With Working Patents (Class 148/554)
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Patent number: 11913105Abstract: A high-efficiency and short-process method for preparing a high-strength and high-conductivity copper alloy is disclosed, comprising the following steps: performing horizontal continuous casting to obtain an as-cast primary billet of copper alloy, wherein the alloying elements in the obtained as-cast primary billet being in a supersaturated solid solution state; after peeling the obtained as-cast primary billet, directly performing continuous extrusion, cold working and aging annealing treatment to obtain a copper alloy, and keeping the alloying elements of the billet in a supersaturated solid solution state during the process of continuous extrusion. The method shortens the flow, reduces energy consumption and improves the product forming rate.Type: GrantFiled: April 26, 2021Date of Patent: February 27, 2024Assignee: Zhejiang UniversityInventors: Jiabin Liu, Hongtao Wang, Youtong Fang, Xiaoyang Fang, Jindong Zhang, Litian Wang, Liang Meng
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Patent number: 11697864Abstract: Disclosed are a copper alloy strip having high heat resistance and thermal dissipation properties which is suitable for a material for shield cans to solve heating of mobile devices, a material for vehicles and semiconductor lead frames, and a material for electrical and electronic parts, such as connectors, relays, switches, etc., widely used in industries including vehicles, and a method of preparing the same.Type: GrantFiled: August 24, 2018Date of Patent: July 11, 2023Assignee: Poongsan CorporationInventors: Won Shin Kwak, Min Jae Jeong, Hye Min Hong
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Patent number: 11643713Abstract: A spinodal copper-nickel-tin alloy with a combination of improved impact strength, yield strength, and ductility is disclosed. The alloy is formed by process treatment steps including solution annealing, cold working and spinodal hardening. These include such processes as a first heat treatment/homogenization step followed by hot working, solution annealing, cold working, and a second heat treatment/spinodally hardening step. The spinodal alloys so produced are useful for applications demanding enhanced strength and ductility such as for pipes and tubes used in the oil and gas industry.Type: GrantFiled: October 20, 2020Date of Patent: May 9, 2023Assignee: Materion CorporationInventors: W. Raymond Cribb, Chad A. Finkbeiner, Fritz C. Grensing
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Patent number: 11519062Abstract: A gradient control method for a microstructure ultrafine crystallization of a deep cone copper shaped charge liner includes the steps of an extrusion forming, a recrystallization heat treatment, and a high-frequency percussion. A multi-pass extrusion is used in the extrusion forming, and in the high-frequency percussion step, a percussion speed is 30,000 to 40,000 times/min, a percussion force is 1600 N to 2000 N, and a number of percussion times is 1 to 3. The forming and surface quality control of the deep cone shaped charge liner are realized by the control technology of the present invention; the plasticity of the material is improved, and fine crystal structures are obtained; and an ultrafine grain gradient structure distributed along the thickness direction is formed in the inner surface of the shaped charge liner.Type: GrantFiled: March 5, 2019Date of Patent: December 6, 2022Assignee: No.59 Research Institute of China Ordnance IndustryInventors: Qiang Chen, Dayu Shu, Qiang Zhao, Zude Zhao, Luchang Che, Yang Wu, Chuankai Hu, Hui Li
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Patent number: 11353305Abstract: Disclosed is a cartridge case for various caliber ammunition that can consist essentially of a powdered metal and/or powdered metal alloy(s) that is formed into the cartridge case through an injection mold processing. Also disclosed is a method for forming a cartridge case, which may include use of Metal Injection Molding (“MIM”) processes to produce the cartridge case which retains a primer, propellant, and/or a bullet. Also disclosed are embodiments related to a case telescoped cartridge that may include a cap and a body. The body can consist essentially of or consists entirely of a powdered metal and/or powdered metal alloy(s) that has been formed through MIM. The cap can comprise plastic that has been formed through plastic molding or comprise powdered metal and/or powdered metal alloy(s) that has been formed through MIM.Type: GrantFiled: April 8, 2020Date of Patent: June 7, 2022Assignee: Concurrent Technologies CorporationInventors: Todd Skowron, Juan Valencia, Shawn Rhodes
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Patent number: 11332815Abstract: A copper alloy sheet material has a composition containing from 0.20 to 6.00% in total of Ni and Co, from 0 to 3.00% of Ni, from 0.20 to 4.00% of Co, and from 0.10 to 1.50% of Si, all in mass %, one or more of Fe, Mg, Zn, Mn, B, P, Cr, Al, Zr, Ti, Sn contained appropriately depending on necessity, the balance of Cu and unavoidable impurities, and has on a polished sheet surface thereof, a ratio SB/SC of 2.0 or more and an area ratio of SB occupied on the surface of 5.0% or more, wherein SB represents an area of a region having a crystal orientation difference from a Brass orientation {011} <211> measured by EBSD (electron backscattered diffraction) of 100 or less, and SC represents an area of a region having a crystal orientation difference from a Cube orientation {001} <100> of 10° or less.Type: GrantFiled: March 27, 2018Date of Patent: May 17, 2022Assignee: DOWA METALTECH CO., LTD.Inventors: Hiroshi Hyodo, Hisashi Suda
