Abstract: Press roll (10) for a laminating machine for producing a packaging material which comprises a carcass layer (42) consisting of paper or carton, and which carcass layer exhibits crease lines, through holes, openings or slits (43), which carcass layer exhibits, on one of its sides, a barrier layer (23), a plastic lining (31) which is arranged outside the barrier layer, and film (25) of laminant thermoplast which is arranged between the carcass layer and the barrier layer, with the said press roll (10) exhibiting a circular-cylindrical jacket surface having a facing (40) consisting of an elastic material. According to the invention, the said facing (40) comprises sections (44, 44′) in the jacket surface, which sections exhibit local deformation ability in relation to the surrounding facing (40, 44). The invention also relates to a method for producing packaging material and to packaging material which has been produced using this method.

Abstract: A composite panel comprised of a sheet of substrate and a coextruded layer of plastic covering the substrate. The panel may be used as a retaining panel for a body of water in a cantilever wall or an anchored sheet pile wall. The retaining panel may include a central portion, two side portions, and two flanges. The retaining panel may also include integral connecting portions. The substrate may be comprised of a material such as aluminum or steel, while the plastic may be a material such as polyvinyl chloride (PVC). Other applications of the composite panel include uses as building panels for sidewalls or roofs.

Abstract: Process for variously decorating sections made of plastic materials, composite materials and the like, comprising a step of pre-treatment for the preparation of the surface, a possible step of pre-painting, a possible step of pre-heating, a step of decoration by transfer from a strip-like flexible support unwinding continuously from a first coil through the action of at least a rotating nip roll, suitably shaped, heated and thermostated, and lastly a possible step of sublimation and fixing, to obtain the transfer of the decoration and the polymerization of colors. Apparatus for the formation of the decoration, comprising a first coil from which a flexible support unwinds at least a rotating nip roll, shaped according to the section to be decorated, heated and thermostated, and at least a second coil for the rewinding of the flexible strip, once the decoration layer and the protection layer have been removed.

Abstract: A process for the manufacturing of non-reinforced load carriers (1) of thermoplastic material. Sheet-shaped work pieces (2) and extended bar sections (3) are manufactured by means of an extruder. The work pieces (2) and bar sections (3) are allowed to cool and post-shrink after the manufacturing. An upper and a lower deck member (11 and 12 respectively) are molded in a number of molds comprising mold halves. A first mold contains shaping cavities being a negative representation of the upper deck member (11). A second mold gives shape to a lower deck member (12). The work pieces (2) are molded against each one cavity by means of vacuum and are pressed together while still hot whereby a hollow unit is formed. Skids (3′) are molded in a similar way. The parts are allowed to cool and post-shrink whereupon they are joined with each other via a number of joining areas (10).

Abstract: A multilayer optical body having improved dimensional stability is disclosed. The optical body includes an optical film, such as an oriented multilayer optical film, and a dimensionally stable layer, such as a transparent polycarbonate layer. In addition, in specific implementations, the invention includes an intermediate layer between the optical film and the dimensionally stable layer. Methods of making the optical body are also disclosed.

Abstract: A method of manufacturing articles utilizing a composite material having a high density of small particles such as microspheres in a matrix material is disclosed. In accordance with one aspect of the present invention, at least first and second layers of flanking material are disposed in a generally non-parallel relationship with respect to each other and then are pulled through a die. While the flanking material layers are being pulled through the die, a composite material is injected into a space defined between the at least first and second layers of flanking material. The composite material and the at least first and second layers of flanking material are heated as they pass through the die to cure the composite material and bond the at least two flanking material layers to the composite material, thereby forming a cured article.

Abstract: A method of reorienting directional features associated with manufacture of continuous fastener materials to produce products having such reoriented features, produces fastener products having an array of individual fastener elements extending from a sheet-form base, the fastener elements adapted to engage mating elements for releasable fastening. The method includes the steps of forming a continuous pre-form product having a planar base defining longitudinal edges and an array of fastener elements extending from the base; joining the longitudinal edges of the pre-form product to form a tube having a seam defined by the joined longitudinal edges; and severing the tube across the seam to form the fastener product with segments of seam extending between longitudinal edges of the fastener product. Various techniques for performing the method and various products taking unique advantage of these techniques are disclosed for providing novel fastener products.

