With Inclusion Patents (Class 148/305)
  • Patent number: 11521770
    Abstract: A soft magnetic alloy includes a composition of (Fe(1-(?+?))X1?X2?)(1-(a+b+c+d+e+f+g))MaTibBcPdSieSfCg. X1 is one or more of Co and Ni. X2 is one or more of Al, Mn, Ag, Zn, Sn, As, Sb, Cu, Cr, Bi, N, O, and rare earth elements. M is one or more of Nb, Hf, Zr, Ta, Mo, W, and V. 0.020?a+b?0.140, 0.001?b?0.140, 0.020<c?0.200, 0.010?d?0.150, 0?e?0.060, a?0, f?0, g?0, a+b+c+d+e+f+g<1, ??0, ??0, and 0??+??0.50 are satisfied. The soft magnetic alloy has a nanohetero structure or a structure of Fe-based nanocrystalline.
    Type: Grant
    Filed: June 4, 2019
    Date of Patent: December 6, 2022
    Assignee: TDK CORPORATION
    Inventors: Kazuhiro Yoshidome, Hiroyuki Matsumoto, Kenji Horino, Hajime Amano, Akito Hasegawa
  • Patent number: 11322300
    Abstract: Provided are a core for a current transformer and a manufacturing method for the same in which high permittivity is formed in order to optimize electric power acquisition efficiency by magnetic induction at a low current. The provided method of manufacturing a core through the steps of winding a metal ribbon, heat treating a core base, impregnating, cutting and polishing, wherein after the core base which is inserted into a mold is heat treated to implement a shape, the core base separated from the mold is heat treated to manufacture the core for the current transformer having high permittivity.
    Type: Grant
    Filed: October 24, 2017
    Date of Patent: May 3, 2022
    Assignee: AMOSENSE CO., LTD
    Inventors: Won-San Na, Jin-Pyo Park, Young-Joon Kim, Jae-Jun Ko, Su-Hyeoung Tak
  • Patent number: 11249147
    Abstract: A magnetic sensor comprises a magnetic material portion; an excitation portion; and a magnetic detection portion, the magnetic sensor detecting a magnetic field by the magnetic detection portion detecting a detection magnetic field generated due to magnetic moments of the magnetic material portion. The excitation portion is configured to include a conductive material formed into an elongated shape, the magnetic material portion is a soft magnetic film formed on a surface of the conductive material, and the magnetic moments of the magnetic material portion are oriented along circumferential directions of the conductive material orthogonal to a longitudinal direction of the conductive material such that the magnetic moments directed to one of the circumferential directions and the magnetic moments direction in another circumferential direction opposite to the one circumferential direction are distributed in substantially equal amounts.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: February 15, 2022
    Assignee: FUJIDENOLO CO., LTD.
    Inventors: Hideki Miyazaki, Shinsuke Kato, Kazunobu Maekawa
  • Patent number: 10598742
    Abstract: Magnetic members of a high-sensitivity magnetoimpedance element and a low-sensitivity magnetoimpedance element are connected to each other in series, and the strength and direction of an external magnetic field is detected on the basis of an impedance variation of this series circuit. The output of a magnetic field detection sensor mainly reflects an impedance variation of the high-sensitivity magnetoimpedance element in a weak magnetic field range, and mainly reflects an impedance variation of the low-sensitivity magnetoimpedance element in a strong magnetic field range, whereby continuous detection is enabled in a wide range from a weak magnetic field to a strong magnetic field.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: March 24, 2020
    Assignee: Yazaki Corporation
    Inventors: Junya Tanigawa, Hiroki Sugiyama, Makoto Ishii
  • Patent number: 10541072
    Abstract: A soft magnetic alloy includes a main component of Fe. The soft magnetic alloy includes a Fe composition network phase where regions whose Fe content is larger than an average composition of the soft magnetic alloy are linked. The Fe composition network phase contains Fe content maximum points that are locally higher than their surroundings. A virtual-line total distance per 1 ?m3 of the soft magnetic alloy is 10 mm to 25 mm provided that the virtual-line total distance is a sum of virtual lines linking the maximum points adjacent each other. A virtual-line average distance that is an average distance of the virtual lines is 6 nm or more and 12 nm or less.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: January 21, 2020
    Assignee: TDK CORPORATION
    Inventors: Kazuhiro Yoshidome, Hiroyuki Matsumoto, Yu Yonezawa, Syota Goto, Hideaki Yokota, Akito Hasegawa, Masahito Koeda, Seigo Tokoro
  • Patent number: 10388444
    Abstract: Alloy powder of a composition formula Fe100-a-b-c-d-e-fCoaBbSicPdCueCf having an amorphous phase as a main phase is provided. Parameters satisfy the following conditions: 3.5?a?4.5 at %, 6?b?15 at %, 2?c?11 at %, 3?d?5 at %, 0.5?e?1.1 at %, and 0?f?2 at %. With this composition, the alloy powder has good magnetic characteristics even when it has a large particle diameter such as 90 ?m. Therefore, yield thereof is improved.
    Type: Grant
    Filed: July 17, 2015
    Date of Patent: August 20, 2019
    Assignee: TOHOKU MAGNET INSTITUTE CO., LTD.
