Incorporation Procedures Patents (Class 162/183)
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Patent number: 7922867Abstract: Process for the production of paper, board and cardboard having high dry strength by separate addition of a polymer comprising vinylamine units and of ligninsulfonic acid and/or a ligninsulfonate to a paper stock, draining of the paper stock and drying of the paper products.Type: GrantFiled: March 9, 2007Date of Patent: April 12, 2011Assignee: BASF SEInventors: Norbert Schall, Ellen Krueger, Martin Ruebenacker
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Patent number: 7918965Abstract: Process for the production of paper, board and cardboard by draining a paper stock with sheet formation in the presence of a retention aid system comprising (i) at least one polymer comprising vinylamine units, in the form of the free bases, of the salts and/or in quaternized form, as the sole cationic polymer, (ii) at least one linear, anionic polymer having a molar mass Mw of at least 1 million and/or at least one branched, anionic, water-soluble polymer and/or bentonite and/or silica gel and (iii) at least one particulate, anionic, crosslinked, organic polymer having a mean particle diameter of at least 1 ?m and an intrinsic viscosity of less than 3 dl/g, and use of the retention aid system comprising the components (i), (ii) and (iii) as an additive in the production of paper, board and cardboard.Type: GrantFiled: September 5, 2006Date of Patent: April 5, 2011Assignee: BASF AktiengesellschaftInventors: Marc Leduc, Oliver Koch, Simon Champ, Rainer Blum, Andreas Merkel, Knut Menke
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Patent number: 7815771Abstract: A process for the manufacture of paper, board or similar products, comprises first of all, adding, to the paper pulp fibrous suspension, at least one main retention aid composed of a cationic (co)polymer. Then optionally the flocs obtained are sheared. Subsequently there is added to the suspension, separately or as a mixture, in any order: at least one secondary retention aid chosen from the group consisting of silica derivatives and anionic or amphoteric organic polymers, and at least one tertiary retention aid composed of a crosslinked anionic organic polymer with a size of greater than or equal to 1 micrometer and exhibiting an intrinsic viscosity of less than 3 dl/g.Type: GrantFiled: November 8, 2004Date of Patent: October 19, 2010Assignee: SNF S.A.S.Inventors: Gatien Faucher, Rene Hund, Christian Jehn-Rendu
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Patent number: 7794566Abstract: The present invention is a method of making a near-premium quality paper product having good strength and absorbency characteristics and a product made by that method. The invention is also a method for retaining a high ash content within a paper web formed by conventional wet pressing. The present invention is also a method for retaining a high percentage of softening agent within a paper web that includes such an agent. Further, the present invention is a soft absorbent paper product having a high void volume. Finally, the invention is also a method for producing a soft, absorbent, and near premium paper product having a high void volume using an undulatory crepe blade having a multiplicity of serrulations in its rake surface which presents differentiated creping angles and/or rake angles as to the paper being creped.Type: GrantFiled: October 15, 2004Date of Patent: September 14, 2010Assignee: Georgia-Pacific Consumer Products LPInventors: Steven L. Edwards, David W. White, Frank D. Harper, John H. Dwiggins
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Patent number: 7691233Abstract: Temporary wet strength additives, more particularly, temporary wet strength additives comprising a polymer backbone, wherein the polymer backbone has an internal homo-crosslinking monomeric unit, a co-crosslinking monomeric unit and a cationic monomeric unit, wherein the homo-crosslinking monomeric unit is derived from a monomer having the following structure: and X is —O—,—NH—, or —NCH3—; and R2 is a substituted or unsubstituted aliphatic groups; and Y3 is —H, —CH3, or a halogen, fibrous structures including such temporary wet strength additives, sanitary tissue products containing such fibrous structures and processes for making such fibrous structures and/or such sanitary tissue product are provided.Type: GrantFiled: June 21, 2007Date of Patent: April 6, 2010Assignee: The Procter & Gamble CompanyInventors: Robert Lee Barcus, Khosrow Parviz Mohammadi, Angela Marie Leimbach, Stephen Robert Kelly
