Group V Metal Containing (v, As, Nb, Sb, Ta, Bi) Patents (Class 136/240)
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Patent number: 11411155Abstract: A thermoelectric conversion material includes a sintered body including a main phase including a plurality of crystal grains including Ce, Mn, Fe, and Sb and forming a skutterudite structure, and a grain boundary between crystal grains adjacent to each other. The grain boundary includes a sintering aid phase including at least Mn, Sb, and O. Thus, with respect to a skutterudite-type thermoelectric conversion material including Sb, which is a sintering-resistant material, it is possible to improve sinterability while maintaining a practical dimensionless figure-of-merit ZT, and to reduce processing cost.Type: GrantFiled: September 25, 2019Date of Patent: August 9, 2022Assignee: HITACHI METALS, LTD.Inventors: Michiko Matsuda, Takeshi Shimada, Yoshihiro Kamitani
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Patent number: 10177295Abstract: The present invention relates to a P-type high-performance thermoelectric material featuring reversible phase change, and a preparation method therefor. The thermoelectric material has a chemical composition of Cu2Se1-xIx, wherein 0<x?0.08. The method comprises: weighing elemental copper metal, elemental selenium metal, and cuprous iodide according to the molar ratio (2?x):(1?x):x, and packaging them in a vacuum; raising the temperature to 1150-1170° C. in stages and performing a melting treatment for 12-24 hours; lowering the temperature to 600-700° C. in stages and then performing an annealing treatment for 5-7 days, the substances being cooled to room temperature in a furnace after the annealing treatment; and performing pressure sintering at 400-500° C.Type: GrantFiled: May 29, 2014Date of Patent: January 8, 2019Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCESInventors: Xun Shi, Huili Liu, Lidong Chen
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Patent number: 10134970Abstract: In the present disclosure, disclosed are a novel compound semiconductor which can be used as a thermoelectric material or the like, and applications thereof. A compound semiconductor according to the present disclosure can be represented by the following chemical formula 1: <Chemical formula 1>[Bi1-xMxCuu-wTwOa-yQ1yTebSez]Ac, where, in the chemical formula 1, M is one or more elements selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb; Q1 is one or more elements selected from the group consisting of S, Se, As and Sb; T is one or more elements selected from transition metal elements; A is one or more elements selected from the group consisting of transition metal elements and compounds of transition metal elements and group VI elements; and 0?x<1, 0.5?u?1.5, 0?w?1, 0.2<a<1.5, 0?y<1.5, 0?b<1.5, 0?z<1.5 and 0<c<0.2.Type: GrantFiled: November 28, 2014Date of Patent: November 20, 2018Assignee: LG CHEM, LTD.Inventors: O-Jong Kwon, Tae-Hoon Kim, Cheol-Hee Park, Kyung-Moon Ko
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Patent number: 9957602Abstract: The invention relates to a method for producing thermoelectric layers by depositing thermoelectric material on a substrate by means of sputter deposition. In order to create a method for producing thermoelectric layers that are better suited for use in thermogenerators, and in particular have higher Seebeck coefficients, the production of a target made of thermoelectric material is proposed by mixing at least two powdered starting materials having a particle size from 0.01 ?m-5000 ?m, while coupling in energy and depositing the thermoelectric material from the target on the substrate by way of magnetron sputter deposition.Type: GrantFiled: June 10, 2010Date of Patent: May 1, 2018Assignee: MAHLE INTERNATIONAL GMBHInventors: Ralph Teunissen, Gerhard Span
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Patent number: 9722164Abstract: Disclosed are methods for the manufacture of n-type and p-type filled skutterudite thermoelectric legs of an electrical contact. A first material of CoSi2 and a dopant are ball-milled to form a first powder which is thermo-mechanically processed with a second powder of n-type skutterudite to form a n-type skutterudite layer disposed between a first layer and a third layer of the doped-CoSi2. In addition, a plurality of components such as iron, and nickel, and at least one of cobalt or chromium are ball-milled form a first powder that is thermo-mechanically processed with a p-type skutterudite layer to form a p-type skutterudite layer “second layer” disposed between a first and a third layer of the first powder. The specific contact resistance between the first layer and the skutterudite layer for both the n-type and the p-type skutterudites subsequent to hot-pressing is less than about 10.0 ??·cm2.Type: GrantFiled: October 2, 2015Date of Patent: August 1, 2017Assignees: UNIVERSITY OF HOUSTON SYSTEM, MASSACHUSETTS INSTITUTE OF TECHNOLOGYInventors: Qing Jie, Zhifeng Ren, Gang Chen
