Oxide Of Iron Formed Patents (Class 148/287)
  • Patent number: 12012365
    Abstract: The invention provides methods and compositions that prevent, mitigate or delay the onset of corrosion of iron or steel (e.g., plain carbon steel) components used as reinforcement or otherwise at least partially embedded in carbonated concrete composite materials and objects based on carbonatable calcium silicate cement.
    Type: Grant
    Filed: February 22, 2019
    Date of Patent: June 18, 2024
    Assignee: SOLIDIA TECHNOLOGIES, LTD.
    Inventors: Jitendra Jain, Anuj Seth, Vahit Atakan, Ahmet Cuneyt Tas, Sadanada Sahu
  • Patent number: 11708622
    Abstract: A bolt of the present invention has a composition comprising: 0.50 mass % or greater and 0.65 mass % or less of carbon (C), 1.5 mass % or greater and 2.5 mass % or less of silicon (Si), 1.0 mass % or greater and 2.0 mass % or less of chromium (Cr), 0.2 mass % or greater and 1.0 mass % or less of manganese (Mn), 1.5 mass % or greater and 5.0 mass % or less of molybdenum (Mo), wherein a total amount of phosphorous (P) and sulfur (S) as impurities is 0.03 mass % or less, the remaining is iron (Fe), and the bolt comprises an iron based oxide film with a film thickness of 3 ?m or greater and 20 ?m or less on the surface thereof. The bolt has excellent delayed fracture resistance and reliably provides a fastening axial force.
    Type: Grant
    Filed: January 30, 2018
    Date of Patent: July 25, 2023
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Takahiro Hamada, Daisuke Kobayashi
  • Patent number: 11697879
    Abstract: Embodiments of the present disclosure generally relate to protective coatings on aerospace components and methods for depositing the protective coatings. In one or more embodiments, a method for producing a protective coating on an aerospace component includes depositing a metal oxide template layer on the aerospace component containing nickel and aluminum (e.g., nickel-aluminum superalloy) and heating the aerospace component containing the metal oxide template layer during a thermal process and/or an oxidation process. The thermal process and/or oxidation process includes diffusing aluminum contained within the aerospace component towards a surface of the aerospace component containing the metal oxide template layer, oxidizing the diffused aluminum to produce an aluminum oxide layer disposed between the aerospace component and the metal oxide template layer, and removing at least a portion of the metal oxide template layer while leaving the aluminum oxide layer.
    Type: Grant
    Filed: September 4, 2019
    Date of Patent: July 11, 2023
    Assignee: APPLIED MATERIALS, INC.
    Inventors: Sukti Chatterjee, Kenichi Ohno, Lance A. Scudder, Yuriy Melnik, David A. Britz, Pravin K. Narwankar, Thomas Knisley, Mark Saly, Jeffrey Anthis
  • Patent number: 11618714
    Abstract: A method of producing a carbonated composite material includes: providing a carbonatable cementitious material in particulate form; mixing the carbonatable cementitious material with water to produce a mix; forming a predetermined shape with the mix, wherein the predetermined shape has an initial pore structure containing an initial pore solution having a first pH; pre-conditioning the predetermined shape to remove a predetermined amount of the water from the predetermined shape to produce a pre-conditioned shape; carbonating the pre-conditioned shape in an environment comprising carbon dioxide to produce a modified pore structure containing a modified pore solution having and a second pH, wherein the difference between the first pH and the second pH is represented by a ?pH, and the ?pH is 1.0 or less.
    Type: Grant
    Filed: October 9, 2020
    Date of Patent: April 4, 2023
    Assignee: Solidia Technologies, Inc.
    Inventors: Anuj Seth, Jitendra Arunchandra Jain, Yussuf Sultan Ali, Matthew David Sulik, Dishen Patel, Makar Makram Ibrahim
  • Patent number: 11414738
    Abstract: An apparatus for manufacturing a stress relieved length of steel having an oxidised surface layer includes: a heating chamber; a reaction chamber coupled to the heating chamber; and a conveying mechanism conveying the length of steel along a path through the heating chamber and reaction chamber. The heating chamber includes a heating apparatus arranged to heat the length of steel in a heating portion of the path. The apparatus further includes a control means including a sealed unit defined by the heating chamber and the reaction chamber and arranged to control both the temperature of the length of steel and the atmosphere to which the length of steel is exposed in an oxidisation portion of the path within the reaction chamber in which the oxidised surface layer is formed. A method of manufacturing a stress relieved length of steel having an oxidised surface layer is also disclosed.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: August 16, 2022
    Assignee: Liberty Performance Steels Limited
    Inventor: Carl Jukes
  • Patent number: 11326243
    Abstract: Low-density hot dip galvanized steel, comprising a steel substrate (1) located at a core portion and a coating layer (3) located on the surface. An interface layer is disposed between the steel substrate (1) and the coating layer (3), the interface layer comprises an iron particle layer (4), iron particles dispersed on the steel substrate (1) and covering the steel substrate (1) are disposed in the iron particle layer (4), and the iron particles are covered by a first inhibition layer (5). The low-density hot dip galvanized steel contains element Al in a mass percentage of 3.0% to 7.0%. Correspondingly, the present invention also comprises a manufacturing method for the low-density hot dip galvanized steel. The low-density hot dip galvanized steel has a low density, a high strength and high galvanizability and coating layer adhesion.
