Plural Diverse Stage Treatments Patents (Class 162/88)
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Patent number: 11993624Abstract: The present invention relates to fractions of high purity lignin which are thermally stable, and to methods of producing said fractions from lignocellulosic material.Type: GrantFiled: October 29, 2020Date of Patent: May 28, 2024Assignee: Virdia, LLCInventors: Robert Jansen, James Alan Lawson, Noa Lapidot, Bassem Hallac, Perry Rotem
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Patent number: 11840585Abstract: The present invention provides a method for derivatizing cellulose pulp at high solids content or even at a fully dry state without pretreating the cellulose, the method comprising preparing a reaction medium comprising urea and at least one derivatization reagent; carrying out a chemical derivatization reaction between the at least one derivatization reagent and the cellulose pulp in a reaction system comprising the cellulose pulp in contact with the reaction medium; and optionally purifying and/or recovering the derivatized cellulose product. The present description also relates to products obtainable using said method.Type: GrantFiled: May 4, 2018Date of Patent: December 12, 2023Assignee: Betulium OyInventor: Nikolaos Pahimanolis
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Patent number: 11716219Abstract: The present disclosure relates to a galvanic isolation device or a bidirectional connecting line of a LIN bus system with two optocouplers arranged in antiparallel, each having a light-emitting element and a light-receiving element, wherein the galvanic isolation device is connectable to a LIN bus via a first signal connection and to a microprocessor via a second signal connection, wherein each signal connection is connected to the respective light-emitting element of an optocoupler, and wherein a diode is connected in antiparallel to the light-emitting element, such that, when a low signal level is applied to one of the signal connections, the signal level at the other signal connection is also low, without the signal being fed back.Type: GrantFiled: October 27, 2020Date of Patent: August 1, 2023Assignee: NIDEC-DRIVEXPERT GMBHInventor: Robert Reichert
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Patent number: 8920603Abstract: The present invention relates to a process of bleaching pulp derived from an alkaline pulping process having a hexenuronic acid content prior to the final bleaching stage from about 1 to about 80 mmol/kg dry pulp, said process comprising three chlorine dioxide stages D0, D1, and D2, wherein the chlorine dioxide charges based on the total chlorine dioxide charge in a) D0 is from about 40 to about 60%; b) D1 is from about 30 to about 55%; c) D2 is from about 4 to about 20%, and wherein the final chlorine dioxide stage D2 is performed at a pH from about 2 to about 4.5. The invention also relates to a bleached pulp obtainable by the process.Type: GrantFiled: October 10, 2007Date of Patent: December 30, 2014Assignee: Akzo Nobel N.V.Inventors: Magnus Björklund, Thomas Christopher Greschik, Håkan Fägersten
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Patent number: 8864942Abstract: A method for producing bleached pulp, including processing unbleached pulp obtained by cooking a lignocellulose substance, followed by treatment with peroxomonosulfuric acid and thereafter by multistage chlorine-free bleaching treatment starting from chlorine dioxide treatment; a method for producing bleached pulp, including processing unbleached pulp for alkali-oxygen bleaching followed by chlorine-free bleaching treatment or totally chlorine-free bleaching treatment to bleach it to a degree of brightness of from 70 to 89%, and further followed by treatment with peroxomonosulfuric acid; and paper produced by the use of the bleached pulp produced according to these production methods, at a papermaking pH of at most 6.Type: GrantFiled: August 9, 2012Date of Patent: October 21, 2014Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Iori Tomoda, Yosuke Uchida, Hiroyuki Nagatani, Ayano Kawae, Takahiro Cho, Wakana Uesugi, Tetsuo Koshitsuka
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Patent number: 8778136Abstract: A modified kraft pulp fiber with unique properties is provided. The modified fiber can be a modified bleached kraft fiber that is almost indistinguishable from its conventional counterpart, except that it has a low degree of polymerization (DP). Methods for making the modified fiber and products made from it are also provided. The method can be a one step acidic, iron catalyzed peroxide treatment process that can be incorporated into a single stage of a multi-stage bleaching process. The products can be chemical cellulose feedstocks, microcrystalline cellulose feedstocks, fluff pulps and products made from them.Type: GrantFiled: May 28, 2010Date of Patent: July 15, 2014Assignee: GP Cellulose GmbHInventors: Arthur J. Nonni, Charles E. Courchene, Christopher Michael Slone, Peter R. Abitz
