Nickel(ni) Or Nickel Base Alloy Patents (Class 148/555)
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Patent number: 5858558Abstract: A nickel-base gamma-sigma intermetallic matrix composite material suitable for forming gas turbine engine components and structural coatings for such components. The composite material contains, in weight percent, about 20 to 50 chromium, about 0 to 32 molybdenum, and about 0.5 to 7 silicon, with the balance being nickel and incidental impurities. In addition, the composite material may contain aluminum and titanium in amounts of up to about 7 and 3 weight percent, respectively. The resulting intermetallic matrix composite material is characterized by a sigma volume fraction of greater than 30 percent, preferably at least about 50 percent, and may have a dendritic, fibrous or lamellar microstructure. The composite material can be cast to form a component, or deposited by known techniques to form a structural coating on a component.Type: GrantFiled: October 30, 1996Date of Patent: January 12, 1999Assignee: General Electric CompanyInventors: Ji-Cheng Zhao, Melvin Robert Jackson
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Patent number: 5838080Abstract: Stepper motor of the type comprising a rotor (1), a stator (2) and a coil (3) consisting of a magnetic core (4) and of a winding (5), in which the stator (2) consists of a soft magnetic alloy of the FeNiCr type, the chemical composition of which includes, by weight: 40%.ltoreq.Ni+Co.ltoreq.60%, 0%.ltoreq.Co.ltoreq.7%, 8%.ltoreq.Cr.ltoreq.13.5%, 8%.ltoreq.Cr+Mn+Si+Mo+Nb+V+W.ltoreq.13.5%, the remainder being iron and impurities resulting from the manufacture. Soft magnetic alloy.Type: GrantFiled: August 6, 1997Date of Patent: November 17, 1998Assignee: Imphy S.A.Inventors: Georges Couderchon, Laurent Chaput, Lucien Coutu, Dominique Gautard
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Patent number: 5817222Abstract: A rare earth metal-nickel hydrogen storage alloy having a composition represented by the formula (1)RNi.sub.x-y M.sub.y (1)(wherein R stands for La, Ce, Pr, Nd, or mixtures thereof, M stands for Co, Al, Mn, Fe, Cu, Zr, Ti, Mo, Si, V, Cr, Nb, Hf, Ta, W, B, C, or mixtures thereof, x satisfies the formula of 3.5.ltoreq.x<5, and y satisfies the formula of 0<y.ltoreq.2, crystals in the alloy having a LaNi.sub.5 type single phase structure, the alloy including in an amount of not less than 5 volume % and less than 95 volume % thereof crystals each containing not less than 2 and less than 17 antiphase boundaries extending perpendicular to C-axis of a grain of the crystal in the alloy per 20 nm along the C-axis, a method of producing the same, and an anode for a nickel hydrogen rechargeable battery containing as an anode material the above rare earth metal-nickel hydrogen storage alloy and an electrically conductive material.Type: GrantFiled: November 27, 1996Date of Patent: October 6, 1998Assignee: Santoku Metal Industry Co., Ltd.Inventor: Akihito Kaneko
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Patent number: 5788785Abstract: The present invention relates to a method for making a gamma prime precipitation strengthened nickel base alloy having an improved resistance to hydrogen embrittlement, particularly crack propagation. The alloy is cast, heat treated to dissolve substantially all the gamma-gamma prime eutectic islands and script carbides without causing incipient melting, cooled to below 1000.degree. C., HIP'ed to eliminate porosity, precipitation treated and aged. The alloy has a microstructure which is essentially free of script carbides, gamma-gamma prime eutectic islands and porosity. The microstructure further includes a plurality of regularly occurring large barrier gamma prime precipitates and a continuous field of fine cuboidal gamma prime precipitates surrounding the large barrier gamma prime precipitates.Type: GrantFiled: November 8, 1996Date of Patent: August 4, 1998Assignee: United Technology CorporationInventors: Daniel P. DeLuca, Charles M. Biondo, Howard B. Jones, Chris C. Rhemer
