With Carbohydrate And/or Protein Or Derivatives Thereof Patents (Class 156/328)
  • Publication number: 20080292886
    Abstract: Compositions suitable for use as wood adhesives are described, which compositions comprise: (a) a polymeric component selected from the group consisting of lignins, proteins, and mixtures thereof, (b) an adhesion promoter comprising at least one component selected from the group consisting of (i) adducts of an epoxide and a resin selected from the group consisting of polyamine resins, polyamidoamine resins, polyamide resins, and combinations thereof, and (ii) combinations of a curing agent and a compound having at least one amine, amide, imine, imide, or nitrogen-containing heterocyclic functional group capable of reacting with at least one functional group of the polymeric component; and (c) an additive selected from the group consisting of urea, N-substituted ureas, N,N-disubstituted ureas, N,N?-disubstituted ureas, N,N,N?-trisubstituted ureas, N,N,N?,N?-tetrasubstituted ureas, urea derivatives, and mixtures thereof.
    Type: Application
    Filed: March 19, 2008
    Publication date: November 27, 2008
    Applicant: Hercules Inc.
    Inventors: Anthony J. Allen, Richard J. Riehle, Joseph Marcinko
  • Publication number: 20080213597
    Abstract: A first variant of an adhesive composition for making a lignocellulosic composite includes soy protein and/or lignin; at least one substantially formaldehyde-free curing agent that includes at least one amine, amide, imine, imide, or nitrogen-containing heterocyclic functional group that can react with at least one functional group of the soy protein; and at least one compound selected from a boron compound, a group IA oxide or hydroxide, or a group IIA oxide or hydroxide. A second variant of an adhesive composition includes a first component selected from soy protein and/or lignin; and at least one substantially formaldehyde-free curing agent selected from a reaction product of epichlorohydrin with ethylenediamine, a reaction product of epichlorohydrin with bis-hexamethylenetriamine, or a reaction product of epichlorohydrin with hexamethylenediamine.
    Type: Application
    Filed: January 19, 2005
    Publication date: September 4, 2008
    Inventor: Kaichang Li
  • Publication number: 20070277928
    Abstract: The invention relates to an adhesive system comprising a protein and one or more polymers containing acetoacetoxy groups. It also relates to a method of producing a laminated wood based product and a particle board.
    Type: Application
    Filed: May 25, 2007
    Publication date: December 6, 2007
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventor: Farideh Khabbaz
  • Patent number: 7244509
    Abstract: Hydrogenated triglycerides having melting temperature above about 50° C. are substituted for paraffin as a coating material for the surface of paper products and the resulting paper products have improved wet strength and moisture resistance in addition to being repulpable thereby providing a distinct environmental advantage over paraffin coated products.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: July 17, 2007
    Inventor: Scott O. Seydel
  • Publication number: 20040102546
    Abstract: A corrugating adhesive that improves the bonding of coated papers, including latex coated medium and linerboards. The corrugating adhesive may comprise a hydrocolloid portion of the adhesive that improves tack and bonding and buffers and absorbs caustic in the adhesive allowing higher caustic in the adhesive formula without premature gelling of the secondary starch portion. Also, methods for making waterproof or water resistant corrugated board from corrugated media and paper liner.
    Type: Application
    Filed: November 22, 2002
    Publication date: May 27, 2004
    Inventors: Roman Skuratowicz, James Linder, Bryan Turner
  • Publication number: 20030145937
    Abstract: A toilet training article in the form of a toilet training pad containing an effervescent agent is disclosed. The toilet training pad, which may be an insertable pad or integrated directly into an undergarment, contains an effervescent agent which releases gas upon being contacted by urine. The effervescent agent may be in the form of a compound containing a substantially inert gas, or may be a combination of compounds that, upon being contacted by urine, produce a gas.
