Dye Or Organic Pigment Containing Patents (Class 148/244)
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Patent number: 11186728Abstract: A method to prevent corrosion of a susceptible article of a two-article system, in which first and second articles of the two-article system have surfaces facing one another and in which the two articles have different anodic indices includes applying a coating material to the surface of the first article and curing the coating material on the surface of the first article. The method further includes contacting and securing the surface of the first article with the surface of the second article. The two articles exhibit substantially no corrosion following exposure to a corrosive environment under standard GMW17026 for a 15 year simulated test.Type: GrantFiled: November 4, 2019Date of Patent: November 30, 2021Assignee: Nylok LLCInventors: Jeffrey M. Stupar, Franco A. Cisternino, Eugene D. Sessa, Robin F. Monahan
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Patent number: 11142827Abstract: A method for anti-corrosion pre-treatment of metal substrates using zirconium-based aqueous anti-corrosion agents comprising polycyclic hydrocarbons that have at least one anellated benzene ring, each having at least two ring-substituted hydroxyl groups in ortho position to each other. The aqueous anti-corrosion agent can be substantially free both of passivating chromium-containing compounds and of fluoride-containing compounds that pickle the metal substrate. Pre-treatment by drying (dry-in-place method) is especially advantageous. Accordingly, the method according to the invention is suitable in particular for the pre-treatment of metal strip, wherein excellent anti-corrosion results are achieved on surfaces of aluminum or steel. The invention further relates to a method for producing coated can lids from aluminum strip by using the previously mentioned zirconium-based anti-corrosion agent. A further aspect comprises an aqueous concentrate for providing the ready-to-use anti-corrosion agents.Type: GrantFiled: August 21, 2018Date of Patent: October 12, 2021Assignee: Henkel AG & Co. KGaAInventors: Joerg Riesop, Volker Geick
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Patent number: 10760176Abstract: Sealed anodic coatings that are resistant to leaching of nickel and nickel-containing products and methods for forming the same are described. Methods involve post-sealing thermal processes to remove at least some of the leachable nickel from the sealed anodic coatings. In some embodiments, the post-sealing thermal processes involve immersing the sealed anodic coating within a heated solution so as to promote diffusion of the leachable nickel out of the sealed anodic coatings and into the heated solution. The resultant sealed anodic coating is pre-leached of nickel and is therefore well suited for many consumer product applications. In some embodiments, a post-sealing thermal process is used to further hydrate and seal the sealed anodic coating, thereby repairing structural defects within the sealed anodic coating.Type: GrantFiled: July 9, 2015Date of Patent: September 1, 2020Assignee: APPLE INC.Inventors: James A. Curran, Eric W. Hamann, Sean R. Novak
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Patent number: 10662544Abstract: A surface treatment process for a metal article provides a uniform and unblemished surface finish to the metal article. The surface treatment process anodizes the metal article to form an anodic oxide layer on a surface, and the metal article is activated using a pre-dyeing solution. The pre-dyeing solution contains complex organic acid and sodium acetate. The anodic oxide layer of the metal article is dyed for color and the dyed anodic oxide layer of the metal article is finally sealed.Type: GrantFiled: January 8, 2018Date of Patent: May 26, 2020Assignees: HONGFUJIN PRECISION ELECTRONICS (CHENGDU) Co., Ltd., HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Xiao-Gang Peng, Kai Fang, Yong-De Pei, Cheng-Bin Bai, Wei Liu, Qi Wang
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Patent number: 10570519Abstract: The invention is directed to a conversion coating composition for coating a metal surface including a water soluble dye, at least one metal compound selected from the group consisting of a zirconium-containing compound, titanium-containing compound and silicon-containing compound; and water, wherein the provides for qualitative characterization of the conversion coating uniformity and thickness by the naked human eye or visible light detecting device; and, a method for coating the metal surfaces using the conversion coating composition.Type: GrantFiled: April 20, 2018Date of Patent: February 25, 2020Assignee: Momentive Performance Materials Inc.Inventor: Dmitry Chernyshov
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Patent number: 10519322Abstract: A corrosion inhibiting composition including a liquid carrier having a surface tension of at most about 35 dynes/cm and an electrically conductive nanomaterial dispersed in the carrier.Type: GrantFiled: August 9, 2016Date of Patent: December 31, 2019Assignee: The Boeing CompanyInventors: Lawrence M. Lawless, Bruce M. Griffin, Craig W. Scott
