Zinc Containing Patents (Class 148/434)
  • Patent number: 11572921
    Abstract: A sintered bearing is made of a sintered compact containing nickel silver (Cu—Ni—Zn) as a base. In the sintered bearing, P is not added in the sintered compact. Alternatively, a content of P in the sintered compact is less than 0.05 mass % in terms of mass ratio to a total mass. Consequently, crystal grains constituting the sintered compact can be micronized. In particular, in the sintered bearing, an average crystal particle diameter of the crystal grains constituting the sintered compact is 20 ?m or less. Consequently, the mechanical strength and the vibration resisting properties can be improved, and the rotation shaft can be prevented from being damaged.
    Type: Grant
    Filed: January 25, 2019
    Date of Patent: February 7, 2023
    Assignee: PORITE CORPORATION
    Inventors: Shigeyuki Tanabe, Shinobu Aso, Hiroshi Nara
  • Patent number: 11421301
    Abstract: This free-cutting copper alloy casting contains: 76.0-79.0% Cu, 3.1-3.6% Si, 0.36-0.85% Sn, 0.06-0.14% P, 0.022-0.10% Pb, with the remainder being made up of Zn and unavoidable impurities. This composition satisfies the following relations: 75.5?f1=Cu+0.8×Si?7.5×Sn+P+0.5×Pb?78.7, 60.8?f2=Cu?4.5×Si—0.8×Sn?P+0.5×Pb?62.2, 0.09?f3=P/Sn?0.35. The area ratios (%) of the constituent phases satisfy the following relations, 30???63, 0???2.0, 0???0.3, 0???2.0, 96.5?f4=?+?, 99.3?f5=?+?+?+?, 0?f6=?+??3.0, and 37?f7=1.05×?+6×?1/2+0.5×??72. The ? phase is present within the ? phase, the long side of the ? phase does not exceed 50 ?m, and the long side of the ? phase does not exceed 25 ?m.
    Type: Grant
    Filed: August 15, 2017
    Date of Patent: August 23, 2022
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Keiichiro Oishi, Kouichi Suzaki, Shinji Tanaka, Yoshiyuki Goto
  • Patent number: 11313013
    Abstract: This free-cutting copper alloy contains more than 77.0% but less than 81.0% Cu, more than 3.4% but less than 4.1% Si, 0.07% to 0.28% Sn, 0.06% to 0.14% P, and more than 0.02% but less than 0.25% Pb, with the remainder being made up of Zn and unavoidable impurities. The composition satisfies the following relations: 1.0?f0=100×Sn/(Cu+Si+0.5×Pb+0.5×P?75.5)?3.7, 78.5?f1=Cu+0.8×Si?8.5×Sn+P+0.5×Pb?83.0, 61.8?f2=Cu?4.2×Si?0.5×Sn?2×P?63.7. The area ratios (%) of the constituent phases satisfy the following relations, 36???72, 0???2.0, 0???0.5, 0???2.0, 96.5?f3=?+?, 99.4?f4=?+?+?+?, 0?f5=?+??3.0, 38?f6=?+6×?1/2+0.5×??80. The long side of the ? phase does not exceed 50 ?m, and the long side of the ? phase does not exceed 25 ?m.
    Type: Grant
    Filed: August 15, 2017
    Date of Patent: April 26, 2022
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Keiichiro Oishi, Kouichi Suzaki, Shinji Tanaka, Yoshiyuki Goto
  • Patent number: 11028464
    Abstract: The present invention provides a lead-free easy-to-cut corrosion-resistant brass alloy with good thermoforming performance. The brass alloy contains: 74.5-76.5 wt % of Cu, 3.0-3.5 wt % of Si, 0.11-0.2 wt % of Fe, 0.04-0.10% wt % of P, Zn and inevitable impurities. The alloy provided by the present invention has good cold-working and hot-working forming performance, and good dezincification corrosion-resistant and stress corrosion-resistant performance, applies to parts that require cutting and grinding forming in water-heating sanitaryware, electronic appliances, automobiles and the like, and especially applies to production and assembling of complex forging products for which stress is inconvenient to eliminate, such as water taps, values and the like.
    Type: Grant
    Filed: January 24, 2014
    Date of Patent: June 8, 2021
    Assignee: XIAMEN LOTA INTERNATIONAL CO., LTD.
    Inventors: Chuankai Xu, Zhenqing Hu, Nianrun Zhou, Siqi Zhang, Jia Long, Huawei Zhang
  • Patent number: 10532406
    Abstract: A sintered sliding material with excellent corrosion resistance, heat resistance, and wear resistance is provided. The sintered sliding material has a composition made of: 36-86 mass % of Ni; 1-11 mass % of Sn; 0.05-1.0 mass % of P; 1-9 mass % of C; and the Cu balance including inevitable impurities. The sintered sliding material is made of a sintered material of a plurality of grains of alloy of Ni—Cu alloy or Cu—Ni alloy, the Ni—Cu alloy and the Cu—Ni alloy containing Sn, P, C, and Si; has a structure in which pores are dispersedly formed in grain boundaries of the plurality of the grains of alloy; and as inevitable impurities in a matrix constituted from the grains of alloy, a C content is 0.6 mass % or less and a Si content is 0.15 mass % or less.