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Patent number: 9561959Abstract: Disclosed is a new compound semiconductor material which may be used for thermoelectric material or the like, and its applications. The compound semiconductor may be represented by Chemical Formula 1 below: Chemical Formula 1 Bi1-xMxCu1-wTwOa-yQ1yTebSez where, in Chemical Formula 1, M is at least one selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb, Q1 is at least one selected from the group consisting of S, Se, As and Sb, T is at least one selected from the group consisting of transition metal elements, 0?x<1, 0<w<1, 0.2<a<1.5, 0?y<1.5, 0?b<1.5 and 0?z<1.5.Type: GrantFiled: October 6, 2014Date of Patent: February 7, 2017Assignee: LG CHEM, LTD.Inventors: O-Jong Kwon, Tae-Hoon Kim, Cheol-Hee Park, Kyung-Moon Ko, Chan-Yeup Chung
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Patent number: 9444028Abstract: Systems and methods are operable to generate electric power from heat. An exemplary direct thermal electric converter embodiment includes at least a first recombination material having a first recombination rate, a second recombination material adjacent to the first recombination material and having a second recombination rate, wherein the second recombination rate is different from the first recombination rate, and a third recombination material adjacent to the second recombination material and having a third recombination rate substantially the same as the first recombination rate. Application of heat generates at least first charge carriers that migrate between the first recombination material and the second recombination material, and generates at least second charge carriers that migrate between the third recombination material and the second recombination material. The migration of the first charge carriers and the migration of the second charge carriers generates an electrical current.Type: GrantFiled: January 6, 2014Date of Patent: September 13, 2016Inventor: Peter Milon Orem
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Publication number: 20150122303Abstract: The present invention provides a thermoelectric conversion material having a low thermal conductivity and having an improved figure of merit, and a method for producing it. The thermoelectric conversion material has, as formed on a substrate having a nano-level microporous nanostructure, a thermoelectric semiconductor layer prepared by forming a thermoelectric semiconductor material into a film, wherein the substrate is a block copolymer substrate formed of a block copolymer that comprises a polymethyl methacrylate unit and a polyhedral oligomeric silsesquioxane-containing polymethacrylate unit, and the thermoelectric semiconductor material is a p-type bismuth telluride or an n-type bismuth telluride. The production method comprises a substrate formation step of forming the nanostructure-having block copolymer substrate, and a film formation step of forming a p-type bismuth telluride or an n-type bismuth telluride into a film to thereby provide a thermoelectric semiconductor layer.Type: ApplicationFiled: February 19, 2013Publication date: May 7, 2015Applicants: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, LINTEC CORPORATIONInventors: Kunihisa Kato, Chihaya Adachi, Koji Miyazaki, Teruaki Hayakawa
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Publication number: 20150114441Abstract: A thermoelectric material including a thermoelectric matrix; and nano-inclusions in the thermoelectric matrix, the nano-inclusions having an average particle diameter of about 10 nanometers to about 30 nanometers.Type: ApplicationFiled: December 30, 2014Publication date: April 30, 2015Inventors: Sang-il KIM, Kyu-hyoung LEE
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Patent number: 9011763Abstract: The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nano-sized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5kBT, wherein kB is the Boltzman constant and T is an average temperature of said nanocomposite composition.Type: GrantFiled: September 20, 2012Date of Patent: April 21, 2015Assignees: Massachusetts Institute of Technology, Trustees of Boston CollegeInventors: Gang Chen, Mildred Dresselhaus, Zhifeng Ren
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Patent number: 9012760Abstract: A thermoelectric device, a method for fabricating a thermoelectric device and electrode materials applied to the thermoelectric device are provided according to the present invention. The present invention is characterized in arranging thermoelectric material power, interlayer materials and electrode materials in advance according to the structure of thermoelectric device; adopting one-step sintering method to make a process of forming bulked thermoelectric materials and a process of combining with electrodes on the devices to be completed simultaneously; and obtaining a ? shape thermoelectric device finally. Electrode materials related to the present invention comprise binary or ternary alloys or composite materials, which comprise at least a first metal selected from Cu, Ag, Al or Au, and a second metal selected from Mo, W, Zr, Ta, Cr, Nb, V or Ti.Type: GrantFiled: March 25, 2010Date of Patent: April 21, 2015Assignee: Shanghai Institute of Ceramics, Chinese Academy of SciencesInventors: Lidong Chen, Monika Backhaus-Ricoult, Lin He, Xiaoya Li, Yunshan Tang, Xugui Xia, Degang Zhao
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Patent number: 8986566Abstract: A thermoelectric material including a composition according to Chemical Formula 1: (Bia-xSb1-a-yMb)2-i(TecSe1-c)3-j??Chemical Formula 1 wherein M is an element of Group 13, 0?a?1, 0<b?0.004, 0?x?b, 0?y?b, x+y=b, 0?c?1, ?0.2?i?0.2, and ?0.2?j?0.2.Type: GrantFiled: June 7, 2012Date of Patent: March 24, 2015Assignee: Samsung Electronics Co., Ltd.Inventors: Kyu-hyoung Lee, Sung-woo Hwang, Sang-il Kim, Sang-mock Lee, Kyung-han Ahn
