Organic Material Containing Patents (Class 106/696)
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Patent number: 11814321Abstract: Cementitious compositions comprising a hydraulic cementitious material, a compound selected from the group consisting of a polyhydroxy aromatic compound, a polycarboxylic acid-containing compound or a salt thereof, ascorbic acid or a salt thereof, or a combination thereof, and a particulate material or a water soluble silicate-containing material that interacts with the compound are described herein. The polyhydroxy aromatic compound can be a water soluble compound having from two to thirty hydroxyl groups. The particulate material can exhibit a particle size distribution, wherein at least about 90% by weight of the particles have a diameter of less than 2 mm. Suitable particulate materials include nanoparticles and microparticles. The cementitious compositions can be used to form building materials. The cementitious compositions are especially suited for inhibiting corrosion of reinforcing steel bars embedded in concrete mixtures. Methods of making and using the cementitious composition are also disclosed.Type: GrantFiled: July 30, 2021Date of Patent: November 14, 2023Assignee: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ALABAMAInventor: Jialai Wang
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Patent number: 11718561Abstract: According to aspects of the present disclosure, a composition is disclosed, which can be utilized to construct a retention structure, e.g., for use with hardscape such as pavers, tile, stone, and other building materials. The composition is a mixture of a cement component (e.g., Portland cement), a sand component, a gravel component, a silica fume component, and fiber component, the above-components mixed in varying ratios. When the cement component, sand component, gravel component, silica fume component, and fiber component are mixed in an effective amount, combined with a water component, and applied against a hardscape, the composition, once cured, defines a retention structure that abuts to, but is not adhered to the hardscape.Type: GrantFiled: October 31, 2018Date of Patent: August 8, 2023Inventors: Christopher K. Yancey, Scott P. Doyle
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Patent number: 11326087Abstract: A sealing composition for sealing an annulus of a wellbore includes from 20 weight percent to 97 weight percent epoxy resin based on the total weight of the composition. The epoxy resin comprising at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, or a compound having formula (OC2H3)—CH2—O—R1—O—CH2—(C2H3O), where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms. The sealing composition also includes from 1 weight percent to 20 weight percent curing agent based on the total weight of the composition.Type: GrantFiled: June 19, 2020Date of Patent: May 10, 2022Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Ali Alsafran, Vikrant Wagle, Hussain Albahrani, Zainab Alsaihati
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Patent number: 11325863Abstract: Provided herein are fiber reinforced cementitious materials and mixtures with increased crack resistance. The cementitious materials and mixtures include a cement and at least one carbon fiber. Also provide is a fiber reinforced cementitious mortar that includes the fiber reinforced cementitious material to which at least one of water, an aggregate material or a chemical admixture is added.Type: GrantFiled: July 30, 2018Date of Patent: May 10, 2022Assignee: The Texas A&M University SystemInventors: Joshua Hogancamp, Zachary Grasley
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Patent number: 11130900Abstract: This document relates to methods for providing long-term zonal isolation in oil wells using cement compositions that contain triazine-based polymeric additives. The cement compositions containing the polymeric additives exhibit increased tensile strength, elastic strength, or both, without suffering a decrease in compressive strength, as compared to the same cement without the polymeric additive.Type: GrantFiled: October 13, 2020Date of Patent: September 28, 2021Assignee: Saudi Arabian Oil CompanyInventors: Hasmukh A. Patel, Carl Thaemlitz
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Patent number: 10995253Abstract: Lithium-containing cement admixtures including a calcium aluminate phosphate cement; a lithium-ion-containing compound; and an aqueous base fluid and methods of introducing the lithium-containing cement admixtures into a subterranean formation. The lithium-containing cement admixtures may further comprise an aluminosilicate or an additive including a set retarder, a set accelerator, a suspension aid, a density reducing agent, a fluid loss control agent, a defoamer, and any combination thereof.Type: GrantFiled: September 16, 2014Date of Patent: May 4, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Kyriacos Agapiou, Samuel J. Lewis