    Type: Grant
    Filed: September 10, 2015
    Date of Patent: January 14, 2020
    Assignee: Diamet Corporation
    Inventors: Shinichi Takezoe, Yoshinari Ishii
  • Patent number: 10287653
    Abstract: In accordance with an exemplary embodiment, a high-strength brass alloy includes, by mass %, about 1.3% to about 2.3% of aluminum (Al), about 1.5% to about 3.0% of manganese (Mn), about 1% maximum of iron (Fe), about 1% maximum of nickel (Ni), about 0.4% maximum of tin (Sn), about 0.5% to about 2.0% of silicon (Si), about 57% to about 60% of copper (Cu), less than about 0.1% of lead (Pb), and the balance of zinc (Zn) and inevitable impurities, with the proviso that the ratio of Si/Mn is in the range of about 0.3 to about 0.7, and with the further proviso that the “zinc equivalent” content according to the following formula: ZnEq=Zn+Si*10?Mn/2+Al*5 is from about 51% to about 58%.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: May 14, 2019
    Assignee: Garrett Transportation I Inc.
    Inventors: Shouxing Zhu, Bin Shen, Marc Wilson
  • Patent number: 10006106
    Abstract: Provided is a brass alloy excellent in recyclability and corrosion resistance while avoiding the addition of Bi and Si, and with which machinability is ensured and processing is facilitated with preventing inclusion of lead. The present invention includes at least 58.0 to 63.0 mass % of Cu, 1.0 to 2.0 mass % of Sn and 0.05 to 0.29 mass % of Sb and the remainder composed of Zn and unavoidable impurities. With the present invention, stress corrosion crack resistance and machinability are improved. 0.05 to 1.5 mass % of Ni is included in a copper alloy to improve stress corrosion crack resistance as a result of the interaction between Ni and Sb. Furthermore, 0.05 to 0.2 mass % of P is included to improve anti-dezincification properties.
    Type: Grant
    Filed: April 8, 2013
    Date of Patent: June 26, 2018
    Assignees: KITZ CORPORATION, KITZ METALWORKS CORPORATION
    Inventors: Hidenobu Tameda, Hisanori Terui, Kei Ito, Tomoyuki Ozasa
  • Patent number: 9963765
    Abstract: A copper alloy for use in water works has not only a reduced lead content and the lowest possible Ni content, but also a reduced Bi content, and still exhibits suitable properties. The copper alloy includes: less than 0.5% by mass of Ni; 0.2% by mass or more and 0.9% by mass or less of Bi; 12.0% by mass or more and 20.0% by mass or less of Zn; 1.5% by mass or more and 4.5% by mass or less of Sn; and 0.005% by mass or more and 0.1% by mass or less of P; wherein the total content of Zn and Sn is 21.5% by mass or less, and the balance is a trace element(s) and Cu.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: May 8, 2018
    Assignee: KURIMOTO, LTD.
    Inventors: Masaaki Yamamoto, Hiroshi Yamada, Takeaki Miyamoto, Syohei Matsuba
  • Patent number: 9951400
    Abstract: A wrought machinable low copper, silicon, zinc alloy having a copper content between about 66 weight percent and about 70 weight percent and wherein the silicon content is between about 1.3 weight percent and about 2.0 weight percent.
    Type: Grant
    Filed: August 3, 2015
    Date of Patent: April 24, 2018
    Assignee: CHASE BRASS AND COPPER COMPANY, LLC
    Inventors: David Dean McDevitt, Charles Lawrence Muller
  • Patent number: 9829122
    Abstract: Copper alloys exhibiting enhanced oxidation resistance are provided by adding an amount of sulfur that is effective to enhance oxidative resistance. Such sulfur addition can be achieved by combining elemental forms of copper and sulfur and heating the mixture to form a molten alloy, or by forming a sulfur-rich pre-mix that is added to a base alloy composition. Forming a pre-mix provides improved homogeneity and distribution of the sulfur predominantly in the form of a metal sulfide.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: November 28, 2017
    Assignee: NIBCO INC.
    Inventor: Benjamin L. Lawrence
  • Patent number: 9617629
    Abstract: The invention includes a copper-nickel-zinc alloy with the following composition in weight %: Cu 47.0 to 49.0%, Ni 8.0 to 10.0%, Mn 0.2 to 0.6%, Si 0.05 to 0.4%, Pb 1.0 to 1.5%, Fe and/or Co up to 0.8%, the rest being Zn and unavoidable impurities, wherein the total of the Fe content and double the Co content is at least 0.1 weight % and wherein mixing silicides containing nickel, iron and manganese and/or containing nickel, cobalt and manganese are stored as spherical or ellipsoidal particles in a structure consisting of an ?- and ?-phase. The invention further relates to a method for producing semi-finished products from a copper-nickel-zinc alloy.
