Zinc(zn), Zinc Base Alloy Or Unspecified Galvanizing Patents (Class 148/533)
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Patent number: 12084734Abstract: Provided are plated steel sheets for hot press forming, hot press formed parts, and manufacturing methods thereof, the plated steel sheets comprising: a base steel sheet comprising, in weight %, C: 0.07 to 0.5%, Si: 0.05 to 1%, Mn: 0.5 to 5%, P: 0.001 to 0.015%, S: 0.0001 to 0.02%, Al: 0.01 to 0.1%, Cr: 0.01 to 1%, N: 0.001 to 0.02%, Ti: 0.1% or less, B: 0.01% or less, Sn: 0.01 to 0.1%, and a balance of Fe and inevitable impurities; an aluminum or aluminum alloy plating layer disposed on at least one surface of the base steel sheet; and an Sn-enriched layer provided between the base steel sheet and the plating layer, wherein the Sn-enriched layer satisfies a specific relationship.Type: GrantFiled: December 3, 2021Date of Patent: September 10, 2024Assignee: POSCO CO., LTDInventors: Jin-Keun Oh, Seong-Woo Kim, Sang-Heon Kim, Hyo-Sik Chun
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Patent number: 12065724Abstract: A tempered and coated steel sheet having a composition containing the following elements, expressed in percentage by weight: 0.17%?carbon?0.25%, 1.8%?manganese?2.3%, 0.5%?silicon?2.0%, 0.03%?aluminum?1.2%, sulphur?0.03%, phosphorus?0.03%, the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet containing in area fraction, 3 to 20% residual austenite, at least 15% of ferrite, 40 to 85% tempered bainite and a minimum of 5% of tempered martensite, wherein cumulated amounts of tempered martensite and residual austenite is between 10 and 30%. The composition may also contain one or more of the following elements chromium?0.4%, molybdenum?0.3%, niobium?0.04%, titanium?0.1%. Methods of manufacturing and use of the tempered and coated steel sheets are also described.Type: GrantFiled: December 19, 2017Date of Patent: August 20, 2024Assignee: ArcelorMittalInventors: Jean-Marc Pipard, Marc Olivier Thenot
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Patent number: 12018181Abstract: An exemplary embodiment of the present invention provides: an adhesive coating composition enabling adherence (coupling) of an electrical steel sheet without using conventional coupling methods such as welding, clamping, and interlocking; an electrical steel sheet laminate to which the same is applied; and a method for manufacturing the same. An adhesive coating composition for an electrical steel sheet, according to an exemplary embodiment of the present invention, includes, on the basis of 100 wt % of total solids: 15 to 70 wt % of a first composition containing an organic resin and an organic/inorganic composite in which inorganic nanoparticles are substituted for an organic resin; 20 to 80 wt % of a second composition containing a metal phosphate and phosphoric acid; and 1 to 10 wt % of a coupling agent. The coupling agent may contain one or more of a silane-based coupling agent, a titanate-based coupling agent, and an aluminate-based coupling agent.Type: GrantFiled: December 17, 2018Date of Patent: June 25, 2024Assignee: POSCO CO., LTDInventors: Jung-Woo Kim, Bongwoo Ha, Taeyoung No
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Patent number: 11905599Abstract: A method and arrangement for manufacturing hot dip galvanized rolled high strength steel product is presented. The method comprises providing a rolled steel product, heating and annealing the rolled steel product for creating a layer of iron oxide on the surface of the rolled steel product, cooling the rolled steel product, having the iron oxide layer, in a first cooling step to a temperature in a temperature range of 560-600° C. and holding for 3-10 seconds, quenching said rolled steel product, covered with the layer of iron oxide, in a second cooling step by immersing it into a zinc bath comprising aluminium and having a temperature between 440-450° C. for 1-5 seconds and cooling the rolled steel product in a third cooling step to room temperature. An arrangement for implementing the method is also presented.Type: GrantFiled: December 10, 2020Date of Patent: February 20, 2024Assignee: Psitec OyInventor: Pertti Sippola
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Patent number: 11866828Abstract: A plated steel sheet for hot stamping including a base metal and a galvanized layer that is formed on a surface of the base metal, wherein the galvanized layer includes a galvannealed layer, a solidified zinc layer, and an oxide layer containing Al, in this order from the base metal, and a proportion of a content of Zn (g/m2) in the solidified zinc layer to a content of Zn (g/m2) in the galvanized layer is 10 to 95%.Type: GrantFiled: March 9, 2021Date of Patent: January 9, 2024Assignee: NIPPON STEEL CORPORATIONInventors: Hiroshi Takebayashi, Kojiro Akiba, Akihiro Sengoku
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Patent number: 11859259Abstract: A zinc-plated steel sheet includes a steel sheet having a predetermined chemical composition and a zinc-plated layer. In the steel sheet, steel microstructures in a range of ? thickness to ? thickness, having the center at ¼ thickness from a steel sheet surface, include, by vol %, ferrite: 0% to 10%, bainite: 0% to 30%, tempered martensite: 50% or more, fresh martensite: 0% to 10%, retained austenite: more than 10% and 30% or less, and pearlite: 0% to 5%. In the zinc-plated steel sheet, the amount of hydrogen emitted when the steel sheet is heated to 200° C. from room temperature after removal of the zinc-plated layer is 0.40 ppm or less per mass of the steel sheet, the tensile strength is 1470 MPa or more, and no cracking occurs in a U-shape bending test where a stress equivalent to 1000 MPa is applied for 24 hours.Type: GrantFiled: April 26, 2019Date of Patent: January 2, 2024Assignee: NIPPON STEEL CORPORATIONInventors: Takafumi Yokoyama, Kunio Hayashi, Masahiro Nakata, Yuji Yamaguchi, Satoshi Uchida
