantFiled: March 11, 2011Date of Patent: May 16, 2017Assignee: MITSUBISHI MATERIALS CORPORATIONInventors: Makio Yamashita, Yoichiro Nakanishi, Hisanobu Tanaka
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Patent number: 9604879Abstract: The present invention relates to the use of a belite calcium aluminate obtainable in a method comprising the following steps: a) providing a starting material that has a molar Ca/(Si+Al+Fe) ratio from 1.0 to 3.5 and a molar Al/Si ratio from 100 to 0.1, b) mixing the raw materials, c) hydrothermal treating of the starting material mixture produced in step b) in an autoclave at a temperature from 100 to 300° C. and a residence time from 0.1 to 24 h, wherein the water/solids ratio is 0.1 to 100, d) tempering the intermediate product obtained in step c) at 350 to 600° C., wherein the heating rate is 10-6000° C./min and the residence time is 0.01-600 min as an accelerator for Portland cement.Type: GrantFiled: May 7, 2014Date of Patent: March 28, 2017Assignee: HEIDELBERGCEMENT AGInventors: Dirk Schmitt, Mohsen Ben Haha, Anca Itul, Nicolas Spencer
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Patent number: 9577128Abstract: The present invention relates to a substrate for a thin film photovoltaic module, characterized in that it is a cementitious product with average surface roughness Ra not higher than 500 nm. The invention also relates to the cementitious product as such, the thin film photovoltaic module comprising it, and a method of molding both of them.Type: GrantFiled: April 19, 2011Date of Patent: February 21, 2017Assignee: ITALCEMENTI S.P A.Inventors: Roberta Alfani, Claudia Capone, Marco Plebani
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Patent number: 9434646Abstract: A new phosphorus-doped sulfo-belite-based clinker, a method for preparing this clinker, as well as the use of the clinker for preparing a hydraulic binder and, later on, grout, concrete or mortar.Type: GrantFiled: March 13, 2014Date of Patent: September 6, 2016Assignee: VICATInventors: Michel Pasquier, Laury Barnes-Davin, Pascal Meric, Guy Beauvent
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Patent number: 9302940Abstract: The present invention relates to binders based on latently hydraulic and/or pozzolanic materials that are activated by an addition of ternesite (C5S2$).Type: GrantFiled: July 16, 2012Date of Patent: April 5, 2016Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Linda Irbe
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Patent number: 9212091Abstract: The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.Type: GrantFiled: July 16, 2012Date of Patent: December 15, 2015Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Patent number: 9090507Abstract: An oxidation resistant low cement silicon carbide composite material, including a high alumina cement matrix portion in an amount of about 8 weight percent, a high alumina spinel portion in an amount between about 5 weight percent and about 20 weight percent, a silica fume portion in an amount of about 8 percent, a chrome aluminum stainless steel alloy needle additive portion, and a silicon carbide portion in an amount defining a remainder of the composition. The high alumina cement portion contains about 68 weight percent alumina and about 31 weight percent calcia, and the high alumina spinel portion contains about 78 weight percent alumina and about 22 weight percent magnesia.Type: GrantFiled: April 18, 2013Date of Patent: July 28, 2015Inventor: William L. Headrick, Jr.
