Plural Diverse Stage Treatments Patents (Class 162/88)
  • Patent number: 11840585
    Abstract: The present invention provides a method for derivatizing cellulose pulp at high solids content or even at a fully dry state without pretreating the cellulose, the method comprising preparing a reaction medium comprising urea and at least one derivatization reagent; carrying out a chemical derivatization reaction between the at least one derivatization reagent and the cellulose pulp in a reaction system comprising the cellulose pulp in contact with the reaction medium; and optionally purifying and/or recovering the derivatized cellulose product. The present description also relates to products obtainable using said method.
    Type: Grant
    Filed: May 4, 2018
    Date of Patent: December 12, 2023
    Assignee: Betulium Oy
    Inventor: Nikolaos Pahimanolis
  • Patent number: 11716219
    Abstract: The present disclosure relates to a galvanic isolation device or a bidirectional connecting line of a LIN bus system with two optocouplers arranged in antiparallel, each having a light-emitting element and a light-receiving element, wherein the galvanic isolation device is connectable to a LIN bus via a first signal connection and to a microprocessor via a second signal connection, wherein each signal connection is connected to the respective light-emitting element of an optocoupler, and wherein a diode is connected in antiparallel to the light-emitting element, such that, when a low signal level is applied to one of the signal connections, the signal level at the other signal connection is also low, without the signal being fed back.
    Type: Grant
    Filed: October 27, 2020
    Date of Patent: August 1, 2023
    Assignee: NIDEC-DRIVEXPERT GMBH
    Inventor: Robert Reichert
  • Patent number: 8920603
    Abstract: The present invention relates to a process of bleaching pulp derived from an alkaline pulping process having a hexenuronic acid content prior to the final bleaching stage from about 1 to about 80 mmol/kg dry pulp, said process comprising three chlorine dioxide stages D0, D1, and D2, wherein the chlorine dioxide charges based on the total chlorine dioxide charge in a) D0 is from about 40 to about 60%; b) D1 is from about 30 to about 55%; c) D2 is from about 4 to about 20%, and wherein the final chlorine dioxide stage D2 is performed at a pH from about 2 to about 4.5. The invention also relates to a bleached pulp obtainable by the process.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: December 30, 2014
    Assignee: Akzo Nobel N.V.
    Inventors: Magnus Björklund, Thomas Christopher Greschik, Håkan Fägersten
  • Patent number: 8864942
    Abstract: A method for producing bleached pulp, including processing unbleached pulp obtained by cooking a lignocellulose substance, followed by treatment with peroxomonosulfuric acid and thereafter by multistage chlorine-free bleaching treatment starting from chlorine dioxide treatment; a method for producing bleached pulp, including processing unbleached pulp for alkali-oxygen bleaching followed by chlorine-free bleaching treatment or totally chlorine-free bleaching treatment to bleach it to a degree of brightness of from 70 to 89%, and further followed by treatment with peroxomonosulfuric acid; and paper produced by the use of the bleached pulp produced according to these production methods, at a papermaking pH of at most 6.
    Type: Grant
    Filed: August 9, 2012
    Date of Patent: October 21, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Iori Tomoda, Yosuke Uchida, Hiroyuki Nagatani, Ayano Kawae, Takahiro Cho, Wakana Uesugi, Tetsuo Koshitsuka
  • Patent number: 8778136
    Abstract: A modified kraft pulp fiber with unique properties is provided. The modified fiber can be a modified bleached kraft fiber that is almost indistinguishable from its conventional counterpart, except that it has a low degree of polymerization (DP). Methods for making the modified fiber and products made from it are also provided. The method can be a one step acidic, iron catalyzed peroxide treatment process that can be incorporated into a single stage of a multi-stage bleaching process. The products can be chemical cellulose feedstocks, microcrystalline cellulose feedstocks, fluff pulps and products made from them.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: July 15, 2014
    Assignee: GP Cellulose GmbH
    Inventors: Arthur J. Nonni, Charles E. Courchene, Christopher Michael Slone, Peter R. Abitz
  • Patent number: 8715462
    Abstract: Methods and apparatus are provided for exploiting coated paper products such as coated paper cups. End products include biofuels that have a high energy density. The biofuels may be mixed with coal or other fuels and have good binding characteristics. In some embodiments, useful chemicals such as HMF are produced. The methods involve heat treatment at relatively mild temperatures and pressures under acidic conditions.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: May 6, 2014
    Inventor: Alexis Fosse Mackintosh
  • Patent number: 8568558
    Abstract: The delignification and bleaching of chemical pulp by a bleaching stage, in which the chemical pulp is reacted first with chlorine dioxide and, after reaction of the chlorine dioxide, is further reacted without intermediate washing with hydrogen peroxide in the presence of a molybdate or tungstate, permits the production of chemical pulp having a whiteness of at least 89.5%, having improved stability to yellowing and reduced oxidative damage.
