Protein And/or Carbohydrate Containing And/or Derivatives Thereof Patents (Class 156/336)
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Patent number: 4964939Abstract: Aqueous starch-based adhesives for use in a variety of applications can be made alkali sensitive or can have enhanced cleanability under aqueous conditions.Type: GrantFiled: August 31, 1988Date of Patent: October 23, 1990Assignee: H. B. Fuller CompanyInventor: Patrick D. Gleason
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Patent number: 4948448Abstract: A method of manufacturing moisture-resistant corrugated paper board, particularly paper board intended for the manufacture of boxes, comprising an outer planar liner, an inner planar liner and a corrugated so-called floating disposed between the liners, wherein the liners and the floating consist of a paper which incorporates a rosin size. The invention is characterized in that the paper (5) on which the floating (7) is to be formed, is impregnated throughout its thickness with a first substance which includes a plastics suspension, preferably a styrene-butadiene suspension, and starch, and in that the paper (1, 3) for the liners, at least with respect to the surface (2, 4) of at least one of the liners (10) which is intended to face away from the floating (7) is coated with a second suspension which includes a plastics suspension preferably a styrene-butadiene suspension, and starch, and in that respective liners (10) are adhesively bonded to the floating (7).Type: GrantFiled: November 25, 1988Date of Patent: August 14, 1990Assignee: Lacani ABInventor: Lennart Tengqvist
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Patent number: 4944823Abstract: Wood surfaces are bonded together by heating and pressing using a preferably dry binder formulation constituting a thorough mixture of an isocyanate and a sugar or starch, the binder formulation also preferably containing a stabilizer and optionally a catalyst and a release agent. The binder formulation may be used with good results in an amount equal to the amount of straight isocyanate resin which would normally be used, i.e. the sugar or starch replaces a quantity of the isocyanate which would normally have been used, thereby reducing the total quantity of isocyanate, thus reducing cost without any disadvantage.Type: GrantFiled: September 26, 1985Date of Patent: July 31, 1990Assignee: Carbocol, Inc.Inventor: John Stofko
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Patent number: 4912209Abstract: This invention presents starch-based alkaline corrugating adhesives having improved green bond strength due to the use of undried starch as the raw starch component in the adhesive. Such adhesives can be used in corrugation processes at much higher corrugator running speeds than the conventionally employed adhesives.Type: GrantFiled: June 15, 1988Date of Patent: March 27, 1990Assignee: National Starch and Chemical CorporationInventors: Craig Leake, Michael Foran, Jeffrey G. Atkinson
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Patent number: 4890444Abstract: A fluted filter media to end cap bonding process and fluid filters formed by the bonding process. The process comprises coating at least one end cap and/or at least one fluted edge of the filter media with a bonding composition, contacting the end cap with the edge of the fluted filter media and curing the bonding composition coating to form a strong, continuous filter media to end cap bond. The bonding composition comprises, in adhesive latex, a thermoplastic resin and an amount of ungelatinized granular starch effective to complex a major portion of the latex water during curing of the bonding composition.Type: GrantFiled: June 17, 1988Date of Patent: January 2, 1990Assignee: H. B. Fuller CompanyInventors: Michael J. Vander Giessen, Robert M. Hume, III, Leonard C. Jannusch
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Patent number: 4880702Abstract: A composition for stabilizing a denture in the form of a thin strip consisting of three layers, piled up one over another, which composition is characterized in that:(a) a swelling ability and solubility of outside layers are higher than those of an inside layer,(b) the swelled outside layers have an ability to adhere to gums and a denture base,(c) the inside layer has a self-supporting ability and a shape-retaining ability for the outside layers, and(d) the inside layer has an ability to adhere to the gums and the denture base after the outside layers have flowed away through dissolution.Type: GrantFiled: December 22, 1987Date of Patent: November 14, 1989Assignee: Shionogi & Co., Ltd.Inventors: Morio Homan, Nizo Sugie, Masakiyo Yoshimura, Yoshikazu Shirakawa
