By Chemical Reaction, E.g., Ion-exchange, Chelating, Catalytic, Etc. Patents (Class 131/334)
  • Publication number: 20040250825
    Abstract: Cut filler compositions, cigarette paper, cigarette filters, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoscale particle composite catalysts capable of acting as a catalyst for the conversion of carbon monoxide to carbon dioxide. The nanoscale composite catalyst comprises metal and/or metal oxide particles supported on nanoscale support particles. The nanoscale composite catalyst can be prepared by forming a mixture by combining nanoscale particles with a colloidal solution, a metal precursor solution with nanoscale particles, or a metal precursor solution with a colloidal solution, and then heat-treating the mixture.
    Type: Application
    Filed: June 13, 2003
    Publication date: December 16, 2004
    Inventors: Sarojini Deevi, Kent B. Koller
  • Patent number: 6810884
    Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod and a non-combustible treatment material for the rod. The treatment material has a porosity less than about 200 Coresta units and a sidestream smoke treatment composition. The treatment composition comprises, in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst. In addition, the invention provides a low sidestream smoke cigarette unit that comprises a cigarette with conventional cigarette paper surrounding a conventional tobacco rod and a non-combustible treatment material surrounding and being substantially in contact with the conventional cigarette paper.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: November 2, 2004
    Assignee: Rothmans, Benson & Hedges Inc.
    Inventors: Stanislav M. Snaidr, Robert E. Becker
  • Patent number: 6799578
    Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod, and a combustible treatment paper having a sidestream smoke treatment composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: October 5, 2004
    Assignee: Rothmans, Benson & Hedges Inc.
    Inventors: Stanislav M. Snaidr, E. Robert Becker
  • Patent number: 6796312
    Abstract: The oral cavity is a source of sensitive biomarkers that allow the development of novel tobacco filters to reverse and eliminate acute adverse effects of tobacco smoke. Useful biomarkers are ubiquitous functional leukocytes and associated essential biochemical mechanisms, including metabolic pathways and specific enzymes, such as myeloperoxidase contained in fluid-cell lavages obtained from the human mouth. These biomarkers derived from the human mouth and sputum from the human respiratory system can be used to evaluate long-term chronic effects of tobacco smoke. A tobacco filter comprising strongly basic anion exchange resins and strongly acidic cation exchange resins with or without activated carbon, is used to detect, reduce and eliminate toxic substances from tobacco smoke while retaining taste and aroma. The novel filter in conjunction with biomarkers allow the establishment of performance standards that permit the direct visualization and measurement of acute adverse reactions caused by tobacco smoke.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: September 28, 2004
    Inventor: Bertram Eichel
  • Patent number: 6792953
    Abstract: A tobacco smoke filter a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye. A method of making a first tobacco smoke filter segment, comprising the steps of, first, providing one or more than one substance; producing a mixture of cellulose fiber and the substance; heating the mixture for a sufficient time at one or more than one temperature sufficient to covalently link the substance to the cellulose fiber; and forming the cellulose fiber with covalently bound substance into the first tobacco smoke filter segment. The substance can be a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: September 21, 2004
    Assignee: Filligent Limited
    Inventors: Craig A. Lesser, Reid W. Von Borstel
  • Patent number: 6789547
    Abstract: Catalytically active carbons are used in cigarette filters for selective oxidation of selected gas phase components in cigarette smoke. The carbons are impregnated with transition metals and sulfur and/or nitrogen ligation. The catalytic activity of the carbon is significantly improved by introducing catalytically active sites by heat treatment in the range of 500-1000° C. in the presence of transition metals and nitrogenous or sulfurous materials. Furthermore, introduction of such metalliferous sites into a active carbon can improve the absorptive affinity of the active carbon for classes of compounds, including aliphatic dienes and aromatic hydrocarbons.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: September 14, 2004
    Assignee: Philip Morris Incorporated
    Inventor: John B. Paine, III
  • Patent number: 6789546
    Abstract: A method of preventing or reducing tobacco smoke-associated injury in the aerodigestive tract of a subject is disclosed. The method comprises administering a therapeutically effective amount of an antioxidant agent capable of preventing or reducing tobacco smoke-associated injury in the aerodigestive tract of a subject.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: September 14, 2004
    Assignee: Technion Research & Development Foundation Ltd.