    Type: Grant
    Filed: February 8, 2013
    Date of Patent: April 11, 2017
    Assignee: WIELAND-WERKE AG
    Inventors: Hans-Achim Kuhn, Rudolf Liebsch
  • Patent number: 9162423
    Abstract: The invention relates to a multilayered bearing shell (2) comprising a back metal layer (3) as a carrier element for the layer structure and at least one further bearing layer joined to the back metal layer (3), wherein the back metal layer (3) is made from a bronze. The back metal layer (3) contains in addition to copper, which forms the matrix of the bronze, tin in a proportion selected from a range with a lower limit of 1.25 wt. % and an upper limit of 12 wt. %, zinc in a proportion selected from a range with a lower limit of 0.25 wt. % and an upper limit of 6 wt. % and phosphorus in a proportion selected from a range with a lower limit of 0.01 wt. % and an upper limit of 0.5 wt. %.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: October 20, 2015
    Assignees: Miba Gleitlager GmbH, MTU Friedrichshafen GmbH
    Inventors: Reiner Boeschen, Robert Mergen, Falko Langbein, Ulrich Schmid
  • Patent number: 9017491
    Abstract: A hot-forged copper alloy part which has a tubular shape, in which an alloy composition contains 59.0 mass % to 84.0 mass % of Cu and 0.003 mass % to 0.3 mass % of Pb with a remainder of Zn and inevitable impurities, a content of Cu [Cu] mass % and a content of Pb [Pb] mass % have a relationship of 59?([Cu]+0.5×[Pb])?64, a shape of the forged part satisfies a formula of 0.4?(average inner diameter)/(average outer diameter)?0.92, 0.04?(average thickness)/(average outer diameter)?0.3, and 1?(tube axis direction length)/(average thickness))?10, a forging material which is to be hot-forged has a tubular shape and satisfies 0.3?(average inner diameter/average outer diameter)?0.88, 0.06?(average thickness)/(average outer diameter)?0.35, and 0.8?(tube axis direction length)/(average thickness))?12, and 0%?(degree of uneven thickness)?30%, 0?(degree of uneven thickness)?75×1/((tube axis direction length)/(average thickness))1/2 in any location in a tube axis direction.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: April 28, 2015
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventors: Keiichiro Oishi, Takayuki Oka, Shin Oikawa
  • Patent number: 8968492
    Abstract: There is provided a brass free from lead (Pb) and possessing excellent machinability, castability, mechanical properties and other properties. A brass consisting of not less than 55% by weight and not more than 75% by weight of copper (Cu), not less than 0.3% by weight and not more than 4.0% by weight of bismuth (Bi), and y % by weight of boron (B) and x % by weight of silicon (Si), y and x satisfying the following requirements: 0?x?2.0, 0?y?0.3, and y>?0.15x+0.015ab, wherein a is 0.2 when Bi is 0.3% by weight ?Bi<0.75% by weight; 0.85 when Bi is 0.75% by weight ?Bi<1.5% by weight; and 1 when Bi is 1.5% by weight ?Bi?4.0% by weight, b is 1 when the apparent content of zinc (Zn) is not less than 37% and less than 41%; and 0.75 when the apparent content of Zn is not less than 41% and not more than 45%, the balance consisting of Zn and unavoidable impurities, is excellent in castability, as well as, for example, in machinability and mechanical properties.
    Type: Grant
    Filed: October 1, 2008
    Date of Patent: March 3, 2015
    Assignee: Toto Ltd.
    Inventor: Toru Uchida
  • Publication number: 20150044089
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 69 to 79 percent, by weight, of copper, 2.0 to 4.0 percent, by weight, of silicon, 0.02 to 0.4 percent, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Application
    Filed: August 19, 2014
    Publication date: February 12, 2015
    Inventor: Keiichiro Oishi
  • Patent number: 8950941
    Abstract: High-strength brass alloy having superior wear maintains single-structure ? phase and Fe-Cr-Si-based intermetallic compounds dispersed in the ? phase. A high-strength brass alloy for sliding member comprises, Zn from 17% to 28%, Al from 3% to 10%, Fe from 1% to 4%, Cr from 0.1% to 4%, Si from 0.5% to 3%, mass ratio, and the remnant including Cu and inevitable impurities. The high-strength brass alloy has structure in which the matrix shows single-phase structure of ? phase and Fe-Cr-Si-based intermetallic compounds are dispersed in the ? phase. The high-strength brass alloy for sliding member has the structure in which the matrix shows single-structure of ? phase and hard Fe-Cr-Si-based intermetallic compounds are dispersed in the ? phase. Thus the hardness is increased and wear resistance is improved.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: February 10, 2015
    Assignee: Oiles Corporation
    Inventors: Maki Hirayama, Taku Watakabe, Kentaro Okubo
  • Publication number: 20140305551
    Abstract: A copper alloy material for electrical and electronic components and a method of preparing the same are disclosed. In particular, a copper alloy material with excellent mechanical strength characteristics, high electrical conductivity, and high thermal stability as a material for information transmission and electrical contact of connectors or the like for home appliances and automobiles, including semiconductor lead frames and a method of preparing the same are disclosed.
    Type: Application
    Filed: October 22, 2013
    Publication date: October 16, 2014
    Applicant: POONGSAN CORPORATION
    Inventors: CHEOL MIN PARK, In Youb Hwang
  • Patent number: 8821655
    Abstract: A copper base alloy achieves a breakthrough electrical conductor product of strength, flexure and conductivity of minimal inverse in relationship of at least 85% IACS electrical conductivity while providing an 80 to 85 ksi tensile strength, an increase of at least 33% in strength compared to prior art and is made from an alloy containing 0.2-0.5 w/o chromium, 0.02-0.20 w/o silver and 0.04-0.16 w/o of a third metallic component selected from tin, magnesium and tin/magnesium together.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: September 2, 2014
    Assignee: Fisk Alloy Inc.