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Patent number: 10836679Abstract: The invention relates to building products that contain graphene and/or graphene oxide in the bulk component thereof. The addition of graphene and/or graphene oxide improves the mechanical properties of said building products, particularly in terms of strength.Type: GrantFiled: December 18, 2015Date of Patent: November 17, 2020Assignee: Knauf Gips KGInventors: Marcin Wieteska, Grzegorz Kiedrzyn
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Patent number: 10822284Abstract: A long-term stabilized aqueous initiator composition, which includes components for curing of a two-component mortar system composition. The long-term stabilized aqueous initiator composition includes an activator component that has an alkali and/or alkaline earth metal salt, an accelerator component that has a water-soluble alkali and/or alkaline earth metal salt, a retarder selected from citric acid, tartaric acid, lactic acid, salicylic, gluconic acid, and a mixture of these components, a mineral filler selected from a limestone filler, corundum, dolomite, alkaline-resistant glass, crushed stone, gravel, pebble, and a mixture of these components, a thickening agent, and water.Type: GrantFiled: October 19, 2016Date of Patent: November 3, 2020Assignee: Hilti AktiengesellschaftInventors: Armin Pfeil, Pascal Beroll
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Patent number: 10766818Abstract: This invention relates to a method for producing a supplementary cementitious material comprising the steps: providing a starting material containing dolomite and aluminium silicate, converting the starting material to the supplementary cementitious material by burning under reducing conditions in the temperature range of >700 to 1100° C. or by burning in the temperature range of 625 to 950° C. in the presence of a mineraliser, and cooling the supplementary cementitious material. The invention further relates to a binder comprising cement and to the ground supplementary cementitious material.Type: GrantFiled: May 23, 2017Date of Patent: September 8, 2020Assignee: HConnect 2 GmbHInventors: Frank Bullerjahn, Maciej Zajac, Dominik Nied
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Patent number: 10640421Abstract: Composition for building materials comprises of fly ash from flue gas desulfurization. The fly ash (? CaSO4 anhydrite), obtained from circulating fluidized bed flue gas desulfurization, is mixed with binder reactants at a ratio of 9:1. It's mainly used for non-structural cement mortar, bricks for paving walkways, brick wall decors, fire-resistant walls for interior partitions, plasterboards and so on. The binder reactants compose of 70% CaSO4.½H2O, 10% Na2SO4, 10% CaO, 5% NaOH, 0˜5% cement and 0˜5% starch. When the binder reactants are mixed with fly ash and water (30% to 40% of the above total weight), the hydration process of CaSO4 anhydrite is accelerated.Type: GrantFiled: August 3, 2017Date of Patent: May 5, 2020Inventors: Chin-Tien Lien, Chien-Fan Lien
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Patent number: 10058841Abstract: A dolomite-based adsorbent for heavy metal, halogen and metalloid is half-fired dolomite, and a content of a residual CaMg(CO3)2 phase in the half-fired dolomite, which is analyzed using a Rietveld method by means of powder X-ray diffraction, is 0.4?x?35.4 (wt %), and preferably, the dolomite-based absorbent for heavy metal, halogen and metalloid further comprises ferrous sulfate.Type: GrantFiled: March 30, 2016Date of Patent: August 28, 2018Assignee: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Yuuki Itaya, Kenji Kuninishi, Shintaro Hayashi
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Patent number: 10059626Abstract: Crumb Rubber augmented masonry blocks including cement, aggregate, water, and crumb rubber. Crumb rubber is extracted from scrape tires after being processed and then mixed in specified percentages with aggregate, cement and water. In the present disclosure sand, which is used in the formation of conventional blocks, is replaced with crumb rubber to produce a sand-free masonry block containing crumb rubber. The developed crumb rubber masonry blocks satisfied the ASTM non-load bearing requirements in addition to satisfying the water absorption test.Type: GrantFiled: April 24, 2017Date of Patent: August 28, 2018Assignee: King Fahd University of Petroleum and MineralsInventors: Nasser M. Al-Aqeeli, Homoud M. Assehdi, Mohammad Maslehuddin
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Patent number: 9919974Abstract: A composite binder comprises: one or more Class F fly ash materials, one or more gelation enhancers, and one or more hardening enhancers, wherein each of the one or more Class F fly ash materials comprises 15 wt. % or less calcium oxide, and wherein the composite binder is a Portland cement-free binder for concrete. Also provided are Geopolymer Composite Cellular Concretes (GCCCs) including the composite binder and methods of making these GCCCs.Type: GrantFiled: February 28, 2014Date of Patent: March 20, 2018Assignee: The Catholic University of AmericaInventors: Weiliang Gong, Werner Lutze, Ian L. Pegg
