Abstract: Of the many methods and compositions provided herein, one method comprises providing a cement composition, wherein the cement composition comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into at least a portion of the subterranean formation; and allowing the cement composition to at least partially set therein. Another method provided herein comprises providing a cement composition that comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into a void located in a pipe string; and allowing the cement composition to at least partially set therein.

Abstract: The present invention relates to dispersants such as superplasticizers for hydratable cementitious compositions, and more particularly to methods for achieving variable degrees of longer slump life in concrete and mortar without loss of stability. This is achieved by using two admixture systems. The first admixture composition has multi-components for achieving initial-slump-enhancement, later-slump-retention, and limiting initial slump. The second admixture composition has the later-slump-enhancing component. Alternatively, conventional water reducers or superplasticizers can be employed initially, followed by the later-slump-enhancing admixture composition.

Abstract: The invention relates to a hydraulic binder whose main constituent is cement to which a mixture comprised of a chromate reducer and a carrier material is added for chromate reduction. The chromate reducer contains two iron(II) sulfate components, with the first component is made of filter salt from the titanium dioxide production, to which a mineral acid regulator, particularly ground limestone, is added. The second component is moist copperas. The hydraulic binder according to the invention is cost-effective and has chromate contents that are considerably lower than the legally permitted limit. The invention also relates to the use of a mixture of filter salt and copperas as a chromate reducer for reducing water-soluble chromate contents in cement.

Abstract: Cementitious slurries capable of controlling and/or preventing strength retrogression during the cementing of a formation contain a bismuth salt or derivative thereof. Bismuth trioxide is preferred. The cementitious slurry may further contain a density modifying agent and/or strength enhancer. The cementitious slurries of the invention are suitable for use over a broad temperature range of from about 45° F. to about 500° F.

Abstract: Methods and compositions for cementing, especially drilling fluids that comprise zeolite and a carrier fluid, and cementing compositions made with such drilling fluids.

Abstract: The invention relates to a hydraulic binder containing, in percentage by weight: from 1.1 to 9% of tricalcium aluminate from 1.5 to 13.5% of tetracalcium ferroaluminate from 0.5 to 1.5% of dodecacalcium heptaaluminate from 0.5 to 1.5% of tetracalcium trialuminate sulphate from 0 to 0.8% of dicalcium silicoaluminate from 5 to 70% of pozzolanic material(s) from 0 to 6% of calcium sulphate the remainder being composed of the non-aluminous constituents of at least one Portland-type clinker. It also relates to concretes or mortars prepared using a binder of this type.

Abstract: A concrete additive for a reinforced concrete composite is provided. The additive can have an exfoliated clay having an exfoliated layered silicate plate comprising structure, and at least one of an oligomer or polymer linking at least a portion of said silicate plate comprising structure. The additive can have a dispersant between the silicate plates. The clay can include sodium or calcium montmorillonite or a phosphatic clay. The oligomer or polymer can include polyvinyl alcohol.

Abstract: The present invention provides methods and compounds for the in situ formation in concrete of chloride sequestering compounds that resist corrosion of metals contained within the concrete. These chloride sequestering compounds may include, but are not limited to, compounds having the formula 3CaO.Fe(2-x)AlxO3.Ca(NO2)2.nH2O and 3CaO.Fe(2-x)AlxO3.Ca(NO3)2.nH2O, where x ranges from about 0 to 1.4 and n ranges from about 8 to 24. In one embodiment, at least one Fe-containing additive is introduced into cement, and at least one anion-containing additive is introduced into mixing water. When the cement and mixing water are combined to create fresh concrete, the additives react to form chloride sequestering compounds. In another embodiment, the additives are introduced or mixed directly into fresh concrete that has already been formed, where they react to create chloride-sequestering compounds. “In situ” formation refers to the creation of a chloride sequestering compound within concrete.

Abstract: A liquid accelerator composition for sprayed concrete, comprising aluminium sulphate, amorphous aluminium hydroxide, alkanolamine and an organic dibasic acid anhydride. The compositions allow the attainment of high early compressive strength, and they can be tailored to give good performance with a wide variety of cement types.

Abstract: Sorbent components containing calcium, alumina, silica, and halogen are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components ? reduce emissions of mercury and sulfur; ? reduce emissions of elemental and oxidized mercury; ? increase the efficiency of the coal burning process through de-slagging of boiler tubes; ? increase the level of Hg, As, Pb, and/or Cl in the coal ash; ? decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and ? make a highly cementitious ash product.

