Abstract: The present invention provides a non-chromium metal surface treating agent which has excellent adhesion with a coating and corrosion resistance, and also has excellent workability and stability. A metal surface treating agent comprising a water-soluble zirconium compound, a water-soluble or water-dispersant acrylic resin and a water-soluble or water-dispersant thermosetting crosslinking agent, wherein said water-soluble zirconium compound has a zirconium content of 500 to 15000 ppm on a mass basis, said acrylic resin has an acid value of solid matter of 150 to 740 mgKOH/g, a hydroxyl value of solid matter of 24 to 240 mgKOH/g, and a solid matter content of 500 to 30000 ppm on a mass basis, and said thermosetting crosslinking agent has a solid matter content of 125 to 7500 ppm on a mass basis.

Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid that preferably has a pH value between 0.5 and 5.

Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.

Abstract: The present invention comprises a method for treating one or more multi-metal articles. The method comprises exposing the one or more articles to a first treatment composition capable of providing a conversion coating on steel- and zinc-based metal, and exposing the one or more articles to a second treatment coating composition suitable for providing a conversion coating on aluminum-based metal articles. Preferably, the first treatment composition comprises a zinc-phosphate conversion coating comprising, zinc ion, phosphate ion, manganese ion, and fluoride ion. Preferably, the second treatment composition comprises a ceramic composite treatment composition.

Abstract: In a process for the chemical pretreatment before painting of composite metal structures that contain aluminum or aluminum alloy portions together with steel, galvanized steel and/or alloy-galvanized steel portions, in a first step the metal structure is treated with a zinc phosphating solution that forms a surface-covering crystalline zinc phosphate layer on steel and on galvanized or alloy-galvanized steel, but without forming a zinc phosphate layer on the aluminum portions, and then in a second step the metal structure is brought into contact with a treatment solution that does not excessively dissolve the crystalline zinc phosphate layer on steel, galvanized and/or alloy-galvanized steel, but forms a conversion layer on the aluminum portions.

Abstract: A surface-treated steel sheet includes a steel sheet, an Al—Zn-base alloy plating layer formed on the steel sheet, a chemical conversion film provided on the alloy plating layer, and a concentric layer of a Cr compound that is formed on the alloy plating layer of the chemical conversion film. The surface-treated steel sheet may include a steel sheet, an zinc-base plating layer formed on the steel sheet, and a film that contains chromium and calcium and that is formed on the zinc-base plating layer.

Abstract: The invention concerns a method for producing an anticorrosive coating for metal parts, free of chromium and chromium-based derivatives and in particular hexavalent chromium, preferably to be applied in thin layers while providing highly efficient protection. Said coating consists of the synergistic association of a first metal zinc layer and one or several coating layers obtained by using an aqueous composition containing a particulate metal, an appropriate solvent, a thickening agent and a binder consisting of a silane.

Abstract: A metal treating composition comprising at least a specific type of dissolved and/or dispersed organic resin, a dissolved vanadium compound in which the valence of vanadium is from 3 to 5, and a dissolved compound that contains at least one of the metals Zr, Ti, Mo, W, Mn, and Ce can provide metal surfaces with superior corrosion resistance, alkali resistance, and fingerprint resistance. The composition contains no chromium to cause pollution problems and/or require pollution abatement.

Abstract: Autodeposition of a coating containing an epoxy resin is accomplished over a metal substrate that has been coated with a zinc phosphate conversion coating without significant removal of the zinc phosphate conversion coating.

Abstract: A process and apparatus prepares and collects metal nanoparticles by forming a vapor of a metal that is solid at room temperature, the vapor of the metal being provided in an inert gaseous carrying medium. At least some of the metal is solidified within the gaseous stream. The gaseous stream and metal material is moved in a gaseous carrying environment into or through a dry mechanical pumping system. While the particles are within the dry mechanical pumping system or after the nanoparticles have moved through the dry pumping system, the vaporized metal material and nanoparticles are contacted with an inert liquid collecting medium.