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Patent number: 8968589Abstract: A composite material comprises a filled skutterudite matrix of formula (I) IyCo4Sb12 in which (I) represents at least one of Yb, Eu, Ce, La, Nd, Ba and Sr, 0.05?y<1; and GaSb particles within the filled skutterudite matrix, wherein the composite material comprises 0.05-5 mol % GaSb particles. Compared with conventional materials, the composite material exhibits a substantially increased Seebeck coefficient, a slightly decreased overall thermal conductivity, and a substantially increased thermoelectric performance index across the whole temperature zone from the low temperature end to the high temperature end, as well as a greatly enhanced thermoelectric efficiency.Type: GrantFiled: September 23, 2010Date of Patent: March 3, 2015Assignee: Shanghai Institute of Ceramics, Chinese Academy of SciencesInventors: Lidong Chen, Xihong Chen, Lin He, Xiangyang Huang, Zhen Xiong, Wenqing Zhang
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Publication number: 20150013741Abstract: The present invention provides a thermoelectric conversion material of which the structure is controlled to have nano-order microscopic pores and which has a low thermal conductivity and has an improved thermoelectric performance index. In the thermoelectric conversion material having a thermoelectric semiconductor layer formed on a block copolymer substrate that comprises a block copolymer having microscopic pores, wherein the block copolymer comprises a polymer unit (A) formed of a monomer capable of forming a homopolymer having a glass transition temperature of 50° C. or higher, and a polymer unit (B) formed of a conjugated dienic polymer.Type: ApplicationFiled: February 19, 2013Publication date: January 15, 2015Applicants: KYUSHU INSTITUTE OF TECHNOLOGY, LINTEC CORPORATIONInventors: Tsuyoshi Mutou, Koji Miyazaki, Yoshika Hatasako, Kunihisa Kato
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Patent number: 8933318Abstract: A thermoelectric material including a compound represented by Formula 1 below: (R1-aR?a)(T1-bT?b)3±y??Formula 1 wherein R and R? are different from each other, and each includes at least one element selected from a rare-earth element and a transition metal, T and T? are different from each other, and each includes at least one element selected from sulfur (S), selenium (Se), tellurium (Te), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), carbon (C), silicon (Si), germanium (Ge), tin (Sn), boron (B), aluminum (Al), gallium (Ga), and indium (In), 0?a?1, 0?b?1, and 0?y<1.Type: GrantFiled: March 31, 2011Date of Patent: January 13, 2015Assignee: Samsung Electronics Co., Ltd.Inventors: Jong-soo Rhyee, Sang-mock Lee
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Patent number: 8865995Abstract: Thermoelectric materials with high figures of merit, ZT values, are disclosed. In many instances, such materials include nano-sized domains (e.g., nanocrystalline), which are hypothesized to help increase the ZT value of the material (e.g., by increasing phonon scattering due to interfaces at grain boundaries or grain/inclusion boundaries). The ZT value of such materials can be greater than about 1, 1.2, 1.4, 1.5, 1.8, 2 and even higher. Such materials can be manufactured from a thermoelectric starting material by generating nanoparticles therefrom, or mechanically alloyed nanoparticles from elements which can be subsequently consolidated (e.g., via direct current induced hot press) into a new bulk material. Non-limiting examples of starting materials include bismuth, lead, and/or silicon-based materials, which can be alloyed, elemental, and/or doped. Various compositions and methods relating to aspects of nanostructured thermoelectric materials (e.g., modulation doping) are further disclosed.Type: GrantFiled: December 3, 2007Date of Patent: October 21, 2014Assignees: Trustees of Boston College, Massachusetts Institute of TechnologyInventors: Zhifeng Ren, Bed Poudel, Gang Chen, Yucheng Lan, Dezhi Wang, Qing Hao, Mildred Dresselhaus, Yi Ma, Xiao Yan, Xiaoyuan Chen, Xiaowei Wang, Joshi R. Giri, Bo Yu
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Patent number: 8853519Abstract: In order to achieve a thermoelectric transducer exhibiting a higher conversion efficiency and an electronic apparatus including such a thermoelectric transducer, a thermoelectric conversion device is provided, including a semiconductor stacked structure including semiconductor layers stacked with each other, the semiconductor layers being made from different semiconductor materials, in which a material and a composition of each semiconductor layer in the semiconductor stacked structure are selected so as to avoid conduction-band or valence-band discontinuity.Type: GrantFiled: May 26, 2011Date of Patent: October 7, 2014Assignee: Fujitsu LimitedInventor: Taisuke Iwai
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Patent number: 8841540Abstract: In accordance with one embodiment of the present disclosure, a thermoelectric device includes a plurality of thermoelectric elements that each include a diffusion barrier. The diffusion barrier includes a refractory metal. The thermoelectric device also includes a plurality of conductors coupled to the plurality of thermoelectric elements. The plurality of conductors include aluminum. In addition, the thermoelectric device includes at least one plate coupled to the plurality of thermoelectric elements using a braze. The braze includes aluminum.Type: GrantFiled: August 3, 2011Date of Patent: September 23, 2014Assignee: Marlow Industries, Inc.Inventors: Joshua E. Moczygemba, James L. Bierschenk, Jeffrey W. Sharp