    Type: Grant
    Filed: January 16, 2011
    Date of Patent: October 29, 2013
    Assignee: Evonik Degussa GmbH
    Inventor: Thomas Dietz
  • Publication number: 20130269891
    Abstract: The invention is directed to a method for increasing brightness of pulp, wherein the method includes: contacting a pulp slurry with chlorine dioxide in a final D (ClO2) bleaching stage; and adding a brightening additive to the final D bleaching stage after at least a portion of the chlorine dioxide has been consumed, in an amount sufficient to increase brightness of the pulp; wherein the brightening additive is an inorganic compound chosen from hypochlorous acid, one or more precursor compounds that form hypochlorous acid in said final D bleaching stage, or a mixture thereof.
    Type: Application
    Filed: December 19, 2011
    Publication date: October 17, 2013
    Applicant: Akzo Nobel Chemicals International B.V.
    Inventors: Douglas W. Reid, John Atwood, Scott Carmichael, Daniel Connell
  • Patent number: 8268123
    Abstract: Provided are a method for producing bleached pulp, comprising processing unbleached pulp obtained by cooking a lignocellulose substance, for alkali-oxygen bleaching followed by treatment with peroxomonosulfuric acid and thereafter by multistage chlorine-free bleaching treatment starting from chlorine dioxide treatment; a method for producing bleached pulp, comprising processing the unbleached pulp for alkali-oxygen bleaching followed by chlorine-free bleaching treatment or totally chlorine-free bleaching treatment to bleach it to a degree of brightness of from 70 to 89%, and further followed by treatment with peroxomonosulfuric acid; and paper produced by the use of the bleached pulp produced according to these production methods, at a papermaking pH of at most 6.
    Type: Grant
    Filed: May 15, 2007
    Date of Patent: September 18, 2012
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Iori Tomoda, Yosuke Uchida, Hiroyuki Nagatani, Ayano Kawae, Takahiro Cho, Wakana Uesugi, Tetsuo Koshitsuka
  • Patent number: 8262856
    Abstract: Process for bleaching of pulps following cooking of the lignocellulosic material with soda and anthraquinone. The process may produce a whiteness on par with the bleaching of kraft pulp when using a similar bleaching sequence. In some instances, the bleaching sequence may be O-A-Do-Eop-D, O-A-ZDo-Eop-D, A-Do, or A-ZDo.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: September 11, 2012
    Assignee: Andritz Inc.
    Inventors: Pam O'Leary, Namhee Shin, C. Bertil Stromberg
  • Patent number: 8257550
    Abstract: Methods for bleaching oxygen delignified and washed pumps having a consistency of between 8 and 20% are disclosed including a first chlorine dioxide bleaching step, washing the bleached pulp, subjecting the washed pulp to an alkaline extraction step to obtain an alkali-containing pulp, adding chlorine dioxide and adjusting the pH in a second chlorine dioxide bleaching step performed directly after the alkaline extraction step without an intermediate washing step, and subjecting the bleached alkali-containing pulp to a peroxide treatment step directly after the second chlorine dioxide bleaching step or with an intermediate washing step prior to the peroxide treatment step.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: September 4, 2012
    Assignee: Metso Paper, Inc.