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Patent number: 11801665Abstract: Provided is a hot-dip galvanized steel sheet to be used for home appliances, vehicles, and the like, and having excellent surface appearance and low-temperature bonding brittleness. The hot-dip galvanized steel sheet includes: a base steel sheet; and a hot-dip galvanized layer formed on the base steel sheet. A surface of the base steel sheet has a centerline average roughness (Ra) of 0.3 or more, a roughness skewness (Rsk) of ?1 or less, and a roughness kurtosis (Rku) of 6 or more.Type: GrantFiled: November 28, 2019Date of Patent: October 31, 2023Assignee: POSCO CO., LTDInventor: Hyeon-Seok Hwang
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Method for producing a high strength steel sheet having improved strength, ductility and formability
Patent number: 11618931Abstract: A method for producing a high strength steel sheet having a yield strength YS of at least 850 MPa, a tensile strength TS of at least 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER of at least 30%. The chemical composition of the steel contains: 0.15%?C?0.25%, 1.2%?Si?1.8%, 2%?Mn?2.4%, 0.1%?Cr?0.25%, Nb?0.05%, Ti?0.05%, Al?0.50%, the remainder being Fe and unavoidable impurities. The sheet is annealed at an annealing temperature TA higher than Ac3 but less than 1000° C. for more than 30 s, by cooling it to a quenching temperature QT between 275° C. and 325° C., at a cooling speed sufficient to have, just after quenching, a structure consisting of austenite and at least 50% of martensite, the austenite content en.) being such that the final structure can contain between 3% and 15% of residual austenite and between 85 and 97% of the sum of martensite and bainite, without ferrite, heated to a partitioning temperature PT between 420° C. and 470° C.Type: GrantFiled: July 3, 2015Date of Patent: April 4, 2023Assignee: ARCELORMITTALInventors: Rashmi Ranjan Mohanty, Hyun Jo Jun, Dongwei Fan -
Patent number: 11603574Abstract: A high-ductility, high-strength steel sheet having excellent close-contact bendability and a method for producing the same. The steel sheet has a specified chemical composition and a microstructure comprising, by area percentage, 50% or more of a ferrite phase, 5% to 30% of a pearlite phase, and 15% or less in total of bainite, martensite, and retained austenite, in which the area percentage of ferrite grains each containing three or more cementite grains having an aspect ratio of 1.5 or less is 30% or less, and the number of inclusions having a particle size of 10 ?m or more present in a portion extending from a surface to a ¼ thickness position is 2.0 particles/mm2 or less.Type: GrantFiled: January 24, 2019Date of Patent: March 14, 2023Assignee: JFE STEEL CORPORATIONInventors: Takuya Hirashima, Yoshihiko Ono
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Patent number: 11597983Abstract: A method for producing a high-strength hot-dip galvannealed steel sheet, in which a high-strength steel sheet is used as a base material, includes a rolling step (x) of rolling a hot-dip galvannealed steel sheet with a coating layer having an Fe concentration of 8% to 17% by mass, and a heat treatment step (y) of heating the coated steel sheet which has been subjected to the rolling step (x) under the conditions satisfying the following formulae (1) and (2): (273+T)×(20+2×log10(t))?8000??(1) 40?T?160??(2) where T: heating temperature (° C.) of the coated steel sheet, and t: holding time (hr) at the heating temperature T.Type: GrantFiled: March 26, 2019Date of Patent: March 7, 2023Assignee: JFE Steel CorporationInventors: Satoshi Maeda, Yoshiyasu Kawasaki, Yusuke Fushiwaki, Mai Aoyama
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Patent number: 11591676Abstract: Provided is a steel sheet used as a material for an automotive exterior panel, etc., and a method for manufacturing the same. More particularly, provided is a cold-rolled steel sheet and a hot-dip galvanized steel sheet, which have excellent bake hardening properties, corrosion resistance, and anti-aging properties, and a method for manufacturing the same.Type: GrantFiled: November 30, 2018Date of Patent: February 28, 2023Assignee: POSCO CO., LTDInventors: Sang-Ho Han, Je-Woong Lee
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Patent number: 11584971Abstract: A flat product of steel with yield strength Rp 0.2 of 660 to 820 MPa, BH2 value greater than 30 MPa, a hole expansion ratio greater than 30%, and a microstructure having a first main component at a proportion of at least 50%, including one or more individual components of ferrite, tempered bainite, and tempered martensite, each with less than 5% carbides, and a second main component at a proportion of 5% to 50%, including one or more individual components of martensite, residual austenite, bainite or perlite, with the steel having a following chemical composition (in weight %): C: 0.04 to 0.12; Si: 0.03 to 0.8; Mn: 1 to 2.5: P: max. 0.08; S: max. 0.01; N: max. 0.01; Al: up to 0.1; Ni+Mo; up to 0.5; Nb: up to 0.08; Ti: up to 0.2; Nb+Ti: min, 0.03; Cr: up to 0.6; the remainder being iron including unavoidable steel-associated elements.Type: GrantFiled: December 11, 2018Date of Patent: February 21, 2023Assignee: Salzgitter Flachstahl GmbHInventors: Ingwer Denks, Joachim Schöttler, Christian Pelz, Patrick Witteler
