Copper Containing Patents (Class 148/303)
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Patent number: 11484942Abstract: An alloy powder having an alloy composition represented by Fe100-a-b-c-d-e-fCuaSibBcCrdSneCf, wherein a, b, c, d, e and f are atomic % meeting 0.80?a?1.80, 2.00?b?10.00, 11.00?c?17.00, 0.10?d?2.00, 0.01?e?1.50, and 0.10?f?0.40.Type: GrantFiled: April 26, 2019Date of Patent: November 1, 2022Assignee: HITACHI METALS, LTD.Inventors: Motoki Ohta, Nobuhiko Chiwata, Tetsuro Kato
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Patent number: 10984932Abstract: An amorphous soft magnetic alloy of the formula (Fe1-?TM?)100-w-x-y-zPwBxLySiz TipCqMnrCus, wherein TM is Co or Ni; L is Al, Cr, Zr, Mo or Nb; 0???0.3, 2?w?18 at %, 2?x?18 at %, 15?w+x?23 at %, 1<y?5 at %, 0?z?4 at %; p, q, r, and s represents an addition ratio such that the total mass of Fe, TM, P, B, L and Si is 100, and 0?p?0.3, 0?q?0.5, 0?r?2, 0?s?1 and r+s>0; the composition fulfills one of the following conditions: L is Cr, Zr, Mo or Nb; or L is a combination of Al and Cr, Zr, Mo or Nb, wherein 0<Al?5 at %, 1?Cr?4 at %, 0<Zr?5 at %, 2?Mo?5 at %, and 2?Nb?5 at %; the alloy has a crystallization start temperature (Tx) which is 550° C. or less, a glass transition temperature (Tg) which is 520° C. or less, and a supercooled liquid region represented by ?Tx=Tx?Tg, which is 20° C. or more.Type: GrantFiled: June 19, 2017Date of Patent: April 20, 2021Assignees: TOKIN CORPORATION, TOHOKU UNIVERSITYInventors: Akiri Urata, Teruhiko Fujiwara, Hiroyuki Matsumoto, Yasunobu Yamada, Akihisa Inoue
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Patent number: 9087631Abstract: In an embodiment, a permanent magnet includes a composition represented by R(Fep(TisM1-s)qCur(Co1-tAt)1-p-q-r)z (R is at least one element selected from rare earth elements, M is at least one element selected from Zr and Hf, A is at least one element selected from Ni, V, Cr, Mn, Al, Ga, Nb, Ta and W, and p, q, r, s, t and z are numbers satisfying 0.3?p?0.6, 0.01?q?0.1, 0.01?r?0.15, 0.2?s?0.8, 0?t?0.2, 6?z?9 in an atomic ratio, respectively), and a structure composed mainly of a Th2Zn17 crystal phase and a CaCu5 crystal phase.Type: GrantFiled: May 19, 2011Date of Patent: July 21, 2015Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Yosuke Horiuchi, Shinya Sakurada
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Patent number: 8854173Abstract: An Fe-based amorphous alloy powder of the present invention has a composition represented by (Fe100-a-b-c-x-y-z-tNiaSnbCrcPxCyBzSit)100-?M?. In this composition, 0 at %?a?10 at %, 0 at %?b?3 at %, 0 at %?c?6 at %, 6.8 at %?x?10.8 at %, 2.2 at %?y?9.8 at %, 0 at %?z?4.2 at %, and 0 at %?t?3.9 at % hold, a metal element M is at least one selected from the group consisting of Ti, Al, Mn, Zr, Hf, V, Nb, Ta, Mo, and W, and the addition amount ? of the metal element M satisfies 0.04 wt %???0.6 wt %. Accordingly, besides a decrease of a glass transition temperature (Tg), an excellent corrosion resistance and high magnetic characteristics can be obtained.Type: GrantFiled: July 15, 2013Date of Patent: October 7, 2014Assignee: Alps Green Devices Co., Ltd.Inventors: Keiko Tsuchiya, Jun Okamoto, Hisato Koshiba
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Patent number: 8835001Abstract: A ferrite sintered magnet has a surface roughness Rz of 3.5 ?m or less. A method for producing a ferrite sintered magnet includes: mixing magnetic powders with at least a binder resin to obtain a magnetic powder mixture; injection molding the magnetic powder mixture inside of a mold having a surface roughness of a surface in contact with the magnetic powder mixture of 2.0 ?m or less with a magnetic field applied to the mold, to obtain a molded body; and sintering the molded body.Type: GrantFiled: March 27, 2012Date of Patent: September 16, 2014Assignee: TDK CorporationInventors: Hideyuki Umezawa, Yoshihiko Minachi, Osanori Mizonoue
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Patent number: 8574380Abstract: The present invention discloses a composite magnetic material. The composite magnetic material may comprise an Nd—Fe—B alloy and a Fe-based soft magnetic alloy having the general formula of Fe100-x-y-z-aAxRaSiyBz. A may be at least one element selected from Cu and Au. R may be at least one element selected from the group consisting of Ti, Zr, Hf, Mo, Nb, Ta, W and V. And the x, a, y, and z may satisfy: 0?x?3, 0?a?10, 0?y?20 and 2?z?25. The present invention further discloses a method of preparing the composite magnetic material as described above. According to the present invention, the composite magnetic material may have an enhanced magnetic energy product and residual magnetism respectively.Type: GrantFiled: March 26, 2010Date of Patent: November 5, 2013Assignee: BYD Company LimitedInventors: Qing Gong, Xin Du, Xiaofeng Cheng
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Permanent magnet and method for manufacturing the same, and motor and power generator using the same
Patent number: 8568539Abstract: According to one embodiment, a permanent magnet is provided with a sintered body having a composition represented by R(FepMqCurCo1-p-q-r)zOw (where, R is at least one element selected from rare-earth elements, M is at least one element selected from Ti, Zr and Hf, and p, q, r, z and w are numbers satisfying 0.25?p?0.6, 0.005?q?0.1, 0.01?r?0.1, 4?z?9 and 0.005?w?0.6 in terms of atomic ratio). The sintered body has therein aggregates of oxides containing the element R dispersed substantially uniformly.Type: GrantFiled: March 25, 2011Date of Patent: October 29, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yosuke Horiuchi, Shinya Sakurada, Keiko Okamoto, Masaya Hagiwara -
