Oxide Of Iron Formed Patents (Class 148/287)
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Patent number: 12012365Abstract: The invention provides methods and compositions that prevent, mitigate or delay the onset of corrosion of iron or steel (e.g., plain carbon steel) components used as reinforcement or otherwise at least partially embedded in carbonated concrete composite materials and objects based on carbonatable calcium silicate cement.Type: GrantFiled: February 22, 2019Date of Patent: June 18, 2024Assignee: SOLIDIA TECHNOLOGIES, LTD.Inventors: Jitendra Jain, Anuj Seth, Vahit Atakan, Ahmet Cuneyt Tas, Sadanada Sahu
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Patent number: 11708622Abstract: A bolt of the present invention has a composition comprising: 0.50 mass % or greater and 0.65 mass % or less of carbon (C), 1.5 mass % or greater and 2.5 mass % or less of silicon (Si), 1.0 mass % or greater and 2.0 mass % or less of chromium (Cr), 0.2 mass % or greater and 1.0 mass % or less of manganese (Mn), 1.5 mass % or greater and 5.0 mass % or less of molybdenum (Mo), wherein a total amount of phosphorous (P) and sulfur (S) as impurities is 0.03 mass % or less, the remaining is iron (Fe), and the bolt comprises an iron based oxide film with a film thickness of 3 ?m or greater and 20 ?m or less on the surface thereof. The bolt has excellent delayed fracture resistance and reliably provides a fastening axial force.Type: GrantFiled: January 30, 2018Date of Patent: July 25, 2023Assignee: NISSAN MOTOR CO., LTD.Inventors: Takahiro Hamada, Daisuke Kobayashi
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Patent number: 11697879Abstract: Embodiments of the present disclosure generally relate to protective coatings on aerospace components and methods for depositing the protective coatings. In one or more embodiments, a method for producing a protective coating on an aerospace component includes depositing a metal oxide template layer on the aerospace component containing nickel and aluminum (e.g., nickel-aluminum superalloy) and heating the aerospace component containing the metal oxide template layer during a thermal process and/or an oxidation process. The thermal process and/or oxidation process includes diffusing aluminum contained within the aerospace component towards a surface of the aerospace component containing the metal oxide template layer, oxidizing the diffused aluminum to produce an aluminum oxide layer disposed between the aerospace component and the metal oxide template layer, and removing at least a portion of the metal oxide template layer while leaving the aluminum oxide layer.Type: GrantFiled: September 4, 2019Date of Patent: July 11, 2023Assignee: APPLIED MATERIALS, INC.Inventors: Sukti Chatterjee, Kenichi Ohno, Lance A. Scudder, Yuriy Melnik, David A. Britz, Pravin K. Narwankar, Thomas Knisley, Mark Saly, Jeffrey Anthis
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Patent number: 11618714Abstract: A method of producing a carbonated composite material includes: providing a carbonatable cementitious material in particulate form; mixing the carbonatable cementitious material with water to produce a mix; forming a predetermined shape with the mix, wherein the predetermined shape has an initial pore structure containing an initial pore solution having a first pH; pre-conditioning the predetermined shape to remove a predetermined amount of the water from the predetermined shape to produce a pre-conditioned shape; carbonating the pre-conditioned shape in an environment comprising carbon dioxide to produce a modified pore structure containing a modified pore solution having and a second pH, wherein the difference between the first pH and the second pH is represented by a ?pH, and the ?pH is 1.0 or less.Type: GrantFiled: October 9, 2020Date of Patent: April 4, 2023Assignee: Solidia Technologies, Inc.Inventors: Anuj Seth, Jitendra Arunchandra Jain, Yussuf Sultan Ali, Matthew David Sulik, Dishen Patel, Makar Makram Ibrahim
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Patent number: 11414738Abstract: An apparatus for manufacturing a stress relieved length of steel having an oxidised surface layer includes: a heating chamber; a reaction chamber coupled to the heating chamber; and a conveying mechanism conveying the length of steel along a path through the heating chamber and reaction chamber. The heating chamber includes a heating apparatus arranged to heat the length of steel in a heating portion of the path. The apparatus further includes a control means including a sealed unit defined by the heating chamber and the reaction chamber and arranged to control both the temperature of the length of steel and the atmosphere to which the length of steel is exposed in an oxidisation portion of the path within the reaction chamber in which the oxidised surface layer is formed. A method of manufacturing a stress relieved length of steel having an oxidised surface layer is also disclosed.Type: GrantFiled: September 28, 2017Date of Patent: August 16, 2022Assignee: Liberty Performance Steels LimitedInventor: Carl Jukes