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Patent number: 4812496Abstract: An adhesive of starch and an ammonium-based latex improves wet-pin adhesion for paperboard and corrugated board. The latexes are typical styrene-butadiene and carboxylated styrene-butadiene latexes but untypically are polymerized in the presence of a volatile base such as ammonium hydroxide.Type: GrantFiled: January 27, 1987Date of Patent: March 14, 1989Assignee: The Dow Chemical CompanyInventors: Arthur N. Leadbetter, James G. Galloway
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Patent number: 4801631Abstract: This invention relates to formaldehyde-free, aqueous glue dispersions which contain polyisocyanates. These systems are particularly suitable for gluing veneers and surface materials on wood and wood products. The systems are prepared from polyisocyanates in combination with extenders based on flours and cold water-soluble of hydrolyzed natural starch. In this process, polyisocyanates or aqueous dispersions thereof are added while stirring to aqueous solutions or mixtures of starch and flour.The extender-containing adhesive systems are aqueous glue dispersions having increased service life which in their preferred embodiment contain about 15 to 30% by weight of polyisocyanates, preferably polyphenyl-polymethylene polyisocyanate (PMDI), 10 to 15% by weight of starch which is soluble in cold water and 14 to 25% by weight of (cereal) flour and optionally, other additives and the appropriate quantity of water adding up to 100% by weight.Type: GrantFiled: February 6, 1987Date of Patent: January 31, 1989Assignee: Bayer AktiengesellschaftInventors: Hanns I. Sachs, Donald R. Larimer
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Patent number: 4787937Abstract: Alkaline-curing, starch-based corrugating adhesives employing ungelatinized tapioca starch and a carrier comprising high amylose starch, wherein the total solids of the adhesive is from 30 to 45% solids by weight, are disclosed. Said adhesives provide improved tack and corrugator running speeds.Type: GrantFiled: September 30, 1987Date of Patent: November 29, 1988Assignee: National Starch and Chemical CorporationInventor: Craig H. Leake
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Patent number: 4778530Abstract: Finely divided almond shell flour is used as an extender in plywood- and laminating-adhesives, alone or in combination with other, different, vegetable shell flours.Type: GrantFiled: November 9, 1987Date of Patent: October 18, 1988Assignee: Agrashell, Inc.Inventor: Joseph W. Ayers
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Patent number: 4775706Abstract: A starch-based alkaline curing adhesive is disclosed. The adhesive, when employed in the preparation of corrugated paperboard provides the paperboard with superior water resistant bonds. The adhesive contains from about 6 to 35%, based on total weight of the adhesive, solids basis, of a latex polymer of a halohydrin quaternary ammonium monomer.Type: GrantFiled: May 30, 1986Date of Patent: October 4, 1988Assignee: National Starch and Chemical CorporationInventors: Carmine P. Iovine, Robert H. Williams, Craig H. Leake
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Patent number: 4769096Abstract: A fluted filter media to end cap bonding process. The process comprises coating at least one end cap and/or at least one fluted edge of the filter media with a bonding composition, contacting the end cap with the edge of the fluted filter media and curing the bonding composition coating to form a strong, continuous filter media to end cap bond. The bonding composition comprises, in adhesive latex, a thermoplastic resin and an amount of ungelatinized granular starch effective to complex a major portion of the latex water during curing of the bonding composition.Type: GrantFiled: February 13, 1986Date of Patent: September 6, 1988Assignee: H.B. Fuller CompanyInventors: Michael J. Vander Giessen, Robert M. Hume, III, Leonard C. Jannusch
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Patent number: 4761184Abstract: A formaldehyde binder containing at least one organic hydroxy compound, at least one amide, and water. This binder is suitable for use in preparing boards from lignocellulosic materials using adhesive based on formaldehyde.Type: GrantFiled: February 11, 1987Date of Patent: August 2, 1988Assignee: Enigma N.V.Inventor: Efthalia V. Markessini