Patent number: 8298351Abstract: A rare earth sintered magnet consists essentially of 26-36 wt % R, 0.5-1.5 wt % B, 0.1-2.0 wt % Ni, 0.1-3.0 wt % Si, 0.05-1.0 wt % Cu, 0.05-4.0 wt % M, and the balance of T and incidental impurities wherein R is a rare earth element, T is Fe or Fe and Co, M is selected from Ga, Zr, Nb, Hf, Ta, W, Mo, Al, V, Cr, Ti, Ag, Mn, Ge, Sn, Bi, Pb, and Zn. Simultaneous addition of Ni, Si, and Cu ensures magnetic properties and corrosion resistance.Type: GrantFiled: May 9, 2011Date of Patent: October 30, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuya Fukui, Takahiro Hashimoto
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Patent number: 8211246Abstract: In one embodiment, a permanent magnet has a composition represented by (Sm1-xRx)(FepMqCurCo1-p-q-r)z, where R is at least one element selected from Nd and Pr, M is at least one element selected from Ti, Zr and Hf, and 0.22?p?0.45, 0.005?q?0.05, 0.01 ?r?0.1, 0.05?x<0.5, and 7?z?9. The permanent magnet includes a Th2Zn17 crystal phase as a main phase, and a ratio of diffraction peak intensity I(113) from a (113) plane of the Th2Zn17 crystal phase in powder X-ray diffraction to diffraction peak intensity I(300) from a (300) plane in powder X-ray diffraction is in a range of 0.9?I(113)/I(300)?1.7.Type: GrantFiled: March 16, 2011Date of Patent: July 3, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Masaya Hagiwara, Shinya Sakurada, Yosuke Horiuchi, Keiko Okamoto, Tsuyoshi Kobayashi, Shiori Kaji
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Patent number: 7837807Abstract: A magnetic core for a current transformer, and a current transformer and a watt hour meter used thereof, which is preferred the detection of a alternate current with a large asymmetrical waveform and a alternate current which a direct current is superimposed are realized. A magnetic core for a current transformer comprising the composition represented by the general formula: Fe100-x-a-y-cMxCuaM?yX?c (atomic %), wherein M is at least one element selected from Co and Ni, M? is at least one element selected from V, Ti, Zr, Nb, Mo, Hf, Ta, X? is at least one element selected from Si and B, and x, a, y, and c meets the composition of 3?x?50, 0.1?a?3, 1?y?10, 2?c?30, and also 7?y+c?30, and an alloy comprising a crystal grain consisting of at least a part or all of the composition with a mean particle size of less than or equal to 50 nm.Type: GrantFiled: March 19, 2007Date of Patent: November 23, 2010Assignee: Hitachi Metals, Ltd.Inventor: Yoshihito Yoshizawa
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Patent number: 7740716Abstract: The present invention provides a technique to improve an adhesion strength between a magnet main body and a protective film. The rare earth sintered magnet of the present invention comprises a magnet main body of a sintered body containing a rare earth element and a protective film formed on the magnet main body, wherein the ratio of a 10-point average surface roughness Rz of the magnet main body on which the protective film is formed to a mean grain size D50 in the magnet main body (Rz/D50 ratio) is kept in a range from 0.20 to 10.00, inclusive. This gives the rare earth sintered magnet which is coated with the protective film having a high adhesion strength of 100 N/m or more and exhibits high corrosion resistance.Type: GrantFiled: November 17, 2005Date of Patent: June 22, 2010Assignee: TDK CorporationInventors: Yasushi Enokido, Gouichi Nishizawa, Chikara Ishizaka
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Patent number: 7722726Abstract: The invention provides a method for producing alloy flakes for rare earth sintered magnets, which makes uniform the intervals, size, orientation, and shape of the R-rich region and the dendrites of the 2-14-1 phase, which inhibits formation of chill, and which produces flakes that are pulverized into powder of a uniform particle size in the pulverization step in the production of a rare earth sintered magnet, and that are pulverized into powder compactable into a product with a controlled shrink ratio, and alloy flakes for a rare earth sintered magnet obtained by the method, and a rare earth sintered magnet having excellent magnetic properties.Type: GrantFiled: March 31, 2005Date of Patent: May 25, 2010Assignee: Santoku CorporationInventors: Kazumasa Shintani, Ryo Murakami, Kazuhiko Yamamoto
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Patent number: 7713360Abstract: It is an object of the present invention to provide a permanent magnet which is observed as a uniform structure without microstructures, but shows a pinning type initial magnetization curve. There is provided a rare earth permanent magnet comprising a magnetic intermetallic compound comprising R, T, N and an unavoidable impurity, wherein R is one or more rare earth elements comprising Y, T is two or more transition metal elements and comprises principally Fe and Co; wherein the magnetic intermetallic compound has an T/R atomic ratio of 6 to 14; a magnetocrystalline anisotropy energy of at least 1 MJ/m3; a Curie point of at least 100° C.; average particle diameter of at least 3 ?m; and a substantially uniform structure; wherein the rare earth permanent magnet has a structure that gives a pinning-type initial magnetization curve; and wherein the magnetic intermetallic compound has a Th2Zn17-type structure, and the like.Type: GrantFiled: February 22, 2005Date of Patent: May 11, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Ken Ohashi