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Patent number: 11326243Abstract: Low-density hot dip galvanized steel, comprising a steel substrate (1) located at a core portion and a coating layer (3) located on the surface. An interface layer is disposed between the steel substrate (1) and the coating layer (3), the interface layer comprises an iron particle layer (4), iron particles dispersed on the steel substrate (1) and covering the steel substrate (1) are disposed in the iron particle layer (4), and the iron particles are covered by a first inhibition layer (5). The low-density hot dip galvanized steel contains element Al in a mass percentage of 3.0% to 7.0%. Correspondingly, the present invention also comprises a manufacturing method for the low-density hot dip galvanized steel. The low-density hot dip galvanized steel has a low density, a high strength and high galvanizability and coating layer adhesion.Type: GrantFiled: June 14, 2017Date of Patent: May 10, 2022Assignee: BAOSHAN IRON & STEEL CO., LTD.Inventors: Xinyan Jin, Qi Yang, Li Wang, Guangkui Hu
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Patent number: 10697053Abstract: The purpose of the present invention is to provides a method for manufacturing a black plated steel sheet that is capable of more evenly blackening the area of the plated steel sheet to be blackened. The present invention relates to a method for manufacturing a black plated steel sheet by bringing a plated steel sheet with an Al- and Mg-containing hot-dip galvanized layer into contact with water vapor inside a sealed vessel. This method performs, in the following order: a first step for heating a plated steel sheet disposed inside a sealed vessel in the presence of a gas, the dew point of which is always less than the plated steel sheet temperature; a second step for evacuating the heated ambient gas inside the sealed vessel to make the pressure of the gas inside the sealed vessel to be 70 kPa or less; and a third step for introducing water vapor inside the sealed vessel in which the pressure of the gas therein has been reduced to 70 kPa or less to blacken the galvanized layer.Type: GrantFiled: August 9, 2016Date of Patent: June 30, 2020Assignee: NISSHIN STEEL CO., LTD.Inventors: Tadashi Nakano, Shin Ueno, Masaya Yamamoto
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Patent number: 10648738Abstract: System and method for using fast response heaters to pre-heat metal before entering a metal treatment furnace, which may improve control over metal processing, especially in response to changes in material, mass flow rate, line speed, and/or desired treatment process. Fast response heaters may be used with control systems to adjust the output of the fast response heater based on operator inputs, direct or indirect sensing of process parameters, and/or the use of thermal models to quickly adjust fast response heater output while a metal treatment furnace remains at a constant temperature or slowly transitions into a new operating state. The resulting gains in process control result in higher quality products, reduced scrap, and increases in line speed and output.Type: GrantFiled: June 23, 2016Date of Patent: May 12, 2020Assignee: NOVELIS INC.Inventors: David Michael Custers, Michael Bull, Andrew Hobbis
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Patent number: 10385438Abstract: There is provided a heat resistant ferritic steel including a base material including, by mass percent, C: 0.01 to 0.3%, Si: 0.01 to 2%, Mn: 0.01 to 2%, P: at most 0.10%, 5: at most 0.03%, Cr: 7.5 to 14.0%, sol.Al: at most 0.3%, and N: 0.005 to 0.15%, the balance being Fe and impurities, and an oxide film that is formed on the base material and contains 25 to 97% of Fe and 3 to 75% of Cr. This heat resistant ferritic steel is excellent in photoselective absorptivity and oxidation resistance.Type: GrantFiled: April 13, 2017Date of Patent: August 20, 2019Assignee: NIPPON STEEL CORPORATIONInventors: Yoshitaka Nishiyama, Shunichi Otsuka
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Patent number: 9738946Abstract: A method for producing a silicon steel normalizing substrate comprises steelmaking, hot rolling and normalizing steps. A normalizing furnace is used in the normalizing step, and along a moving direction of strip steel, the normalizing furnace sequentially comprises: a preheating section, a nonoxidizing heating section, a furnace throat, furnace sections for subsequent normalizing processing, and a delivery seal chamber. Furnace pressures of the normalizing furnace are distributed as follows: the furnace pressure of a downstream furnace section adjacent to the furnace throat along the moving direction of the strip steel is the highest, the furnace pressure decreases gradually from the furnace section with the highest furnace pressure to a furnace section in an inlet direction of the normalizing furnace, and the furnace pressure decreases gradually from the furnace section with the highest furnace pressure to a furnace section in an outlet direction of the normalizing furnace.Type: GrantFiled: March 27, 2012Date of Patent: August 22, 2017Assignee: Baoshan Iron & Steel, Co., Ltd.Inventors: Hongxu Hei, Xiao Chen, Xiandong Liu, Shishu Xie, Dejun Su, Runjie Lin, Peili Zhang, Rongqiang Jiang, Miao Ye
