Amine- Or Amide-aldehyde Patents (Class 162/166)
  • Publication number: 20010018957
    Abstract: A papermaking stock and a method for improving the retention of pulp fines, mineral fillers, dispersed wood resin, and/or synthetic hydrophobic stickies and cellulose fibers in a cellulosic fiber sheet, employs dendrimeric polymers for increasing the retention of fines, fillers, dispersed hydrophobic particles, and cellulosic fibers. The application in the paper industry provides a means of (1) increasing the retention of fillers in paper and decreasing the loss of filler materials in white water waste from papermaking; (2) increasing the retention of cellulosic fines and fibers in the paper-making process; increasing drainage on the paper machine; and (3) removing a significant fraction of the wood resin, plastics, and stickies from the process stream thus enabling a greater extent of reuse of filtrates and, hence, less effluents from mills, fewer problems from wood resins such as deposit formation, loss of strength of product, and contamination of product with dirt particles.
    Type: Application
    Filed: April 4, 2001
    Publication date: September 6, 2001
    Inventors: Lawrence Harvey Allen, Marco Savio Polverari
  • Patent number: 6281291
    Abstract: A composition useful in paper and board making comprises a carboxylated surface size containing at least 40 mole percent of hydrophobic groups and at least about 25 mole percent of carboxylated groups such as styrene-(meth)acrylic aicd copolymers or styrene-maleic acid (anhydride or salt) copolymers, a hydrophilic polyacrylamide and a crosslinking agent such as glyoxylated vinylamide polymers, formaldehyde, melamine-formaldehyde condensates and glyoxyl-extended materials.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: August 28, 2001
    Assignee: Bayer Corporation
    Inventors: Rajiv Bazaj, Gerald Guerro, David Dauplaise
  • Patent number: 6270627
    Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: August 7, 2001
    Assignee: Nalco Chemical Company
    Inventors: Bruce A. Keiser, James E. Whitten
  • Patent number: 6261414
    Abstract: The present invention relates to a method of producing a laminate base material useful for preparing a prepreg or a laminate for electronic equipment such as printed board. The method comprises the steps of: (1) preparing a slurry comprising para-aramid fibers and curable phenolic resin fibers; (2) preparing a sheet from said slurry; (3) adding a resin binder to said sheet so as to bond the fibers with each other, thereby to form a combined non-woven fabric and (4) compressing said non-woven fabric under heating. According to the present invention, a prepreg or laminate is obtained which has an improved high-frequency characteristics and much less warp.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: July 17, 2001
    Assignee: OJI Paper Co., Ltd.
    Inventors: Yoshihisa Kato, Takekazu Adachi, Mamoru Murata
  • Patent number: 6254724
    Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: July 3, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
  • Patent number: 6207013
    Abstract: A process is disclosed for the manufacture of a hydrophilic, humectant, soft, pliant single-ply or multi-ply absorbent papers to which an organic permanent or temporary wet strength agent has been added. Also novel absorbent papers having temporary or permanent wet strength properties are disclosed. These are useful as bathroom tissue and napkins. These products are suitably also prepared using through air drying methods with or without the use of a Yankee dryer, and the products exhibit a unique combination of properties designed to appeal to consumer preferences. In many applications, these products need not be creped, and in that case they do not have the serpentine configuration.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 27, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 6207012
    Abstract: The invention relates to hydrophilic, humectant, soft, pliant, single-ply or multi-ply absorbent papers in the form of a towel. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and a softener which has a melting range of about 0°-40° C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.01 to 15 percent: wet pressing said nascent web, creping said web from said Yankee, and recovering the paper products.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 27, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 6203664
    Abstract: The invention relates to hydrophilic, humectant, soft, pliant, single-ply or multi-ply absorbent papers in the form of a bathroom tissue. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and a softener which has a melting range of about 0°-40°C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.01 to 15 percent: wet pressing said nascent web, creping said web from said Yankee, and recovering the paper products.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 20, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 6200418
    Abstract: The invention relates to hydrophilic, humectant, soft, pliant, single-ply or multi-ply absorbent papers in the form of a napkin. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and a softener which has a melting range of about 0°-40° C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.01 to 15 percent: wet pressing said nascent web, creping said web from said Yankee, and recovering the paper products.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 13, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 6193842
    Abstract: A is a process for preparing insulant boards based on mineral and paper fiber by slurrying mineral fiber, binder and customary additives in water, forming the insulant board by applying the slurry to a wire, and drying and consolidating the insulant board, which comprises using surface-active compounds to achieve faster and better drainage of the filter residues to be dried.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: February 27, 2001
    Assignee: Th Goldschmidt Ag
    Inventor: Manfred Schmuck
  • Patent number: 6190499
    Abstract: Wet pressed absorbent papers having temporary or permanent wet strength properties are disclosed. These are useful as bathroom tissue and napkins. In many applications, these products need not be creped, and in that case they do not have the serpentine configuration.