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Patent number: 8715462Abstract: Methods and apparatus are provided for exploiting coated paper products such as coated paper cups. End products include biofuels that have a high energy density. The biofuels may be mixed with coal or other fuels and have good binding characteristics. In some embodiments, useful chemicals such as HMF are produced. The methods involve heat treatment at relatively mild temperatures and pressures under acidic conditions.Type: GrantFiled: April 30, 2010Date of Patent: May 6, 2014Inventor: Alexis Fosse Mackintosh
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Patent number: 8568558Abstract: The delignification and bleaching of chemical pulp by a bleaching stage, in which the chemical pulp is reacted first with chlorine dioxide and, after reaction of the chlorine dioxide, is further reacted without intermediate washing with hydrogen peroxide in the presence of a molybdate or tungstate, permits the production of chemical pulp having a whiteness of at least 89.5%, having improved stability to yellowing and reduced oxidative damage.Type: GrantFiled: January 16, 2011Date of Patent: October 29, 2013Assignee: Evonik Degussa GmbHInventor: Thomas Dietz
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Publication number: 20130269891Abstract: The invention is directed to a method for increasing brightness of pulp, wherein the method includes: contacting a pulp slurry with chlorine dioxide in a final D (ClO2) bleaching stage; and adding a brightening additive to the final D bleaching stage after at least a portion of the chlorine dioxide has been consumed, in an amount sufficient to increase brightness of the pulp; wherein the brightening additive is an inorganic compound chosen from hypochlorous acid, one or more precursor compounds that form hypochlorous acid in said final D bleaching stage, or a mixture thereof.Type: ApplicationFiled: December 19, 2011Publication date: October 17, 2013Applicant: Akzo Nobel Chemicals International B.V.Inventors: Douglas W. Reid, John Atwood, Scott Carmichael, Daniel Connell
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Patent number: 8268123Abstract: Provided are a method for producing bleached pulp, comprising processing unbleached pulp obtained by cooking a lignocellulose substance, for alkali-oxygen bleaching followed by treatment with peroxomonosulfuric acid and thereafter by multistage chlorine-free bleaching treatment starting from chlorine dioxide treatment; a method for producing bleached pulp, comprising processing the unbleached pulp for alkali-oxygen bleaching followed by chlorine-free bleaching treatment or totally chlorine-free bleaching treatment to bleach it to a degree of brightness of from 70 to 89%, and further followed by treatment with peroxomonosulfuric acid; and paper produced by the use of the bleached pulp produced according to these production methods, at a papermaking pH of at most 6.Type: GrantFiled: May 15, 2007Date of Patent: September 18, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Iori Tomoda, Yosuke Uchida, Hiroyuki Nagatani, Ayano Kawae, Takahiro Cho, Wakana Uesugi, Tetsuo Koshitsuka
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Patent number: 8262856Abstract: Process for bleaching of pulps following cooking of the lignocellulosic material with soda and anthraquinone. The process may produce a whiteness on par with the bleaching of kraft pulp when using a similar bleaching sequence. In some instances, the bleaching sequence may be O-A-Do-Eop-D, O-A-ZDo-Eop-D, A-Do, or A-ZDo.Type: GrantFiled: June 5, 2008Date of Patent: September 11, 2012Assignee: Andritz Inc.Inventors: Pam O'Leary, Namhee Shin, C. Bertil Stromberg
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Patent number: 8257550Abstract: Methods for bleaching oxygen delignified and washed pumps having a consistency of between 8 and 20% are disclosed including a first chlorine dioxide bleaching step, washing the bleached pulp, subjecting the washed pulp to an alkaline extraction step to obtain an alkali-containing pulp, adding chlorine dioxide and adjusting the pH in a second chlorine dioxide bleaching step performed directly after the alkaline extraction step without an intermediate washing step, and subjecting the bleached alkali-containing pulp to a peroxide treatment step directly after the second chlorine dioxide bleaching step or with an intermediate washing step prior to the peroxide treatment step.Type: GrantFiled: February 12, 2009Date of Patent: September 4, 2012Assignee: Metso Paper, Inc.Inventors: Mårten Dahl, Sara Eriksson, Solveig Nordén