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Patent number: 8829324Abstract: A transverse thermoelectric device includes a superlattice body, electrically conductive first and second contacts, and first and second thermal contacts. The superlattice body extends between opposite first and second ends along a first direction and between opposite first and second sides along a different, second direction. The superlattice body includes alternating first and second layers of crystalline materials oriented at an oblique angle relative to the first direction. The electrically conductive first contact is coupled with the first end of the superlattice and the electrically conductive second contact is coupled with the second end of the superlattice. The first thermal contact is thermally coupled to the first side of the superlattice and the second thermal contact is thermally coupled to the second side of the superlattice. A Seebeck tensor of the superlattice body is ambipolar.Type: GrantFiled: January 7, 2013Date of Patent: September 9, 2014Assignee: Northwestern UniversityInventors: Matthew Grayson, Chaunle Zhou
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Patent number: 8801953Abstract: The inventors demonstrate herein that various Zintl compounds can be useful as thermoelectric materials for a variety of applications. Specifically, the utility of Ca3AlSb3, Ca5Al2Sb6, Ca5In2Sb6, Ca5Ga2Sb6, is described herein. Carrier concentration control via doping has also been demonstrated, resulting in considerably improved thermoelectric performance in the various systems described herein.Type: GrantFiled: October 19, 2011Date of Patent: August 12, 2014Assignee: California Institute of TechnologyInventors: G. Jeffrey Snyder, Eric Toberer, Alex Zevalkink
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Patent number: 8795545Abstract: A thermoelectric material and a method of making a thermoelectric material are provided. In certain embodiments, the thermoelectric material comprises at least 10 volume percent porosity. In some embodiments, the thermoelectric material has a zT greater than about 1.2 at a temperature of about 375 K. In some embodiments, the thermoelectric material comprises a topological thermoelectric material. In some embodiments, the thermoelectric material comprises a general composition of (Bi1-xSbx)u(Te1-ySey)w, wherein 0?x?1, 0?y?1, 1.8?u?2.2, 2.8?w?3.2. In further embodiments, the thermoelectric material includes a compound having at least one group IV element and at least one group VI element. In certain embodiments, the method includes providing a powder comprising a thermoelectric composition, pressing the powder, and sintering the powder to form the thermoelectric material.Type: GrantFiled: March 30, 2012Date of Patent: August 5, 2014Assignees: ZT Plus, The Ohio State UniversityInventors: Joseph P. Heremans, Christopher M. Jaworski, Vladimir Jovovic, Fred Harris
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Patent number: 8791353Abstract: Alumina as a sublimation suppression barrier for a Zintl thermoelectric material in a thermoelectric power generation device operating at high temperature, e.g. at or above 1000K, is disclosed. The Zintl thermoelectric material may comprise Yb14MnSb11. The alumina may be applied as an adhesive paste dried and cured on a substantially oxide free surface of the Zintl thermoelectric material and polished to a final thickness. The sublimation suppression barrier may be finalized by baking out the alumina layer on the Zintl thermoelectric material until it becomes substantially clogged with ytterbia.Type: GrantFiled: March 12, 2010Date of Patent: July 29, 2014Assignee: California Institute of TechnologyInventors: Jong-Ah Paik, Thierry Caillat
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Publication number: 20140166065Abstract: A structure of a thermoelectric film including a thermoelectric substrate and a pair of first diamond-like carbon (DLC) layers is provided. The first DLC layers are respectively located on two opposite surfaces of the thermoelectric substrate and have electrical conductivity.Type: ApplicationFiled: March 13, 2013Publication date: June 19, 2014Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Ming-Sheng Leu, Tai-Sheng Chen, Chih-Chao Shih
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Patent number: 8748726Abstract: According to various aspects, exemplary embodiments are provided of thermoelectric materials, which embodiments may have improved figure of merit. In one exemplary embodiment, a thermoelectric material generally includes bismuth telluride nanoparticles, which may be undoped or doped with at least one or more of silver, antimony, tin, and/or a combination thereof. The bismuth telluride nanoparticles may be dispersed in a matrix material comprising particulate bismuth telluride. Methods for making undoped and doped bismuth telluride nanoparticles are also disclosed, which may include a solvothermal method for making bismuth telluride nanoparticles having a size ranging from 1 to 200 nanometers.Type: GrantFiled: February 16, 2012Date of Patent: June 10, 2014Assignee: Laird Technologies, Inc.Inventors: Arup Purkayastha, Purushottam Joshi
