Abstract: A method of producing an extrusion-laminated member comprises extruding a thermoplastic resin from a T-die into the form of a film and laminating the film on a heated metallic base member using a pair of laminating rolls, wherein a pre-roll is disposed between the T-die and one of the laminating rolls to receive the film on the side opposite to the side that adheres onto the base member over the whole width of the film. The film is wound on the pre-roll at an angle (&agr;) of from 10 to 90 degrees. The film received by the pre-roll is fed to the laminating rolls, conveyed by being supported by the laminating rolls on the side opposite to the side that adheres onto the base member, and is fed to a nipping position so as to be melt-adhered onto the heated metallic base member.

Abstract: The invention consists of a multilayer material and a process for manufacturing this material. The multilayer material comprises a polyester substrate which is provided with a thermoset plastic polymer coating and a layer of contact adhesive. The polymer coating is produced by a reaction between a polyurethane polymer containing hydroxyl groups and a low molecular linear polyisocyanate, with catalytic tin-organic additives and colorants. The multilayer material is resistant to tearing and is also weather-resistant. A transparent, reactive layer, consisting, for example of a layer to take toner or ink, or a metallic layer, can be deposited on the side opposite to the polymer-coated substrate. Multilayer materials of this kind are suitable for large-scale covering of supporting frameworks in the construction of model aircraft and are also suitable as a medium onto which images and print may be applied using a plain paper copier, and can also be used to carry advertising.

Abstract: A process for making a protective and decorative surfacing film comprises extrusion coating a solventless polymeric material from an extruder die to form an optically clear first layer on a polyester carrier sheet traveling past the extruder die opening. The extrusion coated first layer is immediately cooled on the carrier sheet to harden it, followed by applying a pigmented second layer to the first layer. The composite paint coat is transferred to a reinforcing backing sheet, after which the carrier sheet is separated from the paint coat to expose the outer surface of the first layer as a high gloss surface with a high distinctness-of-image, providing a transparent protective outer coat for the pigmented second layer. The pigmented second layer can be solvent cast and dried or extruded and hardened as a separate coating on the first layer. The composite paint coat can be bonded to a coextruded size coat and semi-rigid plastic substrate panel to form a thermoformable laminate.

Abstract: The invention is directed to a process for the preparation of polymer laminated base paper, said process comprising laminating a base paper web on at least one side thereof with at least one polymer layer by extrusion-coating at a coating speed of 300 m/min or more, wherein the said base paper web is heated prior to laminating.

Abstract: This invention relates to the extrusion coating of polyethylene terephthalate (PET) onto paperboard. Such structures of this type, generally, provide an enhanced film adhesion of the PET onto the paperboard, while reducing the coat weights of the PET.

Abstract: A coated fabric having desirable weight and high durability, and particular utility in the manufacture of linings for particular articles is described. The fabric has a textile substrate which is coated to provide a structure having an abrasion resistance of at least about 750 cycles to failure when tested according to ASTM D 3884, and more preferably at least about 2200 cycles to failure. The coating is desirably transparent so that the pre-coated shade of the textile substrate is altered less than about 15%, and more preferably less than about 1%, when the fabric is coated. More particularly, the absolute value of the difference in shade depth of the coated fabric and the textile substrate is less than about 0.2, so that no visible shade change results. A method for producing the fabric and articles incorporating the fabric are also described.

Abstract: To provide a multiple coat metal pipe and its fabrication method having excellent corrosion resistance without deteriorating chipping resistance or splashing resistance, capable of being fabricated easily and capable of simply carrying out peel off operation owing to a weak peel off strength wherein corrosion resistance of an end working portion is not deteriorated, there is provided a multiple coat metal pipe which is a metal pipe constituted by multiplexing and coating a first layer including a resin having an adhesive force in respect of a surface treatment layer formed on an outer peripheral face of the metal pipe and capable of being extruded and a second layer provided on an outer peripheral face of the first layer, having a chipping resistance and capable of being extruded, wherein a peel off strength between the first layer and the second layer is 75 g/cm or less.