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Patent number: 11535922Abstract: Provided is a method for manufacturing a high-strength galvanized steel sheet. Heating in a first half of oxidizing treatment is performed at a temperature of 400° C. to 750° C. in an atmosphere having a particular O2 concentration and a particular H2O concentration, and heating in a second half of the oxidizing treatment is performed at a temperature of 600° C. to 850° C. in an atmosphere having a particular O2 concentration and a particular H2O concentration. Subsequently, heating in a heating zone for reduction annealing is performed to a temperature of 650° C. to 900° C. at a particular heating rate in an atmosphere having a particular H2 concentration and a particular H2O concentration with the balance being N2 and inevitable impurities, and soaking in a soaking zone for the reduction annealing is performed in an atmosphere having a particular H2 concentration and a particular H2O concentration with the balance being N2 and inevitable impurities.Type: GrantFiled: September 14, 2017Date of Patent: December 27, 2022Assignee: JFE Steel CorporationInventors: Yoichi Makimizu, Gentaro Takeda, Hiroshi Hasegawa, Yoshimasa Himei, Yoshikazu Suzuki
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Patent number: 11530459Abstract: A cold-rolled and heat-treated steel sheet having a microstructure of, in surface fraction: between 10% and 30% of retained austenite, said retained austenite being present as films having an aspect ratio of at least 3 and as Martensite Austenite islands, less than 8% of such Martensite Austenite islands having a size above 0.5 ?m, at most 10% of fresh martensite and recovered martensite containing precipitates of at least one element chosen among niobium, titanium and vanadium. A manufacturing method thereof is also provided.Type: GrantFiled: November 21, 2018Date of Patent: December 20, 2022Assignee: ArcelorMittalInventors: Kangying Zhu, Astrid Perlade, Coralie Jung, Frederic Kegel
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Patent number: 11519061Abstract: A steel sheet includes: a predetermined chemical composition; and a steel structure represented by, in area %, first martensite in which two or more iron carbides each having a circle-equivalent diameter of 2 nm to 500 nm are contained in each lath: 20% to 95%, ferrite: 15% or less, retained austenite: 15% or less, and the balance: bainite, or second martensite in which less than two iron carbides each having a circle-equivalent diameter of 2 nm to 500 nm are contained in each lath, or the both of these, in which the total area fraction of ND//<111> orientation grains and ND//<100> orientation grains is 40% or less, and the content of solid-solution C is 0.44 ppm or more.Type: GrantFiled: August 31, 2015Date of Patent: December 6, 2022Assignee: NIPPON STEEL CORPORATIONInventors: Riki Okamoto, Hiroyuki Kawata, Masafumi Azuma, Akihiro Uenishi, Naoki Maruyama
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Patent number: 11453927Abstract: A cold rolled steel sheet having a high strength, an aging resistance, a high yield ratio and a small anisotropy of tensile strength is obtained by hot rolling and cold rolling a steel material containing in percent by mass C: 0.06-0.14%, Si: less than 0.50%, Mn: 1.6-2.5%, Nb: not more than 0.080% (including 0%), Ti: not more than 0.080% (including 0%), provided that Nb and Ti are contained in an amount of 0.020-0.080% in total, subjecting a cold rolled steel sheet continuous annealing including steps of soaking-annealing at a temperature of 840-940° C. for a holding time of 30-120 seconds, cooling from the soaking temperature to 600° C. at a rate of not less than 5° C./s, retaining in a temperature range of 600-500° C. for 30-300 seconds and then conducting a secondary cooling to apply such a steel structure that martensite is finely dispersed into ferrite base.Type: GrantFiled: February 5, 2018Date of Patent: September 27, 2022Assignee: JFE Steel CorporationInventors: Yuma Honda, Yoshihiko Ono
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Patent number: 11408044Abstract: There is provided a high-strength steel sheet and a method for producing the same. The high-strength steel sheet has a specified chemical composition and a steel microstructure including, by area fraction, 75.0% or more tempered martensite, 1.0% or more and 20.0% or less fresh martensite, and 5.0% or more and 20.0% or less retained austenite. A hardness ratio of the fresh martensite to the tempered martensite is 1.5 or more and 3.0 or less, the ratio of the maximum KAM value in the tempered martensite in the vicinity of the heterophase interface between the tempered martensite and the fresh martensite to the average KAM value in the tempered martensite is 1.5 or more and 30.0 or less, and the average of ratios of grain sizes of prior austenite grains in the rolling direction to those in the thickness direction is 2.0 or less.Type: GrantFiled: February 9, 2018Date of Patent: August 9, 2022Assignee: JFE STEEL CORPORATIONInventors: Hidekazu Minami, Fusae Shiimori, Shinjiro Kaneko, Takashi Kobayashi, Yuji Tanaka
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Patent number: 11401595Abstract: A high-strength steel sheet having a TS of 780 MPa or more, excellent stretch flangeability, and excellent in-plane anisotropy of TS is provided. A high-strength steel sheet comprises: a predetermined chemical composition; a steel microstructure including, in area fraction, ferrite: 20% or more and 50% or less, lower bainite: 5% or more and 40% or less, martensite: 1% or more and 20% or less, and tempered martensite: 20% or less, and including, in volume fraction, retained austenite: 5% or more, the retained austenite having an average grain size of 2 ?m or less; and a texture having an inverse intensity ratio of ?-fiber to ?-fiber of 3.0 or less.Type: GrantFiled: August 29, 2017Date of Patent: August 2, 2022Assignee: JFE STEEL CORPORATIONInventors: Hidekazu Minami, Shinjiro Kaneko, Reiko Sugihara, Kazunori Tahara, Kazuma Mori