Abstract: The present invention relates to a surface-treated steel sheet coated with a chromate layer having excellent corrosion resistance, fuel resistance and seam weldability, and a chromate solution used for preparing the surface-treated steel sheet. Specifically, the chromate solution of the present invention comprises (a) a main solution prepared by adding to a chrome solution having 0.4 to 0.8 of trivalent chrome composition and 7 to 50 g/l of dissolved chrome, on the basis of the chrome in the chrome solution, 50 to 80 w % of phosphate, 20 to 40 w % of fluoric acid, 300 to 2000 w % of colloidal silica, 5 to 15 w % of sulfuric acid, and 25 to 40 w % of sodium phosphate, and (b) a hardener solution containing added epoxy silane or glycidyl silane of 2 to 10 w % on the basis of total hardener solution, the pH of which is controlled between 2 and 3, wherein 10 to 60 w % of the hardener solution being added to the main solution.

Abstract: A conversion coating that does not substantially diminish the luster of a metal surface on which it is coated nor impair adhesion to the surface of lacquers and printing inks commonly used on beverage containers may be provided by contacting the metal surface with an aqueous liquid composition comprising water and at least the following components: (A) a component of one or more dissolved transition metal compounds that contain zirconium and may also include titanium, provided that zirconium constitutes more than 30% of the moles of the total moles or zirconium and titanium; (B) a component of at least one dissolved compound that contains inorganically bonded fluorine and is not part of component (A); and (C) a component of dissolved organic polymer molecules.

Abstract: A treatment method for hydrophilicity for a heat exchanger which can maintain the deodorizing property and hydrohilicity even after a long-time use, and a heat exchanger thus treated for hydrophilicity by said method are provided.

Abstract: An aqueous metal surface treatment composition comprising the following ingredients:

Abstract: A process for the corrosion protection of steel strips coated with zinc or zinc alloy, characterised in that the steel strips coated with zinc or zinc alloy are brought into contact with an aqueous treatment solution having a pH within the range of from 1.5 to 3.5, which contains 1 to 20 g/l manganese(II) ions and 1 to 150 g/l phosphate ions, and the solution is dried without intermediate rinsing. Optionally the solution may contain in addition: up to 10 g/l zinc ions, up to 10 g/l nickel ions, up to 20 g/l titanium ions, up to 50 g/l silicon ions in the form of silicon compounds, up to 30 g/l fluoride ions, up to 150 g/l of one or more polymers or copolymers of polymerisable carboxylic acids selected from acrylic acid, methacrylic acid and maleic acid, and esters thereof with alcohols having 1 to 6 carbon atoms. The present invention also relates to the correspondingly-treated metal strips.

Abstract: A composition for metal surface treatment which comprises an aluminum ion, a magnesium ion, a manganese ion, a water-soluble organic resin, an acid and water; and a surface treated metal material which has been treated with the composition. The resultant surface treated metal material is free from the danger of water contamination owing to chromium, since the composition is free of chromium, and also is excellent in both electrical conductivity and corrosion resistance. Accordingly, the metal material can be used in a wide variety of applications in place of a conventional chromate-treated steel sheet and the like.

Abstract: The present invention is drawn to a method of lowering the net resistivity of an interconnect by depositing a monomer layer upon an aluminum bonding pad, the treatment thereof to cross link the monomer to form an electrically conductive polymer, and simultaneously, the substantial reduction of alumina, Al2O3, to metallic aluminum. In the method of the present invention, deposition of a monomer layer in a solvent, volatilization of the solvent, and contact with a strong oxidizer such as a potassium permanganate allows for the use of the strong oxidizer without the hindrance of having to deal with a manganese oxide husk on the surface of the aluminum bonding pad. Preferably, the chemical qualities of the monomer will include the tendency to be a reducing agent to the native oxide film of the bonding pad. By selecting a monomer that tends to reduce rather than to oxidize, the problem of thickening the native oxide film is avoided.

Abstract: A coating composition and process have been developed to provide an activated coating on nickel screen for use as cathodes in electrolytic cells for the generation of hydrogen and oxygen. Compared to the earlier Classical Pack Cementation process, the disclosed process is less expensive, reduces processing time from 20 hours to a few minutes, eliminates dusts and toxic gases, and provides improved performance in cells for hydrogen and oxygen generation. The coating is characterized by the presence of two activated layers with a high surface area, a multitude of fissures and a nickel to aluminum weight ratio greater than 20/1 in the top layer and greater than 4/1 in the bottom layer adjacent to the nickel substrate.