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Patent number: 5706881Abstract: A method of making a single crystal or columnar grain superalloy casting comprises casting a superalloy in a mold wherein at least one of the mold and optional core comprises an oxygen-bearing ceramic, directionally solidifying the superalloy to form a single crystal or columnar grain superalloy casting, and solution heat treating the superalloy casting. The heat treatment is conducted under an atmosphere including a carbon-bearing gas, such as a carbon monoxide and inert gas mixture, wherein the carbon-bearing gas is present in an effective amount to reduce loss of carbon from the casting during the heat treatment. The heat treatment can be conducted prior to removal of all of the mold and core, if present, such as, for example, when the cast mold is in the as-knocked out condition wherein residual mold and/or core material is present on the casting. Alternately, the heat treatment can be conducted after removal of the mold and core, if present.Type: GrantFiled: February 18, 1997Date of Patent: January 13, 1998Assignee: Howmet Research CorporationInventors: Robert E. Grunstra, Julie A. Faison, Jacqueline B. Wahl
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Patent number: 5680896Abstract: A method for producing rare earth metal-nickel hydrogen occlusive alloy ingot that contains 90 vol % or more of crystals having a crystal grain size of 1 to 50 .mu.m as measured along a short axis of the crystal and 1 to 100 .mu.m as measured along a long axis of the crystal. The method for producing the rare earth metal-nickel hydrogen occlusive alloy ingot involves melting a rare earth metal-nickel alloy and uniformly solidifying the alloy melt to have a thickness of 0.1 to 20 mm under cooling conditions of a cooling rate of 10.degree. to 1000.degree. C./sec and a sub-cooling degree of 10.degree. to 500.degree. C.Type: GrantFiled: April 6, 1995Date of Patent: October 28, 1997Assignee: Santoku Metal Industry Co., Ltd.Inventors: Kazuhiko Yamamoto, Yuichi Miyake, Chikara Okada, Nobuyuki Kitazume
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Patent number: 5509980Abstract: The present invention is directed to a pre-weld overageing heat treatment for nickel-based superalloys, where the alloy is heated to solutionization temperature for a time sufficient to dissolve the gamma prime phase of the alloy microstructure, then slowly cooled with periods of intermittent heating, so that the gamma prime phase reprecipitates as coarse equiaxed particles, and the presence of fine sized gamma prime phase particles is substantially avoided. The present invention is also directed to a welding method wherein said pre-weld overageing treatment is used.Type: GrantFiled: August 17, 1994Date of Patent: April 23, 1996Assignee: National University of SingaporeInventor: Leong-Chew Lim
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Patent number: 5496424Abstract: A hydrogen absorbing alloy represented by the general formula R.sub.1-x A.sub.x (Ni.sub.5-y B.sub.y).sub.z wherein R is Mm (misch metal) or La, A is at least one element selected from the group consisting of Ce, Nd, Pr, Sm and Y, B is at least one element selected from the group consisting of Al, Sn, V, Cr, Mn, Fe, Co and Cu, 0.ltoreq.x.ltoreq.0.5, 0<y.ltoreq.1.0 and 0.8.ltoreq.z.ltoreq.1.2. The alloy is prepared by subjecting an alloy material of the above composition to a heat treatment so that when the plateau region of the resulting hydrogen absorbing alloy is expressed by a normal cumulative distribution function wherein the hydrogen content of the alloy is taken as frequency and the logarithm of the equilibrium hydrogen pressure of the alloy as a random variable, the alloy is at least 0.04 to up to 0.10 in standard deviation .sigma..Type: GrantFiled: October 5, 1993Date of Patent: March 5, 1996Assignee: Sanyo Electric Co., Ltd.Inventors: Shin Fujitani, Hiroshi Nakamura, Hiroshi Watanabe, Ikuo Yonezu, Toshihiko Saito
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Patent number: 5417782Abstract: A nickel-based superalloy known by the designation "718" and having a typical composition comprising, in percentages by weight, Cr 19, Fe 18, Nb 5, and the remainder Ni, is subjected, after the usual thermo-mechanical and heat treatment steps, to an additional annealing step wherein the temperature and duration are selected from the following range as desired:800.degree. C. for between 5 and 30 hours;750.degree. C. for between 25 and 70 hours; and700.degree. C. for between 100 and 300 hours.This leads to a definite improvement in the behaviour of parts made from the superalloy, in terms of fatigue cracking, when used at temperatures over 650.degree. C.Type: GrantFiled: June 3, 1993Date of Patent: May 23, 1995Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation "SNECMA"Inventor: Jean-Marc Rongvaux