    Type: Application
    Filed: March 6, 2003
    Publication date: August 7, 2003
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard L. Underhill, Marsha M. Malone, Bernard J. Minerath, Beth A. Lange, Duane G. Krzysik, David W. Koenig, Kimberly M. Bleck
  • Publication number: 20030102080
    Abstract: This invention discloses a method for labeling an item wherein a sheet of polymer film is adhered to the item with a layer of water-based adhesive. The invention also discloses a label that includes a sheet of polymer film and a water-based adhesive, and a package that includes an item and a label adhered to the item. The item can be a product container such as a beverage bottle. The polymer film has a water vapor transmission rate of at least about 100 gm/m2/24 hours, and is also less than about 10,000 gm/m2/24 hours. The polymer film is also ink receptive to printing. A particularly suitable polymer film is polylactide (PLA) polymer 4040D. The sheet of polymer film has a thickness from about 0.001 to about 0.003 inches and is substantially transparent. The water-based adhesive can be a natural or synthetic adhesive, and can further include a contact sublayer and a tie sublayer.
    Type: Application
    Filed: September 20, 2002
    Publication date: June 5, 2003
    Inventor: Donald W. Mallik
  • Patent number: 6517664
    Abstract: The invention provides a method for labeling a glass, plastic or metal container or surface with a polymeric label by means of a water based adhesive composition by the following steps: (a) selecting a polymeric label having a density of less than 0.9; (b) applying a water based adhesive to said polymeric label to form a fastenable polymeric label; (c) fastening said fastenable polymeric label to a glass, plastic or metal container or surface; and (d) allowing said polymeric label to dry on said glass, plastic or metal surface or container.
    Type: Grant
    Filed: January 10, 2000
    Date of Patent: February 11, 2003
    Assignee: Process Resources Corporation
    Inventor: Peter J. Dronzek, Jr.
  • Publication number: 20020134502
    Abstract: The invention provides a process for laminating textile sheet materials onto moldable foam or onto foamed moldings, using, as an adhesive, a polymer preparation based on copolymers of one or more monomers selected from the group comprising vinyl esters, acrylates, methacrylates, vinylaromatics and vinyl chloride and from 0.01 to 25% by weight, based on the total weight of the copolymer, of one or more ethylenically unsaturated monomers containing carboxyl groups.
    Type: Application
    Filed: May 23, 2002
    Publication date: September 26, 2002
    Applicant: Wacker Polymer System GmbH & Co. KG
    Inventors: Klaus Kolhammer, Claudia Schmidt, Abdulmajid Hashemzadeh, Doris Bauer
  • Publication number: 20020112805
    Abstract: The invention provides, in a first embodiment, a blocking wax composition. The blocking wax comprises from about 50 to about 90 weight percent of a water-soluble continuous phase and from about 10 to about 50 weight percent of a discontinuous solid phase filler that is substantially inert to the continuous phase. The invention further provides a method for mounting a contact lens blank for machining.
    Type: Application
    Filed: December 19, 2000
    Publication date: August 22, 2002
    Inventors: James A. Bonafini, Anthony D. Parrinello, Peter J. Tinios
  • Patent number: 6368443
    Abstract: Starch-based corrugating adhesives of the carrier, no-carrier and carrier-no-carrier type having improved green strength and water resistance are prepared by adding hemicellulose to the adhesive composition. When the adhesive is the carrier type or the carrier-no-carrier type, the hemicellulose can be extracted from corn fiber in situ during the process of preparing the carrier phase.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: April 9, 2002
    Assignee: Corn Products International, Inc.
    Inventors: Larry E. Fitt, James J. Pienkowski, Jack R. Wallace
  • Patent number: 6329468
    Abstract: A flexible polyolefin-based hot melt adhesive composition having a variety of end uses, particularly in bonding polyethylene and polypropylene films, nonwoven fabrics and elastic attachment applications in nonwoven disposable articles. The composition includes a flexible polyolefin polymer or a blend of flexible polyolefin polymers, a tackifier resin, a plasticizer, and optionally a wax and a stabilizer. The preferred flexible polyolefin polymer has a melt flow rate greater than 5 g/10 min. and a density between 0.86 to 0.90 g/cm3. The hot melt adhesive composition provides a novel combination of desirable properties including good adhesion to a variety of substrates, low viscosity, good heat stability and oil resistance. The adhesive can be applied using common application techniques such as extruding or spraying.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: December 11, 2001
    Assignee: Bostik Findley, Inc.
    Inventor: Baoyu Wang
  • Patent number: 6287412
    Abstract: Corrugating adhesives of the carrier, no-carrier and carrier-no-carrier type having excellent dry pin adhesion, green strength and improved water resistance are prepared with solubilized fiber as a complete or partial substitute for starch. The adhesive composition contains solubilized fiber and, optionally, from about 0.1% to about 99% added starch by weight based on total solubilized fiber and added starch. When the adhesive is the carrier type or the carrier-no-carrier type, the fiber, preferably corn fiber, can be solubilized in situ during the process of preparing the carrier phase.