Abstract: An especially effective hydrophilicizing treatment for solid surfaces, particularly those of conversion coated aluminum, is a liquid mixture of water, organic polymer molecules that include sulfonyl/ate moieties, and preferably also a substance made by mixing with aqueous phosphoric acid at least one metal, metal oxide, or metal hydroxide so as to form a transparent liquid mixture. The treatment liquid preferably has a nearly neutral pH and is applied to a substrate and dried in place by exposure to heat.

Abstract: When a phosphate ester or a dispersed wax is added to a conventional liquid phosphate conversion coating composition, the resulting phosphate coating formed on a metal substrate has a lower coefficient of friction after being oiled than it would have had if the additive had been omitted. The corrosion resistance and paint adhesion properties expected from the conversion coating are not substantially diminished by the additive. Particularly good results are achieved if the phosphate coating composition contains calcium and ferrous cations and the liquid phosphate conversion coating composition is dried into place on the substrate.

Abstract: A visible colored chromium- and phosphorus-free conversion coating can be formed on a metal surface by contacting it with an aqueous liquid composition that comprises an alizarine dye and a product of chemical interaction between a first initial reagent component selected from the group consisting of fluoroacids of the elements titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin; and a second initial reagent component selected from the group consisting of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin and all of oxides, hydroxides, and carbonates of all of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin.

Abstract: A water-based surface-treating agent for metallic materials which gives a film highly satisfactory in corrosion resistance, blackening resistance, wet secondary adhesion to topcoatings, low-pollution characteristics (amount of fixed chromium), chemical resistance (especially acid resistance and alkali resistance), etc., while retaining the intact practical liquid stability of conventional chromate-containing resinous coating agents.

Abstract: The present invention relates to the use asymmetric monolayer forming species and electroconduit forming species to detect target analytes.

Abstract: A chromium-free agent for treating metallic surface comprising the following (i)-(iv):

Abstract: An aqueous metal surface treatment composition that includes (A) an aqueous dispersion of a phenolic novolak resin that includes water and a reaction product of a phenolic resin precursor, a modifying agent and a multi-hydroxy phenolic compound wherein the modifying agent includes at least one functional moiety that enables the modifying agent to react with the phenolic resin precursor and at least one ionic moiety, (B) an acid and, optionally, (C) a flexibilizer. According to one embodiment the modifying agent is an aromatic compound. According to another embodiment the ionic moiety of the modifying agent is sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the dispersed phenolic resin reaction product has a carbon/sulfur atom ratio of 20:1 to 200:1.

Abstract: An aqueous surface treatment bath that has a pH from 2.5 to 4.5 and contains at least 0.1 g/L of orthophosphate ions, from 0.1 to 3 g/L of condensed phosphate ions, from 0.1 to 0.5 g/L of free hydrofluonc acid, and at least 0.1 g/L of water-soluble polymer molecules that, except for short end groups as generally known in the art, conform to general formula (1) below: in which n is the degree of polymerization and has an integral value or each molecule, the average value of n for all of the molecules present being from 2 to 50 and not necessarily integral, X is a hydrogen atom or a moiety Y conforming to general formula (II) wherein each of R1 and R2 is an alkyl moiety or a hydroxy alkyl moiety having from 1 to 3 carbon atoms each, the total number of moieties Y having a ratio to the total number of aromatic rings that is from 0.2:1.0 to 1.0:1.

Abstract: This invention discloses novel catalyzed surface composition altering formulations and methods and catalyzed surface coating formulations and methods, which contain one or more catalysts, along with optional other ingredients, wherein the catalysts serve to effect in situ chemical bonding reactions in that the catalysts function to initiate, to promote, to accelerate, and/or to increase the formation and yield of persistent, solid, corrosion-resistant, impact-resistant, wear-resistant, and/or non-stick surface compositions and surface coating films, which may exhibit pigmentation and other aesthetic features, and may be designed to be environmentally benign. The disclosed formulation and methods may be used to alter the surface composition and to coat the surfaces of vehicles, such as aircraft, and to improve the anti-icing characteristics of the vehicle surfaces.

