Aluminous Cement (e.g., High Alumina, Calcium Aluminate, Etc.) Patents (Class 106/692)
  • Patent number: 11708305
    Abstract: This geopolymer molding production method comprises: a mixing step (S1) for mixing a first material containing aluminum and silicon with a hydrate of an alkali stimulant containing a hydrate of an alkaline hydroxide and/or a hydrate of an alkaline silicate; a compaction step (S2) for compacting the mixture obtained in the mixing step (S1) into a compacted mixture; and a curing step (S3) for curing the compacted mixture.
    Type: Grant
    Filed: January 30, 2018
    Date of Patent: July 25, 2023
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Kanae Kawauchi, Hirofumi Okabe, Masaaki Kaneko, Chiaki Namiki, Tatsuaki Sato, Hideki Nakamura, Ryo Yamamoto, Fumi Takahashi
  • Patent number: 11547981
    Abstract: A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising: a) Preparing a paste in a liquid diluent of hydroxide precursor particles and/or oxyhydroxide precursor particles of transition alumina particles, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 ?m, b) extruding the paste nozzle(s) to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: January 10, 2023
    Inventors: Matthias Georg Schwab, Esther Groeneveld, Peter Berben, Harry Bouwman, Willem Dijkstra, Bart Michielsen, Jasper Lefevere
  • Patent number: 11414346
    Abstract: A cement composition including a dry phase and a liquid phase. The dry phase includes an aluminosilicate source, including amorphous bagasse ash with a concentration between 40 wt. % and 100 wt. % of the weight of the dry phase. The liquid phase includes at least one of water and an alkaline activator solution. The alkaline activator solution includes at least one of an alkali metal stearate, an alkali metal silicate, and an alkali metal hydroxide.
    Type: Grant
    Filed: August 5, 2020
    Date of Patent: August 16, 2022
    Inventors: Amir Bahador Moradi Khou, Alireza Esparham
  • Patent number: 11130711
    Abstract: The present invention relates to a dry refractory particulate composition comprising a zeolithic microstructure, to a green body and to a refractory lining formed therefrom, and to uses thereof.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: September 28, 2021
    Assignee: ImerTech SAS
    Inventors: Pierre Meunier, Nicolas Duvauchelle, Serge Martin-Calle, Jérome Soudier, Romain Techer
  • Patent number: 10815157
    Abstract: Calcium carbonate which has an average particle size in the range of from 0.5 to 3 ?m is used in an inorganic mortar system for a chemical fastening of anchors and post-installed reinforcing bars in mineral substrates. The system includes a curable aluminous cement component A and an initiator component B for initiating the curing process. The component A includes at least one blocking agent selected from phosphoric acid, metaphosphoric acid, phosphorous acid and phosphonic acids, at least one plasticizer, and water. The component B includes an initiator, at least one retarder, at least one mineral filler, and water. Moreover, the calcium carbonate increases load values. Further, a method is used for a chemical fastening of anchors and post-installed reinforcing bars in mineral substrates, such as structures made of brickwork, concrete, pervious concrete or natural stone.
    Type: Grant
    Filed: April 3, 2018
    Date of Patent: October 27, 2020
    Assignee: Hilti Aktiengesellschaft
    Inventors: Anna Sharmak, Armin Pfeil, Friedlinde Götz-Neunhöffer, Daniel Jansen
  • Patent number: 10815153
    Abstract: The present invention provides an apparatus and a method for producing cement through flue gas desulfurization, and specifically provides an apparatus and a method for simultaneously producing magnesium sulfate cement during a magnesium oxide based flue gas desulfurization process. The apparatus of the present invention includes a flue gas desulfurization equipment, a concentration equipment, a crystallization equipment, a centrifugation equipment, a drying equipment, a waste ash supplying equipment, a slag material supplying equipment, a mixing equipment, etc. By adopting the apparatus and method of the present invention, the problems in the present conventional cement production such as high energy cost, severe damage to the environment and so on can be solved, and the problems like high production cost of ordinary magnesium sulfate cement and high transportation cost of supplies thereby causing incapability in a large scale market spreading and application can also be solved.