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Patent number: 10400127Abstract: Methods of preparing porous wood products for painting or finishing are described. The methods comprise applying to a porous wood product a UV-curable coating and curing by UV light the top UV curable coating to 70% to 95% cure, preferably 85% to 95% for spray-applied top UV curable coatings to produce a partially cured porous wood product. The methods typically further include the step of sanding the surface of the partially cured porous wood product and painting or staining, for example with a water-based or solvent-based stain or paint.Type: GrantFiled: January 5, 2018Date of Patent: September 3, 2019Assignee: Pressing Developments, L.L.C.Inventor: Adam Fuhr
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Patent number: 10287439Abstract: Carbonate pigment compositions are provided. In some instances, the pigment compositions are CO2 sequestering pigment compositions. Also provided are methods of making and using the pigment compositions, e.g., in paints and coatings, as well as other applications.Type: GrantFiled: February 27, 2017Date of Patent: May 14, 2019Assignee: Blue Planet, Ltd.Inventors: Brent R. Constantz, Seung-Hee Kang
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Patent number: 10208783Abstract: Disclosed herein is a method of manufacturing a wheel nut. The method includes annealing an aluminum (Al) alloy material and preheating the annealed Al alloy material. The Al alloy material is also forged to form a wheel nut. Furthermore, the method includes performing an anodizing treatment to form a primary coating on the wheel nut and performing a vacuum deposition to form a secondary coating on the wheel nut. In addition, the method includes performing a surface treatment using powder paint to form a tertiary coating on the wheel nut.Type: GrantFiled: November 19, 2015Date of Patent: February 19, 2019Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Chul Hong Bae, Kwang Min Yoon, Young Chan Kim
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Patent number: 9598790Abstract: Provided is a pellicle frame that can prevent generation of haze and reduces a surface glittering defect under irradiation with collected light, and a method of manufacturing the same. The pellicle frame is obtained by using an aluminum frame material having a structure satisfying predetermined conditions on the circle-equivalent diameters of a Mg2Si crystallized product, an AlCuMg crystallized product, an Al—Fe-based crystallized product (AlmFe or Al7Cu2Fe), and an Al2CuMg crystallized product and on the area ratios of those crystallized products each having a circle-equivalent diameter of 1 ?m or more, and in addition, subjecting the aluminum frame material to anodic oxidation processing using an alkaline electrolytic solution containing as an electrolyte a predetermined organic acid salt.Type: GrantFiled: November 27, 2013Date of Patent: March 21, 2017Assignee: NIPPON LIGHT METAL COMPANY, LTD.Inventors: Yoshihiro Taguchi, Takayuki Yamaguchi, Shingo Koizumi, Akira Iizuka, Kiyokazu Koga, Masato Yatsukura
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Patent number: 9493876Abstract: The described embodiments relate generally to cosmetic surfaces and associated treatments to alter a color of cosmetic surfaces. According to one embodiment, cosmetic ink configured to be applied to a cosmetic surface can include a suspension matrix configured to suspend a number of small particles in the suspension matrix. Each of the small particles of the is within a desired overall diameter to cause a user to perceive a desired color due to plasmon resonance of the small particles.Type: GrantFiled: September 10, 2013Date of Patent: November 15, 2016Assignee: Apple Inc.Inventors: Lucy E. Browning, Christopher D. Prest
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Patent number: 9481937Abstract: Compositions, methods, and systems permit selectively etching metal oxide from reactor metal parts (e.g., titanium and/or titanium alloys). The etching composition comprises an alkali metal hydroxide and gallic acid. The method is useful for cleaning reaction chambers used in the deposition of metal oxide films such as aluminum oxide.Type: GrantFiled: April 30, 2009Date of Patent: November 1, 2016Assignee: ASM America, Inc.Inventors: Srini Raghavan, Eric Shero, Mohith Verghese
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Patent number: 9416026Abstract: To collect water in space, a surface of a spaceship facing a direction of travel is coated with a drying agent, nanocoating, or nanostructures which are suitable for use in high vacuum to capture ambient water moisture from space as it impinges on the spaceship.Type: GrantFiled: June 22, 2015Date of Patent: August 16, 2016Inventor: Eurica Califorrniaa