    Type: Grant
    Filed: April 14, 1994
    Date of Patent: September 11, 2001
    Assignee: CPC International, Inc.
    Inventors: J. E. Todd Giesfeldt, Larry E. Fitt, James J. Pienkowski, Jack R. Wallace
  • Patent number: 6239190
    Abstract: There is disclosed a method for effecting a reaction by irradiating a substance which absorbs the radiant energy until the reaction is complete and the absorbency of the material changes so as to reduce or cease absorption of further radiant energy.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: May 29, 2001
    Assignee: Tissuemed Limited
    Inventors: Francis Wilkinson, David John Mandley
  • Patent number: 6238509
    Abstract: The invention relates to an adhesive system for labeling containers, more especially hollow containers, with wrap-around labels. The adhesive system comprises a pick-up adhesive and an overlap adhesive. It is characterized in that, in the wet state, the pick-up adhesive has sufficient wet bond strength for labeling and, in the dried state, does not adhere to at least one of the substrates. The pickup adhesive contains 5 to 85% by weight and preferably 5 to 60% by weight of at least one water-soluble polymer based on casein, starch, dextrin, glucose, polyvinyl alcohol, polyurethane or polyacrylic acid, 0.00 to 1.00% by weight and preferably 0.01 to 0.30% by weight of at least one defoamer, 0.00 to 1.00% by weight and preferably 0.01 to 0.30% by weight of at least one preservative and water as the balance to 100% by weight.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: May 29, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Herlfterkamp, Hermann Onusseit, Horst Buxhofer, Ludwig Broich, Ralf Grauel, Jan Auris
  • Patent number: 6156345
    Abstract: A crosslinkable macromer system that includes two or more polymer-pendent polymerizable groups and one or more polymer-pendent initiator groups. The polymerizable groups and the initiator group(s) can be pendent on the same or different polymeric backbones. The macromer system provides advantages over the use of polymerizable macromers and separate, low molecular weight initiators, including advantages with respect to such properties as nontoxicity, efficiency, and solubility.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: December 5, 2000
    Assignee: SurModics, Inc.
    Inventors: Stephen J. Chudzik, Aron B. Anderson
  • Patent number: 6007833
    Abstract: A crosslinkable macromer system that includes two or more polymer-pendent polymerizable groups and one or more polymer-pendent initiator groups. The polymerizable groups and the initiator group(s) can be pendent on the same or different polymeric backbones. The macromer system provides advantages over the use of polymerizable macromers and separate, low molecular weight initiators, including advantages with respect to such properties as nontoxicity, efficiency, and solubility.
    Type: Grant
    Filed: July 23, 1998
    Date of Patent: December 28, 1999
    Assignee: SurModics, Inc.
    Inventors: Stephen J. Chudzik, Aron B. Anderson
  • Patent number: 5958558
    Abstract: Carrier-type corrugating adhesives are prepared using a carrier phase comprising a combination of tapioca fiber and corn fiber or tapioca fiber and spent germ flake as a substitute for modified or unmodified corn starch to provide an adhesive composition.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: September 28, 1999
    Assignee: CPC International Inc.
    Inventors: J. E. Todd Giesfeldt, Jack R. Wallace
  • Patent number: 5958170
    Abstract: The present invention relates to a method of engraving objects which circumvents the necessity of mechanically scrubbing the engraved surface to remove fillers. Specifically, in the method of the present invention, the fillers are applied directly to the resist stencil instead of being applied to the object to be engraved. Removal of the resist stencil simultaneously removes the filler from the engraved object.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: September 28, 1999
    Assignee: Design Services, Inc.