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Patent number: 9725600Abstract: The present invention relates to an aqueous calcium carbonate containing composition, to methods for producing such aqueous calcium carbonate containing compositions and to the use of the aqueous calcium carbonate containing composition in paper, paper coating, plastics and/or paint applications and as filler in paper.Type: GrantFiled: March 21, 2013Date of Patent: August 8, 2017Assignee: Omya International AGInventors: Samuel Rentsch, Daniel E. Gerard, Matthias Buri, Patrick A. C. Gane, Vesa Kukkamo
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Patent number: 9670095Abstract: Crumb Rubber augmented masonry blocks including cement, aggregate, water, and crumb rubber. Crumb rubber is extracted from scrape tires after being processed and then mixed in specified percentages with aggregate, cement and water. In the present disclosure sand, which is used in the formation of conventional blocks, is replaced with crumb rubber to produce a sand-free masonry block containing crumb rubber. The developed crumb rubber masonry blocks satisfied the ASTM non-load bearing requirements in addition to satisfying the water absorption test.Type: GrantFiled: March 9, 2016Date of Patent: June 6, 2017Assignee: King Fahd University of Petroleum and MineralsInventors: Nasser M. Al-Aqeeli, Homoud M. Assehdi, Mohammad Maslehuddin
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Patent number: 9650782Abstract: Disclosed are an exterior insulation mortar for cold weather which may prevent freezing and improve strength at temperatures below 0° C., and an exterior insulation system using the same.Type: GrantFiled: December 3, 2013Date of Patent: May 16, 2017Assignee: LG HAUSYS, LTD.Inventors: Seung Wook Ji, Eung Kee Lee, Chul June Choi, Myeong Hee Kim, Ji Mun Kim, Byung Joo Jeon
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Patent number: 9624130Abstract: The present invention provides a composition and method for modifying a hydratable cementitious composition such as concrete or mortar using at least three different, distinct carboxylate polymers, even when clay is present in the concrete or mortar that would otherwise diminish dosage efficiency of polycarboxylate polymer used as dispersant. The three polycarboxylate polymers, designated as Polymer I, Polymer II, and Polymer II, are derived from monomer Components A, B, and C wherein Component A is an unsaturated carboxylic acid, Component B is a polyoxyalkylene, and Component C is an unsaturated carboxylate ester. The component molar ratio ranges for A:B:C are different as between Polymers I and II; while a distinct component molar ratio A:B+C is identified for Polymer III. When treated with these three different polycarboxylate polymers, the hydratable cementitious composition is surprisingly enhanced in terms of initial workability and slump retention, especially if clay is present.Type: GrantFiled: February 5, 2016Date of Patent: April 18, 2017Assignee: GCP Applied Technologies Inc.Inventors: Lawrence L. Kuo, Keith St Jean, Yohannes K. Lemma, Nathan A. Tregger, Stephen P. Klaus, Danila F. Ferraz, Klaus-Alexander Rieder, Pierre Estephane
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Patent number: 9567262Abstract: A process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound, said reaction being effected in the presence of a water-soluble dispersant having at least one polyalkyleneglycol structural unit with a functional group at one end of the polyalkyleneglycol, being able to interact as an anchor group with the surface of cement particles, the hardening accelerator composition and its use.Type: GrantFiled: February 25, 2011Date of Patent: February 14, 2017Assignee: Construction Research & Technology GmbHInventors: Luc Nicoleau, Gerhard Albrecht
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Patent number: 9422194Abstract: According to an embodiment, a composition that can be used in a cementing. The composition includes at least: (i) a hydraulic cement; and (ii) a copolymer comprising at least the monomeric units (a) through (d) of the following formula: wherein the monomeric units (a) through (d) can be any sequence and any proportion in the copolymer. With water, the composition of the hydraulic cement and such a copolymer becomes a cement composition. According to the method, the cement composition is introduced into a well and allowed to set in the well.Type: GrantFiled: March 4, 2016Date of Patent: August 23, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Tushar Sureshgiri Gosavi, Ramesh Muthusamy, Rahul Chandrakant Patil, Sandip Prabhakar Patil