    Type: Grant
    Filed: June 14, 2017
    Date of Patent: May 10, 2022
    Assignee: BAOSHAN IRON & STEEL CO., LTD.
    Inventors: Xinyan Jin, Qi Yang, Li Wang, Guangkui Hu
  • Patent number: 10697053
    Abstract: The purpose of the present invention is to provides a method for manufacturing a black plated steel sheet that is capable of more evenly blackening the area of the plated steel sheet to be blackened. The present invention relates to a method for manufacturing a black plated steel sheet by bringing a plated steel sheet with an Al- and Mg-containing hot-dip galvanized layer into contact with water vapor inside a sealed vessel. This method performs, in the following order: a first step for heating a plated steel sheet disposed inside a sealed vessel in the presence of a gas, the dew point of which is always less than the plated steel sheet temperature; a second step for evacuating the heated ambient gas inside the sealed vessel to make the pressure of the gas inside the sealed vessel to be 70 kPa or less; and a third step for introducing water vapor inside the sealed vessel in which the pressure of the gas therein has been reduced to 70 kPa or less to blacken the galvanized layer.
    Type: Grant
    Filed: August 9, 2016
    Date of Patent: June 30, 2020
    Assignee: NISSHIN STEEL CO., LTD.
    Inventors: Tadashi Nakano, Shin Ueno, Masaya Yamamoto
  • Patent number: 10648738
    Abstract: System and method for using fast response heaters to pre-heat metal before entering a metal treatment furnace, which may improve control over metal processing, especially in response to changes in material, mass flow rate, line speed, and/or desired treatment process. Fast response heaters may be used with control systems to adjust the output of the fast response heater based on operator inputs, direct or indirect sensing of process parameters, and/or the use of thermal models to quickly adjust fast response heater output while a metal treatment furnace remains at a constant temperature or slowly transitions into a new operating state. The resulting gains in process control result in higher quality products, reduced scrap, and increases in line speed and output.
    Type: Grant
    Filed: June 23, 2016
    Date of Patent: May 12, 2020
    Assignee: NOVELIS INC.
    Inventors: David Michael Custers, Michael Bull, Andrew Hobbis
  • Patent number: 10385438
    Abstract: There is provided a heat resistant ferritic steel including a base material including, by mass percent, C: 0.01 to 0.3%, Si: 0.01 to 2%, Mn: 0.01 to 2%, P: at most 0.10%, 5: at most 0.03%, Cr: 7.5 to 14.0%, sol.Al: at most 0.3%, and N: 0.005 to 0.15%, the balance being Fe and impurities, and an oxide film that is formed on the base material and contains 25 to 97% of Fe and 3 to 75% of Cr. This heat resistant ferritic steel is excellent in photoselective absorptivity and oxidation resistance.
    Type: Grant
    Filed: April 13, 2017
    Date of Patent: August 20, 2019
    Assignee: NIPPON STEEL CORPORATION
    Inventors: Yoshitaka Nishiyama, Shunichi Otsuka
  • Patent number: 9738946
    Abstract: A method for producing a silicon steel normalizing substrate comprises steelmaking, hot rolling and normalizing steps. A normalizing furnace is used in the normalizing step, and along a moving direction of strip steel, the normalizing furnace sequentially comprises: a preheating section, a nonoxidizing heating section, a furnace throat, furnace sections for subsequent normalizing processing, and a delivery seal chamber. Furnace pressures of the normalizing furnace are distributed as follows: the furnace pressure of a downstream furnace section adjacent to the furnace throat along the moving direction of the strip steel is the highest, the furnace pressure decreases gradually from the furnace section with the highest furnace pressure to a furnace section in an inlet direction of the normalizing furnace, and the furnace pressure decreases gradually from the furnace section with the highest furnace pressure to a furnace section in an outlet direction of the normalizing furnace.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: August 22, 2017
    Assignee: Baoshan Iron & Steel, Co., Ltd.