Abstract: A method of fabricating a multiple coat metal pipe includes a first layer comprising a resin having an adhesive force extruded on a surface treatment layer on an outer peripheral face of a metal pipe and a second layer comprising a resin having a chipping resistance extruded on an outer peripheral face of the first layer providing a coating on the first layer in a substantially non-adhesive state. In the substantially non-adhesive state, a peel off strength between the first layer and a second layer is 75 g/cm or less and the peel off strength enables the second layer to be peeled off from the first layer without peeling off the first layer. The first layer has a different dissolving performance than the second layer and the second layer is extruded at a temperature equal to or higher than a melting point of the first layer.

Abstract: Processes for producing a holographic material involve producing the holographic image on a polished, substantially smooth surface and then transferring the holographic image to a substrate. A metallic coating is applied to a smooth surface of a printing element to provide a coated surface, the coated surface is embossed to provide the holographic image, and the holographic image is transferred to a substrate via a bonding material, thereby producing the holographic material. The holographic material may be used to provide a decorative cover for an object or item, such as a floral grouping or a potted plant.

Abstract: Processes for producing a holographic material involve producing the holographic image on a polished, substantially smooth surface and then transferring the holographic image to a substrate. A metallic coating is applied to a smooth surface of a printing element to provide a coated surface, the coated surface is embossed to provide the holographic image, and the holographic image is transferred to a substrate via a bonding material, thereby producing the holographic material. The holographic material may be used to provide a decorative cover for an object or item, such as a floral grouping or a potted plant.

Abstract: Processes and apparatus for manufacturing an engineered-composite combining rigid flat-rolled sheet metal continuous-strip and selected polyester thermoplastics, which are formed into distinct polymeric layers for melted extrusion deposition on a single surface, at a time, using pressure dies, and other steps, for forming a uniform coat of distinct polymeric layers, which provide high green-strength-adhesion during continuous-in-line travel; and including dual-surface finishing for complete bonding of the polymeric layers on both metallic surfaces.

Abstract: Described herein is a method of preparing a fluoropolymer composite comprising the steps of activating the fluoropolymer substrate and thereafter applying a layer of a different polymer to the activated fluoropolymer substrate. The activation step can be described as a mixed gas plasma discharge or an electrically formed plasma. Also described herein are other methods of surface activation including exposure to excimer laser, gamma rays, x-ray flux, electron beam, sodium naphthalate bath, coupling or curing agents, and others. In particular, described is a fuel pipe comprised of an inner fluorocarbon layer having electrostatic discharge resistance and hydrocarbon evaporative emission resistance chemically bonded to an outer layer of a cross-linked polyethylene polymer. There is no need for additional adhesives. Fluoropolymer layers have excellent chemical resistance.

Abstract: A biaxially oriented polyolefin film having more than one layer and made from a base layer and from at least one outer layer. The base layer include a fatty amide and the outer layer include at least 80% by weight of a linear olefin polymer. The film is suitable, for example, for producing a film laminate by melt extrusion of a polyethylene layer.

Abstract: Beverage or food containers made from sheet material, and methods of making such containers. Such container comprises a layer of paperboard and an expanded foam layer applied as a coating in a liquid carrier, and affixed to a paperboard base layer. The expanded foam has a remote surface preferably defined by intermingled peaks and valleys. The sheet material can include a protective cover layer overlying the remote surface. Such cover layer can comprise paper, plastic film, or foamed thermoplastic. The sheet material can include a heat seal layer, with the heat seal layer overlying, and in surface-to-surface contact with, the foam layer such that the foam layer is between the paperboard and the heat seal layer. Preferred composition for the foam layer is PVDC or AMM.

Abstract: The invention is a method for application of a special low viscosity cyanoacrylate adhesive which is used for the manufacture and repair of wooden furniture. The cyanoacrylate adhesive quickly penetrates and bonds wood to wood. The wooden furniture that results from the process of this invention are cohesive in structure and are ready for immediate use. This special wood grade cyanoacrylate adhesive provided by this invention permits those in the furniture repair or furniture manufacture industries with a method of repairing or assembling wooden furniture in an easy and quick manner.