    Inventors: Abraham Z. Reznick, Rafael M. Nagler, Ifat Klein
  • Publication number: 20040173227
    Abstract: A tobacco smoke filter comprising one or more than one metal phthalocyanine, such as a copper phthalocyanine or an iron phthalocyanine, and further comprising one or more than one polycationic polymer.
    Type: Application
    Filed: March 17, 2004
    Publication date: September 9, 2004
    Inventor: Reid Von Borstel
  • Patent number: 6779529
    Abstract: A cigarette filter includes a multiple section filter which reduces the level of predetermined smoke constituents. The filter includes a fibrous filter plug section, a selective adsorbent section, and a general adsorbent section co-axially aligned in tandem. The selective adsorbent section includes a selective absorbent material which is a phenol-formaldehyde resin matrix surface-functionalized with mainly primary and secondary amine functional groups which removes specific smoke constituents from the tobacco smoke. The general adsorbent section is a material capable of adsorbing a range of chemical compounds without a high degree of specificity.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: August 24, 2004
    Assignee: Brown & Williamson Tobacco Corporation
    Inventors: James N. Figlar, Brian E. Tucker, F. Kelley St. Charles
  • Publication number: 20040110633
    Abstract: Nanocomposite copper-ceria catalysts are provided, which comprise copper oxide nanoparticles, copper nanoparticles, or a mixture thereof combined with ceria nanoparticles. Methods for making such catalysts are also provided, which involve the steps of (i) combining ceria nanoparticles in an aqueous suspension with copper 2,4-pentanedionate to form a slurry; (ii) heating the slurry formed in step (i) under an inert gas atmosphere or an oxygen-argon atmosphere, at a temperature and for a time sufficient to cause decomposition of the copper 2,4-pentanedionate to form copper nanoparticles and/or copper oxide nanoparticles that are combined with the ceria nanoparticles; and (iii) optionally, subjecting the product formed in step (ii) to a heat treatment process under conditions effective to convert at least some of the copper nanoparticles to copper oxide nanoparticles.
    Type: Application
    Filed: December 9, 2002
    Publication date: June 10, 2004
    Inventors: Sarojini Deevi, Sohini PalDey
  • Patent number: 6739344
    Abstract: A cellulose acetate structure excellent in its biodegradability. At least a surface region of the structure includes a biodegradable cellulose acetate composition containing a biodegradation promoting agent contained in cellulose acetate. The agent includes at least one compound selected from the group consisting of a salt of an oxygen acid of phosphorus, an ester of an oxygen acid of phosphorus or a salt thereof, carbonic acid and a salt thereof.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: May 25, 2004
    Assignee: Japan Tobacco Inc.
    Inventor: Yoichiro Yamashita
  • Publication number: 20040045566
    Abstract: A tobacco smoke filter synergist composition is provided comprised of antioxidants and minerals: the former are effective as free radical scavenger and the latter are capable of reducing the other harmful substances from tobacco smoke. In particular, minerals include the magnetized ferrite, which has great adsorbing capacity. The composition can be disposed within one or more chambers.
    Type: Application
    Filed: September 8, 2003
    Publication date: March 11, 2004
    Inventor: Ivo E. Pera
  • Publication number: 20040007242
    Abstract: The invention relates to a low ignition propensity cigarette having a self-extinguishing cigarette wrapper which is capable of self-extinguishing the cigarette. The cigarette wrapper comprises an oxygen storage and donor metal oxide to support and maintain free-burn of the self-extinguishing cigarette while retaining the low ignition propensity property of the self-extinguishing cigarette wrapper. The invention further relates to a low sidestream smoke cigarette having low ignition propensity properties. The wrapper has a composition which reduces sidestream smoke from a burning cigarette and comprises in combination, an oxygen storage and donor metal oxide catalyst and an essentially non-combustible finely divided porous particulate adjunct for the catalyst. The sidestream smoke reducing composition reduces porosity of the wrapper to render the cigarette as self-extinguishable.
    Type: Application
    Filed: April 22, 2003
    Publication date: January 15, 2004
    Applicant: Rothmans, Benson & Hedges Inc.