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Patent number: 4747894Abstract: A method and apparatus for starch adhesive bonding of paper, paperboard, and natural cellulosic-fiber materials, especially liner and fluted corrugating medium, into manufactured items, particularly corrugated board. The method includes applying an adhesive coating, comprising starch and water, to a first substrate (e.g. tips of flutes of a corrugated medium), contacting the applied coating with another substrate (e.g. liner) and while so positioned contacting an exterior surface of at least one of the substrates with an ultrasonic energy generating means so as to transmit ultrasonic energy to the adhesive coating to increase coating adhesion to the substrates.Type: GrantFiled: May 21, 1985Date of Patent: May 31, 1988Assignee: Battelle Memorial InstituteInventors: Herbert N. Johnston, Donald F. Hiscock, Ralph E. Beard
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Patent number: 4681934Abstract: A crosslinking agent constituted by a cyclodextrin clathrate compound of a compound having isocyanate group(s). This crosslinking agent is stable at room temperature and very readily initiates crosslinking. The crosslinking agent is prepared by reacting a compound having isocyanate group(s) with cyclodextrin at 65.degree. C. or below in water, and recovering the clathrate compound from the water.Type: GrantFiled: August 22, 1985Date of Patent: July 21, 1987Inventors: Ichiro Shibanai, Koki Horikoshi, Takashi Kato
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Patent number: 4678824Abstract: Remoistenable adhesive compositions are prepared by adding to ethylene vinyl acetate resin latices which have been polymerized utilizing dextrin as the protective colloid sufficient phosphoric acid to lower the pH to about 2.Type: GrantFiled: February 13, 1986Date of Patent: July 7, 1987Assignee: National Starch and Chemical CorporationInventor: Vincent A. Lauria
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Patent number: 4587332Abstract: The present invention relates to second grade starches and wheat "B" starches in particular which, following conventional modification treatments to produce a correspondingly viscosity-reduced starch, are especially useful in the production of Stein-Hall corrugating adhesives. Corrugated paper board products manufactured using such adhesives have improved properties. In one aspect of the present invention there is provided a modified wheat "B" starch wherein aqueous dispersions of the modified "B" starch have reduced viscosities relative to comparable dispersions of a corresponding unmodified wheat "B" starch, the reduced viscosity not being less than about 12 centipoise grams per cubic centimeter for a specified dispersion.Type: GrantFiled: February 12, 1985Date of Patent: May 6, 1986Assignee: Ogilvie Mills Ltd.Inventors: Christopher C. Lane, Alexander B. Anonychuk, Peter Unger
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Patent number: 4575525Abstract: Remoistenable adhesive compositions are prepared from ethylene vinyl acetate resin latices which have been polymerized utilizing dextrin as the protective colloid. In a preferred embodiment of the invention, remoistenable adhesives characterized by superior adhesion to difficult stocks are prepared by post-addition of dextrin to the dextrin-emulsified ethylene vinyl acetate resin latex.Type: GrantFiled: November 5, 1984Date of Patent: March 11, 1986Assignee: National Starch and Chemical CorporationInventors: Donald M. Wacome, Christopher T. Fazioli, Vincent A. Lauria
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Patent number: 4568714Abstract: An aqueous starch-based corrugating adhesive containing casein, a carboxylated styrene-butadiene copolymer latex and preferably glyoxal is used to adhere liner and medium substrates having normally abherent surfaces.Type: GrantFiled: April 30, 1984Date of Patent: February 4, 1986Assignee: Champion International CorporationInventor: Steven D. Overholt
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Patent number: 4520050Abstract: This invention is a composition for polyester fiber for use in reinforcing, the finish composition being characterized by an oil portion containing a lubricant and 3-30 weight % of a melamine compound.Type: GrantFiled: September 16, 1983Date of Patent: May 28, 1985Assignee: Unitika LimitedInventor: Shigemitsu Murase
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Patent number: 4508773Abstract: Paper products, such as wrapped rolls of newsprint, are provided wherein paper is bonded to paper by a glue formulation that is pumpable at elevated temperatures, which glue formulation includes animal glue, water and a water-soluble salt having an anion that is substantially divalent at the pH of the glue formulation. The paper product is prepared by heating the glue formulation and applying same at an elevated temperature.Type: GrantFiled: April 27, 1983Date of Patent: April 2, 1985Assignee: Eschem Inc.Inventor: Gary A. Maxwell
