Abstract: In the production of a vulcanized rubber-resin composite material by providing a vulcanized rubber molding in a mold, followed by injecting a resin into the mold, a vulcanizable adhesive layer containing brominated poly(2,3-dichlorobutadiene-1,3) as the main component is formed on the surface to be bonded of the vulcanized rubber molding, and then injecting the resin while keeping the vulcanizable adhesive layer to stay as formed on the surface to be bonded, thereby effecting the bonding, where a strong adhesion is established between the vulcanized rubber molding and the resin layer without any heat treatment of the vulcanized rubber molding before provision of the vulcanized rubber molding in the mold or without any heat treatment of the composite material after the resin injection.

Abstract: A synthetic chloroprene rubber adhesive composition which contains carboxylated synthetic chloroprene rubber for the main ingredient thereof and further contains chlorinated polypropylene and/or a chlorinated polypropylene derivatives. The adhesive composition can strongly bond various components to polypropylene used for a speaker frame, etc. unlike conventional synthetic chloroprene rubber adhesives which have insufficient adhesion strength in this application.

Abstract: The present invention provides an aqueous adhesive composition including a resinous phase dispersed in an aqueous medium, the resinous phase containing (a) a polychloroprene, (b) optionally, a halogenated polyolefin different from (a), and (c) optionally, an aminoplast resin. Further provided is an aqueous adhesive composition of a resinous phase dispersed in an aqueous medium wherein the resinous phase includes (a) a polychloroprene, (b) a halogenated polyolefin different from (a), and (c) a polyurethane polymer having ionic salt groups. A multi-layer composite and methods for adhering a thermoplastic material to a rigid substrate using the aqueous adhesive compositions also are provided.

Abstract: What is disclosed are adhesives and bonding methods employing a single coat of a solvent-based adhesive that effectively bonds thermoplastic polymers and especially thermoplastic elastomers. The adhesive components are a organosilane component selected from organosilane-isocyanate adduct and isocyanato-organosilane, a post-chlorinated polymer containing propylene repeating units or derivative thereof, and solvent. Also disclosed are methods for joining a rigid, structural substrate to a molten polymer such as a TPE via injection molding or extrusion. Durable adhesion between the adhesive treated portion of the rigid substrate and the melt-processed polymer is achieved with or without a previous heat treatment on the adhesive-coated substrate prior to joining to the thermoplastic melt.

Abstract: An improved adhesive composition and method for adhering textile reinforcing elements to rubber, particularly ethylene-propylene-diene rubber in the manufacture of rubber articles such as power transmission belts, wherein the adhesive composition comprises a latex of a hydrogenated styrene-butadiene rubber, a carboxylated hydrogenated styrene-butadiene rubber, a hyddogenated nitrile-butadiene rubber, a carboxylated hydrogenated nitrile-butadiene rubber, a chlorosulfonated polyethylene or blends thereof; an aqueous solution of a half-ester of maleinized liquid poybutadiene; and, optionally, up to about 15% by weight carbon black in an aqueous solution.

Abstract: A method for increasing the adhesion of a first layer comprising a fluoropolymer substantially free of interpolymerized units derived from vinylidene fluoride to a second layer comprising a curable elastomer is described. The method comprises adding a dehydrofluorinating composition to the curable elastomer, contacting the layers and curing the layered article so formed. The resulting multilayer compositions and articles are also disclosed.

Abstract: A multi-layer article includes a first polymer layer, a substrate, and a bonding layer on a surface of the first polymer layer and in contact with the substrate.

Abstract: To provide a fluorine-containing adhesive which maintains thermal resistance, chemical resistance, weather resistance and electric insulating property and has strong adhesive property directly to substrates particularly metal and glass, and an adhesive film and laminated article which are obtained by using the fluorine-containing adhesive. There is used a fluorine-containing ethylenic polymer having hydroxyl which is prepared by copolymerizing 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having hydroxyl and 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers copolymerizable with the above-mentioned monomer.

Abstract: A multi-layer structure includes a fluoropolymer bonded to a substrate. The structure is prepared by exposing a bonding composition to actinic radiation, such as ultraviolet radiation, to form the bond. The bonding composition includes a light-absorbing compound and an electron donor. The bonding composition includes non-adhesive materials.