Abstract: A flow enhanced calcium sulfate product includes a calcium sulfate source material, such as a flue gas desulphurization by-product, is pre-blended with a granular feedstock exhibiting good cementitious properties. The flow enhanced calcium sulfate is fed to a cement mill where it is combined with clinker during a finishing grinding process for portland cement. The flow enhanced calcium sulfate exhibits good flowability without changing the properties of the cement.

Abstract: A cement slurry comprising a base for reducing the impact of an alkaline solution may be displaced into a wellbore and allowed to set. The base may comprise a metal carbonate that is soluble in water such as potassium carbonate. The cement slurry may further include cement, water, and a salt that is soluble in the water such as potassium chloride. The alkaline solution may be present in a formate-based drilling fluid displaced into the wellbore ahead of the cement slurry. Despite being contacted by such an alkaline solution, the thickening time of the cement slurry is long enough and the set time is short enough to provide for the formation of an impermeable mass in the annulus of the wellbore. The thickening times may range from about 4 hours to about 16 hours, and the set times may be less than about 24 hours.

Abstract: A rapid setting, controlled low strength composition of Class C fly ash is provided having a quantity of hydrated lime and an iron chelating compound in an amount sufficient to accelerate the hydration and set time of the fly ash. In some examples, a filler material is added. A method for acceleration of the hydration and set time of a cementitious mixture is provided wherein hydrated lime is added to the cementitious mixture in an amount in the range of 0.1% to 15% by weight and an iron chelating compound in an amount in the range of 0.01% to 5.0% by weight of the cementitious material. Further, a calcium source and an iron chelating compound may be added to a Class C fly ash to accelerate the hydration and set time of the ash.

Abstract: Concrete products and mixes with reinforcing carbon graphite fibers, the carbon fibers being provided in the form of resin coated warped beam fabric, and a method for producing reinforced concrete products, where semi-cured carbon fibers are mixed with concrete and then cured through the hydration step to result in the formation of strengthened concrete products.

Abstract: Settable drilling fluids that comprise an aqueous-based drilling fluid and cement kiln dust. Methods of cementing in a subterranean formation that comprise providing a settable drilling fluid comprising an aqueous-based drilling fluid and cement kiln dust, introducing the settable drilling fluid into a subterranean formation, and allowing the settable drilling fluid to set in the subterranean formation. Methods of converting an aqueous-based drilling fluid to a settable drilling fluid that comprise providing the aqueous-based drilling fluid, and adding cement kiln dust to the aqueous-based drilling fluid to form the settable drilling fluid. Methods of drilling a well bore and cementing a well bore that comprise drilling a well bore, circulating an aqueous-based drilling fluid in the well bore during the step of drilling the well bore, adding cement kiln dust to the aqueous-based drilling fluid to form a settable drilling fluid, and allowing the settable drilling fluid to set in the well bore.

Abstract: Settable compositions that comprise water, CKD, and microspheres, wherein the lightweight settable composition has a density less than about 13 pounds per gallon. Methods of cementing that comprise providing a lightweight settable composition having a density less than about 13 pounds per gallon, the lightweight settable composition comprising water, CKD, and microspheres, introducing the lightweight settable composition into a location to be cemented and allowing the lightweight settable composition to set therein.

Abstract: The invention relates to a setting accelerator for a composition comprising Portland cement, in the form of a slurry comprising at least one calcium aluminate, 0.5 4%, preferably 0.6 2.3% of an aluminous cement setting inhibitor by weight in relation to the overall weight of the calcium alumnate, and an anti-sedimentation agent.

Abstract: The present invention relates to an additive which is added in order to reinforce cement. The additive comprises chlorides of alkali metals, alkaline earth metals and/or transition metals and oxides selected from the group consisting of alkali metal and alkaline earth metal oxides, aluminum oxide, silica, apatite and/or zeolites and comprises, in particular, a combination of sodium chloride, ammonium chloride, aluminum chloride, potassium chloride, calcium chloride, magnesium chloride, magnesium oxide, magnesium sulfate, sodium carbonate, silica, apatite and/or zeolites. Additives of this type can be used, inter alia, to stabilize/modify cement; consolidate sand and/or soil, such as when building roads, dykes, tunnels, foundations and the like, immobilize pollutants, during the injection of cement compositions, such as grouting, and for the production of concrete.

Abstract: Improved casing strings, and methods of using improved casing strings in subterranean cementing operations, are provided. An example of an apparatus is a pipe string comprising at least one pipe section and a delivery system of an activator. Another example of an apparatus is a pipe string comprising at least one pipe section and a delivery system of a set retarder. An example of a method is a method of cementing in a subterranean formation. Other examples of methods are methods of cementing in a subterranean formation comprising a well bore.