    Type: Grant
    Filed: December 12, 2016
    Date of Patent: October 27, 2020
    Inventor: Shanghui Tong
  • Patent number: 10414695
    Abstract: In a monolithic refractory, in terms of a proportion in 100 mass % of a refractory raw material having a grain size of 8 mm or smaller, an amount of CaXSr1?XAl2O4 (where, 0?X?0.5) is 0.5 mass % or more and 10 mass % or less, and a polyvalent metal salt of oxycarboxylic acid is 0.05 mass % or more and 1.0 mass % or less.
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: September 17, 2019
    Assignee: NIPPON STEEL CORPORATION
    Inventors: Tsuyoshi Matsui, Koji Goda, Atsunori Koyama, Yoshitaka Sadatomi, Tsubasa Nakamichi
  • Patent number: 10301217
    Abstract: Cementitious compositions and methods for producing the cementitious compositions are described herein. The methods can include mixing a compound of the general formula MaSibXcOd, MaSibXcOd(OH)e, MaSibXc(OH)e, or MaSibXc(OH)e.(H2O)f, wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater, with a rapid setting hydraulic cement to produce a cementitious mixture. The methods can further include hydrating the cementitious mixture and carbonating the cementitious mixture. Carbonating the cementitious mixture can occur simultaneously with hydrating the cementitious mixture or subsequent to hydrating the cementitious mixture. In some embodiments, the non-hydraulic cement can comprise wollastonite. The hydraulic cement can be in an amount of from 5 wt % to 80 wt % of the cementitious composition.
    Type: Grant
    Filed: December 23, 2014
    Date of Patent: May 28, 2019
    Assignee: BORAL IP HOLDINGS (AUSTRALIA) PTY LIMITED
    Inventors: Russell L. Hill, Amitabha Kumar
  • Patent number: 10221098
    Abstract: Disclosed is an ultra-fast setting cement composition including at least amorphous calcium aluminate including by weight, as compared to amorphous calcium aluminate total weight, (a) from 35 to 55% of calcium oxide CaO (C), (b) from 19 to 55% of alumina Al2O3 (A), the C/A molar ratio being higher than or equal to 1.5, preferably higher than or equal to 1.7, characterized in that amorphous calcium aluminate is coated with a surface treatment including an organic compound having at least two hydrophilic functions and one hydrophobic chain. Also disclosed is a method to produce the cement composition, as well as to uses thereof.
    Type: Grant
    Filed: May 13, 2015
    Date of Patent: March 5, 2019
    Assignee: KERNEOS
    Inventors: Jamel Mahiaoui, Jacques Estival, Jean-Noel Bousseau, Anais Martinet
  • Patent number: 10196306
    Abstract: The present invention relates to an ultra-fast setting cement composition containing at least amorphous calcium aluminate including by weight, as compared to amorphous calcium aluminate total weight: (a) from 35 to 55% of calcium oxide CaO (C), (b) from 19 to 55% of alumina Al2O3 (A), the C/A molar ratio being higher than or equal to 1.5, (c) from 0 to 10% of silica SiO2, with the amorphous calcium aluminate including (d) from 5 to 16% of iron oxide Fe2O3. Also disclosed is a method to produce the cement composition, as well as to uses thereof.
    Type: Grant
    Filed: May 13, 2015
    Date of Patent: February 5, 2019
    Assignee: KERNEOS
    Inventor: Bruno Touzo
  • Patent number: 10112871
    Abstract: A building product is made from granular material and a binder that includes steel slag. A process for making the building product includes combining the granular material and the binder and then curing the combined granular material and binder with carbon dioxide. A building material includes a mixture of steel slag and a silica-rich material. The steel slag and silica-rich material is treated by heating. The silica-rich material may be waste glass and/or fly ash. A process for making the building material includes mixing the steel slag and silica-rich material and further heating the mixture.