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Patent number: 9382160Abstract: This invention relates to the development of Crumb Rubber augmented masonry blocks. Crumb rubber is extracted from scrape tires after being processed and then mixed in specified percentages with concrete, cement and water. In the present disclosure sand, which is used in the formation of conventional blocks, is replaced with crumb rubber to produce a sand-free masonry block containing crumb rubber. The developed crumb rubber masonry blocks satisfied the ASTM non-load bearing requirements in addition to satisfying the water absorption test.Type: GrantFiled: April 16, 2014Date of Patent: July 5, 2016Assignee: King Fahd University of Petroleum and MineralsInventors: Nasser M. Al-Aqeeli, Homoud M. Assehdi
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Patent number: 9359254Abstract: A wellbore cement composition includes substantially unhydrated cement powder and additive powder for cement. The additive powder is formulated from ingredients including a liquid additive for cement and solid carrier particles. The liquid additive is absorbed by the solid carrier particles. A wellbore cementing method includes using a dry cement composition, adding water to the dry cement composition, forming a cement slurry, placing the slurry in a wellbore, and setting the placed slurry. The dry cement composition contains substantially unhydrated cement powder and retarder powder for cement. The retarder powder contains a retarder absorbed by solid carrier particles.Type: GrantFiled: November 12, 2013Date of Patent: June 7, 2016Assignee: BAKER HUGHES INCORPORATEDInventors: Mark A. Vorderbruggen, Guido G. Narvaez, Diana Cardona, Dong Shen
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Patent number: 9353003Abstract: The presently disclosed and claimed inventive concept(s) relates generally to a hydraulic composition with a prolonged open time. More particularly, the composition comprises at least one cement retarder and at least one accelerator. The presently disclosed and claimed inventive concept(s) further relates to a dry mortar composition comprising the hydraulic composition having prolonged open time without deterioration of the other cement tile adhesive properties such as workability, setting time, strength development and sag resistance.Type: GrantFiled: March 13, 2014Date of Patent: May 31, 2016Assignee: Hercules IncorporatedInventors: Wilfried Adolf Hohn, Stefan Hucko, Alexander Adolphe Kindler, Vera Louise Nilles, Martin Wunderlich
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Patent number: 9309153Abstract: According to an embodiment, a composition that can be used in cementing. The composition includes at least: (i) a hydraulic cement; (ii) a copolymer comprising at least the monomeric units (a) through (d) of the following formula: wherein the monomeric units (a) through (d) can be any sequence and any proportion in the copolymer. With water, the composition of the hydraulic cement and such a copolymer becomes a cement composition. According to the method, the cement composition is introduced into a well and allowed to set in the well.Type: GrantFiled: April 27, 2012Date of Patent: April 12, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Tushar Sureshgiri Gosavi, Ramesh Muthusamy, Rahul Chandrakant Patil, Sandip Prabhakar Patil
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Patent number: 9284477Abstract: Well cementing compositions comprise water, an inorganic cement and flexible particles having an average density higher than 1.5 g/cm3. The flexible particles may be elastomers. The flexible particles and cement particles may be present in a trimodal particle size distribution. The compositions may be placed in subterranean wells in the context of primary or remedial cementing.Type: GrantFiled: December 16, 2013Date of Patent: March 15, 2016Assignee: Schlumberger Technology CorporationInventors: Fatma Daou, Anthony Loiseau, Bernardo Engelke
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Patent number: 9221716Abstract: A hardening accelerator for mineral binders including an amino alcohol A and/or of a salt of said amino alcohol A, for example, cementitious binders, is provided. The amino alcohol A has a structure according to formula (I) where a) R1 and R2, independently of one another, each represent an alkanol group including 3-4 carbon atoms, b) R3 is an organic group including 1-8 carbon atoms, and c) R3 is different from R1 and/or R2.Type: GrantFiled: November 26, 2013Date of Patent: December 29, 2015Assignee: SIKA TECHNOLOGY AGInventors: Beat Marazzani, Christian Bürge, Christophe Kurz, Gilbert Mäder