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Patent number: 9310679Abstract: A thermally-sensitive, positive-working lithographic printing plate precursor can be used to prepare lithographic printing plates using high pH, silicate-free processing solutions. The precursor has a grained an anodized aluminum-containing substrate including a poly(vinyl phosphonic acid) interlayer. A first ink receptive layer, and optionally a second ink receptive layer, is disposed directly on the poly(vinyl phosphonic acid) interlayer. This first ink receptive layer comprises an aromatic acid dye that comprises at least two aromatic groups in an amount of least 0.5 weight %. In addition, the precursor comprises an infrared radiation absorber in one of the layers.Type: GrantFiled: June 5, 2014Date of Patent: April 12, 2016Assignee: EASTMAN KODAK COMPANYInventors: Gerhard Hauck, Dietmar Frank, Celin Savariar-Hauck
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Patent number: 9128468Abstract: To fabricate an external timepiece element in which there is inserted at least one decoration, the decoration is formed of anterior and posterior parts respectively intended to emerge from the external element and to serve as a mechanism of anchoring the decoration in the external element. A master mold is provided, the master mold including a hollow pattern cavity matching dimensions of the anterior part of the decoration. The decoration is placed in the pattern cavity. The master mold is filled by the galvanic deposition of a metal. The external element obtained is removed from the master mold.Type: GrantFiled: July 17, 2012Date of Patent: September 8, 2015Assignee: The Swatch Group Research and Development Ltd.Inventors: Pascal Grossenbacher, Thomas Froelicher
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Patent number: 8871309Abstract: A method for coating a metal substrate with a white to off-white or gray colored autodeposited coating comprising water, polymeric resin, HF and pigment particles comprising a core of titanium dioxide, an intermediate zirconia and/or alumina layer, and an outer organic layer, optionally the particles are treated with an anionic surfactant.Type: GrantFiled: May 7, 2012Date of Patent: October 28, 2014Assignee: Henkel AG & Co. KGaAInventors: Omar Lufti Abu-Shanab, Bashir Ahmed, Manesh Nadupparambil Sekharan, William E. Fristad, Nicholas Herdzik
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Patent number: 8313570Abstract: A composition for coating a metal substrate with a white to off-white or gray colored autodeposited coating comprising water, polymeric resin, HF and pigment particles comprising a core of titanium dioxide, an intermediate zirconia and/or alumina layer, and an outer organic layer, optionally the particles are treated with an anionic surfactant.Type: GrantFiled: September 18, 2007Date of Patent: November 20, 2012Assignee: Henkel KGaAInventors: Omar L. Abu-Shanab, Bashir Ahmed, Manesh Nadupparambil Sekharan, William E. Fristad, Nicholas Herdzik
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Publication number: 20120199250Abstract: A method of preparing an aluminum or aluminum alloy substrate to accept an adherent coating thereon is provided. The method includes the steps of degreasing the substrate, deoxidizing the substrate, and providing a prepaint conversion coating on the degreased and deoxidized substrate. The prepaint conversion coating composition comprises i) a source of fluoride ions; ii) a source of zirconium ions; iii) an acrylic resin; and iv) an optical brightener and forms a colorless, chromium-free conversion coating on the aluminum substrate that can be observed by exposing the treated substrate to UV light.Type: ApplicationFiled: February 4, 2011Publication date: August 9, 2012Inventors: Roberto Zoboli, Sara Salsa, Massimo Garzone
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Patent number: 8216688Abstract: In a dyeing method of an aluminum-based member, a first color forming material is held in a hole of a first region of an anodized film, a second color forming material is held in holds of a second region that is smaller than the first region by diagonally spraying, When the second colored layer is formed, a gradation region is formed in a boundary with the first region and the second region, and the hole are closed.Type: GrantFiled: March 17, 2011Date of Patent: July 10, 2012Assignee: Corona Kogyo CorporationInventor: Masao Yamaguchi
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Patent number: 7332021Abstract: A coating composition comprising an aqueous mixture containing acid-stable particles and one or more fluoroacids. The amount of the acid-stable particles in the coating composition is from 0.005% to 8% by weight on a dry weight basis. The acid-stable particles can be selected from aluminum-modified silica particles, nonaluminum-modified silica particles, and organic particles selected from anionically stabilized polymer dispersion particles. The invention is also directed to a coating on a metal substrate. The coating contains acid-stable particles attached to the metal substrate through a metal-oxide matrix. The metal-oxide matrix comprises a metal selected from titanium, zirconium, silicon, hafnium, boron, aluminum, germanium, or tin.Type: GrantFiled: July 22, 2003Date of Patent: February 19, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventors: William E. Fristad, Jeng-Li Liang, David C. Montrose