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Patent number: 11384415Abstract: The present invention relates to a steel alloy with high energy absorption capacity and good formability, comprising beside inevitable impurities due to smelting and iron the following components in weight percent: C 0.05-0.6% Sum of Cr+2*Ti+3*(Mo+V+Nb)+4*W=2-7%, wherein the structure of the steel alloy comprises beside martensite portions of 10-40 Vol.-% retained austenite, wherein the energy absorption capacity expressed by the product of tensile strength (Rm) and uniform strain (Ag) is higher than 12,000 MPa % and the steel alloy has a minimal tensile strength of 1000 MPa. In addition, the invention relates to a steel tube product with high energy absorption capacity and good formability, which is characterized in that it at least partially consists of such a steel alloy.Type: GrantFiled: November 16, 2016Date of Patent: July 12, 2022Assignee: Benteler Steel/Tube GmbHInventors: Niko Grosse-Heilmann, Andreas Peters, Isabella-Maria Zylla, Ernst Kozeschnik, Michael Kaufmann, Jozef Balun
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Patent number: 11377712Abstract: A hot dipped high manganese steel and a manufacturing method therefor. The high manganese steel comprises a steel base plate and a coating on the surface of the steel base plate. The core of the steel base plate is austenite. The surface layer of the steel base plate is a ferrite fine grain layer. The ferrite fine grain layer comprises an oxide of Al. Furthermore, the steel base plate of the hot dipped high manganese steel comprises, in mass percentages, 10 to 30% of Mn element, 1 to 2% of Al element, and 0.4 to 0.8% of C element. The manufacturing method comprises: 1) manufacturing strip steel; 2) primary annealing and acid washing; 3) secondary annealing and hot dipping.Type: GrantFiled: April 20, 2018Date of Patent: July 5, 2022Assignee: BAOSHAN IRON & STEEL CO., LTD.Inventors: Xinyan Jin, Yong Zhong, Guangkui Hu
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Patent number: 11352679Abstract: A steel product includes the following chemical composition in wt. %: C: 0.01 to <0.3, Mn: 4 to <10, Al: 0.003 to 2.9, Mo: 0.01 to 0.8, Si: 0.02 to 0.8, Ni: 0.005 to 3, P: <0.04, S: <0.02, N: <0.02, with the remainder being iron including unavoidable steel-associated elements, wherein an alloy composition satisfies the equation 6<1.5 Mn+Ni<8; or the equation 0.11<C+Al<3, or an alloy composition contains, in addition to Ni, at least one or more of the elements, in wt. %, B: 0.0005 to 0.014; V: 0.006 to 0.1; Nb: 0.003 to 0.1; Co: 0.003 to 3; W: 0.03 to 2 or Zr: 0.03 to 1. The steel product has a microstructure of 2 to 90 vol. % austenite, less than 40 vol. % ferrite and/or bainite, with the remainder being martensite.Type: GrantFiled: October 27, 2017Date of Patent: June 7, 2022Assignee: Salzgitter Flachstahl GmbHInventors: Peter Palzer, Manuel Otto, Kai Köhler, Thomas Evertz
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Patent number: 11345973Abstract: Provided are a high-strength steel sheet having a yield strength of 550 MPa or more and excellent fatigue-strength of a weld and a method for manufacturing the steel sheet. A high-strength steel sheet has a specified chemical composition, a steel microstructure observed in a cross section in a thickness direction parallel to a rolling direction including 40% to 75% of a martensite phase in terms of volume fraction, in which a total volume fraction of martensite grains whose average grain diameter ratios with respect to adjacent ferrite grains are ¼ or more and 1 or less is 60% or more with respect to an entire martensite phase, and a yield strength (YP) of 550 MPa or more.Type: GrantFiled: March 29, 2018Date of Patent: May 31, 2022Assignee: JFE STEEL CORPORATIONInventors: Lingling Yang, Tatsuya Nakagaito, Gosuke Ikeda
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Patent number: 11339453Abstract: An apparatus can be used for heating a steel sheet. A positive electrode is configured to make contact with a first electrode area of the steel sheet and a negative electrode is configured to make contact with a second electrode area of the steel sheet. A cooling member includes a cooling block configured to make contact with a cooling area adjacent to a third edge parallel to a second direction. The cooling member is configured to radiate heat generated from the steel sheet. The positive electrode, the negative electrode, and the cooling member are arranged on the steel sheet such that the resistance of a path from the positive electrode to the negative electrode through an area with which the cooling member makes contact is higher than the resistance of a path from the positive electrode to the negative electrode through the cooling member.Type: GrantFiled: March 6, 2020Date of Patent: May 24, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventor: Young Tae Kim
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Patent number: 11306381Abstract: Provided are a hot-dip zinc plated steel material and a method for preparing same, the hot-dip zinc plated steel material comprising: base iron comprising 0.01-1.6 wt % of Si and 1.2-3.1 wt % of Mn; a Zn—Al—Mg alloy plating layer; and an Al-rich layer formed on the interface of the base iron and Zn—Al—Mg alloy plating layer, wherein the rate of occupied surface area of the Al-rich layer is 70% or higher (including 100%).Type: GrantFiled: December 21, 2016Date of Patent: April 19, 2022Assignee: POSCOInventors: Il-Ryoung Sohn, Dae-Young Kang, Jong-Sang Kim, Tae-Chul Kim, Min-Suk Oh
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Patent number: 11293075Abstract: A steel sheet for hot press comprises: a predetermined chemical composition; and a steel microstructure that includes ferrite and cementite and in which Mn?/Mn? is 1.4 or more, where Mn? is a Mn concentration of the ferrite and Mn? is a Mn concentration of the cementite.Type: GrantFiled: June 8, 2020Date of Patent: April 5, 2022Assignee: JFE STEEL CORPORATIONInventors: Koichi Nakagawa, Yoshikiyo Tamai