    Inventor: Joseph Saleh
  • Patent number: 8795446
    Abstract: A copper alloy material, having an alloy composition containing any one or both of Ni and Co in an amount of 0.4 to 5.0 mass % in total, and Si in an amount of 0.1 to 1.5 mass %, with the balance being copper and unavoidable impurities, wherein a ratio of an area of grains in which an angle of orientation deviated from S-orientation {2 3 1}<3 4 6> is within 30° is 60 % or more, according to a crystal orientation analysis in EBSD measurement; an electrical or electronic part formed by working the copper alloy material; and a method of producing the copper alloy material.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: August 5, 2014
    Assignee: Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Kiyoshige Hirose, Tatsuhiko Eguchi
  • Publication number: 20140212324
    Abstract: Provided by the present invention are a fine crystallite high-function metal alloy member, a method for manufacturing the same, and a business development method thereof, in which a crystallite of a metal alloy including a high-purity metal alloy whose crystal lattice is a face-centered cubic lattice, a body-centered cubic lattice, or a close-packed hexagonal lattice is made fine with the size in the level of nanometers (10?9 m to 10?6 m) and micrometers (10?6 m to 10?3 m), and the form thereof is adjusted, thereby remedying drawbacks thereof and enhancing various characteristics without losing superior characteristics owned by the alloy.
    Type: Application
    Filed: April 10, 2012
    Publication date: July 31, 2014
    Applicant: THREE-O CO., LTD.
    Inventor: Kazuo Ogasa
  • Patent number: 8715431
    Abstract: A Cu—Fe—P copper alloy sheet which has the high strength and the high electrical conductivity compatible with excellent bendability is provided. The Cu—Fe—P copper alloy sheet contains 0.01% to 3.0% of Fe and 0.01% to 0.3% of P on a percent by mass basis, wherein the orientation density of the Brass orientation is 20 or less and the sum of the orientation densities of the Brass orientation, the S orientation, and the Copper orientation is 10 or more and 50 or less in the microstructure of the copper alloy sheet.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: May 6, 2014
    Assignee: Kobe Steel, Ltd.
    Inventors: Yasuhiro Aruga, Katsura Kajihara
  • Patent number: 8641838
    Abstract: A copper alloy sheet material, having a composition containing any one or both of Ni and Co in an amount of 0.5 to 5.0 mass % in total, and Si in an amount of 0.3 to 1.5 mass %, with the balance of copper and unavoidable impurities, wherein an area ratio of cube orientation {0 0 1} <1 0 0> is 5 to 50%, according to a crystal orientation analysis in EBSD measurement.
    Type: Grant
    Filed: December 1, 2010
    Date of Patent: February 4, 2014
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Kiyoshige Hirose, Koji Sato
  • Patent number: 8603390
    Abstract: A brazing alloy including copper (Cu), phosphorus (P), and strontium (Sr) and any one element of indium (In), boron (B), silver (Ag), tin (Sn), cesium (Cs), germanium (Ge), and nickel (Ni). The brazing alloy includes 5.0 to 7.5 wt % of phosphorus (P) and 0.1 to 5.0 wt % of strontium (Sr) and the remainder is composed of copper (Cu). The brazing alloy includes copper (Cu), phosphorus (P), and strontium (Sr) unlike the existing alloy element. The brazing alloy further includes, as alloy components, one or more elements of indium (In), boron (B), silver (Ag), and tin (Sn). The brazing alloy includes no silver (Ag) or the silver (Ag) content is reduced compared to an existing brazing alloy containing silver (Ag).
    Type: Grant
    Filed: May 8, 2012
    Date of Patent: December 10, 2013
    Assignee: Alcoma, Ltd.
    Inventor: Chu Hyon Cho
  • Publication number: 20130284327
    Abstract: A copper alloy for an electric device contains Mg in a range of 1.3 atomic % or more and less than 2.6 atomic %, Al in a range of 6.7 atomic % or more and 20 atomic % or less, and the balance substantially consisting of Cu and unavoidable impurities. A method of producing a copper alloy includes: performing heating of a copper material to a temperature of not lower than 500° C. and not higher than 1000° C.; performing quenching to cool the heated copper material to 200° C. or lower with a cooling rate of 200° C./min or more; and performing working of the cooled copper material, wherein the copper material is composed of a copper alloy containing Mg in a range of 1.3 atomic % or more and less than 2.6 atomic %, Al in a range of 6.7 atomic % or more and 20 atomic % or less.
    Type: Application
    Filed: November 24, 2011
    Publication date: October 31, 2013
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kazunari Maki, Yuki Ito
  • Publication number: 20130276938
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 69 to 79 percent, by weight, of copper, 2.0 to 4.0 percent, by weight, of silicon, 0.02 to 0.4 percent, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 24, 2013
    Inventor: Mitsubishi Shindoh Co., Ltd.