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Patent number: 7682488Abstract: A method of forming a cellulosic web is discussed, the product of which may, for example, possess at least one of increased softness, strength, and absorbency. The method measures the total anionic charge and controls the net charge of an aqueous stream.Type: GrantFiled: June 27, 2007Date of Patent: March 23, 2010Assignee: Georgia-Pacific Consumer Products LPInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Patent number: 7638017Abstract: The invention concerns a pigment, filler or mineral containing a natural calcium carbonate, treated with one of more providers of H3O+ ions and gaseous CO2, allowing a reduction in the weight of paper for a constant surface area without loss of physical properties when it is used as a pigment or coating filler for the said paper. In particular, the invention concerns a pigment, filler or mineral containing a natural calcium carbonate or dolomite or mixtures of talc and calcium carbonate, of kaolin and carbonate or carbonate alone or in combination with natural and/or synthetic fibres or similar, treated with one or more medium-strong or strong providers of H3O+ ions in the presence of gaseous CO2. Applications are particularly in the paper industry, obtaining in particular good sheet properties i.e. a reduction its weight for a given surface area.Type: GrantFiled: July 30, 2003Date of Patent: December 29, 2009Assignee: Omya Development AGInventors: Patrick A. C. Gane, Matthias Buri, Rene Vinzenz Blum, Beat Karth
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Patent number: 7585392Abstract: A method of making absorbent cellulosic sheet with increased wet/dry CD tensile ratio includes treating the fiber at high consistency with debonder in a pulper, for example. The process enables the use of large amounts of debonder in a wet-press process in order to achieve wet/dry CD tensile ratios of greater than 30%.Type: GrantFiled: October 4, 2007Date of Patent: September 8, 2009Assignee: Georgia-Pacific Consumer Products LPInventors: Bruce J. Kokko, Steven L. Edwards
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Publication number: 20090218060Abstract: Fluorescent nanoparticles such as quantum dots are incorporated into paper and other web products such as plastics to achieve cross-direction and machine direction on-line detection of selected components during manufacture. Fluorescent nanoparticles markers are added in known proportions into product formulations along with the selected components of interest. By detecting the fluorescence from the nanoparticles, the selected components can be traced at various stages of production. In addition, by using different fluorescent nanoparticles that emit radiation at different wavelengths, data from individual materials or layers in a composite structure can be ascertained simultaneously with a single sensor. The technique is particularly suited for monitoring expensive and difficult-to-measure components that may be present only in trace quantities.Type: ApplicationFiled: February 28, 2008Publication date: September 3, 2009Inventors: Michael Kon Yew Hughes, Sebastian Yoder
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Patent number: 7582188Abstract: A composition includes an alkenyl succinic anhydride sizing agent or an alkyl ketene dimer sizing agent. The alkenyl succinic anhydride sizing agent is present in an amount ranging from about 1.0 pounds per ton to about 4.0 pounds per ton. The alkyl ketene dimer sizing agent is present in an amount ranging from about 2.0 pounds per ton to about 10.0 pounds per ton. A metallic salt is also incorporated in the composition.Type: GrantFiled: October 14, 2005Date of Patent: September 1, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: John L. Stoffel, Hai Q Tran, Ronald A. Askeland, Lawrence E Gibson, Steven D Schultz, Michael F Koenig, Sen Yang, William R Sperry, Richard R Hartman
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Patent number: 7578903Abstract: The invention is directed to obtain a colored sanitary tissue paper giving a bright feeling in spite of modest color. The invention provides a colored sanitary tissue paper with a color difference between before and after dyeing of 15 or more in D value of Hunter's color difference formula defined in JIS Z 8730; D=(?L2+?a2+?b2)1/2.Type: GrantFiled: December 2, 2004Date of Patent: August 25, 2009Assignee: Daio Paper CorporationInventors: Tetsuya Uehara, Minoru Iwasaki