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Patent number: 11162164Abstract: The present invention relates a method of producing a copper-titanium (Cu—Ti)-based copper alloy, and provides a method of producing a copper alloy material for automobile and electrical/electronic components requiring high performance by satisfying high strength and bendability together.Type: GrantFiled: September 21, 2018Date of Patent: November 2, 2021Assignee: Poongsan CorporationInventors: Cheol Min Park, Jun Hyung Kim, Hyo Moon Nam, Sun Young Mun
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Patent number: 11162163Abstract: The present invention relates to a production method of a copper-titanium (Cu—Ti)-based copper alloy material and a copper alloy material produced therefrom. Thus, the copper alloy material has target yield strength, electrical conductivity, and bending workability and thus is applied to automobiles and electric/electronic parts requiring high performance.Type: GrantFiled: September 21, 2018Date of Patent: November 2, 2021Assignee: Poongsan CorporationInventors: Cheol Min Park, Jun Hyung Kim, Hyo Moon Nam, Tae Yang Kwon
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Patent number: 11021774Abstract: There are provided a copper alloy plate having high strength, high electrical conductivity, a high bending deflection coefficient, and excellent stress relaxation characteristics, and an electronic component preferred for high current applications or heat dissipation applications. A copper alloy plate comprising 0.8 to 5.0% by mass of one or more of Ni and Co and 0.2 to 1.5% by mass of Si, with the balance being copper and an unavoidable impurity, having a tensile strength of 500 MPa or more, and having an A value of 0.5 or more, the A value being given by the following formula: A=2X(111)+X(220)?X(200) X(hkl)=I(hkl)/I0(hkl) wherein I(hkl) and I0(hkl) are diffraction integrated intensities of a (hkl) face obtained for a rolled face and a copper powder, respectively, using an X-ray diffraction method.Type: GrantFiled: April 9, 2014Date of Patent: June 1, 2021Assignee: JX Nippon Mining & Metals CorporationInventor: Takaaki Hatano
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Patent number: 10858723Abstract: A spinodal copper-nickel-tin alloy with a combination of improved impact strength, yield strength, and ductility is disclosed. The alloy is formed by process treatment steps including solution annealing, cold working and spinodal hardening. These include such processes as a first heat treatment/homogenization step followed by hot working, solution annealing, cold working, and a second heat treatment/spinodally hardening step. The spinodal alloys so produced are useful for applications demanding enhanced strength and ductility such as for pipes and tubes used in the oil and gas industry.Type: GrantFiled: January 25, 2019Date of Patent: December 8, 2020Assignee: Materion CorporationInventors: W. Raymond Cribb, Chad A. Finkbeiner, Fritz C. Grensing
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Patent number: 10815557Abstract: A copper alloy sheet material which contains 0.5 to 2.5% by mass of Ni, 0.5 to 2.5% by mass of Co, 0.30 to 1.2% by mass of Si and 0.0 to 0.5% by mass of Cr, the balance being Cu and unavoidable impurities. The material fulfills the relationships 1.0?I {200}/I0 {200}?5.0 and 5.0 ?m?GS?60.0 ?m, and these have the relationship (Equation 1): 5.0?{(I {200}/I0 {200})/GS}×100?21.0, in which the I {200} represents an X-ray diffraction intensity of a {200} crystal plane, the I0 {200} represents an X-ray diffraction intensity of a {200} crystal plane of standard pure copper powder, and the GS (?m) represents an average crystal grain size. An electrical conductivity is 43.5% to 55.0% IACS and 0.2% yield strength is 720 to 900 MPa.Type: GrantFiled: March 23, 2017Date of Patent: October 27, 2020Assignee: JX Nippon Mining & Metals CorporationInventor: Kei Saegusa
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Patent number: 10745787Abstract: A copper alloy sheet material has a copper alloy component system that has a high conductivity of 75.0% IACS or more and has both high strength and good stress relaxation resistance characteristics. A copper alloy sheet material has a composition containing, by mass %, from 0.01 to 0.50% of Zr, from 0.01 to 0.50% of Sn, a total content of from 0 to 0.50% of Mg, Al, Si, P, Ti, Cr, Mn, Co, Ni, Zn, Fe, Ag, Ca, and B, with the balance Cu, and unavoidable impurities, and a metal structure having a number density NA Of fine second phase particles having a particle diameter of approximately from 5 to 50 nm of 10.0 per 0.12 mm2 or more and a ratio NB/NA of a number density NB (per 0.012 mm2) of coarse second phase particles having a particle diameter exceeding approximately 0.2 mm and the NA of 0.50 or less.Type: GrantFiled: August 29, 2016Date of Patent: August 18, 2020Assignee: DOWA METALTECH CO., LTD.Inventors: Tsuyoshi Ito, Kuniaki Miyagi, Hiroto Narieda, Tomotsugu Aoyama, Akira Sugawara