  • Patent number: 8506730
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 69 to 79 percent, by weight, of copper, 2.0 to 4.0 percent, by weight, of silicon, 0.02 to 0.4 percent, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Grant
    Filed: March 31, 2005
    Date of Patent: August 13, 2013
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventor: Keiichiro Oishi
  • Patent number: 8470101
    Abstract: Disclosed is a lead-free copper alloy for casting which contains 0.1-0.7% of S, 8% or less (excluding 0%) of Sn, and 6% or less (excluding 0%) of Zn, and in which a sulfide is dispersed and the average spheroidization ratio of the sulfide is 0.7 or greater. Due to this constitution, said lead-free copper alloy for casting has excellent mechanical properties such as strength, high pressure resistance and good machinability and, therefore, is useful as a starting material for faucet metal fittings, water faucet and so on, even though the alloy contains no lead which causes deterioration of water.
    Type: Grant
    Filed: May 17, 2010
    Date of Patent: June 25, 2013
    Assignees: Shiga Valve Cooperative, Biwalite Co., Ltd.
    Inventors: Takeshi Kobayashi, Toru Maruyama, Ryozo Matsubayashi, Hiroyuki Abe, Masakazu Teramura
  • Patent number: 8444779
    Abstract: The invention provides Cu—Ni—Si—Co alloys having excellent strength, electrical conductivity, and press-punching properties. In one aspect, the invention is a copper alloy for electronic materials, containing 1.0 to 2.5 mass % of Ni, 0.5 to 2.5 mass % of Co, and 0.30 to 1.2 mass % of Si, the balance being Cu and unavoidable impurities, wherein the copper alloy for electronic material has a [Ni+Co+Si] content in which the median value ? (mass %) satisfies the formula 20 (mass %)???60 (mass %), the standard deviation ? (Ni+Co+Si) satisfies the formula ? (Ni+Co+Si)?30 (mass %), and the surface area ratio S (%) satisfies the formula 1%?S?10%, in relation to the compositional variation and the surface area ratio of second-phase particles size of 0.1 ?m or greater and 1 ?m or less when observed in a cross section parallel to a rolling direction.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: May 21, 2013
    Assignee: JX Nippon Mining & Metals Co., Ltd.
    Inventors: Naohiko Era, Hiroshi Kuwagaki
  • Patent number: 8435361
    Abstract: A novel copper-zinc alloy is particularly suited for a valve guide. The copper-zinc alloy contains 59 to 73% copper, 2.7 to 8.3% manganese, 1.5 to 6% aluminum, 0.2 to 4% silicon, 0.2 to 3% iron, 0 to 2% lead, 0 to 2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: May 7, 2013
    Assignee: Diehl Metall Stiftung & Co. KG
    Inventors: Norbert Gaag, Alexander Dehnelt
  • Patent number: 8430979
    Abstract: A copper alloy having an improved combination of yield strength and electrical conductivity contains, by weight, from 1% to 2.5% of nickel, from 0.5% to 2.0% of cobalt, with a total nickel plus cobalt content of from 1.7% to 4.3%, from 0.5% to 1.5% of silicon with a ratio of (Ni+Co)/Si of between 3.5 and 6, and the balance copper and inevitable impurities wherein the wrought copper alloy has an electrical conductivity in excess of 40% IACS. A further increase in the combination of yield strength and electrical conductivity as well as enhanced resistance to stress relaxation is obtained by a further inclusion of up to 1% of silver.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: April 30, 2013
    Assignee: GBC Metals, LLC
    Inventors: Frank N. Mandigo, Peter W. Robinson, Derek E. Tyler, Andreas Boegel, Hans-Achim Kuhn, Frank M. Keppeler, Joerg Seeger
  • Patent number: 8425697
    Abstract: A tin-free lead-free free-cutting magnesium brass alloy contains 56.0 to 64.0 wt % Cu, 1.05 to about 2.1 wt % Mg, 0.21 to 0.4 wt % P and other elements 0.002 to 0.9 wt % which contain at least two elements selected from Al, Si, Sb, rare earth elements, Ti and B and the balance being Zn with unavoidable impurities, accordingly a cutting percentage of the alloy is at least 80%. The process for producing such alloy is also proposed. The invented alloy is excellent in cuttability, castability, hot and cold workability, corrosion resistance, mechanical properties and weldability and particularly applicable in spare parts, forging and casting which need cutting and grinding process. The cost of necessary metal materials of the invented alloy is lower than lead-free free-cutting bismuth and antimony brass alloy and is equivalent to lead-contained brass alloy.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: April 23, 2013
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Publication number: 20130087255
    Abstract: Disclosed is a Cu—Co—Si-based copper alloy for electronic materials, which is capable of achieving high levels of strength, electrical conductivity, and also anti-setting property; and contains 0.5 to 3.0% by mass of Co, 0.1 to 1.0% by mass of Si, and the balance of Cu and inevitable impurities; wherein out of second phase particles precipitated in the matrix a number density of the particles having particle size of 5 nm or larger and 50 nm or smaller is 1×1012 to 1×1014 particles/mm3, and a ratio of the number density of particles having particle size of 5 nm or larger and smaller than 10 nm relative to the number density of particles having particle size of 10 nm or larger and 50 nm or smaller is 3 to 6.
