Cyclic Injection Then Production Of A Single Well Patents (Class 166/263)
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Patent number: 6484805Abstract: A method and an apparatus for injecting a fluid into a borehole. The method includes the step of injecting an injection fluid into a primary injection zone in a borehole at an injection fluid pressure. The primary injection zone is bounded by a proximal injection zone interface and a distal injection zone interface. The proximal injection zone interface and the distal injection zone interface are maintained at pressures which are substantially balanced with the injection fluid pressure. The apparatus includes a body adapted for passage through a borehole, at least four radially extendable and retractable zone interface elements spaced longitudinally along the body which when extended define at least three zones along the body, a zone interface element actuator for selectively extending and retracting the zone interface elements, and a fluid delivery system for delivering a fluid to each zone.Type: GrantFiled: June 8, 2000Date of Patent: November 26, 2002Assignee: Alberta Research Council Inc.Inventors: Ernest H. Perkins, Douglas A. Lillico, Kevin Rispler
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Patent number: 6457522Abstract: The present invention provides a clean water separation system with an electric submersible pumping device and a surface separator and pumping device for the separation and transfer of different density fluids and solids. The electric submersible pumping device can be an encapsulated device that works in conjunction with a separator and pumping system that are located on the surface, to separate fluids and solids.Type: GrantFiled: November 28, 2000Date of Patent: October 1, 2002Assignee: Wood Group ESP, Inc.Inventors: Yasser Khan Bangash, John Derek Jones, Michael R. Berry
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Patent number: 6450256Abstract: A method of stimulating coalbed methane production by injecting gas into a producer and subsequently placing the producer back on production is described. A decrease in water production may also result. The increase in gas production and decrease in water production may result from: (1) the displacement of water from the producer by gas; (2) the establishment of a mobile gas saturation at an extended distance into the coalbed, extending outward from the producer; and (3) the reduction in coalbed methane partial pressure between the coal matrix and the coal's cleat system.Type: GrantFiled: June 6, 2001Date of Patent: September 17, 2002Assignee: The University of Wyoming Research CorporationInventor: Charles G. Mones
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Publication number: 20020125010Abstract: A microemulsion comprising, (i) an oil phase, (ii) an aqueous phase comprising an aqueous solution of a water soluble oil field or gas field production chemical or an aqueous dispersion of a water dispersible oil field or gas field production chemical and (iii) at least one surfactant, wherein the aqueous phase is distributed in the oil phase in the form of droplets having a diameter in the range 1 to 1000 mn or in the form of microdomains having at least one dimension of length, breath or thickness in the range 1 to 1000 nm.Type: ApplicationFiled: December 14, 2001Publication date: September 12, 2002Inventors: Ian Ralph Collins, Isabelle Vervoort
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Patent number: 6431280Abstract: This patent relates to a process whereby a filter/seive is produced by injecting the interactive chemicals used to form gels and polymers at reservoir temperatures independently and sequentially into a well in such a manner that the chemicals only come into contact with each other at the desired depth of penetration in the formation. At this location in the reservoir, which can be determined by appropriate calculation, the injection is stopped and the intermixed and superimposed chemicals are allowed to react to form the filter/seive of a gel or polymer depending upon the nature of the individual chemicals injected.Type: GrantFiled: April 2, 2001Date of Patent: August 13, 2002Inventors: Geoffrey Stanley Bayliss, Paul Stuart Bayliss
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Patent number: 6431279Abstract: An improved method for the chlorine dioxide treatment of oil and/or gas well bores is provided, which eliminates the need for costly and complex chlorine dioxide-generating equipment and yields very high concentrations of chlorine dioxide down hole. The preferred method involves the introduction of reactant(s) into a well and causing a reaction to generate chlorine dioxide in situ. Chlorite and hypochlorite ion sources (e.g., sodium chlorite and sodium hypochlorite) are introduced into the well along with an acid. The well may then be flushed with water to force the reactants and chloride dioxide downwardly to the well formation.Type: GrantFiled: July 14, 2000Date of Patent: August 13, 2002Assignee: Jacam Chemicals, L.L.C.Inventors: Gene H. Zaid, Donald W. Sanders
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Patent number: 6412559Abstract: A process for recovering methane from a coal bed and/or sequestering a fluid more strongly adsorbing than methane (“SAG”) in a coal bed involves fracturing an injection well and cyclically injecting SAG with intervening shut-in periods. Even though the absolute permeability of the coal bed decreases with continued SAG sorption, the SAG injectivity, surprisingly and unexpectedly, increases while injecting SAG at pressures greater than reservoir pressure, but less than fracture pressure or fracture extension pressure. The increased injectivity is thought to be due to a reduction in near-well flow resistance.Type: GrantFiled: December 18, 2000Date of Patent: July 2, 2002Assignee: Alberta Research Council Inc.Inventors: William Daniel Gunter, Matthew John Mavor, David Hin-Sum Law
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Patent number: 6405799Abstract: A process for in situ upgrading of a heavy hydrocarbon includes the steps of (a) positioning a well in a reservoir containing a heavy hydrocarbon having an initial API gravity of less than or equal to about 8; (b) injecting a light solvent into the well at reservoir conditions so as to provide an upgraded hydrocarbon in the reservoir, the upgraded hydrocarbon having an improved API gravity greater than the initial API gravity; and (c) producing the upgraded hydrocarbon from the well.Type: GrantFiled: June 28, 2000Date of Patent: June 18, 2002Assignee: Intevep, S.A.Inventors: Carlos Vallejos, Tito Vasquez, Gerson Siachoque, Ignacio Layrisse
