Soil Stabilization Patents (Class 106/900)
  • Patent number: 5264029
    Abstract: The soil composition of this invention is comprised of a mixture of sand, clay, a plasticizer material, water, and a coloring pigment, if desired. The components of the soil composition are preferably present in the following proportions by weight: sand 50-70%; clay 10-40%; plasticizer 0.5-5.0%; water 5-20%; and coloring pigment 1-5%. The method of making the invention involves continuously mixing a portion of the sand and the plasticizer in an agitation mixer. The same becomes coated with the plasticizer, whereupon a quantity of clay is then added, followed by an additional portion of the plasticizer material It is particularly important that the sand particles become coated with the plastizing compound and clay. The coloring pigments are added and mixed thereafter. As soon as complete mixing takes place, material can be immediately transferred from the mixer to suitable packaging.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: November 23, 1993
    Assignee: True Pitch, Inc.
    Inventor: Boris Kviesitis
  • Patent number: 5263797
    Abstract: The present invention provides improved soil-cement compositions and methods of forming subterranean cementitious masses using the compositions. The soil-cement compositions are basically comprised of hydraulic cement, water present in the compositions in amounts sufficient to form slurries of the solids therein, a dispersant comprised of a mixture of sodium dihydrogen phosphate buffer, ferrous lignosulfonate, ferrous sulfate and tannic acid and soil present in an amount whereby the volume ratio of cement, water and dispersant to soil in the compositions is in the range of from about 0.3:1 to about 2.1:1.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: November 23, 1993
    Assignee: Halliburton Energy Services
    Inventors: Kurt O. Lindstrom, Wendell D. Riley
  • Patent number: 5252003
    Abstract: The specification discloses a method for the treatment of particulate materials such as soils and sludges containing arsenic compounds which comprises contacting the material with a source of iron (III) ions and a source of magnesium (II) ions to stabilize the material against leaching of arsenic. A preferred source of iron (III) ions is iron (III) sulfate and a preferred source of magnesium (II) ions is magnesium oxide.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: October 12, 1993
    Assignee: International Technology Corporation
    Inventor: John F. McGahan
  • Patent number: 5248327
    Abstract: The soil aggregate stability of a soil, particularly a crusting or compacting soil, is improved by the addition of a coal-derived product which is a humic acid gel, a humic acid salt gel, a humic acid salt which is capable of forming a gel in water or mixtures thereof.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: September 28, 1993
    Assignee: National Energy Council
    Inventors: Michael C. Laker, Johannes Dekker, Izak J. Cronje
  • Patent number: 5234485
    Abstract: A method of immobilizing a contaminant comprising mixing the contaminant with a reaction partner that is capable of chemically interacting with the contaminant to form a water-insoluble reaction product, the reaction partner being mixed in the form of a hydrophobic solid preparation, which is either obtained by grinding the reaction partner with an inert material and treating it with a hydrophobing agent or which contains the educt or reaction product of a dispersion by chemical reaction preliminarily treated with a hydrophobing agent, the mixing being conducted to form a soil or soil-like material with cohesive constituents of a clay-like structure.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: August 10, 1993
    Inventor: Friedrich Bolsing
  • Patent number: 5228808
    Abstract: A method is shown for stabilizing sulfate bearing soils in which a silica compound is incorporated into the soils with the soils being further stabilized by the application of lime. The silica compound can be either an amorphous, flume silica, a crystalline silica, a silica gel, sodium silicate, potassium silicate or combination thereof. The silica compound and lime can be incorporated into the soils in a single step.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: July 20, 1993
    Assignee: Chemical Lime Company
    Inventors: J. T. McKennon, Norman L. Hains, David C. Hoffman
  • Patent number: 5216171
    Abstract: 2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or --PX(OR.sup.4).sub.2 orR.sup.1 and R.sup.2 together form .dbd.CR.sup.5 R.sup.6 or --CO--Z--CO--,X is oxygen or sulfur,R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.6 -alkenyl, amino, C.sub.1 -C.sub.6 -alkylamino, di-C.sub.1 -C.sub.6 -alkylamino, morpholino, piperidino, pyrazolidino or C.sub.1 -C.sub.8 -alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl or substituted or unsubstituted phenyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, or substituted or unsubstituted phenyl,R.sup.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: June 1, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Hans Ziegler, Juergen Pfister, Gerhard Nilz, Gisela Lorenz, Juergen Dressel
  • Patent number: 5201608
    Abstract: A process for sealing soil formations, especially for sealing the base of a waste dump or encapsulating waste dumps or old sources of pollution. By this process, sewage sludge or river mud is mixed with water absorbent aggregate that is approximately 30-70 wt %, based on sludge or mud dry weight, forming a compressible non-hardening mixture. The resultant mixture is then applied to the soil formation and compressed mechanically, forming a non-hardening seal.