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Patent number: 9181131Abstract: The present invention relates to a redispersible powder composition for use in the preparation of dry mortar formulations, especially of cementitious bound tile adhesives (CBTA). The invention further relates to a dry mortar formulation comprising said redispersible powder composition. Furthermore, the invention is directed to a method of increasing the open time of a dry mortar formulation without deteriorating the mechanical strength of the cured dry mortar formulation.Type: GrantFiled: May 12, 2011Date of Patent: November 10, 2015Assignee: Dow Global Technologies LLCInventors: Lars Fengler, Rene Kiesewetter
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Patent number: 9145335Abstract: A process for preparing a setting and hardening accelerator for mineral binders includes the following steps: a) reacting a calcium compound CV with a silicon compound SV, and b) adding an acidic compound having a molecular weight of not more than 200 g/mol, more particularly 40-100 g/mol.Type: GrantFiled: December 5, 2012Date of Patent: September 29, 2015Assignee: SIKA TECHNOLOGY AGInventors: Franz Wombacher, Beat Marazzani, Christian Bürge, Christophe Kurz, Gilbert Mäder
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Publication number: 20150118484Abstract: The present invention provides an environment-friendly natural-like artificial stone containing fly ash. A formulation and a method of producing the artificial stone is compared with the existing artificial stone. The artificial stone produced by the present invention has characteristics of higher long-term strength and density, excellent weather resistance and corrosion resistance, and also of thermal insulation and sound insulation, in some degree. It has very strong durability and color stability under a variety of adverse weather conditions, without efflorescence and coming off, and with hardly any color change.Type: ApplicationFiled: December 26, 2011Publication date: April 30, 2015Applicant: SHANGHAI APE STONE CO., LTDInventors: Guomai Chen, Malhua Chen, Yi Xia, Jiye You, Rendao Zhou, Liang Zeng
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Patent number: 9011596Abstract: The present invention provides a method for producing a cured article of a hydraulic composition, prepared by mixing glycerol, cement and water, the hydraulic composition containing a sulfate ion, the method including step 1 of preparing the hydraulic composition such that a molar ratio of the sulfate ion to the glycerol, sulfate ion/glycerol, is 5.0 to 20 and the content of the sulfate ion is 3.0 to 15 parts by weight to 100 parts by weight of cement; and step 2 of aging and curing the hydraulic composition obtained in the step 1.Type: GrantFiled: March 26, 2012Date of Patent: April 21, 2015Assignee: Kao CorporationInventors: Yusuke Yoshinami, Toshimasa Hamai, Hiroyuki Kawakami, Yohei Yoshikawa
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Publication number: 20150090451Abstract: A well cementing composition comprises water, an inorganic cement, a gas generating agent and a gas stabilizer. The gas generating agent may contain materials that release hydrogen gas, carbon dioxide gas or nitrogen gas or combinations thereof. The gas stabilizer comprises an aqueous mixture comprising polyglycols, oxyalkylates and methanol, or coco trimethyl ammonium chloride, or a mixture comprising ammonium fatty alcohol ether sulfate and ethylene glycol monobutyl ether, or combinations thereof. When used to cement a subterranean well, the compositions improve the compressive strength, increase the rate at which compressive strength develops, preserve cement homogeneity, or enhance cement expansion or a combination thereof.Type: ApplicationFiled: September 30, 2014Publication date: April 2, 2015Inventors: Arnaud Joseph Gino Bourlon, Olivier Porcherie, Sylvaine Le Roy-Delage
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Patent number: 8974595Abstract: A dry composition including at least one binder and an oil comprising at least one compound of formula (I) below: wherein, Z represents an optionally substituted, linear or branched C4 to C28 alkyl radical or an optionally substituted, linear or branched C4 to C28 alkenyl radical, and R, R? and R? are identical or different and separately represent an optionally substituted, linear or branched hydrogen atom, hydroxyl radical, C1 to C12 alkyl radical, an optionally substituted, linear or branched C1 to C12 heteroalkyl radical, an optionally substituted, linear or branched C5 to C10 cycloalkyl radical, or an optionally substituted, linear or branched C6 to C18 aryl radical.Type: GrantFiled: August 25, 2011Date of Patent: March 10, 2015Assignee: Sika Technology AGInventors: Christophe Guyot, Laurent Guillot
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Publication number: 20150041098Abstract: A printable refractory material is provided having a liquid and powder component configured for use in a 3-D powder printer, where the material forms hydraulic bonds when the liquid and powder components are combined. Methods of printing the refractory material and forming castings therefrom are also provided.Type: ApplicationFiled: August 6, 2014Publication date: February 12, 2015Inventors: Daniel S. McGuire, Eric E. Hellmstrom, Charles M. Olson