    Inventors: Mårten Dahl, Sara Eriksson, Solveig Nordén
  • Patent number: 7374637
    Abstract: The method is for bleaching cellulose pulp in a bleach line that has at least two bleaching steps. The filtrate distribution is led up through the bleaching line counter-currently to the flow of cellulose pulp established in the bleaching line. A single joint main conduit is used for the bleaching steps. Wash filtrates obtained from the wash steps, used after or before the bleaching step, are led in conduits to branch locations on the main conduit that are positioned downstream of the branch location for drawing off of wash and/or dilution liquor for the wash step in question. All branch points in the joint main conduit are in fluid communication with one another along the main conduit.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: May 20, 2008
    Assignee: GL&V Management Hungary kft
    Inventors: Vidar Snekkenes, Lennart Gustavsson
  • Patent number: 7368036
    Abstract: The present invention discloses methods of bleaching chemical pulp that use xylanase enzymes after chemical bleaching. The method comprises the steps of carrying out a chlorine dioxide stage to produce a partially bleached pulp, treating the partially bleached pulp with a xylanase enzyme, optionally in the presence of oxygen and hydrogen peroxide, in a mild extraction stage, then bleaching the pulp with a second chlorine dioxide stage. The method allows the mill to decrease the usage of sodium hydroxide or other alkali, while decreasing the use of chlorine dioxide, and possibly improving the yield and strength of the pulp, while maintaining a similar level of bleached brightness of the pulp. The pulp bleaching method of the present invention may be performed in a pulp mill as part of a complex pulp bleaching process.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: May 6, 2008
    Assignee: Iogen Bio-Products Corporation
    Inventors: Jeffrey S. Tolan, Corina Popovici
  • Patent number: 7267744
    Abstract: This invention provides a process for treating chemical woodpulp, or chemical cellulose including cotton linter, including the step of applying an electron processing technology (EPT) step to chemical woodpulp, or chemical cellulose, as the case may be, on an in-line basis to provide control of pulp viscosity or degree of polymerization (DP). The invention also provides a method of process control in treating the aforementioned woodpulp or cellulose, including the step of using radiation dose-viscosity relationship curve for applying an EPT step on an in-line basis. The in-line EPT step may, in one form of the invention, replace and hence eliminate a chemical DP reduction step.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: September 11, 2007
    Assignee: Sappi Limited
    Inventors: Ian Graveson, Heinzhorst Mobius, Derek Andrew Weightman
  • Patent number: 7189329
    Abstract: There is provided a method of inhibiting the development of a biofilm adjacent a surface, the method comprising intermittently applying a biofilm inhibiting substance to a collection of microorganisms having biofilm developing potential. Other embodiments are also described.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: March 13, 2007
    Assignee: A.Y. Laboratories Ltd.
    Inventor: Ayala Barak
  • Patent number: 7182835
    Abstract: Methods for bleaching chemical pulp are disclosed including dewatering the pulp to a concentration of from 25 to 40%, bleaching in a first chlorine dioxide stage, followed by a second alkaline bleaching stage, followed by a third chlorine dioxide bleaching stage, dewatering the bleached pulp to a concentration of from 10 to 40% and producing a filtrate, and recycling the filtrate to control the pulp concentration of the dewatered chemical pulp to from 8 to 15% in the first bleaching stage.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: February 27, 2007
    Assignee: Metso Paper, Inc.
    Inventors: Lars-Åke Lindström, Solveig Nordén, Gunnar Carré
  • Publication number: 20040200589
    Abstract: Bleached, Kraft chemical pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In one embodiment, the pulp has a hemicellulose content greater than about 17 weight percent as measured by the 18% caustic solubility test. In another aspect, a method for making wood cellulose pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In the method, a lignocellulosic material is pulped in caustic sulfide to provide a first brownstock, which is treated with oxygen to provide a second brownstock, which is then bleached to provide the pulp product.
    Type: Application
    Filed: April 8, 2003
    Publication date: October 14, 2004
    Inventors: William J. Herring, David B. Jack, Grant R. Bourree
  • Publication number: 20040200587
    Abstract: Bleached, Kraft chemical pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In one embodiment, the pulp has a hemicellulose content greater than about 17 weight percent as measured by the 18% caustic solubility test. In another aspect, a method for making wood cellulose pulp having increased hemicellulose content compared to conventional Kraft chemical pulps. In the method, a lignocellulosic material is pulped in caustic sulfide to provide a first brownstock, which is treated with oxygen to provide a second brownstock, which is then bleached to provide the pulp product.