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Patent number: 11279986Abstract: Provided is a cold-rolled high-strength steel having a tensile strength of not less than 1500 MPa and an excellent formability, the chemical elements thereof having the following mass percent ratios: 0.25%-0.40% of C, 1.50%-2.50% of Si, 2.0%-3.0% of Mn, 0.03%-0.06% of Al, P?0.02%, S?0.01%, N?0.01% and at least one of 0.1%-1.0% of Cr and 0.1%-0.5% of Mo, with the balance being Fe and other unavoidable impurities. The microstructure of the cold-rolled high-strength steel has 5%-20% of residual austenite and 70%-90% of martensite, and the carbon concentration ratio of the residual austenite to the martensite is greater than 3.5 and less than 15. The cold-rolled high-strength steel sheet has a high strength and an excellent formability through a rational ingredient design and microstructure control.Type: GrantFiled: September 20, 2017Date of Patent: March 22, 2022Assignee: BAOSHAN IRON & STEEL CO., LTD.Inventors: Shu Zhou, Yong Zhong, Li Wang
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Patent number: 11220722Abstract: Provided are a steel sheet having a tensile strength of 950 MPa or more and good toughness and a method for manufacturing the same. The steel sheet has a specific composition and a metallographic structure containing: a ferrite area fraction of 30% or less (including 0%), a tempered martensite area fraction of 70% or more (including 100%), and a retained austenite area fraction of 4.5% or less (including 0%), wherein the average aspect ratio of an iron based carbide, precipitated in tempered martensite grains, having a grain size in the largest 10% is 3.5 or more.Type: GrantFiled: August 29, 2017Date of Patent: January 11, 2022Assignee: JFE Steel CorporationInventors: Noriaki Kohsaka, Yoshikazu Suzuki, Takeo Kikuchi, Yoshimasa Himei
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Patent number: 11208704Abstract: A high-strength cold-rolled steel sheet has a component composition containing, on a percent by mass basis, C: 0.12% or more and 0.25% or less, Si: less than 0.5%, Mn: 2.0% or more and 3.0% or less, P: 0.05% or less, S: 0.005% or less, Al: 0.01% or more and 0.10% or less, and N: 0.010% or less, the balance being Fe and incidental impurities, the total area percentage of martensite and tempered martensite satisfying 20% or more and 90% or less, the area percentage of ferrite satisfying 10% or less, the area percentage of bainite satisfying 10% or more and 80% or less, the area percentage of a martensite-austenite constituent in the bainite being 1% or more and 10% or less, the area percentage of cementite having an average grain size of 1 ?m or less in the bainite being 0.1% or more and 5.0% or less.Type: GrantFiled: April 19, 2017Date of Patent: December 28, 2021Assignee: JFE Steel CorporationInventors: Takuya Hirashima, Hiromi Yoshitomi
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Patent number: 11208709Abstract: Provided are a high-strength steel sheet having a yield strength of 550 MPa or higher and having a small amount of springback and width-direction uniformity in material properties as well as a manufacturing method therefor. The high-strength steel sheet has a yield strength (YP) of 550 MPa or higher and has a specific component composition and a microstructure containing a ferrite phase, 40 to 70% of a martensite phase in area ratio, and 5 to 30% of a bainite phase in area ratio, where: an average grain size of the martensite phase is 2 to 8 ?m and an average grain size of the ferrite phase is 11 ?m or less on a cross-section in the thickness direction and in a direction orthogonal to a rolling direction; and the average grain size of the ferrite phase is 3.0 times or less the average grain size of martensite.Type: GrantFiled: February 21, 2018Date of Patent: December 28, 2021Assignee: JFE STEEL CORPORATIONInventors: Lingling Yang, Noriaki Kohsaka, Tatsuya Nakagaito
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Patent number: 11174529Abstract: A high-strength steel sheet having a microstructure represented by, in area %, martensite: 5% or more; ferrite: 20% or more; and pearlite: 5% or less. A ratio of the number of bulging type martensite grains to the number of martensite grains on grain boundary triple points of a matrix is 70% or more, wherein: the bulging type martensite grain is on one of the grain boundary triple points of the matrix; and at least one of grain boundaries of the bulging type martensite grain, the grain boundaries connecting two adjacent grain boundary triple points of the bulging type martensite grain and grains of the matrix, has a convex curvature to an outer side with respect to line segments connecting the two adjacent grain boundary triple points. An area ratio VM/A0 is 1.0 or more.Type: GrantFiled: May 6, 2016Date of Patent: November 16, 2021Assignee: NIPPON STEEL CORPORATIONInventors: Riki Okamoto, Yoshinari Ishida, Yoshihiro Suwa, Takafumi Yokoyama
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Patent number: 11131003Abstract: A method for producing a cold rolled steel sheet having a tensile strength?1470 MPa and a total elongation TE?19%, the method comprising the steps of annealing at an annealing temperature AT?Ac3 a non-treated steel sheet whose chemical composition contains in weight %: 0.34%?C?0.40%, 1.50%?Mn?2.30%, 1.50?Si?2.40%, 0%<Cr?0.5%, 0%<Mo?0.3%, 0.01%?Al?0.07%, the remainder being Fe and unavoidable impurities, quenching the annealed steel sheet by cooling it to a quenching temperature QT<Ms transformation point and between 150° C. and 250° C., and making a partitioning treatment by reheating the quenched steel sheet to a partitioning temperature PT between 350° C. and 420° C. and maintaining the steel sheet at this temperature during a partitioning time Pt between 15 seconds and 120 seconds.Type: GrantFiled: May 15, 2019Date of Patent: September 28, 2021Assignee: ARCELORMITTALInventors: Olga A. Girina, Damon Panahi