Abstract: Rollers, substrates, products and the like are not smeared with a sticky volatile component when a gas is blown from a blower provided near an extruding die to produce laminates. The blower is heated by a heater at a temperature not below the volatilization temperature of the volatile component volatilized from a resin film of thermoplastic resin extruded in molten conditions from the extruding die, and therefore the volatile component cannot stick on the blower and is immediately volatilized on the blower.

Abstract: Oligomeric materials contain ultraviolet light absorbing compounds that are covalently bound to the oligomer backbone through an ester or amide linkage. These ultraviolet light absorbing oligomers may be combined with polymers such as polyolefins to provide protection against the harmful effects of ultraviolet light.

Abstract: Method of coating a metallic substrate (1) with thermoplastic coating material, comprising a preheating the substrate in such as way that, just prior to coating, it is at a temperature between 70° C. and 150° C., preferably between 100° C. and 130° C. in the case of a coating containing polypropene and between 80 and 110° C. in the case of a coating containing polyethene; coextrusion, in the first coating station of a sheet (6) comprising a polyolefin covering layer and a modified polyolefin adhesion layer; coating of the substrate (1) with a molten sheet in the presence of ozone by pressing it with the adhesion layer against the surface of the substrate; transportation of the strip (9) coated on one side to a second coating station and heating the strip so that, just before coating, the strip is at a temperature between 70° C. and 130° C., preferably between 80° C. and 120° C.

Abstract: The invention relates to a laminated packaging material comprising a core layer of paper or paperboard and a gas barrier layer of a polyarmide blend including a condensation polymer of metaxylene diamine and adipic acid (Nylon-MXD6) and a second crystalline or semicrystalline polyamide, applied on one side of the core layer by means of co-extrusion coating. The invention also relates to a method of producing the laminated packaging material and to a packaging container which is produced from the laminated packaging material.

Abstract: A method for forming a glossy decorative laminate is disclosed. The method is achieved by stacking a decorative laminate sheet assembly having a top layer, casting a polypropylene release sheet wherein the polypropylene release sheet is processed with chill rollers treated in a manner which improves the gloss characteristics of the resulting decorative laminate, positioning the polypropylene release sheet on the top layer of the decorative laminate sheet assembly, applying heat and pressure to the decorative laminate sheet assembly and the polypropylene release sheet sufficient to bond the decorative laminate and releasably bond the polypropylene release sheet to the top layer of the decorative laminate sheet assembly, and removing the polypropylene release sheet from the top layer of the decorative laminate sheet assembly to reveal a decorative laminate exhibiting desirable gloss characteristics.

Abstract: Articles including material laminated to a surface of a microcellular substrate are disclosed, as well as methods of making these articles. Microcellular polymeric material in sheet form can be extruded and continuously fed from the extruded to a lamination system, or microcellular sheet can be produced and stored, and then fed into a lamination system.

Abstract: A method of curl control for lamination of a polymer sheet to each side of a core material comprising providing a bottom polymer sheet, bringing said bottom sheet into contact with a heat source, providing said core material, bringing said core material into contact with said bottom polymer sheet while simultaneously applying a binder between said bottom sheet and said core to form a laminate, providing a top polymer sheet, bringing said top sheet into contact with said laminate and while simultaneously applying a binder between said top sheet and said laminate to form a composite wherein each sheet to core modulus ratio is greater than 1 and wherein said composite has a desired curl.

Abstract: The present invention is a process for continuous extrusion coating the surfaces of a metal strip which includes the steps of moving said metal strip by means of a plurality of rolls. The strip then has impinged on its first and second surfaces to be coated an oxidizing flame. The first surface passes through a corona discharge and extruded on to the first surface is a melted polymeric extrudiate. Thereafter, the surface is passed over a chill roll having a temperature less than said extrudiate to provide a first coated surface. The second surface is then subjected to a oxidizing flame and corona discharge and a melted polymeric extrudiate is extruded on to the second surface. Thereafter, the second surface is passed over a chill roll having a temperature less than said extrudiate to provide a second coated surface. The coated strip is then reheated to about the melt temperature of said extrudiates and quenched to provide an extrusion coated strip of the present invention.