    Type: Application
    Filed: April 8, 2011
    Publication date: April 11, 2013
    Applicant: JX Nippon Mining & Metals Corporation
    Inventor: Hiroshi Kuwagaki
  • Publication number: 20130056116
    Abstract: A copper alloy for an electronic device containing Mg in a range of 2.6 atomic % or more and 9.8 atomic % or less, Al in a range of 0.1 atomic % or more and 20 atomic % or less, and the balance substantially consisting of Cu and unavoidable impurities.
    Type: Application
    Filed: May 12, 2011
    Publication date: March 7, 2013
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yuki Ito, Kazunari Maki
  • Publication number: 20130048162
    Abstract: One aspect of this copper alloy for an electronic device is composed of a binary alloy of Cu and Mg which includes Mg at a content of 3.3 to 6.9 atomic %, with a remainder being Cu and inevitable impurities, and a conductivity ? (% IACS) is within the following range when the content of Mg is given as A atomic %, ??{1.7241/(?0.0347×A2+0.6569×A+1.7)}×100. Another aspect of this copper alloy for an electronic device is composed of a ternary alloy of Cu, Mg, and Zn which includes Mg at a content of 3.3 to 6.9 atomic % and Zn at a content of 0.1 to 10 atomic %, with a remainder being Cu and inevitable impurities, and a conductivity ? (% IACS) is within the following range when the content of Mg is given as A atomic % and the content of Zn is given as B atomic %, ??{1.7241/(X+Y+1.7)}×100 X=?0.0347×A2+0.6569×A Y=?0.0041×B2+0.2503×B.
    Type: Application
    Filed: May 13, 2011
    Publication date: February 28, 2013
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yuki Ito, Kazunari Maki
  • Patent number: 8366841
    Abstract: A lead-free free-cutting corrosion-resistant silicon-bismuth brass alloy, including the following: between 60.0 and 65.0 wt % of Cu, between 0.6 and 1.8 wt % of Si, between 0.2 and 1.5 wt % of Bi, between 0.02 and 0.5 wt % of Al, less than 1.5 wt % of Ni+Mn+Sn, between 0.01 and 0.5 wt % of La—Ce alloy, between 0.002 and 0.02 wt % of B, with the remainder being Zn and inevitable impurities, wherein the total amount of impurities are no more than 0.5 wt %.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: February 5, 2013
    Assignees: Ningbo Xingaoda Advanced Metallic Materials Co., Ltd, Ningbo Aoda New Metal Materials Co., Ltd
    Inventors: Feng Peng, Baoping Xia, Jianping Liu, Bin Feng, Changshun Zheng, Wenjian Liu
  • Publication number: 20130014861
    Abstract: The distribution of Ni—Si compound grains is controlled to thereby improve the properties of Corson alloys. The copper alloy for electronic materials comprises 0.4 to 6.0% mass of Ni and 0.1 to 1.4% by mass of Si, with the balance being Cu and unavoidable impurities. The copper alloy comprising: small particles of Ni—Si compound having a particle size of equal to or greater than 0.01 ?m and smaller than 0.3 ?m; and large particles of Ni—Si compound having a particle size of equal to of greater than 0.3 ?m and smaller than 1.5 ?m. The number density of the small particles is 1 to 2000 pieces/?m2 and the number density of the large particles is 0.05 to 2 pieces/?m2.
    Type: Application
    Filed: April 2, 2010
    Publication date: January 17, 2013
    Applicant: JX Nippon Mining & Metal Corporation
    Inventor: Mitsuhiro Ookubo
  • Patent number: 8349097
    Abstract: A dezincification-resistant copper alloy and a method for producing a product containing the same are proposed by the present invention. The dezincification-resistant alloy of the present invention contains 59.5 to 64 wt % of copper (Cu); 0.1 to 0.5 wt % of bismuth (Bi); 0.08 to 0.16 wt % of arsenic (As); 5 to 15 ppm of boron (B); 0.3 to 1.5 wt % of tin (Sn); 0.1 to 0.7 wt % of zirconium (Zr); less than 0.05 wt % of lead (Pb); and zinc (Zn) in balance. The dezincification-resistant copper alloy of the present invention has excellent casting properties, good toughness and machinability, and can be corrosion-resistant. Thus, the alloy can reduce dezincification on the surfaces.
    Type: Grant
    Filed: September 17, 2009
    Date of Patent: January 8, 2013
    Assignee: Modern Islands Co., Ltd.
    Inventors: Wen Lin Lo, Xiao Rong Fang
  • Publication number: 20120312430
    Abstract: The present invention relates to a copper alloy having particular benefits for electronic parts and a method for making the same. The alloy having the composition of 0.05 wt % of Fe, 0.025˜0.15 wt % P, 0.01˜0.25 wt % Cr, 0.01˜0.15 wt %, Si 0.01˜0.25 wt % Mg, and the balance of Cu and minor impurities. The method of making the copper alloy includes: forming the molten alloy, casting to obtain an ingot, hot rolling the ingot at 850˜1,000° C., cooling, cold rolling the hot rolled product (after cooling the same), annealing the cold rolled product at 400˜600° C. for 1˜10 hours, intermediate rolling the annealed product with a reduction ratio of 30˜70%, heat treating the intermediate rolled product at 500˜800° C. for 30˜600 seconds, and finishing rolling the heat treated product with a reduction ratio of 20˜40%.