    Type: Application
    Filed: April 8, 2003
    Publication date: October 14, 2004
    Inventors: William J. Herring, David B. Jack, Grant R. Bourree
  • Patent number: 6776876
    Abstract: Chemical cellulose pulp produced by alkaline delignification and having a kappa number of under 24 (e.g. 14 or below) having hexenuronic acid is treated to remove at least 50% of the hexenuronic acid (e.g. 90-97%) such as by treating the pulp at a temperature over 85° C. (e.g. about 90-180° C., preferably about 90-110° C.) at a pH between about 2-5 (e.g. about 2.5-4), which also results in a reduction of kappa number by at least two units (e.g. about 2-9 units, preferably about 3-6 units). The treatment time t, in minutes, is at least 0.5 exp(10517/(T+273)−24), where T is the treatment temperature in degrees C. The chemical cellulose pulp is bleached in at least one bleaching stage; where the bleaching stage is a chlorine dioxide, ozone, or peracid, treatment takes place before bleaching. Under some other circumstances treatment can take place simultaneous with bleaching or after bleaching.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: August 17, 2004
    Assignee: Andritz Oy
    Inventors: Tapani J. Vuorinen, U. Johanna Buchert, Anita B.-L. Teleman, T. Maija Tenkanen
  • Patent number: 6773547
    Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1 up to 5 weight %. Such a low consistency slurry is then mixed with high partial pressure ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: August 10, 2004
    Assignees: American Air Liquide, Inc., Air Liquide Canada
    Inventors: V. S. Meenakshi Sundaram, Steven A. Fisher, Sebastien Corbiel, Derek Hornsey
  • Publication number: 20040149404
    Abstract: The invention relates to a method of bleaching cellulose pulp in a bleach line having at least two bleaching steps D1, D2 of alkaline or acidic type, and a bleaching line for the method, in which the filtrate distribution is led up through the bleaching line in counter-current to the flow of cellulose pulp established in the bleaching line. Instead of a conventional filtrate distribution including filtrate tanks, a single joint main conduit 1 is used for the bleaching steps of the same type. Wash filtrate obtained from the wash steps of the same type used after or before the bleaching step, is led to a branch point A2, A4, A6 on the main conduit 1, that is positioned after the branch point for drawing off of wash and/or dilution liquor for the wash step in question A1, A3, A5, A7. All branch points in the joint main conduit are in open communication with each other in the main conduit, at least as seen in a direction from the last bleaching step.
    Type: Application
    Filed: January 13, 2004
    Publication date: August 5, 2004
    Inventors: Vidar Snekkenes, Lennart Gustavsson
  • Publication number: 20040112556
    Abstract: The present invention relates to a method for end-bleaching of pulp containing metal ions after a sequence comprising alkaline bleaching stages only and optionally treatment with complex forming agent, wherein the end-bleaching comprises two chlorine dioxide stages at a pulp concentration of 8-20% and pH 2.5-4.5 wherein the pulp after the first chlorine dioxide stage is washed and dewatered to a concentration of 12-50% for removal of the out-dissolved metal ions and that alkali thereupon is added to the pulp for fast alkali extraction and increase of pH to 8-14, whereupon the pulp is provided with acid and chlorine dioxide and introduced into the second chlorine dioxide stage.
    Type: Application
    Filed: September 22, 2003
    Publication date: June 17, 2004
    Inventor: Ann-Sofi Nasholm
  • Publication number: 20040112555
    Abstract: The present invention discloses methods of bleaching chemical pulp that combine xylanase enzymes with hydrogen peroxide, peracids, or a mixture. The method comprises the steps of carrying out a chemical pulping operation, optionally followed by delignifying the pulp with oxygen, then combining xylanase enzymes with hydrogen peroxide, peracids, or a mixture to bleach the pulp. The method allows the mill to use both xylanase and peracids in a single bleaching tower to decrease the usage of chlorine dioxide and other bleaching chemicals. The pulp bleaching method of the present invention may be performed in a pulp mill as part of a complex pulp bleaching process.