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Patent number: 8715538Abstract: Thermoelectric conversion materials, expressed by the following formula: Bi1-xMxCuwOa-yQ1yTeb-zQ2z. Here, M is at least one element selected from the group consisting of Ba, Sr, Ca, Mg, Cs, K, Na, Cd, Hg, Sn, Pb, Mn, Ga, In, Tl, As and Sb; Q1 and Q2 are at least one element selected from the group consisting of S, Se, As and Sb; x, y, z, w, a, and b are 0?x<1, 0<w?1, 0.2<a<4, 0?y<4, 0.2<b<4 and 0?z<4. These thermoelectric conversion materials may be used for thermoelectric conversion elements, where they may replace thermoelectric conversion materials in common use, or be used along with thermoelectric conversion materials in common use.Type: GrantFiled: June 22, 2012Date of Patent: May 6, 2014Assignee: LG Chem, Ltd.Inventors: Cheol-Hee Park, Se-Hui Sohn, Seung-Tae Hong, Won-Jong Kwon, Tae-Hoon Kim
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Patent number: 8692106Abstract: The invention is a bulk-processed thermoelectric material and a method for fabrication. The material measures at least 30 microns in each dimension and has a figure of merit (ZT) greater than 1.0 at any temperature less than 200° C. The material comprises at least two constituents; a host phase and a dispersed second phase. The host phase is a semiconductor or semimetal and the dispersed phase of the bulk-processed material is comprised of a plurality of inclusions. The material has a substantially coherent interface between the host phase and the dispersed phase in at least one crystallographic direction.Type: GrantFiled: December 7, 2009Date of Patent: April 8, 2014Assignee: Carrier CorporationInventors: Rhonda R. Willigan, Susanne M. Opalka, Joseph V. Mantese, Slade R. Culp, Jefferi J. Covington
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Patent number: 8684114Abstract: An improved circular multi-element semiconductor thermoelectric hybrid utilizes a make-before-break high frequency switching output component to provide nominal alternating current voltage outputs. Overall efficiency of heat conversion is improved by coupling a chiller to the thermoelectric generator where exhaust heat produces chilled liquid or air that is conveyed to the cold side of the thermoelectric device. The thermoelectric generator is used in a variety of transportation vehicles including manufactured vehicles, retrofitted vehicles and vehicle power combinations.Type: GrantFiled: March 26, 2012Date of Patent: April 1, 2014Inventors: Jon Murray Schroeder, Gerald Phillip Hirsch
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Patent number: 8664509Abstract: A thermoelectric apparatus includes a first and a second assemblies, at least a first and a second heat conductors. The first assembly includes a first and a second substrates, and several first thermoelectric material sets disposed between the first and second substrates. The first substrate has at least a first through hole. The second assembly includes a third and a fourth substrates, and several second thermoelectric material sets disposed between the third and fourth substrates. The fourth substrate has at least a second through hole. Each of the first and second thermoelectric material sets has a p-type and an n-type thermoelectric element. The first and second heat conductors respectively penetrate the first and second through holes. Two ends of the first heat conductor respectively connect the second and fourth substrates, while two ends of the second heat conductor respectively connect the first and third substrates.Type: GrantFiled: March 4, 2011Date of Patent: March 4, 2014Assignee: Industrial Technology Research InstituteInventors: Chun-Kai Liu, Ming-Ji Dai, Suh-Yun Feng, Li-Ling Liao
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Patent number: 8658880Abstract: A method of drawing a glass clad wire is provided herein, the method comprising: (i) sealing off one end of a glass tube such that the tube has an open end and a closed end; (ii) introducing a wire material inside the glass tube; (iii) heating a portion of the glass tube such that the glass partially melts to form a first ampoule containing the wire material to be used in a drawing operation; (iv) introducing the first ampoule containing the wire material into a heating device; (v) increasing the temperature within the heating device such that the glass tube is heated enough for it to be drawn and wire material melts; and (vi) drawing the glass clad wire comprising a continuous wire of wire material, wherein the wire material is a metal, semi-metal, alloy, or semiconductor thermoelectrically active material, and wherein the wire diameter is equal to or smaller than about 5 ?m.Type: GrantFiled: June 12, 2009Date of Patent: February 25, 2014Assignee: ZT3 Technologies, Inc.Inventors: Biprodas Dutta, Ian L. Pegg, Sezhian Annamalai, Rudra P. Bhatta, Jugdersuren Battogtokh