    Type: Grant
    Filed: November 8, 1990
    Date of Patent: April 13, 1993
    Inventor: Jost-Ulrich Kugler
  • Patent number: 5199822
    Abstract: A composite fill material (22) comprising soil (18) and spent lime (14) and a method for filling depressed land areas (24) therewith. The method for filling land areas (24) includes generating spent lime (14) by adding lime to water (12) in order to precipitate out minerals causing water hardness. The generated spent lime (14) is mixed with soil (18) to form a composite fill material (22) which is subsequently utilized to fill depressed land areas (24) thus creating a solid soil base.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: April 6, 1993
    Inventor: Robert V. Rogers
  • Patent number: 5184917
    Abstract: The method of treating a waste liquid or solid hydrocarbon to reduce risk of environmental contamination by the waste hydrocarbon, that includes forming a flowable cementitious paste of Portland cement and additives; introducing the hydrocarbon into the mix and distributing the hydrocarbon therein; forming the mix into a shape for curing, and allowing the formed mix to cure so as to encapsulate the hydrocarbon in the cured concrete mix.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: February 9, 1993
    Assignee: Polar Marine, Inc.
    Inventor: Donald H. Rez
  • Patent number: 5162600
    Abstract: A method of treating lead contaminated soil to reduce the amount of mobile lead contained in the soil, the method which comprises: (a) providing an agent selected from the group consisting of inorganic phosphate compounds, inorganic phosphite compounds and mixtures thereof; and (b) contacting the agent with the soil to react the agent with the lead and form immobilized, acid-insoluble lead compounds, thereby reducing the amount of mobile lead in the soil.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: November 10, 1992
    Assignee: Rheox, Inc.
    Inventors: Charles A. Cody, Steven J. Kemnetz, William Bronner
  • Patent number: 5151123
    Abstract: The soil composition of this invention is comprised of a mixture of sand, clay, a plasticizer material, water, and a coloring pigment, if desired. The components of the soil composition are preferably present in the following proportions by weight: sand 50-70%; clay 10-40%; plasticizer 0.5-5.0%; water 5-20%; and coloring pigment 1-5%. The method of making the invention involves continuously mixing a portion of the sand and the plasticizer in an agitation mixer. The same becomes coated with the plasticizer, whereupon a quantity of clay is then added, followed by an additional portion of the plasticizer material. It is particularly important that the sand particles become coated with the plastizing compound and clay. The coloring pigments are added and mixed thereafter. As soon as complete mixing takes place, material can be immediately transferred from the mixer to suitable packaging.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: September 29, 1992
    Assignee: True Pitch, Inc.
    Inventor: Boris Kviesitis
  • Patent number: 5145285
    Abstract: A multidimensional structural reinforcing element is disclosed, the element designed for inclusion within a matrix of soil, concrete, stone, and other materials to improve the index properties of the matrix. The elements have a hub portion with arms extending radially therefrom. The arms may include additional structural elements such as cubes or spheres on the distal ends thereof and the surface of the elements may be roughened to increase the surface area and the gripping function of the elements relative to the matrix material.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: September 8, 1992
    Inventors: Nathaniel S. Fox, Evert C. Lawton
  • Patent number: 5143481
    Abstract: The invention relates to a method of utilizing sewage sludge to form a stablized sterile or pasteurized material which can be used as fertilizer, as fill for land development, or as a cover in solid-waste disposal applications. Fluidized bed combustion residue, fly ash, or FBCR and fly ash are added directly to the sewage sludge exothermic heat is released and the mixture is cured in order to eliminate bacterial and other pathogenic agents. The mixture has a soil-like consistancy, making it spreadable. The mixture has both the nutritive benefits of sewage sludge as a fertilizer and alkalinity for treatment of overly acidic soil.