    Type: Application
    Filed: February 2, 2004
    Publication date: June 17, 2004
    Inventors: Jeffrey Tolan, Miro Suchy
  • Patent number: 6736934
    Abstract: The present invention relates to a method of pretreating, by acidification and chelation, of pulp to be bleached with peroxide. Especially, the invention relates to intensifying, and at the same time simplifying the pretreatment required by peroxide bleaching. It is characteristic of the invention to introduce pulp into an acid tower (14, 112) where the pressure is 0 to 20 bar, preferably 1 to 10 bar, and the temperature 75 to 130° C. preferably 80 to 110° C., to treat the pulp in acid tower (14, 112) at a pH of 2 to 6, preferably 3 to 4, for 20 to 240 minutes, for decreasing the kappa number by 1-9, preferably 2-6 kappa units, to transfer the pulp from acid tower (14, 112) to a tower (24) of a second treatment stage, to treat the pulp with either a complexing agent at a pH of 4 to 9, preferably 5 to 6, or with an oxidizing chemical such as chlorine dioxide, Caro's acid, peracids or equivalent, and to wash and/or press the pulp.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: May 18, 2004
    Assignee: Andritz Oy
    Inventors: Kaj Henricson, Olavi Pikka
  • Patent number: 6706143
    Abstract: The invention relates to methods for reducing the amount of halogenated organics produced during a halogen bleaching process for lignocellulosic pulp fibers. According to the disclosed invention, it has been discovered that the use of a chelating agent prior to a non-halogen containing bleaching stage of a pulp bleaching process is effective to increase the brightness of the resulting bleached pulp without the need to increase the amount of halogen compounds required to obtain the same pulp brightness and without adversely affecting the pulp viscosity and yield.
    Type: Grant
    Filed: July 3, 2000
    Date of Patent: March 16, 2004
    Assignee: International Paper Company
    Inventor: Ted Y. Tsai
  • Publication number: 20040026051
    Abstract: An environmentally friendly (ECF), yet commercially viable, process produces fully bleached (typically having a brightness of over 89 or 90% ISO) cellulose pulp using a (ZEND) treatment. Typically pulp is produced in an essentially sulphur-free pulping process (such as an soda/AQ process), and is then treated by a D-EO-, D-EP-, or D-EOP-sequence before the (ZEND) treatment. Optional oxygen delignification may also be used, and subsequent elemental-chlorine-free bleaching sequences may also be employed, although normally not necessary since the pulp after the (ZEND) treatment has high brightness and good viscosity (e.g. over 21 cP).
    Type: Application
    Filed: August 5, 2003
    Publication date: February 12, 2004
    Applicant: ANDRITZ INC.
    Inventor: C. Bertil Stromberg
  • Patent number: 6679972
    Abstract: A process for the bleaching of lignin present in pulp fibers in an aqueous environment such as a pulp suspension. The invention also relates to a process for producing paper or board from pulp containing bleached lignin. According to the invention carbon dioxide is used for the bleaching of lignin.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: January 20, 2004
    Assignee: AGA Aktiebolag
    Inventor: Anna Tigerström
  • Patent number: 6660128
    Abstract: A method for selectively delignifying lignocellulosic materials and bleaching of pulp and dyes using a combination of an oxidative enzyme and a metal complex. More specifically, the process involves the oxidation of a transition metal redox complex by a phenol oxidizing enzyme such as laccase or peroxidase to mediate the catalytic delignification of chemical pulp and bleaching of textile dye. This process is unique in that only a catalytic amount of metal complex mediator is required on softwood or hardwood kraft pulp, and that recycling or regeneration of the mediator for further pulp delignification is possible. The redox mediator is characterized in that it contains a transition metal ion coordinated with molecules or ions in such a way that the complexes have a formal redox potential between 0.5 and 1.2 volt measured against a normal hydrogen electrode.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: December 9, 2003
    Assignees: Pulp and Paper Research Institute of Canada, Universié de Montréal
    Inventors: Robert Bourbonnais, Dominic Rochefort, Michael G. Paice, Sylvie Renaud, Dónal Leech
  • Publication number: 20030213571
    Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.
    Type: Application
    Filed: June 16, 2003
    Publication date: November 20, 2003
    Inventors: V.S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil, Steven A. Fisher
  • Publication number: 20030178163
    Abstract: A method of bleaching chemical pulp, comprising two bleaching stages (D0 and, respectively, D1) with chlorine dioxide as dominating bleaching chemical and at least one intermediate alkaline bleaching stage (E). The ingoing pulp is dewatered to a concentration of 25-40% before the first chlorine dioxide stage (D0) and to 10-40% after the second chlorine dioxide stage (D1). Filtrate from the dewatering after the second chlorine dioxide stage (D1) is re-cycled and utilized for controlling the pulp concentration to 8-15% of the dewatered pulp to the first chlorine dioxide stage (D0).