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Patent number: 9441893Abstract: Described herein are devices and methods for thawing frozen biological products efficiently without harming the products.Type: GrantFiled: March 14, 2013Date of Patent: September 13, 2016Assignee: Grifols, S.A.Inventors: Ajoy Velayudhan, Robert Large
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Patent number: 9115433Abstract: In a method for surface treatment of stainless steel, the thermally produced layers of oxide are contacted with a composition effective to dissolve iron ions out of the layers of oxide.Type: GrantFiled: October 15, 2009Date of Patent: August 25, 2015Assignee: POLIGRAT GMBHInventors: Olaf Boehme, Siegfried Piesslinger-Schweiger
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Patent number: 9040168Abstract: The galvannealed steel sheet includes: a galvannealed layer formed on at least one surface of a steel sheet and contains includes an amount of 0.05 mass % to 0.5 mass % of Al, an amount of 6 mass % of 12 mass % of Fe, and the balance composed of Zn and inevitable impurities; and a mixed layer formed on a surface of the galvannealed layer and includes a composite oxide of Mn, Zn, and P and an aqueous P compound, wherein the composite oxide includes 0.1 mg/m2 to 100 mg/m2 of Mn, an amount of 1 mg/m2 to 100 mg/m2 of P, and Zn, and a P/Mn ratio is 0.3 to 50, and wherein the total size of an area of the mixed layer in which an attached amount of P is equal to or more than 20 mg/m2 is 20% to 80% of a surface area of the mixed layer.Type: GrantFiled: July 12, 2010Date of Patent: May 26, 2015Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Kazuhiko Honda, Noriyuki Suzuki, Yoichi Ikematsu
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Publication number: 20150007808Abstract: A glass-to-metal sealing device of a solar receiver has a metal collar and a glass cylinder to be sealed together. The glass cylinder is made of a borosilicate glass having a coefficient of thermal expansion within the range of [3.1, 3.5]·10?6° C.?1 in a temperature range of [50, 450]° C. The metal collar s made of an austenitic alloy having a coefficient of thermal expansion in the range of [3.5, 6.0]·10?6° C.?1 in the temperature range of [50, 450]° C. The end portion of the metal collar is beveled so as to increase its mechanical flexibility and, further, the end portion of the metal collar is processed via a thermal treatment in order to establish a bond between the metal and the glass surfaces.Type: ApplicationFiled: January 22, 2013Publication date: January 8, 2015Applicant: ARCHIMEDE SOLAR ENERGY S.R.L.Inventors: Thomas Chiarappa, Claudio Raggi
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Publication number: 20150003935Abstract: A steel is used for providing a bolt that has a high strength and still exhibits excellent hydrogen embrittlement resistance. The steel contains C of 0.30% to 0.50%, Si of 1.0% to 2.5%, Mn of 0.1% to 1.5%, P of greater than 0% to 0.015%, S of greater than 0% to 0.015%, Cr of 0.15% to 2.4%, Al of 0.010% to 0.10%, N of 0.001% to 0.10%, Cu of 0.1% to 0.50%, Ni of 0.1% to 1.0%, Ti of 0.05% to 0.2%, and V of 0% to 0.2%, with the remainder including iron and inevitable impurities, in which a ratio [Ni]/[Cu] is 0.5 or more, and a total content [Ti]+[V] is 0.085% to 0.30%.Type: ApplicationFiled: November 26, 2012Publication date: January 1, 2015Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yosuke Matsumoto, Atsushi Inada, Masamichi Chiba
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Patent number: 8906170Abstract: An alloy casting having a protective layer disposed on a surface of the casting is provided. The protective layer is resistant to liquid metal attack, and wherein the protective layer includes an oxide of an element present in the alloy. A method of forming a protective layer on a surface of the alloy casting is also provided. The method includes disposing the alloy in a mold, and oxidizing an element of the alloy to form a protective layer on the surface of the casting.Type: GrantFiled: June 24, 2008Date of Patent: December 9, 2014Assignee: General Electric CompanyInventors: Michael Frances Xavier Gigliotti, Jr., Stephen Francis Rutkowski, Shyh-Chin Huang, Roger John Petterson, Luana Emiliana Iorio, Andrew John Elliott
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Publication number: 20140251505Abstract: Optimal wetting and adhesion of the hot-dip coating by way of pre-oxidation in a DFF pre-heating furnace and humidification of the annealing atmosphere in a holding zone is achieved in a hot dip galvanised flat steel product.Type: ApplicationFiled: July 5, 2012Publication date: September 11, 2014Applicant: THYSSENKRUPP STEEL EUROPE AGInventors: Marc Blumenau, Oliver Brehm, Michael Peters, Rudolf Schoenenberg, Andreas Westerfeld, Martin Norden