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Patent number: 7473325Abstract: A current transformer core made of an alloy having a composition represented by the general formula: Fe100-x-a-y-cMxCuaM?yX?c (by atomic %), wherein M is Co and/or Ni, M? is at least one element selected from the group consisting of V, Ti, Zr, Nb, Mo, Hf, Ta and W, X? is Si and/or B, and x, a, y and c are numbers satisfying 10?x?50, 0.1?a?3, 1?y?10, 2?c?30, and 7?y+c?31, respectively; at least part or all of the alloy structure being composed of crystal grains having an average particle size of 50 nm or less.Type: GrantFiled: December 16, 2005Date of Patent: January 6, 2009Assignee: Hitachi Metals, Ltd.Inventors: Yoshihito Yoshizawa, Masamu Naoe
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Patent number: 7438768Abstract: Hydrogen embrittlement is prevented in Sm2Co17-based magnets and R2Fe14B-based magnets by metal plating the magnet, then carrying out heat treatment, or by forming a metal oxide or metal nitride layer on the metal plating layer or directly on the magnet itself.Type: GrantFiled: December 24, 2002Date of Patent: October 21, 2008Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuaki Sakaki, Masaki Kasashima, Ryuji Hamada, Takehisa Minowa
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Publication number: 20080223489Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: ApplicationFiled: March 17, 2008Publication date: September 18, 2008Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroaki NAGATA, Tadao NOMURA, Takehisa MINOWA
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Patent number: 7250840Abstract: A layered product prepared by applying a surface treatment to an adherend having a surface with a low binding property with an anaerobic adhesive, which does not require a complex work, primer application, effected by accelerating an adhesive curing rate, and does not change surface conditions of the adherend. The layered product comprises an adherend, an uneven deposition comprising Cu, V, a Cu alloy or a V alloy and having a height of 500 nm or less on the surface of the adherend, and an adhesive layer formed at least on the uneven deposition.Type: GrantFiled: March 28, 2005Date of Patent: July 31, 2007Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Ryo Osugi
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Patent number: 7192493Abstract: A sintered body with a composition consisting of 25% to 35% by weight of R (wherein R represents one or more rare earth elements, providing that the rare earth elements include Y), 0.5% to 4.5% by weight of B, 0.02% to 0.6% by weight of Al and/or Cu, 0.03% to 0.25% by weight of Zr, 4% or less by weight (excluding 0) of Co, and the balance substantially being Fe, wherein a coefficient of variation (CV) showing the dispersion of Zr is 130 or lower. This sintered body enables to inhibit the grain growth, while keeping the decrease of magnetic properties to a minimum, and to improve the suitable sintering temperature range.Type: GrantFiled: September 29, 2003Date of Patent: March 20, 2007Assignee: TDK CorporationInventors: Gouichi Nishizawa, Chikara Ishizaka, Tetsuya Hidaka, Akira Fukuno
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Patent number: 7175718Abstract: A material for a rare earth permanent magnet having a high magnetic coercive force and a high residual magnetic flux density. 28 to 35% by weight of at least one rare earth element selected from the group consisting of neodymium, praseodymium, dysprosium, terbium, and holmium, 0.9 to 1.3% by weight of boron, 0.25 to 3% by weight of phosphorus, iron, and inevitable impurities. It can further comprise 0.1 to 3.6% by weight of cobalt and 0.02 to 0.25% by weight of copper.Type: GrantFiled: June 19, 2001Date of Patent: February 13, 2007Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Hideharu Nobutoki, Suguru Nagae, Satoru Hayasi
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Publication number: 20040261906Abstract: The present invention relates to a method of producing a magnetic particle including forming a layer containing an alloy particle that can form CuAu type or Cu3Au type hard magnetic order alloy phase on a support, oxidizing the layer, and annealing the layer in non-oxidizing atmosphere. The invention also relates to a method of producing a magnetic particle including producing an alloy particle that can form hard magnetic order alloy phase, oxidizing the alloy particle, and annealing the particle in non-oxidizing atmosphere, and a magnetic particle produced by the foregoing production method. Further, the invention relates to a magnetic recording medium comprising a magnetic layer containing a magnetic particle and a method of producing a magnetic recording medium including forming a layer containing an alloy that can form the foregoing hard magnetic order alloy phase, oxidizing the layer, and annealing the layer in non-oxidizing atmosphere.Type: ApplicationFiled: July 22, 2004Publication date: December 30, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Yasushi Hattori, Koukichi Waki, Keizo Ogawa