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Patent number: 7553395Abstract: Print media and methods of making print media are disclosed. One exemplary print medium, among others, includes a substrate having a fibrous component. In addition, a cationic guanidine polymer compound or salt thereof and a metallic salt are each disposed within the fibrous component of the substrate.Type: GrantFiled: April 2, 2004Date of Patent: June 30, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: John L Stoffel, Bill Sperry, Richard J McManus, Hai Q Tran, Yi-Hua Tsao
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Patent number: 7547376Abstract: The invention provides a paper quality improver for papermaking that allows improvement in the bulky value and the optical properties such as brightness and opacity as well as in the paper strength of a sheet obtained by papermaking a pulp material. The paper quality improver for papermaking is a paper quality improver for papermaking containing a copolymer (A) having a constituent unit derived from at least one nonionic monomer having a solubility parameter of 20.5 (MPa)1/2 or less and a constituent unit derived from at least one anionic or cationic monomer and a surfactant (B) at a certain ratio, the quality improver providing at least one paper quality improving effect of: (i) standard improved bulky value: 0.02 g/cm or more; (ii) standard improved opacity: 1.0 point or more; and (iii) standard improved brightness: 0.5 point or more.Type: GrantFiled: July 17, 2003Date of Patent: June 16, 2009Assignee: Kao CorporationInventor: Haruyuki Satoh
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Publication number: 20090139676Abstract: The invention provides a method and apparatus for optimally feeding an ASA emulsion into a papermaking process. An intense transmission of ultrasonic energy rapidly and efficiently forms an ASA emulsion. Nearly simultaneous to forming the emulsion, the emulsion is fed into a high-speed dual conduit feeding apparatus, which quickly mixes the ASA emulsion with other chemicals and feeds the mixture directly into a papermaking process. The invention operates so fast that virtually no hydrolysis of the ASA occurs. This both prevents damage to the papermaking machinery and improves the quality of the produced paper. The invention operates 10-20 times faster than mechanical based emulsion methods and requires 1/7 as much energy to operate. The invention also self-monitors the process and can automatically correct any detected problems with the fed ASA emulsion.Type: ApplicationFiled: February 9, 2009Publication date: June 4, 2009Inventors: Aleksandar Todorovic, Tommy Jacobson
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Patent number: 7534323Abstract: Use for the oleo-repellent paper sizing of carboxylic perfluoropolyethers of formula T-O—Rf-T??(I) wherein T=—CF2—COOH or —CF2CF2—COOH and Rf is a (per)fluoropolyoxyalkylene chain.Type: GrantFiled: June 2, 2004Date of Patent: May 19, 2009Assignee: Solvay Solexis, S.p.A.Inventors: Paolo Iengo, Piero Gavezotti
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Patent number: 7504000Abstract: The invention relates to a method for producing a sheet of paper (6) comprising paper fibres and calcium carbonate mainly in the form of calcite crystals linked directly to the paper fibres. The inventive method is characterised in that it comprises the following steps:—(i) an aqueous composition comprising calcium bicarbonates (5) and/or hydrated and/or dissolved carbon dioxide (3) and (ii) an aqueous composition comprising calcium hydroxide (4) are mixed in an aqueous medium in such a way as to precipitate the calcium carbonate in the form of vaterite crystals;—paper fibres (2, 2?) are immediately added;—the vaterite crystals are left to transform into calcite crystals on contact with the fibres;—said mixture containing the calcite crystals which are fixed to the fibres is subsequently sent on the conveying wire of the papermaking machine (M) for drainage and so that the sheet of paper can be formed;—the sheet of paper (6) thus obtained is treated, if necessary, and dried.Type: GrantFiled: February 14, 2002Date of Patent: March 17, 2009Assignee: ArjowigginsInventor: Christian Richard
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Patent number: 7504001Abstract: The objective of the present invention is to provide a papermaking method that can enhance the retention in the papermaking steps. This invention provides a method including making paper by adding to pulp slurry a silica sol which is prepared through a reaction between an aqueous solution of sodium silicate and a mineral acid, and which has, under a SiO2 concentration from 15 to 50 g/L wherein the value of the concentration is shown by [C], a viscosity from 0.12×[C] mPa·s to 15 mPa·s measured at 25° C, and a cationic component and/or an amphoteric component.Type: GrantFiled: March 31, 2003Date of Patent: March 17, 2009Assignees: Seiko PMC Corporation, Tokuyama CorporationInventors: Masanori Kosuga, Masatomi Ogawa, Yoshiaki Koga