Abstract: An economical, three-dimensional reusable plastic article that is resistant to damage and stress caused by a variety of factors is disclosed. The plastic article comprises a polycarbonate/polyester plastic blend, and optionally further comprises a plastic insert. The polycarbonate/polyester blend may be fused directly to the optional plastic insert. Alternatively, the polycarbonate/polyester blend may be tied to the optional plastic insert through the use of an adhesive layer and/or a tie layer.

Abstract: A process for producing an electrode assembly for an electric double layer capacitor having an electrode layer comprising a carbonaceous material and a first binder, formed on at least one side of a metal current collector foil, which comprises the following steps A to D: Step A: a step of coating an electroconductive adhesive comprising an electroconductive powder, a second binder and a solvent, on at least one side of a metal current collector foil; Step B: a step of drying the metal current collector foil coated with the electroconductive adhesive to remove at least a part of the solvent and to form an electroconductive bonding layer; Step C: a step of preparing a formed product of sheet shape comprising the carbonaceous material and the first binder; and Step D: a step of placing the formed product of sheet shape on the electroconductive bonding layer to form a laminate comprising the metal current collector foil and the formed product of sheet shape, and rolling the laminate to reduce the thickness o

Abstract: A method for producing a polyolefin stretched sheet which comprises extruding a polyolefin having a weight average molecular weight of 100,000 to 500,000 into a primary sheet, rolling the primary sheet at a rolling magnification of 5 or more, and stretching the rolled sheet into a polyolefin sheet which is totally stretched at a stretching magnification of 15 or more. The method can be employed for producing a polyolefin stretched sheet excellent in creep resistance, tensile strength and modulus in tension, with no use of a ultra-high molecular weight polyethylene and with excellent productivity.

Abstract: Provided is a water-decomposable absorbent article including an absorbent body that has a water-decomposable top sheet, a water-decomposable back sheet, a water-decomposable adsorbent core sandwiched between the top sheet and the back sheet, and an adhesive layer provided on the back sheet to fit the absorbent article to an external support; and a water-decomposable release sheet for protecting the adhesive layer before use with covering the adhesive layer. The release sheet includes a release layer that faces the adhesive layer, a water-decomposable fibrous layer, and a water-soluble polymer layer sandwiched between the release layer and the fibrous layer. A basis weight of the release layer is at least 0.05 g/m2 but smaller than 0.3 g/m2, and an equilibrium contact angle between a surface of the release layer and a water drop thereon is at least 100 degrees.

Abstract: An adhesive useful in making recyclable carpet is prepared from a copolymer dispersion and a filler. The copolymer dispersion is prepared in an emulsion polymerization of a mixture of monomers comprising styrene, butadiene, an alkylacrylic acid monomer, in which the alkyl radical of the alkylacrylic acid monomer is a C1 to C6 branched or unbranched hydrocarbyl radical, and a combination of a second ethylenically unsaturated monocarboxylic acid with an ethylenically unsaturated dicarboxylic acid, in which the alkylacrylic acid monomer is present in a quantity predominating the combination of the second ethylenically unsaturated monocarboxylic acid with the ethylenically unsaturated dicarboxylic acid. The adhesive can be completely removed from the face fibers by applied shear in the presence of aqueous alkaline solution. Recyclable carpets made with the adhesive exhibit high delamination strength, both when wet and when dry.

Abstract: Polyester-containing multilayer biaxially-oriented polypropylene films are provided. According to the invention, a two- or three-layer polyester-containing cap layer is bonded to a monoaxially oriented polypropylene core, followed by orientation of the resulting composite in a direction transverse to the direction of orientation of the core layer. At least one tie layer is interposed between the core and the polyester. Advantageously, the polyester contains silicone fluid as a processing aid.

Abstract: Laminates of thermoplastic films and nonwoven fibrous webs are made at high speeds on the order of about 700 fpm to about 1200 fpm. Bond strengths of film and nonwoven laminates are effectively controlled to make breathable laminates at high speeds. Air cooling devices cause the air to flow substantially parallel to the extruded plastic web during drawdown and provide a plurality of cooling air vortices to effectively cool the web. Film gauge control is also achieved by the method.