    Inventors: Hongxu Hei, Xiao Chen, Xiandong Liu, Shishu Xie, Dejun Su, Runjie Lin, Peili Zhang, Rongqiang Jiang, Miao Ye
  • Patent number: 9441893
    Abstract: Described herein are devices and methods for thawing frozen biological products efficiently without harming the products.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: September 13, 2016
    Assignee: Grifols, S.A.
    Inventors: Ajoy Velayudhan, Robert Large
  • Patent number: 9115433
    Abstract: In a method for surface treatment of stainless steel, the thermally produced layers of oxide are contacted with a composition effective to dissolve iron ions out of the layers of oxide.
    Type: Grant
    Filed: October 15, 2009
    Date of Patent: August 25, 2015
    Assignee: POLIGRAT GMBH
    Inventors: Olaf Boehme, Siegfried Piesslinger-Schweiger
  • Patent number: 9040168
    Abstract: The galvannealed steel sheet includes: a galvannealed layer formed on at least one surface of a steel sheet and contains includes an amount of 0.05 mass % to 0.5 mass % of Al, an amount of 6 mass % of 12 mass % of Fe, and the balance composed of Zn and inevitable impurities; and a mixed layer formed on a surface of the galvannealed layer and includes a composite oxide of Mn, Zn, and P and an aqueous P compound, wherein the composite oxide includes 0.1 mg/m2 to 100 mg/m2 of Mn, an amount of 1 mg/m2 to 100 mg/m2 of P, and Zn, and a P/Mn ratio is 0.3 to 50, and wherein the total size of an area of the mixed layer in which an attached amount of P is equal to or more than 20 mg/m2 is 20% to 80% of a surface area of the mixed layer.
    Type: Grant
    Filed: July 12, 2010
    Date of Patent: May 26, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kazuhiko Honda, Noriyuki Suzuki, Yoichi Ikematsu
  • Publication number: 20150007808
    Abstract: A glass-to-metal sealing device of a solar receiver has a metal collar and a glass cylinder to be sealed together. The glass cylinder is made of a borosilicate glass having a coefficient of thermal expansion within the range of [3.1, 3.5]·10?6° C.?1 in a temperature range of [50, 450]° C. The metal collar s made of an austenitic alloy having a coefficient of thermal expansion in the range of [3.5, 6.0]·10?6° C.?1 in the temperature range of [50, 450]° C. The end portion of the metal collar is beveled so as to increase its mechanical flexibility and, further, the end portion of the metal collar is processed via a thermal treatment in order to establish a bond between the metal and the glass surfaces.
    Type: Application
    Filed: January 22, 2013
    Publication date: January 8, 2015
    Applicant: ARCHIMEDE SOLAR ENERGY S.R.L.
    Inventors: Thomas Chiarappa, Claudio Raggi
  • Publication number: 20150003935
    Abstract: A steel is used for providing a bolt that has a high strength and still exhibits excellent hydrogen embrittlement resistance. The steel contains C of 0.30% to 0.50%, Si of 1.0% to 2.5%, Mn of 0.1% to 1.5%, P of greater than 0% to 0.015%, S of greater than 0% to 0.015%, Cr of 0.15% to 2.4%, Al of 0.010% to 0.10%, N of 0.001% to 0.10%, Cu of 0.1% to 0.50%, Ni of 0.1% to 1.0%, Ti of 0.05% to 0.2%, and V of 0% to 0.2%, with the remainder including iron and inevitable impurities, in which a ratio [Ni]/[Cu] is 0.5 or more, and a total content [Ti]+[V] is 0.085% to 0.30%.
    Type: Application
    Filed: November 26, 2012
    Publication date: January 1, 2015
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Yosuke Matsumoto, Atsushi Inada, Masamichi Chiba
  • Patent number: 8906170
    Abstract: An alloy casting having a protective layer disposed on a surface of the casting is provided. The protective layer is resistant to liquid metal attack, and wherein the protective layer includes an oxide of an element present in the alloy. A method of forming a protective layer on a surface of the alloy casting is also provided. The method includes disposing the alloy in a mold, and oxidizing an element of the alloy to form a protective layer on the surface of the casting.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: December 9, 2014
    Assignee: General Electric Company
    Inventors: Michael Frances Xavier Gigliotti, Jr., Stephen Francis Rutkowski, Shyh-Chin Huang, Roger John Petterson, Luana Emiliana Iorio, Andrew John Elliott
  • Publication number: 20140251505
    Abstract: Optimal wetting and adhesion of the hot-dip coating by way of pre-oxidation in a DFF pre-heating furnace and humidification of the annealing atmosphere in a holding zone is achieved in a hot dip galvanised flat steel product.