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Patent number: 7494565Abstract: The invention discloses a paper or paperboard produced from a slurry comprising cellulose fibers and an effective amount of SMS. In addition, a method for increasing retention and dewatering during the papermaking process is also disclosed. The method involves the addition of an effective amount of SMS to said papermaking process. The invention also discloses a method for increasing retention and drainage in a papermaking process comprising the steps of: adding both an effective amount of starch and an effective amount of SMS to a slurry of said papermaking process, wherein said starch is selected from the group consisting of: tapioca starch; potato starch; corn starch; waxy maize starch; rice starch; and wheat starch. Moreover, the invention comprises a method for increasing retention and drainage in a papermaking process comprising the steps of: adding both an effective amount of modified starch and an effective amount of SMS to a slurry of said papermaking process.Type: GrantFiled: June 1, 2006Date of Patent: February 24, 2009Assignee: Nalco CompanyInventors: Laura M. Sherman, Jane B. Wong Shing, James G. Smith
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Publication number: 20090029902Abstract: Combinatorially generated peptides are provided that have binding affinity for calcium carbonates. The peptides may be used to deliver benefit agents to various calcium carbonate surfaces.Type: ApplicationFiled: July 26, 2007Publication date: January 29, 2009Inventors: SCOTT D. CUNNINGHAM, Steven Dale Ittel, John P. O'Brien, Pierre E. Rouviere
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Patent number: 7476272Abstract: The present invention relates to Aluminum trihydrate slurries comprising aluminum trihydrate particles, an acrylic dispersant, citric acid, synthetic hectorite clay, optionally a compound to adjust pH, a biocide and water. These slurries may be mixed with titanium dioxide slurries to produce a stable slurry blends useful in paper and paper-board applications.Type: GrantFiled: November 29, 2006Date of Patent: January 13, 2009Assignee: E.I. Du Pont de Nemours & CompanyInventors: Maureen A. Defeo, Glenn Richard Evers, Patrick F. McIntyre
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Patent number: 7473334Abstract: A method of preparing a modified diallyl-N,N-disubstituted ammonium halide polymer and use of the polymer in combination with one or more high molecular weight, water soluble cationic, anionic, nonionic, zwitterionic or amphoteric polymers for increasing retention and drainage in a papermaking furnish.Type: GrantFiled: October 15, 2004Date of Patent: January 6, 2009Assignee: Nalco CompanyInventors: Jane B. Wong Shing, Alessandra Gerli, Xavier S. Cardoso, Angela P. Zagala, Przem Pruszynski, Cathy C. Doucette
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Patent number: 7459059Abstract: The invention discloses a paper or paperboard produced from a slurry comprising cellulose fibers and an effective amount of SMS. In addition, a method for increasing retention and dewatering during the papermaking process is also disclosed. The method involves the addition of an effective amount of SMS to said papermaking process.Type: GrantFiled: September 21, 2005Date of Patent: December 2, 2008Assignee: Nalco CompanyInventors: Bruce A. Keiser, Laura M. Sherman
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Publication number: 20080257509Abstract: The present invention relates to a method for reducing the spreading of additional agent(s) which is/are introduced into the process at a papermaking machine. A flowable paper pulp including fibres and a process liquid and having a consistency of not more than 10% is conducted towards the paper machine's headbox (5). Prior to the introduction (14) of said additional agent the consistency of the pulp is increased to a value higher than 10% by removing (8) process liquid and conducting (11) it in the upstream direction, while compensating process liquid is introduced (13) downstream. The present invention also relates to an arrangement at a paper machine, where separating means (8) are arranged in the process direction before means (14) for introducing additional agent (s).Type: ApplicationFiled: June 28, 2005Publication date: October 23, 2008Inventors: Paul Olof Meinander, Risto Nykanen, Ken Meine