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Patent number: 11111553Abstract: A high-strength steel sheet having a tensile strength (TS) of 1,320 MPa or more and good workability. The high-strength steel sheet has a specific component composition and a steel microstructure containing, on an area-percentage basis with respect to the entire steel microstructure, 40% or more and less than 85% of a lower bainite, 5% or more and less than 40% martensite including tempered martensite, 10% or more and 30% or less retained austenite, and 10% or less (including 0%) polygonal ferrite, the retained austenite having an average C content of 0.60% by mass or more. Additionally, a Mn segregation value at a surface of the steel sheet is 0.8% or less, the ratio R/t of a limit bending radius (R) to a thickness (t) of the steel sheet is 2.0 or less, and tensile strength×total elongation of the steel sheet is 15,000 MPa % or more.Type: GrantFiled: February 7, 2017Date of Patent: September 7, 2021Assignee: JFE STEEL CORPORATIONInventors: Yusuke Kimata, Yoshihiko Ono, Kenji Kawamura
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Patent number: 11060158Abstract: The present invention relates to a method of manufacturing a directional electric steel plate having excellent surface wettability and magnetic properties. More particularly, the present invention relates to a directional electric steel plate in which a surface of a steel plate consisting of Si: 2.0 to 6.5%, acid soluble Al: 0.4 to 5%, Mn: 0.20% or less (0% exclusive), N: 0.010% or less (0% exclusive), S: 0.010% or less (0% exclusive), P: 0.005 to 0.05%, C: 0.04 to 0.12% and a balance of Fe and other unavoidable impurities is hot-dip plated with aluminum or an aluminum-silicon alloy, and heat-treated, so that aluminum on the hot-dip plated layer is diffused or infiltrated into the steel plate, and a method of manufacturing the same.Type: GrantFiled: December 21, 2015Date of Patent: July 13, 2021Assignee: POSCOInventor: Dae Hyun Song
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Patent number: 11021776Abstract: A hot rolled, ultra-high strength, complex metallographic structured or multi-phase structured steel that improves formability during stamping or forming process, while possessing one or more of the following properties: excellent castability, rollability and coatability, excellent structural performance, excellent stretch formability, excellent stretch flangeability, excellent dent resistance, excellent durability, excellent impact performance, excellent intrusion and crash resistance without the purposeful addition of boron.Type: GrantFiled: November 3, 2017Date of Patent: June 1, 2021Assignee: NUCOR CORPORATIONInventor: Weiping Sun
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Patent number: 11008632Abstract: A steel sheet is provided that has a tensile strength of 540 MPa or more, includes a particular composition; and has a steel structure containing ferrite and a secondary phase, in which an area fraction of the ferrite is 50% or more, the secondary phase contains 1.0% or more and 25.0% or less of martensite in terms of area fraction with respect to the entirety, the ferrite has an average crystal grain size of 3 ?m or more, a difference in hardness between the ferrite and the martensite is 1.0 GPa or more and 8.0 GPa or less, and, in a texture of the ferrite, an inverse intensity ratio of ?-fiber to ?-fiber is 0.8 or more and 7.0 or less.Type: GrantFiled: March 7, 2017Date of Patent: May 18, 2021Assignee: JFE Steel CorporationInventors: Hidekazu Minami, Yoshimasa Funakawa, Shinjiro Kaneko
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Patent number: 10982309Abstract: Disclosed are a hot-rolled galvanized steel sheet having excellent galling resistance and formability, and a method for manufacturing the same. The hot-rolled galvanized steel sheet, includes: a base steel; and a hot-rolled galvanizing layer formed on the surface of the base steel, wherein the hot-rolled galvanizing layer provides a hot-rolled galvanized steel sheet having a Mn crystallite having a size of 10 ?m or less between the resin dendrites of zinc that form sequins.Type: GrantFiled: August 22, 2017Date of Patent: April 20, 2021Assignee: POSCOInventors: Sang-Heon Kim, Hyeon-Seok Hwang, Suk-Kyu Lee, Sun-Ho Jeon, Yon-Kyun Song, Bong-Hwan Yoo
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Patent number: 10954580Abstract: A method for producing a steel sheet having a microstructure including 71% to 91% martensite and bainite, 9% to 13% retained austenite, and at most 20% ferrite is provided. The method includes providing a cold-rolled steel sheet including, in weight percent: 0.13%?C?0.22%, 1.2%?Si?2.3%, 0.02%?Al?1.0%, with 1.25%?Si+Al?2.35%, 2.4%?Mn?3%, Ti?0.05%, Nb?0.05% and a remainder of Fe and unavoidable impurities, annealing the steel sheet to obtain 80% to 100% austenite and 0% to 20% ferrite, quenching the steel sheet at a cooling rate between 20° C./s and 50° C./s to a quenching temperature between 240° C. and 310° C., heating the steel sheet to a partitioning temperature between 400° C. and 465° C. and maintaining the steel sheet at the partitioning temperature for 50 to 250 seconds, then immediately cooling the sheet to room temperature. Steel sheets are also provided.Type: GrantFiled: December 21, 2016Date of Patent: March 23, 2021Assignee: ARCELORMITTALInventors: Pavan Venkatasurya, Hyun Jo Jun