    Type: Application
    Filed: July 5, 2012
    Publication date: September 11, 2014
    Applicant: THYSSENKRUPP STEEL EUROPE AG
    Inventors: Marc Blumenau, Oliver Brehm, Michael Peters, Rudolf Schoenenberg, Andreas Westerfeld, Martin Norden
  • Publication number: 20140227555
    Abstract: A base steel sheet has a hot-dip galvanized layer formed on a surface thereof, in which, in a steel sheet structure in a range of ? thickness to ? thickness centered around ¼ thickness of a sheet thickness from a surface, a volume fraction of a retained austenite phase is 5% or less, and a total volume fraction of phases of bainite, bainitic ferrite, fresh martensite, and tempered martensite is 40% or more, an average effective crystal grain diameter is 5.0 ?m or less, a maximum effective crystal grain diameter is 20 ?m or less, and a decarburized layer with a thickness of 0.01 ?m to 10.0 ?m is formed on a surface layer portion, in which a density of oxides dispersed in the decarburized layer is 1.0×1012 to 1.0×1016 oxides/m2, and an average grain diameter of the oxides is 500 nm or less.
    Type: Application
    Filed: September 28, 2012
    Publication date: August 14, 2014
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
  • Patent number: 8747573
    Abstract: The invention relates to a method for producing corrosion-resistant surfaces of nitrated or nitrocarburated steel components, the surfaces having roughness heights (Rz) of Rz?1.5 ?m. The method comprises the following steps: oxidation of the surfaces of the nitrated or nitrocarburated components in a first oxidation step; carrying out at least a second oxidation of the component surfaces in an immediately subsequent oxidation step; polishing the component surface in a final method step, directly after the final oxidation.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: June 10, 2014
    Assignee: Durferrit GmbH
    Inventor: Ulrich Baudis
  • Patent number: 8728252
    Abstract: A process for treating a non-ferrous metal component, comprising placing the component into a process chamber at an elevated temperature, biasing the component to have a potential capable of attracting ions, introducing oxygen into the chamber at a pressure such that a glow discharge comprising oxygen ions is generated, the process chamber additionally comprising a glow discharge ionization enhancing means, and activating the glow discharge ionization enhancing means thereby increasing charged species density of the glow discharge, the oxygen ions flowing towards the component and colliding the surface thereof at least some of which diffuse into the component.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: May 20, 2014
    Assignees: Tecvac Limited, The University of Sheffield
    Inventors: Junia Cristina Avelar Batista Wilson, Elliott Ashley Fielding Spain, Jonathan Housden, Allan Matthews, Adrian Leyland
  • Patent number: 8652271
    Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to feed water pipe made of carbon steel in a BWR plant. This film-forming aqueous solution is supplied into the feed water pipe through the circulation pipe, and then, a nickel metal film is formed on an inner surface of the feed water pipe. After the nickel metal film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the feed water pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the feed water pipe. Then, the nickel ferrite film is come into contact with water containing dissolved-oxygen at 150° C. or above to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe. Corrosion of the carbon steel member composing the plant can further reduce.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: February 18, 2014
    Assignee: Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
  • Patent number: 8652275
    Abstract: A process for melt dip coating a strip of high-tensile steel with alloy constituents including zinc and/or aluminum includes the following steps. The strip is heated in a continuous furnace initially in a reductive atmosphere to a temperature of approximately 650° C., at which the alloy constituents diffuse to the surface in small amounts. The surface, consisting predominantly of pure iron, is converted into an iron oxide layer by a short heat treatment at a temperature of up to 750° C. in a reaction chamber which is integrated in a continuous furnace and has an oxidizing atmosphere. In a subsequent annealing treatment at a higher temperature in a reductive atmosphere, this iron oxide layer prevents the alloy constituents from diffusing to the surface. In the reductive atmosphere, the iron oxide layer is converted into a pure iron layer to which the zinc and/or aluminum are applied in the molten bath with optimum adhesion.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: February 18, 2014
    Assignee: ThyssenKrupp Steel AG
    Inventors: Ronny Leuschner, Manfred Meurer, Wilhelm Warnecke, Sabine Zeizinger, Gernot Nothacker, Michael Ullmann, Norbert Schaffrath
  • Patent number: 8652272
    Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to a feed water pipe made of carbon steel in a BWR plant. This solution is supplied into the pipe through the circulation pipe, and a nickel metal film is formed on an inner surface of the pipe. After the film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the pipe. The nickel ferrite film comes into contact with water containing dissolved oxygen at or above 150° C. to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe.