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Patent number: 9073784Abstract: The present invention relates to a ternesite calcium sulfoaluminate clinker as well as a ternesite clinker containing 20 to 100% by weight of C5S2$ and less than 15% by weight of C4A3$, as well as the use of ternesite as an additive to calcium sulfoaluminate (ferrite) (belite) (CSA(F)(B)) clinker, calcium sulfoaluminate (ferrite) (belite) cement, and calcium sulfoaluminate (ferrite) (belite) binder containing 10 to 90% by weight of CSA(F)(B) and 90 to 10% by weight of ternesite.Type: GrantFiled: July 16, 2012Date of Patent: July 7, 2015Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Maciej Zajac
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Patent number: 9073785Abstract: The present invention relates to the production of ternesite clinkers containing 20 to 95% by weight C5S2$ and less than 15% by weight C4A3$, and to the use of ternesite as an additive to hydraulic and/or latent hydraulic and/or pozzolanic materials.Type: GrantFiled: July 16, 2012Date of Patent: July 7, 2015Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Patent number: 9067825Abstract: The present invention relates to the production of a ternesite-belite-calcium sulfoaluminate (ferrite) clinker. The invention also relates to the use of alternative raw materials for clinker production, for example raw materials based on industrial byproducts, including those of low quality, such as lump slag and ash having a low glass content and/or a high free lime content and/or a high content of crystalline high-temperature phases, as well as naturally occurring rocks and rock glasses of comparative chemical composition.Type: GrantFiled: July 16, 2012Date of Patent: June 30, 2015Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Patent number: 9067826Abstract: The present invention relates to the production of ternesite clinkers containing 20 to 100% by weight C5S2$ and less than 15% by weight C4A3$, and to the use of ternesite as an additive to Portland cement or Portland composite cement, and to a binder containing 20 to 95% by weight Portland cement (clinker) and 80 to 5% by weight ternesite (clinker).Type: GrantFiled: July 16, 2012Date of Patent: June 30, 2015Assignee: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Linda Irbe
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Patent number: 9023150Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.Type: GrantFiled: September 19, 2012Date of Patent: May 5, 2015Inventors: D. Chad Brenneis, Craig W. Roddy, James R. Benkley, Preston DePlacido, William J. Caveny, Rickey L. Morgan, Ronnie G. Morgan
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Patent number: 9022228Abstract: A domestic appliance filter for use in a laundry treatment device includes a basic filter material with a hydrophobic coating for filtering out matter from a process water duct or a process air duct. The basic filter material includes a material which is resistant to temperatures of 160° C. or more and the hydrophobic coating on the basic filter material effects a surface energy of less than 35 mN/m.Type: GrantFiled: December 1, 2009Date of Patent: May 5, 2015Assignee: BSH Bosch und Siemens Hausgeräte GmbHInventor: Klaus Grunert
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Patent number: 8999057Abstract: Provided herein are systems, methods, and compositions related to mixtures of calcium aluminate cements with compositions comprising carbonate. The compositions comprising carbonates may be formed by sequestering carbon dioxide.Type: GrantFiled: September 27, 2012Date of Patent: April 7, 2015Assignee: Calera CorporationInventors: Laurence Clodic, Samuel O. Morgan, Irvin Chen
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Patent number: 8974593Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.Type: GrantFiled: October 17, 2012Date of Patent: March 10, 2015Assignee: Roman Cement, LLCInventors: John M. Guynn, Andrew S. Hansen
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Publication number: 20150060070Abstract: Cement compositions and methods of making the same are provided. The composition comprises cement or lime, water and Lassenite, a pozzolanic strength retrogression inhibitor.Type: ApplicationFiled: August 30, 2013Publication date: March 5, 2015Applicant: Halliburton Energy Services, Inc.Inventors: Ramesh Muthusamy, Tushar Gosavi, Rahul Chandrakant Patil
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Patent number: 8968463Abstract: A material capable for trapping a flammable gas such as hydrogen comprising at least one metal oxide in a cementitious matrix is disclosed. According to some aspects, the preparation of such a material and its different uses are also disclosed.Type: GrantFiled: December 9, 2009Date of Patent: March 3, 2015Assignee: Commissariat a l'Energie Atomique et aux Energies AlternativesInventors: David Lambertin, Celine Cau Dit Coumes, Fabien Frizon, Christophe Joussot-Dubien