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Publication number: 20040261905Abstract: The present invention relates to a method of producing a magnetic particle including forming a layer containing an alloy particle that can form CuAu type or Cu3Au type hard magnetic order alloy phase on a support, oxidizing the layer, and annealing the layer in non-oxidizing atmosphere. The invention also relates to a method of producing a magnetic particle including producing an alloy particle that can form hard magnetic order alloy phase, oxidizing the alloy particle, and annealing the particle in non-oxidizing atmosphere, and a magnetic particle produced by the foregoing production method. Further, the invention relates to a magnetic recording medium comprising a magnetic layer containing a magnetic particle and a method of producing a magnetic recording medium including forming a layer containing an alloy that can form the foregoing hard magnetic order alloy phase, oxidizing the layer, and annealing the layer in non-oxidizing atmosphere.Type: ApplicationFiled: July 22, 2004Publication date: December 30, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Yasushi Hattori, Koukichi Waki, Keizo Ogawa
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Patent number: 6773517Abstract: A rare-earth alloy ingot is produced by melting an alloy composed of 20-30 wt % of a rare-earth constituent which is Sm alone or at least 50 wt % Sm in combination with at least one other rare-earth element, 10-45 wt % of Fe, 1-10 wt % of Cu and 0.5-5 wt % of Zr, with the balance being Co, and quenching the molten alloy in a strip casting process. The strip-cast alloy ingot has a content of 1-200 &mgr;m size equiaxed crystal grains of at least 20 vol % and a thickness of 0.05-3 mm. Rare-earth sintered magnets made from such alloys exhibit excellent magnetic properties and can be manufactured under a broad optimal temperature range during sintering and solution treatment.Type: GrantFiled: September 10, 2001Date of Patent: August 10, 2004Assignee: Shin-Etsu Chemical Co, Ltd.Inventors: Kazuaki Sakaki, Koji Sato, Takahiro Hashimoto, Hajime Nakamura, Takehisa Minowa
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Patent number: 6758918Abstract: Disclosed is an isotropic SmFeN powdery magnet material for producing resin-bonded magnets. The magnet powder is prepared by melt-spinning of a molten alloy and nitriding the alloy powder thus obtained to form a magnet alloy having an alloy composition of one of the formulae, by atomic %: SmxFe100-x-vNv, SmxFe100-x-y-vM1yNv and SmxFe100-x-z-vM2zNv wherein M1 is at least one member selected from the group consisting of Hf and Zr; and M2 is at least one member selected from the group consisting of Si, Nb, Ti, Ga, Al, Ta and C; 7≦x≦12, 0.1≦y≦1.5, 0.1≦z≦1.0 and 0.5≦v≦20; the crystal structure is TbCu7 type; and the thickness of the flakes is 10-40 &mgr;m.Type: GrantFiled: May 29, 2001Date of Patent: July 6, 2004Assignee: Diado Steel Co., Ltd.Inventors: Takahiko Iriyama, Ryo Omatsuzawa, Takayuki Nishio
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Publication number: 20040118484Abstract: A sintered body with a composition consisting of 25% to 35% by weight of R (wherein R represents one or more rare earth elements, providing that the rare earth elements include Y), 0.5% to 4.5% by weight of B, 0.02% to 0.6% by weight of Al and/or Cu, 0.03% to 0.25% by weight of Zr, 4% or less by weight (excluding 0) of Co, and the balance substantially being Fe, wherein a coefficient of variation (CV) showing the dispersion of Zr is 130 or lower. This sintered body enables to inhibit the grain growth, while keeping the decrease of magnetic properties to a minimum, and to improve the suitable sintering temperature range.Type: ApplicationFiled: September 29, 2003Publication date: June 24, 2004Applicant: TDK CORPORATIONInventors: Gouichi Nishizawa, Chikara Ishizaka, Tetsuya Hidaka, Akira Fukuno
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Patent number: 6726781Abstract: A permanent magnet is provided which retains its magnetic properties and exhibits a linear extrinsic demagnetization curve at elevated temperatures up to 700° C. The magnet is represented by the general formula RE(CoWFeVCuXTY)Z, where RE is a rare earth metal selected from the group consisting of Sm, Gd, Pr, Nd, Dy, Ce, Ho, Er, La, Y, Tb, and mixtures thereof and T represents a transition metal(s) selected from the group consisting of Zr, Hf, Ti, Mn, Cr, Nb, Mo, W, V, Ni, Ta, and mixtures thereof.Type: GrantFiled: September 12, 2002Date of Patent: April 27, 2004Assignees: University of Dayton, Electron Energy CorporationInventors: Marlin S. Walmer, Christina H. Chen, Shiqiang Liu, Michael H. Walmer, G. Edward Kuhl
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Patent number: 6623541Abstract: A sintered rare earth magnet consisting essentially of 20-30% by weight of R (wherein R is Sm or a mixture of Sm and another rare earth element), 10-45% by weight of Fe, 1-10% by weight of Cu, 0.5-5% by weight of Zr, and the balance of Co has on its surface a composite layer containing Sm2O3 and/or CoFe2O4 in Co or Co and Fe. The magnet is resistant to hydrogen embrittlement.Type: GrantFiled: July 30, 2001Date of Patent: September 23, 2003Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuaki Sakaki, Masanobu Shimao, Hajime Nakamura, Takehisa Minowa