Abstract: A process for making a protective and decorative surfacing film comprises extrusion coating a solventless polymeric material from an extruder die to form an optically clear first layer on a polyester carrier sheet traveling past the extruder die opening. The extrusion coated first layer is immediately cooled on the carrier sheet to harden it, followed by applying a pigmented second layer to the first layer. The composite paint coat is transferred to a reinforcing backing sheet, after which the carrier sheet is separated from the paint coat to expose the outer surface of the first layer as a high gloss surface with a high distinctness-of-image, providing a transparent protective outer coat for the pigmented second layer. The pigmented second layer can be solvent cast and dried or extruded and hardened as a separate coating on the first layer. The composite paint coat can be bonded to a coextruded size coat and semi-rigid plastic substrate panel to form a thermoformable laminate.

Abstract: A multi-layer tube comprises a metal tube having an outer surface and a zinc layer bonded to the metal tube outer surface, wherein the zinc layer is selected from the group consisting of zinc plating, zinc nickel alloys, zinc cobalt alloys, zinc aluminum alloys, and mixtures thereof. A surface treatment layer is bonded to the zinc layer, wherein the surface treatment layer is selected from the group consisting of a zinc/aluminum/rare earth alloy, phosphate, chromate and mixtures thereof. A first polymeric layer is bonded to the surface treatment layer, wherein the first polymeric layer is selected from the group consisting of a thermoplastic elastomer, an ionomer, a nylon, a fluoropolymer, and mixtures thereof. A second polymeric layer is bonded to the first polymeric layer, wherein the second polymeric layer is selected from the group consisting of a nylon, a thermoplastic elastomer, a fluoropolymer, and mixtures thereof.

Abstract: A method and apparatus for applying an extrudable material to a substrate, in which a concentrated light beam is directed onto the substrate before or after the application of the extrudable material. The energy of the beam is concentrated on the substrate surface, wherein it is subsequently transferred to the extrudable material deposited on its surface, thereby increasing the temperature and lowering the viscosity of the closely situated material so as to facilitate material penetration into the substrate. This method allows the use of illumination of modest energy density, of wavelengths absorbed by the extrudable material, or of such cross-sectional extent that it may not be transmitted through the extrusion device by which the extrudable material is deposited.

Abstract: A non-foil composite laminate for an improved container providing an effective barrier for the containment of essential oils and prevention of losses of vitamin C. The non-foil composite laminate comprises an inner barrier layer of amorphous nylon and outer layers of heat sealable olefin polymer, facilitating manufacture while retaining desirable barrier properties.

Abstract: Methods of preparing biaxially oriented polyethylene films with improved optics and sealability properties are provided. The methods include stretching in the machine direction a multi-layer base sheet having a core layer with a first and a second side, at least one skin layer and outer surfaces; then coating at least one of the outer surfaces with a resin selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene and blends thereof, and finally, stretching the base sheet in a direction transverse to the machine direction.

Abstract: Films, made of polyethylenes and filers, and articles made therefrom greater WVTR than previously available films based on conventional Zeigler-Natta based polyethylenes. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made in widely varying filler content, generally polyethylene to filler ratios of 30/70 to 70/30. The metallocene based polyethylenes when combined with filler also permit the extrusion of thinner films leading to lighter weight and softer films. The m-polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50%, a Mw/Mn below 3, and a Mz/Mw below 2.

Abstract: The fuel hose of this invention is a fuel hose comprising a tubular fluororesin inner ply and, as laminated onto the peripheral surface thereof, a thermoplastic resin or rubber outer ply, the tubular fluororesin inner ply having been molded from a fluororesin with an F/C ratio, i.e. ratio of the number of fluorine atoms (F) to the number of carbon atoms (C), of not greater than 1.6 and the peripheral surface layer of the fluororesin inner ply having been modified into the following treated layer (A). (A) a layer with a distribution of oxygen atoms and having an F/C ratio, i.e. ratio of the number of fluorine atoms (F) to the number of carbon atoms (C), of not greater than 1.12 and an O/C ratio, i.e. ratio of the number of oxygen atoms (O) to the number of carbon atoms (C), of not less than 0.08.