    Type: Grant
    Filed: March 23, 2015
    Date of Patent: October 30, 2018
    Assignee: THE ROYAL INSTITUTION FOR THE ADVANCEMENT OF LEARNING/MCGILL UNIVERSITY
    Inventors: Yixin Shao, Mehrdad Mahoutian, Zaid Ghouleh
  • Patent number: 10023498
    Abstract: Compositions and methods for terminating water flow in a subterranean formation are described. The compositions include a calcium aluminate cement, a Portland cement, a non-aqueous carrier fluid, and a polyphosphate. The cement compositions, upon making contact with water, form a viscous gel that sets into a hardened mass with extraordinary compressive strengths in a short period of time.
    Type: Grant
    Filed: October 16, 2014
    Date of Patent: July 17, 2018
    Assignee: Halliburton Energy Services, Inc
    Inventors: Kyriacos Agapiou, Thomas J. Pisklak, Larry Eoff
  • Patent number: 10011526
    Abstract: A hydraulic binder which includes a clinker with a specific shape, the clinker including as main phases, given as weight percentages relative to the total weight of the clinker: (i) 70 to 95% of a belite phase having a particle size such that the Dv50 ranges from 5 to 15 ?m; (ii) 5 to 30% of a calcium aluminoferrite phase; and (iii) less than 5% of minor phases; the clinker having an Al2O3/Fe2O3 weight ratio of less than 1.5; and the clinker including less than 5% of alite phase and less than 5% of calcium sulphoaluminate phase; and at least 0.5% dry weight of an activator made of calcium sulphate, as a weight percentage relative to the total weight of phases (i) to (iii).
    Type: Grant
    Filed: January 15, 2016
    Date of Patent: July 3, 2018
    Assignee: LAFARGE
    Inventors: Pascal Bost, Alexander Pisch, Ellis Gartner, Vincent Morin, Isabelle Dubois-Brugger
  • Patent number: 9994484
    Abstract: A method of making a rapid setting composition for cement boards is disclosed. Compositions including a hydraulic cement preferably portland cement, an alkali metal citrate such as tripotassium citrate, and a phosphate such as sodium trimetaphosphate, with optional gypsum, and no alkanolamine accelerant, and no fly ash based cement. An interaction between the alkali metal citrate and the phosphate increases the effectiveness of accelerating reactions of the portland cement without need for an alkanolamine accelerant, even in the presence of gypsum. This allows unexpected quick setting and increased early-age compressive strength without shrinkage in the cement board compositions.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: June 12, 2018
    Assignee: UNITED STATES GYPSYM COMPANY
    Inventor: Marianela Perez-Pena
  • Patent number: 9981252
    Abstract: A method for preparing a catalyst comprising (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: May 29, 2018
    Assignee: Johnson Matthey PLC
    Inventors: Mikael Per Uno Carlsson, Jonathan Geoffrey Oliver, Mark Robert Feaviour, David James Birdsall, Samuel Arthur French
  • Patent number: 9828298
    Abstract: Disclosed are cement compositions for applying to honeycomb bodies as a plugging cement composition, segment cement, or even as an after-applied artificial skin or coating. The cement compositions generally comprise an inorganic powder batch mixture; an organic binder; a liquid vehicle; and a gelled inorganic binder. Also disclosed are honeycomb bodies having the disclosed cement compositions applied thereto, and methods for making same.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: November 28, 2017
    Assignee: Corning Incorporated
    Inventors: Thomas James Deneka, Crystal Lynn Michels, Patrick David Tepesch, John Forrest Wight, Jr.
  • Patent number: 9764365
    Abstract: A hydraulic binder based on a sulfoaluminate clinker including the mineralogical phases ye'elimite C4A3$, mayenite C12A7, free lime CaO, and optionally belite C2S, characterized in that, in the clinker, the mineralogical phases are 20% to 50% by weight of ye'elimite C4A3$ phase, 5% to 80% by weight of mayenite C12A7 phase, and 1% to 5% by weight of free lime CaO, the weight ratio between the mayenite C12A7 and ye'elimite C4A3$ phases being between 0.1 and 10. The binder can be used to treat polluted soils, in particular soils with a leachable fraction greater than 0.4% that contains predominantly anions and/or heavy metal cations by mixing the soil with the hydraulic binder, in soil/binder weight proportions of between 1 and 40 parts of binder for 100 parts of soil. It makes it possible to stabilize soils which are polluted or to stabilize soils before dumping.