Abstract: A two part aqueous adhesive comprising a main agent containing a polychloroprene latex as a main component and a curing agent, the main agent and the curing agent being separated during storing or transporting.

Abstract: An aqueous adhesive composition, as for bonding nitrile rubbers to a metal substrate, has very good pre-bake resistance. The adhesive composition comprises a phenolic novolac or resole resin, chlorinated natural rubber, a reactive fillers, and precipitated silica. Utilization of the adhesive composition results in essentially failure of the nitrile rubber.

Abstract: The invention relates to a handling module for at least one component (12) for mounting on and removal from a component carrier (14), having a holding device (22) which has at least one receptacle which is matched to the component (12), having a coil (42) which is arranged at an end of the holding device (22) which faces towards the component (22), is energized when the holding device (22) is being at least partially positioned with respect to the at least one component (12) and positions the at least one component (12) with respect to the holding device (22) by means of magnetic holding force.

Abstract: A method of producing a rubber-resin composite whose vulcanized rubber and thermoplastic resin moldings are bonded together by high adhesive strength at low cost, satisfying both moldability and mechanical strength. It comprises: (1) making the vulcanized rubber molding by vulcanization molding, (2) forming an adhesive layer, whose principal ingredient is chlorosulfonated polyethylene, on a surface of the rubber molding to be bonded to the resin, and (3) while arranging the rubber molding in a mold, pouring the thermoplastic resin containing 30˜60 wt. % of glass fiber in a molten state into the mold to form the resin molding.

Abstract: A pressurized aerosol solvent cement product and a method of using the same is disclosed. The aerosol solvent cement product includes an aerosol solvent cement composition disposed in a container. The aerosol solvent cement composition includes tetrahydrofuran, a thermoplastic resin soluble in tetrahydrofuran, a propellant, and a stabilizing composition.

Abstract: There is provided a power transmission belt which comprises a compression layer and an adhesive rubber layer which are adhered to each other by vulcanizing together and which has aramid fiber cords embedded in the adhesive rubber layer, wherein the compression layer and the adhesive rubber layer are formed of vulcanizate of an ethylene-&agr;-olefin-diene rubber compound and wherein the aramid fiber cords having a first twisting coefficient and a final twisting coefficient both in the range from 650 to 950 are adhesion treated with a resorcin-formalin-latex adhesive composition wherein the latex comprises at least one of chlorosulfonated polyethylene and alkylated chlorosulfonated polyethylene in an amount of 50-100% by weight based on the solid components of the resorcin-formalin-latex and adhered to and embedded in the adhesive rubber layer. A process for the production of such power transmission belt is also provided.

Abstract: A multi-layer structure includes a layer of a fluoropolymer bonded to a substrate. The structure is prepared by exposing a bonding composition to actinic radiation, such as ultraviolet radiation, to form the bond. The bonding composition includes a light-absorbing electron donor.

Abstract: In one embodiment, the present invention relates to a bonded assembly made of a magnesium containing metal comprising at least about 25% by weight magnesium, a thermoplastic elastomer, and an adhesive between the magnesium containing metal and the thermoplastic elastomer, the adhesive comprising from about 20% to about 99% by weight of a polymeric material.

Abstract: A process for making a low-gloss exterior body panel or member includes forming a thermoplastically formable dry paint transfer film on a heat-resistant temporary carrier having a low-gloss microroughness. The dry paint transfer film has a polymeric outer clear coat layer and a polymeric base coat layer containing a dispersed pigment. The clear coat layer contains (a) uniformly dispersed filler particles in an amount below about five parts by weight of the total resin binder solids and (b) a dispersion of a fluorinated polymeric material in a solvent solution of an acrylic resin. The dispersion has an average particle size from about 20 to about 35 microns. The dry paint transfer film is laminated to a semi-rigid thermoplastically formable resinous backing sheet on a side opposite from the clear coat layer. A relatively thick substrate sheet is extruded from a thermoformable polymeric material. A paint-coated thick sheet laminate is formed by laminating the backing sheet to the extruded sheet.

Abstract: A laminated optical element has an IR transmissive substrate and a laminated IR transmissive polymeric layer on at least one surface of the IR transmissive substrate. The polymer layer may be a fluoropolymer or polyethylene and has an aspheric/diffractive surface. The polymer layer is affixed to the substrate by adhesive or, alternatively, the polymer layer is formed directly on the substrate resulting in a unitary optical element that is IR transmissive.

Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.

Abstract: Packing material with good gas barrier properties comprising a first and a second layer of a fibrous material or, e.g. paper or cardboard, and a layer of a water based polymer, e.g. polyvinyl alcohol, placed between and in direct contact with the layers of fibrous material and functioning both as a gas barrier and as a binding agent in the packaging material. The packaging material is produced through bringing together and binding together with each other a first and a second strip or sheet of a fibrous material by means of a layer of a water based polymer, e.g polyvinyl alcohol, applied between and in direct contact with the strips or sheets. The surplus water in the thus applied polymer layer is absorbed by the fibrous material in one and/or the other strip or sheet to form the intermediate layer functioning as gas barrier and binding agent.

Abstract: A higher-barrier acrylic/chlorinated vinyl or acrylic/chlorinated vinyl/vinyl latex adhesive component and a lower-barrier acrylic of arcylic/vinyl latex adhesive component are mixed in relative proportions and used to adhere films of low-barrier material, such as films of polyolefins, thereby providing an adhesive layer of controlled gas barrier properties.

Abstract: The invention provides contact adhesives comprising an adhesive component comprising polychloroprene rubber, and an internal coagulant. The contact adhesives may also contain a resinous component selected from the group consisting of ethylene-vinyl acetate copolymer, polyvinyl acetate homopolymer, polyvinyl acetate copolymer, acrylic copolymer, polyvinyl acetate acrylic copolymer, and combinations thereof. The internal coagulant may be hygroscopic salt, amino acid, or a combination thereof.

Abstract: The invention provides a process for preparing adhesives having improved adhesion, in the form of their aqueous dispersions or water-redispersible dispersion powders, by emulsion polymerization in the presence of polyvinyl alcohol with or without drying of the dispersion obtainable by this process, which comprises polymerizing a comonomer mixture comprising

Abstract: The invention provides a process, and product thereof, for forming a chemically resistant fusion bonded seal between chemically dissimilar materials by use of a chlorinated polyolefin film for protective garments. The process involves placing the chlorinated polyolefin film between two dissimilar films such as a facepiece and the fabric film of the garment and applying heat and pressure. The resulting fusion bonded film composite is strong, flexible and upon the application of sufficient stress exhibits total cohesive rupture failure.

Abstract: A higher-barrier acrylic/chlorinated vinyl or acrylic/chlorinated vinyl/vinyl latex adhesive component and a lower-barrier acrylic or acrylic/vinyl latex adhesive component are mixed in relative proportions and used to adhere films of low-barrier material, such as films of polyolefins, thereby providing an adhesive layer of controlled gas barrier properties.

Abstract: Disclosed is a method for forming a bright metallized laminate. In one aspect, the method includes press polishing a polyvinylidene difluoride-containing film, either before or after the deposition of a discontinuous layer of indium islands, so that the polyvinylidene difluoride-containing film becomes microscopically smooth. In another aspect, the method includes applying a thermoplastic leveling layer to a polyvinylidene difluoride-containing film and thereafter depositing a discontinuous layer of indium islands upon the thermoplastic leveling layer.

Abstract: Boric acid is mixed, preferably at 0.1 to 10 w. % in relation to the solid content, into a sprayable dispersion based on an acrylic acid ester copolymer and a colloidal chloroprene polymerisate. The spray is applied to at least one or both substrate surfaces, the substrate surfaces to be glued are laid against each other wet and pressed together with at least 0.1 N/cm2 for at least approximately 0.5 seconds. The sprayable dispersion is preferably used for gluing foams, after a short compression the initial adhesion is so high that further processing or transport can be begun immediately.

Abstract: A single membrane insulation material including a nonwoven insulation mat, a fluoropolymer dispersion surface coated to one side of the mat and a fluoropolymer film component laminated to the thus coated side of the mat under conditions of elevated temperature and pressure. The coating has a depth of penetration which is less than the total thickness of said mat.

Abstract: A methacrylate ester or acrylate ester adhesive composition including a retarding additive to extend the open time and/or reduce the peak exotherm temperature. The retarding additive is selected from the group consisting of non-protonic Lewis acids and zinc salts and mixtures thereof.