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Patent number: 8637758Abstract: Disclosed is a thermoelectric material which is represented by the following composition formula (1) or (2) and comprises as a major phase an MgAgAs type crystal structure: (Tia1Zrb1Hfc1)xNiySn100-x-y??composition formula (1); (Lnd(Tia2Zrb2Hfc2)1-d)xNiySn100-x-y??composition formula (2); (wherein a1, b1, c1, x and y satisfy the conditions of: 0<a1<1, 0<b1<1, 0<c1<1, a1+b1+c1=1, 30?x?35 and 30?y?35, and Ln is at least one element selected from the group consisting of Y and rare earth elements, and a2, b2, c2 and d satisfy the conditions of: 0?a2?1, 0?b2?1, 0?c2?1, a2+b2+c2=1 and 0<d?0.3).Type: GrantFiled: October 24, 2011Date of Patent: January 28, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Naoki Shutoh, Shinya Sakurada, Naruhito Kondo, Nobuhisa Takezawa
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Publication number: 20130319495Abstract: The present invention relates to a thermoelectric device using a bulk material of a nano type, a thermoelectric module having the thermoelectric device and a method of manufacturing thereof. According to the present invention, thin film of a nano thickness is formed on a bulk material formed as several nano types to be re-connected for prohibiting the phonon course.Type: ApplicationFiled: January 20, 2012Publication date: December 5, 2013Applicant: LG INNOTEK CO., LTD.Inventors: Se Joon Kim, Jong Bae Shin
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Patent number: 8591758Abstract: The present invention provides a method of making a substantially phase pure compound including a cation and an anion. The compound is made by mixing in a ball-milling device a first amount of the anion with a first amount of the cation that is less than the stoichiometric amount of the cation, so that substantially all of the first amount of the cation is consumed. The compound is further made by mixing in a ball-milling device a second amount of the cation that is less than the stoichiometric amount of the cation with the mixture remaining in the device. The mixing is continued until substantially all of the second amount of the cation and any unreacted portion of anion X are consumed to afford the substantially phase pure compound.Type: GrantFiled: June 8, 2011Date of Patent: November 26, 2013Assignee: California Institute of TechnologyInventors: Jean-Pierre Fleurial, Sabah K. Bux, Richard B. Kaner
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Patent number: 8563844Abstract: Embodiments of a thin-film heterostructure thermoelectric material and methods of fabrication thereof are disclosed. In general, the thermoelectric material is formed in a Group IIa and IV-VI materials system. The thermoelectric material includes an epitaxial heterostructure and exhibits high heat pumping and figure-of-merit performance in terms of Seebeck coefficient, electrical conductivity, and thermal conductivity over broad temperature ranges through appropriate engineering and judicious optimization of the epitaxial heterostructure.Type: GrantFiled: March 9, 2012Date of Patent: October 22, 2013Assignees: Phononic Devices, Inc., Board of Regents of the University of OklahomaInventors: Allen L. Gray, Robert Joseph Therrien, Patrick John McCann
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Patent number: 8551441Abstract: New methods for improving thermoelectric properties of bismuth telluride based materials are described. Constrained deformation, such as by canned/sandwich, or encapsulated, rolling and plane strain channel die compression, particularly at temperatures above 80% of the melting point of the material on an absolute temperature scale, changes the crystallographic texture and grain size to desirably increase the values of both the thermoelectric power factor and the thermoelectric figure of merit ZT for the material.Type: GrantFiled: May 11, 2012Date of Patent: October 8, 2013Assignee: United States of America as represented by the Secretary of the Air ForceInventors: Raghavan Srinivasan, Jonathan E. Spowart, Nicholas Gothard
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Publication number: 20130247953Abstract: Thermoelectric devices and associated materials and assembly methods are generally described. Certain aspects relate to electrode materials and electrode configurations for use in thermoelectric devices. In some embodiments, the inventive thermoelectric devices comprise electrodes comprising silicon, such as silicides of cobalt, iron, and/or nickel. Such electrode materials can be useful for making electrical contact with a wide variety of thermoelectric materials, including skutterudite materials. The thermoelectric devices described herein can be used to convert applied voltages to thermal gradients and or to convert thermal gradients to electricity.Type: ApplicationFiled: March 23, 2012Publication date: September 26, 2013Applicants: Trustees of Boston College, Massachusetts Institute of TechnologyInventors: Andrew Muto, Gang Chen, Zhifeng Ren
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Patent number: 8535637Abstract: Disclosed is a new thermoelectric conversion material represented by the chemical formula 1: Bi1-xCu1-yO1-zTe, where 0?x<1, 0?y<1, 0?z<1 and x+y+z>0. A thermoelectric conversion device using said thermoelectric conversion material has good energy conversion efficiency.Type: GrantFiled: May 3, 2012Date of Patent: September 17, 2013Assignee: LG Chem, Ltd.Inventors: Cheol-Hee Park, Se-Hui Sohn, Won-Jong Kwon, Seung-Tae Hong, Tae-Hoon Kim