    Type: Grant
    Filed: April 18, 1991
    Date of Patent: September 1, 1992
    Assignee: American Fly Ash Company
    Inventors: Glenn O. Schumacher, LaVerne Weber, Mitchell Nowicki, Alan Dunbar, Jeffrey M. Douglas
  • Patent number: 5143550
    Abstract: The method of disposal of hydrocarbon sludge (such as petroleum-derived sludge residue from a hydrocracker) comprises mixing the sludge with spent silica-alumina catalyst particulate fines, of particle size not exceeding 50 micrometers, so as to form friable aggregates of the particulate fines in which the individual particles are bound together by the sludge. The resulting formulation is useful, inter alia, for road-making.
    Type: Grant
    Filed: May 21, 1991
    Date of Patent: September 1, 1992
    Inventor: George A. Willacy
  • Patent number: 5125770
    Abstract: The invention relates to a method of stabilizing the soil and preventing erosion. According to the invention such a method is characterized by treating the soil with a mixed product of a pre-gelatinized starch and 0.5-5% by weight, calculated on the dry starch, of a surfactant compound which contains an unbranched saturated alkyl group and is selected from the alkyl sulfates having 10-16 carbon atoms, the alkyl sulfonates having 10-16 carbon atoms and the fatty acid alcohols having 8-12 carbon atoms. The invention also relates to said mixed product.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: June 30, 1992
    Assignee: Cooperatieve Verkoop- en Productievereniging van Aardappelmeel en Derivaten AVEBE B.A.
    Inventors: Henderik Hesseling, Andries Kraak
  • Patent number: 5122012
    Abstract: A method is shown for reducing the swelling action of sulfates in clay bearing soils while increasing the bearing strength values of the soils by treating soils having high sulfate content with a barium containing compound in an amount effective to react with the sulfate present in the soils, thereby forming less soluble reaction products and decreasing the tendency of the soil to form ettringite. The soil is further stabilized by the application of lime.
    Type: Grant
    Filed: February 5, 1991
    Date of Patent: June 16, 1992
    Assignee: Chemical Lime Company
    Inventor: Daniel D. Walker, Jr.
  • Patent number: 5120344
    Abstract: The present invention relates to a method for producing a closing layer which improves the water and nutrient retention of soils, particularly of sandy soils, characterized in that a layer of clay mineral/polymer gel capable of binding and releasing water in a reversible manner is introduced into the soil, preferably 20-60 cm below the soil surface, in such a way that a clay mineral is reacted either before or after or during activation in the presence of water, with 0.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: June 9, 1992
    Assignees: Altalanos Iparfejlesztesi Rt., Vizepitooipari Troszt
    Inventors: Oszkar Libor, Gabor Nagy, Tamas Szekely, Rudolf Mester, Kalman Kazareczki, Tibor Muller, Jeno Kiss, Zoltan Saghi, Adam Hosszu
  • Patent number: 5114275
    Abstract: A process for improved hydrophobic waste storage is described wherein a latex comprising a preformed, high molecular weight polymer having a high affinity for hydrophobic liquids, is sprayed on the waste prior to admixing an inorganic matrix material. Alternately, a liner for use in a waste pit which is to contain hydrophobic waste liquids or concentrated aqueous salt solutions is produced in situ by blending and compacting a latex comprising a hydrophobic polymer and clay onto the surface of the waste pit.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: May 19, 1992
    Inventors: Philip W. West, William H. Daly
  • Patent number: 5106424
    Abstract: Decontamination of a beach or soil area that has hydrocarbon contamination including removing hydrocarbon contaminated sand or soil from an area; mixing the contaminated soil or sand with cement and water; and forming concrete from the mix.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: April 21, 1992
    Assignee: Polar Marine Inc.
    Inventor: Donald H. Rez
  • Patent number: 5085424
    Abstract: A laminated playing surface and its method of making wherein a chemically blown polyolefin foam sheet is laminated by an adhesive to a scrim sheet saturated with a stabilizing agent which when heated contracts the lamination so that it can stretch tight between opposed edge portions affixed to the surface of the playing site.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: February 4, 1992
    Assignee: Grandstand International Corp.