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Patent number: 10774405Abstract: Steel has a chemical composition that contains 0.050% to 0.40% of C, 0.50% to 3.0% of Si, 3.0% to 8.0% of Mn, and 0.001% to 3.0% of sol. Al, by mass %, and has a metallographic structure that contains 10% to 40% of austenite in terms of % by volume. The average concentration of C in austenite is 0.30% by 0.60%, by mass %, structure uniformity, which is represented by a value obtained by subtracting the minimum value from the maximum value of Vickers hardness that is measured, in the metallographic structure is 30 Hv or less, and the tensile strength is 900 MPa to 1800 MPa.Type: GrantFiled: January 6, 2014Date of Patent: September 15, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Koutarou Hayashi, Akira Seki, Kazuya Mishio, Shuhei Shimokawa
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Patent number: 10731241Abstract: An Al—Zn—Si—Mg alloy coated strip that has Mg2Si phase particles that are ?2 ?m and have a globular shape. A method of forming an Al—Zn—Si—Mg alloy coated strip comprises (a) heat treating a solidified coating to facilitate globularisation of Mg2Si phase particles in the coating and/or (b) changing the coating bath chemistry to form intermetallic compound phases that act as nucleation sites for Mg2Si phase particles with the result that small Mg2Si particles form on solidification of the coating.Type: GrantFiled: May 27, 2010Date of Patent: August 4, 2020Assignee: Bluescope Steel LimitedInventors: Ross McDowall Smith, Qiyang Liu, Joe Williams
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Patent number: 10718044Abstract: A hot-dip galvanized steel sheet includes: a predetermined chemical composition; and a steel structure represented by: in terms of area ratio, polygonal ferrite: 10% or less; upper bainite: 20% or less; retained austenite: 5% or less; and martensite: 70% or more, in which: martensite having Fe carbides at a number density of 1×106/mm2 or more is contained by 50% or more, in terms of area ratio, with respect to the entire amount of martensite; and the steel structure has an average effective crystal grain diameter of 5.0 ?m or less.Type: GrantFiled: July 15, 2016Date of Patent: July 21, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Takafumi Yokoyama, Kunio Hayashi, Masafumi Azuma, Eisaku Sakurada, Hiroyuki Kawata, Genki Abukawa
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Patent number: 10711336Abstract: Provided is an alloyed hot-dip galvanized steel sheet including a base steel sheet, the base steel sheet containing a given amount of C, Si, Mn, and other elements. The alloyed hot-dip galvanized steel sheet is provided with an alloyed hot-dip galvanized layer on a surface of the base steel sheet, the alloyed hot-dip galvanized layer containing, in mass %, Fe: more than or equal to 5% and less than or equal to 15%, and having a thickness of more than or equal to 3 ?m and less than or equal to 30 ?m.Type: GrantFiled: November 8, 2018Date of Patent: July 14, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Soshi Fujita, Shintaro Yamanaka
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Patent number: 10604829Abstract: Disclosed herein is a high-strength plated steel sheet having a plated layer on the surface of a base steel sheet and containing predetermined steel components. The steel sheet includes, in the order from the interface of the base steel sheet and the plated layer towards the base steel sheet: a soft layer having a Vickers hardness that is 90% or less of the Vickers hardness at a portion t/4 of the base steel sheet, where t is a sheet thickness of the base steel sheet; and a hard layer consisting of a structure which is mainly composed of martensite and bainite and in which the average grain size of prior austenite is 20 ?m or less. The average depth D of the soft layer is 20 ?m or greater, and the average depth d of an internal oxide layer is 4 ?m or greater and smaller than D.Type: GrantFiled: January 5, 2016Date of Patent: March 31, 2020Assignee: Kobe Steel, Ltd.Inventors: Muneaki Ikeda, Michiharu Nakaya
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Patent number: 10590521Abstract: Steel strip provided with a hot dip galvanized zinc alloy coating layer, in which the coating of the steel strip is carried out in a bath of molten zinc alloy, the zinc alloy in the coating of: 0.3-2.3 weight % magnesium; 0.6-2.3 weight % aluminium; optional <0.2 weight % of one or more additional elements; unavoidable impurities; the remainder being zinc in which the zinc alloy coating layer has a thickness of 3-12 ?m.Type: GrantFiled: May 3, 2017Date of Patent: March 17, 2020Assignee: TATA STEEL IJMUIDEN B.V.Inventors: Theodorus Franciscus Jozef Maalman, Robert Bleeker, Margot Julia Vlot
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Patent number: 10584407Abstract: Zn alloy plated steel material having excellent weldability and processed-part corrosion resistance and a method for production of Zn alloy plated steel material are provided. In the Zn alloy plated steel material comprising base steel material and a Zn alloy plating layer, the Zn alloy plating layer includes, by wt %, Al: 0.1-5.0%, Mg: 0.1-5.0%, as well as a remainder of Zn and inevitable impurities. The Zn alloy plated steel material includes a lower interface layer and an upper interface layer between the base steel material and the Zn alloy plating layer, wherein the lower interface layer is formed on the base steel material and has a dense structure, and the upper interface layer is formed on the lower interface layer and has a network-type or island-type structure.Type: GrantFiled: December 24, 2015Date of Patent: March 10, 2020Assignee: POSCOInventors: Min-Suk Oh, Sang-Heon Kim, Tae-Chul Kim, Jong-Sang Kim, Hyun-Chu Yun, Bong-Hwan Yoo, Il-Ryoung Sohn