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Patent number: 5330591Abstract: A nickel-based alloy useful in the manufacture of a glass fibre centrifuge of which the composition consists essentially of the following elements expressed as percentage by weight:______________________________________ Cr 27.5-29.5% W 6.5-7.8% C 0.69-0.73% Fe 7-10% ______________________________________the remainder substantially being nickel and having in its crystalline structure M.sub.23 C.sub.6 type carbides, M being chromium, at least one equivalent metal, or combination thereof, the M.sub.23 C.sub.6 carbides being substantially secondary.Type: GrantFiled: April 6, 1992Date of Patent: July 19, 1994Assignee: Isover Saint-GobainInventor: Stella Vasseur
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Patent number: 5302217Abstract: Superalloy castings having large variations in section thickness are heat treated using a cyclic stress relief procedure, with the temperature being cycled between about 50.degree. F. (28.degree. C.) and 150.degree. F. (83.degree. C.) below the second phase particle solvus temperature, to relieve the residual stresses incurred during cooling within the mold following casting, followed by a solution cycle at a temperature about 25.degree. F. (14.degree. C.) below the second phase particle solvus temperature to dissolve some or all of the second phase particles.Type: GrantFiled: December 23, 1992Date of Patent: April 12, 1994Assignee: United Technologies CorporationInventors: William J. Gostic, Charles M. Biondo, Timothy P. Fuesting
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Patent number: 5225004Abstract: Bulk rapidly solidified magnetic materials having a density of greater than 90%, a thickness of at least 250 microns, and preferably a low oxygen content, are produced by a liquid dynamic compaction process which, depending upon the chosen operating conditions, can yield materials ranging from crystalline to partially crystalline to amorphous. The materials so produced are directly useful, i.e. without having to be reduced to a powder and consolidated into a shape, to produce permanent magnets.Type: GrantFiled: April 30, 1991Date of Patent: July 6, 1993Assignee: Massachusetts Institute of TechnologyInventors: Robert C. O'Handley, Nicholas J. Grant, Yutaka Hara, Enrique J. Lavernia, Tetsuji Harada, Teiichi Ando
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Patent number: 5167734Abstract: A process for identificaiton, evaluation and removal of microshrinkage of investment cast superalloy parts and parts produced by the process. Parts free of deleterious microshrinkage capable of longer life at existing stress levels or use at higher alternating stresses are produced by first subjecting the parts to hot isostatic pressing to eliminate nonsurface connected subsurface microshrinkage. Next, in order to expose near-surface microshrinkage microscopically connected to the surface, the parts are immersed in an acid solution for a time sufficient to uniformly remove at least about 0.005 inches of the original as cast surface. The exposed microshrinkage is evaluated for acceptability or removal by standard nondestructive techniques, such as liquid penetration evaluation.Type: GrantFiled: December 9, 1991Date of Patent: December 1, 1992Assignee: General Electric CompanyInventors: Peter W. Mueller, Thomas F. Berry, Robert E. Allen, Christopher C. Glynn, Larry R. Samons
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Patent number: 5154884Abstract: A nickel-base superalloy, particularly adapted for use in gas turbine engine single crystal blades and vanes is provided with a specific composition and heat treated in a particular manner to exhibit an improved balance of critical high temperature mechanical properties and resistance to oxidation and hot corrosion significantly superior to presently available alloys. In its broad form, the alloy composition comprises, by weight, 7-12% Cr, 1-5% Mo, 3-5% Ti, 3-5% Al, 5-15% Co, 3-12% W, up to 10% Re, 2-6% Ta, up to 2% Cb, up to 3% V, up to 2% Hf, the balance being essentially nickel and incidental impurities. Nickel-base superalloy single crystal articles formed of the alloy are described, as is the method, including heat treatment, employed to make the article.Type: GrantFiled: September 18, 1991Date of Patent: October 13, 1992Assignee: General Electric CompanyInventors: Carl S. Wukusick, Leo Buchakjian, Jr.