    Inventor: Sidney B. Wood, Jr.
  • Patent number: 5082500
    Abstract: A sprayable composition and a method of protecting material with the composition is disclosed. The composition comprises a polymer such as hydroxyethyl cellulose, clay, and water to provide a cover layer which, after spraying, is tough, flexible and water-repellent. Other materials such as shredded paper and gypsum can be used in the cover layer. The composition is effective as a cover layer over material such as soil, refuse at a dump site, or grain in a stockpile.
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: January 21, 1992
    Assignee: Newastecon, Inc.
    Inventors: Thomas Nachtman, John Hull, Patrick O'Shea
  • Patent number: 5059251
    Abstract: Impermeabilization and/or consolidation product for soils and building materials, usable by injection, characterized by the fact that it is obtained by mixture of a compound of slag in suspension in water and of a silica liquor having a ratio of SiO.sub.2 Na.sub.2 O lower than 2 and a silica content greater than about 10% by weight.
    Type: Grant
    Filed: January 29, 1990
    Date of Patent: October 22, 1991
    Assignee: Societe Anonyme dite - Soletanche
    Inventor: Daniel Gouvenot
  • Patent number: 5059252
    Abstract: A method for on-site bioremediation of soils contaminated with petroleum derived hazardous wastes is described. This method for enhancing bioremediation includes the step of applying a cationic ion exchange resin to the contaminated soil in an amount sufficient to promote growth of organisms capable of degrading the hazardous waste.
    Type: Grant
    Filed: December 12, 1989
    Date of Patent: October 22, 1991
    Assignee: Advanced Environmental Technologies, Inc.
    Inventor: Arthur E. Renfro, Jr.
  • Patent number: 5037480
    Abstract: A base and subbase composition of quicklime and waste aggregate is disclosed, the composition having high strength and a high resilient modulus.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: August 6, 1991
    Assignee: Baker Rock Crushing Company
    Inventor: Gerald A. Baker
  • Patent number: 5018906
    Abstract: The invention relates to the field of soil stabilization.It is aimed more precisely at a pulverulent product stabilizing soils in place, and its method of application. This product consists of the combination of a fatty amine such as distearyldimethylammonium chloride in powder form and of at least one pulverulent product chosen from cements, slaked limes, fly ash, water-repellents and their mixtures with compatible fillers and adjuvants.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: May 28, 1991
    Inventor: Monique F. Bonier-Sahuc
  • Patent number: 5013349
    Abstract: The present invention provides a soil conditioner composed of a powdery or granular composition in which a filler is integrally included in hydrogel and a method of producing the same wherein an aqueous solution of a hydrophilic cross-linkable polymer is mixed with a filler and then the mixture is subjected to cross linking treatment by which the polymer is made to have cross-linked structure and formed into gel. Since the filler is integrally included in hydrogel, the soil conditioner, when mixed with soil, does not separate into the respective components, and there is no problem of the hydrogel emerging up to the surface of soil with the passage of time.
    Type: Grant
    Filed: August 17, 1983
    Date of Patent: May 7, 1991
    Assignee: Japan Exlan Company Limited
    Inventor: Koji Tanaka
  • Patent number: 5006176
    Abstract: The present invention relates to a coagulant for soil and/or sand and method for preventing washout using the same. The coagulant comprises approximately 10 parts by weight of carboxymethylcellulose, approximately 10 parts by weight of calcium chloride, approximately 10 parts by weight of sodium metasilicate powder, 0.3 to 100 parts by weight of silicon dioxide and 1 to 300 parts by weight of calcium carbonate. The method for preventing washout comprises the steps of scattering the coagulant over the surface of the soil and/or sand in a manner such that 360 to 1000 g of the coagulant is applied to a volume of surface area of 1 m.sup.2 and a depth of 10 cm, and excavating the soil and/or sand to a depth of 5 to 20 cm and mixing the coagulant and the soil and/or sand while adjusting water content of the soil and/or sand in the range of 30 to 45%. In the method, a part of --OH of cellulose in carboxymethylcellulose is denatured into --OCH.sub.3 which is soluble in water and highly adhesive.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: April 9, 1991
    Assignees: Shiro Sejima, Yoshiyuki Oka, Ken Murata
    Inventor: Yoshiyuki Oka
  • Patent number: 5000789
    Abstract: There is disclosed a method for chemically stabilizing cohesive soils. Sulfuric acid, citrus stripper oil, and water are admixed to the soil. Then the soil is packed to consolidate the soil particles.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: March 19, 1991
    Assignee: CSS Technology, Inc.