    Inventors: Warren Finlay, Stanislav M. Snaidr
  • Publication number: 20040007241
    Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes which involve the use of partially reduced nanoparticle additives capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide are provided. The compositions, articles and methods of the invention can be used to reduce the amount of carbon monoxide and/or nitric oxide present in mainstream smoke. The partially reduced additive can be formed by partially reducing Fe2O3, to produce a mixture of various reduced forms such as Fe3O4, FeO and/or Fe, along with unreduced Fe2O3.
    Type: Application
    Filed: April 7, 2003
    Publication date: January 15, 2004
    Inventors: Ping Li, Firooz Rasouli, Mohammad R. Hajaligol
  • Publication number: 20030183239
    Abstract: A tobacco smoke filter a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye. A method of making a first tobacco smoke filter segment, comprising the steps of, first, providing one or more than one substance; producing a mixture of cellulose fiber and the substance; heating the mixture for a sufficient time at one or more than one temperature sufficient to covalently link the substance to the cellulose fiber; and forming the cellulose fiber with covalently bound substance into the first tobacco smoke filter segment. The substance can be a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye.
    Type: Application
    Filed: March 10, 2003
    Publication date: October 2, 2003
    Inventors: Craig A. Lesser, Reid W. Von Borstel
  • Patent number: 6615840
    Abstract: An electrical smoking system comprising a cigarette and an electric lighter, wherein the cigarette comprises a wrapper surrounding a tubular tobacco mat partially filled with material tobacco so as to define a filled tobacco rod portion and an unfilled tobacco rod portion. The wrapper includes an ammonium containing compound filler therein effective to reduce gaseous components of the tobacco smoke produced during smoking of the cigarette. The system includes a lighter comprising at least one heating blade and a controller adapted to control heating of the heater blade, the lighter arranged to at least partially receive the cigarette such that the heater blade heats a heating zone of the cigarette.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: September 9, 2003
    Assignee: Philip Morris Incorporated
    Inventors: Jay A Fournier, John B. Paine, III
  • Publication number: 20030140933
    Abstract: The oral cavity is a source of sensitive biomarkers that allow the development of novel tobacco filters to reverse and eliminate acute adverse effects of tobacco smoke. Useful biomarkers are ubiquitous functional leukocytes and associated essential biochemical mechanisms, including metabolic pathways and specific enzymes, such as myeloperoxidase contained in fluid-cell lavages obtained from the human mouth. These biomarkers derived from the human mouth and sputum from the human respiratory system can be used to evaluate long-term chronic effects of tobacco smoke. A tobacco filter comprising strongly basic anion exchange resins and strongly acidic cation exchange resins with or without activated carbon, is used to detect, reduce and eliminate toxic substances from tobacco smoke while retaining taste and aroma. The novel filter in conjunction with biomarkers allow the establishment of performance standards that permit the direct visualization and measurement of acute adverse reactions caused by tobacco smoke.
    Type: Application
    Filed: August 30, 2001
    Publication date: July 31, 2003
    Inventor: Bertram Eichel
  • Patent number: 6595218
    Abstract: A cigarette filter having a reagent which chemically reacts with and removes a gaseous component of a smoke stream. The reagent contains functional groups covalently bonded to a non-volatile inorganic substrate which is incorporated in the filter. The filter can remove gaseous components such as aldehydes from tobacco smoke. Preferred functional groups are 3-aminopropylsilyl groups covalently bonded to silica gel (APS silica gel). The reagent can be contained in a space in the filter or incorporated in one or more filter elements such as tipping paper, shaped paper insert, mouthpiece plug, solid filter element, or free-flow filter element. The reagent can be part of or coated on paper such as tipping or filter paper or incorporated in non-paper filter elements formed from fibrous materials such as cellulose acetate or polypropylene fibers. Other preferred reagents include aminoethylaminopropylsilyl (AEAPS) silica gel and aminoethylaminoethylaminopropylsilyl (AEAEAPS) silica gel.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: July 22, 2003
    Assignee: Philip Morris Incorporated
    Inventors: Kent B. Koller, Susan E. Wrenn, Willie G. Houck, Jr., John B. Paine, III
  • Patent number: 6591839
    Abstract: A filter material for reducing the content of harmful substances in tobacco smoke. The filter material comprises a ground and not additionally activated expanded clay produced without adding foreign substances, and zeolite as the filter material. The filter is suitable for tobacco products such as cigarettes, cigars and cigarillos, and for smoking articles such as tobacco pipes and cigarette and cigar holders.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: July 15, 2003
    Inventors: Dieter Meyer, Hans-Peter Braun
  • Patent number: 6571802
    Abstract: A molded article molded from a cellulose acetate composition comprising, contained in cellulose acetate, a composite material of a decomposition accelerating agent formed of at least one compound selected from the group consisting of oxygen acid of phosphorus, oxygen acid of sulfur, oxygen acid of nitrogen, a partial ester or hydrogen salt of these oxygen acids, carbonic acid and its hydrogen salt, a sulfonic acid and a carboxylic acid, with a reaction controlling agent formed of at least one compound selected from the group consisting of a nitrogen-containing compound, a hydroxy compound, an oxygen-containing heterocyclic compound and a sulfur-containing heterocyclic compound.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: June 3, 2003
    Assignee: Japan Tobacco Inc.