Abstract: Methods for cementing and cement compositions are provided, wherein the cement composition comprises cementitious material and an aqueous suspension of zeolite and a chromate reducing agent.

Abstract: In at least one embodiment, the present invention relates to a gypsum composition suitable for use in the manufacture of construction materials comprising a) gypsum, b) water, and c) a water repellancy composition comprising a hydroxy-based cellulose and a siliconate.

Abstract: Cement compositions are provided that comprise a hydraulic cement, water, and a set retarder composition, the set retarder composition comprising an acrylamide polymer derivative; and an iron compound. In some embodiments, cement compositions are provided that comprise a hydraulic cement comprising a cement, water, and a set retarder composition, the set retarder composition comprising a lignin-based retarder and an iron compound.

Abstract: Concrete and/or cement products and mixes with reinforcing carbon graphite fibers having a length of about 2½ inches to about 3½ inches, and/or nano and/or micron sized carbon fibers, and a method of reinforcing concrete.

Abstract: Cement compositions, that comprise water, a cement, a strength-retrogression additive, and an acid, wherein the acid comprises ethylenediamine tetra acetic acid, nitrilotriacetic acid, or a combination thereof, are provided. Methods of cementing in a subterranean formation, methods of retarding the set time of a cement composition, and set retarder compositions also are provided.

Abstract: Exemplary compositions and methods for reducing hexavalent chromium in cementitious compositions involve the use of a liquid additive composition, comprising stannous chloride. Along with the stannous chloride may be used at least one co-additive comprising an antioxidant, oxygen scavenger, or mixture thereof, and/or at least one agent comprising a cement grinding aid, cement quality improver, or mixture thereof.

Abstract: The invention provides a method for making a concrete floor slab using sub-grade waterproofing in a manner that favors the use of water-based adhesives for affixing floor covering materials. The method comprises casting a hydratable cementitious composition onto a flooring membrane, the composition having a shrinkage reduction admixture and a water:cementitious binder ratio sufficiently low that substantially all of the water moisture is retained in the hydration reaction, and achieving a fully adhered bond with the flooring membrane.

Abstract: Cementing compositions are provided that comprise water, cement kiln dust, vitrified shale, zeolite, and/or amorphous silica, that utilize a packing volume fraction such that the solid particulate materials of the fluid are in a hindered settling state. Methods of cementing are provided that utilize compositions comprising water, cement kiln dust, vitrified shale, zeolite, and/or amorphous silica, that utilize a packing volume fraction such that the solid particulate materials of the fluid are in a hindered settling state.

Abstract: The present invention provides settable compositions that comprise water and cement kiln dust. The settable compositions optionally may comprise an additive that comprises at least one of the following group: fly ash; shale; slag cement; zeolite; metakaolin; and combinations thereof. The settable compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the settable composition; introducing the settable composition into a location to be cemented; and allowing the settable composition to set therein. The location to be cemented may be above ground or in a subterranean formation.

Abstract: An accelerator composition for use with sprayed cementitious compositions, which is an aqueous solution or dispersion of a blend of the essential Components 1–3 Component 1—aluminium sulphate Component 2—at least one of an alkanolamine and an alkylene diamine or triamine Component 3—hydrofluoric acid optionally with at least one of Components 4–7, with the proviso that at least one of Component 4 or Component 5 be present: Component 4—at least one of sodium hydroxide, potassium hydroxide, lithium hydroxide, magnesium hydroxide, lithium carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, sodium sulphate, potassium sulphate, magnesium sulphate and lithium sulphate; Component 5—C1–C10 aliphatic mono- and dicarboxylic acids and their metal salts; Component 6—aluminium hydroxide; Component 7—at least one of phosphoric acid and phosphorous acid. The accelerators have excellent long-term stability and work well with “difficult” cements, such as some Japanese OPCs.

Abstract: Provided herein are settable spotting compositions that comprise cement kiln dust and associated methods of use. Also provided are methods that comprise providing a settable spotting composition comprising cement kiln dust; introducing the settable spotting composition into a well bore that penetrates the subterranean formation so as to displace at least a portion of a second fluid from the well bore.