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Patent number: 10662515Abstract: A copper alloy sheet material includes 0.5 to 2.5 mass % of Ni, 0.5 to 2.5 mass % of Co, 0.30 to 1.2 mass % of Si and 0.0 to 0.5 mass % of Cr and the balance Cu and unavoidable impurities, wherein an X-ray diffraction intensity ratio is 1.0?I{200}/I0{200}?5.0 when I{200} is a result of the X-ray diffraction intensity of {200} crystal plane of sheet surface and I0{200} is a result of the X-ray diffraction intensity of {200} crystal plane of a standard powder of pure copper, and wherein 0.2% yield strength in a rolling parallel direction (RD) is 800 MPa or more and 950 MPa or less, an electrical conductivity of 43.5% IACS or more and 53.0% IACS or less, 180 degree bending workability in a rolling parallel direction (GW) and a rolling perpendicular direction (BW) is R/t=0, and a difference between the rolling parallel direction (RD) and a rolling perpendicular direction (TD) of the 0.2% yield strength is 40 MPa or less.Type: GrantFiled: March 28, 2017Date of Patent: May 26, 2020Assignee: JX Nippon Mining & Metals CorporationInventor: Kei Saegusa
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Patent number: 10619232Abstract: The invention relates to a connecting element (4, 5), in particular a screw (4) or a nut (5), for mechanically connecting components (1, 2), the connecting element (4, 5) consisting at least partially of a material with a mechanical tensile strength of at least 350 MPa. According to the invention, the material of the connecting element (4, 4?, 5, 8) has an electrical conductivity of at least 50% IACS. The invention also relates to a corresponding production method for a connecting element (4, 5) of this type.Type: GrantFiled: January 29, 2016Date of Patent: April 14, 2020Assignee: Isabellenhuette Heusler GmbH & Co. KGInventors: Jan Marien, Jens Hartmann, Daniel Zuckermann
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Patent number: 10358697Abstract: The present invention provides a Cu—Co—Ni—Si alloy for an electronic component having improved reliability in which in addition to high strength and high electrical conduction, bendability generally difficult to achieve with strength is also provided to a Corson copper alloy. The present invention is a Cu—Co—Ni—Si alloy for an electronic component comprising 0.5 to 3.0% by mass of Co and 0.1 to 1.0% by mass of Ni, a concentration (% by mass) ratio of Ni to Co (Ni/Co) being adjusted in the range of 0.1 to 1.0, the alloy comprising Si so that a (Co+Ni)/Si mass ratio is in the range of 3 to 5, and comprising a balance comprising Cu and unavoidable impurities, wherein a coefficient of variation of concentration ratios of Co to Ni (Co/Ni) measured for at least 100 second-phase particles is 20% or less.Type: GrantFiled: October 4, 2016Date of Patent: July 23, 2019Assignee: JX Nippon Mining & Metals CorporationInventor: Hiroyasu Horie
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Patent number: 10017841Abstract: Copper alloy casting contains Cu: 58-72.5 mass %; Zr: 0.0008-0.045 mass %; P: 0.01-0.25 mass %; one or more elements selected from Pb: 0.01-4 mass %, Bi: 0.01-3 mass %, Se: 0.03-1 mass %, and Te: 0.05-1.2 mass %; and Zn: a remainder, wherein [Cu]?3[P]+0.5([Pb]+[Bi]+[Se]+[Te])=60-90, [P]/[Zr]=0.5-120, and 0.05[?]+([Pb]+[Bi]+[Se]+[Te])=0.45-4 (the content of an element ‘a’ is denoted as [a] mass %; the content of ? phase is denoted as [?]% by area ratio; and an element ‘a’ that is not contained is denoted as [a]=0). The total content of ? phase and ? phase is 85% or more, ? phase content is 25% or less by area ratio, and mean grain size in the macrostructure during melt-solidification is 250 ?m or less.Type: GrantFiled: August 10, 2005Date of Patent: July 10, 2018Assignee: MITSUBISHI SHINDOH CO., LTD.Inventor: Keiichiro Oishi
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Patent number: 9982335Abstract: A manufacturing method of a cylindrical sputtering target material formed of copper or a copper alloy is provided, the method including: a continuous casting step of casting a cylindrical ingot having an average crystal grain diameter equal to or smaller than 20 mm using a continuous casting machine or a semi-continuous casting machine; and a cold working step and a heat treatment step of repeatedly performing cold working and a heat treatment with respect to the cylindrical ingot, to form the cylindrical sputtering target material in which an average crystal grain diameter of an outer peripheral surface is from 10 ?m to 150 ?m and a proportion of the area of crystal grains having a crystal grain diameter more than double the average crystal grain diameter is less than 25% of the entire crystal area.Type: GrantFiled: February 20, 2015Date of Patent: May 29, 2018Assignee: MITSUBISHI MATERIALS CORPORATIONInventors: Akira Sakurai, Satoshi Kumagai, Takashi Sonohata, Michiaki Ohto
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Patent number: 9653191Abstract: The present invention relates to a copper alloy for electric and electronic device, a copper alloy sheet for electric and electronic device, a conductive component for electric and electronic device, and a terminal. The copper alloy for electric and electronic device includes more than 2.0 mass % to 15.0 mass % of Zn; 0.10 mass % to 0.90 mass % of Sn; 0.05 mass % to less than 1.00 mass % of Ni; 0.001 mass % to less than 0.100 mass % of Fe; 0.005 mass % to 0.100 mass % of P; and a remainder comprising Cu and unavoidable impurities, in which 0.002?Fe/Ni<1.500, 3.0<(Ni+Fe)/P<100.0, and 0.10<Sn/(Ni+Fe)<5.00 were satisfied by atomic ratio, and a yield ratio YS/TS is more than 90% which is calculated from a strength TS and a 0.2% yield strength YS when a tensile test is performed in a direction parallel to a rolling direction.Type: GrantFiled: December 26, 2013Date of Patent: May 16, 2017Assignees: MITSUBISHI MATERIALS CORPORATION, MITSUBISHI SHINDOH CO., LTD.Inventors: Kazunari Maki, Hiroyuki Mori, Daiki Yamashita