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Publication number: 20140227555Abstract: A base steel sheet has a hot-dip galvanized layer formed on a surface thereof, in which, in a steel sheet structure in a range of ? thickness to ? thickness centered around ¼ thickness of a sheet thickness from a surface, a volume fraction of a retained austenite phase is 5% or less, and a total volume fraction of phases of bainite, bainitic ferrite, fresh martensite, and tempered martensite is 40% or more, an average effective crystal grain diameter is 5.0 ?m or less, a maximum effective crystal grain diameter is 20 ?m or less, and a decarburized layer with a thickness of 0.01 ?m to 10.0 ?m is formed on a surface layer portion, in which a density of oxides dispersed in the decarburized layer is 1.0×1012 to 1.0×1016 oxides/m2, and an average grain diameter of the oxides is 500 nm or less.Type: ApplicationFiled: September 28, 2012Publication date: August 14, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
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Patent number: 8747573Abstract: The invention relates to a method for producing corrosion-resistant surfaces of nitrated or nitrocarburated steel components, the surfaces having roughness heights (Rz) of Rz?1.5 ?m. The method comprises the following steps: oxidation of the surfaces of the nitrated or nitrocarburated components in a first oxidation step; carrying out at least a second oxidation of the component surfaces in an immediately subsequent oxidation step; polishing the component surface in a final method step, directly after the final oxidation.Type: GrantFiled: October 29, 2008Date of Patent: June 10, 2014Assignee: Durferrit GmbHInventor: Ulrich Baudis
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Patent number: 8728252Abstract: A process for treating a non-ferrous metal component, comprising placing the component into a process chamber at an elevated temperature, biasing the component to have a potential capable of attracting ions, introducing oxygen into the chamber at a pressure such that a glow discharge comprising oxygen ions is generated, the process chamber additionally comprising a glow discharge ionization enhancing means, and activating the glow discharge ionization enhancing means thereby increasing charged species density of the glow discharge, the oxygen ions flowing towards the component and colliding the surface thereof at least some of which diffuse into the component.Type: GrantFiled: March 24, 2008Date of Patent: May 20, 2014Assignees: Tecvac Limited, The University of SheffieldInventors: Junia Cristina Avelar Batista Wilson, Elliott Ashley Fielding Spain, Jonathan Housden, Allan Matthews, Adrian Leyland
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Patent number: 8652271Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to feed water pipe made of carbon steel in a BWR plant. This film-forming aqueous solution is supplied into the feed water pipe through the circulation pipe, and then, a nickel metal film is formed on an inner surface of the feed water pipe. After the nickel metal film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the feed water pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the feed water pipe. Then, the nickel ferrite film is come into contact with water containing dissolved-oxygen at 150° C. or above to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe. Corrosion of the carbon steel member composing the plant can further reduce.Type: GrantFiled: August 3, 2010Date of Patent: February 18, 2014Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
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Patent number: 8652275Abstract: A process for melt dip coating a strip of high-tensile steel with alloy constituents including zinc and/or aluminum includes the following steps. The strip is heated in a continuous furnace initially in a reductive atmosphere to a temperature of approximately 650° C., at which the alloy constituents diffuse to the surface in small amounts. The surface, consisting predominantly of pure iron, is converted into an iron oxide layer by a short heat treatment at a temperature of up to 750° C. in a reaction chamber which is integrated in a continuous furnace and has an oxidizing atmosphere. In a subsequent annealing treatment at a higher temperature in a reductive atmosphere, this iron oxide layer prevents the alloy constituents from diffusing to the surface. In the reductive atmosphere, the iron oxide layer is converted into a pure iron layer to which the zinc and/or aluminum are applied in the molten bath with optimum adhesion.Type: GrantFiled: December 2, 2005Date of Patent: February 18, 2014Assignee: ThyssenKrupp Steel AGInventors: Ronny Leuschner, Manfred Meurer, Wilhelm Warnecke, Sabine Zeizinger, Gernot Nothacker, Michael Ullmann, Norbert Schaffrath
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Patent number: 8652272Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to a feed water pipe made of carbon steel in a BWR plant. This solution is supplied into the pipe through the circulation pipe, and a nickel metal film is formed on an inner surface of the pipe. After the film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the pipe. The nickel ferrite film comes into contact with water containing dissolved oxygen at or above 150° C. to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe.Type: GrantFiled: January 22, 2013Date of Patent: February 18, 2014Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