    Type: Application
    Filed: October 28, 2010
    Publication date: December 13, 2012
    Inventors: Dae Hyun Kim, Dong Woo Lee, In Dal Kim, Sang Young Choi, Ji Hoon Lee, Bo Min Jeon
  • Patent number: 8293034
    Abstract: The present invention provides a lead-free brass alloy, including 0.3 to 0.8 wt % of aluminum, 0.01 to 0.4 wt % of bismuth, 0.05 to 1.5 wt % of iron and more than 96 wt % of copper and zinc, wherein the copper is present in an amount ranging from 58 to 75 wt %. The brass alloy of the present invention meets the standard of the environmental regulation, wherein the lead content is less than 0.25 wt % based on the weight of the alloy. Further, the brass alloy of the present invention has 0.05 to 1.5 wt % of iron and less than 0.4% of bismuth, so as to lower production cost, eliminate cracks and increase production yield.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: October 23, 2012
    Assignee: Modern Islands Co., Ltd.
    Inventors: Wei Te Wu, Wen Lin Lo, Keng J. Lin, Hung C. Lu
  • Patent number: 8287669
    Abstract: A copper alloy for electric and electronic equipments, containing from 0.5 to 4.0 mass % of Ni, from 0.5 to 2.0 mass % of Co, and from 0.3 to 1.5 mass % of Si, with the balance of copper and inevitable impurities, wherein R{200} is 0.3 or more, in which the R{200} is a proportion of a diffraction intensity from a {200} plane of the following diffraction intensities and is represented by R{200}=I{200}/(I{111}+I{200}+I{220}+I{311}), I{111} is a diffraction intensity from a {111} plane, I{200} is a diffraction intensity from a {200} plane, I{220} is a diffraction intensity from a {220} plane, and I{311} is a diffraction intensity from a {311} plane, each at the material surface.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: October 16, 2012
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Tatsuhiko Eguchi, Kuniteru Mihara, Kiyoshige Hirose
  • Patent number: 8273192
    Abstract: The present invention relates to a lead-free, bismuth-free free-cutting phosphorous brass alloy and its method of manufacture. The alloy comprises: Cu; Zn; 0.59 to 1.6 wt % P; and other elements in the amount of 0.005 to 0.6 wt %, which comprise at least two elements selected from the group consisting of Al, Si, Sb, Sn, Rare earth element (RE), Ti and B, and the balance being unavoidable impurities. The phosphorous brass alloy contains a combined wt % of Cu and Zn of between 97.0 wt % and 99.5 wt %, within which the content of Zn is above 40 wt %. Considering the solid solubility of P in the matrix of copper will be decreased rapidly with the temperature decrease and form the brittle intermetallic compounds Cu3P with Cu, the present invention relies upon P to ensure excellent cuttability of the invented alloy. The invented alloy is reasonably priced, and has excellent cuttability, castability, hot and cold workability, dezincification corrosion resistance, mechanical properties and weldability.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: September 25, 2012
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chuankai Xu, Zhenqing Hu, Siqi Zhang
  • Patent number: 8273193
    Abstract: The present invention supplies a lead-free, bismuth-free free-cutting silicon brass alloy with high zinc which preferably comprises 35.0 to 42.0 wt % Zn, 0.1 to 1.5 wt % Si, 0.03 to 0.3 wt % Al, 0.01 to 0.36 wt % P, 0.01 to 0.1 wt % Ti, 0.001 to 0.05 wt % rare earth metals selected from the group consisting of La and Ce, 0.05 to 0.5 wt % Sn, and/or 0.05 to 0.2 wt % Ni, and the balance being Cu and unavoidable impurities. In yet another embodiment, the alloy may be boron-free. The invented alloy is excellent in castability, weldability, cuttability, electroplating properties, corrosion resistance, mechanical properties. The alloy is especially applicable in castings which need cutting and welding under low pressure die casting, such as castings for faucet bodies in the water supply system. The alloy is also suitable for use in components which are produced from casting ingots by die forging.
    Type: Grant
    Filed: January 4, 2010
    Date of Patent: September 25, 2012
    Assignee: Xiamen Lota International Co., Ltd.
    Inventors: Chankai Xu, Zhenqing Hu, Siqi Zhang
  • Publication number: 20120175026
    Abstract: The present invention provides a Cu—Fe—P alloy which has a high strength, high conductivity and superior bending workability. The copper alloy comprises 0.01 to 1.0% Fe, 0.01 to 0.4% P, 0.1 to 1.0% Mg, and the remainder Cu and unavoidable impurities. The size of oxides and precipitates including Mg in the copper alloy is controlled so that the ratio of the amount of Mg measured by a specified measurement method in the extracted residue by a specified extracted residue method to the Mg content in said copper alloy is 60% or less, thus endowing the alloy with a high strength and superior bending workability.
    Type: Application
    Filed: March 23, 2012
    Publication date: July 12, 2012
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel, Ltd.)
    Inventors: Yasuhiro AGRUGA, Katsura Kajihara, Takeshi Kudo
  • Patent number: 8137489
    Abstract: A copper alloy material has a rolled surface having a plurality of crystal faces parallel to the rolled surface. The crystal faces includes at least one crystal face selected from a group consisted of {011}, {1nn} (n is an integer, n?1), {11m} (m is an integer, m?1), {023}, {012}, and {135}. Diffraction intensities of the crystal faces in an inverse pole figure obtained by crystal diffraction measurement of the rolled surface as a reference satisfy the relationships of: {011}>{155}>{133}, {011}>{023}>{012}, and {011}>{135}>{112}.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: March 20, 2012
    Assignee: Hitachi Cable, Ltd.