    Inventors: Akihiro Makino, Nobuyuki Nishiyama, Parmanand Sharma, Kana Takenaka
  • Patent number: 10121586
    Abstract: A manufacturing method of an amorphous soft magnetic core using a Fe-based amorphous metallic powder includes size-sorting an amorphous metallic powder obtained by pulverizing an amorphous ribbon prepared by a rapid solidification process (RSP) and then using the amorphous metallic powder having a particle size distribution so as to comprise 10 to 85 wt. % of powder having a particle size of 75 to 100 ?m, 10 to 70 wt. % of powder having a particle size of 50 to 75 ?m, and 5 to 20 wt. % of powder having a particle size of 5 to 50 ?m to manufacture an amorphous soft magnetic core with excellent high-current DC bias characteristic and good core loss characteristic.
    Type: Grant
    Filed: January 21, 2014
    Date of Patent: November 6, 2018
    Assignee: AMOGREENTECH CO., LTD.
    Inventors: Byoung Ki Lee, Se Joong Yoon, Mi Rae Kim
  • Patent number: 9983273
    Abstract: A magnetic field detecting sensor includes a bridge circuit which is connected to multiple magnetoresistive effect elements and is capable of outputting a differential voltage between specified connection points, a magnetic field generating conductor for providing the magnetoresistive effect elements with a magnetic field in a direction opposite to that of the detection magnetic field by disposing a magnetic body near the center of the bridge circuit, a differential operation circuit which the differential voltage is input in and makes a feedback current flow to the magnetic field generating conductor, wherein the feedback current generates the magnetic field in a direction opposite to that of the detection magnetic field in the magnetic field generating conductor, and a voltage converting circuit for outputting the feedback current as a voltage value. The magnetic field generating conductor and the magnetoresistive effect elements are formed in the same stacked body.
    Type: Grant
    Filed: May 14, 2015
    Date of Patent: May 29, 2018
    Assignee: TDK CORPORATION
    Inventors: Akihiro Ogawa, Tamon Kasajima, Kei Tanabe
  • Patent number: 9857436
    Abstract: The magnetometers possess detector part with a magnetic wire sensitive to magnetic field consisting of a domain structure of the surface domain with circular spin alignment and core domain with longitudinal spin alignment and micro coil surrounding its magnetic wire to pick up the change of longitudinal magnetizing caused by spin rotation in surface domain with circular spin alignment called as GSR effect excited by pulse with frequency of 0.5 GHz to 4 GHz. Peak coil voltage is detected by a circuit characterized with pulse generator, GSR element, Buffer circuit, sample holding circuit, amplifier circuit and means to invert it to external magnetic field. The induced coil voltage caused by parasitic coil capacitance and wiring loop is vanished by combination coil of right and left turn coil. The magnetometers can provide lower noise, wide measuring range with a small size detector part and is applied to smartphones, wearable computer and so on.
    Type: Grant
    Filed: February 12, 2016
    Date of Patent: January 2, 2018
    Assignee: MAGNEDESIGN CORPORATION
    Inventor: Yoshinobu Honkura
  • Patent number: 9753059
    Abstract: A device for use in a power transmission system to sense GICs. The device may be a part of a reactance-injecting device on a power line, it may be a standalone device, or it may be a part of another type of device. The device may include a sensor to sense magnetic fields (e.g., a Hall effect sensor). The sensor may be positioned in the air gap of a magnetic core formed concentrically around the power line. The signal from the sensor may be converted to a digital signal and separately processed to determine the magnitude of the AC current and the magnitude of the DC (or quasi-DC) current. If the output signal of another A/C current sensor is available, that output signal may be used to adjust/calibrate the determined magnitude of the DC current. The sensor may communicate with other devices in a network to provide GIC information.
    Type: Grant
    Filed: November 13, 2015
    Date of Patent: September 5, 2017
    Assignee: SMART WIRES, INC.
    Inventors: Frank Kreikebaum, Paul Phillipsen, Stuart E. Ross, Yuli Starodubtsev
  • Publication number: 20140338793
    Abstract: A method includes producing an amorphous precursor to a nanocomposite, the amorphous precursor comprising a material that is substantially without crystals not exceeding 20% volume fraction; performing devitrification of the amorphous precursor, wherein the devitrification comprises a process of crystallization; forming, based on the devitrification, the nanocomposite with nano-crystals that contains an induced magnetic anisotropy; tuning, based on one or more of composition, temperature, configuration, and magnitude of stress applied during annealing and modification, the magnetic anisotropy of the nanocomposite; and adjusting, based on the tuned magnetic anisotropy, a magnetic permeability of the nanocomposite.
    Type: Application
    Filed: May 15, 2014
    Publication date: November 20, 2014
    Inventors: Alex M. Leary, Paul R. Ohodnicki, Michael E. McHenry, Vladimir Keylin, Joseph Huth, Samuel J. Kernion
  • Patent number: 8491731
    Abstract: An alloy composition of FeaBbSicPxCyCuz. Parameters meet the following conditions: 79?a?86 atomic %; 5?b?13 atomic %; 0?c?8 atomic %; 1?x?8 atomic %; 0?y?5 atomic %, 0.4?z?1.4 atomic %; and 0.08?z/x?0.8. Or, parameters meet the following conditions: 81?a?86 atomic %; 6?b?10 atomic %; 2?c?8 atomic %; 2?x?5 atomic %; 0?y?4 atomic %; 0.4?z?1.4 atomic %, and 0.08?z/x?0.8.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: July 23, 2013
    Inventor: Akihiro Makino
  • Patent number: 8287666
    Abstract: A magnetic alloy having a composition represented by the general formula of Fe100-x-yCuxBy (atomic %), wherein x and y are numbers meeting the conditions of 0.1?x?3, and 10?y?20, or the general formula of Fe100-x-y-zCuxByXz (atomic %), wherein X is at least one element selected from the group consisting of Si, S, C, P, Al, Ge, Ga and Be, and x, y and z are numbers meeting the conditions of 0.1?x?3, 10?y?20, 0<z?10, and 10<y+z?24), the magnetic alloy having a structure containing crystal grains having an average diameter of 60 nm or less in an amorphous matrix, and a saturation magnetic flux density of 1.7 T or more.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: October 16, 2012
    Assignee: Hitachi Metals, Ltd.