Abstract: A method for making a reclosable package. The method includes extruding a package body having first and second sides that face in opposite directions; extruding a pair of closure profiles adapted to be interconnected with one another; and extruding a pair of slider retaining shoulders adapted for retaining a slider on the package. The method also includes forming a precursor package structure by connecting the closure profiles and the retaining shoulders to the package body while the package body, the retaining shoulders and the closure profiles are in a molten state. As so connected, the closure profiles are positioned to project outward from the first side of the package body, and the retaining shoulders are positioned to project outward from the second side of the package body.

Abstract: A double sided tape for detachably mounting a flexible printing plate to a flexographic printing press cylinder includes pressure-sensitive adhesive layers on opposed sides of a coextruded multilayer carrier having a core formed of a thermoplastic elastomer containing a uniform distribution of voids and one or more skin layers formed of film-forming thermoplastic polymer. The cellular thermoplastic elastomer is constructed to accommodate compressibility loads imposed during printing and to resist shear and tensile loads imposed during tape removal.

Abstract: A method is provided for producing a unique printable multi-layer composite structural material, and in turn a unique scratch-resistant, self-laminated printed material. A printable multi-layer composite structural material is formed which includes a first underlying substrate capable of being transported through a printing device, a second layer formed on the first layer which is flowable when heated to at least it's melting point and being fusible below it's melting point, and a third layer formed on the second layer which is printable. The third layer is also permeable so that when the second layer is in a flowable state it permeates through and about said second layer.

Abstract: A heat shrinkable film suitable for use in cook-in applications is provided which exhibits a transverse direction free shrink at 50° C. of less than about 2% and a transverse direction free shrink at 57° C. of at least about 3%. The food contact layer includes a polymer having a surface energy of at least about 0.034 J/m2 and a second layer includes at least one member selected from the group consisting of polyester, polyvinylidene chloride, polyamide and polyalkylene carbonate. Preferably, the desired shrink properties are attained by annealing the film under controlled conditions.

Abstract: The present invention provides coextruded or laminated multilayer films having at least one layer of a halopolymer such as poly(chlorotrifluoro ethylene) (PCTFE), at least one layer of a naphthalene containing polymer such as poly(ethylene naphthalate) (PEN), and an intermediate adhesive layer. The invention further provides methods of producing oriented, multilayer films which comprise either coextruding or laminating at least one layer of a halopolymer to a surface of at least one layer of a naphthalene containing polymer by an intermediate adhesive layer. The multilayer film may be uniaxially or biaxially stretched, and an optional thermoplastic polymer layer may be attached to another surface of either the halopolymer layer, the naphthalene containing polymer layer, or both, by another intermediate adhesive layer.

Abstract: A continuous sheet having a three-dimensional pattern providing the optical functions is produced by the use of a release sheet of a curable resin on which the three-dimensional pattern is formed, a change in a surface-gloss of a layer of the release sheet on which the three-dimensional pattern is formed, is not more than 30% in pressing a hot plate heated to 160° C. under a force of 20 kg/cm2 for 3 seconds and the release sheet may be wound in a form of cylinder of not more than 12 inches in diameter. In accordance with the present invention, it is possible to enhance a degree of freedom of processing conditions and thermoplastic resins to be used and to produce a continuous sheet having high performance optical functions efficiently.

Abstract: The invention relates to a biaxially oriented polyester film which has three layers and which, together with very good electromagnetic properties compared with prior art films, has improved abrasion properties. The two sides of the film are built up from at least one base layer B and, applied to this base layer, outer layers A and C, where these outer layers have a defined number of elevations of defined height. The invention also relates to a process for producing the film and to its use as magnetic tape film.

Abstract: This invention relates to the extrusion coating of polyethylene terephthalate (PET) onto paperboard. Such structures of this type, generally, provide an enhanced film adhesion of the PET onto the paperboard, while reducing the coat weights of the PET.

Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer or a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 60% by weight of ethylene terephthalate units and/or units from cycloaliphatic or aromatic diols and/or dicarboxylic acids, with the proviso that the Tg2 value of the polyester film is above the Tg2 value of the base layer but below the Tg2 value of the outer layer, where the base layer comprises particles and the Ra value of at least one surface is between 1 and 1000. The film has low gas transmission. It is particularly suitable for packaging uses, specifically for packaging foodstuffs and other consumable items, or as magnetic tape film and as capacitor film.

Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer or a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 60% by weight of ethylene terephthalate units and/or units from aliphatic, cycloaliphatic, or aromatic diols and/or dicarboxylic acids, with the proviso that the base layer has a diethylene glycol content in the range from 0.9 to 3.0% by weight.

Abstract: The invention relates to a biaxially oriented polyester film which has very good optical properties and good processing behavior and which after it has been metallized or coated with oxidic materials exhibits a high oxygen barrier and which is built up from at least one base layer B and at least one layer A applied on top of this base layer, this layer A having a number N of elevations/protrusions per mm2 of film surface area which is related to their respective heights h and diameters d by the following equations: log N/mm2<Ah−Bh*log h/&mgr;m, 0.01 &mgr;m<h<10 &mgr;m  (1) wherein Ah=1.4; Bh=2.5 log N/mm2<Ad−Bd*log d/&mgr;m, 0.4 &mgr;m<d<10 &mgr;m  (2) wherein Ad=3.4; Bd=2.4.

Abstract: Process for producing a pressure-sensitive double-sided adhesive tape, in which a) a ready-made rubber-based backing material is introduced into a screw extruder, where 1. the backing material is heated by means of heating elements present on the screw extruder, 2. in a degassing zone, the backing material is freed from volatile constituents by means of the application of reduced pressure, 3.

Abstract: An integrated process for making an inflatable laminated article comprises extruding a first film and a second film, followed by cooling the first film and the second film so that the films will not fuse to one another upon contact with each other. The films are then brought into contact with one another, and selected portions of one or both films are heated so that the films are heat sealed to one another in a selected area having a desired pattern. The unsealed area between the film provides inflatable chambers between the first film and the second film. An alternative process utilizes a film tubing in lay-flat configuration to produce a laminated inflatable article.

Abstract: Products in the form of cushioning devices made from flexible membranes employing at least one layer including thermoplastic urethane and at least one layer of a copolymer of ethylene and vinyl alcohol are inflatable to a relatively high pressure. The cushioning devices maintain the internal inflatant pressure for extended periods of time by employing a phenomenon referred to in the industry as diffusion pumping. Ideally, the cushioning devices of the present invention can be permanently inflated with gases such as nitrogen or air.

Abstract: Processes and apparatus for manufacturing an engineered-composite combining rigid flat-rolled sheet metal continuous-strip and selected polyester thermoplastics, which are formed into distinct polymeric layers for melted extrusion deposition on a single surface, at a time, using pressure dies, and other steps, for forming a uniform coat of distinct polymeric layers, which provide high green-strength-adhesion during continuous-in-line travel; and including dual-surface finishing for complete bonding of the polymeric layers on both metallic surfaces.

Abstract: A biaxially oriented polyolefin film having more than one layer and made from a base layer and from at least one outer layer. The base layer include a fatty amide and the outer layer include at least 80% by weight of a linear olefin polymer. The film is suitable, for example, for producing a film laminate by melt extrusion of a polyethylene layer.

Abstract: Shaped elastomer portions are to be produced on an elastomer seal. For that purpose the shaped elastomer portions are provided with a thermoplastic layer, preferably by co-extrusion. The thermoplastic layer is converted into a molten state by heating. The shaped elastomer portions are then pressed against oppositely disposed regions of the elastomer seal and cooled until the thermoplastic layer has hardened again and a fixed bond has occurred on the one hand in relation to the shaped elastomer portions and on the other hand to the elastomer seal.

Abstract: A practically applicable plate-like body attached with a resin frame in which a thermoplastic elastomer is used as a resin material for the frame.

Abstract: This invention concerns a method and an installation for producing a spunbonded fabric, characterized in that it consists in: producing a spunbonded lap (5) against the surface of which is delivered at least a web (V1 and/or V2) of discontinuous fibers, obtained by carding. The formed complex is compacted by pressing and is continuously transferred onto a line (10) for water jet binding treatment, driving the fibers in the direction of thickness, the fibers which are bound together like a splice between and around the continuous filaments while remaining visible at the surface. After drying, the final product is obtained.