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Patent number: 4490201Abstract: An improved method of making a carbon composite product wherein a fabric comprised of oxidized or otherwise stabilized polyacrylonitrile fibers is heat treated and then coated with a closely controlled amount of a carbonaceous binder such as a polyimide resin. The fabric is then further heat treated to thermally fuse the resin to the fabric to form a rigid, easily handleable material. The carbonaceous binder is applied to the fabric in a manner whereby substantial encapsulation of the individual fibers is avoided. Next the material is cut into swatches of a predetermined size and shape and the segments are arranged into a basic or starting substrate having a volume greater than the desired volume of the end product. The basic substrate thus formed is then subjected to controlled temperatures and pressures to form a shaped substrate having a known fiber volume, a high degree of open porosity and a shape substantially corresponding to the shape desired of the end product.Type: GrantFiled: August 10, 1981Date of Patent: December 25, 1984Assignee: The B. F. Goodrich CompanyInventor: Donald H. Leeds
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Patent number: 4478658Abstract: A method is disclosed for sealing edible capsules comprised of telescopically engaged tubular capsule halves that define a junction seam between them. The method comprises adhesively applying against at least a portion of the seam a frangible, edible label adapted to cover the seam at the point of intersection therewith, and to fracture upon slight displacement of the capsule halves with respect to each other. In one embodiment, the present method comprises the preparation of individual labels, the application to such labels of a quantity of adhesive and the subsequent application of the labels to the capsule. In an alternate embodiment, the labels, comprising a film forming material, are directly applied to the capsule by the projection of a hot melt of the film forming material onto the capsule at the location of the seam.Type: GrantFiled: December 20, 1982Date of Patent: October 23, 1984Assignee: Warner-Lambert CompanyInventor: Fritz Wittwer
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Patent number: 4478662Abstract: A process affixes a honeycomb structure to a plate in a manner whereby the structure and the plate may be chucked and the exposed surface of the honeycomb may be machined. The steps of the process include applying to the surface of the plate a viscous coating of honey; embedding one surface of the honeycomb in the viscous honey coating to leave the opposite honeycomb surface exposed for machining, and curing the coating to more tightly secure the honeycomb to the surface.Type: GrantFiled: November 17, 1982Date of Patent: October 23, 1984Inventor: Demitrious Canellos
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Patent number: 4471082Abstract: An adhesive composition comprising a mixture of water based polymer in latex form and a material generally referred to as a thickening agent is disclosed for removably adhering a product to a substrate, for example a carpet with an attached backing to a flooring substrate. The adhesive may be applied as a layer to the carpet backing, dried and subsequently activated with water to adhere the carpet to the floor. After drying, the adhesive layer may be reactivated with water to permit the carpet to be removed from the floor. The adhesive layer when dried on the surface of a latex foam backed carpet provides a non-tacky surface which additionally increases the abrasion resistance of the latex foam backing thereby reducing damage to the backing during normal storage and handling.Type: GrantFiled: December 8, 1982Date of Patent: September 11, 1984Assignee: Polysar LimitedInventors: John C. Kwok, Ivan S. Lee
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Patent number: 4440884Abstract: An aqueous adhesive, resistant to humidity and water, which debonds in the presence of strong base, comprises finely divided aluminum, a natural product bonding agent and water.Type: GrantFiled: October 20, 1982Date of Patent: April 3, 1984Assignee: H. B. Fuller CompanyInventor: Leonard C. Jannusch