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Patent number: 6592682Abstract: The invention concerns a method for preparing a magnetic material by forging, characterised in that, in a first embodiment, it comprises the following steps; placing in a sheath an alloy based on at least one rare earth, at least one transition metal and at least one other element selected among boron and carbon; bringing the whole alloy to a temperature not less than 500° C.; forging the whole at a deformation speed of the material not less than 8 s−1. After forging, it is possible to subject the resulting product to at least one annealing and hydridation then dehydridation, in another embodiment, it consists in starting with an alloy based on at least one rare earth and one transition metal and proceeding as in the first embodiment. After forging and, optionally, annealing, hydridation and dehydridation treatments, the resulting material is subjected to nitriding.Type: GrantFiled: June 8, 2001Date of Patent: July 15, 2003Assignee: Santoku CorporationInventors: Daniel Fruchart, Rene Perrier De La Bâthie, Sophie Rivoirard, Patricia Rango
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Patent number: 6565673Abstract: Carbon addition to the rapidly solidified, preferably melt spun, alloy system of Sm(Co, Fe, Cu, Zr) provides for good isotropic magnetic properties. Importantly, these alloys are nanocomposite in nature and comprise the SmCoC2 phase. Thermal processing of these materials can achieve good magnetic properties at lower temperatures and/or shorter processing times than conventional Sm(Co, Fe, Cu, Zr) powders for bonded magnet application.Type: GrantFiled: June 15, 2001Date of Patent: May 20, 2003Assignee: Santoku CorporationInventors: Wei Gong, Bao-Min Ma
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Patent number: 6478891Abstract: The ribbon shaped magnet material (quenched ribbon 8) according to the present invention is obtained by ejecting a molten liquid 6 of an alloy containing rare earth elements and transition metals from a nozzle 3, and quenching the molten liquid allowing it to collide with a circumference face 53 of a cooling roll 5. The micostructure of the quenched ribbon comprises. soft magnetic phases and hard magnetic phases in adjoining relation to one another. Crystal grain sizes of the quenched ribbon 8 preferably satisfy the following equations [1] and [2], and preferably satisfy at least one of the following equations [3] and [4]: D1s/D1h≦0.9 [1] D2s/D2h≦0.8 [2] 0.5≦D1h/D2h≦1 [3] 0.Type: GrantFiled: July 24, 2001Date of Patent: November 12, 2002Assignee: Seiko Epson CorporationInventors: Akira Arai, Hiroshi Kato
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Patent number: 6475302Abstract: Disclosed is a permanent magnet which comprises an alloy containing a hard magnetic phase having a ThMn12 type tetragonal structure and a nonmagnetic phase. The alloy is represented by a general formula given below: [R1-a(M1)a][T1-b-c(M2)b(M3)c]dx&agr; where R is at least one rare earth element (including Y), Ml is at least one element selected from the group consisting of Zr and Hf, T is at least one element selected from the group consisting of Fe, Co and Ni, M2 is at least one element selected from the group consisting of Cu, Bi, Sn, Mg, In and Pb, M3 is at least one element selected from the group consisting of Al, Ga, Ge, Zn, B, P and S, X is at least one element selected from the group consisting of Si, Ti, V, Cr, Mn, Nb, Mo, Ta and W, and the atomic ratios of a, b, c, d and &agr; fall within the ranges of 0≦a≦0.6, 0.01≦b≦0.20, 0≦c≦0.05, 6≦d≦11, and 0.5≦&agr;≦2.0.Type: GrantFiled: December 28, 2000Date of Patent: November 5, 2002Assignee: Kabushiki Kaisha ToshibaInventors: Wu Mei, Toshiya Sakamoto, Shinya Sakurada, Takao Sawa, Akihiko Tsutai, Akiko Saito, Masashi Sahashi
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Publication number: 20020139447Abstract: In this invention, enhancement of the coercive force of the Fe-B-R based magnetic anisotropic sintered magnets was studied by increasing a content of B and, in addition, containing into material a small amount of such as Al, Si, Cu, Cr, Ni, and Mn effective of enhancing the coercive force and excluding from the material harmful impurities such as P, S, and Sb. This material was powdered by usual melting, casting, crushing, or direct reduction method. This powder was subjected to orientation in a magnetic field, compacted, sintered and subjected to heat treatment. Thus the Fe-B-R based sintered permanent magnets were obtained that have the maximum energy product more than 20MGOe and the coercive force more than 15kOe.Type: ApplicationFiled: March 5, 2002Publication date: October 3, 2002Inventors: Satoshi Hirosawa, Kohki Tokuhara, Ken Makita, Hiroshi Nagata
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Patent number: 6451132Abstract: A permanent magnet is provided which retains its magnetic properties and exhibits a linear extrinsic demagnetization curve at elevated temperatures up to 700° C. The magnet is represented by the general formula RE(CowFevCuxTy)z, where RE is a rare earth metal selected from the group consisting of Sm, Gd, Pr, Nd, Dy, Ce, Ho, Er, La, Y, Th, and mixtures thereof and T represents a transition metal(s) selected from the group consisting of Zr, Hf, Ti, Mn, Cr, Nb, Mo, W, V, Ni, Ta, and mixtures thereof.Type: GrantFiled: January 3, 2000Date of Patent: September 17, 2002Assignee: University of DaytonInventors: Marlin S. Walmer, Christina H. Chen, Shiqiang Liu, Michael H. Walmer, G. Edward Kuhl