Abstract: In one embodiment, the present invention relates to a bonded assembly made of a magnesium containing metal comprising at least about 25% by weight magnesium, a thermoplastic elastomer, and an adhesive between the magnesium containing metal and the thermoplastic elastomer, the adhesive comprising from about 20% to about 99% by weight of a polymeric material.

Abstract: An adhesive fluororesin (A) comprising an ethylene-tetrafluoroethylene copolymer having at least one characteristic selected from the group consisting of a melt flow characteristic which is a melt flow rate of at least 40 and an infrared absorption characteristic which is a distinct absorption peak within a wavenumber range of from 1,720 to 1,800 cm.sup.-1 in its infrared absorption spectrum.

Abstract: CPVC adhesives for joining CPVC substrates, pipes and articles are provided which comprise (a) about 5 to about 25 wt. % CPVC resin, (b) about 20 to about 90 wt. % of a single pentanone or blends of pentanones, (c) 0 to about 20 wt. % total heterocyclic solvent, and (d) 0 to about 45 wt. % total of non-heterocyclic solvents other than component (b) (such as MEK, acetone, cyclohexanone, and so forth). The CPVC adhesive compositions of this invention permit a reduction in the content of heterocyclic solvents to be achieved while meeting performance standards applicable to CPVC pipe joining, such as hydrostatic burst strength and hydrostatic sustained pressure test.

Abstract: The present invention relates to battery parts comprising molded pieces made of polyolefin resin, whose surface to be bonded are treated so as to have at least one functional group selected from the group consisting of hydroxyl group, carboxyl group, carbonyl group, fluorosulfuryl group, sulfonic group and its metallic bases, said molded pieces being bonded together with reactive hot-melt adhesive.

Abstract: One-component hot-curing structural adhesives based on liquid rubbers, which may optionally contain functional groups, solid rubbers, thermoplastic polymer powders and sulfur and also vulcanization accelerators are suitable for bonding metal parts. Tensile shear strengths of more than 15 MPa and high breaking elongations of more than 15% can be obtained. These adhesives are substantially free from low molecular weight epoxy resins and are particularly suitable for use in white-shell assembly in the car industry.

Abstract: Process to adhere PTFE in film or in sheets adhere to metal or plastic substrata which comprises:1) making the substratum surface rough by sandblasting;2) spreading on a PTFE sheet a suspension comprising a solvent or water and a blend of a fluoroelastomer of vinylidene fluoride (VDF) with perfluoropropylene (HFP) to which PTFE is added; sintering between 330.degree. C.-400.degree. C.;3) the already treated PTFE part as in point 2) is covered again with a suspension of the same fluoroelastomer of 2);4) the substratum 1) is put into contact with the PTFE sheet treated as in 3) with the surface which has been subjected to the treatment; the system is then put in press at a temperature comprised between 150.degree. and 200.degree. C.

Abstract: A fuser member for fixing toner to a recording medium having a fluoropolymer non-stick topcoat on a compliant silicone rubber baselayer bonded to a metallic insert is provided. The fluoropolymer is adhered to the silicone rubber baselayer using a primer of a blend of silane and a polyamide resin. The primed silicone baselayer is preheated in an infrared oven to remove low molecular weight fractions. A primer is applied to the prebaked rubber and completely dried before applying the fluoroelastomer topcoat by spaying.

Abstract: The present invention relates to a method of engraving objects which circumvents the necessity of mechanically scrubbing the engraved surface to remove fillers. Specifically, in the method of the present invention, the fillers are applied directly to the resist stencil instead of being applied to the object to be engraved. Removal of the resist stencil simultaneously removes the filler from the engraved object.

Abstract: A method for constructing a laminate comprising two layers, including an acrylic homopolymer layer and a microporous PTFE layer wherein the acrylic layer is a felt and is pretreated by immersion into an adhesive solution and introduced to the PTFE layer and subjected to heat and pressure to form a laminate useful as a filtration material. A laminate useful as a filtration material is formed by the immersion process.

Abstract: A composition comprising a high-melting perfluoroplastic swollen at a swelling temperature to the extent of at least one percent with a solution of a second, lower-melting perfluoropolymer in a solvent; and an assembly made by contacting said swollen perfluoroplastic material with a surface of an interlayer at a first temperature, contacting another surface of the interlayer with a substrate and applying pressure to cause the interlayer to adhere to both the perfluoroplastic and the substrate and thus form an assembly, and heating the assembly to a second temperature.