    Inventor: Yoichiro Yamashita
  • Publication number: 20030075193
    Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoparticle additives capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. Cut filler compositions are described which comprise tobacco and at least one nanoparticle additive. Cigarettes are provided, which comprise a tobacco rod, containing a cut filler having at least one nanoparticle additive. Methods for making a cigarette are provided, which involve (i) adding a nanoparticle additive to a cut filler; (ii) providing the cut filler comprising the additive to a cigarette making machine to form a tobacco rod; and (iii) placing a paper wrapper around the tobacco rod to form the cigarette.
    Type: Application
    Filed: August 31, 2001
    Publication date: April 24, 2003
    Inventors: Ping Li, Mohammad Hajaligol
  • Patent number: 6530377
    Abstract: A tobacco smoke filter comprising a porous substrate comprising dry water and a porphyrin dispersed therein. The porous substrate can further comprise microcapsules. The microcapsules can comprise one or more substances selected from the group consisting of chlorophyllin, methylcellulose, sodium pyroglutamate and a vegetable oil. The porous substrate can further comprise sodium pyroglutamate.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 11, 2003
    Assignee: Filligent Limited
    Inventors: Craig Lesser, Reid W. Von Borstel
  • Patent number: 6481442
    Abstract: A smoking article including a wrapper surrounding a tobacco column and a selective filter element is disclosed. The selective filter element includes at least one carrier having a developed structure and a plurality of moieties capable of the nucleophilic attack of carbonyl-containing combustion products of the smoking article supported by the at least one carrier. The selective filter element may include at least one additional filter element such as cellulose acetate. The developed structure of the at least one carrier encourages the interaction of the carbonyl-containing combustion products and the plurality of moieties capable of the nucleophilic attack. Carries include polymers, which may have branch, such as partially oxidized cellulose and polyaniline. Carries may also be a zeolite or an inorganic oxide such as aluminum, of silicon, of aluminum and silicon, and combinations thereof. In yet another carrier is an activated carbon.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: November 19, 2002
    Assignee: Lorillard Licensing Company, LLC
    Inventors: Alexander J. Dyakonov, David A. Grider, Tatyana A. Dyakonov
  • Publication number: 20020166564
    Abstract: A smoking article capable of delivering a regulated smoke composition to a smoker, includes a combustible filler wrapped in a combustible sheath and a filter unit designed to remove components from the smoke, disposed within the sheath. The filter unit includes a mass of porous silica or resin particles, where the porous silica or resin particles have an average particle size of from about 35 to about 400 &mgr;m and preferably an average porosity of from about 10 Å to about 1000 Å. The porous cigarette filter is self-compensating with respect to air ventilation.