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: February 20, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 6179962
    Abstract: Process for making paper having improved strength characteristics by adding to the pulp water-soluble and/or water-dispersible cationic polymer and oxidized galactose type of alcohol configuration containing polymer.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: January 30, 2001
    Assignee: Hercules Incorporated
    Inventors: Richard Lee Brady, Raymond Thomas Leibfried, Sr., Tuyen Thanh Nguyen
  • Patent number: 6171444
    Abstract: Compositions and methods are provided for the sizing of paper, to enhance the quality of images printed thereon. The novel sizing compositions contain as a sizing agent a mixture of a polyacid and a polybase. When applied to a paper substrate, such as in an internal or external sizing process, the sizing compositions result in a sized paper substrate that provides high quality printed images when printed with an ink containing a reactive dye having ionizable and/or nucleophilic groups capable of reacting with the sizing agent. Images printed on a paper substrate coated with the sizing compositions of the invention are bleed-resistant, water-resistant (e.g., water-fast), and/or are characterized by an enhanced chroma and hue.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: January 9, 2001
    Assignee: SRI International
    Inventor: Asutosh Nigam
  • Patent number: 6162327
    Abstract: A multifunctional tissue paper product having a combination of good wet strength, flexibility and preferably absorbency. This combination allows the tissue paper to be strong enough for use as a paper towel, yet soft enough for use as a facial tissue.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: December 19, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Anjana Batra, David Louis DeAngelo, Arman Ebrahimpour
  • Patent number: 6153049
    Abstract: Ethyleneamine compound(s), or mixtures thereof, are used in effective amounts to reduce or inhibit the deposition of white pitch on the paper making equipment during the processing to recycle coated paper.
    Type: Grant
    Filed: March 25, 1998
    Date of Patent: November 28, 2000
    Assignee: The Dow Chemical Company
    Inventor: Alan P. Croft
  • Patent number: 6146497
    Abstract: Additives for addition to starting materials in cellulose based products for imparting strength and crepe. Additives for use in paper production which impart strength to the product and which can be used in creping adhesives. Enzyme activated resins for use in paper production. Enzyme-activated adhesives for use in paper production. Paper products comprising the aforementioned additives or resins. Methods for imparting strength or crepe to paper products.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: November 14, 2000
    Assignee: Hercules Incorporated
    Inventor: Tuyen T. Nguyen
  • Patent number: 6114435
    Abstract: Solutions of polymers containing vinylamine units, which solutions have a long shelf life, are prepared by hydrolyzing polymers containing N-vinylcarboxamide units with acids in an aqueous medium and removing the carboxylic acids eliminated from the polymers as esters from the aqueous polymer solution after the hydrolysis by adding at least stoichiometric amounts of at least one C.sub.1 -C.sub.6 -alcohol and distilling off the esters from the reaction mixture, and said aqueous solutions are used as dry and wet strength agents in papermaking.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: September 5, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Claudia Nilz, Manfred Winter, Michael Kroner, Andreas Stange, Rudolf Schuhmacher
  • Patent number: 6090242
    Abstract: Novel polymers are provided having phosphonated and sulphonated substituent groups such that the polymer is multifunctional in its use. Optional amide substituent are used to reduce electrostatic charge density or for hydrogen bonding. An advantage of the polymer is the flexibility of using it for multiple purposes. A particular application is for bonding paper fillers and paper fiber together.