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Publication number: 20080245493Abstract: A board capable of capturing and decomposing both formaldehyde and acetaldehyde comprises a wood fiber board comprising a plant fiber of 30 wt % or more, and an aldehyde capturing agent comprising at least carbodihydrazide which is impregnated and solidified inside the side of the fiber board. In addition to the wood fiber board, a fiber board made of a mixture material of a resin fiber and a plant fiber combined. A carbodihydrazide is sprayed onto the fiber board in the form of water solution and optionally comprises a surfactant.Type: ApplicationFiled: September 25, 2007Publication date: October 9, 2008Applicant: NICHIHA CORPORATIONInventors: Tsutomu Nishio, Akira Hatano, Manabu Kuki
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Publication number: 20080066880Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, dispersion micropolymer in a salt solution.Type: ApplicationFiled: September 14, 2006Publication date: March 20, 2008Inventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian
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Patent number: 7344621Abstract: A paper additive composition comprising an amide compound (a) obtained by reacting a polyamine and a carboxylic acid or a salt of the amide compound (a) is provided. The polyamine is shown by formula (1): R—(NH—R1)n-NH2??(1) (wherein R is H2N—R1 or R2, and each R1 is independently an alkylene group having 1 to 4 carbon atoms, R2 is an alkyl group or alkenyl group having 12 to 22 carbon atoms, and n is an integer of 1 to 3); the number of carbon atoms of the carboxylic acid is 10 to 24; the amide compound is obtained by reacting the carboxylic acid at a ratio of 0.5 to 4.3 moles per 1 mol of the polyamine; and the ratio of a tertiary amine value to a total amine value of the amide compound (a) is 0.60 to 0.99.Type: GrantFiled: March 23, 2004Date of Patent: March 18, 2008Assignee: NOF CorporationInventors: Yasuyuki Nakamura, Tetsuya Tamai, Kazumichi Asakura
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Patent number: 7320740Abstract: The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.Type: GrantFiled: June 21, 2005Date of Patent: January 22, 2008Assignee: Rayonier TRS Holdings Inc.Inventors: Othman A. Hamed, Harry J. Chmielewski, Dana B. McBee
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Patent number: 7318881Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, a sizing dispersion comprising a polymer having an aromatic group, and a sizing promoter comprising a polymer having an aromatic group, wherein the sizing dispersion and the sizing promoter are added separately to the aqueous suspension.Type: GrantFiled: May 10, 2004Date of Patent: January 15, 2008Assignee: Akzo Nobel N.V.Inventors: Erik Lindgren, Sten Frölich, Michael Persson, Barbro Magnusson
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Publication number: 20070277949Abstract: The present invention relates to a process for the production of paper which comprises: (a) providing an aqueous cellulosic suspension; (b) separately adding to the suspension: (i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper. The invention further relates to a process in which a nitrogen-containing organic compound having a molecular weight less than 1,000 is mixed with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix and which premix is added to the suspension.Type: ApplicationFiled: May 31, 2007Publication date: December 6, 2007Applicant: AKZO NOBEL N.V.Inventors: Jonas Liesen, Jeanette Risen, Kristina Mohlin, Agneta Lernbrink
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Patent number: 7285184Abstract: A cellulosic pulp, method of producing the pulp, and associated paper product produced therefrom produced by providing mercerized cellulosic fibers and depositing a hemicellulose coating upon the mercerized fibers. The hemicellulose is deposited upon the fibers by combining a hemicaustic solution with the mercerized fibers in the presence of an acidifying agent. When formed into a paper sheet, the invented fibers form a highly porous paper having improved strength and reduced dusting.Type: GrantFiled: April 21, 2003Date of Patent: October 23, 2007Assignee: Rayonier, Inc.Inventors: Jian Li, Steve F. Boller
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Patent number: 7270727Abstract: Sized paper containing an amphoteric promoter resin that is a polymerization reaction product of a quaternary diallylammonium monomer, optionally a diallylammonium monomer, and an unsaturated organic acid is described. The method of sizing paper with such amphoteric promoter resin compound and a sizing agent provides sized paper with significantly improved sizing property characteristics, and the sized paper exhibits superior retention of brightness due to added optical brighteners.Type: GrantFiled: April 28, 2003Date of Patent: September 18, 2007Assignee: Hercules IncorporatedInventor: Daniel F. Varnell