    Inventor: David Cetrangolo
  • Patent number: 5932298
    Abstract: Methods for preparing viscoelastic compositions (e.g., adhesives such as hot melt adhesives) in which a pre-viscoelastic composition (e.g., a pre-adhesive composition) is combined with a packaging material and then polymerized.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: August 3, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John D. Moon
  • Patent number: 5885266
    Abstract: An absorbent article such as a diaper, an incontinence guard or a sanitary napkin includes a liquid-permeable outer sheet, a liquid-impermeable bottom sheet and an absorbent body placed therebetween. The outer sheet and the absorbent body are at least partially joined together with a hydrophilic glue.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: March 23, 1999
    Assignee: SCA Molnlycke AB
    Inventors: Thami Chihani, Anders Silfverstrand
  • Patent number: 5866247
    Abstract: An insulator material made from rice husks is provided for producing a bulk insulator, characterized by a density in the range from 200 through 250 kg/m.sup.3 in the packaged condition. A method for the manufacture of insulator material from rice husks as well as method for producing a bulk insulator from rice husks are also provided.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: February 2, 1999
    Assignee: Frank Ziech
    Inventors: Carsten Klatt, Frank Ziech
  • Patent number: 5795420
    Abstract: A method of applying a finishing sheet to a substrate, such as a body part of a scooter or motorcycle which includes the steps of printing a graphic design on that side of a transparent finishing sheet which is to face towards the substrate on which it is applied and applying a film adhesive to the side of the sheet on which the graphic design is printed. The method also includes applying the finishing sheet to the substrate by thermo-vacuum forming; during this forming, the sheet is heated to soften the sheet, to melt the adhesive and to rewet the ink used to print the graphic. The thermoformed finishing sheet is trimmed along the perimeter of the substrate.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: August 18, 1998
    Assignee: Wintune Graphics, Inc.
    Inventor: Everett W. English
  • Patent number: 5733868
    Abstract: A composition and method for repairing damaged connective tissue is provided. The composition comprises pseudo-poly(amino acids) and/or classic poly(amino acids) that exhibit adhesiveness for connective tissues. The composition is formed into an adhesive tissue repair implant and pressed against the damaged tissue to adhere the adhesive composition to the tissue.
    Type: Grant
    Filed: April 16, 1996
    Date of Patent: March 31, 1998
    Assignee: DePuy Orthopaedics, Inc.
    Inventors: Dale R. Peterson, Samuel I. Stupp
  • Patent number: 5639333
    Abstract: Corrugating adhesives free of incompatibility problems with water soluble partially hydrolized polyvinyl alcohol comprise a major portion of water, starch, strong base, a boric acid compound and a partially hydrolized water soluble polyvinyl alcohol composition.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: June 17, 1997
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventor: Paul L. Krankkala
  • Patent number: 5593625
    Abstract: Fiber-reinforced protein-based biocomposite particulate material containing a legume-based thermosetting resin and cellulosic material, and rigid biocomposite pressure-formed materials produced therefrom, are provided. The particulate material and resultant pressure-formed materials contain the legume-based resin and fibrous cellulosic material in amounts such that the ratio of cellulose solids to resin solids is about 0.8:1.0 to about 1.5:1.0. Particularly preferred pressure-formed materials also include a secondary thermosetting binder, such as an isocyanate.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: January 14, 1997
    Assignee: Phenix Biocomposites, Inc.
    Inventors: Michael J. Riebel, Paul L. Torgusen, Kenneth D. Roos, Donald E. Anderson, Carl Gruber
  • Patent number: 5589528
    Abstract: A water-soluble, biodegradable, repulpable, waterbearing colloidal hydrogel material manufactured from a mixture of natural organic materials, water and additives which is capable of being heated and applied with hot melt glue application equipment for use in paper bag sealing, corrugated and paperboard carton closure, and fishing lures.
    Type: Grant
    Filed: February 7, 1996
    Date of Patent: December 31, 1996
    Inventor: Lawrence S. Bogardy
  • Patent number: 5454898
    Abstract: Corrugating adhesives free of incompatibility problems with water soluble partially hydrolized polyvinyl alcohol comprise a major portion of water, starch, strong base, a boric acid compound and a partially hydrolized water soluble polyvinyl alcohol composition.
    Type: Grant
    Filed: October 6, 1989
    Date of Patent: October 3, 1995
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventor: Paul L. Krankkala
  • Patent number: 5344484
    Abstract: An isocyanate bonded wood composite, such as a doorskin, comprising about 95% to about 99% by weight wood fiber, about 1% to about 4% by weight of an organic isocyanate and 0% to about 2% by weight of a wax, and its method of manufacture, are disclosed. The isocyanate bonded wood composite is manufactured by admixing the ingredients, then pressing the admixed ingredients at a temperature of about 200.degree. F. to about 320.degree. F., for a sufficient time and at a sufficient pressure, to provide an isocyanate bonded wood composite having a density of about 0.9 g/cc to about 1.1 g/cc, and that demonstrates improved porosity and adhesive properties.