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Patent number: 9490039Abstract: Cu—Co—Si-based alloy strip, which has not only an excellent balance between strength and electrical conductivity but also suppressed hanging curl, is provided. The copper alloy strip for electronic materials comprises 0.5-2.5 mass % of Co, 0.1-0.7 mass % of Si, the balance Cu and inevitable impurities, wherein, from a result obtained from measurement of an X ray diffraction pole figure, using a rolled surface as a reference plane, the following (a) is satisfied. (a) A diffraction peak height at ? angle 120° among diffraction peak intensities by ? scanning at ?=25° in a {200} pole figure is at least 10 times that of standard copper powder.Type: GrantFiled: March 15, 2012Date of Patent: November 8, 2016Assignee: JX Nippon Mining & Metals CorporationInventors: Hiroshi Kuwagaki, Yasuhiro Okafuji
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Patent number: 9478323Abstract: A Cu—Si—Co-based alloy having an enhanced spring limit is provided. The copper alloy comprises 0.5-2.5 mass % of Co, 0.1-0.7 mass % of Si, the balance Cu and inevitable impurities, wherein, from a result obtained from measurement of an X ray diffraction pole figure, using a rolled surface as a reference plane, a peak height at ? angle of 90° among diffraction peaks in {111} Cu plane with respect to {200} Cu plane by ? scanning at ?=35° is at least 2.5 times that of a standard copper powder.Type: GrantFiled: March 2, 2012Date of Patent: October 25, 2016Assignee: JX Nippon Mining & Metals CorporationInventors: Yasuhiro Okafuji, Hiroshi Kuwagaki
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Patent number: 9455058Abstract: In a high-strength and high-electrical conductivity copper alloy rolled sheet, 0.14 to 0.34 mass % of Co, 0.046 to 0.098 mass % of P, 0.005 to 1.4 mass % of Sn are contained, [Co] mass % representing a Co content and [P] mass % representing a P content satisfy the relationship of 3.0?([Co]?0.007)/([P]?0.009)?5.9, a total cold rolling ratio is equal to or greater than 70%, a recrystallization ratio is equal to or less than 45% a an average grain size of recrystallized grains is in the range of 0.7 to 7 ?m, an average grain diameter of precipitates is in the range of 2.0 to 11 nm, and an average grain size of fine crystals is in the range of 0.3 to 4 ?m. By the precipitates of Co and P, the solid solution of Sn, and fine crystals, the strength, conductivity and ductility of the copper alloy rolled sheet are improved.Type: GrantFiled: December 25, 2009Date of Patent: September 27, 2016Assignee: MITSUBISHI SHINDOH CO., LTD.Inventor: Keiichiro Oishi
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Patent number: 9401230Abstract: Cu—Ni—Si—Co copper alloy strip having excellent balance between strength and electrical conductivity which can prevent the drooping curl is provided. The copper alloy strip for an electronic materials contains 1.0-2.5% by mass of Ni, 0.5-2.5% by mass of Co, 0.3-1.2% by mass of Si, and the remainder comprising Cu and unavoidable impurities, wherein the copper alloy strip satisfies both of the following (a) and (b) as determined by means of X-ray diffraction pole figure measurement based on a rolled surface: (a) among a diffraction peak intensities obtained by ? scanning at ?=20° in a {200} pole figure, a peak height at ? angle 145° is not more than 5.2 times that of standard copper powder; (b) among a diffraction peak intensities obtained by ? scanning at ?=75° in a {111} pole figure, a peak height at ? angle 185° is not less than 3.4 times that of standard copper powder.Type: GrantFiled: November 11, 2011Date of Patent: July 26, 2016Assignee: JX Nippon Mining & Metals CorporationInventor: Hiroshi Kuwagaki
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Patent number: 9225214Abstract: A disk motor including: a rotor including, a commutator disk including a commutator pattern, and at least one coil disk including a coil pattern; a stator including a magnetic flux generating part opposed to the coil pattern of the coil disk; an electric current supply part configured to supply electric current to the coil pattern via the commutator disk and, an output shaft configured to be rotated by a rotational force of the rotor, wherein a radiating pattern is provided to an outer periphery side of the commutator pattern of the commutator disk.Type: GrantFiled: August 28, 2012Date of Patent: December 29, 2015Assignee: HITACHI KOKI CO., LTD.Inventor: Hideyuki Tanimoto
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Patent number: 9214252Abstract: [Technical Problem] The invention is to provide a method for manufacture of an ultrafine conductor having sufficient electrical conductivity, and enhanced strength and stretch properties while suppressing manufacture cost, the same ultrafine conductor, as well as a material suited for the same ultrafine conductor. [Solution to Problem] To solve the above problem, there is provided a material for an ultrafine conductor, which includes a matrix formed of copper, chromium particles contained in the matrix, and tin contained in the matrix. The tin is present as a solid solution in the matrix.Type: GrantFiled: June 27, 2014Date of Patent: December 15, 2015Assignee: YAZAKI CORPORATIONInventor: Tsuyoshi Watanabe