    Type: Grant
    Filed: April 6, 1999
    Date of Patent: July 18, 2000
    Assignee: Minerals Technologies Inc.
    Inventors: Donald Kendall Drummond, Patrick Clinton Wernett
  • Patent number: 6017418
    Abstract: Hydrophilic, humectant, soft, pliant, single-ply or multiply absorbent papers in the form of napkin, towel, bathroom tissue or facial tissue are disclosed. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and ad a softener which has a melting range of about 0.degree.-40.degree. C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.
    Type: Grant
    Filed: May 6, 1997
    Date of Patent: January 25, 2000
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
  • Patent number: 5989391
    Abstract: A product obtained by reacting a sulfonated amino resin and an amino group-containing substance in a weight ratio of from 1:0.05 to 1:3.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: November 23, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Kiyomi Ema, Takaichi Sugiyama, Hisanobu Urahata, Michie Kaneko
  • Patent number: 5954921
    Abstract: The present invention relates to agents for the pulp and/or surface sizing of paper, which comprise aqueous, solventless dispersions of cationic polymers, and to a process for sizing paper by using said agent. The sizing agents according to the present invention which can be used both in pulp and surface sizing obtain as active substance copolymers ofa) 30-70 mole-% of a monomer Iwithb) 70-30 mole-% of a monomer II,and optionallyc) 0-20 mole-% of C.sub.8 -C.sub.30 monoolefins,andd) 0-10 mole-% of further monomers copolymerizable with a), b), and optionally c), the sum of monomers a), b), c), and d) amounting to 100 mole-%.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: September 21, 1999
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Kurt Dahmen, Richard Mertens, Thomas Muller, Johann Schulte
  • Patent number: 5942086
    Abstract: The invention relates to a process of applying a polyhydroxy high molecular weight polymer or like material to a substrate, comprising adding to a solution of such material in anionic form a flocculent of oppositely charged form in order to insolubilise such material, and thereafter applying such insolubilised material to said substrate. The invention has particular application in respect of production of paper by adding to the slurry supplied in paper production of an anionic starch and a cationic flocculent in predetermined amounts. The cationic polymer is preferably added prior to addition of the anionic starch. The cationic polymer preferably has a molecular weight of 150,000 or more and the anionic starch is preferably added in an amount of from 75% to 125% of the reaction ratio amount. Preferably, the cationic polymer flocculent is added in an amount of 0.5 kg or more per 1,000 kg of paper substrate and the anionic starch showing an amount of 2 kg or more per 1,000 kg of paper substrate.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: August 24, 1999
    Assignee: Philip Chem-Solv, Inc.
    Inventor: David Malcolm Owen
  • Patent number: 5871616
    Abstract: Enzymatic dehalogenation of undesirable nitrogen-free organohalogen compounds is carried out by adding a dehalogenase to an aqueous composition comprising a nitrogen-free organohalogen compound and a nitrogen-containing cationic polymer. The enzymatic dehalogenation of the nitrogen-free organohalogen compound is achieved without any substantial effect upon the nitrogen-free organohalogen compound. The dehalogenation method may be carried out via continuous, batch, or semi-continuous processes.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 16, 1999
    Assignee: Hercules Incorporated
    Inventors: Alan Bull, David J. Hardman, Brian M. Stubbs, Paul J. Sallis
  • Patent number: 5863385
    Abstract: The present invention relates to the use of oil-in-water emulsions to clean machines and parts of plants in the production of pulp, paper, paper board, and cardboard and to prevent impurities of adhesives and adherent resins to those units.The emulsion comprises as component of the oil phase at least one of the following substances:1. a saturated or unsaturated, open-chain or cyclic, normal or isomeric hydrocarbon with 8-30 carbon atoms2. a saturated or unsaturated fatty alcohol, a saturated or unsaturated fatty acid, a fatty acid monoalkylester, a fatty acid amide or a fatty acid monoalkylamide of a saturated or unsaturated fatty acid, all of the compounds mentioned under 2. having 8 to 30 carbon atoms3. a mono- or polyester of a saturated or unsaturated, mono- or multivalent carboxylic acid with 2 to 30 carbon atoms and polyols, with the exception of polyethylene glycols4. a polyamide of saturated or unsaturated fatty acids with 8 to 30 carbon atoms and aliphatic polyamides with two to six nitrogen atoms5.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: January 26, 1999
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Frank Siebott, Joachim Werres
  • Patent number: 5853542
    Abstract: Paper sizing enhancer that is a polymerization reaction product of a quaternary diallylammonium monomer and a diallylammonium monomer, as well as compositions containing the sizing enhancer and a sizing agent. The method of sizing paper with such paper sizing enhancer compound and a sizing agent provides sized paper with significantly improved sizing property characteristics, and the sized paper exhibits high print quality when used in inkjet printing applications.