    Inventors: Motoki Ohta, Yoshihito Yoshizawa
  • Patent number: 8282745
    Abstract: An Fe-based soft magnetic alloy includes: Fe; and a component R, wherein the component R contains at least one of P, C, B, and Si, there is a temperature difference of equal to or greater than 20° C. between a precipitation temperature of an ?-Fe crystal phase and a precipitation temperature of an Fe compound, the Fe-based soft magnetic alloy is formed of a mixed-phase structure in which an amorphous phase and the ?-Fe crystal phase are mixed, and a diameter of a crystallite of the ?-Fe crystal phase is equal to or smaller than 50 nm, and a volume fraction of the ?-Fe crystal phase to the total is equal to or lower than 40%. In addition, the composition formula is represented by Fe100?x?uJxRu, a component J contains at least one of Cr, Co, Ni, and Nb, and 0 at %?x?6 at %, 17 at %?u?25 at %, and 17 at %?x+u?27.1 at % are satisfied.
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: October 9, 2012
    Assignee: Alps Green Devices Co., Ltd.
    Inventors: Keiko Tsuchiya, Hisato Koshiba, Jun Okamoto, Takao Mizushima
  • Patent number: 8007600
    Abstract: The invention provides a soft magnetic thin strip which contains nanoscale fine grains and exhibits a high saturation magnetic flux density and excellent soft magnetic characteristics; a process for production of the same; magnetic parts; and an amorphous thin strip to be used in the production. In the invention, an amorphous thin strip is used, which is represented by the composition formula: Fe100-x-y-zAxMyXz-aPa (wherein A is at least one element selected from between Cu and Au; M is at least one element selected from among Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and Mn; X is at least one element selected from between B and Si; and x, y, z and a (in terms of atomic percentage) satisfy the relationships: 0.5?x?1.5, 0?y?2.5, 10?z?23, and 0.35?a?10 respectively) and permits 180° bending.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: August 30, 2011
    Assignee: Hitachi Metals, Ltd.
    Inventors: Motoki Ohta, Yoshihito Yoshizawa
  • Publication number: 20100108196
    Abstract: A soft magnetic ribbon that especially in a relatively low magnetic field region of 500 A/m or less, is high in the squareness of magnetic flux density-magnetization curve. There is disclosed a soft magnetic ribbon of 100 ?m or less thickness comprising a parent phase structure in which by volume ratio, 30% or more of crystal grains of 60 nm or less (not including 0) crystal grain diameter are dispersed in an amorphous phase and comprising an amorphous layer disposed on the surface side of the parent phase structure. Preferably, the soft magnetic ribbon is represented by the composition formula Fe100-x-yCuxXy (wherein X is at least one element selected from among B, Si, S, C, P, Al, Ge, Ga and Be), in which the atomic percents (%) satisfy the relationships 0<x?5 and 10?y?24.
    Type: Application
    Filed: March 4, 2008
    Publication date: May 6, 2010
    Applicant: Hitachi Metals, LTD
    Inventors: Motoki Ohta, Yoshihito Yoshizawa
  • Publication number: 20090266448
    Abstract: A magnetic alloy having a composition represented by the general formula of Fe100-x-yCuxBy (atomic %), wherein x and y are numbers meeting the conditions of 0.1?x?3, and 10?y?20, or the general formula of Fe100-x-y-zCuxByXz (atomic %), wherein X is at least one element selected from the group consisting of Si, S, C, P, Al, Ge, Ga and Be, and x, y and z are numbers meeting the conditions of 0.1?x?3, 10?y?20, 0?z?10, and 10<y+z?24), the magnetic alloy having a structure containing crystal grains having an average diameter of 60 nm or less in an amorphous matrix, and a saturation magnetic flux density of 1.7 T or more.
    Type: Application
    Filed: September 19, 2006
    Publication date: October 29, 2009
    Applicant: HITACHI METALS, LTD.
    Inventors: Motoki Ohta, Yoshihito Yoshizawa
  • Publication number: 20090065100
    Abstract: Even if produced from a broad amorphous alloy ribbon, a nano crystal soft magnetic alloy, a magnetic core made of a nano crystal soft magnetic alloy, and the amorphous alloy ribbon for a nano crystal soft magnetic alloys which has the excellent alternate magnetic property, the small dispersion, the excellent temporal stability in high temperature, the excellent mass productivity can be provided. An amorphous alloy ribbon, wherein the alloy composition is represented by Fe100-a-b-c-dMaSibBcCd (atomic %), 0<a?10, 0?b?20, 2?c?20, 0<d?2, 9?a+b+c+d?35, and an amorphous alloy ribbon consists of inevitable impurities, and said M is at least one element selected from Ti, V, Zr, Nb, Mo, Hf, Ta, and W, and C concentration takes maximum value at 2-20 nm depth from the surface of said amorphous alloy with equivalent SiO2.