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Patent number: 7063735Abstract: A coating composition comprising an aqueous mixture containing inorganic particles, a catechol compound, and one or more fluoroacids. The preferred fluoroacids are selected from fluorotitanic acid, fluorozirconic acid, fluorosilicic acid, fluoroboric acid, fluorostannic acid, fluorogermanic acid, fluorohafnic acid, fluoroaluminic acid or salts of each thereof. The invention is also directed to a coating on a metal substrate. The coating comprises silica particles attached to the metal substrate through a metal-oxide matrix. The metal-oxide matrix comprises a metal selected from titanium, zirconium, silicon, hafnium, boron, aluminum, germanium, or tin, and a catechol compound.Type: GrantFiled: January 10, 2003Date of Patent: June 20, 2006Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: William E. Fristad, Jeng-Li Liang, Timothy S. Kelly
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Patent number: 7029541Abstract: In a preferred embodiment of the present invention, a conversion coating composition comprising chromium (III) ions, cobalt (II) ions, and nitric acid is provided. The coating composition is substantially free of chromium (VI) ions and substantially free of an oxidizing agent. The present trivalent chromium based conversion coating provides corrosion protection equal to or greater than most hexavalent chromium conversion coatings.Type: GrantFiled: January 24, 2002Date of Patent: April 18, 2006Assignee: Pavco, Inc.Inventors: Leonard L. Diaddario, Jr., Michael Marzano
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Patent number: 6794046Abstract: An article made of magnesium or its alloys, some or all of whose surface has a conversion coating, the conversion coating comprising MgO, Mn2O3 and MnO2 plus at least one oxide from the group consisting of vanadium, molybdenum and tungsten; and also a process for producing such an article, and its use.Type: GrantFiled: September 21, 2001Date of Patent: September 21, 2004Assignee: AHC Oberflachenechnik GmbH & Co. OHGInventors: Peter Kurze, Ulrike Kruger, Marco Kohler, Dora B{overscore (a)}nerjee
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Patent number: 6719852Abstract: A processing solution for forming a hexavalent chromium free, corrosion resistant trivalent chromate conversion film on zinc or zinc alloy plating layers comprises a silicon compound; trivalent chromium and oxalic acid in a molar ratio ranging from 0.5 to 1.5, wherein the trivalent chromium is present in the form of a water-soluble complex with oxalic acid; and cobalt ions, which form a hardly soluble metal salt with oxalic acid and are stably present in the processing solution without causing any precipitation, wherein the solution reacts with zinc when bringing it into contact with the zinc or zinc alloy plating to form a hexavalent chromium free, corrosion resistant, trivalent chromate conversion film containing zinc, chromium, cobalt, oxalic acid and silicon on the plating. This solution can provide a corrosion resistant trivalent chromate conversion film excellent in the corrosion resistance after heating.Type: GrantFiled: March 1, 2002Date of Patent: April 13, 2004Assignee: Dipsol Chemicals Co., Ltd.Inventors: Katsuhide Oshima, Shigemi Tanaka, Manabu Inoue, Tomitaka Yamamoto
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Patent number: 6464800Abstract: A visible colored chromium- and phosphorus-free conversion coating can be formed on a metal surface by contacting it with an aqueous liquid composition that comprises an alizarine dye and a product of chemical interaction between a first initial reagent component selected from the group consisting of fluoroacids of the elements titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin; and a second initial reagent component selected from the group consisting of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin and all of oxides, hydroxides, and carbonates of all of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin.Type: GrantFiled: April 30, 2001Date of Patent: October 15, 2002Assignee: Henkel CorporationInventors: Lawrence R. Carlson, Patrick A. Scalera, Therese E. Niemi, Shawn E. Dolan
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Patent number: 5723183Abstract: The invention is the chemical composition and method for forming a chemical conversion coating on ferrous metal surfaces and subsequent coloring of said conversion coating through the application of a water-soluble dye. The conversion coating has an ordered crystalline structure composed of ferrous oxalate or other ferrous dicarboxylates. The conversion coating can be colored through the application of a water-soluble reactive dye which bonds with Fe (II) within the ferrous dicarboxylate matrix, bound to the dicarboxylate molecules, thereby becoming water insoluble and permanent. When sealed with an appropriate rust preventive top coat, the result is an attractive and protective finish of minimal thickness which can be applied through simple immersion process techniques. Said finish can serve as a final protective finish on a fabricated ferrous metal article and also affords a degree of lubricity for assembly, break-in purposes, or anti-galling protection and serves as an adhesive base for paint.Type: GrantFiled: September 16, 1996Date of Patent: March 3, 1998Assignee: Birchwood Laboratories, Inc.Inventors: Richard K. Williams, David J. Halverson, James N. Tuttle, Jr.