    Type: Application
    Filed: February 12, 2003
    Publication date: September 25, 2003
    Inventors: Lars-Ake Lindstrom, Solveig Norden, Gunnar Carre
  • Publication number: 20030155086
    Abstract: The invention relates to improvements in the bleaching of a lignocellulosic pulp by adding carbon dioxide to provide a beneficial pH profile in the chlorine dioxide bleaching or delignification. The resulting bleached pulp is used in the production of paper or pulp. The invention also relates to the use of carbon dioxide for providing a desired pH profile in a chlorine dioxide bleaching stage.
    Type: Application
    Filed: March 3, 2003
    Publication date: August 21, 2003
    Inventors: Krister Sjoblom, Malena Rennel
  • Patent number: 6579412
    Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: June 17, 2003
    Assignees: L'Air Liquide - Societe' Anonyme a' Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide LP
    Inventors: V. S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil
  • Patent number: 6569284
    Abstract: The specification discloses an improved bleaching sequence which provides significant reduction in filtrate volumes and amounts of absorbable organic halide (AOX), color, and chemical oxygen demand (COD) in the effluent. These reductions are achieved without adversely affecting the brightness and viscosity properties of the bleached pulp and without a high capital cost and operating cost penalty or impact on existing mill processes. The bleaching sequence according to the invention for reducing filtrate volumes is an EOD1EOPD2 or EOPD1EOPD2 bleaching sequence wherein substantially all of the filtrates from the later bleaching stages are recycled to earlier bleaching stages and eventually treated in the initial EO or EOP stage prior to discharge from the plant.
    Type: Grant
    Filed: July 1, 1998
    Date of Patent: May 27, 2003
    Assignee: International Paper Company
    Inventors: Caifang Yin, Jasper H. Field
  • Patent number: 6540872
    Abstract: Methods for bleaching chemical pulps are disclosed including a final bleaching sequence of bleaching with chlorine dioxide, treating with a chelating agent, in which the bleaching and treating steps are carried out in sequence without an intermediate washing step, washing the bleached pulp, and bleaching with hydrogen peroxide.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: April 1, 2003
    Assignee: Velmet Fibertech Aktiebolag
    Inventor: Mårten Dahl
  • Publication number: 20030006017
    Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.
    Type: Application
    Filed: July 24, 2002
    Publication date: January 9, 2003
    Inventors: V.S. Meenakshi Sundaram, Derek Hornsey, Sebastien Corbeil, Steven A. Fisher
  • Publication number: 20020088570
    Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1 up to 5 weight %. Such a low consistency slurry is then mixed with high partial pressure ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.
    Type: Application
    Filed: May 11, 2001
    Publication date: July 11, 2002
    Inventors: V.S. Meenakshi Sundaram, Steven A. Fisher, Sebastien Corbiel, Derek Hornsey
  • Publication number: 20020056533
    Abstract: A method of bleaching chemical cellulose pulp from an alkaline (e.g. kraft) pulping process in a chlorine dioxide stage includes (without between step washing) bleaching the pulp in a first chlorine dioxide step, and adjusting the pH of the pulp in the first chlorine dioxide step so that the final pH of the step is over 4; and then (b) effecting acid treatment of the chemical cellulose pulp at a pH of between 2-5 (preferably 2.5-4) and a temperature of over 80° C. (preferably between about 90-110° C.). The temperature in the first chlorine dioxide stage is preferably over 75° C., e.g. between about 80-100° C., and for a time of less than ten minutes, with a chlorine dioxide dosage of between about 0.5-1.5% active chlorine. Preferably a second chlorine dioxide step is practiced after the acid treatment, preferably at substantially the same conditions as the first chlorine dioxide step.
    Type: Application
    Filed: March 5, 1999
    Publication date: May 16, 2002
    Inventors: TAPANI VUORINEN, SARI JUUTILAINEN, AKI VILPPONEN
  • Patent number: 6375797
    Abstract: In a method and apparatus for treating pulp, a peroxide treatment of chemical pulp, i.e., both sulphite pulp and kraft pulp, is used to quickly reduce the Kappa number of the pulp. The method involves treating a chemical pulp with at least hydrogen peroxide or its equivalent, the kappa number of which chemical pulp has been brought to a level below 20 by either at least cooking or cooking and delignifying. The pulp is treated in a fast alkaline or neutral peroxide stage (Pk) (e.g. a small reactor having a volume of, or proportional to, less than about 90 cubic meters for 1500 tons per day pulp treatment) to reduce the kappa number by 1-10 units, and preferably by 3-7 kappa units, in which treatment the reaction time is less than 10 minutes, and is preferably less than 5 minutes. The pulp is then transferred substantially without intermediate washing of any type to a bleaching tower, and then bleached further in an acidic bleaching step (e.g. a D or Z step) in the bleaching tower.