    Type: Application
    Filed: September 21, 2006
    Publication date: March 12, 2009
    Applicant: HITACHI METALS, LTD.
    Inventors: Yoshihito Yoshizawa, Yuichi Ogawa
  • Patent number: 7282103
    Abstract: The present invention provides an iron-base amorphous alloy thin strip excellent in soft magnetic properties, an iron core manufactured by using said thin strip, and a mother alloy for producing a rapidly cooled and solidified thin strip. More specifically, the present invention is an iron-base amorphous alloy thin strip produced by rapidly cooling and solidifying molten metal by ejecting it onto a moving cooling substrate through a pouring nozzle having a slot-shaped opening, characterized by having an ultra-thin oxide layer of a thickness in the range from 5 to 20 nm on one or both of the surfaces of the amorphous mother phase containing P in the range from 0.2 to 12 atomic %.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: October 16, 2007
    Assignee: Nippon Steel Corporation
    Inventors: Hiroaki Sakamoto, Yuichi Sato
  • Publication number: 20030205295
    Abstract: A magnetic powder core comprises a molded article of a mixture of a glassy alloy powder and an insulating material. The glassy alloy comprises Fe and at least one element selected from Al, P, C, Si, and B, and has a texture primarily composed of an amorphous phase. The glassy alloy exhibits a temperature difference &Dgr;Tx, which is represented by the equation &Dgr;Tx=Tx−Tg, of at least 20 K in a supercooled liquid, wherein Tx indicates the crystallization temperature and Tg indicates the glass transition temperature. The magnetic core precursor is produced mixing the glassy alloy powder with the insulating material, compacting the mixture to form a magnetic core precursor, and annealing the magnetic core precursor at a temperature in the range between (Tg−170) K and Tg K to relieve the internal stress of the magnetic core precursor. The glassy alloy exhibits low coercive force and low core loss.
    Type: Application
    Filed: May 20, 2003
    Publication date: November 6, 2003
    Inventors: Shoji Yoshida, Hidetaka Kenmotsu, Takao Mizushima, Kazuaki Ikarashi, Yutaka Naito
  • Patent number: 6261386
    Abstract: Compositions and methods for obtaining nanocrystal dispersed amorphous alloys are described. A composition includes an amorphous matrix forming element (e.g., Al or Fe); at least one transition metal element; and at least one crystallizing agent that is insoluble in the resulting amorphous matrix. During devitrification, the crystallizing agent causes the formation of a high density nanocrystal dispersion. The compositions and methods provide advantages in that materials with superior properties are provided.
    Type: Grant
    Filed: October 21, 1998
    Date of Patent: July 17, 2001
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: John H. Perepezko, Donald R. Allen, James C. Foley
  • Patent number: 6232775
    Abstract: A magneto-impedance element comprises an alloy composed of at least one of Fe, Co and Ni. The alloy has a mixed texture of an amorphous phase and a fine crystalline phase having an average crystal grain size of 50 nm or less. The magneto-impedance element shows a change in impedance in response to an external magnetic field by applying an alternating current. The magneto-impedance element is applied to an azimuth sensor, an autocanceler, or a magnetic head.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: May 15, 2001
    Assignees: Alps Electric Co., LTD
    Inventors: Yutaka Naitoh, Teruo Bitoh, Takashi Hatanai, Akihiro Makino, Junichi Ouchi, Shinichi Sasaqawa, Akihisa Inoue, Tsuyoshi Masumoto
  • Patent number: 6124047
    Abstract: A soft magnetic film comprises a Co--M--T--C alloy wherein a film structure is predominantly made of an amorphous phase and element M and C are chemically combined. The use of this film as a lower core layer in an MR/inductive composite-type thin film magnetic head ensures high saturation magnetic flux density, high resistivity, low magnetostriction constant and appropriate magnetic field, and leads to improvements in core and shield functions of the lower core layer.
    Type: Grant
    Filed: July 29, 1998
    Date of Patent: September 26, 2000
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 6083325
    Abstract: A method for making a Fe-based soft magnetic alloy where an alloy melt is injected onto a moving cooling unit to form an amorphous alloy ribbon. The alloy melt contains Fe as a main component, B and at least one metallic element M selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, the composition of the alloy melt being selected such that the resulting amorphous alloy ribbon is characterized by a first crystallization temperature at which fine grain bcc Fe crystallites precipitate, and a second crystallization temperature at which a compound phase containing Fe--B and/or Fe--M precipitates. The amorphous alloy ribbon is then annealed at a temperature which is higher that the first crystallization temperature and less than the second crystallization temperature for an annealing time in the range of 0 minutes to 20 minutes.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: July 4, 2000
    Assignee: Alps Electric Co., Ltd.