    Inventor: Ervin Merritt
  • Patent number: 4997695
    Abstract: A mixture of swellable clay, such as bentonite, is charged with an additive which provides an excess of single-charged cations which tend to neutralize the deleterious effects of double-charged cations which are naturally present in seawater and industrial waste. The mixture is deposited on and carried by a sheet to facilitate its uses as a pond liner or a foundation sealant.
    Type: Grant
    Filed: February 1, 1989
    Date of Patent: March 5, 1991
    Assignee: James Clem Corporation
    Inventor: Arthur J. Clem
  • Patent number: 4997701
    Abstract: A mixture of swellable clay, such as bentonite, is charged with an additive which provides an excess of univalent ions which tend to neutralize the deleterious effects of ions which are naturally present in seawater. The mixture is deposited on and carried by a sheet to facilitate its uses as a pond liner or a foundation sealant.
    Type: Grant
    Filed: November 21, 1988
    Date of Patent: March 5, 1991
    Assignee: James Clem Corporation
    Inventor: Arthur J. Clem
  • Patent number: 4990373
    Abstract: An aqueous foamable membrane-forming composition comprised of a water dispersible polymeric latex, preferably styrene-butadiene latex, and an alkyl ether sulfate surface active agent. The composition desirably contains a alcohol having 12 to 14 carbon atoms, an acrylic acid polymer viscosity modifying agent and powdered carbon. Compositions of the invention in dilute aqueous form can be foamed and deposited on a surface to be covered, such as a landfill. Upon standing, the foam develops into a substantially stable, weather resistent membrane.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: February 5, 1991
    Assignee: Rusmar Incorporated
    Inventor: Paul A. Kittle
  • Patent number: 4964918
    Abstract: A grouting composition for sealing a borehole or other cavity comprising 90-99.9% finely divided water swellable clay and 0.1-10% thinner. The grouting composition is mixed with fresh water to provide a completely reswellable, unflocculated, easily placed, low permeability sealing composition. The thinner allows a very high concentration of water-swellable clay in the composition. A preferred grouting composition comprises 98-99.9% sodium bentonite and 0.1-2% polyacrylate thinner. In use, 50 lb. of the preferred grouting composition is mixed with 11-14 gallons fresh water, to provide a grouting mixture which comprises about 30-35% reswellable solids.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: October 23, 1990
    Assignee: Wyo-Ben, Inc.
    Inventors: Richard K. Brown, Robert W. Stichman
  • Patent number: 4941924
    Abstract: There is disclosed a method for chemically stabilizing cohesive soils. Sulfuric acid, citrus stripper oil, and water are admixed to the soil. Then the soil is packed to consolidate the soil particles.
    Type: Grant
    Filed: August 22, 1988
    Date of Patent: July 17, 1990
    Assignee: Chemical Soil Stabilization Technology, Inc.
    Inventor: Ervin Merritt
  • Patent number: 4940366
    Abstract: A method is disclosed for preparing excavated soil to render it suitable as hardened backfill by mixing with the soil a cementitious substance and ice particles, the ice particles being used in lieu of the water normally required to react with the cementitious substance.
    Type: Grant
    Filed: February 26, 1988
    Date of Patent: July 10, 1990
    Inventor: Toshiro Suzuki
  • Patent number: 4925493
    Abstract: A soil or dirt mixture that will not freeze into a stiff mass, and a method of making the same, are provided. The mixture is comprised of soil and wax, especially paraffin wax. The soil and wax are heated up, and are then mixed together while being continuously stirred until the mixture is cool.