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Patent number: 4431757Abstract: The invention provides an adhesive composition of the two-part separate application type comprising solutions A and B. The solution A is an aqueous solution of a high polymer having an amide bond or an imide bond within the molecule, or an aqueous dispersion obtained by adding a rubber latex and/or synthetic resin emulsion to the aqueous solution of the high polymer. The solution B is an aqueous solution of a dialdehyde compound, or an aqueous solution or dispersion obtained by adding a crosslinking agent for crosslinking the high polymer of the solution A to the aqueous solution of the dialdehyde compound.Type: GrantFiled: July 19, 1982Date of Patent: February 14, 1984Assignee: Konishi Co., Ltd.Inventors: Toshinao Okitsu, Tomio Uchida
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Patent number: 4424291Abstract: A corrugating adhesive composition which exhibits superior tack performance is obtained by replacing, on a solids basis, from 5 to 100%, by weight, of the gelatinized starch carrier of a typical known starch-corrugating adhesive with a polymer containing at least 10%, by weight, of carboxyl groups derived from a polymerizable ethylenically unsaturated mono- or polycarboxylic acid or a mixture of these polymers.Type: GrantFiled: August 10, 1981Date of Patent: January 3, 1984Assignee: National Starch and Chemical CorporationInventors: Craig H. Leake, Michael A. Silano
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Patent number: 4400480Abstract: A crosslinking additive for imparting water resistance to starch-based corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of 1 mole acetone to about 2 to 5.5 moles formaldehyde, adding to the reaction mixture at least an effective amount of dihydroxyethylene urea to scavenge the free formaldehyde in the mixture, and reacting until the amount of unreacted formaldehyde remaining is reduced to about 0.1-2%. The crosslinking additive thus obtained, which is low in free formaldehyde, may be added directly to a starch-based corrugating adhesive or may be first mixed with dimethylol dihydroxyethylene urea.Type: GrantFiled: September 2, 1982Date of Patent: August 23, 1983Assignee: National Starch and Chemical CorporationInventors: Michael A. Silano, Robert D. Featherston
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Patent number: 4397756Abstract: The invention is a composition of matter and method for its use in reducing formaldehyde emission from wood composite panels bonded with aminoplast resins. The preferred composition comprises urea, a carbohydrate based material such as cooked or gelatinized starch, and an acidic catalyst for the resin. The ratio of urea to carbohydrate based material is in the range of 10:1 to 40:1 while the urea forms from 20-60% of the composition. In use, the composition is preferably sprayed on the wood particles, flakes or fiber in the blender at the same time resin is added. Typical usage is 0.4-3 parts, on a urea basis, added to each 100 parts of dry wood substance. Depending on several factors, the reduction in formaldehyde emission ranges from 60-90% without serious deterioration occurring in any other product physical properties.Type: GrantFiled: August 10, 1981Date of Patent: August 9, 1983Assignee: Weyerhaeuser CompanyInventor: William F. Lehmann
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Patent number: 4359341Abstract: A process for preparing a carrier type starch which is characterized by the steps of mixing two starch portions having different gelatinization temperatures with water to form a slurry and causing gelatinization of the starch portion having the lower gelatinization temperature to thereby form a stable gelatinized carrier for the raw starch portion having the higher gelatinization temperature. The ratio of the starch portion having the lower gelatinization temperature to the starch portion having the higher gelatinization temperature is preferably of the order of from 1:10 to 1:4 and the ratio by weight of the starch portions to water is of the order of from 1:2 to 1:4, preferably about 1:3. A carrier type starch based adhesive comprising a mixture of a gelatinized carrier starch portion and a raw starch portion having a higher gelatinization temperature dispersed in the carrier portion is also disclosed.Type: GrantFiled: November 27, 1981Date of Patent: November 16, 1982Assignee: Harper-Love Adhesives CorporationInventor: Leon A. Allen