    Type: Grant
    Filed: May 13, 2013
    Date of Patent: September 19, 2017
    Assignee: CIMENTS FRANCAIS
    Inventors: Emmanuel Moudilou, Cyril Guerandel, Bruno Le Rolland, Stephanie Delair
  • Patent number: 9650294
    Abstract: This burned cement clinker is a burned cement clinker including at least one selected from the group consisting of fluorine, sulfur, chlorine and bromine, and at least one metallic element(s) selected from the group consisting of elements in groups 3 through 12 of the periodic table. Preferably, the amount of fluorine is within a range from 300 to 750 mg/kg, the amount of sulfur (expressed in terms of SO3) is within a range from 1.5 to 3.0% by mass, the amount of at least one chlorine equivalent(s) selected from the group consisting of chlorine and bromine is within a range from 150 to 350 mg/kg, and the amount of at least one metallic element selected from the group consisting of elements in groups 3 through 12 of the periodic table is within a range from 0.2 to 0.8% by mass.
    Type: Grant
    Filed: March 11, 2011
    Date of Patent: May 16, 2017
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Makio Yamashita, Yoichiro Nakanishi, Hisanobu Tanaka
  • Patent number: 9604879
    Abstract: The present invention relates to the use of a belite calcium aluminate obtainable in a method comprising the following steps: a) providing a starting material that has a molar Ca/(Si+Al+Fe) ratio from 1.0 to 3.5 and a molar Al/Si ratio from 100 to 0.1, b) mixing the raw materials, c) hydrothermal treating of the starting material mixture produced in step b) in an autoclave at a temperature from 100 to 300° C. and a residence time from 0.1 to 24 h, wherein the water/solids ratio is 0.1 to 100, d) tempering the intermediate product obtained in step c) at 350 to 600° C., wherein the heating rate is 10-6000° C./min and the residence time is 0.01-600 min as an accelerator for Portland cement.
    Type: Grant
    Filed: May 7, 2014
    Date of Patent: March 28, 2017
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Dirk Schmitt, Mohsen Ben Haha, Anca Itul, Nicolas Spencer
  • Patent number: 9577128
    Abstract: The present invention relates to a substrate for a thin film photovoltaic module, characterized in that it is a cementitious product with average surface roughness Ra not higher than 500 nm. The invention also relates to the cementitious product as such, the thin film photovoltaic module comprising it, and a method of molding both of them.
    Type: Grant
    Filed: April 19, 2011
    Date of Patent: February 21, 2017
    Assignee: ITALCEMENTI S.P A.
    Inventors: Roberta Alfani, Claudia Capone, Marco Plebani
  • Patent number: 9434646
    Abstract: A new phosphorus-doped sulfo-belite-based clinker, a method for preparing this clinker, as well as the use of the clinker for preparing a hydraulic binder and, later on, grout, concrete or mortar.
    Type: Grant
    Filed: March 13, 2014
    Date of Patent: September 6, 2016
    Assignee: VICAT
    Inventors: Michel Pasquier, Laury Barnes-Davin, Pascal Meric, Guy Beauvent
  • Patent number: 9302940
    Abstract: The present invention relates to binders based on latently hydraulic and/or pozzolanic materials that are activated by an addition of ternesite (C5S2$).
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: April 5, 2016
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Linda Irbe
  • Patent number: 9212091
    Abstract: The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: December 15, 2015
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
  • Patent number: 9090507
    Abstract: An oxidation resistant low cement silicon carbide composite material, including a high alumina cement matrix portion in an amount of about 8 weight percent, a high alumina spinel portion in an amount between about 5 weight percent and about 20 weight percent, a silica fume portion in an amount of about 8 percent, a chrome aluminum stainless steel alloy needle additive portion, and a silicon carbide portion in an amount defining a remainder of the composition. The high alumina cement portion contains about 68 weight percent alumina and about 31 weight percent calcia, and the high alumina spinel portion contains about 78 weight percent alumina and about 22 weight percent magnesia.