    Inventors: Teruo Bitoh, Yasuo Hayakawa, Takashi Hatanai, Akihiro Makino, Akihisa Inoue, Tsuyoshi Masumoto
  • Patent number: 5994191
    Abstract: Low resistivity metal silicide layers are formed on a gate electrode and source/drain regions at an optimum thickness for reducing parasitic series resistances with an attendant consumption of silicon from the gate electrode and source/drain regions. Consumed silicon from the gate electrode and source/drain regions is then replaced employing metal induced crystallization, thereby avoiding a high leakage current. Embodiments include depositing a layer of amorphous silicon on the metal silicide layers and heating at a temperature of about 400.degree. C. to about 600.degree. C. initiating metal induced crystallization, thereby causing the metal silicide layers grow upwardly as silicon in the underlying gate electrode and source/drain regions is replaced.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Qi Xiang, Shekhar Pramanick
  • Patent number: 5858125
    Abstract: A magnetoresistive material of the present invention has a structure in which many clusters are surrounded by a crystal phase of Cu and/or Ag, where each cluster has a grain size of 20 nm or less and composed of an amorphous phase containing at least one ferromagnetic metal element T as a main component selected from Fe, Co and Ni, and at least one element M selected from Ti, Zr, Hf, V, Nb, Ta, Mo and W.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: January 12, 1999
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 5833770
    Abstract: A soft magnetic alloy used as a radio frequency magnetic material and having high resistivity and high magnetic permeability in a high frequency band, and an inductor, a wave absorber and antenna each comprising the soft magnetic alloy. The soft magnetic alloy has a crystal phase containing Co as a main component and at least one element T selected as a primary component from Fe, Ni, Pd, Mn and Al, and having a face-centered cubic structure, a body-centered cubic structure or a mixture thereof having an average crystal grain size of 30 nm or less; and a ferromagnetic amorphous phase surrounding the crystal phase and containing at least one element M selected from Ti, Zr, Hf, Nb, Ta, Mo, W, Y and rare earth elements, O, N, C, B, at least one oxide of element M, Fe and element T.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: November 10, 1998
    Assignee: Alps Electric Co., Ltd.
    Inventors: Kumiko Ominato, Naoya Hasegawa, Yasuo Hayakawa, Akihiro Makino
  • Patent number: 5780177
    Abstract: A magnetic thin film is disclosed which has a composition represented substantially by the following chemical formula and, the same time, has the whole or part of the thin film formed of an amorphous region:{(Fe.sub.1-x Co.sub.x).sub.1-y (B.sub.1-z X.sub.z).sub.y }.sub.1-a RE.sub.awherein X represents at least one element selected from among the Group 4B elements in the CAS version of the Periodic Table, RE represents rare earth elements including Sm, and x, y, z, and a represent numerical values satisfying the following expressions, 0<x<1, 0<z<1, 0.05<y<0.36, and 0<a.ltoreq.0.1.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: July 14, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroshi Tomita, Tetsuhiko Mizoguchi
  • Patent number: 5750273
    Abstract: A thin film magnetic element is disclosed which uses a soft magnetic thin film having a composition represented by the general formula:T.sub.100-x-y M.sub.x (AO.sub.v).sub.y(wherein T stands for at least one element selected from the group consisting of Fe and Co, M for at least one element selected from the group consisting of Zr, Hf, Nb, and Y, and A for at least one element selected from the group consisting of Si, Ge, Sn, B, P, and C, and x, y, and v respectively satisfy the expressions, 5.ltoreq.x.ltoreq.20 at. %, 8.ltoreq.y.ltoreq.25 at. %, and 0.ltoreq.v.ltoreq.2), consisting of a homogeneous amorphous phase, and having resistivity of not less than 1000 .mu..OMEGA..multidot.cm. Further, a thin film magnetic element is disclosed which uses a soft magnetic thin film of a microstructure having a composition substantially represented by the general formula, T.sub.100-x-z M.sub.x (AO.sub.v).sub.z (1.ltoreq.z.+-.10 at.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: May 12, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tetsuo Inoue, Hiroshi Tomita, Tetsuhiko Mizoguchi, Hiromi Fuke
  • Patent number: 5741373
    Abstract: An Fe-based soft magnetic alloy having a high saturated magnetic flux density and having a composition represented by formula (I) below:(Fe.sub.1-a Q.sub.a).sub.b B.sub.x T.sub.y T'.sub.z (I)wherein Q represents at least one element selected from the group consisting of Co and Ni; T represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, with Zr and/or Hf being always included; T' represents at least one element selected from the group consisting of Cu, Ag, Au, Ni, Pd and Pt; a, b, x, y and z are real numbers satisfying relationships below:0.ltoreq.a.ltoreq.0.05,0.ltoreq.b.ltoreq.93 atomic %,0.5.ltoreq.x.ltoreq.16 atomic %,4.ltoreq.y.ltoreq.10 atomic %,0.ltoreq.z.ltoreq.4.5 atomic %provided that when 0<z.ltoreq.4.5 atomic %, Q represents Co and 0<b.ltoreq.92 atomic %; and when z=0, 0.5.ltoreq.x.ltoreq.8 atomic % and 4.ltoreq.y.ltoreq.9 atomic %.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: April 21, 1998
    Assignees: Alps Electric Co., Ltd., Tsuyoshi Masumoto
    Inventors: Kiyonori Suzuki, Akihiro Makino, Tsuyoshi Masumoto, Akihisa Inoue, Noriyuki Kataoka
  • Patent number: 5725686
    Abstract: A pulse transformer comprising a magnetic core formed of a thin strip of nanocrystalline soft magnetic alloy in which fine nanocrystalline grains having a grain size of not more than 50 nm occupy at least 50 volume % of the structure, characterized in that the AC relative initial magnetic permeability at -20.degree. C. and 50.degree. C. is not less than 50000.
    Type: Grant
    Filed: July 20, 1994
    Date of Patent: March 10, 1998
    Assignee: Hitachi Metals, Ltd.