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Patent number: 4357194Abstract: Composite products are formed, such as of lignocellulosic particles, by bonding through the transformation of added sugars and/or starches together with lignin and/or other phenolic containing materials, with the optional presence of added catalyst, the transformation causing the composition to convert into a furan-lignin type binder in situ by heat and pressure. The bonding composition is suitably activated by contact with live steam.Type: GrantFiled: April 14, 1981Date of Patent: November 2, 1982Assignees: John Stofko, John JanskyInventor: John Stofko
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Patent number: 4339491Abstract: Disclosed is a process for bonding wallpaper to a wall insulation board or film of a foamed organic polymer, comprising the steps of providing a layer of wall insulation comprising a foamed organic polymer; providing a layer of wallpaper; applying to the surface of either the layer of wall insulation or the layer of wallpaper a coating of an adhesive composition suitable for bonding the layers together, wherein the adhesive composition comprises an amount of a flame retardant agent sufficient to render the adhesive composition flame retardant; and bonding the layer of wallpaper to the layer of wall insulation. Also disclosed is a composite sheeting produced by this process.Type: GrantFiled: March 12, 1981Date of Patent: July 13, 1982Assignee: Hoechst AktiengesellschaftInventors: Uwe Lauterbach, Wolfgang Michel
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Patent number: 4333767Abstract: A method for the manufacture of an adhesive from animal blood is described in which the blood is dried and stored as a dried mass of blood and in which this dried mass of blood is then converted to a sprayable solution of up to 40% concentration by the addition of water. The ready-to-use adhesive is finally prepared by the admixture, preferably during spraying, of a monobasic organic acid in a quantity sufficient to produce a pH value of the adhesive between 3.0 and 4.0.In a modification of the method an extender or diluent preferably in the form of sodium chloride, is added to the blood prior to drying. The drying step can be carried out by means of vacuum drying, freeze drying or drying through atomization. It is also advantageous to cool the blood to a temperature of approximately 4.degree. C. in the period between accumulation and drying.The resulting adhesive is particularly suitable for use as a binder in the manufacture of particle board from wooden chips.Type: GrantFiled: December 14, 1979Date of Patent: June 8, 1982Assignee: Bison-Werke Bahre und Greten GmbH & Co., KGInventor: Arno Nass
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Patent number: 4206245Abstract: Valuable products are obtained from Theobroma fruits by preferably removing the peels from said fruits, opening the fruits, separating the seeds from the preferably peeled parenchymatous part of the fruits, and immediately thereafter fermenting the seeds and processing said parenchymatous part. Preferably the fruits are pretreated, for instance, with an alkaline solution and, after peeling, are neutralized, or they are pretreated with a preserving agent. The parenchymatous part of the fruits is expressed to yield the fruit flesh juice containing a hydrocolloid which has proved to be a valuable emulsifying, thickening, stabilizing, suspending agent and protective colloid. The expressed Theobroma fruit flesh is converted into a nutritious animal feed, especially for small animals. Thus the Theobroma fruits are substantially completely utilized.Type: GrantFiled: February 13, 1978Date of Patent: June 3, 1980Inventors: Ulla Drevici, Noe Drevici
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Patent number: 4186242Abstract: A process for the preparation of lignocellulosic composite using urea-formaldehyde adhesive is described characterized by treating the lignocellulosic constituents with ammonium-base lignosulfonate prior to pressing to decrease the emission of formaldehyde.Type: GrantFiled: March 8, 1976Date of Patent: January 29, 1980Assignee: Georgia-Pacific CorporationInventor: Howard W. Holmquist
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Patent number: 4183997Abstract: Solid lignocellulosic material is bonded together by heating and pressing at a natural wood, pH by reacting sugars, starches or both in the presence of a catalyst capable of catalyzing transformation of the sugars and starches into a solid, insoluble in water, and an alkaline buffering agent if needed, for example to make waterproof plywood or composite products from particulate wood without hydrolytic degradation of the wood.Type: GrantFiled: October 4, 1977Date of Patent: January 15, 1980Assignee: John JanskyInventor: John Stofko