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Patent number: 5505792Abstract: A method of providing color to a polyacrylamide based, dried-in-place, non-chromate conversion coating is provided. The addition of a phthalo green pigment and optionally a nonionic surfactant to an aqueous, dried-in-place conversion coating treatment solution provides for a colored conversion coating without adversely affecting the corrosion resistance or adhesion properties of the conversion coating.Type: GrantFiled: December 14, 1993Date of Patent: April 9, 1996Assignee: Betz Laboratories, Inc.Inventors: Jiangbo Ouyang, Philip D. Deck, William L. Harpel, Bruce V. Haberle
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Patent number: 5470613Abstract: A black, no-rinse conversion coating on metal surfaces is provided. The treatment of a metal such as aluminum or aluminum alloys with a composition of hexavalent chromium, an acrylic/itaconic modified styrene butyl acrylate polymer resin, a fluoacid, and carbon black results in a black no-rinse conversion coating.Type: GrantFiled: January 27, 1994Date of Patent: November 28, 1995Assignee: Betz Laboratories, Inc.Inventor: Edward A. Rodzewich
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Patent number: 5292378Abstract: A method of providing color to a dried-in-place, non-chromate conversion coating is provided. The addition of a phthalo green pigment and optionally a nonionic surfactant to an aqueous, dried-in-place conversion coating treatment solution provides for a colored conversion coating without adversely effecting the corrosion resistance or adhesion properties of the conversion coating.Type: GrantFiled: March 26, 1993Date of Patent: March 8, 1994Assignee: Betz Laboratories, Inc.Inventors: Jiangbo Ouyang, Bruce V. Haberle, Philip D. Deck, William L. Harpel
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Patent number: 5215864Abstract: A method and apparatus for engraving a metal plate in two or more colors. Selected areas of an oxidized aluminum plate are colored by a first dye to which the plate has an affinity. The selected areas may then be sealed by hydration. Portions of the selected areas of the colored oxidized aluminum plate can then be further engraved by the application of a focussed laser beam, which removes any of the first dye and the sealant, thereby restoring the affinity of the selected portions of the plate. The areas of the plate having an affinity for dyes can be colored by secondary and additional colors and shades thereof.Type: GrantFiled: September 28, 1990Date of Patent: June 1, 1993Assignee: Laser Color Marking, IncorporatedInventor: Peter Laakmann
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Patent number: 5022938Abstract: The present invention relates to compositions and methods for providing a corrosion-resistant coating on a zinc-cobalt alloy surface said surface with a hexavalent chromium-containing treatment solution. In a preferred embodiment, the solution comprises:(a) about 2 to about 30 g/l of CrO.sub.3 ;(b) 0 to about 25 g/1 of dichromate ion such that the total Cr.sup.+6 is about 1 to about 35 g/l;(c) about 0.5 to about 20 g/l of NH.sub.4.sup.+ ; and(d) about 5 to about 30 g/l of formate ion.The solution additionally comprises:(e) about 2 to about 25 g/l of Cl.sup.- ; and has a pH controlled by the addition of HCl or NaOH of about 0.8 to about 2.5. The solution is substantially-free of sulfate, chlorate and nitrate. In one embodiment, the formate is optional and low levels of Cr.sup.+6 are employed.Type: GrantFiled: July 31, 1989Date of Patent: June 11, 1991Assignee: OMI International CorporationInventor: Walter J. Wieczerniak
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Patent number: 4814209Abstract: External rust-staining, for example at the exterior of buildings or on the superstructure or topside of ships, caused by rust dripping onto a surface is inhibited by painting the surface with a top-coat paint comprising a film-forming binder and a substance capable of reacting with rust to form a colorless material. The said substance can for example be a polyphosphonate salt pigment, an oxalate or a glass releasing phosphate ions.Type: GrantFiled: October 30, 1987Date of Patent: March 21, 1989Assignee: International Paint Public Limited CompanyInventor: David E. J. Arnold