    Type: Grant
    Filed: October 8, 1992
    Date of Patent: September 6, 1994
    Assignee: Masonite Corporation
    Inventor: John P. Walsh
  • Patent number: 5247066
    Abstract: A crosslinking additive for imparting water resistance to starch-based alkaline corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of from 2 to 5 moles of formaldehyde per mole of acetone. The condensate is thereafter treated with from 1.0 to 2.0 moles of hydrogen peroxide per mole of unreacted formaldehyde which oxidizes the residual formaldehyde to formic acid. The treated crosslinking additive will contain less than 0.4% unreacted formaldehyde and may be added directly to a starch-based corrugating adhesive.
    Type: Grant
    Filed: August 29, 1991
    Date of Patent: September 21, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Jules E. Schoenberg, Michael Foran
  • Patent number: 5197973
    Abstract: This invention pertains to a synthetic adhesive composition for use in aqueous environments. The composition comprises polypeptide chains having an .alpha.-helical structure in aqueous environments and capable of cohesive and adhesive interactions. The polypeptide chains comprise polar and apolar amino acids, the apolar and polar amino acids being arranged to define apolar and polar vertical spiraling stripes on the helix surface. The apolar stripes allow the polypeptide chains to aggregate into superhelical structures and the polar stripes allow interchain crosslinking within and between the superhelical structures.
    Type: Grant
    Filed: December 14, 1990
    Date of Patent: March 30, 1993
    Assignee: Creative BioMolecules, Inc.
    Inventors: Roy H. L. Pang, Charles M. Cohen, Peter C. Keck
  • Patent number: 5181959
    Abstract: The present invention relates to a high-concentration starch adhesive prepared by treating a starch slurry at a temperature of 100.degree. C. or above to form a gelatinized solution and suspending an ungelatinized starch in the gelatinized solution. According to the present invention, the viscosity of the starch adhesive can be kept stable over a long period of time; the problems such as warp due to the expansion and contraction, by the absorption of water, of the material to be adhered, can be solved; and the quantity of heat necessitated in the adhesion step can be much reduced.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: January 26, 1993
    Assignee: Honshu Paper Co., Ltd.
    Inventors: Shigeki Nagai, Haruo Sato, Nagahisa Karube
  • Patent number: 5179141
    Abstract: A latex adhesive made from a polymer such as a ethylene/vinyl acetate or styrene/butadiene copolymer, a low-boiling alcohol, such as isopropanol, a non-crystallizing polyhydric alcohol such as sorbitol, and preferably a cellulose thickener. The latex adhesive dries so quickly that an adhesively edge-padded stack of paper sheets formed using the adhesive can be cut by hand into tablets within about 30 minutes. These tablets do not leave an upstanding ridge of adhesive when a number of the sheets are torn off.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: January 12, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Clair J. Emery, Kenneth J. Perrington
  • Patent number: 5130353
    Abstract: A process for incorporating by thermal diffusion a photochromic substance into a synthetic organic host material is described. In the process, a surface of the host material containing a coating of a resin composition of from about 5 to about 50 parts of hydroxy (C.sub.2 -C.sub.3) alkyl cellulose, e.g., hydroxy propyl cellulose, and from about 95 to about 50 parts of poly(vinylpyrrolidone), which resin composition contains a photochromic substance, is heated to diffuse at least a portion of the photochromic substance into the surface of the host material. Subsequently, the coating is removed by washing with warm soapy water. In a particular embodiment, the host material is a polymer prepared from diethylene glycol bis(allyl carbonate).
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: July 14, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Scott Fischer, Cletus N. Welch
  • Patent number: 5093393
    Abstract: A starch-based corrugating adhesive providing a controlled rate of viscosity increase and green bond formation comprising water, starch, caustic alkali, an active boron source, and polyvinyl alcohol having an intermediate degree of hydrolysis (about 92% to 98%), wherein the polyvinyl alcohol constituent imparts a definite increase in the rate of viscosity building of the adhesive, the rate of viscosity increase being controlled to provide an effective green bond and final adhesive bond on a corrugated board surface.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: March 3, 1992
    Assignee: H. B. Fuller Company
    Inventors: John A. Faber, Paul L. Krankkala
  • Patent number: 5057591
    Abstract: The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.