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: April 23, 2002
    Assignee: Andritz-Ahlstrom Oy
    Inventors: Kaj Henricson, Olavi Pikka
  • Patent number: 6342124
    Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant: R1—O—[(C2H4O)m/(AO)n]—H  (1) R2—O—[(C2H4O)m/(AO)p]—(AO)q—H  (2) (R3)t—X—[(C2H4O)m/(AO)p]—(AO)r—H  (3) where R1 stands for a branched alkyl group having 6 to 12 carbon atoms, m stands for an average added mol number of 4 to 15, A stands for a propylene, butylene or phenylethylene group, n stands for an average added mol number of 0 to 4, the addition shown in [ ] is in a random or block form, R2 stands for a linear or branched alkyl group having 6 to 12 carbon atoms, p stands for an average added mol number of 0 to 3.9, q stands for an average added mol number of 0.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: January 29, 2002
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
  • Patent number: 6315863
    Abstract: Collection of a post-chlorination washer filtrate and recycle thereof to acidify a wood pulp stream entering the initial chlorine dioxide bleaching stage is provided in order to reduce the formation of barium scale.
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: November 13, 2001
    Assignee: Weyerhaeuser Company
    Inventor: David B. Jack
  • Patent number: 6306253
    Abstract: In the treatment of cellulose pulp in connection with bleaching, the pulp is first cooked and, if necessary, oxygen delignified in order to reduce the Kappa number below 24, preferably below 14, and after that the pulp is treated in an acid stage at a pH of 2-5 and at a temperature range of 75-130° C. in order to reduce the Kappa number by 2-9 units. To prevent essential weakening of the strength properties of the pulp in the acid stage treatment tower, the retention time, t min, is 30 to 300 minutes and the treatment temperature, T° C. is Tmin<T<Tmax, in which T min = 10517 24 + ln ⁡ ( 2 ⁢ t ) - 273 and Tmax=Tmin+23° C.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: October 23, 2001
    Assignee: Andritz-Ahlstrom Oy
    Inventor: Kaj O. Henricson
  • Publication number: 20010020521
    Abstract: In the treatment of cellulose pulp in connection with bleaching, the pulp is first cooked and, if necessary, oxygen delignified in order to reduce the Kappa number below 24, preferably below 14, and after that the pulp is treated in an acid stage at a pH of 2-5 and at a temperature range of 75-130° C. in order to reduce the Kappa number by 2-9 units. To prevent essential weakening of the strength properties of the pulp in the acid stage treatment tower, the retention time, t min, is 30 to 300 minutes and the treatment temperature, T° C.
    Type: Application
    Filed: February 27, 2001
    Publication date: September 13, 2001
    Applicant: Andritz-Ahlstrom Inc.
    Inventor: Kaj O. Henricson
  • Publication number: 20010017196
    Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant:
    Type: Application
    Filed: April 13, 2001
    Publication date: August 30, 2001
    Applicant: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
  • Patent number: 6258208
    Abstract: A method for the manufacture of bleached cellulose pulp, in conjunction with which lignocellulose material is digested to form cellulose pulp by means of an alkaline digestion liquor, and the cellulose pulp in the form of a suspension is screened, if necessary, and subjected in series to at least oxygen gas delignification/bleaching (O), if required, chlorine dioxide bleaching (D) and bleaching with non chlorine-containing, oxidative bleaching agent (O, P, Z), with the various bleaching stages interspersed with washing and/or reconcentration of the cellulose pulp in at least one stage, characterized in that complexing agents are added to the cellulose pulp in conjunction with the chlorine dioxide bleaching. It is also important for the mol quotient of the cellulose pulp for magnesium/manganese, during bleaching with a non chlorine-containing, oxidative bleaching agent, to be maintained at or brought to a value exceeding 20, and preferably exceeding 40.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: July 10, 2001
    Assignee: Mo Och Domsjo Aktiebolag
    Inventors: Otto S. A. G. Lindeberg, Lars A. G. Ahlenius, Jan G. Lidén, Sture E. O. Noréus
  • Patent number: 6248209