    Type: Grant
    Filed: January 22, 2013
    Date of Patent: February 18, 2014
    Assignee: Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
  • Patent number: 8636854
    Abstract: A method for coating a flat steel product manufactured from a high strength steel with a metallic coating, wherein the flat steel product is initially subjected to a heat treatment, in order then, in the heated state, to be hot-dip galvanized with the metallic coating in a melting bath containing overall at least 85% zinc and/or aluminum. The heat treatment includes heating the steel product in a reducing atmosphere, followed by converting a surface of the flat product to an iron oxide layer by a heat treatment lasting 1 to 10 secs in an oxidizing atmosphere, followed by annealing in a reducing atmosphere over a period of time which is longer than the duration of the formation of the iron oxide layer such that the iron oxide layer is reduced at least on its surface to pure iron, followed by cooling the product to a melting bath temperature.
    Type: Grant
    Filed: April 26, 2006
    Date of Patent: January 28, 2014
    Assignee: ThyssenKrupp Steel AG
    Inventors: Ronny Leuschner, Manfred Meurer, Wilhelm Warnecke, Sabine Zeizinger, Gernot Nothacker, Michael Ullmann, Norbert Schaffrath
  • Publication number: 20130327604
    Abstract: A number of variations may include a brake rotor having a surface oxide layer and methods of making the same.
    Type: Application
    Filed: August 15, 2013
    Publication date: December 12, 2013
    Applicant: GM Global Technology Operations LLC
    Inventors: Michael L. Holly, Douglas N. Reed
  • Patent number: 8562751
    Abstract: A dry cleaning method of a substrate processing apparatus includes forming a metal oxide by oxidizing a metal film adhered to the inside of a processing chamber of the substrate processing apparatus; forming a complex by reacting the metal oxide with ?-diketone; and sublimating the complex to be removed. A cleaning gas containing oxygen and ?-diketone is supplied into the processing chamber while heating the inside of the processing chamber. A flow rate ratio of oxygen to ?-diketone in the cleaning gas is set such that a formation rate of the metal oxide is lower than a formation rate of the complex.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: October 22, 2013
    Assignees: Tokyo Electron Limited, Central Glass Company, Limited
    Inventors: Isao Gunji, Yusaku Izawa, Hitoshi Itoh, Tomonori Umezaki, Yuta Takeda, Isamu Mori
  • Patent number: 8529709
    Abstract: A method of reducing the formation of electrically resistive scale on a an article comprising a silicon-containing ferritic stainless subjected to oxidizing conditions in service includes, prior to placing the article in service, subjecting the article to conditions under which silica, which includes silicon derived from the steel, forms on a surface of the steel. Optionally, at least a portion of the silica is removed from the surface to placing the article in service. A ferritic stainless steel alloy having a reduced tendency to form silica on at least a surface thereof also is provided. The steel includes a near-surface region that has been depleted of silicon relative to a remainder of the steel.
    Type: Grant
    Filed: March 5, 2008
    Date of Patent: September 10, 2013
    Assignee: ATI Properties, Inc.
    Inventor: James M. Rakowski
  • Patent number: 8470102
    Abstract: The invention deals with a process for manufacturing a hot-dip galvanized or galvannealed steel sheet having a TRIP microstructure, said process comprising the steps consisting in: -providing a steel sheet whose composition comprises, by weight: 0.01?C?0.22%, 0.50?Mn?2.0%, 0.2?Si?2.0%, 0.005?Al?2.0%, Mo<1.0%, Cr?1.0%, P<0.02%, Ti?0.20%, V?0.40%, Ni?1.0%, Nb?0.20%, the balance of the composition being iron and unavoidable impurities resulting from the smelting, -oxidizing said steel sheet in a direct flame furnace where the atmosphere comprises air and fuel with an air-to-fuel ratio between 0.80 and 0.95, so that a layer of iron oxide having a thickness from 0.05 to 0.2 ?m is formed on the surface of the steel sheet, and an internal oxide of Si and/or Mn and/or Al is formed, -reducing said oxidized steel sheet, at a reduction rate from 0.001 to 0.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: June 25, 2013
    Assignee: ArcelorMittal France
    Inventors: Florence Bertrand, Didier Huin, Hubert Saint-Raymond
  • Patent number: 8470097
    Abstract: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance to a heat transfer component surface includes providing a silicon containing steel composition including an alloy and a Si-partitioned non-metallic film formed on a surface of the alloy. The alloy is formed from the composition ?, ?,and ?, in which ? is a metal selected from the group consisting of Fe, Ni, Co, and mixtures thereof, ? is Si, and ? is at least one alloying element selected from the group consisting of Cr, Al, Mn, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Sc, La, Y, Ce, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au, Ga, Ge, As, In, Sn, Sb, Pb, B, C, N, P, O, S and mixtures thereof. The Si-partitioned non-metallic film comprises at least one of sulfide, oxysulfide and mixtures thereof.