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Patent number: 7374637Abstract: The method is for bleaching cellulose pulp in a bleach line that has at least two bleaching steps. The filtrate distribution is led up through the bleaching line counter-currently to the flow of cellulose pulp established in the bleaching line. A single joint main conduit is used for the bleaching steps. Wash filtrates obtained from the wash steps, used after or before the bleaching step, are led in conduits to branch locations on the main conduit that are positioned downstream of the branch location for drawing off of wash and/or dilution liquor for the wash step in question. All branch points in the joint main conduit are in fluid communication with one another along the main conduit.Type: GrantFiled: November 16, 2005Date of Patent: May 20, 2008Assignee: GL&V Management Hungary kftInventors: Vidar Snekkenes, Lennart Gustavsson
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Patent number: 7368036Abstract: The present invention discloses methods of bleaching chemical pulp that use xylanase enzymes after chemical bleaching. The method comprises the steps of carrying out a chlorine dioxide stage to produce a partially bleached pulp, treating the partially bleached pulp with a xylanase enzyme, optionally in the presence of oxygen and hydrogen peroxide, in a mild extraction stage, then bleaching the pulp with a second chlorine dioxide stage. The method allows the mill to decrease the usage of sodium hydroxide or other alkali, while decreasing the use of chlorine dioxide, and possibly improving the yield and strength of the pulp, while maintaining a similar level of bleached brightness of the pulp. The pulp bleaching method of the present invention may be performed in a pulp mill as part of a complex pulp bleaching process.Type: GrantFiled: March 5, 2003Date of Patent: May 6, 2008Assignee: Iogen Bio-Products CorporationInventors: Jeffrey S. Tolan, Corina Popovici
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Patent number: 7267744Abstract: This invention provides a process for treating chemical woodpulp, or chemical cellulose including cotton linter, including the step of applying an electron processing technology (EPT) step to chemical woodpulp, or chemical cellulose, as the case may be, on an in-line basis to provide control of pulp viscosity or degree of polymerization (DP). The invention also provides a method of process control in treating the aforementioned woodpulp or cellulose, including the step of using radiation dose-viscosity relationship curve for applying an EPT step on an in-line basis. The in-line EPT step may, in one form of the invention, replace and hence eliminate a chemical DP reduction step.Type: GrantFiled: March 14, 2002Date of Patent: September 11, 2007Assignee: Sappi LimitedInventors: Ian Graveson, Heinzhorst Mobius, Derek Andrew Weightman
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Patent number: 7189329Abstract: There is provided a method of inhibiting the development of a biofilm adjacent a surface, the method comprising intermittently applying a biofilm inhibiting substance to a collection of microorganisms having biofilm developing potential. Other embodiments are also described.Type: GrantFiled: February 21, 2006Date of Patent: March 13, 2007Assignee: A.Y. Laboratories Ltd.Inventor: Ayala Barak
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Patent number: 7182835Abstract: Methods for bleaching chemical pulp are disclosed including dewatering the pulp to a concentration of from 25 to 40%, bleaching in a first chlorine dioxide stage, followed by a second alkaline bleaching stage, followed by a third chlorine dioxide bleaching stage, dewatering the bleached pulp to a concentration of from 10 to 40% and producing a filtrate, and recycling the filtrate to control the pulp concentration of the dewatered chemical pulp to from 8 to 15% in the first bleaching stage.Type: GrantFiled: August 14, 2001Date of Patent: February 27, 2007Assignee: Metso Paper, Inc.Inventors: Lars-Åke Lindström, Solveig Nordén, Gunnar Carré
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Publication number: 20040200587Abstract: Bleached, Kraft chemical pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In one embodiment, the pulp has a hemicellulose content greater than about 17 weight percent as measured by the 18% caustic solubility test. In another aspect, a method for making wood cellulose pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In the method, a lignocellulosic material is pulped in caustic sulfide to provide a first brownstock, which is treated with oxygen to provide a second brownstock, which is then bleached to provide the pulp product.Type: ApplicationFiled: April 8, 2003Publication date: October 14, 2004Inventors: William J. Herring, David B. Jack, Grant R. Bourree