    Type: Grant
    Filed: April 26, 1989
    Date of Patent: May 15, 1990
    Inventor: Michael A. Lamoreaux
  • Patent number: 4923500
    Abstract: Soil conditioning and method for desalination and reclamation of irrigated soil.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: May 8, 1990
    Inventors: Truman V. Sylling, Stephen L. Allen
  • Patent number: 4904304
    Abstract: A chemical grout for ground injection which is prepared by incorporating from 0.1 to 4.5 parts by weight of sulfamic acid and from 0.2 to 10.0 parts by weight of a water soluble magnesium salt into 100 parts by weight of an aqueous sol having a pH of 8 to 10.5 and containing from 5 to 25% by weight of colloidal silica (as SiO.sub.2) having a particle size of 3 to 7 m.mu., and from 0.05 to 1.5% by weight of Na.sub.2 O. This injecting grout has a gelation time not longer than 300 minutes. Soft ground can be consolidated by using the grout.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: February 27, 1990
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Yoshitane Watanabe, Eiji Okumura, Mikio Ando
  • Patent number: 4889563
    Abstract: Process for retarding and controlling the formation of gels or precipitates derived from aluminum and corresponding compositions, plus the corresponding applications--in particular regarding oil wells.
    Type: Grant
    Filed: July 2, 1986
    Date of Patent: December 26, 1989
    Assignee: Dowell Schlumberger Incorporated
    Inventors: Alan Parker, Colin Davidson
  • Patent number: 4844815
    Abstract: A method for stabilizing a mercury-containing waste comprising adding elemental sulfur and cement kiln dust to the waste in amounts effective to reduce the amount of leachable mercury to an environmentally acceptable level.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: July 4, 1989
    Assignee: Chemical Waste Management, Inc.
    Inventors: Milton Ader, Edward F. Glod, Edward G. Fochtman
  • Patent number: 4822420
    Abstract: Disclosed is a sealing composition for soil barriers. The composition is formed of 50 to 95% of a solids mixture of clay minerals and fillers, the clay mineral being 5 to 90% of the solids mixture; a binding agent which is a mixture of an aqueous solution of alkali water glass with a silane of the formula R--Si(OR'.sub.3) in which R is an aliphatic moiety of 1 to 6 carbon atoms, which may be substituted with reactive groups, and R' represents identical or different alkyl moieties of 1 to 4 carbon atoms; and water.
    Type: Grant
    Filed: February 25, 1987
    Date of Patent: April 18, 1989
    Assignee: Huels Troisdorf AG
    Inventors: Rudolf Burkhardt, Hansjurgen Hass, Reiner Hitze, Gunther Zoche
  • Patent number: 4820799
    Abstract: A process for producing a water-soluble polyelectrolyte comprising mixing acrylic acid or methacrylic acid with ammonium carbonate and a polyhydric alcohol--glycerol or ethylene glycol at a molar ratio therebetween of 2-6:1-2:1 respectively; adding hydrogen peroxide to the resulting reaction mass in an amount of from 0.1 to 1.0% by mass of the acid; polymerization of the reaction mass first at a temperature of 60.degree. to 80.degree. C. then at a spontaneous elevation of temperature to 110.degree.-140.degree. C.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: April 11, 1989
    Assignee: Institut Khimi Akademii Nauk Uzbekskoi SSR
    Inventors: Farykhdzhon A. Artykov, Ljudmila A. Lilbok, Jury P. Novikov, Karim S. Akhmedov, Aziz S. Zainutdinov, Sadriddin Zainutdinov
  • Patent number: 4799549
    Abstract: Stable, gel-forming aqueous microemulsions, well adopted for the reversible stabilization or plugging of soil/rock formations, e.g., subterranean well formations, are comprised of (i) an aqueous solution of a water-soluble alkali metal silicate, (ii) a gelling reagent therefor, and (iii) at least one surface active agent.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: January 24, 1989
    Assignee: Rhone-Poulenc Specialites Chimique
    Inventors: Bernard Vinot, Gerard Berrod, Jean-Louis Brun
  • Patent number: 4790691
    Abstract: Composite mixtures comprise soil and from about 0.1 to 5 percent by weight of additive fiber. A related method for improving the engineering properties of soil includes the steps of adding from about 0.1 to 5 percent by weight of fibers to soil and mixing the fibers and soil together to form a blend.