Abstract: Rollers, substrates, products and the like are not smeared with a sticky volatile component when a gas is blown from a blower provided near an extruding die to produce laminates. The blower is heated by a heater at a temperature not below the volatilization temperature of the volatile component volatilized from a resin film of thermoplastic resin extruded in molten conditions from the extruding die, and therefore the volatile component cannot stick on the blower and is immediately volatilized on the blower.

Abstract: The present invention pertains to carpet and method of making it. In one aspect, the carpet includes (a) a primary backing which has a face and a back surface, (b) a plurality of fibers attached to the primary backing and extending from the face of the primary backing and exposed at the back surface of the primary backing, (c) an adhesive backing, (d) an optional secondary backing adjacent to the adhesive backing, and (e) at least one homogeneously branched linear ethylene polymer. The method includes extrusion coating at least one homogeneously branched linear ethylene polymer onto the back surface of a primary backing to provide an adhesive backing. The method can include additional steps or procedures, either separately or in various combinations.

Abstract: A process for the preparation of a pourous composite product. The process steps are forming a homogeneous mixture having one or more insoluble polymers, one or more soluble or calcinable polymers and one or more fillers, in particular with a high specific surface; extruding the mixture to form an extruded precursor product; removing the soluble or calcinable polymer or polymers from the extruded precursor product, in order to form pores, and recovering the pourous composite product.

Abstract: A body ply (12) comprising an elastomeric sheet (30) and a plurality of rows of reinforcement cords (32) embedded therein. The plurality of rows can comprise two parallel rows (32a, 32b) of reinforcement cords and the reinforcement cords in one row can be transversely staggered relative to the reinforcement cords in an adjacent row. To make the body ply (12), the reinforcement cords (32) are introduced into a die assembly (44) and rubber is extruded around and between the reinforcement cords. Existing equipment, namely an extrusion apparatus (40) conventionally used to manufacture steel belts or single layer body ply material, can be used to make the body ply material by providing an appropriate replacement insert (56) for its die assembly.

Abstract: The present invention relates to a method of manufacturing a part made of a composite material comprising reinforcing fibers embedded in a matrix made of a polymerizable and/or crosslinkable material, wherein:

Abstract: A method for manufacturing an optical device is disclosed. The method includes coating a substrate with a resin thin layer, wherein temperature of the resin thin layer is controlled lower than a polymerization reaction starting temperature thereof and the resin is not substantially polymerized, heating the resin thin layer to a temperature higher than polymerization reaction starting temperature and glass-transition temperature but lower than a thermal decomposition starting temperature of the resin so that the resin thin layer is polymerized on the substrate to form a resin thin film thereon, pressing a stamp having an inverted micro-asperity pattern against the resin thin film such that a micro-asperity pattern is formed on a surface of the resin thin film; cooling the resin thin film to a temperature lower than the glass-transition temperature; and separating the stamp from the resin thin film.

Abstract: The present invention provides for a method of manufacturing a preform for a RTM molding process that will increase both the handling capability of the preform and the final part quality. The invention consists of applying a patterned discontinuous layer of liquid resin over at least one side of a layer of reinforcing fibers. The resin film can consist of a homogeneous liquid, an aqueous dispersion or a melted resin applied at an elevated temperature. In one embodiment, there is present a roller having a patterned surface. Liquid resin is applied to the surface of the patterned roller via a second roller. The layer of reinforcing fibers is passed by the roller in such a fashion that the resin from the pattern on the surface of the roller is transferred to the layer of reinforcing fibers. The contact of the roller with the layer of reinforcing fibers is sufficient to force some of the resin into the fibers themselves.

Abstract: Laminates of thermoplastic films and nonwoven fibrous webs are made at high speeds on the order of about 700 fpm to about 1200 fpm. Bond strengths of film and nonwoven laminates are effectively controlled to make breathable laminates at high speeds. Air cooling devices cause the air to flow substantially parallel to the extruded plastic web during drawdown and provide a plurality of cooling air vortices to effectively cool the web. Film gauge control is also achieved by the method.

Abstract: In the invention, a method is provided for producing a composite nonwoven fabric. A polymer is extruded into heated continuous filaments, possibly elastic, from the die head to a first chilled roller, wherein the extruder is configured to provide the continuous filaments to the chilled roller in a canted direction that is at a tangent or angle to the surface of the first chilled roller. The filaments are conveyed in a downward direction by way of chilled rollers to a nip. In a next step, the nonwoven web is sprayed with an adhesive and is laminated on the continuous filaments in the nip to form a composite nonwoven fabric. The continuous filaments move vertically downward approximately in line with the lamination process, facilitating automatic re-threading of filaments when they are broken or interrupted in their travel downward onto the chilled rolls.