    Type: Grant
    Filed: May 15, 2012
    Date of Patent: June 25, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: ChangMin Chun, Mark A Greaney, Thomas Bruno, Ian A Cody, Trikur A Ramanarayanan, LeRoy A Clavenna
  • Patent number: 8465599
    Abstract: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance for a heat transfer component is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition ?, ?, and ?, wherein ? is a steel containing at least about 5 to about 40 wt. % chromium, ? is a chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) formed on the surface of the steel ?, wherein M is a metal containing at least 5 wt. % Cr based on the total weight of the metal M, and ? is a top layer formed on the surface of the chromium-enriched oxide ?, comprising sulfide, oxide, oxysulfide, and mixtures thereof. The top layer ? comprises iron sulfide (Fe1-xS), iron oxide (Fe3O4), iron oxysulfide, iron-chromium sulfide, iron-chromium oxide, iron-chromium oxysulfide, and mixtures thereof.
    Type: Grant
    Filed: July 28, 2011
    Date of Patent: June 18, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: ChangMin Chun, Mark A. Greaney, Thomas Bruno, Ian A. Cody, Trikur A. Ramanarayanan
  • Patent number: 8430973
    Abstract: The present invention relates to a process for improving the heat and corrosion resistance of stainless steel by means of a novel passivation process. This process comprises a chemical treatment with an aqueous solution comprising a complexing agent combination of at least one oxidant, a subsequent rinsing and a subsequent treatment at elevated temperature in an oxygen-containing atmosphere. The stainless steel surfaces obtained according to the invention have a homogeneous passive layer having increased chemical resistance and resistance to thermal discoloration.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: April 30, 2013
    Assignee: Poligrat GmbH
    Inventors: Olaf Böhme, Siegfried Piesslinger-Schweiger
  • Publication number: 20130098509
    Abstract: An object of the present invention is to provide a method for producing a surface-modified rare earth metal-based sintered magnet having extremely excellent corrosion resistance even in an environment with fluctuating temperature and humidity and also having excellent magnetic characteristics. The method for producing a surface-modified rare earth metal-based sintered magnet of the present invention as a means for achieving the object is characterized by comprising a step of subjecting a rare earth metal-based sintered magnet to a heat treatment at 200° C. to 600° C. in an atmosphere having an oxygen partial pressure of 1×103 Pa to 1×105 Pa and a water vapor partial pressure of 45 Pa or less with the ratio between the oxygen partial pressure and the water vapor partial pressure (oxygen partial pressure/water vapor partial pressure) being 450 to 20000.
    Type: Application
    Filed: June 29, 2011
    Publication date: April 25, 2013
    Applicant: HITACHI METALS, LTD.
    Inventors: Mahoro Fujihara, Koshi Yoshimura
  • Patent number: 8419866
    Abstract: A novel method of manufacturing a transition metal oxide having a spinel structure is provided. A mixture of powdery metals of metal elements constituting the transition metal oxide is heated in an oxidizing atmosphere to generate the transition metal oxide.
    Type: Grant
    Filed: January 27, 2010
    Date of Patent: April 16, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Takashi Ryu, Toshiyuki Nakamura, Makoto Ohmori
  • Publication number: 20130074992
    Abstract: A method of manufacturing a metal part according to the present invention includes heating a shaped product of stainless steel to 600° C. or more in an oxygen-free atmosphere and heat-treating the shaped product in an oxygen atmosphere after the heating.
    Type: Application
    Filed: September 13, 2012
    Publication date: March 28, 2013
    Applicant: NHK SPRING CO., LTD.