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Patent number: 8920557Abstract: Provided are an additive for skim coat mortar and a skim coat mortar composition including the same, and the additive is a blend of cellulose ether having hydroxyalkylalkyl cellulose cross-linked with an aldehyde compound and hydroxyalkyl cellulose cross-linked with an aldehyde compound. By applying the additive to a skim coat mortar composition, it is possible to improve workability, surface luster, and a creamy property while maintaining a water retention property.Type: GrantFiled: November 7, 2013Date of Patent: December 30, 2014Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: A Reum Lee, Sung Hoon Kim, Nak Woon Choi
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Publication number: 20140343194Abstract: Stabilized aqueous suspensions include aluminous cement and/or calcium sulfoaluminous cement and binding compositions including the aqueous suspension in combination with organic binders, which are stable at room temperature and at high temperature as well as methods for preparing the same are described.Type: ApplicationFiled: December 19, 2012Publication date: November 20, 2014Applicant: KERNEOSInventors: Pascal Taquet, Pierre-Antoine Andreani, Veronique Watt, Emilie Reveyrand
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Patent number: 8876968Abstract: The present invention relates to a current composition for cementing oil or gas wells. The composition comprises calcium aluminate cement in which the proportion of HC203 is at least 50% by weight, dispersant, microsilica, mineral particles, water and optionally a retarder.Type: GrantFiled: September 26, 2011Date of Patent: November 4, 2014Assignee: Elkem ASInventors: Phillippe Revil, Hong Peng
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Patent number: 8821630Abstract: The invention relates to compositions and methods for modifying cementitious materials such as by reducing setting time. Polymer compositions of the invention are derived by polyetherifying mono-glycerols, optionally with alkylene glycols, to obtain polyglycerol homopolymers or copolymers, and then carboxylating the obtained polyglycerol homopolymers and/or copolymers with an organic acid having at least two carboxylic functionalities. The set retardation effect of the carboxylated-carboxylic polyglycerol polymer compositions in cementitious materials is reduced is compared to polyglycerol polymer not having the carboxylated-carboxylic groups, while its water reducing ability is maintained without loss of early compressive strength. Cementitious compositions and methods involving the carboxylated-carboxylic polyglycerol are also covered by the invention.Type: GrantFiled: May 6, 2011Date of Patent: September 2, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Lawrence L. Kuo, Izabela Goc-Maciejewska, Romain Faivre
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Publication number: 20140238677Abstract: The current invention relates to the use of chitin nanocrystals and chitin nanocrystal derivatives. More specifically, the present invention relates to the use of chitin nanocrystals and chitin nanocrystals used in oil and gas operations. The chitin nanocrystals and chitin nanocrystals derivatives can be used as additives to cement and wellbore fluids and can be used to inhibit corrosion in pipelines, on downhole tools and on other oil and gas related equipment.Type: ApplicationFiled: February 28, 2013Publication date: August 28, 2014Applicant: Halliburton Energy Services, Inc.Inventor: Lee Jeremy Hall
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Patent number: 8802753Abstract: An additive for manufacturing permeable concretes with improved properties and method for manufacturing the same are provided. The additive comprises in a total composition: 33.70 to 54.90% water; 0.30 to 0.50% defoamer; 0.30 to 0.40% bactericide; 0.30 to 0.50% polyglycol; 7.20 to 24.00% of a combination of emulsifiers; 15.50 to 17.00% moisturizer; 0.8 to 22.90% dispersant; and 0.70 to 1.00% biopolymer. The additive for manufacturing permeable concretes can be added to any type of stony aggregate and/or cement improving the product's mechanical properties required in each step before, during, and after of the setting.Type: GrantFiled: June 28, 2012Date of Patent: August 12, 2014Inventor: Jaime Grau Genesias
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Publication number: 20140208983Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising placing into a wellbore a composition comprising a calcium aluminate cement and a polyvalent cation-containing compound, and allowing the composition to set. A method of increasing the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound. A method of adjusting the thickening time of a calcium aluminate cement comprising contacting the calcium aluminate cement with a polyvalent cation-containing compound and at least one other set modifier.Type: ApplicationFiled: March 31, 2014Publication date: July 31, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Ying XU, B. Raghava REDDY, Rickey Lynn MORGAN, Lance BROTHERS