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Publication number: 20040200589Abstract: Bleached, Kraft chemical pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In one embodiment, the pulp has a hemicellulose content greater than about 17 weight percent as measured by the 18% caustic solubility test. In another aspect, a method for making wood cellulose pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In the method, a lignocellulosic material is pulped in caustic sulfide to provide a first brownstock, which is treated with oxygen to provide a second brownstock, which is then bleached to provide the pulp product.Type: ApplicationFiled: April 8, 2003Publication date: October 14, 2004Inventors: William J. Herring, David B. Jack, Grant R. Bourree
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Patent number: 6776876Abstract: Chemical cellulose pulp produced by alkaline delignification and having a kappa number of under 24 (e.g. 14 or below) having hexenuronic acid is treated to remove at least 50% of the hexenuronic acid (e.g. 90-97%) such as by treating the pulp at a temperature over 85° C. (e.g. about 90-180° C., preferably about 90-110° C.) at a pH between about 2-5 (e.g. about 2.5-4), which also results in a reduction of kappa number by at least two units (e.g. about 2-9 units, preferably about 3-6 units). The treatment time t, in minutes, is at least 0.5 exp(10517/(T+273)−24), where T is the treatment temperature in degrees C. The chemical cellulose pulp is bleached in at least one bleaching stage; where the bleaching stage is a chlorine dioxide, ozone, or peracid, treatment takes place before bleaching. Under some other circumstances treatment can take place simultaneous with bleaching or after bleaching.Type: GrantFiled: September 8, 1997Date of Patent: August 17, 2004Assignee: Andritz OyInventors: Tapani J. Vuorinen, U. Johanna Buchert, Anita B.-L. Teleman, T. Maija Tenkanen
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Patent number: 6773547Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1 up to 5 weight %. Such a low consistency slurry is then mixed with high partial pressure ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.Type: GrantFiled: May 11, 2001Date of Patent: August 10, 2004Assignees: American Air Liquide, Inc., Air Liquide CanadaInventors: V. S. Meenakshi Sundaram, Steven A. Fisher, Sebastien Corbiel, Derek Hornsey
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Publication number: 20040149404Abstract: The invention relates to a method of bleaching cellulose pulp in a bleach line having at least two bleaching steps D1, D2 of alkaline or acidic type, and a bleaching line for the method, in which the filtrate distribution is led up through the bleaching line in counter-current to the flow of cellulose pulp established in the bleaching line. Instead of a conventional filtrate distribution including filtrate tanks, a single joint main conduit 1 is used for the bleaching steps of the same type. Wash filtrate obtained from the wash steps of the same type used after or before the bleaching step, is led to a branch point A2, A4, A6 on the main conduit 1, that is positioned after the branch point for drawing off of wash and/or dilution liquor for the wash step in question A1, A3, A5, A7. All branch points in the joint main conduit are in open communication with each other in the main conduit, at least as seen in a direction from the last bleaching step.Type: ApplicationFiled: January 13, 2004Publication date: August 5, 2004Inventors: Vidar Snekkenes, Lennart Gustavsson
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Publication number: 20040112556Abstract: The present invention relates to a method for end-bleaching of pulp containing metal ions after a sequence comprising alkaline bleaching stages only and optionally treatment with complex forming agent, wherein the end-bleaching comprises two chlorine dioxide stages at a pulp concentration of 8-20% and pH 2.5-4.5 wherein the pulp after the first chlorine dioxide stage is washed and dewatered to a concentration of 12-50% for removal of the out-dissolved metal ions and that alkali thereupon is added to the pulp for fast alkali extraction and increase of pH to 8-14, whereupon the pulp is provided with acid and chlorine dioxide and introduced into the second chlorine dioxide stage.Type: ApplicationFiled: September 22, 2003Publication date: June 17, 2004Inventor: Ann-Sofi Nasholm
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Publication number: 20040112555Abstract: The present invention discloses methods of bleaching chemical pulp that combine xylanase enzymes with hydrogen peroxide, peracids, or a mixture. The method comprises the steps of carrying out a chemical pulping operation, optionally followed by delignifying the pulp with oxygen, then combining xylanase enzymes with hydrogen peroxide, peracids, or a mixture to bleach the pulp. The method allows the mill to use both xylanase and peracids in a single bleaching tower to decrease the usage of chlorine dioxide and other bleaching chemicals. The pulp bleaching method of the present invention may be performed in a pulp mill as part of a complex pulp bleaching process.Type: ApplicationFiled: February 2, 2004Publication date: June 17, 2004Inventors: Jeffrey Tolan, Miro Suchy