Abstract: An accelerator composition for use with sprayed cementitious compositions, which is an aqueous solution or dispersion of a blend of the essential Components 1–3 Component 1—aluminium sulphate Component 2—at least one of an alkanolamine and an alkylene diamine or triamine Component 3—hydrofluoric acid optionally with at least one of Components 4–7, with the proviso that at least one of Component 4 or Component 5 be present: Component 4—at least one of sodium hydroxide, potassium hydroxide, lithium hydroxide, magnesium hydroxide, lithium carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, sodium sulphate, potassium sulphate, magnesium sulphate and lithium sulphate; Component 5—C1–C10 aliphatic mono- and dicarboxylic acids and their metal salts; Component 6—aluminium hydroxide; Component 7—at least one of phosphoric acid and phosphorous acid. The accelerators have excellent long-term stability and work well with “difficult” cements, such as some Japanese OPCs.

Abstract: Methods of using cement compositions that comprise basalt fibers in subterranean formations are provided. An example of such a method may comprise providing a cement composition that comprises water, a hydraulic cement, and a plurality of basalt fibers; introducing the cement composition into a subterranean formation; allowing the cement composition to set therein. Also provided are methods of cementing a pipe string in a well bore and methods of enhancing the compressive strength of a cement composition.

Abstract: The present invention relates to well bore operations, and more particularly, to contained micro-particles, and methods for using such contained micro-particles in cementing operations. An exemplary method of facilitating the use of micro-particles in a well bore fluid comprises the steps of providing contained micro-particles, and adding the contained micro-particles to the well bore fluid. In an exemplary embodiment, the well bore fluids of the present invention comprise encapsulated micro-particles. In another exemplary embodiment, the well bore fluids of the present invention comprise pelletized micro-particles.

Abstract: Cement compositions including environmentally compatible defoamers and methods of using such cement compositions are provided herein. An example of a method is a method of cementing in a subterranean formation. Another example of a method is a method of reducing foam generation in a cement composition. An example of a composition is a cement composition including water, hydraulic cement, and a defoamer. Another example of a composition is a defoamer.

Abstract: Exemplary compositions and methods for reducing hexavalent chromium in cementitious compositions involve the use of a liquid additive composition, comprising stannous chloride. Along with the stannous chloride may be used at least one co-additive comprising an antioxidant, oxygen scavenger, or mixture thereof, and/or at least one agent comprising a cement grinding aid, cement quality improver, or mixture thereof.

Abstract: The present invention relates to substantially hydrated cement particulates. More particularly, the present invention relates to compositions comprising substantially hydrated cement particulates and associated methods of use in drilling and subterranean applications. These substantially hydrated cement particulates may be included in drilling and subterranean treatment fluids, inter alia, as carrier particles for admixtures, lost circulation materials, density-varying additives, proppants, and the like.

Abstract: A method of resisting corrosion of metal elements in concrete is provided. It includes introducing into concrete containing metal elements, at least one combination compound capable of sequestering chloride ions having the formula 3Me(II)O.(R,R?)2O3.Me(II)(anion)2.nH2O, where R and R? are different and are independently selected from the group consisting of Al, Fe and Cr; anion is selected from the group consisting of NO2, NO3 and OH, n is 0 to 24, and Me(II) is a cation and is selected from the group consisting of Ca, Ba, Sr, Mn, Zn and combinations thereof. In one embodiment of the invention, concrete structures may be rehabilitated by providing an overlay containing the combination compound, with the overlay being provided in situ or as a preformed member and with possible use of a slurry in combination with an overlay segment.

Abstract: The present invention provides settable compositions that comprise water and cement kiln dust. The settable compositions optionally may comprise an additive that comprises at least one of the following group: fly ash; shale; slag cement; zeolite; metakaolin; and combinations thereof. The settable compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the settable composition; introducing the settable composition into a location to be cemented; and allowing the settable composition to set therein. The location to be cemented may be above ground or in a subterranean formation.

Abstract: The present invention provides methods and compounds for the direct sequestration of chloride ions without requiring the addition of a source of anion such as nitrite or nitrate. A direct sequestration additive is introduced to fresh concrete or hardened concrete where the additive reacts with incoming chloride ions to form a low solubility, chloride-containing compound which captures or sequesters chloride ions. In a preferred embodiment, the chloride-containing compound comprises 3CaO.Fe(2-x)AlxO3.CaCl2.nH2O, where x ranges from about 0 to 1.4, and n ranges from about 8 to 24. The chloride ions may be provided in the form of deicing salt or sea water. Because chloride-containing compounds such as 3CaO.Fe(2-x)AlxO3.CaCl2.nH2O are formed directly without requiring the addition of a source of anion (e.g. nitrite or nitrate), the process is referred to as “direct sequestration.