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Patent number: 4181553Abstract: A two component removable adhesive hanger is disclosed which has a hook support component with a bifurcated end folded to form a pair of hook support legs and adhesively secured to a backing sheet component, the backing sheet component having adhesive means thereon to secure the hanger assembly to the wall, or similar surface. A hook member is supported by the hook support legs to enable the hanging of an article thereon. The backing sheet component extends downwardly beyond the hook support legs so as to provide an increased adhesive area and to prevent the hook from bearing directly against the surface to which the hanger is attached. The hanger is removable by manually separating the hook support component from the backing sheet component and subsequently dissolving the backing sheet by the application of water. Both the hook support component and the backing sheet component may be made from water dissolvable paper or the hook support component may be made from metal, plastic or like material.Type: GrantFiled: April 13, 1978Date of Patent: January 1, 1980Assignee: Anchor Wire Corporation of TennesseeInventor: James W. Hogg
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Patent number: 4175996Abstract: A method of glueing articles of the tobacco industry such as cigarettes, cigarellos, cigars, filter tips, coupling sleeves, etc., characterized by the use of a glue which at ambient temperature is in gel form composed mainly of water and gelatine, the gelatine concentration being in the 25-180% range in relation to the water weight, and a minor quantity of plasticizer for the gelatine in aqueous solution, belonging to the food polymers group comprising natural and modified vegetable gums and cellulose ethers, the plasticizer's concentration being within the 0.25-8% range in relation to the weight of the gelatine alone, and being adjusted so that the temperature at which the liquefied gel viscosity remains superior to 50 centipoises and becomes lower than 1000 centipoises is within the 40-70.degree. C. range.Type: GrantFiled: March 2, 1978Date of Patent: November 27, 1979Assignee: Service d'Exploitation Industrielle des Tabacs et des AllumettesInventors: Jean-Claude Battard, Jean Buisson
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Patent number: 4141745Abstract: A proteinaceous adhesive composition in which a dry mix comprised of protein, solubilizing agents and fillers is added to water containing tetrahydrofurfuryl alcohol at the time of use. The adhesive composition is especially useful in joining untreated and fire-retardant-treated porous substrates to fire-retardant-treated porous substrates as well as joining a porous substrate to a relatively non-porous substrate and provides advantages of good bond strength and increased assembly time.Type: GrantFiled: November 8, 1976Date of Patent: February 27, 1979Assignee: National Casein of New JerseyInventor: Carolyn N. Bye
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Patent number: 4116740Abstract: This disclosure relates to a water resistant adhesive composition for use in the manufacture of corrugated board and its preparation. The adhesive is prepared by using a thin boiling or modified waxy variety starch of a fluidity of at least 25 as a component in the gelatinized carrier portion of the adhesive. This produces a high solids carrier which results in a final adhesive of good stability whose use enables corrugated board to be produced at faster than normal rates. This adhesive is particularly useful to increase production rates of heavy weight and multiwall board.Type: GrantFiled: July 18, 1975Date of Patent: September 26, 1978Assignee: Anheuser-Busch, IncorporatedInventors: Camillus B. Musselman, Edward M. Bovier
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Patent number: 4117183Abstract: A composition comprising water, finely particulate gypsum and starch is coated on a paper cover sheet in a selective pattern such that the starch composition is disposed only at limited areas of the bond liner surface, and wherein substantial areas of the bond liner surface are free of the coating; the coated paper, either in the wet stage or after drying being used as paper cover sheets to form gypsum wallboard by applying an aqueous slurry of calcined gypsum, which may be free of starch, to the coated surface and setting the gypsum, resulting in a gypsum wallboard having excellent adhesion between the paper cover sheets and the gypsum core.Type: GrantFiled: February 18, 1977Date of Patent: September 26, 1978Assignee: United States Gypsum CompanyInventor: William J. Long