Abstract: Disclosed herein is a surface treatment agent for steel, characterized in that, said agent contains 0.1-15% by mass of chromium sulfate and 10-40% by mass of a binder resin containing butyral resin or a mixture of butyral resin with another resin which is compatible with butyral resin.

Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.

Abstract: The disclosure relates to aqueous-based gels and, in some cases, usage of such gels to impart corrosion resistance to steel and/or zinc containing surfaces, e.g., galvanized steel. The gel comprises water, at least one thickener, at least one silica containing material and an optional surfactant.

Abstract: An aluminum-containing metal material for, for example, a heat-exchanger for motorcars is surface-treated by chemically etching an Al-containing metal material surface, forming a first protective layer on the etched surface by a chemical conversion treatment with an aqueous solution of Zr phosphate or Ti phosphate, and coating the first protective layer with a second protective layer containing a hydrophilic resin including non-cross-linked hydrophilic functional groups and at least partially cross-linked reactive functional groups different from the hydrophilic functional groups, to impart high hydrophilicity and resistance to odor generation and corrosion to the aluminum-containing metal material surface.

Abstract: A chromium(VI)-free, chromium(III)-containing and substantially coherent conversion layer on zinc or zinc alloys presenting, even in the absence of further components such as silicate, cerium, aluminum and borate, a corrosion protection of approx. 100 to 1000 h in the salt spray test according to DIN 50021 SS or ASTM B 117-73 until first attack according to DIN 50961 Chapter 10; being clear, transparent and substantially colorless and presenting multi-colored iridescence; having a layer thickness of approx. 100 nm to 1000 nm; and being hard, adhering well and being resistant to wiping.

Abstract: The present invention relates to a method for treating a surface of zinc or of an alloy of zinc and aluminum, said method comprising the step of treating said surface with an aqueous solution having a pH of below 3 and comprising a complex formed from at least one species of metal oxo ion in conjunction with at least one species of hetero ion, the metal oxo ion being selected from the group consisting of molybdate, tungstate and vanadate; the hetero ion being selected from the group consisting of phosphorus (V), aluminium (III), silicon (IV), manganese (II), manganese (IV), zirconium (IV), titanium (IV), tin (IV), cerium (III) and nickel (II); and with a film forming acid tolerant resin compatible with the selected ions.

Abstract: A method of manufacturing a resin-coated aluminum alloy sheet for drawn and ironed cans, which coated sheet can be subsequently formed into a drawn and ironed can without its wall breaking, and having substantial strength, the can-forming process including a bending and bending back operation at a die shoulder rounded portion of small radius, and a subsequent dry ironing operation. The coated sheet is formed by homogenization heat treating an aluminum alloy ingot containing essentially 0.5 to 2.0 wt % of Mn, 0.2 to 2.0 wt % of Mg, 0.05 to 0.4 wt % of Si and not more than 0.7 wt % of Fe, wherein (Si+Fe)≦0.9 wt %, and subjecting the aluminum alloy ingot to hot rolling to obtain an aluminum alloy sheet, followed by continuous annealing, cold rolling, and surface treatment, heating the resultant sheet, and then coating both surfaces of the sheet with a thermoplastic resin at a predetermined temperature, and immediately quenching the sheet.

Abstract: A method of manufacturing a resin-coated aluminum alloy sheet for drawn and ironed cans, which can be formed into a drawn and ironed can free from its wall breaking and having enough strength as a can, when it is formed through a composite forming process, the process including a bending and bending back operation at a die shoulder rounded portion of a small shoulder radius and a subsequent ironing operation, under dry condition; which comprises the steps of homogenization heat treating an aluminum alloy ingot containing essentially 0.5 to 2.0 wt % of Mn, 0.2 to 2.0 wt % of Mg, 0.05 to 0.4 wt % of Si and not more than 0.7 wt % of Fe as inevitable impurities, wherein (Si+Fe)≦0.