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Patent number: 6736934Abstract: The present invention relates to a method of pretreating, by acidification and chelation, of pulp to be bleached with peroxide. Especially, the invention relates to intensifying, and at the same time simplifying the pretreatment required by peroxide bleaching. It is characteristic of the invention to introduce pulp into an acid tower (14, 112) where the pressure is 0 to 20 bar, preferably 1 to 10 bar, and the temperature 75 to 130° C. preferably 80 to 110° C., to treat the pulp in acid tower (14, 112) at a pH of 2 to 6, preferably 3 to 4, for 20 to 240 minutes, for decreasing the kappa number by 1-9, preferably 2-6 kappa units, to transfer the pulp from acid tower (14, 112) to a tower (24) of a second treatment stage, to treat the pulp with either a complexing agent at a pH of 4 to 9, preferably 5 to 6, or with an oxidizing chemical such as chlorine dioxide, Caro's acid, peracids or equivalent, and to wash and/or press the pulp.Type: GrantFiled: July 28, 1997Date of Patent: May 18, 2004Assignee: Andritz OyInventors: Kaj Henricson, Olavi Pikka
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Patent number: 6706143Abstract: The invention relates to methods for reducing the amount of halogenated organics produced during a halogen bleaching process for lignocellulosic pulp fibers. According to the disclosed invention, it has been discovered that the use of a chelating agent prior to a non-halogen containing bleaching stage of a pulp bleaching process is effective to increase the brightness of the resulting bleached pulp without the need to increase the amount of halogen compounds required to obtain the same pulp brightness and without adversely affecting the pulp viscosity and yield.Type: GrantFiled: July 3, 2000Date of Patent: March 16, 2004Assignee: International Paper CompanyInventor: Ted Y. Tsai
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Publication number: 20040026051Abstract: An environmentally friendly (ECF), yet commercially viable, process produces fully bleached (typically having a brightness of over 89 or 90% ISO) cellulose pulp using a (ZEND) treatment. Typically pulp is produced in an essentially sulphur-free pulping process (such as an soda/AQ process), and is then treated by a D-EO-, D-EP-, or D-EOP-sequence before the (ZEND) treatment. Optional oxygen delignification may also be used, and subsequent elemental-chlorine-free bleaching sequences may also be employed, although normally not necessary since the pulp after the (ZEND) treatment has high brightness and good viscosity (e.g. over 21 cP).Type: ApplicationFiled: August 5, 2003Publication date: February 12, 2004Applicant: ANDRITZ INC.Inventor: C. Bertil Stromberg
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Patent number: 6679972Abstract: A process for the bleaching of lignin present in pulp fibers in an aqueous environment such as a pulp suspension. The invention also relates to a process for producing paper or board from pulp containing bleached lignin. According to the invention carbon dioxide is used for the bleaching of lignin.Type: GrantFiled: February 15, 2002Date of Patent: January 20, 2004Assignee: AGA AktiebolagInventor: Anna Tigerström
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Patent number: 6660128Abstract: A method for selectively delignifying lignocellulosic materials and bleaching of pulp and dyes using a combination of an oxidative enzyme and a metal complex. More specifically, the process involves the oxidation of a transition metal redox complex by a phenol oxidizing enzyme such as laccase or peroxidase to mediate the catalytic delignification of chemical pulp and bleaching of textile dye. This process is unique in that only a catalytic amount of metal complex mediator is required on softwood or hardwood kraft pulp, and that recycling or regeneration of the mediator for further pulp delignification is possible. The redox mediator is characterized in that it contains a transition metal ion coordinated with molecules or ions in such a way that the complexes have a formal redox potential between 0.5 and 1.2 volt measured against a normal hydrogen electrode.Type: GrantFiled: October 10, 2000Date of Patent: December 9, 2003Assignees: Pulp and Paper Research Institute of Canada, Universié de MontréalInventors: Robert Bourbonnais, Dominic Rochefort, Michael G. Paice, Sylvie Renaud, Dónal Leech
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Publication number: 20030213571Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.Type: ApplicationFiled: June 16, 2003Publication date: November 20, 2003Inventors: V.S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil, Steven A. Fisher