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Patent number: 10570473Abstract: Provided is a high-strength cold-rolled steel sheet having excellent ductility and stretch-flangeability as well as weldability in a range in which a tensile strength is 980 MPa or higher and a 0.2% yield strength is less than 700 MPa (preferably 500 MPa or higher). In the high-strength cold-rolled steel sheet of the present invention, the chemical composition is adjusted as appropriate, and the area ratio of below-mentioned metal structures at a position of ¼ sheet thickness in the steel sheet satisfies following requirements: tempered martensite: 10 area % to less than 30 area %, bainite: more than 70 area %, total of tempered martensite and bainite: 90 area % or more, ferrite: 0 area % to 5 area %, and retained austenite: 0 area % to 4 area %. The high-strength cold-rolled steel sheet has excellent ductility, stretch-flangeability, and weldability, and has a tensile strength of 980 MPa or higher and a 0.2% yield strength of less than 700 MPa.Type: GrantFiled: March 19, 2015Date of Patent: February 25, 2020Assignee: Kobe Steel, Ltd.Inventors: Michitaka Tsunezawa, Michiharu Nakaya
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Patent number: 10563280Abstract: The present invention relates to a high-strength and high-manganese steel sheet suitable for an outer panel or a vehicle body of a transport vehicle and, more specifically, to a high-strength and high-manganese steel sheet having excellent vibration-proof properties and a method for producing the same.Type: GrantFiled: December 24, 2013Date of Patent: February 18, 2020Assignee: POSCOInventors: Sung-Kyu Kim, Kwang-Geun Chin, Tae-Jin Song, Tai-Ho Kim, Won-Tae Cho, Sun-Ho Jeon
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Patent number: 10550457Abstract: Zn alloy plated steel material having excellent weldability and processed-part corrosion resistance and a method for production of Zn alloy plated steel material are provided. In the Zn alloy plated steel material comprising base steel material and a Zn alloy plating layer, the Zn alloy plating layer includes, by wt %, Al: 0.1-5.0%, Mg: 0.1-5.0%, as well as a remainder of Zn and inevitable impurities. The Zn alloy plated steel material includes a lower interface layer and an upper interface layer between the base steel material and the Zn alloy plating layer, wherein the lower interface layer is formed on the base steel material and has a dense structure, and the upper interface layer is formed on the lower interface layer and has a network-type or island-type structure.Type: GrantFiled: December 24, 2015Date of Patent: February 4, 2020Assignee: POSCOInventors: Min-Suk Oh, Sang-Heon Kim, Tae-Chul Kim, Jong-Sang Kim, Hyun-Chu Yun, Bong-Hwan Yoo, Il-Ryoung Sohn
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Patent number: 10544477Abstract: A method for manufacturing a high-strength galvanized steel sheet includes performing hot rolling, cold rolling, first annealing, pickling, and second annealing. The first annealing is performed to obtain a steel sheet having a steel microstructure including ferrite in an amount of 10% or more and 60% or less in terms of area ratio, and martensite, bainite, and retained austenite in a total amount of 40% or more and 90% or less in terms of area ratio. The second annealing includes heating to an annealing temperature of 750° C. or higher and 850° C. or lower, holding at the annealing temperature for 10 seconds or more and 500 seconds or less, cooling at an average cooling rate of 1° C./s or more and 15° C./s or less, performing a galvanizing treatment, and cooling to a temperature of 150° C. or lower at an average cooling rate of 5° C./s or more and 100° C./s or less.Type: GrantFiled: June 9, 2015Date of Patent: January 28, 2020Assignee: JFE Steel CorporationInventors: Hideyuki Kimura, Koichiro Fujita, Hiroshi Hasegawa, Mai Aoyama
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Patent number: 10538830Abstract: A steel sheet of the present invention has a steel structure obtained by performing a soaking at a dual phase region temperature of Ac1 temperature or higher and lower than Ac3 temperature for a soaking time of 15 seconds or longer and 35 seconds or shorter, next, performing a primary cooling to a temperature range of 250° C. or higher and 380° C. or lower within 3 seconds at a cooling rate of 0.5° C./s or more and 30° C./s or less, and performing a retention in a temperature range of 260° C. or higher and 370° C. or lower for 180 seconds or longer and 540 seconds or shorter, in which a yield ratio is 65% or less and tensile strength is 590 MPa or more after the primary cooling.Type: GrantFiled: October 5, 2012Date of Patent: January 21, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Yuji Fukumoto, Takashi Aramaki, Junichi Yasui, Norimitsu Harada
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Patent number: 10526671Abstract: A high-strength cold-rolled steel sheet having excellent ductility and stretch flangeability includes: a chemical composition consisting, in mass %, C: 0.06 to 0.3, Si: 0.6 to 2.5%, Mn: 0.6 to 3.5%, P: at most 0.1%, S: at most 0.05%, Ti: 0 to 0.08%, Nb: 0 to 0.04%, total of Ti and Nb: 0 to 0.10%, sol.Al: 0 to 2.0%, Cr: 0 to 1%, Mo: 0 to 0.3%, V: 0 to 0.3%, B: 0 to 0.005%, Ca: 0 to 0.003%, REM: 0 to 0.003% and the remainder of Fe and impurities; a microstructure having a main phase including at least 40 area % in total of martensite and/or bainite; and a texture in which proportion of an average X-ray intensity in an {100}<011> to {211}<011> orientations relative to an average X-ray intensity of a random structure not having a texture is less than 6.Type: GrantFiled: February 13, 2013Date of Patent: January 7, 2020Assignee: NIPPON STEEL CORPORATIONInventors: Kengo Hata, Toshiro Tomida, Norio Imai, Jun Haga, Takuya Nishio