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Patent number: 8636854Abstract: A method for coating a flat steel product manufactured from a high strength steel with a metallic coating, wherein the flat steel product is initially subjected to a heat treatment, in order then, in the heated state, to be hot-dip galvanized with the metallic coating in a melting bath containing overall at least 85% zinc and/or aluminum. The heat treatment includes heating the steel product in a reducing atmosphere, followed by converting a surface of the flat product to an iron oxide layer by a heat treatment lasting 1 to 10 secs in an oxidizing atmosphere, followed by annealing in a reducing atmosphere over a period of time which is longer than the duration of the formation of the iron oxide layer such that the iron oxide layer is reduced at least on its surface to pure iron, followed by cooling the product to a melting bath temperature.Type: GrantFiled: April 26, 2006Date of Patent: January 28, 2014Assignee: ThyssenKrupp Steel AGInventors: Ronny Leuschner, Manfred Meurer, Wilhelm Warnecke, Sabine Zeizinger, Gernot Nothacker, Michael Ullmann, Norbert Schaffrath
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Publication number: 20130327604Abstract: A number of variations may include a brake rotor having a surface oxide layer and methods of making the same.Type: ApplicationFiled: August 15, 2013Publication date: December 12, 2013Applicant: GM Global Technology Operations LLCInventors: Michael L. Holly, Douglas N. Reed
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Patent number: 8562751Abstract: A dry cleaning method of a substrate processing apparatus includes forming a metal oxide by oxidizing a metal film adhered to the inside of a processing chamber of the substrate processing apparatus; forming a complex by reacting the metal oxide with ?-diketone; and sublimating the complex to be removed. A cleaning gas containing oxygen and ?-diketone is supplied into the processing chamber while heating the inside of the processing chamber. A flow rate ratio of oxygen to ?-diketone in the cleaning gas is set such that a formation rate of the metal oxide is lower than a formation rate of the complex.Type: GrantFiled: January 17, 2012Date of Patent: October 22, 2013Assignees: Tokyo Electron Limited, Central Glass Company, LimitedInventors: Isao Gunji, Yusaku Izawa, Hitoshi Itoh, Tomonori Umezaki, Yuta Takeda, Isamu Mori
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Patent number: 8529709Abstract: A method of reducing the formation of electrically resistive scale on a an article comprising a silicon-containing ferritic stainless subjected to oxidizing conditions in service includes, prior to placing the article in service, subjecting the article to conditions under which silica, which includes silicon derived from the steel, forms on a surface of the steel. Optionally, at least a portion of the silica is removed from the surface to placing the article in service. A ferritic stainless steel alloy having a reduced tendency to form silica on at least a surface thereof also is provided. The steel includes a near-surface region that has been depleted of silicon relative to a remainder of the steel.Type: GrantFiled: March 5, 2008Date of Patent: September 10, 2013Assignee: ATI Properties, Inc.Inventor: James M. Rakowski
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Patent number: 8470102Abstract: The invention deals with a process for manufacturing a hot-dip galvanized or galvannealed steel sheet having a TRIP microstructure, said process comprising the steps consisting in: -providing a steel sheet whose composition comprises, by weight: 0.01?C?0.22%, 0.50?Mn?2.0%, 0.2?Si?2.0%, 0.005?Al?2.0%, Mo<1.0%, Cr?1.0%, P<0.02%, Ti?0.20%, V?0.40%, Ni?1.0%, Nb?0.20%, the balance of the composition being iron and unavoidable impurities resulting from the smelting, -oxidizing said steel sheet in a direct flame furnace where the atmosphere comprises air and fuel with an air-to-fuel ratio between 0.80 and 0.95, so that a layer of iron oxide having a thickness from 0.05 to 0.2 ?m is formed on the surface of the steel sheet, and an internal oxide of Si and/or Mn and/or Al is formed, -reducing said oxidized steel sheet, at a reduction rate from 0.001 to 0.Type: GrantFiled: June 11, 2008Date of Patent: June 25, 2013Assignee: ArcelorMittal FranceInventors: Florence Bertrand, Didier Huin, Hubert Saint-Raymond
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Patent number: 8470097Abstract: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance to a heat transfer component surface includes providing a silicon containing steel composition including an alloy and a Si-partitioned non-metallic film formed on a surface of the alloy. The alloy is formed from the composition ?, ?,and ?, in which ? is a metal selected from the group consisting of Fe, Ni, Co, and mixtures thereof, ? is Si, and ? is at least one alloying element selected from the group consisting of Cr, Al, Mn, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Sc, La, Y, Ce, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au, Ga, Ge, As, In, Sn, Sb, Pb, B, C, N, P, O, S and mixtures thereof. The Si-partitioned non-metallic film comprises at least one of sulfide, oxysulfide and mixtures thereof.Type: GrantFiled: May 15, 2012Date of Patent: June 25, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: ChangMin Chun, Mark A Greaney, Thomas Bruno, Ian A Cody, Trikur A Ramanarayanan, LeRoy A Clavenna