    Type: Application
    Filed: March 26, 2002
    Publication date: November 14, 2002
    Inventor: Michael T. Sung
  • Patent number: 6478032
    Abstract: The invention relates to a cigarette paper having a low total filler content, 20% by weight of the paper or less, a proportion of the filler being a filler capable of effecting visible sidestream smoke reduction. The basis weight of the paper is about 30 g m−2 or more. Smoking articles made with such papers provide a synergistic sidestream smoke component reduction when compared with control cigarettes. Papers according to the invention with the addition of various burn additives are also described.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: November 12, 2002
    Assignee: British-American Tobacco (Investments) Limited
    Inventors: Paul David Case, Alan George Stephenson
  • Patent number: 6470894
    Abstract: A composition for inclusion within a cigarette, cigar, pipe or smokeless tobacco. The composition can be included within the tobacco itself, a filter for filtering tobacco smoke once burned or even within the paper or wrapper surrounding the tobacco product. In the cigarette filter, be it internal or external filters, the antioxidant complex is capable of scavenging and neutralizing the free radicals emanating from the burning or heated tobacco and passing through the filter as the smoker inhales. The composition is also capable of reducing free radical damage to the oro-pharyngeal cavity, respiratory tract and lungs resulting from tobacco smoke. The composition includes glutathione and preferably L-glutathione and green tea and/or grape seed extract.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: October 29, 2002
    Assignee: Thione International, Inc.
    Inventors: Theodore Hersh, Rebecca Hersh
  • Patent number: 6415798
    Abstract: A composition for inclusion within a cigarette, cigar, pipe or smokeless tobacco. The composition can be included within the tobacco itself, a filter for filtering tobacco smoke once burned within the paper or wrapper surrounding the tabacco product. In the cigarette filter, be it internal or external filters, the antioxidant complex is capable of scavenging and neutralizing the free radicals emanating from the burning or heated tobacco and passing through the filter as the smoker inhales. The composition is also capable of reducing free radical damage to the oro-pharyngeal cavity, respiratory tract and lungs resulting from tobacco smoke. The composition includes glutathione and preferaby L-glutathione and sources of the antioxidant enzymes catalase and superoxide dismutase.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: July 9, 2002
    Assignee: Thione International, Inc.
    Inventors: Theodore Hersh, Rebecca Hersh
  • Publication number: 20020062834
    Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod, and a combustible treatment paper having a sidestream smoke treatment composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst.
    Type: Application
    Filed: September 18, 2001
    Publication date: May 30, 2002
    Inventors: Stanislav M. Snaidr, E. Robert Becker
  • Patent number: 6371127
    Abstract: A device for minimizing cigarette sidestream smoke and reducing the free-burn rate of a burning cigarette, the device comprises: I) a non-combustible tubular element (12) encasing an effective length of a tobacco charge (22) of a cigarette (14) located in a tubular element; and II) the tubular element having a means for both minimizing sidestream smoke emission from a burning tobacco charge and reducing free-burn rate of such burning tobacco charge to increase the number of puffs from the burning tobacco charge.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: April 16, 2002
    Assignee: Rothmans, Benson & Hedges Inc.
    Inventors: Stanislav M. Snaidr, Larry Bowen, Warren A. Brackmann
  • Patent number: 6334448
    Abstract: A poison-reduced cigarette includes adding hydrate of double salt of ferroso-ferric chloride into tobacco and cigarette filter to react with nicotine to form salt which will not be absorbed by the mucous membranes in the smoker's respiratory system for minimizing nicotine poison and for enhancing the smoker's health.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: January 1, 2002
    Inventor: Dai-Ming Kuo
  • Patent number: 6311696
    Abstract: The invention relates to low delivery cigarettes, usually having a mainstream particulate matter delivery of about 9 mg or less. An embodiment has a rod of tobacco material and a filter element. The filter element is an alkali filter material section having a loading level of less than 12% by weight of the section. The characteristics of the cigarettes are arranged so that, when smoked, the alkaline filter material is exposed to an amount of smoke acceptable to achieve an increased perception of smoke impact.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: November 6, 2001
    Assignee: British-American Tobacco Company Limited
    Inventors: David John Dittrich, Richard Thomas Fiebelkorn
  • Patent number: 6286516
    Abstract: A cigarette sidestream smoke treatment material made from a sheet of non-combustible active components provides a porous structure capable of treating sidestream smoke. The treatment material, as used in combination with a cigarette, provides a low sidestream smoke emitting cigarette unit. The material has a porosity which encourages a conventional free-burn rate of a conventional cigarette. The material may comprise a sorbent capable of sorbing components of the sidestream smoke, and an oxygen storage component which releases oxygen at free-burn rate temperatures to ensure that conventional free-burn rate is maintained and to enhance the oxidation treatment of the adsorbed non-aqueous components. Preferably, an oxidation catalyst is included in the material and most desirably the oxygen storage component may also function as the oxidation catalyst. Particularly preferred materials which perform the dual function are oxides of cerium.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: September 11, 2001
    Assignee: Rothmans, Benson & Hedges Inc.