Abstract: A free radical curable composition that includes a free radical curable and a vinyl aromatic compound that is chemically different than the free radical curable component, wherein the vinyl aromatic compound is present in an amount sufficient to decelerate the cure rate of the free radical composition without adversely effecting completion of cure and the properties of the curable composition after it has cured. The composition is particularly useful as a two part adhesive that includes a free radical catalyst system and a diene elastomer.

Abstract: A multi-layer article comprises a substantially non-fluorinated layer, and a fluorinated layer of fluoropolymer comprising interpolymerized monomeric units derived from one or more of hexafluoropropylene and tetrafluoroethylene monomers, one or more non-fluorinated olefinically unsaturated monomer, and substantially no vinylidene fluoride monomer. The multi-layer article further comprises an aliphatic di-, or polyamine which provides increased adhesion between the layers as compared to a multi-layer article not containing the aliphatic di-, or polyamine. The multi-layer article can be prepared by mixing the aliphatic di-, or polyamine into the substantially non-fluorinated polymeric material, or by applying the aliphatic di-, or polyamine to a surface of one or more of the substantially non-fluorinated polymeric material or the fluoropolymer, and thereafter preparing a multi-layer article.

Abstract: Disclosed is a solvent-based cement for bonding joints of polyvinyl chloride pipe and fittings. The cement of the composition contains at least about 10% by weight of a polyvinyl chloride resin, at least about 2% by weight of a solid alcohol having a melting point above at least about 20.degree. C., and at least about 10% by weight of a solvent or a mixture of solvents. There is also provided a method of joining two pieces of thermoplastic material, such a poly(vinyl chloride) piping and fittings, and the product piece having one or more joints formed thereby.

Abstract: A method for low temperature attachment of components is provided which uses an electrically conductive adhesive. The electrically conductive adhesive may be defined by a substrate having numerous passageways through the substrate. The passageways are defined by a plurality of walls of the material making up the substrate. The walls are covered with a layer of conductive metal. The passageways at the outer surfaces are filled with a non-conductive pressure sensitive adhesive resin.

Abstract: The present invention relates to methods for bonding articles made of polymers, and in particular, fluoropolymers. According to a first embodiment of the present invention, the method comprises the steps of coating the surface of either one or both of the articles to be bonded with a third polymer so that one or both of the articles has a layer of the third polymer adhered thereto, and bringing the articles into contact with each other after the articles are coated in order to bond the articles together. According to a second embodiment, the method comprises the steps of placing a composite layer comprising either conductive or magnetic materials, or both, between the articles, bringing the articles and the composite layer into contact with each other and electromagnetically heating the composite layer to bond the articles together.

Abstract: An adhesive composition using as the primary binder an emulsion of butadiene-vinylidene chloride copolymer is disclosed. The composition is particularly suited for binding rubber to metal in a variety of uses such as vibration damping devices. The adhesive composition has resistance to hot water and or water glycol solutions.

Abstract: A method of making a fuser member such as a fuser roller, pressure roller, or fuser belt, comprising of bonding an outermost fluoropolymer resin layer to an inner fluoroelastomer layer by means of a fluoropolymer-containing polyamide-imide primer layer.

Abstract: Process for the stiffening of textile or leather materials, includes (a) applying an aqueous polymer dispersion to a textile structure on the basis of a woven or nonwoven fabric, or a leather material; (b) drying the textile structure or leather material; and (c) the stiffening material thus produced is deformed and glued with the textile and leather material to be stiffened, in which an aqueous dispersion of a two-phase, sealable emulsion graft copolymer having a soft phase and a hard phase is applied. The hard phase has a glass transition temperature of Tg of at least 50.degree. C. and includes monomer units such as methyl methacrylate, styrene, diisopropyl fumarate and vinyl chloride. The soft phase has a glass transition temperature Tg of at least 30.degree. C.

Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.

Abstract: A process for adhering high-melting perfluoroplastic materials is disclosed, which process comprises swelling a material comprised of a first perfluoropolymer with a solution of a second lower-melting perfluoropolymer, and then adhering the material to a substrate with an interlayer of the same second perfluoropolymer. The final assembly, as well as intermediate assemblies or compositions which can be made and stored, are also disclosed.