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Patent number: 4107379Abstract: Solid lignocellulosic material is bonded together by heating and pressing with a bonding composition comprising at least one carbohydrate and an acid capable of catalysing hydrolysis of the carbohydrate, for example to make plywood or particle board.Type: GrantFiled: February 10, 1977Date of Patent: August 15, 1978Assignees: John Stofko, John JanskyInventor: John Stofko
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Patent number: 4070197Abstract: A gas impermeable hollow silicon carbide body is formed by slip-casting two separate hollow silicon carbide bodies, the two separate bodies are then cemented together by means of a silicon carbide slip and then the joined pieces are fired at a temperature sufficiently elevated to recrystallize the cast bodies and to form a recrystallized joint between the two pieces, thereafter the body is subjected to a silicon atmosphere to deposit sufficient additional silicon in the body to provide a structure which is essentially impermeable to gases.Type: GrantFiled: June 14, 1976Date of Patent: January 24, 1978Assignee: Norton CompanyInventor: Samuel H. Coes
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Patent number: 4014727Abstract: This disclosure relates to an adhesive composition for use in the manufacture of corrugated board and its preparation. The adhesive is prepared by using a thin boiling or modified waxy variety starch of fluidity of 25 or greater as a component in the gelatinized carrier portion of the adhesive. This produces a high solids carrier which results in a final adhesive of good stability whose use enables corrugated board to be produced at faster than normal rates. This adhesive is particularly useful to increase production rates of heavy weight and multiwall board.Type: GrantFiled: July 18, 1975Date of Patent: March 29, 1977Assignee: Anheuser-Busch, IncorporatedInventors: Camillus B. Musselman, Edward M. Bovier
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Patent number: 4009062Abstract: A specially prepared paper bond liner, gypsum wallboard, and gypsum wallboard process which bonds the liner to the core by an adhesive confined to the paper-core interface, the adhesive comprising certain starches placed on the bond liner in their raw state.Type: GrantFiled: May 2, 1975Date of Patent: February 22, 1977Assignee: United States Gypsum CompanyInventor: William J. Long
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Patent number: 4008116Abstract: The invention relates to an aqueous adhesive solution based on polyvinyl alcohol in combination with unboiled unoxidized alkali hydrolyzed neutralized starch for the mechanical labelling of bottles and glass vessels in high speed labelling machines. When dry the adhesive is resistant to condensation water. The solution has a polyvinyl alcohol content of 12% to 25%, based on the total weight of the solution and a thickener content of 0.1% to 1% by weight. The polyvinyl alcohol and starch are present in the weight ratio of 85% to 65% of polyvinyl alcohol, to 15% to 35% of unmodified, hydrolized starch.Type: GrantFiled: December 18, 1974Date of Patent: February 15, 1977Assignee: Henkel & Cie G.m.b.H.Inventor: Hans-Georg Sebel
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Patent number: 3997703Abstract: A multilayered molded plastic having at least one layer comprising pullulan. The molded plastic is low in gas permeability, transparent, high in strength and non-toxic.Type: GrantFiled: February 27, 1975Date of Patent: December 14, 1976Assignees: Sumitomo Chemical Company, Limited, Hayashibara Biochemical Laboratories, IncorporatedInventors: Seizo Nakashio, Kozo Tsuji, Nobuhiro Toyota, Fumio Fujita, Takami Sato
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Patent number: 3984275Abstract: An aqueous acidic adhesive composition is described comprising starch, polyvinylacetate, a copolymer of vinylacetate and ethylene and, optionally, a water-resistant thermosetting resin such as urea-formaldehyde or melamine-formaldehyde. The adhesive is particularly useful as a corrugator adhesive in the preparation of corrugated paperboard which requires a high wet bond strength. Because of its excellent "green bond" characteristics, the corrugators can be run at high speeds to produce a product having acceptable wet bond strengths with the important additional advantages that the bond is strong, tough and flexible.Type: GrantFiled: April 25, 1974Date of Patent: October 5, 1976Assignee: International Paper CompanyInventors: Leroy Charles Hofmann, Alexander Sadle