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Patent number: 7255776Abstract: A method including improving a property of a paper product precursor by adding a molten wax suspension to paper product precursor, the molten wax suspension including a suspension of liquid wax particles in a liquid solvent, the liquid wax particles being at a temperature higher than the melting point of the wax. The molten wax suspension may be added to the paper product precursor in a production line prior to making a finished paper product. A finished paper product may be made from the paper product precursor.Type: GrantFiled: June 16, 2005Date of Patent: August 14, 2007Assignee: H A Industrial Technologies LtdInventors: Haggai Shoshany, Amnon Shoshany
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Patent number: 7252741Abstract: A method of forming a cellulosic web is discussed, the product of which may, for example, possess at least one of increased softness, strength, and absorbency. The method measures the total anionic charge and controls the net charge of an aqueous stream.Type: GrantFiled: October 27, 2005Date of Patent: August 7, 2007Assignee: Georgia-Pacific Consumer Products LPInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Publication number: 20070169903Abstract: A method of making paper or paperboard is described, which includes introducing at least one charged starch, preferably having a degree of substitution greater than 0.045, and at least one optical brightening agent to a papermaking pulp and then forming the pulp into paper or paperboard. The present invention further describes methods of improving optical brightener performance.Type: ApplicationFiled: January 24, 2007Publication date: July 26, 2007Inventors: Rosa M. Covarrubias, Gary A. Headrick, Alan B. Rosenberg
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Patent number: 7244339Abstract: A process for manufacturing a paper stock for use in making paper, paperboard and similar cellulosic products, by adding, at one or more different points of the wet end of the paper-making machine, a secondary retention and drainage agent containing a liquid smectite, and a primary retention and drainage agent comprising a natural or synthetic polymer. The retention and drainage agents can be added in any order, thus improving the retention, drainage, formation and drying, without affecting the whiteness, and enhancing the physical values of the paper, paperboard, cardboard and other similar products. The smectite can be an enhanced, concentrated, liquid smectite that can avoid the need for an on-site preparation unit.Type: GrantFiled: May 6, 2004Date of Patent: July 17, 2007Inventor: German Vergara Lopez
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Publication number: 20070151688Abstract: The present invention relates to a process for producing paper which comprises: providing an aqueous suspension comprising cellulosic fibres, adding to the suspension, after all points of high shear, a cationic polysaccharide; and a polymer P2 being an anionic polymer; and, dewatering the obtained suspension to form paper.Type: ApplicationFiled: December 20, 2006Publication date: July 5, 2007Applicant: AKZO NOBEL N.V.Inventors: Fredrik Solhage, Joakim Carlen, Birgitta Johansson
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Patent number: 7232503Abstract: An internal size and a method for sizing board, such as liquid packaging board, with a hydrophobising internal size containing oxetanon derivative or 2-oxetanon. The main part of the hydrocarbon chains R? and R? of the oxetanon derivative or 2-oxetanon are derived from linear fatty acids, and ?20 w-%, typically 2 to 15 w-%, most typically 5 to 12 w-% of the hydrocarbon chains are derived from branched and mainly saturated fatty acids.Type: GrantFiled: April 10, 2002Date of Patent: June 19, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Markku Nurminen, Kenneth Sundberg, Claes Zetter
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Patent number: 7220339Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1-C2 alkyl, R3 is hydrogen, C1-C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.Type: GrantFiled: June 12, 2006Date of Patent: May 22, 2007Assignee: Akzo Nobel N.V.Inventors: Oliver Struck, Christian Przybyla, Achim Sieger, Mathias Hahn, Dirk Ruppelt, Werner Jaeger