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Patent number: 8747550Abstract: The present disclosure provides improved water-repellent admixtures for cementitious materials. The water-repellent admixtures are incorporated during masonry processing to improve the water resistance of the final product. Solid water-repellent admixtures may be conveniently incorporated into pre-blended dry mortar mixes. In some variations, a pre-blended dry mortar mix comprises a cementitious material, an aggregate, and a dry water-repellent admixture, wherein the water-repellent admixture contains one or more materials selected from the group consisting of silanes, siloxanes, free fatty acids, fatty acid derivatives, particulated polymers, and particulated copolymers, and wherein the water-repellent admixture is present in the pre-blended dry mortar mix in a dosage from about 0.01% to about 1.00% by weight of the pre-blended dry mortar mix.Type: GrantFiled: November 28, 2012Date of Patent: June 10, 2014Assignee: ACM Chemistries, Inc.Inventors: Craig T. Walloch, Theodore G. Light, Marshall L. Brown, Matthew J. Oesterle
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Patent number: 8728229Abstract: The present invention provides a cement slurry composition, containing a hydraulic cement material, (A) a first water-soluble low molecular weight compound and (B) a second water-soluble low molecular weight compound differing from the compound (A), wherein a combination of the compounds (A) and (B) is (I) the compound (A) selected from cationic surfactants and the compound (B) selected from anionic aromatic compounds; or (II) the compound (A) selected from cationic surfactants and the compound (B) selected from brominated compounds, and in the compound (A), a ratio of compounds having a hydrocarbon group of 18 or more carbon atoms is not less than 45% by weight.Type: GrantFiled: June 11, 2009Date of Patent: May 20, 2014Assignee: Kao CorporationInventors: Koji Koyanagi, Toshiharu Kojima, Hotaka Yamamuro
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Patent number: 8720563Abstract: A cement composition for use in an oil or gas well, the cement composition comprises: a calcium aluminate cement; water; an organic acid; and a polymeric mixture comprising: (A) water; (B) citric acid; (C) a first polymer, wherein the first polymer: (i) comprises a cellulose backbone and carboxymethyl functional groups; and (ii) has a molecular weight of less than 100,000; and (D) a second polymer, wherein the second polymer: (i) comprises a lignosulfonate; and (ii) has a molecular weight of less than 100,000, wherein a test composition consisting essentially of: the cement; the water; the organic acid; and the polymeric mixture, and in the same proportions as in the cement composition has a thickening time of at least 5 hours at a temperature of 300° F. (148.9° C.) and a pressure of 10,000 psi (68.9 MPa).Type: GrantFiled: May 9, 2012Date of Patent: May 13, 2014Assignee: Halliburton Energy Services, IncInventors: Trissa Joseph, Pankaj Phani Chakraborty, Mohand Melbouci
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Publication number: 20140109799Abstract: The present invention relates to a current composition for cementing oil or gas wells. The composition comprises calcium aluminate cement in which the proportion of HC203 is at least 50% by weight, dispersant, microsilica, mineral particles, water and optionally a retarder.Type: ApplicationFiled: September 26, 2011Publication date: April 24, 2014Applicant: ELKEM ASInventors: Phillippe Revil, Hong Peng
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Publication number: 20140060388Abstract: Ultra-high-performance cementitious materials are made using suitably functionalized and relatively low-cost carbon nanofibers and graphite platelets. Polyelectrolytes and surfactants are physisorbed upon these graphite nanomaterials in water, and dispersion of nanomaterials in water is achieved by stirring. Stable and well-dispersed suspensions of nanomaterials in water are realized without using energy-intensive and costly methods, and also without the use of materials which could hinder the hydration and strength development of ultra-high-performance cementitious materials. The water incorporating dispersed nanomaterials is then mixed with the cementitious matrix and, optionally, microfibers, and cured following standard concrete mixing and curing practices. The resulting cementitious materials incorporating graphite nanomaterials and optionally microfibers offer a desired balance of strength, toughness, abrasion resistance, moisture barrier attributes, durability and fire resistance.Type: ApplicationFiled: August 31, 2012Publication date: March 6, 2014Applicant: METNA COInventors: Muhammad Maqbool Sadiq, Anagi Manjula Balachandra, Parviz Soroushian