    Type: Grant
    Filed: April 18, 2013
    Date of Patent: July 28, 2015
    Inventor: William L. Headrick, Jr.
  • Patent number: 9073784
    Abstract: The present invention relates to a ternesite calcium sulfoaluminate clinker as well as a ternesite clinker containing 20 to 100% by weight of C5S2$ and less than 15% by weight of C4A3$, as well as the use of ternesite as an additive to calcium sulfoaluminate (ferrite) (belite) (CSA(F)(B)) clinker, calcium sulfoaluminate (ferrite) (belite) cement, and calcium sulfoaluminate (ferrite) (belite) binder containing 10 to 90% by weight of CSA(F)(B) and 90 to 10% by weight of ternesite.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: July 7, 2015
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Maciej Zajac
  • Patent number: 9073785
    Abstract: The present invention relates to the production of ternesite clinkers containing 20 to 95% by weight C5S2$ and less than 15% by weight C4A3$, and to the use of ternesite as an additive to hydraulic and/or latent hydraulic and/or pozzolanic materials.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: July 7, 2015
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
  • Patent number: 9067825
    Abstract: The present invention relates to the production of a ternesite-belite-calcium sulfoaluminate (ferrite) clinker. The invention also relates to the use of alternative raw materials for clinker production, for example raw materials based on industrial byproducts, including those of low quality, such as lump slag and ash having a low glass content and/or a high free lime content and/or a high content of crystalline high-temperature phases, as well as naturally occurring rocks and rock glasses of comparative chemical composition.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: June 30, 2015
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
  • Patent number: 9067826
    Abstract: The present invention relates to the production of ternesite clinkers containing 20 to 100% by weight C5S2$ and less than 15% by weight C4A3$, and to the use of ternesite as an additive to Portland cement or Portland composite cement, and to a binder containing 20 to 95% by weight Portland cement (clinker) and 80 to 5% by weight ternesite (clinker).
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: June 30, 2015
    Assignee: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Linda Irbe
  • Patent number: 9023150
    Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: May 5, 2015
    Inventors: D. Chad Brenneis, Craig W. Roddy, James R. Benkley, Preston DePlacido, William J. Caveny, Rickey L. Morgan, Ronnie G. Morgan
  • Patent number: 9022228
    Abstract: A domestic appliance filter for use in a laundry treatment device includes a basic filter material with a hydrophobic coating for filtering out matter from a process water duct or a process air duct. The basic filter material includes a material which is resistant to temperatures of 160° C. or more and the hydrophobic coating on the basic filter material effects a surface energy of less than 35 mN/m.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: May 5, 2015
    Assignee: BSH Bosch und Siemens Hausgeräte GmbH
    Inventor: Klaus Grunert
  • Patent number: 8999057
    Abstract: Provided herein are systems, methods, and compositions related to mixtures of calcium aluminate cements with compositions comprising carbonate. The compositions comprising carbonates may be formed by sequestering carbon dioxide.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: April 7, 2015
    Assignee: Calera Corporation
    Inventors: Laurence Clodic, Samuel O. Morgan, Irvin Chen
  • Patent number: 8974593
    Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: March 10, 2015
    Assignee: Roman Cement, LLC
    Inventors: John M. Guynn, Andrew S. Hansen
  • Publication number: 20150060070
    Abstract: Cement compositions and methods of making the same are provided. The composition comprises cement or lime, water and Lassenite, a pozzolanic strength retrogression inhibitor.
    Type: Application
    Filed: August 30, 2013
    Publication date: March 5, 2015
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Ramesh Muthusamy, Tushar Gosavi, Rahul Chandrakant Patil
  • Patent number: 8968463
    Abstract: A material capable for trapping a flammable gas such as hydrogen comprising at least one metal oxide in a cementitious matrix is disclosed. According to some aspects, the preparation of such a material and its different uses are also disclosed.
    Type: Grant
    Filed: December 9, 2009
    Date of Patent: March 3, 2015
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: David Lambertin, Celine Cau Dit Coumes, Fabien Frizon, Christophe Joussot-Dubien
  • Publication number: 20150040801
    Abstract: The disclosure relates generally to mold compositions and methods of molding and the articles so molded. More specifically, the disclosure relates to mold compositions and methods for casting titanium-containing articles, and the titanium-containing articles so molded.