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Patent number: 8465599Abstract: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance for a heat transfer component is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition ?, ?, and ?, wherein ? is a steel containing at least about 5 to about 40 wt. % chromium, ? is a chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) formed on the surface of the steel ?, wherein M is a metal containing at least 5 wt. % Cr based on the total weight of the metal M, and ? is a top layer formed on the surface of the chromium-enriched oxide ?, comprising sulfide, oxide, oxysulfide, and mixtures thereof. The top layer ? comprises iron sulfide (Fe1-xS), iron oxide (Fe3O4), iron oxysulfide, iron-chromium sulfide, iron-chromium oxide, iron-chromium oxysulfide, and mixtures thereof.Type: GrantFiled: July 28, 2011Date of Patent: June 18, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: ChangMin Chun, Mark A. Greaney, Thomas Bruno, Ian A. Cody, Trikur A. Ramanarayanan
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Patent number: 8430973Abstract: The present invention relates to a process for improving the heat and corrosion resistance of stainless steel by means of a novel passivation process. This process comprises a chemical treatment with an aqueous solution comprising a complexing agent combination of at least one oxidant, a subsequent rinsing and a subsequent treatment at elevated temperature in an oxygen-containing atmosphere. The stainless steel surfaces obtained according to the invention have a homogeneous passive layer having increased chemical resistance and resistance to thermal discoloration.Type: GrantFiled: February 22, 2008Date of Patent: April 30, 2013Assignee: Poligrat GmbHInventors: Olaf Böhme, Siegfried Piesslinger-Schweiger
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Publication number: 20130098509Abstract: An object of the present invention is to provide a method for producing a surface-modified rare earth metal-based sintered magnet having extremely excellent corrosion resistance even in an environment with fluctuating temperature and humidity and also having excellent magnetic characteristics. The method for producing a surface-modified rare earth metal-based sintered magnet of the present invention as a means for achieving the object is characterized by comprising a step of subjecting a rare earth metal-based sintered magnet to a heat treatment at 200° C. to 600° C. in an atmosphere having an oxygen partial pressure of 1×103 Pa to 1×105 Pa and a water vapor partial pressure of 45 Pa or less with the ratio between the oxygen partial pressure and the water vapor partial pressure (oxygen partial pressure/water vapor partial pressure) being 450 to 20000.Type: ApplicationFiled: June 29, 2011Publication date: April 25, 2013Applicant: HITACHI METALS, LTD.Inventors: Mahoro Fujihara, Koshi Yoshimura
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Patent number: 8419866Abstract: A novel method of manufacturing a transition metal oxide having a spinel structure is provided. A mixture of powdery metals of metal elements constituting the transition metal oxide is heated in an oxidizing atmosphere to generate the transition metal oxide.Type: GrantFiled: January 27, 2010Date of Patent: April 16, 2013Assignee: NGK Insulators, Ltd.Inventors: Takashi Ryu, Toshiyuki Nakamura, Makoto Ohmori
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Publication number: 20130074992Abstract: A method of manufacturing a metal part according to the present invention includes heating a shaped product of stainless steel to 600° C. or more in an oxygen-free atmosphere and heat-treating the shaped product in an oxygen atmosphere after the heating.Type: ApplicationFiled: September 13, 2012Publication date: March 28, 2013Applicant: NHK SPRING CO., LTD.Inventors: Ryuichi Kawatake, Takashi Maruyama
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Patent number: 8382916Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.Type: GrantFiled: June 7, 2010Date of Patent: February 26, 2013Assignee: Kobe Steel, Ltd.Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
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Publication number: 20120308917Abstract: One aspect of the invention is a method of surface alloying stainless steel, In one embodiment, the method includes providing a stainless steel surface having an initial amount of iron and an initial amount of chromium; and preferentially removing iron from the stainless steel surface to obtain a surface having an amount of iron less than the initial amount of iron and an amount of chromium greater than the initial amount of chromium. Another aspect of the invention is a unitary stainless steel article.Type: ApplicationFiled: June 6, 2011Publication date: December 6, 2012Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Mahmoud H. Abd Elhamid, Gayatri Vyas Dadheech