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Publication number: 20150107726Abstract: The present invention provides a Cu—Fe—P alloy which has a high strength, high conductivity and superior bending workability. The copper alloy comprises 0.01 to 1.0% Fe, 0.01 to 0.4% P, 0.1 to 1.0% Mg, and the remainder Cu and unavoidable impurities. The size of oxides and precipitates including Mg in the copper alloy is controlled so that the ratio of the amount of Mg measured by a specified measurement method in the extracted residue by a specified extracted residue method to the Mg content in said copper alloy is 60% or less, thus endowing the alloy with a high strength and superior bending workability.Type: ApplicationFiled: December 29, 2014Publication date: April 23, 2015Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yasuhiro ARUGA, Katsura Kajihara, Takeshi Kudo
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Patent number: 9002499Abstract: Methods for determining a recovery state of a metal alloy are disclosed herein. In one example, a fluctuation in a crystallographic grain orientation of the metal alloy is determined by utilizing electron backscatter diffraction (EBSD) data of the metal alloy. A processor of an electron backscatter diffraction machine utilizes a local orientation deviation quantifier to correlate the fluctuation in the crystallographic grain orientation of the metal alloy with a plastic strain recovery of the metal alloy. Other examples of the method are also disclosed herein.Type: GrantFiled: March 20, 2012Date of Patent: April 7, 2015Assignee: GM Global Technology Operations LLCInventors: Rajesh Raghavan, Shashank Tiwari, Sushil Kumar Mishra
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Patent number: 8992702Abstract: There is provided a copper alloy sheet including 1.0 to 3.5 mass % Ni, 0.5 to 2.0 mass % Co, and 0.3 to 1.5 mass % Si, a Co/Ni mass ratio being 0.15 to 1.5, an (Ni+Co)/Si mass ratio being 4 to 7, and a balance being composed of Cu and an unavoidable impurity, wherein in observation results of a crystal grain boundary property and crystal orientation by EBSP measurement, a density of twin boundaries among all crystal grain boundaries is 40% or more and an area ratio of crystal grains with Cube orientation is 20% or more, on a rolled surface.Type: GrantFiled: July 9, 2010Date of Patent: March 31, 2015Assignee: Dowa Metaltech Co., LtdInventors: Weilin Gao, Akira Sugawara, Ryosuke Miyahara, Hisashi Suda
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Publication number: 20150053314Abstract: Manufacturing method of a copper alloy sheet including melting and casting a raw material of a copper alloy having a composition containing 1.0 mass % to 3.5 mass % Ni, 0.5 mass % to 2.0 mass % Co, and 0.3 mass % to 1.5 mass % Si with a balance being composed of Cu and an unavoidable impurity. The method includes the steps of first cold rolling, intermediate annealing, second cold rolling, a solution heat treatment and aging. The solution heat treatment includes: heating at 800° C. to 1020° C.; first quenching to 500° C. to 800° C.; maintaining the 500° C. to 800° C. temperature for 10 seconds to 600 seconds; and second quenching to 300° C. or lower.Type: ApplicationFiled: October 30, 2014Publication date: February 26, 2015Inventors: Weilin Gao, Akira Sugawara, Ryosuke Miyahara, Hisashi Suda
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Patent number: 8951371Abstract: A method of producing a copper alloy containing a precipitate X composed of Ni and Si and a precipitate Y that includes (a) Ni and 0% Si, (b) Si and 0% Ni, or (c) neither Ni nor Si, wherein the precipitate X has a grain size of 0.001 to 0.1 ?m, and the precipitate Y has a grain size of 0.01 to 1 ?m.Type: GrantFiled: December 22, 2010Date of Patent: February 10, 2015Assignee: The Furukawa Electric Co., Ltd.Inventors: Kuniteru Mihara, Tatsuhiko Eguchi, Nobuyuki Tanaka, Kiyoshige Hirose
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Publication number: 20140318673Abstract: A copper alloy material, having an alloy composition containing any one or both of Ni and Co in an amount of 0.4 to 5.0 mass % in total, and Si in an amount of 0.1 to 1.5 mass %, with the balance being copper and unavoidable impurities, wherein a ratio of an area of grains in which an angle of orientation deviated from S-orientation {2 3 1} <3 4 6> is within 30° is 60% or more, according to a crystal orientation analysis in EBSD measurement; an electrical or electronic part formed by working the copper alloy material; and a method of producing the copper alloy material.Type: ApplicationFiled: June 24, 2014Publication date: October 30, 2014Inventors: Hiroshi KANEKO, Kiyoshige HIROSE, Tatsuhiko EGUCHI
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Publication number: 20140311633Abstract: A spinodal copper-nickel-tin alloy with a combination of improved impact strength, yield strength, and ductility is disclosed. The alloy is formed by process treatment steps including solution annealing, cold working and spinodal hardening. These include such processes as a first heat treatment/homogenization step followed by hot working, solution annealing, cold working, and a second heat treatment/spinodally hardening step. The spinodal alloys so produced are useful for applications demanding enhanced strength and ductility such as for pipes and tubes used in the oil and gas industry.Type: ApplicationFiled: April 23, 2014Publication date: October 23, 2014Applicant: Materion CorporationInventors: W. Raymond Cribb, Chad A. Finkbeiner, Fritz C. Grensing