    Inventors: Larry Bowen, Stanislav M. Snaidr, E. Robert Becker, Warren A. Brackmann
  • Patent number: 6209547
    Abstract: A cigarette filter having a reagent which chemically reacts with and removes a gaseous component of a smoke stream. The reagent contains functional groups covalently bonded to a non-volatile inorganic substrate which is incorporated in the filter. The filter can remove gaseous components such as aldehydes from tobacco smoke. Preferred functional groups are 3-aminopropylsilyl groups covalently bonded to silica gel (APS silica gel). The reagent can be contained in a space in the filter or incorporated in one or more filter elements such as tipping paper, shaped paper insert, mouthpiece plug, solid filter element, or free-flow filter element. The reagent can be part of or coated on paper such as tipping or filter paper or incorporated in non-paper filter elements formed from fibrous materials such as cellulose acetate or polypropylene fibers.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: April 3, 2001
    Assignee: Philip Morris Incorporated
    Inventors: Kent B. Koller, Susan E. Wrenn, Willie G. Houck, Jr., John B. Paine, III
  • Patent number: 6153119
    Abstract: A process, and product which uses the process, for reducing tar and nicotine in cigarettes, whereby a novel emulsified complex of Sterotex/permanganate is incorporated into a cigarette. The complex displays a synergistic reaction having a dose response relationship permitting linear adjustment to reduce more than 85% of the tar and nicotine in the mainstream smoke of a cigarette. Chemical analysis of the smoke condensate demonstrates the oxidation of nicotine to nicotinic acid, a B6 vitamin.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: November 28, 2000
    Inventor: Michael Sung
  • Patent number: 6145511
    Abstract: A description is given of a filter cigarette, whose filtera) contains fibrous filter material,b) contains an additive with an antimutagenic action on the cigarette smoke in a quantity of less than 15 wt. %, based on the fiber weight of the filter andc) on smoking a similar unventilated filter cigarette, but not containing additive, has a nicotine retention R.sub.N (in %) (determined according to CORESTA recommended method No. 9) satisfying the following formula:R.sub.N .gtoreq.100*(1-D)in which:D=exp(A*B+C),withA=21 mm-filter length (mm) for filter lengths.ltoreq.25 mm orA=-4 mm for filter lengths>25 mm,B=9.3*10.sup.-3 (1/mm) andC=-(d.sup.4 *.DELTA.p*K+L)with d=filter diameter (mm),.DELTA.p=draw resistance of filter (mm hydraulic pressure),K=1.0228*10.sup.-6 (1/(mm.sup.4 *mm hydraulic pressure)) andL=0.2334.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: November 14, 2000
    Assignee: Rhodia Acetow AG
    Inventors: Eberhard Teufel, Wolfgang Sexauer, Rolf Willmund
  • Patent number: 6119699
    Abstract: A smoking article capable of delivering a regulated smoke composition to a smoker, includes: a) a combustible filler wrapped in a combustible sheath; and b) at least one affinity chromatographic filter unit designed to preferentially remove specific targeted components from the smoke disposed within the sheath adjacent the combustible filler. The filter unit includes a mass of silica or resin particles having chemically bonded to their surfaces functional groups which exhibit preferential affinity for the targeted components and which reversibly bind the targeted components to elute components having a lower affinity than a previously bound component.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: September 19, 2000
    Inventor: Michael T. Sung
  • Patent number: 6000404
    Abstract: The invention relates to a cigarette paper having a low total filler content, 20% by weight of the paper or less, a proportion of the filler being a filler capable of effecting visible sidestream smoke reduction. The basis weight of tbh paper is about 30 g m.sup.-2 or more.Smoking articles made with such papers provide a synergistic sidestream smoke component reduction when compared with control cigarettes. Papers according to thee invention with the addition of various burn additives are also described.