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Patent number: 8287663Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.Type: GrantFiled: May 17, 2011Date of Patent: October 16, 2012Assignee: Birchwood Laboratories, Inc.Inventors: William V. Block, Bryce D. Devine
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Publication number: 20120246935Abstract: A method and device for reducing sulfidation corrosion and depositional fouling in heat transfer components within a refining or petrochemical facility is disclosed. The heat transfer components are formed from a corrosion and fouling resistant steel composition containing a Cr-enriched layer having a surface roughness of less than 40 micro inches (1.1 ?m) and a protective layer formed thereon.Type: ApplicationFiled: May 15, 2012Publication date: October 4, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Mark A. GREANEY, Thomas BRUNO, Ashley E. COOPER, Ian A. CODY, ChangMin CHUN
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Patent number: 8216394Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.Type: GrantFiled: August 14, 2006Date of Patent: July 10, 2012Assignee: Kobe Steel, Ltd.Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
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Patent number: 8187359Abstract: An object of the present invention is to provide a method for producing granulated metallic iron superior in rust resistance. Another object of the present invention is to provide a method for producing such granulated metallic iron. In the method, the granulated metallic iron is produced by agglomerating a material mixture including an iron-oxide-containing material and a carbonaceous reducing agent; charging and heating the agglomerated material mixture in a moving hearth-type reducing furnace to reduce the iron oxide in the material mixture with the carbonaceous reducing agent to obtain hot granulated metallic iron; and cooling the hot granulated metallic iron, wherein the hot granulated metallic iron is cooled while its relative position is changed; and an oxide coating is formed on the surface of the hot granulated metallic iron by bringing moisture into contact with almost the entire surface of the hot granulated metallic iron.Type: GrantFiled: March 24, 2006Date of Patent: May 29, 2012Assignee: Mesabi Nugget LLCInventors: Koji Tokuda, Osamu Tsuge
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Publication number: 20120085310Abstract: An engine valve comprising a chromiferous steel and a protective surface layer (5) which consists of iron chrome oxide. A method for manufacture of an engine valve with a protective layer includes an engine component of a chromiferous steel which is heated (200) at a predetermined temperature for a predetermined time so that a layer (5) of iron chrome oxide is formed on the engine component's surface, and the engine component is then cooled (300) to room temperature.Type: ApplicationFiled: June 14, 2010Publication date: April 12, 2012Inventor: Magnus Bergström
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Publication number: 20110186131Abstract: A substrate for selenium compound semiconductor has at least a steel base and an aluminum base. The aluminum base is arranged on one end in a direction of lamination of the steel base and the aluminum base, the steel base is arranged on the other end in the direction. An alloy layer having a thickness of from 0.01 ?m to 10 ?m is formed between the steel base and the aluminum base. A thermal oxide film having a thickness of 6 nm or more is formed on a surface of the steel base opposite to the aluminum base.Type: ApplicationFiled: January 28, 2011Publication date: August 4, 2011Applicant: FUJIFILM CorporationInventors: Atsushi MUKAI, Shigenori Yuya, Toshiaki Fukunaga, Ryuichi Nakayama
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Publication number: 20110139308Abstract: The invention relates to a method for the production and removal of a temporary protective layer for a cathodic coating, particularly for the production of a hardened steel component with an easily paintable surface, wherein a steel sheet made of a hardenable steel alloy is subjected to a preoxidation, wherein said preoxidation forms a FeO layer with a thickness of 100 nm to 1,000 nm and subsequently a melt dip coating is conducted, wherein, during the melt dip coating, a zinc layer is applied having a thickness of 5 to 20 ?m, preferably 7 to 14 ?m, on each side, wherein the melt dip process and the aluminum content of the zinc bath is adjusted such that, during the melt dip coating, an aluminum content for the barrier layer results of 0.15 g/m2 to 0.Type: ApplicationFiled: January 30, 2008Publication date: June 16, 2011Applicant: VOESTALPINE STAHL GMBHInventors: Martin Peruzzi, Josef Faderl, Siegfried Kolnberger, Werner Brandstatter
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Patent number: 7901467Abstract: A process for treating the working surfaces of equipment used in the production and processing of polycarbonate is disclosed. The thermal treatment in an oxidative atmosphere results in resin and molded articles having improved optical quality.Type: GrantFiled: October 25, 2007Date of Patent: March 8, 2011Assignee: Bayer MaterialScience AGInventors: Wolfgang Ebert, Rainer Mellis, Alexander Meyer, Bert Ruytinx, Alexander Karbach, Delef Michalski-Vollmer