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Patent number: 8628713Abstract: An inorganic board contains, in a solid content ratio, 30 to 70 mass % of hydraulic material, 5 to 15 mass % of reinforcing fiber, and 1 to 30 mass % of wollastonite having a wet volume (after being allowed to stand for 30 minutes) of 15 to 45 ml. Also, a method includes: step of producing a slurry containing hydraulic material, reinforcing fiber, and wollastonite; step of producing a sheet by dehydrating the slurry; and step of pressing and curing the sheet; wherein, in the step of producing a slurry, a composition of the slurry is set so as to contain, in a solid content ratio, 30 to 70 mass % of hydraulic material, 5 to 15 mass % of reinforcing fiber, and 1 to 30 mass % of wollastonite having a wet volume (after being allowed to stand for 30 minutes) of 15 to 45 ml.Type: GrantFiled: March 5, 2013Date of Patent: January 14, 2014Assignee: Nichiha CorporationInventors: Satoshi Ikeda, Yusuke Omori
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Patent number: 8617506Abstract: To provide a method and facility for enabling CO2 gas generated in a cement manufacturing facility to be separated and recovered at a high concentration. To this end, according to the present invention, the calcination of a cement material and the recovery of CO2 gas generated in a calciner are performed by one of the following steps of: [1] superheating the cement material before calcination to at least the calcination temperature thereof in a superheating furnace and then mixing the superheated cement material with a new cement material before calcination in a mixer/calciner; [2] mixing, in the mixer/calciner, the cement material before calcination with a part of high-temperature cement clinker discharged from a cement kiln; and [3] using an externally heated calciner.Type: GrantFiled: April 30, 2009Date of Patent: December 31, 2013Assignee: Mitsubishi Materials CorporationInventors: Hirokazu Shima, Eiichi Motohashi, Junzhu Wang, Yoshinori Takayama
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Publication number: 20130333593Abstract: The present invention provides a method for producing a cured article of a hydraulic composition, prepared by mixing glycerol, cement and water, the hydraulic composition containing a sulfate ion, the method including step 1 of preparing the hydraulic composition such that a molar ratio of the sulfate ion to the glycerol, sulfate ion/glycerol, is 5.0 to 20 and the content of the sulfate ion is 3.0 to 15 parts by weight to 100 parts by weight of cement; and step 2 of aging and curing the hydraulic composition obtained in the step 1.Type: ApplicationFiled: March 26, 2012Publication date: December 19, 2013Applicant: KAO CORPORATIONInventors: Yusuke Yoshinami, Toshimasa Hamai, Hiroyuki Kawakami, Yohei Yoshikawa
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Publication number: 20130299170Abstract: A cement composition for use in an oil or gas well, the cement composition comprises: a calcium aluminate cement; water; an organic acid; and a polymeric mixture comprising: (A) water; (B) citric acid; (C) a first polymer, wherein the first polymer: (i) comprises a cellulose backbone and carboxymethyl functional groups; and (ii) has a molecular weight of less than 100,000; and (D) a second polymer, wherein the second polymer: (i) comprises a lignosulfonate; and (ii) has a molecular weight of less than 100,000, wherein a test composition consisting essentially of: the cement; the water; the organic acid; and the polymeric mixture, and in the same proportions as in the cement composition has a thickening time of at least 5 hours at a temperature of 300° F. (148.9° C.) and a pressure of 10,000 psi (68.9 MPa).Type: ApplicationFiled: May 9, 2012Publication date: November 14, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Trissa JOSEPH, Pankaj CHAKRABORTY, Mohand MELBOUCI
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Publication number: 20130294845Abstract: A dry grout composition including a calcium aluminosulfate based hydraulic cement, a mineral filler, a thixotropic agent, and a superplasticizer agent. Also, an anchoring capsule, containing the dry grout composition, for use in anchoring reinforcing member dowel, or anchor elements in a hole of a substrate, and a method of use.Type: ApplicationFiled: July 3, 2013Publication date: November 7, 2013Inventor: JACQUES BERTRAND
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Patent number: 8551240Abstract: A cement retarder system for use in underground wells included a borate compound, an organophosphonate salt, and a copolymer formed from AMPS and a monomer selected from the group consisting of acrylic acid, acrylamide and mixtures thereof.Type: GrantFiled: March 3, 2010Date of Patent: October 8, 2013Assignee: Schlumberger Technology CorporationInventors: Michel Michaux, Tatiana Pyatina