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: December 14, 1999
    Assignee: British American Tobacco (Investments) Limited
    Inventors: Paul David Case, Alan George Stephenson
  • Patent number: 5970988
    Abstract: This invention provides cellulose ester fibers having an intermediate degree of substitution per anhydroglucose unit (DS/AGU) along with pigments which act as photooxidation catalysts. The fibers are useful as filter materials for tobacco products. The filter materials thus provided are easily dispersible and biodegradable and do not persist in the environment.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: October 26, 1999
    Assignee: Eastman Kodak Company
    Inventors: Charles M. Buchanan, Robert M. Gardner, James E. Harris, Gether Irick, Jr., David V. Strickler, Jr.
  • Patent number: 5944025
    Abstract: A smoking article and its method of construction and operation to provide products of combustion which are used to form flavorable aerosol gases delivered to the smoker's mouth while controlling the composition of such gases of combustion. Hot gases generated in a catalytic section in which fuel and air combust aided by a honeycomb catalytically coated surface including alumina and a cerium compound.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: August 31, 1999
    Assignee: Brown & Williamson Tobacco Company
    Inventors: Christopher J. Cook, Adriano Polo, Matthew H. Zoller, Beth E. Waltermire, Sandra F. Smith
  • Patent number: 5921248
    Abstract: There are disclosed filters for tobacco combustion products that, when employed in conjunction with exposure to tobacco smoke, inhibit the accumulation of AGEs and AGE-like tobacco- and tobacco smoke-derived adducts in individuals exposed to tobacco smoke. There is further disclosed a use of ascorbic acid and derivatives thereof for the preparation of filters to inhibit the accumulation of advanced glycation endproducts (AGEs) and AGE-like tobacco- and tobacco smoke-derived adducts in individuals exposed to tobacco smoke.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: July 13, 1999
    Assignee: The Picower Institute for Medical Research
    Inventors: Iain D. Nicholl, Richard J. Bucala
  • Patent number: 5909736
    Abstract: This invention refers to a method of withholding noxious compounds contained in cigarette smoke (NO, NOx, carcinogenic nitrosocompounds, free radicals, H.sub.2 O.sub.2, CO, aldehydes, and trace elements) which were up to today insufficiently retained by conventional cigarette filters. The method described specifically refers to the enrichment of common convention filters with biological substances of the metal ions (Fe.sup.2+, Cu.sup.2+, Mg.sup.2+) complexed with porphirin ring as well as Fe.sup.2+ ions stereospecifically bound to protein molecules, either separately or in combinations. The enrichment of these conventional filters with the abovementioned biological substances alters neither the physical properties of the cigarette smoke (odor, taste and appearance) nor the physical properties of the filter itself.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: June 8, 1999
    Inventors: Ioannis Stavridis, George Deliconstantinos
  • Patent number: 5839448
    Abstract: Cigarette filters are disclosed which comprise entangled continuous filaments of lyocell. The filaments may be entangled for example by hydroentangling a web which comprises one or more layers of lyocell filaments in spread tow form or by directing radial or circumferential water jets at a tow of lyocell filaments in rod form.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: November 24, 1998
    Assignee: Courtaulds Fibres (Holdings) Limited
    Inventor: Calvin R. Woodings
  • Patent number: 5829449
    Abstract: A composition for inclusion within a cigarette, cigar or pipe. The composition can be included within the tobacco itself, a filter for filtering tobacco smoke once burned or even within the paper or wrapper surrounding the tobacco product. The composition is capable of reducing free radical damage to the oro-pharyngeal cavity, respiratory tract and lungs resulting from tobacco smoke. The composition includes L-glutathione and a source of selenium such as selenomethionine.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: November 3, 1998
    Assignee: Thione International, Inc.
    Inventors: Theodore Hersh, Rebecca Hersh
  • Patent number: 5810020
    Abstract: There is disclosed a process for denitrifying tobacco materials and removing barium from tobacco materials, comprising mixing an aqueous-immiscible organic solvent containing a crown ether with an aqueous solution containing soluble components from tobacco materials, agitating this mixture, and separating the organic phase containing a crown ether-cation-nitrate (or nitrite) complex from the aqueous phase containing the denitrified tobacco materials, wherein the cation consists essentially of barium and potassium. There is further disclosed a process for eliminating tobacco-specific nitrosamines (TSNAs) from cured, denitrified tobacco material, comprising contacting the denitrified tobacco material with a trapping sink, wherein the trapping sink comprises a select transition metal complex which is readily nitrosated to form a nitrosyl complex with little kinetic or thermodynamic hindrance.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: September 22, 1998
    Assignee: Osmotek, Inc.