    Type: Grant
    Filed: August 25, 1988
    Date of Patent: October 15, 1991
    Assignee: Borden, Inc.
    Inventors: William D. Detlefsen, Lewis D. Creel, Lee R. Johnson
  • Patent number: 5055503
    Abstract: A water resistant, starch-based alkaline corrugating adhesive which includes a polysaccharide graft copolymer containing a reactive aminoethyl halide group.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: October 8, 1991
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Craig H. Leake, John J. Tsai, Eric A. Meier
  • Patent number: 4972018
    Abstract: An adhesive of starch, an ammonium-based latex and ammonium zirconium carbonate improves the hot, green bond properties of the adhesive formulation for paperboard and corrugated board. The latexes are typical styrene-butadiene and carboxylated styrene-butadiene latexes but untypically are polymerized in the presence of a volatile base such as ammonium hydroxide.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: November 20, 1990
    Assignee: The Dow Chemical Company
    Inventor: Arthur N. Leadbetter
  • Patent number: 4963604
    Abstract: A polymeric or plastic pigment, useful as a partial replacement for the inorganic pigment conventionally employed in paper coating compositions is disclosed. The pigment comprises a copolymer of an animal or vegetable protein and a monomer havingh a glass transition temperature (Tg) greater than about 70.degree. C. polymerized in a surfactant free system. When employed in paper coating compositions the pigment provides a coating of improved gloss and ink holdout, as compared to a coating in which the pigment composition consists only of an inorganic material. Improved water resistance, improved water holding and a potential for reduction in the coating sticking to the calender during the paper finishing process are obtained as compared to conventional polymeric pigments.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: October 16, 1990
    Assignee: Protein Technologies International, Inc.
    Inventors: Charles E. Coco, Lawrence M. Scacciaferro
  • Patent number: 4933383
    Abstract: Corrugating adhesives free of incompatibility problems with a fully hydrolyzed polyvinyl alcohol comprise a major portion of water, starch, strong base, a boric acid compound and a fully hydrolyzed water soluble polyvinyl alcohol composition.
    Type: Grant
    Filed: January 10, 1989
    Date of Patent: June 12, 1990
    Assignee: H. B. Fuller Company
    Inventors: Thomas O. Murdock, Paul L. Krankkala
  • Patent number: 4890444
    Abstract: A fluted filter media to end cap bonding process and fluid filters formed by the bonding process. The process comprises coating at least one end cap and/or at least one fluted edge of the filter media with a bonding composition, contacting the end cap with the edge of the fluted filter media and curing the bonding composition coating to form a strong, continuous filter media to end cap bond. The bonding composition comprises, in adhesive latex, a thermoplastic resin and an amount of ungelatinized granular starch effective to complex a major portion of the latex water during curing of the bonding composition.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: January 2, 1990
    Assignee: H. B. Fuller Company
    Inventors: Michael J. Vander Giessen, Robert M. Hume, III, Leonard C. Jannusch
  • Patent number: 4880702
    Abstract: A composition for stabilizing a denture in the form of a thin strip consisting of three layers, piled up one over another, which composition is characterized in that:(a) a swelling ability and solubility of outside layers are higher than those of an inside layer,(b) the swelled outside layers have an ability to adhere to gums and a denture base,(c) the inside layer has a self-supporting ability and a shape-retaining ability for the outside layers, and(d) the inside layer has an ability to adhere to the gums and the denture base after the outside layers have flowed away through dissolution.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: November 14, 1989
    Assignee: Shionogi & Co., Ltd.
    Inventors: Morio Homan, Nizo Sugie, Masakiyo Yoshimura, Yoshikazu Shirakawa
  • Patent number: 4855354
    Abstract: The invention relates to a curable aldehyde resin and starch composition useful as a saturant and laminating adhesive for paperboard products, including dual arch corrugated cardboard. The aldehyde resin to starch ratio is from approximately 7:5 to 5:1 by weight. By the present invention is produced corrugated paperboard which has substantially improved crush strength over that obtained with polyvinyl acetate adhesives, and higher moisture resistance than either polyvinyl acetate or starch adhesives.