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Publication number: 20140305551Abstract: A copper alloy material for electrical and electronic components and a method of preparing the same are disclosed. In particular, a copper alloy material with excellent mechanical strength characteristics, high electrical conductivity, and high thermal stability as a material for information transmission and electrical contact of connectors or the like for home appliances and automobiles, including semiconductor lead frames and a method of preparing the same are disclosed.Type: ApplicationFiled: October 22, 2013Publication date: October 16, 2014Applicant: POONGSAN CORPORATIONInventors: CHEOL MIN PARK, In Youb Hwang
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Patent number: 8845829Abstract: A method of manufacturing a Cu alloy conductor includes the steps of: adding and dissolving In of 0.1-0.7 weight % to a Cu matrix containing oxygen of 0.001-0.1 weight % (10-1000 weight ppm) to form a molten Cu alloy, performing a continuous casting with the molten Cu alloy, rapidly quenching a casting material to a temperature by at least 15° C. or more lower than a melting point of molten Cu alloy, controlling the casting material at a temperature equal to or lower than 900° C., and performing a plurality of hot rolling processes to the casting material such that a temperature of a final hot rolling is within a range of from 500 to 600° C. to form the rolled material.Type: GrantFiled: March 3, 2010Date of Patent: September 30, 2014Assignee: Hitachi Metals, Ltd.Inventors: Seigi Aoyama, Takaaki Ichikawa, Hiroyoshi Hiruta, Hiromitsu Kuroda
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Publication number: 20140209215Abstract: A copper-based alloy wire made of a material selected from the group consisting of a copper-gold alloy, a copper-palladium alloy and a copper-gold-palladium alloy is provided. The alloy wire has a polycrystalline structure of a face-centered cubic lattice and consists of a plurality of equi-axial grains. The quantity of grains having annealing twins is 10 percent or more of the total quantity of the grains of the copper-based alloy wire.Type: ApplicationFiled: January 16, 2014Publication date: July 31, 2014Inventors: Tung-Han CHUANG, Jun-Der LEE, Hsing-Hua TSAI
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Patent number: 8784580Abstract: Disclosed is a Cu—Ni—Si copper alloy sheet that excels in strength and formability and is used in electrical and electronic components. The copper alloy sheet contains, by mass, 1.5% to 4.5% Ni and 0.3% to 1.0% of Si and optionally contains at least one member selected from 0.01% to 1.3% of Sn, 0.005% to 0.2% of Mg, 0.01% to 5% of Zn, 0.01% to 0.5% of Mn, and 0.001% to 0.3% of Cr, with the remainder being copper and inevitable impurities. The average size of crystal grains is 10 ?m or less, the standard deviation ? of crystal grain size satisfies the condition: 2?<10 ?m, and the number of dispersed precipitates lying on grain boundaries and having a grain size of from 30 to 300 nm is 500 or more per millimeter.Type: GrantFiled: February 14, 2008Date of Patent: July 22, 2014Assignee: Kobe Steel, Ltd.Inventors: Akira Fugono, Hiroshi Sakamoto
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Publication number: 20140190596Abstract: Disclosed is a beryllium-free copper alloy having high strength, high electric conductivity and good bending workability and a method of manufacturing the copper alloy. Provided is a copper alloy having a composition represented by the composition formula by atom %: Cu100-a-b-c(Zr, Hf)a(Cr, Ni, Mn, Ta)b(Ti, Al)c [wherein 2.5?a?4.0, 0.1<b?1.5 and 0?c?0.2; (Zr, Hf) means one or both of Zr and Hf; (Cr, Ni, Mn, Ta) means one or more of Cr, Ni, Mn and Ta; and (Ti, Al) means one or both of Ti and Al], and having Cu primary phases in which the mean secondary dendrite arm spacing is 2 ?m or less and eutectic matrices in which the lamellar spacing between a metastable Cu5(Zr, Hf) compound phase and a Cu phase is 0.2 ?m or less.Type: ApplicationFiled: March 29, 2012Publication date: July 10, 2014Applicant: TOHOKU UNIVERSITYInventors: Akihisa Inoue, Nobuyuki Nishiyama, Haruko Yamazaki
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Patent number: 8652274Abstract: A copper alloy includes Si to facilitate deoxidation, and can be easily manufactured even when including elements such as Cr or Sn. The copper alloy has high conductivity and high workability without negatively affecting the tensile strength. The copper alloy contains 0.2 to 0.4 wt % of Cr, 0.05 to 0.15 wt % of Sn, 0.05 to 0.15 wt % of Zn, 0.01 to 0.30 wt % of Mg, 0.03 to 0.07 wt % of Si, with the remainder being Cu and inevitable impurities. A method for manufacturing the copper alloy includes obtaining a molten metal having the described composition; obtaining an ingot; heating the ingot at a temperature of 900-1000° C. to perform a hot rolling process; cold rolling; performing a first aging process at a temperature of 400-500° C. for 2 to 8 hours; cold rolling; and performing a second aging process at a temperature of 370-450° C. for 2 to 8 hours.Type: GrantFiled: December 7, 2010Date of Patent: February 18, 2014Assignee: Poonsgan CorporationInventors: Dae Hyun Kim, Dong Woo Lee, In Dal Kim, Sang Young Choi, Ji Hoon Lee, Bo Min Jeon
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Patent number: 8641838Abstract: A copper alloy sheet material, having a composition containing any one or both of Ni and Co in an amount of 0.5 to 5.0 mass % in total, and Si in an amount of 0.3 to 1.5 mass %, with the balance of copper and unavoidable impurities, wherein an area ratio of cube orientation {0 0 1} <1 0 0> is 5 to 50%, according to a crystal orientation analysis in EBSD measurement.Type: GrantFiled: December 1, 2010Date of Patent: February 4, 2014Assignee: The Furukawa Electric Co., Ltd.Inventors: Hiroshi Kaneko, Kiyoshige Hirose, Koji Sato