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Publication number: 20030178163Abstract: A method of bleaching chemical pulp, comprising two bleaching stages (D0 and, respectively, D1) with chlorine dioxide as dominating bleaching chemical and at least one intermediate alkaline bleaching stage (E). The ingoing pulp is dewatered to a concentration of 25-40% before the first chlorine dioxide stage (D0) and to 10-40% after the second chlorine dioxide stage (D1). Filtrate from the dewatering after the second chlorine dioxide stage (D1) is re-cycled and utilized for controlling the pulp concentration to 8-15% of the dewatered pulp to the first chlorine dioxide stage (D0).Type: ApplicationFiled: February 12, 2003Publication date: September 25, 2003Inventors: Lars-Ake Lindstrom, Solveig Norden, Gunnar Carre
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Publication number: 20030155086Abstract: The invention relates to improvements in the bleaching of a lignocellulosic pulp by adding carbon dioxide to provide a beneficial pH profile in the chlorine dioxide bleaching or delignification. The resulting bleached pulp is used in the production of paper or pulp. The invention also relates to the use of carbon dioxide for providing a desired pH profile in a chlorine dioxide bleaching stage.Type: ApplicationFiled: March 3, 2003Publication date: August 21, 2003Inventors: Krister Sjoblom, Malena Rennel
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Patent number: 6579412Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.Type: GrantFiled: July 24, 2002Date of Patent: June 17, 2003Assignees: L'Air Liquide - Societe' Anonyme a' Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide LPInventors: V. S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil
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Patent number: 6569284Abstract: The specification discloses an improved bleaching sequence which provides significant reduction in filtrate volumes and amounts of absorbable organic halide (AOX), color, and chemical oxygen demand (COD) in the effluent. These reductions are achieved without adversely affecting the brightness and viscosity properties of the bleached pulp and without a high capital cost and operating cost penalty or impact on existing mill processes. The bleaching sequence according to the invention for reducing filtrate volumes is an EOD1EOPD2 or EOPD1EOPD2 bleaching sequence wherein substantially all of the filtrates from the later bleaching stages are recycled to earlier bleaching stages and eventually treated in the initial EO or EOP stage prior to discharge from the plant.Type: GrantFiled: July 1, 1998Date of Patent: May 27, 2003Assignee: International Paper CompanyInventors: Caifang Yin, Jasper H. Field
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Patent number: 6540872Abstract: Methods for bleaching chemical pulps are disclosed including a final bleaching sequence of bleaching with chlorine dioxide, treating with a chelating agent, in which the bleaching and treating steps are carried out in sequence without an intermediate washing step, washing the bleached pulp, and bleaching with hydrogen peroxide.Type: GrantFiled: February 25, 1997Date of Patent: April 1, 2003Assignee: Velmet Fibertech AktiebolagInventor: Mårten Dahl
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Publication number: 20030006017Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.Type: ApplicationFiled: July 24, 2002Publication date: January 9, 2003Inventors: V.S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil, Steven A. Fisher
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Publication number: 20020088570Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1 up to 5 weight %. Such a low consistency slurry is then mixed with high partial pressure ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.Type: ApplicationFiled: May 11, 2001Publication date: July 11, 2002Inventors: V.S. Meenakshi Sundaram, Steven A. Fisher, Sebastien Corbiel, Derek Hornsey
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Publication number: 20020056533Abstract: A method of bleaching chemical cellulose pulp from an alkaline (e.g. kraft) pulping process in a chlorine dioxide stage includes (without between step washing) bleaching the pulp in a first chlorine dioxide step, and adjusting the pH of the pulp in the first chlorine dioxide step so that the final pH of the step is over 4; and then (b) effecting acid treatment of the chemical cellulose pulp at a pH of between 2-5 (preferably 2.5-4) and a temperature of over 80° C. (preferably between about 90-110° C.). The temperature in the first chlorine dioxide stage is preferably over 75° C., e.g. between about 80-100° C., and for a time of less than ten minutes, with a chlorine dioxide dosage of between about 0.5-1.5% active chlorine. Preferably a second chlorine dioxide step is practiced after the acid treatment, preferably at substantially the same conditions as the first chlorine dioxide step.Type: ApplicationFiled: March 5, 1999Publication date: May 16, 2002Inventors: TAPANI VUORINEN, SARI JUUTILAINEN, AKI VILPPONEN