Abstract: A cement slurry comprising a base for reducing the impact of an alkaline solution may be displaced into a wellbore and allowed to set. The base may comprise a metal carbonate that is soluble in water such as potassium carbonate. The cement slurry may further include cement, water, and a salt that is soluble in the water such as potassium chloride. The alkaline solution may be present in a formate-based drilling fluid displaced into the wellbore ahead of the cement slurry. Despite being contacted by such an alkaline solution, the thickening time of the cement slurry is long enough and the set time is short enough to provide for the formation of an impermeable mass in the annulus of the wellbore. The thickening times may range from about 4 hours to about 16 hours, and the set times may be less than about 24 hours.

Abstract: Disclosed are concrete and fiber cement formulations and products comprising low-density calcium silicate hydrate, and methods for producing these formulations and products. The disclosed formulations exhibit accelerated curing times. Other advantages of the disclosed formulations include improved dimensional stability in extruded products, reduced cracking, and reduced wash-out in underwater applications. The products of the disclosed formulation have lower cost of production and faster time to market.

Abstract: This invention relates to improved methods for completing wells in unconsolidated subterranean zones. More specifically, the present invention relates to cement compositions useful in subterranean applications, and more particularly, to permeable cement compositions and methods for forming consolidated permeable cement masses in well bores to prevent sand influx into the well bores with produced fluids. In one embodiment, the permeable cement compositions of the present invention comprise a hydraulic cement, water, and a degradable material capable of undergoing an irreversible degradation downhole.

Abstract: A magnetic device and method for making it involve a magnetic device specifically constructed of grains in a matrix. The matrix may be cement or plaster. The grains have an average diameter that is greater than their magnetic domains. The device may be applied to shielding applications for frequencies ranging from 100 kHz to 10 GHz. The shielding may be applied to walls of a building, consumer products such as magnetic disks, and the like. The grains may be any ferromagnetic material, including ferrite.

Abstract: Cement compositions, that comprise water, a cement, a strength-retrogression additive, and an acid, wherein the acid comprises ethylenediamine tetra acetic acid, nitrilotriacetic acid, or a combination thereof, are provided. Methods of cementing in a subterranean formation, methods of retarding the set time of a cement composition, and set retarder compositions also are provided.

Abstract: A burned product containing 100 parts by weight of C2S, 10 to 100 parts by weight of C2AS, and 20 parts by weight or less of C3A; a cement admixture prepared by grinding the burned product; and a cement containing 100 parts by weight of ground portland cement clinker and 5 to 100 parts by weight of a ground product of the burned product.

Abstract: Methods, cement compositions and oil suspensions of powders are provided. The oil suspensions of silica powder comprise silica powder, mineral oil, an oleophilic clay, an oleophilic surfactant and a hydrophilic surfactant.

Abstract: The invention provides a method for making a concrete floor slab using sub-grade waterproofing in a manner that favors the use of water-based adhesives for affixing floor covering materials. The method comprises casting a hydratable cementitious composition onto a flooring membrane, the composition having a shrinkage reduction admixture and a water:cementitious binder ratio sufficiently low that substantially all of the water moisture is retained in the hydration reaction, and achieving a fully adhered bond with the flooring membrane.

Abstract: Extremely fast setting of cementitious compositions for producing cement-based products such as cement boards is made possible by adding an alkanolamine to a hydraulic cement such as portland cement, and forming a slurry with water under conditions that provide an initial slurry temperature of at least 90° F. Use of alkanolamine under conditions disclosed herein allows an extremely rapid setting of the cementitious composition. Additional reactive materials may be included such as high alumina cement, calcium sulfate and a pozzolanic material such as fly ash. The extremely fast rapid set permits rapid production of cementitious products.

Abstract: A cement repair composition is provided for repairing thin concrete. The composition comprises, in weight percentages: fine aggregates, 50-80%; Portland cement, 10-20%; reinforcing fibers such as polyethylene, steel and fiberglass fibers, 0-5%; and a plurality of further additives. The additives preferably include a lithium admixture, an air entraining admixture and a water reducing chemical additive, and a shrinkage compensating chemical additive, in a combined weight percentage of 0.01 to 5%.

Abstract: A cement composition is basically comprised of a hydraulic cement, water in an amount sufficient to form a pumpable slurry and a fluid loss control polymer additive comprised of 69 weight % of the calcium salt of 2-acrylamido-2-methyl propane sulfonic acid, 14 weight % of the calcium salt of maleic acid, 14 weight % of N-vinyl caprolactam and 3 weight % of 4-hydroxybutyl vinyl ether.