    Type: Grant
    Filed: September 11, 1995
    Date of Patent: December 29, 1998
    Assignee: Hercules Incorporated
    Inventor: Kyle J. Bottorff
  • Patent number: 5830320
    Abstract: The invention is a method of enhancing the strength of paper products, particularly the dry strength, without adversely affecting repulpability. It is also directed to the resulting products. It is particularly applicable but not limited to products with significant amounts of secondary fiber in the furnish. Preferably, about 10-30% of the fiber is separated from the furnish at some point prior to sheeting. This is treated with a cationic wet strength resin which is allowed to bond to the fiber. Cationic polyamide-epichlorohydrin resins are particularly useful. The treated fiber is them mixed with the untreated balance of the fiber at some point before the paper machine. Screnning fines on repulping do not normally exceed 2-3%.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: November 3, 1998
    Assignee: Weyerhaeuser Company
    Inventors: David W. Park, Frank R. Hunter
  • Patent number: 5824190
    Abstract: Compositions containing hydrophilic polyacrylamide and hydrophobic surface size agents and the methods for using such compositions in paper and board to improve printability, sizing and strength are provided in the instant invention.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: October 20, 1998
    Assignee: Cytec Technology Corp.
    Inventors: Gerald Guerro, David Dauplaise, Rajiv Bazaj
  • Patent number: 5824192
    Abstract: Disclosed is a method for the production of paper and an adjuvant composition comprising the following ingredients: 30 to 80% by weight of phenolic resin or modified phenolic resin; 10 to 50% by weight of melamine resin; and 5 to 35% by weight of at least one naphthalene sulphonate salt. The ingredients are under granulated form or dissolved in an aqueous solution. The method comprises the step of admixing the adjuvant composition with a solution of one or several polyethylene oxide having a molecular weight varying from 1.times.10.sup.6 to 13.times.10.sup.6 and with an aqueous mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibers, on a wire screen and the drainage of the aqueous medium.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: October 20, 1998
    Assignee: E. QU. I. P. International Inc.
    Inventor: Georges Radu
  • Patent number: 5804035
    Abstract: A process is dislcosed for recovering chips and fibers from residues of ter-derived materials, old pieces of furniture, production residues, water and other timber-containing materials glued with urea-formaldehyde binders or other binders capable of being hydrolysed or chemically disintegrated by disintegrating the timber-derived materials at a high temperature. In a first step of the process, the residues of timber-derived materials are impregnated with an impregnating solution and previously swollen until they have absorbed at least 50% of their own weight of impregnating solution. In a second step, the thus impregnated residues of timber-derived materials are heated up to 80.degree. C. to 120.degree. C. The thus disintegrated residues of timber-derived materials are then sorted by sieving and/or wind screening. The residues of timber-derived material have edges of at least 10 to 20 cm length.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: September 8, 1998
    Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung e.V.