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Patent number: 6375797Abstract: In a method and apparatus for treating pulp, a peroxide treatment of chemical pulp, i.e., both sulphite pulp and kraft pulp, is used to quickly reduce the Kappa number of the pulp. The method involves treating a chemical pulp with at least hydrogen peroxide or its equivalent, the kappa number of which chemical pulp has been brought to a level below 20 by either at least cooking or cooking and delignifying. The pulp is treated in a fast alkaline or neutral peroxide stage (Pk) (e.g. a small reactor having a volume of, or proportional to, less than about 90 cubic meters for 1500 tons per day pulp treatment) to reduce the kappa number by 1-10 units, and preferably by 3-7 kappa units, in which treatment the reaction time is less than 10 minutes, and is preferably less than 5 minutes. The pulp is then transferred substantially without intermediate washing of any type to a bleaching tower, and then bleached further in an acidic bleaching step (e.g. a D or Z step) in the bleaching tower.Type: GrantFiled: May 22, 1998Date of Patent: April 23, 2002Assignee: Andritz-Ahlstrom OyInventors: Kaj Henricson, Olavi Pikka
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Patent number: 6342124Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant: R1—O—[(C2H4O)m/(AO)n]—H (1) R2—O—[(C2H4O)m/(AO)p]—(AO)q—H (2) (R3)t—X—[(C2H4O)m/(AO)p]—(AO)r—H (3) where R1 stands for a branched alkyl group having 6 to 12 carbon atoms, m stands for an average added mol number of 4 to 15, A stands for a propylene, butylene or phenylethylene group, n stands for an average added mol number of 0 to 4, the addition shown in [ ] is in a random or block form, R2 stands for a linear or branched alkyl group having 6 to 12 carbon atoms, p stands for an average added mol number of 0 to 3.9, q stands for an average added mol number of 0.Type: GrantFiled: April 13, 2001Date of Patent: January 29, 2002Assignee: Sanyo Chemical Industries, Ltd.Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
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Patent number: 6315863Abstract: Collection of a post-chlorination washer filtrate and recycle thereof to acidify a wood pulp stream entering the initial chlorine dioxide bleaching stage is provided in order to reduce the formation of barium scale.Type: GrantFiled: June 18, 1998Date of Patent: November 13, 2001Assignee: Weyerhaeuser CompanyInventor: David B. Jack
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Patent number: 6306253Abstract: In the treatment of cellulose pulp in connection with bleaching, the pulp is first cooked and, if necessary, oxygen delignified in order to reduce the Kappa number below 24, preferably below 14, and after that the pulp is treated in an acid stage at a pH of 2-5 and at a temperature range of 75-130° C. in order to reduce the Kappa number by 2-9 units. To prevent essential weakening of the strength properties of the pulp in the acid stage treatment tower, the retention time, t min, is 30 to 300 minutes and the treatment temperature, T° C. is Tmin<T<Tmax, in which T min = 10517 24 + ln ⁡ ( 2 ⁢ t ) - 273 and Tmax=Tmin+23° C.Type: GrantFiled: April 14, 1998Date of Patent: October 23, 2001Assignee: Andritz-Ahlstrom OyInventor: Kaj O. Henricson
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Publication number: 20010020521Abstract: In the treatment of cellulose pulp in connection with bleaching, the pulp is first cooked and, if necessary, oxygen delignified in order to reduce the Kappa number below 24, preferably below 14, and after that the pulp is treated in an acid stage at a pH of 2-5 and at a temperature range of 75-130° C. in order to reduce the Kappa number by 2-9 units. To prevent essential weakening of the strength properties of the pulp in the acid stage treatment tower, the retention time, t min, is 30 to 300 minutes and the treatment temperature, T° C.Type: ApplicationFiled: February 27, 2001Publication date: September 13, 2001Applicant: Andritz-Ahlstrom Inc.Inventor: Kaj O. Henricson
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Publication number: 20010017196Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant:Type: ApplicationFiled: April 13, 2001Publication date: August 30, 2001Applicant: SANYO CHEMICAL INDUSTRIES, LTD.Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