    Type: Grant
    Filed: January 7, 1988
    Date of Patent: August 8, 1989
    Assignee: Borden, Inc.
    Inventors: Paul J. Mohler, Thomas A. Romz, Baird E. Lithgow
  • Patent number: 4855002
    Abstract: Polymerizable acrylic monomer adhesive systems comprising thirty to eighty percent by weight powdered aluminum filler material are disclosed. More specifically, the adhesive compositions comprise at least one polymerizable acrylate monomer system; an effective amount for initiation of a free radical initiator; and elemental (atomized) aluminum metal powder or powdered alumina.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: August 8, 1989
    Assignee: Loctite Corporation
    Inventors: David J. Dunn, Patrick P. Vano, James P. Moran, Jr., Mark Holmes, Elliott Frauenglass
  • Patent number: 4828643
    Abstract: A method of manufacturing a liquified fiber-phenol-formaldehyde resin includes heating a mixture of phenol, formaldehyde, liquified cellulosic fiber and alkali at a temperature of 60.degree. C. to 100.degree. C. and a pH of 8-13. The liquified cellulosic fiber comprises about 5 to about 80 percent of the total weight of phenol, formaldehyde and liquified fiber. Also disclosed are fibrous articles manufactured using this resin as a binder, such as fiberboards, particle board, plywood, oriented strand board, and waferboard.
    Type: Grant
    Filed: January 12, 1987
    Date of Patent: May 9, 1989
    Assignee: Masonite Corporation
    Inventors: William Newman, Michael E. Rakauskas
  • Patent number: 4826719
    Abstract: Corrugating adhesive free of incompatibility problems with a fully hydrolyzed polyvinyl alcohol comprise a major portion of water, starch, strong base, a boric acid compound and a fully hydrolyzed water soluble polyvinyl alcohol composition.
    Type: Grant
    Filed: July 15, 1986
    Date of Patent: May 2, 1989
    Assignee: H. B. Fuller Company
    Inventors: Thomas O. Murdock, Paul L. Krankkala
  • Patent number: 4814039
    Abstract: Resin shock, the unwanted viscosity increase caused by the addition of certain reactive resins to boron containing alkaline starch-based corrugated board adhesives, can be reduced by the presence of compounds containing hydroxyl groups.
    Type: Grant
    Filed: October 2, 1987
    Date of Patent: March 21, 1989
    Assignee: H. B. Fuller Company
    Inventor: Stephen M. Willging
  • Patent number: 4812496
    Abstract: An adhesive of starch and an ammonium-based latex improves wet-pin adhesion for paperboard and corrugated board. The latexes are typical styrene-butadiene and carboxylated styrene-butadiene latexes but untypically are polymerized in the presence of a volatile base such as ammonium hydroxide.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: March 14, 1989
    Assignee: The Dow Chemical Company
    Inventors: Arthur N. Leadbetter, James G. Galloway
  • Patent number: 4801631
    Abstract: This invention relates to formaldehyde-free, aqueous glue dispersions which contain polyisocyanates. These systems are particularly suitable for gluing veneers and surface materials on wood and wood products. The systems are prepared from polyisocyanates in combination with extenders based on flours and cold water-soluble of hydrolyzed natural starch. In this process, polyisocyanates or aqueous dispersions thereof are added while stirring to aqueous solutions or mixtures of starch and flour.The extender-containing adhesive systems are aqueous glue dispersions having increased service life which in their preferred embodiment contain about 15 to 30% by weight of polyisocyanates, preferably polyphenyl-polymethylene polyisocyanate (PMDI), 10 to 15% by weight of starch which is soluble in cold water and 14 to 25% by weight of (cereal) flour and optionally, other additives and the appropriate quantity of water adding up to 100% by weight.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: January 31, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hanns I. Sachs, Donald R. Larimer
  • Patent number: 4781781
    Abstract: A solid flexible polymeric material is formed by solidifying a water-based latex which contains an inorganic filler. The filler is sand and this may be stabilized in the latex with xanthan gum. The solid material may be a foamed or non-foamed layer which may be used as integral carpet backing, as carpet underlay, or as an adhesive for bonding a reinforcing fabric to the back of carpeting.
    Type: Grant
    Filed: August 27, 1987
    Date of Patent: November 1, 1988
    Inventor: Gerald Hallworth