    Inventors: Andreas Michanickl, Christian Boehme
  • Patent number: 5785813
    Abstract: An efficient and effective method for treating tissue making stock to make soft tissues involves adding a softening agent to a first papermaking furnish of short fibers, such as eucalyptus fibers. A second papermaking furnish of long fibers, such as softwood fibers, is blended with the short fiber furnish. Thereafter, wet strength agents and/or dry strength agents are added to the blended furnish. The treated furnish is then fed to a headbox and processed into soft tissue in any suitable manner.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: July 28, 1998
    Assignee: Kimberly-Clark Worldwide Inc.
    Inventors: Michael John Smith, Vinay Kumar Rao, Gary Lee Shanklin
  • Patent number: 5762799
    Abstract: A filtering medium in the form of a sheet of paper for filters for fluids in general, wherein the paper impregnating agent is an aqueous emulsion of:an anionic aqueous disperse system of a copolymer based on n-butylacrylate-styrene.Dosage: 20%-50% by weight;an aqueous disperse system of a copolymer which can be thermally cross-linked and is based on butyl acrylate and acrylonitrile.Dosage: 30%-70% by weight;an aqueous disperse system of melamine-formaldehyde resin, etherified with methanol.Dosage: 1%-20% by weight;an aqueous disperse system of fluorocarbon resin.Dosage: 5%-40% by weight;an aqueous emulsion of organopolysiloxane.Dosage: 0%-15% by weight.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: June 9, 1998
    Assignee: Fad-Fabriano Autoadesivi S.p.A.
    Inventor: Gianmaria Dadea
  • Patent number: 5738759
    Abstract: A recording material including paper containing cellulose fibers as the main component, with the elongation percentage of the paper in the cross direction thereof when immersed in water at 20.degree. C. for 1 minute being 1.8 % or less, is produced and recycled. In addition, paper containing cellulose fibers, with the same elongation percentage as mentioned above in the machine direction thereof is also provided.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: April 14, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Kitazawa, Shigeaki Kimura, Eiichi Kawamura, Toshiyuki Kawanishi, Masato Igarashi
  • Patent number: 5730839
    Abstract: The invention consists of soft, bulky tissue products that result from the presence of a debonder/softening agent in the outer layers of the tissue and creping under "closed" pocket conditions. The debonder/softening agents belong to a group of organic chemicals that include several imidazolinium quaternary compounds. These chemicals do not adversely interfere with adhesion, unlike most debonders, to the drying surface of the tissue machine. They can, therefore, be placed in the outer layers of the tissue that contact the dryer surface and improve creping. The tissue can then be creped off of the drying surface using a closed pocket, that is a pocket angle of less than 80 degrees. The closed pocket creping normally produces a thicker, less dense tissue but with coarse crepe. Closed pocket creping and the presence of most debonders in the dryer side layers would be expected to also produce coarse crepe structures.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: March 24, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Greg Arthur Wendt, Gary Vance Anderson, Kelly Steven Lehl, Stephen John McCullough, Wen Zyo Schroeder
  • Patent number: 5695610
    Abstract: Aqueous pigment slurries which contain up to 80% by weight of a finely divided pigment in dispersed form and from 0.1 to 5% by weight of a water-soluble reaction product of(a) a polyamidoamine grafted with ethyleneimine and(b) a bifunctional or polyfunctional crosslinking agents which have a halohydrin, glycidyl, aziridine or isocyanate unit or a halogen atom as a functional group,the reaction product, in 25% strength by weight aqueous solution at 20.degree. C., having a viscosity of at least 100 mPa.s, are used as an additive to the paper stock in the production of filler-containing paper.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: December 9, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Auhorn, Friedrich Linhart, Dietmar Monch, Jurgen Weiser, Primoz Lorencak
  • Patent number: 5688371
    Abstract: Process for fixing anionic interfering substances in papermaking process by the addition of cationic polycondensation products obtained by reactinga) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups withb) cyanamide, dicyandiamide, guanidine or biguanidine, wherein up to 50 mol. % of cyanamide, dicyandiamide or biguanidine may be replaced with a dicarboxylic acid or a mono- or diester thereof, with elimination of ammonia, optionally in the presence of a catalyst,optionally together with other auxiliaries.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: November 18, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Konig, Jurgen Kopp, Udo-Winfried Hendricks, Jurgen Reiners, Peter Nowak