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Publication number: 20150040801Abstract: The disclosure relates generally to mold compositions and methods of molding and the articles so molded. More specifically, the disclosure relates to mold compositions and methods for casting titanium-containing articles, and the titanium-containing articles so molded.Type: ApplicationFiled: October 13, 2014Publication date: February 12, 2015Applicant: GENERAL ELECTRIC COMPANYInventor: Bernard Patrick BEWLAY
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Patent number: 8944166Abstract: Methods and compositions that protect cement compositions from corrosion, particularly from wet carbon dioxide, are provided. A soluble salt additive is provided to react with reaction products generated during the reactions that occur when cement is exposed to wet carbon dioxide. The soluble salt reacts to form an insoluble salt that forms a protective layer on the surface of the cement that protects it from further corrosion from exposure to wet carbon dioxide.Type: GrantFiled: January 17, 2014Date of Patent: February 3, 2015Assignee: Baker Hughes IncorporatedInventors: Mark Alan Vorderbruggen, Richard F. Stevens, Qi Qu
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Publication number: 20150000568Abstract: The carefully controlled addition of inorganic fillers to calcium sulfoaluminate rapid-setting cements can lead to significant improvement and optimization of its properties. Generally, prior art achieves cement optimization using costly and unstable organic additives. In the present invention, the addition of three inorganic additives such as coal ash, limestone or kiln dust led to appreciable improvement in the properties of calcium sulfoaluminate-containing cements. The addition of coal fly ash led to increased compressive strength and freeze-thaw durability while decreasing shrinkage and autoclave expansion. The addition of limestone was shown to control the compressive strength while not affecting the setting time, and the addition of cement kiln dust was shown to control the compressive strength while increasing the setting time. And finally, the presence of a super plasticizing agent was shown to negatively affect both compressive strength and shrinkage when used in combination with fly ash.Type: ApplicationFiled: September 16, 2014Publication date: January 1, 2015Inventors: Eric P. Bescher, Edward K. Rice, Grant M. Kao
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Publication number: 20140338569Abstract: The present invention relates to a white calcium aluminate cement containing at least 90% by weight of monocalcium aluminate, an A/C value in the range of 1.75 to 2.0, a fineness according to Blaine in the range of 3500 to 6000 cm2/g, a slope n in the range of 1.1 to 1.5 and a location parameter x? of 8-20 ?m in an RRSB particle size grid according to DIN 66145 as well as its use in formulations of the construction chemical industry and the refractory industry.Type: ApplicationFiled: May 15, 2014Publication date: November 20, 2014Applicant: CALUCEM GMBHInventors: Douglas OSTRANDER, Markus SCHMID
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Publication number: 20140343194Abstract: Stabilized aqueous suspensions include aluminous cement and/or calcium sulfoaluminous cement and binding compositions including the aqueous suspension in combination with organic binders, which are stable at room temperature and at high temperature as well as methods for preparing the same are described.Type: ApplicationFiled: December 19, 2012Publication date: November 20, 2014Applicant: KERNEOSInventors: Pascal Taquet, Pierre-Antoine Andreani, Veronique Watt, Emilie Reveyrand
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Patent number: 8876968Abstract: The present invention relates to a current composition for cementing oil or gas wells. The composition comprises calcium aluminate cement in which the proportion of HC203 is at least 50% by weight, dispersant, microsilica, mineral particles, water and optionally a retarder.Type: GrantFiled: September 26, 2011Date of Patent: November 4, 2014Assignee: Elkem ASInventors: Phillippe Revil, Hong Peng
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Publication number: 20140311385Abstract: An oxidation resistant low cement silicon carbide composite material, including a high alumina cement matrix portion in an amount of about 8 weight percent, a high alumina spinel portion in an amount between about 5 weight percent and about 20 weight percent, a silica fume portion in an amount of about 8 percent, a chrome aluminum stainless steel alloy needle additive portion, and a silicon carbide portion in an amount defining a remainder of the composition. The high alumina cement portion contains about 68 weight percent alumina and about 31 weight percent calcia, and the high alumina spinel portion contains about 78 weight percent alumina and about 22 weight percent magnesia.Type: ApplicationFiled: April 18, 2013Publication date: October 23, 2014Inventor: William L. Headrick, Jr.