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Patent number: 8535554Abstract: A process for forming thermoelectric nanoparticles includes the steps of providing a core material and a bismuth containing compound in a reverse micelle; providing a tellurium containing compound either in or not in a reverse micelle; reacting the bismuth containing compound with the tellurium containing compound in the presence of a base, forming a composite thermoelectric nanoparticle having a core and shell structure.Type: GrantFiled: July 27, 2010Date of Patent: September 17, 2013Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Michael Paul Rowe, Minjuan Zhang, Paul Jantzen
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Patent number: 8524106Abstract: A thermoelectric material of the p-type having the stoichiometric formula Zn4Sb3, wherein part of the Zn atoms optionally being substituted by one or more elements selected from the group comprising Sn, Mg, Pb and the transition metals in a total amount of 20 mol % or less in relation to the Zn atoms is provided by a process involving zone-melting of a an arrangement comprising an interphase between a “stoichiometric” material having the desired composition and a “non-stoichiometric” material having a composition deviating from the desired composition. The thermoelectric materials obtained exhibit excellent figure of merits.Type: GrantFiled: July 13, 2011Date of Patent: September 3, 2013Assignees: Aarhus Universitet, Deutsches Zentrum für Luft- und Raumfahrt Advanced TechnologyInventors: Bo Brummerstedt Iversen, Britta Lundtoft, Mogens Christensen, Dieter Platzek
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Patent number: 8519256Abstract: T provide an N type thermoelectric material having figure of the merit improved to be comparable to or higher than that of P type thermoelectric material, the N type thermoelectric material of the present invention contains at least one kind of Bi and Sb and at least one kind of Te and Se as main components, and contains bromine (Br) and iodine (I) to have carrier in such a concentration that corresponds to the contents of bromine (Br) and iodine (I).Type: GrantFiled: September 7, 2011Date of Patent: August 27, 2013Assignee: Kyocera CorporationInventors: Kenichi Tajima, Koichi Tanaka
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Publication number: 20130180560Abstract: A thermoelectric structure including a thermoelectric material having a thickness less than 50 nm and a semi-insulating material in electrical contact with the thermoelectric material. The thermoelectric material and the semi-insulating materials have an equilibrium Fermi level, across a junction between the thermoelectric material and the semi-insulating material, which exists in a conduction band or a valence band of the thermoelectric material. The thermoelectric structure is for thermoelectric cooling and thermoelectric power generation.Type: ApplicationFiled: December 21, 2012Publication date: July 18, 2013Applicant: RESEARCH TRIANGLE INSTITUTEInventor: RESEARCH TRIANGLE INSTITUTE
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Patent number: 8487178Abstract: A thermoelectric material including a body centered cubic filled skutterudite having the formula AxFeyNizSb12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.Type: GrantFiled: January 14, 2011Date of Patent: July 16, 2013Assignee: UT-Battelle, LLCInventor: David Joseph Singh
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Publication number: 20130174884Abstract: A transverse thermoelectric device includes a superlattice body, electrically conductive first and second contacts, and first and second thermal contacts. The superlattice body extends between opposite first and second ends along a first direction and between opposite first and second sides along a different, second direction. The superlattice body includes alternating first and second layers of crystalline materials oriented at an oblique angle relative to the first direction. The electrically conductive first contact is coupled with the first end of the superlattice and the electrically conductive second contact is coupled with the second end of the superlattice. The first thermal contact is thermally coupled to the first side of the superlattice and the second thermal contact is thermally coupled to the second side of the superlattice. A Seebeck tensor of the superlattice body is ambipolar.Type: ApplicationFiled: January 7, 2013Publication date: July 11, 2013Applicant: Northwestern UniversityInventor: Northwestern University
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Patent number: 8481843Abstract: A thermoelectric composition comprises a material represented by the general formula (AgaX1?a)1±x(SnbPb1?b)mM?1?yQ2+m wherein X is Na, K, or a combination of Na and K in any proportion; M? is a trivalent element selected from the group consisting of Sb, Bi, lanthanide elements, and combinations thereof; Q is a chalcogenide element selected from the group consisting of S, Te, Se, and combinations thereof; a and b are independently >0 and ?1; x and y are independently >0 and <1; and 2?m?30. The compositions exhibit a figure of merit ZT of up to about 1.4 or higher, and are useful as p-type semiconductors in thermoelectric devices.Type: GrantFiled: August 31, 2004Date of Patent: July 9, 2013Assignee: Board of Trustees Operating Michigan State UniversityInventors: Mercouri G. Kanatzidis, Kuei-Fang Hsu