    Abstract: An aqueous alkaline slurry of cellulose pulp is bleached with oxygen or peroxide by using a compound represented by general formula (1), (2) or (3) as a bleaching assistant: R1—O—[(C2H4O)m/(AO)n]—H  (1) R2—O—[(C2H4O)m/(AO)p]—(AO)q—H  (2) (R3)t—X—[(C2H4O)m/(AO)p]—(AO)r—H  (3) where R1 stands for a branched alkyl group having 6 to 12 carbon atoms, m stands for an average added mol number of 4 to 15, A stands for a propylene, butylene or phenylethylene group, n stands for an average added mol number of 0 to 4, the addition shown in [ ] is in a random or block form, R2 stands for a linear or branched alkyl group having 6 to 12 carbon atoms, p stands for an average added mol number of 0 to 3.9, q stands for an average added mol number of 0.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: June 19, 2001
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Hiroaki Maeda, Daisuke Nakamura, Nobuo Hisada
  • Patent number: 6235153
    Abstract: A bleached pulp having a high brightness and a satisfactory pulp viscosity is produced from a lignocellulosic material with a high efficiency by subjecting an aqueous slurry of a pulp to a bleaching step including at least one stage in which the pulp is bleached with chlorine dioxide under a pressure of, for example, 0.0980 to 0.883 MPa (1.0 to 9.0 kg/cm2), created by a compressed gas, preferably at a pH of 2 to 5, at a temperature of 50 to 120° C. and in a pulp consistency of 5 to 40%.
    Type: Grant
    Filed: August 28, 1998
    Date of Patent: May 22, 2001
    Assignee: Oji Paper Co., Ltd.
    Inventors: Yosuke Uchida, Takahiro Miura, Makoto Iwasaki
  • Patent number: 6221209
    Abstract: Process for bleaching a chemical paper pulp to a brightness of at least 89° ISO, consisting in subjecting the pulp to a treatment sequence of several stages including a final bleaching stage with hydrogen peroxide in alkaline medium carried out in the presence of at least one stabilising agent and at a consistency of at least 25% by weight of solids, the stages preceding this final stage having purified the pulp so that its manganese content does not exceed 3 ppm by weight with respect to the solids and that the pulp has been delignified beforehand to a kappa number not exceeding 5.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: April 24, 2001
    Assignee: Solvay Interox (Société Anonyme)
    Inventors: François Desprez, Johan Devenyns, Nicholas Troughton, Paul Essemaeker
  • Patent number: 6174412
    Abstract: A soft, bright and strong tissue paper product and a process for preparing such a tissue paper product is provided. The inventive tissue paper product is prepared from raw cotton linter fibers and demonstrates unexpected medical benefits or advantages in addition to a balance of properties.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: January 16, 2001
    Assignee: Purely Cotton, Inc.
    Inventors: Tim Paterson-Brown, Benjamin T. Painter, Simon T. Zuanic, Thomas A. White
  • Patent number: 6126782
    Abstract: A method for the manufacture of non-chlorine bleached pulp, from alkaline digested cellulose pulp, wherein a suspension of the cellulose pulp is subjected to a series to oxygen gas delignification (O), treatment with complexers (Q) and bleaching with non chlorine-containing oxidative bleaching agents (O,P,Z). The various treatment stages interspersed with washing and/or reconcentration of the cellulose pulp in at least one stage, in conjunction with which a suspension liquid is conveyed essentially in strict counter-current, with the result that the pulp manufacturing process is essentially totally closed with regard to the liquid circuit.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: October 3, 2000
    Assignee: Mo Och Domsjo Aktiebolag
    Inventors: Jan G. Liden, Lars .ANG.. G. Ahlenius, Otto S. A. G. Lindeberg, Sture E. O. Noreus
  • Patent number: 6123809
    Abstract: A process for the delignification and bleaching of chemical pulp utilizes an acid treatment stage aimed at reducing the quantity of hexene uronic acids present in the pulp by at least 30%, and a pH adjustment stage of the pulp aimed at depositing or redepositing ions of alkaline-earth metals on the fibres of the pulp. The process further includes a washing stage of the pulp and a treatment stage of the pulp with an oxidizing agent. A chelating agent is added to the pulp before and/or during the acid treatment stage and/or before or during the pH adjustment stage or between the pH adjustment stage and washing stage.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: September 26, 2000
    Assignee: Solvay Interox (Societe Anony.)
    Inventors: Johan Devenyns, Eric Chauveheid, Lucien Plumet