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Patent number: 8864901Abstract: Inorganic polymer compositions and methods for their preparation are described herein. The compositions include the reaction product of a reactive powder, an activator, and optionally a retardant. The reactive powder includes fly ash, calcium sulfoaluminate cement, and less than 10% by weight portland cement. In some examples, the composition is substantially free from alkanolamines. In some examples, the ratio of water to reactive powder is from 0.06:1 to less than 0.2:1. Also described herein are building materials including the compositions.Type: GrantFiled: November 30, 2011Date of Patent: October 21, 2014Assignee: Boral IP Holdings (Australia) Pty LimitedInventors: Redmond Richard Lloyd, Louise Margaret Keyte, Russell L. Hill, Zhaozhou Zhang, Mark Hollett, Li Ai
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Patent number: 8835338Abstract: This binder for monolithic refractories includes a solid solution obtained by dissolving Ca components in ?-SrAl2O4 or ?-SrAl2O4, wherein when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 40 nm to 75 nm, and when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 35 nm to 70 nm.Type: GrantFiled: April 28, 2011Date of Patent: September 16, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Yoshitoshi Saito, Atsunori Koyama
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Patent number: 8828136Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.Type: GrantFiled: March 25, 2014Date of Patent: September 9, 2014Assignee: PKL CorporationInventors: Edward K. Rice, Grant M. Kao, Eric P. Bescher
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Publication number: 20140238274Abstract: The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.Type: ApplicationFiled: July 16, 2012Publication date: August 28, 2014Applicant: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Publication number: 20140208983Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising placing into a wellbore a composition comprising a calcium aluminate cement and a polyvalent cation-containing compound, and allowing the composition to set. A method of increasing the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound. A method of adjusting the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound and at least one other set modifier.Type: ApplicationFiled: March 31, 2014Publication date: July 31, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Ying XU, B. Raghava REDDY, Rickey Lynn MORGAN, Lance BROTHERS
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Publication number: 20140202360Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.Type: ApplicationFiled: March 25, 2014Publication date: July 24, 2014Applicant: PKL CorporationInventors: Edward K. Rice, Grant M. Kao, Eric P. Bescher
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Publication number: 20140123879Abstract: Methods and compositions are disclosed that comprise interground perlite and hydraulic cement. An embodiment provides a composition comprising interground perlite and hydraulic cement. Another embodiment provides a composition comprising: interground unexpanded perlite and Portland cement, the interground having a mean particle size of about 0.5 microns to about 10 microns; and water.Type: ApplicationFiled: December 30, 2013Publication date: May 8, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Jeffery Dwane Karcher, D. Chad Brenneis, Craig W. Roddy, James R. Benkley
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Patent number: 8715411Abstract: A method for producing a clinker for cement, comprising grinding a raw flour comprising, especially, Al2O3, Fe2O3 and SO3 in contents such that the formula for calculating SO3 content of=0.261×Al2O3?0.638×Fe2O3+k, where 2.5<k<3.5, then by sintering flour in an overn wherein the temperature is between 1250° C. and 1350° C. and oxygen content is between 2.5% and 10% by volume.Type: GrantFiled: June 17, 2011Date of Patent: May 6, 2014Assignee: Cemex Research Group AGInventors: Juan Carlos Martinez, Norma Leticia Garza Gonzalez, Karla Serrano Gonzalez, Homero Ramirez Tovias
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Patent number: 8708033Abstract: The disclosure relates generally to mold compositions comprising calcium aluminate and calcium titanate. The disclosure also relates to methods of molding and the articles so molded using the mold compositions. More specifically, the disclosure relates to calcium aluminate/calcium titanate mold compositions and methods for casting titanium-containing articles, and the titanium-containing articles so molded.Type: GrantFiled: August 29, 2012Date of Patent: April 29, 2014Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Joan McKiever, Brian Michael Ellis, Nicholas Vincent McLasky