  • Patent number: 5667635
    Abstract: A pre-moistened wet wipe provides functional wet strength in use, yet is dispersible if flushed down the toilet so that plumbing and sewage treatment facilities do not become clogged. A particular embodiment of the wipe consists of three uncreped through-air-dried tissue plies that are attached to each other by edge embossing. The two outer plies contain a wet strength agent to provide wet poke-through resistance to two large, centrally-located unembossed regions. The center ply contains no wet strength agent to aid in dispersibility. The embossing around the edges of the wipe further degrades the strength of the wipe in the embossed areas to assist in dispersibility when the wipe is flushed.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: September 16, 1997
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Maug Hla Win, Mark Alan Burazin, Steven Alexander Engel, Bernhardt Edward Kressner, William Dee Lloyd, Walter Theodore Schultz
  • Patent number: 5626720
    Abstract: A method for the control of pitch in an aqueous system used in pulp or paper making is disclosed which comprises adding to the system, or to the pulp making or paper making machinery, a water soluble polymer derived from (a) an epihalohydrin, a diepoxide or a precursor of an epihalohydrin or diepoxide, (b) an alkyl amine having a functionality with respect to an epihalohydrin of 2 and (c) an amine which has a functionality with respect to an epihalohydrin greater than 2 and which does not possess any carbonyl groups.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: May 6, 1997
    Assignee: W.R. Grace & Co.-Conn.
    Inventor: Thord Gustav G. Hassler
  • Patent number: 5622786
    Abstract: An improved-strength, polymer-reinforced paper which includes fibers, of which at least about 30 percent on a dry weight basis are eucalyptus fibers; and from about 15 to about 60 percent by weight, based on the dry weight of the fibers, of a latex binder.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: April 22, 1997
    Assignee: Kimberly-Clark Corporation
    Inventors: Robert E. Weber, Linda G. Harris, Amy B. Reed
  • Patent number: 5597448
    Abstract: Pitch in paper mills is controlled by treating paper mill systems with a water soluble polymer which contains a lower alkyl N-vinyl amide or a hydrolyzed lower alkyl N-vinyl amide.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: January 28, 1997
    Assignee: Nalco Chemical Company
    Inventors: Peter E. Reed, Carol S. Greer
  • Patent number: 5595828
    Abstract: An improved-strength, polymer-reinforced paper which includes fibers, of which at least about 30 percent on a dry weight basis are eucalyptus fibers; and from about 15 to about 60 percent by weight, based on the dry weight of the fibers, of a latex binder.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: January 21, 1997
    Assignee: Kimberly-Clark Corporation
    Inventors: Robert E. Weber, Linda G. Harris, Amy B. Reed
  • Patent number: 5547541
    Abstract: A densifying agent is applied to fibers in order to improve the densification properties of the fibers. The fibers have hydrogen bonding functional groups. The densifying agent are denser than the fibers to which the densifying agent is applied. The densifying agent can be organic or inorganic. The improved densification properties are observed without the presence of particles bound to the fibers or in the presence of particles that are not bound to the fibers. Softening agents can also be applied to the fibers in order to soften the fibers and articles including such fibers. Softening agents may be selected from the group of densifying agents.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: August 20, 1996
    Assignee: Weyerhaeuser Company
    Inventors: Michael R. Hansen, Richard H. Young, Sr.
  • Patent number: 5498315
    Abstract: A method of enhancing the opacity of paper and paper of enhanced opaqueness is provided wherein a reaction product of dimerized acid and alkanol diamine an further including a surfactant, is added to a slurry of cellulose fibers in a papermaking process. A viscosity controlling gent may be added to the reaction product.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: March 12, 1996
    Assignee: Sequa Chemicals, Inc.