    Inventors: Yoshihito Yoshizawa, Yoshio Bizen, Shin Nakajima, Shunsuke Arakawa
  • Patent number: 5725685
    Abstract: A soft magnetic alloy thin film includes a fine crystalline phase and an amorphous phase. The fine crystalline phase includes an average crystalline grain size of 10 nm or less in diameter and has body-centered cubic structure mainly composed of Fe. The amorphous phase has a nitrogen (N) compound as the main composition and occupies at least 50% of the structure of the thin film. An element M is incorporated at least in the amorphous phase, and includes at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, W, and rare earth metal elements. A plane-type magnetic device is made using this thin film.
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: March 10, 1998
    Assignee: Alps Electric Co., Ltd.
    Inventors: Yasuo Hayakawa, Akihiro Makino
  • Patent number: 5656101
    Abstract: A soft magnetic alloy thin film includes a fine crystalline phase and an amorphous phase. The fine crystalline phase includes an average crystalline grain size of 10 nm or less in diameter and has body-centered cubic structure mainly composed of Fe. The amorphous phase has a nitrogen (N) compound as the main composition and occupies at least 50% of the structure of the thin film. An element M is incorporated at least in the amorphous phase, and includes at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, W, and rare earth metal elements. A plane-type magnetic device is made using this thin film.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: August 12, 1997
    Assignee: Alps Electric Co., Ltd.
    Inventors: Yasuo Hayakawa, Akihiro Makino
  • Patent number: 5591276
    Abstract: There is provided according to the present invention a magnetic alloy with ultrafine crystal grains having a composition represented by the general formula:Fe.sub.100-x-y M.sub.x B.sub.y (atomic %)wherein M represents at least one element selected from Ti, Zr, Hf, V, Nb, Mo, Ta, Cr, W and Mn, 4.ltoreq.x.ltoreq.15, 2.ltoreq.y.ltoreq.25, and 7.ltoreq.x+y.ltoreq.35, at least 50% of the alloy structure being occupied by crystal grains having an average grain size of 500 .ANG. or less, and the crystal grains being based on a bcc structure. It may further contain X (Si, Ge, P, Ga, etc.) and/or T (Au, Co, Ni, etc.). This magnetic alloy has an excellent saturation magnetic flux density, permeability and heat resistance.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: January 7, 1997
    Assignee: Hitachi Metals, Ltd.
    Inventors: Yoshihito Yoshizawa, Yoshio Bizen, Shigekazu Suwabe, Kiyotaka Yamauchi, Toshikazu Nishiyama
  • Patent number: 5456770
    Abstract: An amorphous magnetic alloy of a composition represented by Fe.sub.a Si.sub.b B.sub.c Sn.sub.x, where 60<a.ltoreq.90, 1.ltoreq.b.ltoreq.19, 6.ltoreq.c.ltoreq.20, 0.01.ltoreq.x<10 (atomic %) and a+b+c+x=100.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: October 10, 1995
    Assignee: Nippon Steel Corporation
    Inventors: Takashi Sato, Toshio Yamada, Masahiro Fujikura, Wataru Ohashi, Satoshi Yamashita, Hideo Hagiwara
  • Patent number: 5449419
    Abstract: An Fe-based soft magnetic alloy having a high saturated magnetic flux density and having a composition represented by formula (I) below:(Fe.sub.1-a Q.sub.a).sub.b B.sub.x T.sub.y T'.sub.z (I)wherein Q represents at least one element selected from the group consisting of Co and Ni; T represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, with Zr and/or Hf being always included; T' represents at least one element selected from the group consisting of Cu, Ag, Au, Ni, Pd and Pt; a, b, x, y and z are real numbers satisfying relationships below:0.ltoreq.a.ltoreq.0.05 atomic %,0<b.ltoreq.93 atomic %,0.5.ltoreq.x.ltoreq.16 atomic %,4.ltoreq.y.ltoreq.10 atomic %,0.ltoreq.z.ltoreq.4.5 atomic %provided that when 0<z.ltoreq.4.5 atomic %, Q represents Co and 0<b.ltoreq.92 atomic %; and when z=0, 0.5.ltoreq.x.ltoreq.8 atomic % and 4.ltoreq.y.ltoreq.9 atomic %.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: September 12, 1995
    Assignees: Alps Electric Co., Ltd., Tsuyoshi Masumoto
    Inventors: Kiyonori Suzuki, Akihiro Makino, Tsuyoshi Masumoto, Akihisa Inoue, Noriyuki Kataoka
  • Patent number: 5340413
    Abstract: Fe-Ni based soft magnetic alloys having nanocrystalline particles substantially uniformly distributed throughout an amorphous matrix are disclosed. The soft magnetic alloys of the present invention may be represented by the general formula:(Fe.sub.1-x Ni.sub.x).sub.a M.sub.b (B.sub.1-y Si.sub.y).sub.cwhere M is a metal chosen from the group consisting of Mo, Cr, Hf, Nb, Ta, Ti, V, W, Zr. The quantity "x" is between about 0.2 and about 0.9; a is between about 60 and 90; b is between about 0.1 and 10; y is between 0 and 0.5; and c is between about 0.1 and about 30, with the stipulation that all the elements, plus impurities, add up to 100. Also described is a process for making the nanocrystalline alloys and for optimizing certain magnetic properties of said alloys via a two step anneal.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: August 23, 1994
    Assignee: AlliedSignal Inc.