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Publication number: 20140014240Abstract: A Cu—Si—Co-based alloy having an enhanced spring limit is provided. The copper alloy comprises 0.5-2.5 mass % of Co, 0.1-0.7 mass % of Si, the balance Cu and inevitable impurities, wherein, from a result obtained from measurement of an X ray diffraction pole figure, using a rolled surface as a reference plane, a peak height at ? angle of 90° among diffraction peaks in {111} Cu plane with respect to {200} Cu plane by ? scanning at ?=35° is at least 2.5 times that of a standard copper powder.Type: ApplicationFiled: March 2, 2012Publication date: January 16, 2014Applicant: JX NIPPON MINING & METALS CORPORATIONInventors: Yasuhiro Okafuji, Hiroshi Kuwagaki
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Publication number: 20140014241Abstract: Cu—Co—Si-based alloy strip, which has not only an excellent balance between strength and electrical conductivity but also suppressed hanging curl, is provided. The copper alloy strip for electronic materials comprises 0.5-2.5 mass % of Co, 0.1-0.7 mass % of Si, the balance Cu and inevitable impurities, wherein, from a result obtained from measurement of an X ray diffraction pole figure, using a rolled surface as a reference plane, the following (a) is satisfied. (a) A diffraction peak height at ? angle 120° among diffraction peak intensities by ? scanning at ?=25° in a {200} pole figure is at least 10 times that of standard copper powder.Type: ApplicationFiled: March 15, 2012Publication date: January 16, 2014Applicant: JX NIPPON MINING & METALS CORPORATIONInventors: Hiroshi Kuwagaki, Yasuhiro Okafuji
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Publication number: 20140014239Abstract: A process for manufacturing copper-nickel-silicon alloys includes the sequential steps of casting the copper alloy; hot working the cast copper-base alloy to effect a first reduction in cross-sectional area; solutionizing the cast copper-base alloy at a temperature and for a time effective to substantially form a single phase alloy; first age annealing the alloy at a temperature and for a time effective to precipitate an amount of a second phase effective to form a multi-phase alloy having silicides; cold working the multi-phase alloy to effect a second reduction in cross-sectional area; and second age annealing the multiphase alloy at a temperature and for a time effective to precipitate additional silicides thereby raising conductivity, wherein the second age annealing temperature is less than the first age annealing temperature.Type: ApplicationFiled: April 17, 2013Publication date: January 16, 2014Applicants: Wieland-Werke AG, GBC Metals, LLCInventors: Frank N. Mandigo, Peter W. Robinson, Derek E. Tyler, Andreas Boegel, Hans-Achim Kuhn, Frank M. Keppeler, Joerg Seeger
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Publication number: 20130333812Abstract: To provide a copper alloy of the FCC structure containing Ni: 3.0 to 29.5 mass %, Al: 0.5 to 7.0 mass %, and Si: 0.1 to 1.5 mass %, with the remainder consisting of Cu and incidental impurities, wherein the copper alloy is of the high strength, but is excellent in workability, and has high electrical conductivity, and can control property thereof, by precipitating a ?? phase of the L12 structure including Si at an average particle diameter of 100 nm or less in a parent phase of the copper alloy.Type: ApplicationFiled: December 13, 2011Publication date: December 19, 2013Applicants: Tohoku Techno Arch Co., Ltd., Nippon Seisen Co., Ltd.Inventors: Kiyohito Ishida, Rysuke Kainuma, Ikuo Ohnuma, Toshihiro Omori, Takashi Miyamoto, Hiroki Sato
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Publication number: 20130284323Abstract: The present invention relates to a Cu—Co—Si—Zr alloy material which contains 1.0-2.5 wt % of Co, 0.2-0.7 wt % of Si and 0.001-0.5 wt % of Zr with the elemental ratio Co/Si being 3.5-5.0. The Cu—Co—Si—Zr alloy material contains second phase particles having a diameter of 0.20 ?m or more but less than 1.00 ?m at a density of 3,000-500,000 particles/mm2, and has a crystal grain size of 10 ?m or less, an electrical conductivity of 60% IACS or more and good bending workability. The alloy material can be produced by setting the temperature of heating that is carried out after casting and before a solution heat treatment to a temperature that is higher than the later-described solution heat treatment temperature by 45° C. or more, by setting the cooling rate from the start temperature of hot rolling to 600° C. to 100° C./min or less, and by selecting the solution heat treatment temperature from (50× Co wt %+775)° C. to (50× Co wt %+825)° C. (inclusive).Type: ApplicationFiled: January 12, 2012Publication date: October 31, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventor: Yasuhiro Okafuji
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Publication number: 20130263978Abstract: Cu—Ni—Si—Co copper alloy strip having excellent balance between strength and electrical conductivity which can prevent the drooping curl is provided. The copper alloy strip for an electronic materials contains 1.0-2.5% by mass of Ni, 0.5-2.5% by mass of Co, 0.3-1.2% by mass of Si, and the remainder comprising Cu and unavoidable impurities, wherein the copper alloy strip satisfies both of the following (a) and (b) as determined by means of X-ray diffraction pole figure measurement based on a rolled surface: (a) among a diffraction peak intensities obtained by ? scanning at ?=20° in a {200} pole figure, a peak height at ? angle 145° is not more than 5.2 times that of standard copper powder; (b) among a diffraction peak intensities obtained by ? scanning at ?=75° in a {111} pole figure, a peak height at ? angle 185° is not less than 3.4 times that of standard copper powder.Type: ApplicationFiled: November 11, 2011Publication date: October 10, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventor: Hiroshi Kuwagaki