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Patent number: 7850791Abstract: Alloys containing aluminium are characterised by an outstanding oxidation resistance at high temperatures, that is based on, inter alia, the formation of a thick and slow-growing aluminium oxide layer on material surfaces. If the formation of the aluminium oxide layer reduces the aluminium content of the alloy so far that a critical aluminium concentration is not reached, no other protective aluminium oxide layer can be formed. This leads disadvantageously to a very rapid breakaway oxidation, and the destruction of the component. This effect is stronger at temperatures above 800° C. due to the fact that, often at this point, metastable Al2O3 modifications, especially ?- or ?-Al2O3, are formed instead of ?-Al2O3 that is generally formed at high temperatures. The above-mentioned oxide modifications are disadvantageously characterised by significantly higher growth rates.Type: GrantFiled: November 20, 2004Date of Patent: December 14, 2010Assignee: Forschungszentrum Julich GmbHInventor: Willem J. Quadakkers
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Patent number: 7811392Abstract: It is an object of the present invention to efficiently suppress radionuclide deposition on a reactor component of nuclear power plant. Radionuclide deposition on the surface of a metallic reactor component of nuclear power plant is suppressed by forming a ferrite film on the component, wherein the film is formed, after decontamination for removing radionuclides contaminants from the component surface is completed and before the plant is started up, by contacting a treatment solution which mixes a first agent containing the iron (II) ions, a second agent for oxidizing the iron (II) ions into the iron (III) ions and a third agent for adjusting pH level of a solution to 5.5 to 9.0 in this order with the reactor component surface.Type: GrantFiled: July 14, 2006Date of Patent: October 12, 2010Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Hideyuki Hosokawa, Makoto Nagase, Kazushige Ishida, Youichi Wada, Naoshi Usui, Motohiro Aizawa, Motomasa Fuse
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Publication number: 20100236667Abstract: The present invention aims at providing a method for production of a steel product which surely retains scale during cooling, storage, and transportation and permits scale to scale off easily at the time of mechanical descaling and pickling that precede the secondary fabrication. The steel product is produced by heating and hot rolling a steel billet and spraying the hot-rolled steel product with steam and/or water mist having a particle diameter no larger than 100 ?m, for surface oxidation.Type: ApplicationFiled: June 7, 2010Publication date: September 23, 2010Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Takeshi Kuroda, Hidenori Sakai, Mikako Takeda, Takuya Kochi, Takashi Onishi, Tomotada Maruo, Takaaki Minamida
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Publication number: 20100193082Abstract: The method of surface treatment, as applied onto a metal base material, of the present invention includes a reduction treatment step of reduction-treating the oxide film formed on the metal base material and an oxidation treatment step of oxidation-treating the oxide film having been subjected to the reduction treatment.Type: ApplicationFiled: July 10, 2008Publication date: August 5, 2010Inventors: Hajime Hasegawa, Yusuke Watanabe
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Patent number: 7673541Abstract: Colored razor blades are provided. Methods for manufacturing such blades are also provided, including methods involving depositing an oxide coating prior to heat treatment of the blade material and heat treating under conditions selected to enhance the color of the coating.Type: GrantFiled: June 3, 2004Date of Patent: March 9, 2010Assignee: The Gillette CompanyInventors: Kenneth J. Skrobis, Alfred Porcaro, Ronald J. Swanson, Eric Liu
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Publication number: 20090252991Abstract: Provided is an iron nitride-based magnetic powder that comprises magnetic particles having a mean particle size of at most 20 nm. The magnetic particle has a core of a main phase of Fe16N2 and has, on the outer side of the core, an oxide phase derived from a metal Fe phase formed by reduction of iron nitride. In relation to the weatherability index ??s and the saturation magnetization as thereof, the magnetic powder satisfies ??s?0.8×?s?30. In this, ??s=(?s??s1)/?s×100. ?s1 means the saturation magnetization of the magnetic powder kept in an atmosphere of 60° C. and 90% RH for 1 week. The powder can be obtained by exposing powder particles having a main phase of Fe16N2 to a reducing gas to partly reduce the region of the surface of the particles into a metal Fe phase (gradual reduction) followed by exposing them to an oxidizing gas to oxidize a part of the surface of the metal Fe phase into an oxide phase (gradual oxidation).Type: ApplicationFiled: June 8, 2007Publication date: October 8, 2009Inventors: Yuzo Ishikawa, Kenji Masada