    Type: Application
    Filed: October 13, 2014
    Publication date: February 12, 2015
    Applicant: GENERAL ELECTRIC COMPANY
    Inventor: Bernard Patrick BEWLAY
  • Patent number: 8944166
    Abstract: Methods and compositions that protect cement compositions from corrosion, particularly from wet carbon dioxide, are provided. A soluble salt additive is provided to react with reaction products generated during the reactions that occur when cement is exposed to wet carbon dioxide. The soluble salt reacts to form an insoluble salt that forms a protective layer on the surface of the cement that protects it from further corrosion from exposure to wet carbon dioxide.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: February 3, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: Mark Alan Vorderbruggen, Richard F. Stevens, Qi Qu
  • Publication number: 20150000568
    Abstract: The carefully controlled addition of inorganic fillers to calcium sulfoaluminate rapid-setting cements can lead to significant improvement and optimization of its properties. Generally, prior art achieves cement optimization using costly and unstable organic additives. In the present invention, the addition of three inorganic additives such as coal ash, limestone or kiln dust led to appreciable improvement in the properties of calcium sulfoaluminate-containing cements. The addition of coal fly ash led to increased compressive strength and freeze-thaw durability while decreasing shrinkage and autoclave expansion. The addition of limestone was shown to control the compressive strength while not affecting the setting time, and the addition of cement kiln dust was shown to control the compressive strength while increasing the setting time. And finally, the presence of a super plasticizing agent was shown to negatively affect both compressive strength and shrinkage when used in combination with fly ash.
    Type: Application
    Filed: September 16, 2014
    Publication date: January 1, 2015
    Inventors: Eric P. Bescher, Edward K. Rice, Grant M. Kao
  • Publication number: 20140338569
    Abstract: The present invention relates to a white calcium aluminate cement containing at least 90% by weight of monocalcium aluminate, an A/C value in the range of 1.75 to 2.0, a fineness according to Blaine in the range of 3500 to 6000 cm2/g, a slope n in the range of 1.1 to 1.5 and a location parameter x? of 8-20 ?m in an RRSB particle size grid according to DIN 66145 as well as its use in formulations of the construction chemical industry and the refractory industry.
    Type: Application
    Filed: May 15, 2014
    Publication date: November 20, 2014
    Applicant: CALUCEM GMBH
    Inventors: Douglas OSTRANDER, Markus SCHMID
  • Publication number: 20140343194
    Abstract: Stabilized aqueous suspensions include aluminous cement and/or calcium sulfoaluminous cement and binding compositions including the aqueous suspension in combination with organic binders, which are stable at room temperature and at high temperature as well as methods for preparing the same are described.
    Type: Application
    Filed: December 19, 2012
    Publication date: November 20, 2014
    Applicant: KERNEOS
    Inventors: Pascal Taquet, Pierre-Antoine Andreani, Veronique Watt, Emilie Reveyrand
  • Patent number: 8876968
    Abstract: The present invention relates to a current composition for cementing oil or gas wells. The composition comprises calcium aluminate cement in which the proportion of HC203 is at least 50% by weight, dispersant, microsilica, mineral particles, water and optionally a retarder.
    Type: Grant
    Filed: September 26, 2011
    Date of Patent: November 4, 2014
    Assignee: Elkem AS
    Inventors: Phillippe Revil, Hong Peng
  • Publication number: 20140311385
    Abstract: An oxidation resistant low cement silicon carbide composite material, including a high alumina cement matrix portion in an amount of about 8 weight percent, a high alumina spinel portion in an amount between about 5 weight percent and about 20 weight percent, a silica fume portion in an amount of about 8 percent, a chrome aluminum stainless steel alloy needle additive portion, and a silicon carbide portion in an amount defining a remainder of the composition. The high alumina cement portion contains about 68 weight percent alumina and about 31 weight percent calcia, and the high alumina spinel portion contains about 78 weight percent alumina and about 22 weight percent magnesia.