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Publication number: 20020043301Abstract: A class of density enhanced, electromagnetic-pulse-compacted, bonded permanent magnets having the following properties:Type: ApplicationFiled: February 13, 2001Publication date: April 18, 2002Inventors: Marlin Walmer, Jinfang Liu, Michael Walmer
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Publication number: 20020007875Abstract: A R—Fe—B base permanent magnet material is composed of a R—Fe—B magnet alloy which contains 87.5-97.5 vol % of a Fe14R2B1 primary phase and 0.1-3 vol % of a rare earth oxide or a rare earth and transition metal oxide. The alloy contains as a major component in its metal structure a compound selected from among zirconium-boron compounds, niobium-boron compounds and hafnium-boron compounds. The compound has an average grain size of at most 5 &mgr;m and is uniformly distributed within the alloy such that the maximum interval between neighboring grains of the compound is at most 50 &mgr;m. Rare-earth permanent magnet materials of this composition and structure have excellent magnetic properties.Type: ApplicationFiled: June 13, 2001Publication date: January 24, 2002Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Kenji Yamamoto, Koro Tatami, Takehisa Minowa
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Patent number: 6334909Abstract: A cold accumulating material comprising magnetic substance expressed by the general formula: RCu1−xM1+x (1) wherein R denotes at least one of rare earth element selected from the group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Er, Ho, Tm and Yb, M denotes at least one element selected from the group consisting of Ag, Au, Al, Ga, In, Ge, Sn, Sb, Si, Bi, Ni, Pd, Pt, Zn, Co, Rh, Ir, Mn, Fe, Ru, Cr, Mo, W, V, Nb, Ta, Ti, Zr and Hf, and wherein Ni and Ge are not simultaneously selected, and x in atomic ratio satisfies a relation: −0.95≧x≧0.90. According to the above structure, there can be provided a cold accumulating material and a refrigerator using the cold accumulating material capable of exhibiting a remarkable and stable refrigerating performance at an extremely low temperature for a long time.Type: GrantFiled: June 17, 1999Date of Patent: January 1, 2002Assignee: Kabushiki Kaisha ToshibaInventors: Masami Okamura, Tomohisa Arai, Keisuke Hashimoto
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Patent number: 6273966Abstract: A high performance rare earth-transition metal magnetostrictive material with increased impurities having the formula (Rx1Rx2 . . . Rx11)1(My1My2 . . . My6)z is provided. Each R is selected from the group of elements consisting of lanthanum, cerium, praseodymium, neodymium, samarium, gadolinium, terbium, dysprosium, holmium, erbium and yttrium, where 0≦x1≦1, 0≦x2≦1 . . . 0≦x11≦1 and where x1+x2+ . . . +x11=1. Each M is selected from the group of elements consisting of iron, manganese, cobalt, nickel, aluminum and silicon, where 0≦y1≦1, 0≦y2≦1 . . . 0≦y6≦1, where y1+y2+ . . . +y6=1 and where 1.8≦z≦2.1. The material has oxygen impurities, nitrogen impurities and carbon impurities. The oxygen impurities having an atomic percent ranging from 6,011 to 34,000 parts per million. The nitrogen impurities having an atomic percent ranging from 575 to 4,400 parts per million.Type: GrantFiled: December 3, 1998Date of Patent: August 14, 2001Assignee: Etrema Products, Inc.Inventors: Jonathan D. Snodgrass, O. Dale McMasters
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Patent number: 6270591Abstract: The invention refers to amorphous and nanocrystalline magnetic glass-covered wires. The wires consist of a metallic amorphous or nanocrystalline core with diameters by the order of 10−6 m, having compositions based on transition metal-metalloids and other additional metals and a glass cover, having a thickness of the wall by the same order of magnitude. The wires present high or medium saturation inducation, positive, negative or nearly zero magnetostriction and values of the coercive field and of the magnetic permeability in function of the requested applications in a field of electronics and electrotechnics to achieve sensors, transducers, inductive coils, trnasformers, magnetic shields, devices working on the basis of the correlation between the magnetic properties of the metallic core and the optical properties of the glass cover.Type: GrantFiled: June 25, 1998Date of Patent: August 7, 2001Inventors: Horia Chiriac, Firuta Barariu, Adrian Tibor Ovari, Gheorghe Pop
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Patent number: 6197127Abstract: A heat regenerating material for very low temperature use consisting of a magnetic heat regenerating material particle aggregate, wherein, among magnetic heat regenerating material particles constituting the magnetic heat regenerating material particle aggregate, a ratio of the particles being destroyed when a simple harmonic oscillation of the maximum acceleration of 300 m/s2 is added 1×106 times on the magnetic heat regenerating material particle aggregate is 1% by weight or less. Such a heat regenerating material for very low temperature use has an excellent mechanical characteristics against mechanical vibration and acceleration. A refrigerator comprises a heat regenerator constituted by packing the above described heat regenerating material for very low temperature use into a heat regenerator container. Such a refrigerator can exhibit an excellent refrigeration performance over a long term.Type: GrantFiled: August 21, 1998Date of Patent: March 6, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Masami Okamura, Naoyuki Sori