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Patent number: 7125469Abstract: Temporary wet strength resins, more particularly, temporary wet strength resins comprising a polymer backbone, wherein the polymer backbone comprises a co-crosslinking monomeric unit, preferably a reversible co-crosslinking monomeric unit, especially in the presence of water, a homo-crosslinking monomeric units and a cationic monomeric unit, fibrous structures comprising such temporary wet strength resins, sanitary tissue products comprising such fibrous structures and processes for making such fibrous structures and/or such sanitary tissue product. Such fibrous structures and sanitary tissue products exhibit high initial wet tensile strength and improved flushability properties.Type: GrantFiled: October 16, 2003Date of Patent: October 24, 2006Assignee: The Procter & Gamble CompanyInventors: Robert Lee Barcus, Khosrow Parviz Mohammadi, Angela Marie Leimbach, Stephen Robert Kelly
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Patent number: 7125471Abstract: Enzyme-treated papermaking sludges are provided, as are methods of making the enzyme-treated sludge. Papermaking processes that incorporate the enzyme-treated papermaking sludges into papermaking pulp are also provided as are paper and paperboard products made from the resultant pulp.Type: GrantFiled: November 29, 2001Date of Patent: October 24, 2006Assignee: Buckman Laboratories International, Inc.Inventors: Walter B. Hill, Jr., Brian G. Hart, Lowell F. Lott, Robert J. Turnbull, James W. Fitzhenry, Daniel E. Glover, Philip M. Hoekstra
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Patent number: 7056419Abstract: Carbon dioxide may be used to adjust the electrical properties of papermaking compositions. Such papermaking compositions may contain a colloid phase, an aqueous phase, and optionally, pulp fibers. Examples of electrical properties whose values may be adjusted include zeta potential, electrical charge demand, conductivity, and streaming potential. The carbon dioxide may be introduced at many different points in a papermaking process, including calcium carbonate slurry feeds, pulp fiber slurries, diluted pulp fibers slurries, broke, and whitewater. When a value or range of values based upon an electrical property is predetermined, such as an optimal value or range, introduction of carbon dioxide may be used to adjust the value such that it is closer to the predetermined value.Type: GrantFiled: September 6, 2003Date of Patent: June 6, 2006Assignee: American Air Liquide, Inc.Inventors: V. S. Meenakshi Sundaram, Daniel Duarte, Steven Fisher
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Patent number: 6998016Abstract: The present invention is a through-air-drying process for producing a fibrous web that possesses not only softness and absorbency but also strength. The method of the present invention monitors and controls the overall charge in the headbox.Type: GrantFiled: December 20, 2001Date of Patent: February 14, 2006Assignee: Fort James CorporationInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Process for stabilizing the PH of a pulp suspension and for producing paper from the stabilized pulp
Patent number: 6991705Abstract: The invention relates to a process for stabilizing the pH of a pulp suspension with buffering agents and to a process for producing paper from a stabilized pulp suspension. The alkalinity of the pulp suspension is increased by a combination of an alkali metal hydroxide feed and a carbon dioxide feed. Said feeds provide a significant buffering effect which stablilizes the pH of said pulp suspension for the paper making process.Type: GrantFiled: June 12, 1998Date of Patent: January 31, 2006Assignee: Aga AktiebolagInventors: Hannu Juhani Leino, Anna Linnea Holmberg -
Patent number: 6986832Abstract: The invention relates to a method and a mixer for mixing flows of a papermaking process. In the invention, a first flow is conveyed through a tube, and turbulence is generated in it by means of form parts located on the inner periphery of the tube. The mixing zone of the mixer comprises feed openings on the inner periphery of the tube for feeding a second flow from a feed channel outside the tube into the first flow, whereby the flows are mixed as a result of the turbulence generated by the form parts. According to a preferred embodiment of the invention, at least one form part comprises a feed opening.Type: GrantFiled: February 19, 2002Date of Patent: January 17, 2006Assignee: Metso Paper Inc.Inventors: Perttu Lamminen, Matti Hietaniemi, Juhani Sams, Kati Lindroos