Abstract: This invention discloses novel catalyzed surface composition altering formulations and methods and catalyzed surface coating formulations and methods, which contain one or more catalysts, along with optional other ingredients, wherein the catalysts serve to effect in situ chemical bonding reactions in that the catalysts function to initiate, to promote, to accelerate, and/or to increase the formation and yield of persistent, solid, corrosion-resistant, impact-resistant, wear-resistant, and/or non-stick surface compositions and surface coating films, which may exhibit pigmentation and other aesthetic features, and may be designed to be environmentally benign. This invention discloses novel means to alter the surface composition and to coat the surface of metals, plastics, fabrics, woods, and the like through catalytically supported chemical reactions that produce functionally improved surface performance for industrial, commercial, domestic and other purposes.

Abstract: Compositions and methods for treating substrates are disclosed. The compositions are generally described as epoxy-novolac resins containing a Mannich derivatized bisphenol side chain. The methods, which comprise contacting the surface to be treated with these compositions, improve the corrosion resistance and/or adhesion properties of the treated surface.

Abstract: Here are provided a composition for hydrophilic treatment of aluminum or aluminum alloy which can form film having persistent corrosion resistance and hydrophilicity and not generating odor, and a method for hydrophilic treatment.

Abstract: The present invention relates to an anticorrosive treatment including following steps (1) contacting a metal to be treated with an aqueous solution containing one or more kinds of compounds containing phosphorus ions, (2) washing it if desired, and (3) applying anticorrosive coatings containing one or more kinds of sulfur compounds and a water dispersible silica in a composition containing an aqueous resin and water as main components.

Abstract: A composition for passivating a metal substrate is provided. The composition is prepared by mixing together: a) Group IIIB or IVB metal compound; and b) a reaction product of an epoxy group-containing polymer or oligomer, a hydroxy functional acid and a dialkanolamine. The compositions, which are substantially free of chrome, are used to treat metal substrates prior to the application of a protective or decorative coating.

Abstract: A chromate treatment bath composition, afforded by the introduction, into an aqueous solution containing hexavalent Cr ions and trivalent Cr ions, of a nonionic-anionic composite surfactant that has an anionic moiety and a nonionic moiety composed of a polyethylene glycol group or a group consiting of an ethylene oxide addition polymer, provides metal surfaces onto which a layer of the composition containing 5 to 150 mg/m.sup.2 of total chromium is dried with a chromate film that has an excellent alkali resistance and water resistance, a high chromium fixing ratio, an excellent corrosion resistance, and an excellent paint film adherence.

Abstract: A metal surface treatment composition which can improve the corrosion resistance and the tight adhesion to coating films and impart slipperiness. The composition is an aqueous solution, dispersion or emulsion containing both an acrylic resin having nitrogenous heterocycles, amino and/or ammonium groups and hydrophobic groups and a heavy metal or a salt thereof. The amino or ammonium groups have at least one structure selected from among those represented by general formulae (I) (wherein in R.sub.1, R.sub.2 : hydrogen, hydroxyl, substituted or unsubstituted, linear or branched C.sub.1 -C.sub.5 alkyl, or substituted or unsubstituted, linear or branched C.sub.1 -C.sub.5 hydroxyalkyl) and (II) (wherein R.sub.3, R.sub.4, R.sub.5 : hydrogen, hydroxyl, substituted or unsubstituted, linear or branched C.sub.1 -C.sub.5 alkyl, or substituted or unsubstituted, linear or branched C.sub.1 -C.sub.5 hydroxyalkyl).

Abstract: An aqueous solution and method for applying the solution to a metal surface form a zinc phosphate coating on the metal surface. The zinc phosphate coating minimizes corrosion and improves adhesion of subsequently coated materials such as sealants and paints. The solution of the composition and method of application consume free acidity otherwise left on the metal surface, and obviate the need for subsequent rinsing or extensive drying or stoving operations. The composition includes an aqueous solution including water, zinc dihydrogen phosphate, phosphoric acid, a polyhydric polymer, a metal salt, and optionally, a fluoride.