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Patent number: 6258208Abstract: A method for the manufacture of bleached cellulose pulp, in conjunction with which lignocellulose material is digested to form cellulose pulp by means of an alkaline digestion liquor, and the cellulose pulp in the form of a suspension is screened, if necessary, and subjected in series to at least oxygen gas delignification/bleaching (O), if required, chlorine dioxide bleaching (D) and bleaching with non chlorine-containing, oxidative bleaching agent (O, P, Z), with the various bleaching stages interspersed with washing and/or reconcentration of the cellulose pulp in at least one stage, characterized in that complexing agents are added to the cellulose pulp in conjunction with the chlorine dioxide bleaching. It is also important for the mol quotient of the cellulose pulp for magnesium/manganese, during bleaching with a non chlorine-containing, oxidative bleaching agent, to be maintained at or brought to a value exceeding 20, and preferably exceeding 40.Type: GrantFiled: September 27, 1996Date of Patent: July 10, 2001Assignee: Mo Och Domsjo AktiebolagInventors: Otto S. A. G. Lindeberg, Lars A. G. Ahlenius, Jan G. Lidén, Sture E. O. Noréus
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Patent number: 6248209Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant: R1—O—[(C2H4O)m/(AO)n]—H (1) R2—O—[(C2H4O)m/(AO)p]—(AO)q—H (2) (R3)t—X—[(C2H4O)m/(AO)p]—(AO)r—H (3) where R1 stands for a branched alkyl group having 6 to 12 carbon atoms, m stands for an average added mol number of 4 to 15, A stands for a propylene, butylene or phenylethylene group, n stands for an average added mol number of 0 to 4, the addition shown in [ ] is in a random or block form, R2 stands for a linear or branched alkyl group having 6 to 12 carbon atoms, p stands for an average added mol number of 0 to 3.9, q stands for an average added mol number of 0.Type: GrantFiled: October 28, 1997Date of Patent: June 19, 2001Assignee: Sanyo Chemical Industries, Ltd.Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
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Patent number: 6235153Abstract: A bleached pulp having a high brightness and a satisfactory pulp viscosity is produced from a lignocellulosic material with a high efficiency by subjecting an aqueous slurry of a pulp to a bleaching step including at least one stage in which the pulp is bleached with chlorine dioxide under a pressure of, for example, 0.0980 to 0.883 MPa (1.0 to 9.0 kg/cm2), created by a compressed gas, preferably at a pH of 2 to 5, at a temperature of 50 to 120° C. and in a pulp consistency of 5 to 40%.Type: GrantFiled: August 28, 1998Date of Patent: May 22, 2001Assignee: Oji Paper Co., Ltd.Inventors: Yosuke Uchida, Takahiro Miura, Makoto Iwasaki
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Patent number: 6221209Abstract: Process for bleaching a chemical paper pulp to a brightness of at least 89° ISO, consisting in subjecting the pulp to a treatment sequence of several stages including a final bleaching stage with hydrogen peroxide in alkaline medium carried out in the presence of at least one stabilising agent and at a consistency of at least 25% by weight of solids, the stages preceding this final stage having purified the pulp so that its manganese content does not exceed 3 ppm by weight with respect to the solids and that the pulp has been delignified beforehand to a kappa number not exceeding 5.Type: GrantFiled: June 29, 1993Date of Patent: April 24, 2001Assignee: Solvay Interox (Société Anonyme)Inventors: François Desprez, Johan Devenyns, Nicholas Troughton, Paul Essemaeker
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Patent number: 6174412Abstract: A soft, bright and strong tissue paper product and a process for preparing such a tissue paper product is provided. The inventive tissue paper product is prepared from raw cotton linter fibers and demonstrates unexpected medical benefits or advantages in addition to a balance of properties.Type: GrantFiled: March 1, 1999Date of Patent: January 16, 2001Assignee: Purely Cotton, Inc.Inventors: Tim Paterson-Brown, Benjamin T. Painter, Simon T. Zuanic, Thomas A. White
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Patent number: 6126782Abstract: A method for the manufacture of non-chlorine bleached pulp, from alkaline digested cellulose pulp, wherein a suspension of the cellulose pulp is subjected to a series to oxygen gas delignification (O), treatment with complexers (Q) and bleaching with non chlorine-containing oxidative bleaching agents (O,P,Z). The various treatment stages interspersed with washing and/or reconcentration of the cellulose pulp in at least one stage, in conjunction with which a suspension liquid is conveyed essentially in strict counter-current, with the result that the pulp manufacturing process is essentially totally closed with regard to the liquid circuit.Type: GrantFiled: July 8, 1996Date of Patent: October 3, 2000Assignee: Mo Och Domsjo AktiebolagInventors: Jan G. Liden, Lars .ANG.. G. Ahlenius, Otto S. A. G. Lindeberg, Sture E. O. Noreus