    Inventors: Louis R. Dragner, Bernard F. North
  • Patent number: 5494555
    Abstract: A method of enhancing the opacity of paper and paper of enhanced opaqueness is provided wherein a reaction product of fatty acid, diamine and a glyoxal product an further including a surfactant, is added to a slurry of cellulose fibers in a papermaking process.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: February 27, 1996
    Assignee: Sequa Chemicals, Inc.
    Inventors: Louis R. Dragner, Bernard F. North
  • Patent number: 5470434
    Abstract: Decay-resistant paper suitable for the manufacture of a pot for raising and transplanting seedling is the one partly containing decayable portions, which is prepared by heating paper made of a natural fiber, or a fiber blend composed of a natural fiber and a synthetic fiber, and impregnated with a compound capable of crosslinking the paper cellulose, at a temperature causing the reaction of antidecay treatment and at a temperature causing no such reaction in different portions. Such decay-resistant paper partly containing decayable portions can be easily prepared by bringing the above-mentioned paper impregnated with a compound capable of crosslinking the paper cellulose into contact in a single step with a heating apparatus comprising a heating part of a temperature causing the reaction of antidecay treatment and a heating part of a temperature causing no such reaction.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: November 28, 1995
    Assignee: Nihon Tensaiseito Kabushiki Kaisha
    Inventors: Hidekazu Terasawa, Masashi Tanimura, Sumio Ito
  • Patent number: 5445878
    Abstract: A urea-formaldehyde resin modified with a water-insoluble anionic phosphate ester is used as binder in the preparation of glass fiber mats using a hydroxyethyl cellulose white water system. High tear strength glass fiber mats can be produced in a hydroxyethyl cellulose white water system using such a binder.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: August 29, 1995
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: George E. Mirous
  • Patent number: 5368694
    Abstract: A method for controlling or inhibiting the deposition of pitch derived from aqueous pulp suspensions having a neutral or cationic soluble charge onto paper machine equipment surfaces which contact the pulp, comprising a) contacting the pulp with an anionic polymer in an amount sufficient to maintain an anionic charge in the pulp and b) contacting the paper machine equipment surfaces with a cationic polymer in an amount sufficient to inhibit the deposition of pitch deposits thereon.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: November 29, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Evan V. Rohlf, Fletcher Walley, Richard J. Wagner
  • Patent number: 5350612
    Abstract: A multi-ply, wet-strength, removable label or coupon for packages intended for retail use, particularly suitable for items where refrigeration and/or condensation is a condition of the product life cycle. The coupon structure includes a base ply formed of moisture resistant, wet-strength paper with printable or coatable upper and under sides. The base ply is adhered to a removable top ply with a combination of bonding agents and release coatings. The top ply may also be moisture resistant. The coupon structure is preferably supplied in a cut-sheet format for convenient use and storage.
    Type: Grant
    Filed: August 4, 1992
    Date of Patent: September 27, 1994
    Assignee: Beckett Corporation
    Inventors: Michael D. Stern, Stephen G. Dudley, Dale D. Reschenberg
  • Patent number: 5320711
    Abstract: Compositions comprising microparticles of a cross-linkable, glyoxalated (meth)acrylamide containing, polymeric material are disclosed. They are prepared using inverse microemulsion polymerization techniques and are useful as wet- and dry-strength agents in paper production.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: June 14, 1994
    Assignee: Cytec Technology Corp.
    Inventors: David L. Dauplaise, Joseph J. Kozakiewicz, Joseph M. Schmitt
  • Patent number: 5300194
    Abstract: Accumulation of pitch or stickies in pulp or paper making is controlled by applying to the pulp or paper making equipment which is not in continuous contact with water separately a water soluble cationic polymer and a water soluble anionic polymer.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: April 5, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Ulrich Welkener, Thord Hassler
  • Patent number: 5286347
    Abstract: A method for inhibiting the deposition of pitch on and/or for removing pitch from the surfaces of pulping and papermaking machinery by adding an effective amount of a melamine formaldehyde-type polymer to a pulp slurry or furnish in contact with said machinery.
    Type: Grant
    Filed: May 5, 1992
    Date of Patent: February 15, 1994
    Assignee: Calgon Corporation
    Inventor: Paul F. Richardson