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Patent number: 6045629Abstract: An alloy used for the production of a rare-earth magnet alloy, particularly the boundary-phase alloy in the two-alloy method is provided to improve the crushability.The alloy consists of (a) from 35 to 60% of Nd, Dy and/or Pr, 1% or less of B, and the balance being Fe, or (b) from 35 to 60% of Nd, Dy and/or Pr, 1% or less of B, and at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga, and the balance being Fe. The total volume fraction of R.sub.2 Fe.sub.17 and R.sub.2 Fe.sub.14 B phases (Fe may be replaced with Cu, Co, Al or Ga) is 25% or more in the alloy. The average size of each of the R.sub.2 Fe.sub.17 and R.sub.2 Fe.sub.14 B phases is 20 .mu.m or less. The alloy can be produced by a centrifugal casting at an average accumulating rate of melt at 0.1 cm/second or less.Type: GrantFiled: February 3, 1998Date of Patent: April 4, 2000Assignees: Showa Denko K.K., TDK CorporationInventors: Hiroshi Hasegawa, Shiro Sasaki, Yoichi Hirose, Shinya Fujito, Koichi Yajima
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Patent number: 6042657Abstract: A cold heat accumulating material for extremely low temperatures which comprises cold heat accumulating granular bodies in which a rate of particles, which are destroyed when a compressive force of 5 MPa is applied thereto by a mechanical strength evaluation die, out of the magnetic cold heat accumulating particles constituting the magnetic cold heat accumulating granular bodies is not than 1 wt. %. In this magnetic cold heat accumulating granular bodies, a rate of magnetic cold heat accumulating particles having more than 1.5 form factor R expressed by L2/4.pi.A, wherein L represents a circumferential length of a projected image of each magnetic cold heat accumulating particle, and A a real of the projected image, is not more than 5%. Such a cold heat accumulating material for extremely low temperatures is capable of providing excellent mechanical properties with respect to mechanical vibration with a high reproducibility.Type: GrantFiled: February 21, 1997Date of Patent: March 28, 2000Assignee: Kabushiki Kaisha ToshibaInventors: Masami Okamura, Naoyuki Sori
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Patent number: 6017402Abstract: A composite magnetostrictive material having a magnetostrictive performance required for a practical use and yet a higher strength. A composite magnetostrictive material 1 is comprised of a matrix 2 formed of a magnetostrictive material of an RM-based alloy, wherein R is a rare earth element and M is one of a transition metal and aluminum, and dispersion phases 3 dispersed in the matrix and formed of at least one of an RM-based metal, R and M.Type: GrantFiled: August 28, 1997Date of Patent: January 25, 2000Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Tohru Sukigara, Teruyoshi Kita, Jun Takizawa
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Patent number: 5985049Abstract: Composite bodies of magnetostrictive materials of the type RE-Fe.sub.2, where RE is one or more of the rare earth elements, preferably samarium or terbium, can be suitably hot pressed with a matrix metal selected from the group consisting of aluminum, copper, iron, magnesium or nickel to form durable and machinable magnetostrictive composites still displaying appreciable magnetostrictive strains.Type: GrantFiled: May 26, 1998Date of Patent: November 16, 1999Assignee: General Motors CorporationInventors: Frederick Eugene Pinkerton, Jan Francis Herbst, Tenneille Weston Capehart, Charles Bernard Murphy, Earl George Brewer
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Patent number: 5948179Abstract: An alloy used for the production of a rare-earth magnet alloy, particularly the boundary-phase alloy in the two-alloy method is provided to improve the crushability.The Alloy consists of (a) from 35 to 60% of Nd, Dy and/or Pr, and the balance being Fe, or (b) from 35 to 60% of Nd, Dy and/or Pr, and at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga, and the balance being Fe. The volume fraction of R.sub.2 Fe.sub.17 phase (Fe may be replaced with Cu, Co, Al or Ga) is 25% or more in the alloy and the average size of an R.sub.2 Fe.sub.17 phase is 20 .mu.m or less. The alloy can be produced by a centrifugal casting at an average accumulating rate of melt at 0.1 cm/second or less.Type: GrantFiled: November 12, 1997Date of Patent: September 7, 1999Assignees: Showa Denko K.K., TDK CorporationInventors: Hiroshi Hasegawa, Shiro Sasaki, Yoichi Hirose, Shinya Fujito, Koichi Yajima
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Patent number: 5772796Abstract: A rare earth element containing permanent magnet which retains its magnetic properties at elevated temperatures by a combination of reducing the temperature coefficient of intrinsic coercivity lower than -0.2%/.degree.C., and increasing the intrinsic coercivity to over 10 kO.sub.e.Type: GrantFiled: November 20, 1995Date of Patent: June 30, 1998Assignee: YBM Magnex International, Inc.Inventor: Andrew S. Kim