    Inventors: Ryuichi Kawatake, Takashi Maruyama
  • Patent number: 8382916
    Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: February 26, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
  • Publication number: 20120308917
    Abstract: One aspect of the invention is a method of surface alloying stainless steel, In one embodiment, the method includes providing a stainless steel surface having an initial amount of iron and an initial amount of chromium; and preferentially removing iron from the stainless steel surface to obtain a surface having an amount of iron less than the initial amount of iron and an amount of chromium greater than the initial amount of chromium. Another aspect of the invention is a unitary stainless steel article.
    Type: Application
    Filed: June 6, 2011
    Publication date: December 6, 2012
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Mahmoud H. Abd Elhamid, Gayatri Vyas Dadheech
  • Patent number: 8287663
    Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: October 16, 2012
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, Bryce D. Devine
  • Publication number: 20120246935
    Abstract: A method and device for reducing sulfidation corrosion and depositional fouling in heat transfer components within a refining or petrochemical facility is disclosed. The heat transfer components are formed from a corrosion and fouling resistant steel composition containing a Cr-enriched layer having a surface roughness of less than 40 micro inches (1.1 ?m) and a protective layer formed thereon.
    Type: Application
    Filed: May 15, 2012
    Publication date: October 4, 2012
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Mark A. GREANEY, Thomas BRUNO, Ashley E. COOPER, Ian A. CODY, ChangMin CHUN
  • Patent number: 8216394
    Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.
    Type: Grant
    Filed: August 14, 2006
    Date of Patent: July 10, 2012
    Assignee: Kobe Steel, Ltd.
    Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
  • Patent number: 8187359
    Abstract: An object of the present invention is to provide a method for producing granulated metallic iron superior in rust resistance. Another object of the present invention is to provide a method for producing such granulated metallic iron. In the method, the granulated metallic iron is produced by agglomerating a material mixture including an iron-oxide-containing material and a carbonaceous reducing agent; charging and heating the agglomerated material mixture in a moving hearth-type reducing furnace to reduce the iron oxide in the material mixture with the carbonaceous reducing agent to obtain hot granulated metallic iron; and cooling the hot granulated metallic iron, wherein the hot granulated metallic iron is cooled while its relative position is changed; and an oxide coating is formed on the surface of the hot granulated metallic iron by bringing moisture into contact with almost the entire surface of the hot granulated metallic iron.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: May 29, 2012
    Assignee: Mesabi Nugget LLC
    Inventors: Koji Tokuda, Osamu Tsuge
  • Publication number: 20120085310
    Abstract: An engine valve comprising a chromiferous steel and a protective surface layer (5) which consists of iron chrome oxide. A method for manufacture of an engine valve with a protective layer includes an engine component of a chromiferous steel which is heated (200) at a predetermined temperature for a predetermined time so that a layer (5) of iron chrome oxide is formed on the engine component's surface, and the engine component is then cooled (300) to room temperature.
    Type: Application
    Filed: June 14, 2010
    Publication date: April 12, 2012
    Inventor: Magnus Bergström
  • Publication number: 20110186131
    Abstract: A substrate for selenium compound semiconductor has at least a steel base and an aluminum base. The aluminum base is arranged on one end in a direction of lamination of the steel base and the aluminum base, the steel base is arranged on the other end in the direction. An alloy layer having a thickness of from 0.01 ?m to 10 ?m is formed between the steel base and the aluminum base. A thermal oxide film having a thickness of 6 nm or more is formed on a surface of the steel base opposite to the aluminum base.
    Type: Application
    Filed: January 28, 2011
    Publication date: August 4, 2011
    Applicant: FUJIFILM Corporation
    Inventors: Atsushi MUKAI, Shigenori Yuya, Toshiaki Fukunaga, Ryuichi Nakayama
  • Publication number: 20110139308
    Abstract: The invention relates to a method for the production and removal of a temporary protective layer for a cathodic coating, particularly for the production of a hardened steel component with an easily paintable surface, wherein a steel sheet made of a hardenable steel alloy is subjected to a preoxidation, wherein said preoxidation forms a FeO layer with a thickness of 100 nm to 1,000 nm and subsequently a melt dip coating is conducted, wherein, during the melt dip coating, a zinc layer is applied having a thickness of 5 to 20 ?m, preferably 7 to 14 ?m, on each side, wherein the melt dip process and the aluminum content of the zinc bath is adjusted such that, during the melt dip coating, an aluminum content for the barrier layer results of 0.15 g/m2 to 0.