    Type: Grant
    Filed: October 3, 1986
    Date of Patent: December 13, 1988
    Inventor: W. Wayne Freed
  • Patent number: 4787453
    Abstract: A method for treating a fines-containing formation to prevent the migration and/or swelling of particulate matter. The method comprises injecting into the formation water and/or steam which contains at least one water-soluble organosilicon compound. Suitable compounds include those which are not normally considered to be water-soluble, but which hydrolyze to form water-soluble materials such as silanols.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: November 29, 1988
    Assignee: Union Oil Company of California
    Inventors: Gregory S. Hewgill, David R. Watkins, Leonard J. Kalfayan
  • Patent number: 4755226
    Abstract: Sealing and/or stabilizing and/or binding preparations comprising modified alkali metal silicate solutions having a molar ratio of SiO.sub.2 to Me.sub.2 O of from 2 to 4.5 wherein Me represents sodium or potassium; sodium metaborate and/or potassium metaborate in a molar ratio of SiO.sub.2 to B.sub.2 O.sub.3 of from 5 to 400; and glyoxal, and to the use of these preparations.
    Type: Grant
    Filed: February 5, 1987
    Date of Patent: July 5, 1988
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Friedemann, Wolfgang Pesch, Kurt Feulner
  • Patent number: 4755206
    Abstract: A stable, concentrated solution intended for subsequent aqueous dilution and application to sodium contaminated soils for the productive reclamation thereof is prepared by a process comprising:(a) preparing an initial aqueous solution having a concentration in the range of from about 1 to 4%% by weight of a water soluble calcium or magnesium salt and dissolving therein from about 1 to 2% by weight of a water soluble polymer having an average molecular weight of at least about 1,00,000;preparing a substantially saturated aqueous solution of the water soluble calcium or magnesium salt empolyed in step (a); and(c) mixing from about 5 to 20% by volume of the polymer-containing solution of step (a) with from about 80 to 95% by volume of the substantially saturated solution of step (b) to obtain the stable, concentrated solution.A particularly preferred salt is calcium nitrate and particularly preferred polymers are high molecular weight anionic polyacrylamide polymers.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: July 5, 1988
    Inventor: Greig J. Clark
  • Patent number: 4743288
    Abstract: A process for treating soil which comprises applying to the soil an aqueous solution of a formaldehyde-based pre-condensate containing a condensation initiator in an amount sufficient for condensation to be completed within a predetermined period of time not exceeding 24 hours. Preferably a urea-formaldehyde pre-condensate is used. Advantageously the solution also contains a polysaccharide (alginic acid, alginate, low methoxyl pectin, gum karaya, gum arabic) which is capable of forming a gel with divalent metal cations, particularly calcium, present in soil.The treated soil has improved erosion resistance.
    Type: Grant
    Filed: July 18, 1984
    Date of Patent: May 10, 1988
    Assignee: SAREA AG
    Inventor: Pierre Hirsbrunner
  • Patent number: 4735658
    Abstract: The invention describes a novel material intended for use in public works, constituted by a mixture of granular, alluvial or clay soils, of hydrophilic polymers and cationic hydrophobating additives, wherein this material presents a high insensitivity to variations of ambient humidity and is intended in particular for use with building roads.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: April 5, 1988
    Assignees: Ceca S.A., L'Etat Francais
    Inventors: Claude Blet, Didier Chabert, Laurent Frouin, Jean-Louis Reymonet, Ngoc L. Tran
  • Patent number: 4731120
    Abstract: The fill according to the invention comprises a mixture of 1-30% by weight cement with 99-70% by weight of various waste material, fly-ash, de-sulphurization product or granulated blast-furnace slag. The mixture can be used dry or mixed with water, and may also be mixed with air to form small bubbles, thereby rendering the mixture frost resistant. The fill can be used to fill different cavities and pits, such as pipe-laying and cable-laying trenches, floor cavities and holes in streets and roads, and for covering mounds of waste, rubbish dumps and for encapsulating harmful waste. When filling pipe-laying and cable-laying trenches, the intermediate layer of sand, and will thereby prevent water from entering into or leaking from the pipes, while at the same time holding the pipes in position and affording a stabilizing effect against ground movement.
    Type: Grant
    Filed: February 3, 1987
    Date of Patent: March 15, 1988
    Assignee: Cementa AB
    Inventor: Kyosti Tuutti