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Publication number: 20130167893Abstract: A thermoelectric material has a Heusler alloy type crystal structure and is based on an Fe2VAl basic structure having a total number of valence electrons of 24 per chemical formula. The thermoelectric material has a structure expressed by General Formula Fe2V1?ZAl1+Z, where 0.03?z?0.12, or General Formula Fe2V1?ZAl1+Z, where ?0.12?z??0.03, by controlling its chemical compositional ratio. The former acts as a p-type material and has a Seebeck coefficient whose absolute value reaches a peak at a temperature of 400 K or higher; and the latter acts as an n-type material and has a Seebeck coefficient whose absolute value reaches a peak at a temperature of 310 K or higher.Type: ApplicationFiled: September 7, 2011Publication date: July 4, 2013Applicant: NATIONAL UNIVERSITY CORPORATION NAGOYA INSTITUTE OF TECHNOLOGYInventors: Yoichi Nishino, Suguru Tanaka
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Publication number: 20130139864Abstract: Provided is a thermoelectric device including two legs having a rough side surface and a smooth side surface facing each other. Phonons may be scattered by the rough side surface, thereby decreasing thermal conductivity of the device. Flowing paths for electrons and phonons may become different form each other, because of a magnetic field induced by an electric current passing through the legs. The smooth side surface may be used for the flowing path of electrons. As a result, in the thermoelectric device, thermal conductivity can be reduced and electric conductivity can be maintained.Type: ApplicationFiled: September 12, 2012Publication date: June 6, 2013Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTEInventors: Younghoon Hyun, Moon Gyu Jang, Young Sam Park, Taehyoung Zyung, Yil Suk Yang, Jong-Kee Kwon
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Patent number: 8455751Abstract: High performance thin film thermoelectric couples and methods of making the same are disclosed. Such couples allow fabrication of at least microwatt to watt-level power supply devices operating at voltages greater than one volt even when activated by only small temperature differences.Type: GrantFiled: December 2, 2003Date of Patent: June 4, 2013Assignee: Battelle Memorial InstituteInventors: Larry C. Olsen, Peter M. Martin, John W. Johnston, John G. DeSteese
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Patent number: 8383926Abstract: The thermoelectric structure is formed by a network of wires oriented substantially in a weft direction of the structure. It comprises first and second conducting wires of different kinds, interwoven to form cold and hot junctions distributed respectively in a top plane and a bottom plane. The junctions are alternately cold and hot along any one conducting wire. The thermoelectric structure comprises at least one high dielectric wire in the top plane, and at least one low dielectric wire in the bottom plane. The dielectric wires are interwoven with the first and second conducting wires so as to keep the top and bottom planes at a distance from one another.Type: GrantFiled: March 27, 2007Date of Patent: February 26, 2013Assignee: Commissariat a l'Energie AtomiqueInventors: Marc Plissonnier, Charles Salvi, Thierry Lanier, Denis Coulaux
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Publication number: 20130037071Abstract: A thermoelectric module which has at least one thermoelectric element for converting energy between thermal energy and electrical energy. The at least one thermoelectric element has a first surface and a second surface opposite the first surface. The thermoelectric module further has a first electrode, the first electrode having at least a first region which is arranged directly on the first surface and a second electrode, the second electrode having at least a second region which is arranged directly on the second surface. At least one of the first region and the second region has a metal alloy which exhibits an Invar effect.Type: ApplicationFiled: August 10, 2012Publication date: February 14, 2013Applicant: Vacuumschmelze GmbH & Co, KGInventors: Joachim Gerster, Alberto Bracchi, Michael Müller
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Publication number: 20130032190Abstract: A thermoelectric material including a thermoelectric semiconductor; and a nanosheet disposed in the thermoelectric semiconductor, the nanosheet having a layered structure and a thickness from about 0.1 to about 10 nanometers. Also a thermoelectric element and thermoelectric module including the thermoelectric material.Type: ApplicationFiled: July 31, 2012Publication date: February 7, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Sung-woo HWANG, Kyu-hyoung LEE, Sang-mock LEE
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Patent number: 8334450Abstract: A Seebeck solar cell device is disclosed, combining both photovoltaic and thermoelectric techniques. The device may be formed using, for example, a conventional photovoltaic cell formed from a doped silicon wafer. The material used to form conductors to the front and rear regions of the cell are chosen for their thermoelectric characteristics, including the sign, or polarity, of their Seebeck coefficients. The distal portion of each conductor is insulated from the solar and waste heat and, in some embodiments, is also coupled to a cooling mechanism. Multiple such devices can be connected in series or parallel.Type: GrantFiled: September 4, 2006Date of Patent: December 18, 2012Inventor: Joseph A. Micallef