    Inventors: Takemi Muroga, Noboru Hagiwara, Yoshiki Yamamoto
  • Publication number: 20110240182
    Abstract: Disclosed is a Ni—Si—Co copper alloy that is suitable for use for various kinds of electronic parts and has particularly good uniform plating adhesion properties. The copper alloy for electronic materials comprises Ni: 1.0-2.5 mass %, Co: 0.5-2.5 mass % and Si: 0.3-1.2 mass % and the remainder is made of Cu and unavoidable impurities. For the copper alloy for electronic materials, the mean crystal size, at the plate thickness center, is 20 ?m or less, and there are five or fewer crystal particles that contact the surface and have a long axis of 45 ?m or greater per 1 mm rolling direction length. The copper alloy may comprise a maximum of 0.5 mass % Cr and may comprise a maximum in total of 2.0 mass % of one, two or more selected from a group comprising Mg, P, As, Sb, Be, B, Mn, Sn, Ti, Zr, Al, Fe, Zn and Ag.
    Type: Application
    Filed: December 11, 2009
    Publication date: October 6, 2011
    Applicant: JX Nippon Mining & Metals Corporation
    Inventor: Hiroshi Kuwagaki
  • Publication number: 20110240180
    Abstract: There is provided a copper alloy sheet including 1.0 to 3.5 mass % Ni, 0.5 to 2.0 mass % Co, and 0.3 to 1.5 mass % Si, a Co/Ni mass ratio being 0.15 to 1.5, an (Ni+Co)/Si mass ratio being 4 to 7, and a balance being composed of Cu and an unavoidable impurity, wherein in observation results of a crystal grain boundary property and crystal orientation by EBSP measurement, a density of twin boundaries among all crystal grain boundaries is 40% or more and an area ratio of crystal grains with Cube orientation is 20% or more, on a rolled surface.
    Type: Application
    Filed: July 9, 2010
    Publication date: October 6, 2011
    Applicant: DOWA METALTECH CO., LTD.
    Inventors: Weilin Gao, Akira Sugawara, Ryosuke Miyahara, Hisashi Suda
  • Patent number: 7909946
    Abstract: A copper alloy consists essentially of Cu: 69 to 88 mass %, Si: 2 to 5 mass %, Zr: 0.0005 to 0.04 mass %, P: 0.01 to 0.25 mass %, and Zn: balance; has relation of, in terms of content of element a, [a] mass %, f0=[Cu]?3.5[Si]?3[P]=61 to 71, f1=[P]/[Zr]=0.7 to 200, f2=[Si]/[Zr]=75 to 5000, and f3=[Si]/[P]=12 to 240; has a metal structure containing ? phase and, K phase and/or ? phase, and has relation of, in terms of a content of phase b, [b]%, in an area rate, f4=[?]+[?]+[K]?85 and f5=[?]+[K]+0.3[?]?[?]=5 to 95; and has an average grain diameter of 200 ?m or less in a macrostructure when melted and solidified.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: March 22, 2011
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventor: Keiichiro Oishi
  • Publication number: 20110056591
    Abstract: Brass alloy powder has a brass composition formed by a mixed phase of ?-phase and ?-phase, and contains 0.5 to 5.0 mass % of chromium. The chromium includes a component that is solid-solved in a mother phase of brass, and a component that is precipitated at crystal grain boundaries.
    Type: Application
    Filed: April 24, 2009
    Publication date: March 10, 2011
    Applicants: Japan Science and Technology Agency, Osaka University
    Inventors: Katsuyoshi Kondoh, Gen Katano, Hisashi Imai, Yoshiharu Kosaka, Akimichi Kojima
  • Patent number: 7883588
    Abstract: In a Cu—Bi based sintered alloy, to which hard particles, such as Fe3P, are added, the main constituent components of the microstructure are a Cu matrix, Bi phase and the hard particles. In the sintering method of the present invention, the flow of the Bi phase is suppressed to as low level as possible. The novel structure is that the contact between the Bi phase and hard particles is kept to a low ratio. A lead-free bearing used for a fuel injection pump according to the present invention contains from 1 to 30 mass % of Bi and from 0.1 to 10 mass % of hard particles having from 10 to 50 ?m of the average particle diameter, the balance being Cu and unavoidable impurities. The properties of the main component phases are utilized at a high level such that the sliding properties are equivalent to those of a Pb containing Cu-based sintered alloy.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: February 8, 2011
    Assignees: Taiho Kogyo Co., Ltd., Denso Corporation
    Inventors: Hiromi Yokota, Daisuke Yoshitome, Hiroaki Hayakawa, Naruhiko Inayoshi, Youichi Murakami, Masashi Suzuki, Takahiro Nozu
  • Patent number: 7883589
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 71.5 to 78.5 percent, by weight, of copper, 2.0 to 4.5 percent, by weight, of silicon, 0.005 percent up to but less than 0.02, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Grant
    Filed: May 26, 2006
    Date of Patent: February 8, 2011
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventor: Keiichiro Oishi