    Type: Application
    Filed: January 30, 2008
    Publication date: June 16, 2011
    Applicant: VOESTALPINE STAHL GMBH
    Inventors: Martin Peruzzi, Josef Faderl, Siegfried Kolnberger, Werner Brandstatter
  • Patent number: 7901467
    Abstract: A process for treating the working surfaces of equipment used in the production and processing of polycarbonate is disclosed. The thermal treatment in an oxidative atmosphere results in resin and molded articles having improved optical quality.
    Type: Grant
    Filed: October 25, 2007
    Date of Patent: March 8, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Wolfgang Ebert, Rainer Mellis, Alexander Meyer, Bert Ruytinx, Alexander Karbach, Delef Michalski-Vollmer
  • Patent number: 7850791
    Abstract: Alloys containing aluminium are characterised by an outstanding oxidation resistance at high temperatures, that is based on, inter alia, the formation of a thick and slow-growing aluminium oxide layer on material surfaces. If the formation of the aluminium oxide layer reduces the aluminium content of the alloy so far that a critical aluminium concentration is not reached, no other protective aluminium oxide layer can be formed. This leads disadvantageously to a very rapid breakaway oxidation, and the destruction of the component. This effect is stronger at temperatures above 800° C. due to the fact that, often at this point, metastable Al2O3 modifications, especially ?- or ?-Al2O3, are formed instead of ?-Al2O3 that is generally formed at high temperatures. The above-mentioned oxide modifications are disadvantageously characterised by significantly higher growth rates.
    Type: Grant
    Filed: November 20, 2004
    Date of Patent: December 14, 2010
    Assignee: Forschungszentrum Julich GmbH
    Inventor: Willem J. Quadakkers
  • Patent number: 7811392
    Abstract: It is an object of the present invention to efficiently suppress radionuclide deposition on a reactor component of nuclear power plant. Radionuclide deposition on the surface of a metallic reactor component of nuclear power plant is suppressed by forming a ferrite film on the component, wherein the film is formed, after decontamination for removing radionuclides contaminants from the component surface is completed and before the plant is started up, by contacting a treatment solution which mixes a first agent containing the iron (II) ions, a second agent for oxidizing the iron (II) ions into the iron (III) ions and a third agent for adjusting pH level of a solution to 5.5 to 9.0 in this order with the reactor component surface.
    Type: Grant
    Filed: July 14, 2006
    Date of Patent: October 12, 2010
    Assignee: Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Hideyuki Hosokawa, Makoto Nagase, Kazushige Ishida, Youichi Wada, Naoshi Usui, Motohiro Aizawa, Motomasa Fuse
  • Publication number: 20100236667
    Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.
    Type: Application
    Filed: June 7, 2010
    Publication date: September 23, 2010
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
  • Publication number: 20100193082
    Abstract: The method of surface treatment, as applied onto a metal base material, of the present invention includes a reduction treatment step of reduction-treating the oxide film formed on the metal base material and an oxidation treatment step of oxidation-treating the oxide film having been subjected to the reduction treatment.
    Type: Application
    Filed: July 10, 2008
    Publication date: August 5, 2010
    Inventors: Hajime Hasegawa, Yusuke Watanabe
  • Patent number: 7673541
    Abstract: Colored razor blades are provided. Methods for manufacturing such blades are also provided, including methods involving depositing an oxide coating prior to heat treatment of the blade material and heat treating under conditions selected to enhance the color of the coating.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: March 9, 2010
    Assignee: The Gillette Company
    Inventors: Kenneth J. Skrobis, Alfred Porcaro, Ronald J. Swanson, Eric Liu
  • Publication number: 20090252991
    Abstract: Provided is an iron nitride-based magnetic powder that comprises magnetic particles having a mean particle size of at most 20 nm. The magnetic particle has a core of a main phase of Fe16N2 and has, on the outer side of the core, an oxide phase derived from a metal Fe phase formed by reduction of iron nitride. In relation to the weatherability index ??s and the saturation magnetization as thereof, the magnetic powder satisfies ??s?0.8×?s?30. In this, ??s=(?s??s1)/?s×100. ?s1 means the saturation magnetization of the magnetic powder kept in an atmosphere of 60° C. and 90% RH for 1 week. The powder can be obtained by exposing powder particles having a main phase of Fe16N2 to a reducing gas to partly reduce the region of the surface of the particles into a metal Fe phase (gradual reduction) followed by exposing them to an oxidizing gas to oxidize a part of the surface of the metal Fe phase into an oxide phase (gradual oxidation).
    Type: Application
    Filed: June 8, 2007
    Publication date: October 8, 2009
    Inventors: Yuzo Ishikawa, Kenji Masada