    Type: Application
    Filed: April 18, 2013
    Publication date: October 23, 2014
    Inventor: William L. Headrick, Jr.
  • Patent number: 8864901
    Abstract: Inorganic polymer compositions and methods for their preparation are described herein. The compositions include the reaction product of a reactive powder, an activator, and optionally a retardant. The reactive powder includes fly ash, calcium sulfoaluminate cement, and less than 10% by weight portland cement. In some examples, the composition is substantially free from alkanolamines. In some examples, the ratio of water to reactive powder is from 0.06:1 to less than 0.2:1. Also described herein are building materials including the compositions.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: October 21, 2014
    Assignee: Boral IP Holdings (Australia) Pty Limited
    Inventors: Redmond Richard Lloyd, Louise Margaret Keyte, Russell L. Hill, Zhaozhou Zhang, Mark Hollett, Li Ai
  • Patent number: 8835338
    Abstract: This binder for monolithic refractories includes a solid solution obtained by dissolving Ca components in ?-SrAl2O4 or ?-SrAl2O4, wherein when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 40 nm to 75 nm, and when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 35 nm to 70 nm.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: September 16, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Yoshitoshi Saito, Atsunori Koyama
  • Patent number: 8828136
    Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.
    Type: Grant
    Filed: March 25, 2014
    Date of Patent: September 9, 2014
    Assignee: PKL Corporation
    Inventors: Edward K. Rice, Grant M. Kao, Eric P. Bescher
  • Publication number: 20140238274
    Abstract: The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.
    Type: Application
    Filed: July 16, 2012
    Publication date: August 28, 2014
    Applicant: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
  • Publication number: 20140208983
    Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising placing into a wellbore a composition comprising a calcium aluminate cement and a polyvalent cation-containing compound, and allowing the composition to set. A method of increasing the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound. A method of adjusting the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound and at least one other set modifier.
    Type: Application
    Filed: March 31, 2014
    Publication date: July 31, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Ying XU, B. Raghava REDDY, Rickey Lynn MORGAN, Lance BROTHERS
  • Publication number: 20140202360
    Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.
    Type: Application
    Filed: March 25, 2014
    Publication date: July 24, 2014
    Applicant: PKL Corporation
    Inventors: Edward K. Rice, Grant M. Kao, Eric P. Bescher
  • Publication number: 20140123879
    Abstract: Methods and compositions are disclosed that comprise interground perlite and hydraulic cement. An embodiment provides a composition comprising interground perlite and hydraulic cement. Another embodiment provides a composition comprising: interground unexpanded perlite and Portland cement, the interground having a mean particle size of about 0.5 microns to about 10 microns; and water.
    Type: Application
    Filed: December 30, 2013
    Publication date: May 8, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Jeffery Dwane Karcher, D. Chad Brenneis, Craig W. Roddy, James R. Benkley
  • Patent number: 8715411
    Abstract: A method for producing a clinker for cement, comprising grinding a raw flour comprising, especially, Al2O3, Fe2O3 and SO3 in contents such that the formula for calculating SO3 content of=0.261×Al2O3?0.638×Fe2O3+k, where 2.5<k<3.5, then by sintering flour in an overn wherein the temperature is between 1250° C. and 1350° C. and oxygen content is between 2.5% and 10% by volume.
    Type: Grant
    Filed: June 17, 2011
    Date of Patent: May 6, 2014
    Assignee: Cemex Research Group AG
    Inventors: Juan Carlos Martinez, Norma Leticia Garza Gonzalez, Karla Serrano Gonzalez, Homero Ramirez Tovias
  • Patent number: 8708033
    Abstract: The disclosure relates generally to mold compositions comprising calcium aluminate and calcium titanate. The disclosure also relates to methods of molding and the articles so molded using the mold compositions. More specifically, the disclosure relates to calcium aluminate/calcium titanate mold compositions and methods for casting titanium-containing articles, and the titanium-containing articles so molded.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: April 29, 2014
    Assignee: General Electric Company
    Inventors: Bernard Patrick Bewlay, Joan McKiever, Brian Michael Ellis, Nicholas Vincent McLasky