    Inventors: Steven Northway, Robert Salter
  • Patent number: 5746231
    Abstract: A tobacco smoke filter comprising a porous substrate having a humectant, such as sodium pyroglutamate, dispersed therein to absorb moisture from the tobacco smoke thereby wet-filtering the tobacco smoke. The tobacco smoke filter can also comprise a porous substrate having microcapsules dispersed therein. The microcapsules can comprise a humectant such as sodium pyroglutamate. The microcapsules further preferably comprise one or more of methylcellulose, chlorophyllin and at least one vegetable oil. The tobacco smoke filter can also comprise a porous substrate having dry water and a porphyrin dispersed therein. The tobacco smoke filter can also comprise a porous substrate having a copper-containing porphyrin dispersed therein.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: May 5, 1998
    Assignee: Craig Lesser
    Inventors: Craig Lesser, Reid W. Von Borstel
  • Patent number: 5685323
    Abstract: A disposable filter attachment for smoking articles, such as cigarettes, comprises first and second filter segments and an insertion tube at one end thereof for receiving and supporting a conventional filtered or unfiltered cigarette to be smoked. The first filter segment contains a carbonaceous material for removing gas phase components of the mainstream cigarette smoke. The total pressure drop across the filter attachment is very low, e.g., less than about 15 mm of water at 17.5 cc/sec air flow and preferably in the range of about 3 mm to about 12 mm of water at 17.5 cc/sec air flow.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: November 11, 1997
    Assignee: R. J. Reynolds Tobacco Company
    Inventors: Evon Llewellyn Crooks, Barry Smith Fagg, Annette Snow Ludolf, Dennis Lee Potter
  • Patent number: 5676163
    Abstract: The invention is concerned with a process for counteracting smoke malodour wherein enclosed air spaces wherein smoke maladour is present, or substrates on which smoke malodour has deposited are brought in contact with one or more perfumery aldehydes of the class I according to general structure, wherein R1 and R2 each may be: hydrogen, alkyl, hydroxyl or alkoxy, or together may be methylenedioxy or with a perfume containing such aldehydes. Preferably the perfume also contains one or more perfumery aldehydes of class according to general structure, wherein R1 is a phenyl ring optionally substituted with an alkyl group, R2 represents hydrogen or both R2 taken together represent a double bond, and R3 is hydrogen or an alkyl chain with 1 to 6 carbon atoms. The smoke malodour counteracting perfumes preferably contain at least 3.5% w/w of class I aldehydes and at least 10% w/w of class II aldehydes.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: October 14, 1997
    Assignee: Quest International BV
    Inventors: John Martin Behan, Julie Anne Goodall, Keith Douglas Perring, Christopher Charles Piddock, Alan Forbes Provan
  • Patent number: 5671758
    Abstract: tobacco filled smoking article adopted to produce less toxic substances such as carbon monoxide in the combustion gases, adding solid inert, stable non polluting catalysts in or near the tobacco, causing substantial catalytic reduction of carbon monoxide in the combustion gases.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: September 30, 1997
    Inventor: Paul I. Rongved
  • Patent number: 5657772
    Abstract: A filter for a smoking article incorporating particles coated with platinum selectively reduces the amount of volatiles of mainstream smoking article smoke passing through the filter. The platinum may be a continuous or discontinuous coating, usually on a coating of another metal, and this coating(s) will usually encapsulate the particle substrate. This substrate may be low activity activated carbon.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: August 19, 1997
    Assignee: Rothmans International Services Limited
    Inventors: Martin Graham Duke, Edward Dennis John
  • Patent number: 5507304
    Abstract: A blend of cellulose acetate and starch acetate used to make fibers, filaments, yarns, fabrics, plastic materials and other uses is disclosed. Additionally, the invention relates to the process of making said blend; cigarette filters made from tow composed of said blend; cigarettes made with filters made from tow of said blend as well as acetate flake and other compositions containing said blend.
    Type: Grant
    Filed: September 5, 1995
    Date of Patent: April 16, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: Joanne C. Maheras, John B. Hopkins, Jr., Heribert Tetzlaff