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Patent number: 5674327Abstract: An alloy ingot for permanent magnet consists essentially of rare earth metal and iron and optionally boron. The two-component alloy ingot contains 90 vol % or more of crystals having a crystal grain size along a short axis of 0.1 to 100 .mu.m and that along a long axis of 0.1 to 100 .mu.m. The three-component alloy ingot contains 90 vol % or more of crystals having a crystal grain size along a short axis of 0.1 to 50 .mu.m and that along a long axis of 0.1 to 100 .mu.m. The alloy ingot is produced by solidifying the molten alloy uniformly at a cooling rate of 10.degree. to 1000.degree. C./sec. at a sub-cooling degree of 10.degree. to 500.degree. C. A permanent magnet and anisotropic powders are produced from the alloy ingot.Type: GrantFiled: April 19, 1996Date of Patent: October 7, 1997Assignee: Santoku Metal Industry Co., Ltd.Inventors: Kazuhiko Yamamoto, Yuichi Miyake, Chikara Okada
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Patent number: 5658396Abstract: Disclosed is a magnetic material which exhibits an improved saturation magnetic flux density and an improved magnetic anisotropy and, thus, is adapted for use as a raw material of a permanent magnet or a bond magnet of a high performance. The magnetic material is represented by a general formulaR.sub.x Co.sub.y Fe.sub.100-x-y (I)where R is at least one element selected from the rare earth elements, x and y are atomic percent individually defined as 4.ltoreq.x.ltoreq.20 and 0.01.ltoreq.y.ltoreq.70, and Co and Fe occupy 90 atomic percent or more in the principal phase of the compound.Type: GrantFiled: October 6, 1995Date of Patent: August 19, 1997Assignee: Kabushiki Kaisha ToshibaInventors: Shinya Sakurada, Takahiro Hirai, Akihiko Tsutai
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Patent number: 5466307Abstract: This invention relates to a rare earth containing multicomponent magnetic alloy powder consisting of no less than six components. During its preparation by reduction and diffusion process, one or more than one dispersing agent is added to the mixture of starting materials so that the allowable range of operational parameters is widened, the stability of product quality improved and the production cost reduced. Extensive studies have been made on the behavior of copper and calcium during processing making it possible to make precise compositional control of the final product. Rare earth permanent magnetic alloy powder of the R.sub.2 Co.sub.17 type prepared in accordance with the method of this invention ensures satisfactory quality and consistency.Type: GrantFiled: July 6, 1993Date of Patent: November 14, 1995Assignee: Shanghai Yue Long Non-Ferrous Metals LimitedInventors: Maofu Tong, Jiancheng Xiong, Xiangdong Geng
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Patent number: 5456769Abstract: Disclosed is a magnetic material which exhibits an improved saturation magnetic flux density and an improved magnetic anisotropy and, thus, is adapted for use as a raw material of a permanent magnet or a bond magnet of a high performance. The magnetic material is represented by a general formulaR.sub.X Co.sub.y Fe.sub.100-x-y (I)where R is at least one element selected from the rare earth elements, x and y are atomic percent individually defined as 4.ltoreq.x.ltoreq.20 and 0.01.ltoreq.y.ltoreq.70, and Co and Fe occupy 90 atomic percent or more in the principal phase of the compound, and the principal phase has a TbCu.sub.7 crystal structure.Type: GrantFiled: March 1, 1994Date of Patent: October 10, 1995Assignee: Kabushiki Kaisha ToshibaInventors: Shinya Sakurada, Takahiro Hirai, Akihiko Tsutai
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Patent number: 5382303Abstract: Novel permanent magnets of Sm.sub.2 Co.sub.17 type crystal structure are provided herein. The magnets preferably have samarium, cobalt, iron, copper and zirconium in specified amounts. They have superior magnetic properties, including maximum energy product, intrinsic coercivity and second quadrant loop squareness. The compositions of the magnets can be expressed by a general formula [Co.sub.a Fe.sub.b Cu.sub.c Zr.sub.d ].sub.e Sm. Preferred embodiments, wherein a is about 0.6 to about 0.7, b is about 0.2 to about 0.3, c is about 0.06 to about 0.07, d is about 0.02 to about 0.03, and e is about 7.2 to about 7.4, have unexpectedly high maximum energy product, high intrinsic coercive force and squareness. Processes for producing the improved alloy are also provided.Type: GrantFiled: April 13, 1992Date of Patent: January 17, 1995Assignee: SPS Technologies, Inc.Inventors: Richard L. Anderson, Fred G. Jones
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Patent number: 5362336Abstract: A permanent magnet material having as main components thereof a rare earth element, a transition element (except for rare earth elements and Cu and Ag), and nitrogen and containing as an additive component thereof at least one element selected from the group consisting of Cu, Ag, Al, Ga, Zn, Sn, In, Bi, and Pb. It finds extensive utility in magnetic recording materials such as magnetic tapes, magnetic recording devices, and motors, for example.Type: GrantFiled: May 28, 1992Date of Patent: November 8, 1994Assignee: Yoshida Kogyo K.K.Inventors: Tadashi Yamaguchi, Naomasa Kimura, Akihisa Inoue