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Patent number: 6984290Abstract: Pulp fibers can be treated with water insoluble chemical additives resulting in a minimal amount of unretained water insoluble chemical additives present after redispersing the treated pulp fibers in the process water. One embodiment of the present invention is a method for preparing chemically treated pulp fiber. A fiber slurry is created comprising process water and pulp fibers. The fiber slurry is transported to a web-forming apparatus of a pulp sheet machine thereby forming a wet fibrous web. The wet fibrous web is dried to a predetermined consistency thereby forming a dried fibrous web. The dried fibrous web is treated with a water insoluble chemical additive thereby forming a chemically treated dried fibrous web containing chemically treated pulp fibers.Type: GrantFiled: March 14, 2003Date of Patent: January 10, 2006Assignee: Kimberly-Clark WOrldwide, Inc.Inventors: Troy Michael Runge, Louise Cynthia Ellis Coe, Mike Thomas Goulet, Sheng-Hsin Hu
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Patent number: 6964725Abstract: The present invention is a tissue product comprising at least one tissue sheet. Each tissue sheet comprises a first side and an opposing second side. At least one tissue sheet comprises selectively treated pulp fiber treated with at least one hydrophobic chemical additive distributed non-uniformly in the z-direction within the tissue sheet. The tissue sheet has a % z-directional hydrophobic chemical additive gradient between the first side of the tissue sheet and the second side of the tissue sheet of about 20% or greater.Type: GrantFiled: November 6, 2002Date of Patent: November 15, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, James Daniel Lorenz, David Andrew Moline, Troy Michael Runge, Thomas Hampshire Schulz
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Patent number: 6962645Abstract: An absorbent composite (10) having a fibrous matrix that includes absorbent material is disclosed. The fibrous matrix defines voids (14) and passages between the voids, which are distributed throughout the composite. Absorbent material (18) is located within some of the voids (14). Absorbent material located in these voids is expandable into the void. In a preferred embodiment, the composite's fibrous matrix includes resilient and matrix fibers (16). The composite optionally includes a wet strength agent.Type: GrantFiled: November 13, 2002Date of Patent: November 8, 2005Assignee: National Institute for Strategic Technology AcquisitionInventors: Peter A. Graef, Fred B. Howard
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Patent number: 6939441Abstract: A stock size intended to be added as a solution to the pulp stock in connection with the manufacture of paper or board in order to improve the characteristics of the paper or board, e.g.), to reduce the absorption of liquids, to increase the dry strength and wet strength. The stock size contains a polymer, which is based on styrene maleic acid and stabilised with a polysaccharide, such as cationic starch. The stock size is advantageously prepared in a steam jet cooker. The stock size is suitably used as a stock size in the manufacturing of liquid packaging board.Type: GrantFiled: April 17, 2001Date of Patent: September 6, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Markku Nurminen, Mari Niinikoski
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Patent number: 6939443Abstract: The invention relates to a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000, and a cationic strength component. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.Type: GrantFiled: June 19, 2002Date of Patent: September 6, 2005Assignee: Lanxess CorporationInventors: Michael Ryan, William Brevard, Sr., David Dauplaise, Michael Lostocco, Robert Proverb, David Wesley Lipp
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Patent number: 6936136Abstract: The disclosed invention is directed to pulp fibers suitable for forming a wet-laid paper product which include amino-functionality which is non-extractable in an aqueous phase. The pulp fibers may be prepared by applying an amino-functional additive to a fibrous web prior to the finishing operation at a pulp mill. The fibrous web may then be repulped at a papermaking machine to form a paper web which includes the amino-functionalized fibers of the present invention. A paper web formed of the amino-functionalized fibers may display unique and/or improved reactivity toward certain papermaking additives.Type: GrantFiled: December 31, 2002Date of Patent: August 30, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas G. Shannon, David Moline