Abstract: A laminate having a metal reinforcement and a bonding veneer is disclosed, wherein the bonding veneer is a peroxide cured rubber including at least one of a polybutadiene and (meth)acrylate. A feature layer is formed on the bonding veneer and can be any of a variety of cross-linkable materials such as EPDM and EPM.

Abstract: A composition containing thermoplastic elastomer and elastic fine particles is extruded into a sheet-like shape from an extruder. Then, by expanding this sheet-like shape member, a covering sheet having minute unevenness attributable to the elastic fine particles formed on the surface is produced. The covering sheet may have an adhesive layer, a substrate layer, a foamed resin layer, etc., on the opposite side to the surface having a matt feeling. Such covering sheet can be produced with good productivity without creating environmental problems such as a problem related to solvent, etc. By molding using the covering sheet, a molding having matt feeling can be obtained.

Abstract: Robust homofilament fibers are meltspun from a differently shaped dual capillary spinneret design to induce differential fiber morphology to produce crimping. Crimping may further be aided by quenching and drawing of the fibers.

Abstract: Methods for forming a thermoplastic film with an attached closure strip are disclosed. The film can be used to produce zippered reclosable plastic bags. The methods include providing a thermoplastic film web having a sealing surface and a closure strip having a binding surface, both being in a non-melted condition. The film web and the closure strip are aligned in non-overlapping relationship and a heated thermoplastic binder layer is positioned on the film web sealing surface and on the closure strip binding surface quickly after extrusion. The hot binder layer transfers enough heat to the closure strip and to the film web to melt the closure strip binding surface and the film web sealing surface. Pressure is applied to seal the closure strip to the film web. An apparatus for practicing the method and a reclosable bag formed from the thermoplastic film with attached closure strips are also disclosed.

Abstract: A method of manufacturing a laminated thermoplastic resin sheet having an improved transparency without generating a wrinkle and an apparatus therefor are provided. The laminated thermoplastic resin sheet is manufactured by using an apparatus including an endless belt wound between a first cooling roll having an elastic material, a second cooling roll and a third cooling roll brought into contact with the first cooling roll through the belt, arranging a guide roll near the first roll so as to introduce a molten thermoplastic resin sheet between the first and third cooling rolls in such a manner as to be brought into contact with the belt and the third cooling roll substantially at the same time, and introducing a thermoplastic resin film between the belt and the third cooling roll via the guide roll.

Abstract: The invention relates to a film made of plastic having at least one mineral additive, wherein capillaries are formed through expansion at phase transition limits between the plastic and the mineral additives. Said film forms a laminate in conjunction with a plastic non-woven fabric, the laminate remaining in an expanded state. The plastic film and non-woven fabric materials display the same or substantially similar plastic expansion characteristics.

Abstract: A joint to be adhered to nylon resin moldings is disclosed, which comprises a copolymerized nylon or a composition comprising a copolymerized nylon or a copolymerized nylon blend and at least one of a nucleating agent and a lubricant. A method for adhering nylon resin moldings is also disclosed, which comprises adhering nylon resin moldings to the joint using a solvent adhesive. The joint and the solvent adhesive enable formation of an effective adhesive layer.

Abstract: The fuel hose of this invention is a fuel hose comprising a tubular fluororesin inner ply and, as laminated onto the peripheral surface thereof, a thermoplastic resin or rubber outer ply, the tubular fluororesin inner ply having been molded from a fluororesin with an F/C ratio, i.e. ratio of the number of fluorine atoms (F) to the number of carbon atoms (C), of not greater than 1.6 and the peripheral surface layer of the fluororesin inner ply having been modified into the following treated layer (A). (A) a layer with a distribution of oxygen atoms and having an F/C ratio, i.e. ratio of the number of fluorine atoms (F) to the number of carbon atoms (C), of not greater than 1.12 and an O/C ratio, i.e. ratio of the number of oxygen atoms (O) to the number of carbon atoms (C), of not less than 0.08.