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Publication number: 20130180630Abstract: A Cu—Co—Si-based alloy that has even mechanical properties and that is provided with favorable mechanical and electrical properties as a copper alloy for an electronic material is provided. The copper alloy for an electronic material comprises 0.5% by mass to 3.0% by mass of Co, 0.1% by mass to 1.0% by mass of Si, and the balance Cu with inevitable impurities. An average grain size is in the range of 3 ?m to 15 ?m and an average difference between a maximum grain size and a minimum grain size in every observation field of 0.05 mm2 is 5 ?m or less.Type: ApplicationFiled: September 6, 2011Publication date: July 18, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventors: Yasuhiro Okafuji, Takuma Onda, Hiroshi Kuwagaki
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Patent number: 8444779Abstract: The invention provides Cu—Ni—Si—Co alloys having excellent strength, electrical conductivity, and press-punching properties. In one aspect, the invention is a copper alloy for electronic materials, containing 1.0 to 2.5 mass % of Ni, 0.5 to 2.5 mass % of Co, and 0.30 to 1.2 mass % of Si, the balance being Cu and unavoidable impurities, wherein the copper alloy for electronic material has a [Ni+Co+Si] content in which the median value ? (mass %) satisfies the formula 20 (mass %)???60 (mass %), the standard deviation ? (Ni+Co+Si) satisfies the formula ? (Ni+Co+Si)?30 (mass %), and the surface area ratio S (%) satisfies the formula 1%?S?10%, in relation to the compositional variation and the surface area ratio of second-phase particles size of 0.1 ?m or greater and 1 ?m or less when observed in a cross section parallel to a rolling direction.Type: GrantFiled: August 22, 2008Date of Patent: May 21, 2013Assignee: JX Nippon Mining & Metals Co., Ltd.Inventors: Naohiko Era, Hiroshi Kuwagaki
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Publication number: 20130098511Abstract: A Cu—Co—Si alloy having an improved balance between electrical conductivity and strength is provided. Disclosed is a copper alloy for electronic materials, which contains 0.5% to 4.0% by mass of Co and 0.1% to 1.2% by mass of Si, with the balance being Cu and unavoidable impurities, and in which the mass % ratio of Co and Si (Co/Si) is 3.5?Co/Si?5.5, an area ratio of discontinuous precipitation (DP) cells is 5% or less, and an average value of a maximum width of discontinuous precipitation (DP) cells is 2 ?m or less.Type: ApplicationFiled: April 8, 2011Publication date: April 25, 2013Applicant: JX Nippon Mining & Metals CorporationInventor: Takuma Onda
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Publication number: 20130092297Abstract: The present invention provides a Cu—Co—Si system alloy sheet, being suitable for use in a variety of electronic device components, in particular, having excellent uniform adhesive property for plate. The copper alloy sheet for electronic materials, contains 0.5 to 3.0 mass % Co, 0.1 to 1.0 mass % Si, the balance being Cu and unavoidable impurities, wherein an average grain size in the center part of the sheet thickness is 20 ?m or less, and the number of the crystal grain, being tangent to a surface of the sheet and having 45 ?m or more of the length of major axis, is 5 or less in the area of 1 mm in a rolling direction.Type: ApplicationFiled: March 24, 2011Publication date: April 18, 2013Applicant: JX Nippon Mining & Metals CorporationInventor: Hiroshi Kuwagaki
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Publication number: 20130087255Abstract: Disclosed is a Cu—Co—Si-based copper alloy for electronic materials, which is capable of achieving high levels of strength, electrical conductivity, and also anti-setting property; and contains 0.5 to 3.0% by mass of Co, 0.1 to 1.0% by mass of Si, and the balance of Cu and inevitable impurities; wherein out of second phase particles precipitated in the matrix a number density of the particles having particle size of 5 nm or larger and 50 nm or smaller is 1×1012 to 1×1014 particles/mm3, and a ratio of the number density of particles having particle size of 5 nm or larger and smaller than 10 nm relative to the number density of particles having particle size of 10 nm or larger and 50 nm or smaller is 3 to 6.Type: ApplicationFiled: April 8, 2011Publication date: April 11, 2013Applicant: JX Nippon Mining & Metals CorporationInventor: Hiroshi Kuwagaki
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Patent number: 8409375Abstract: A method of producing a copper alloy wire rod, containing: a casting step for obtaining an ingot by pouring molten copper of a precipitation strengthening copper alloy into a belt-&-wheel-type or twin-belt-type movable mold; and a rolling step for rolling the ingot obtained by the casting step, which steps are continuously performed, wherein an intermediate material of the copper alloy wire rod in the mid course of the rolling step or immediately after the rolling step is quenched.Type: GrantFiled: December 1, 2008Date of Patent: April 2, 2013Assignee: The Furukawa Electric Co., Ltd.Inventors: Hirokazu Yoshida, Tsukasa Takazawa