Abstract: The present invention is drawn to a method of lowering the net resistivity of an interconnect by depositing a monomer layer upon an aluminum bonding pad, the treatment thereof to cross link the monomer to form an electrically conductive polymer, and simultaneously, the substantial reduction of alumina, Al.sub.2 O.sub.3, to metallic aluminum. In the method of the present invention, deposition of a monomer layer in a solvent, volatilization of the solvent, and contact with a strong oxidizer such as a potassium permanganate allows for the use of the strong oxidizer without the hindrance of having to deal with a manganese oxide husk on the surface of the aluminum bonding pad. Preferably, the chemical qualities of the monomer will include the tendency to be a reducing agent to the native oxide film of the bonding pad. By selecting a monomer that tends to reduce rather than to oxidize, the problem of thickening the native oxide film is avoided.

Abstract: The invention provides an aluminum alloy sheet that has excellent formability, high coat-baking hardenability, excellent corrosion resistance, and is particularly suitable for external automobile body plates. The aluminum alloy sheet comprises: 0.9 to 1.3 wt. % of Si, 0.4 to 0.6 wt. % of Mg, 0.05 to 0.15 wt. % of Mn, 0.01 to 0.1 wt. % of Ti, with the remainder comprising Al and inevitable impurities, while limiting Fe as an impurity to 0.2 wt. % or less and Cu as an impurity to 0.1 wt. % or less. The aluminum homogenizing an aluminum ingot with the above-described composition; cooling the homogenized ingot to a temperature of 450.degree. C. or below to begin hot-rolling; finishing hot-rolling in a temperature range from 250 to 350.degree. C.; applying intermediate annealing to the hot-rolled plate; conducting cold-rolling at a draft of 70% or more; applying a solid solution treatment followed by quenching the alloy sheet and holding it at 530.degree. C. or above for 60 sec.

Abstract: A solution and a process for non-chromium rust proof coating is disclose. The rust proof coating solution includes a composite of which the main components are an aqueous resin and water, with 0.2-20 g/l of triazine thiol compound and 0.1/5 g/l phosphoric acid contained therein. The rust proof process is a process for coating a zinc-coated steel or a non-coated steel with the rust proof coating solution as described above.

Abstract: A method for treating aluminum to enhance corrosion resistance of its surface. The chemical conversion coating aluminum and aluminum alloys are exposed to an aqueous PU solution to form a PU film on the surface. The aqueous PU solution comprises: (i) 5-15% weight of water dispersable polyurethane resin, (ii) 0.1-56 weight of cross-linking agent, and (iii) 80-94.9% weight of water.

Abstract: To inhibit the blackening of zinciferous metal-plated steel sheet while also generating a good corrosion resistance, fingerprint resistance, and chromium fixation ratio for the steel sheet, it is coated with an aqueous liquid composition that has a pH not exceeding 2.5 and contains hexavalent chromium ion, trivalent chromium ion, nickel ion, inorganic acid (preferably phosphoric acid), and film-forming resin, with a weight ratio between the nickel content and the total chromium content of 0.05 to 1, and the liquid coating is dried onto the treated metalsurface to form a blackening resistant coating that contains from 0.1 to 10 g/m.sup.2 resin and from 2 to 150 mg/m.sup.2 of total chromium.

Abstract: A chromium-free composition for treating metal surface comprising (a) a hydroxyl group-containing organic resin, (b) a phosphoric acid and (c) at least one of ions and compounds of at least one metal selected from the group consisting of Cu, Co, Fe, Mn, Sn, V, Mg, Ba, Al, Ca, Sr, Nb, Y and Zn, and (d) at least one of colloids (sol) or powders of SiO.sub.2, SnO.sub.2, Fe.sub.2 O.sub.3, Fe.sub.3 O.sub.4, MgO, ZrO.sub.2, Al.sub.2 O.sub.3 and Sb.sub.2 O.sub.5 ; as well as a metal sheet or metal article having thereon (i) a coating film of the chromium-free composition and optionally (ii) a coating film of a coating composition comprising an organic resin and if desired a colloid (sol) or a powder.

Abstract: The uniformity of gloss of a dried autodeposited resin film on a metal surface can be increased by rinsing the wet autodeposited film initially formed with an aqueous modifying rinse having a pH from 6 to 11 and comprising from 0.2 to 10.0 g/L in total of polymers of carboxylic acid monomers having an ethylenic double bond and salts thereof.