    Inventor: Ronald Martis
  • Patent number: 5252148
    Abstract: A soft magnetic alloy having a composition of general formula:(Fe.sub.1-a Ni.sub.a).sub.100-x-y-z-p-q Cu.sub.x Si.sub.y B.sub.z Cr.sub.p M.sup.1.sub.q (I)wherein M.sup.1 is V or Mn or a mixture of V and Mn, 0.ltoreq.a.ltoreq.0.5, 0.1.ltoreq.x.ltoreq.5, 6.ltoreq.y.ltoreq.20, 6.ltoreq.z.ltoreq.20, 15.ltoreq.y+z.ltoreq.30, 0.5.ltoreq.p.ltoreq.10, and 0.5.ltoreq.q.ltoreq.10 and possessing a fine crystalline phase is suitable as a core, especially a wound core and a compressed powder core.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: October 12, 1993
    Assignee: TDK Corporation
    Inventors: Masao Shigeta, Asako Kajita, Ippo Hirai, Tsutomu Choh
  • Patent number: 5186765
    Abstract: The extremely low temperature cold accumulating material for use in refrigerators, for example, comprises particles containing at least one kind of rare earth element selected from a group consisting of Y, La, Ce, Pr, Nd, Pm, Sm Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb. The proportion of particles each having a particle size of 0.01 to 3 mm is 70% or greater by weight with respect to the whole particles and the proportion of particles each having a shape such that the ratio of the major diameter to the minor diameter is not greater than 5 is 70% or greater by weight with respect to the whole particles. The particles are manufactured by quenching and solidifying a molten metal containing at least one kind of rare earth element described above. The thus manufactured extremely low temperature cold accumulating material is improved in cold accumulating efficiency and is specifically improved in mechanical strength and in chemical stability.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: February 16, 1993
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tomohisa Arai, Naoyuki Sori, Masashi Sahashi, Yoichi Tokai
  • Patent number: 5178689
    Abstract: Fe-based soft magnetic alloy having excellent soft magnetic characteristics with high saturated magnetic flux density, characterized in that it has fine crystal grains dispersed in an amorphous phase and is expressed by the general formula:Fe.sub.100-a-b-c Cu.sub.a M.sub.b Y.sub.cwhere:"M" is at least one or more selected from elements of groups IVa, Va, VIa of the periodic table, Mn, Co, Ni, Al, and the Platinum group,"Y" is at least one or more selected from Si, B, P, or Cand 3<a.ltoreq.8 (atomic %)0.1<b.ltoreq.83.1.ltoreq.a+b.ltoreq.1215.ltoreq.c.ltoreq.28.Also described is a dust core made from an alloy powder having fine crystal grains dispersed in an amorphous phase and expressed by the formulaFe.sub.100-a-b-c-d-e Cu.sub.a M'.sub.b M".sub.c Si.sub.d B.sub.
    Type: Grant
    Filed: June 5, 1991
    Date of Patent: January 12, 1993
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masami Okamura, Takao Sawa
  • Patent number: 5133814
    Abstract: A novel soft magnetic amorphous alloy thin film which, on account of the composition of the film consisting in a combination of a transition metal, a metalloid or semiconducting element, namely B, C or Si and an oxide derived from the starting material, is endowed with a comminuted and dispersed structure of a magnetic amorphous phase and a nonmagnetic amorphous phase. The soft magnetic amorphous alloy thin film may be applied to a magnetic head for short wavelength recording which is required to cope with high frequency characteristics and high coercivity of the recording medium.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: July 28, 1992
    Assignee: Sony Corporation
    Inventors: Hideaki Matsuyama, Hideaki Karamon
  • Patent number: 5104464
    Abstract: A soft magnetic alloy film has a composition formula expressed by Fex Mz Cw. M is at least one metallic element selected from a group consisting of Ti, Zr, Hf, Nb, Ta, Mo or W, or a mixture of these metallic elements. The composition ratio of x, z and w satisfies the relation expressed by 50 atomic %.ltoreq.x.ltoreq.96 atomic %, 2 atomic %.ltoreq.z.ltoreq.30 atomic %, 0.5 atomic %.ltoreq.w.ltoreq.25 atomic %, and x+z+w=100. The metallic structure of the soft magnetic alloy film basically consists of crystal grains having an average grain size of 0.08 .mu.m or below. The metallic structure contains the crystal phase of carbide of the element M.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: April 14, 1992
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 5069731
    Abstract: A low-frequency transformer including a magnetic core made of an alloy having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-.alpha. Cu.sub.x Si.sub.y B.sub.z M'.sub..alpha. (atomic %)wherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, W, Ta, Mo, Zr, Hf and Ti, and a, x, y, z and .alpha. respectively satisfy 0.ltoreq.a.ltoreq.0.3, 0.1.ltoreq.x.ltoreq.3, 0.ltoreq.y.ltoreq.17, 4.ltoreq.z.ltoreq.17, 10.ltoreq.y+z.ltoreq.28 and 0.1.ltoreq..alpha..ltoreq.5, at least 50% of the alloy structure being occupied by fine crystal grains having an average grain size of 1000 .ANG. or less when measured by their maximum diameters. The alloy may further contain at least one element selected from the group consisting of Ge, P, C, Ga, Al and N.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: December 3, 1991
    Assignee: Hitachi Metals, Ltd.
    Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
  • Patent number: 5067991
    Abstract: An Fe-based soft magnetic alloy represented substantially by the general formula:Fe.sub.a Cu.sub.b V.sub.c Si.sub.d B.sub.ewherein a, b, c, d, and e are numbers respectively satisfying the following formula:a+b+c+d+e=100 (atomic percentage)0.01.ltoreq.b.ltoreq.3.50.01.ltoreq.c.ltoreq.1510.ltoreq.d.ltoreq.253.ltoreq.e.ltoreq.1217.ltoreq.d+e.ltoreq.30),and the alloy structure thereof having fine crystal grains, for example, in the range of 20 to 95% in area ratio. This Fe-based soft magnetic alloy has high saturation magnetic flux density, and excellent soft magnetic characteristics. Also, it is excellent in the processability and anti-shock properties.
    Type: Grant
    Filed: June 6, 1989
    Date of Patent: November 26, 1991
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takao Sawa, Masami Okamura
  • Patent number: 4985088
    Abstract: Fe-based soft magnetic alloy having excellent soft magnetic characteristics with high saturated magnetic flux density, characterized in that it has fine crystal grains and is expressed by the general formula:(Fe.sub.1-a-b Cu.sub.a M.sub.b).sub.100-c Y.sub.cwhere "M" is at least one or more selected from rare earth elements, "Y" is at least one or more selected from Si, B, P, and C, and "a", "b" and "c" are as follows:0.005.ltoreq.a.ltoreq.0.050.005.ltoreq.b.ltoreq.0.115.ltoreq.c.ltoreq.28 (at %).Also described is a method of treating the alloy to segregate fine crystal grains which comprises heat treating the alloy for a period of from one minute to ten hours at a temperature of from 50.degree. C. below the crystallization temperature to 120.degree. C. above the crystallization temperature.
    Type: Grant
    Filed: May 17, 1989
    Date of Patent: January 15, 1991
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masami Okamura, Takao Sawa
  • Patent number: 4925742
    Abstract: A thin film having a large high Kerr rotation angle is formed of a compound having a composition represented by the following formula (I):J.sub.x L.sub.y Q.sub.(100-x-y) (I)whereinJ: at least one of F, Cl, Br and I;L: at least one of B, C, Al, Si, P, As, Sb, Bi, Se, Te, Ti, V, Cr, Mn, Ni, Ga, Ge, Zr, Nb and Mo;Q: at least one of Fe and Co;x: a value of 3-80; andy: a value satisfying the following equation (II):3.ltoreq.x+y.ltoreq.80 (II)The film is produced by reacting a halogen or halogen-containing gas, which has occurred as a result of decomposition of a halogen compound, with a metal plasma or halogen-containing metal plasma and allowing the resultant component to deposit as a thin film on a substrate.
    Type: Grant
    Filed: October 18, 1988
    Date of Patent: May 15, 1990
    Assignees: Research Development Corporation of Japan, Tokin Corporation
    Inventors: Eishu Sugawara, Taketoshi Nakayama, Tsuyoshi Masumoto
  • Patent number: 4921763
    Abstract: The present invention provides, by combining as the composition of the soft magnetic thin film transition metals and two different kinds of metalloid (semiconductor) elements, herein B, C and Si, a novel amorphous soft magnetic thin film having a structure wherein two phases, namely the ferromagnetic amorphous phase and the non-magnetic amorphous phase and finely dispersed for realizing a soft magnetic thin film that is superior in high frequency characteristics and that may be applied to the magnetic head technology for short wavelength recording that may be advantageously employed with a high coercive force medium.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: May 1, 1990
    Assignee: Sony Corporation
    Inventor: Hideaki Karamon
  • Patent number: 4837094
    Abstract: An oxygen-containing ferromagnetic amorphous alloy having the formulaM.sub.x G.sub.y O.sub.zwherein M is one or more transition elements of Fe, Co and Ni; or a combination of said transition element or elements and one or more elements selected from the group consisting of V, Cr, Mn, Nb, Mo, Hf, Ta, W, Pt, Sm, Gd, Tb, Dy and Ho; G is one or more elements selected from the group consisting of B, Si, Ge, As, Sb, Ti, Sn, Al and Zr; and x, y and z are the fractional atomic percentages of M, G and O and y+y+z=100 and this alloy in combination with a substrate.
    Type: Grant
    Filed: February 4, 1987
    Date of Patent: June 6, 1989
    Assignees: Research Development Corporation of Japan, Casio Computer Co., Ltd.
    Inventor: Toshio Kudo
  • Patent number: 4812181
    Abstract: A method for achieving a flat magnetization loop in cores, such as for use in inductive components, which are wound of amorphous ribbon includes the steps of subjecting the wound core to long-term heat treatment of more than 10 hours, and selecting the temperature during the heat treatment so low that less than half of the ribbon cross-section exhibits crystalline precipitations which occur during the heat treatment.
    Type: Grant
    Filed: March 16, 1987
    Date of Patent: March 14, 1989
    Assignee: Vacuumschmelze GmbH
    Inventors: Hans-Rainer Hilzinger, Giselher Herzer
  • Patent number: 4781754
    Abstract: A method is provided for rapidly solidifying rare earth-transition metal containing alloy. It entails introducing the alloy into the flame of a plasma torch and directing the torch flame onto the inside surface of a rotating quench cylinder. A non-oxidizing gas is also directed onto the quench surface so that the alloy solidifies at a rate such that a powder having a substantially amorphous to finely crystalline microstructure is obtained and such that the solidified alloy does not adhere to the quench surface and can be easily collected.
    Type: Grant
    Filed: September 24, 1987
    Date of Patent: November 1, 1988
    Assignee: General Motors Corporation
    Inventors: Vito W. Soranno, Frank G. Pirrallo, Thomas H. Van Steenkiste