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Publication number: 20020056550Abstract: Gaseous and liquid carbon dioxide (CO2) are applied to a landfill well to penetrate the landfill under rapid pressurization and depressurization repeated in cycles, with or without leachate or fluid in the well. These cycles can be repeated until the CO2 flows more freely down a lower pressure gradient in the well into the landfill surrounding the well screen, creating fissures in the landfill which allow methane and other gases to enter the well, thereby significantly enhancing methane and other landfill gas recovery.Type: ApplicationFiled: January 8, 2002Publication date: May 16, 2002Inventors: Steven Catanla, Neil Mansuy
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Patent number: 6338386Abstract: Gaseous and liquid carbon dioxide (CO2) are applied to a landfill well to penetrate the landfill under rapid pressurization and depressurization repeated in cycles, with or without leachate or fluid in the well. These cycles can be repeated until the CO2 flows more freely down a lower pressure gradient in the well into the landfill surrounding the well screen, creating fissures in the landfill which allow methane and other gases to enter the well, thereby significantly enhancing methane and other landfill gas recovery.Type: GrantFiled: May 11, 2000Date of Patent: January 15, 2002Assignee: Subsurface TechnologiesInventors: Steven Catania, Neil Mansuy
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Patent number: 6305472Abstract: An enhanced oil recovery process uses an injectant containing water and an additive. The additive is an organic compound having a total of 1 to 10 carbons and at least one functional group containing a heteroatom. The additive is present at a concentration of between about 0.01% and about 20% by weight of the composition. The injectant is injected at a temperature of between about 100° F. to about 500° F. Hot water flooding with the additive provides enhanced oil recovery in medium to heavy oil reservoirs.Type: GrantFiled: November 20, 1998Date of Patent: October 23, 2001Assignee: Texaco Inc.Inventors: William C. Richardson, Kenneth R. Kibodeaux
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Patent number: 6302206Abstract: A method for treating a gas well to prevent any fresh water, which may have condensed out of the gas stream, from damaging the gas producing formation during the shut-in period. The well is shut-in and then an additive, e.g. a salt, alcohol, etc., is injected into the well to convert any accumulated fresh water into an aqueous solution which will not damage the formation. The additive can be injected in solid form or as a solution.Type: GrantFiled: November 17, 1999Date of Patent: October 16, 2001Assignees: Vastar Resources, Inc., Atlantic Richfield CompanyInventors: Scott James Wilson, Marvin Eugene Miller
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Patent number: 6298918Abstract: The invention relates to a pneumatic system for lifting petroleum, for application in wells, which may be flowing or non-flowing wells, preferably with low productivity levels or with low static pressure. The system uses cyclic pressurization and depressurization of a petroleum storage chamber located in the lower portion of the well by the injection of gas to force the fluid which has accumulated in the storage chamber to be lifted via the production column. After the storage chamber has been emptied to a certain degree, it is depressurized to allow refilling. When the storage chamber is depressurized, the gas may be diverted to the annular space between the production column and an auxiliary lift tube, where it plays a part in increasing the height of the column of fluid which it is possible to lift. A control system is responsible for the cyclic nature of the operation.Type: GrantFiled: January 31, 2000Date of Patent: October 9, 2001Assignee: Petroleo Brasileiro S.A.-PetrobrasInventors: Zadson De Almeida Franco, Francisco Alberto Cerqueira De Oliveira
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Publication number: 20010018975Abstract: An enhanced oil recovery process uses an injectant containing water and an additive. The additive is an organic compound having a total of 1 to 10 carbons and at least one functional group containing a heteroatom. The additive is present at a concentration of between about 0.01% and about 20% by weight of the composition. The injectant is injected at a temperature of between about 100° F. to about 500° F. Hot water flooding with the additive provides enhanced oil recovery in medium to heavy oil reservoirs.Type: ApplicationFiled: November 20, 1998Publication date: September 6, 2001Inventors: WILLIAM C RICHARDSON, KENNETH R. KIBODEAUX
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Patent number: 6280000Abstract: A method for removing water and producing methane from a subterranean coal seam. The method includes drilling a first substantially vertical well bore to the depth of the target coal seam, enlarging the bore of the vertical well at the depth of a target coal seam to provide an enlarged cavity, drilling an offset well intersecting the cavity substantially horizontally and then drilling through the cavity in order to drill substantially horizontal drainage well bores in the coal seam. The method may be used as a pre-mining step in conjunction with subterranean mining of the coal seam in order to remove methane and other dangerous gases and excess water from the coal seam in advance of mining operations.Type: GrantFiled: November 20, 1998Date of Patent: August 28, 2001Inventor: Joseph A. Zupanick
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Publication number: 20010010432Abstract: Improved method and system for accessing subterranean deposits from the surface that substantially eliminates or reduces the disadvantages and problems associated with previous systems and methods. In particular, the present invention provides an articulated well with a drainage pattern that intersects a horizontal cavity well. The drainage patterns provide access to a large subterranean area from the surface while the vertical cavity well allows entrained water, hydrocarbons, and other deposits to be efficiently removed and/or produced.Type: ApplicationFiled: February 20, 2001Publication date: August 2, 2001Applicant: CDX Gas, LLC, Texas limited liability companyInventor: Joseph A. Zupanick
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Patent number: 6257334Abstract: A pair of vertically spaced, parallel, co-extensive, horizontal injection and production wells and a laterally spaced, horizontal offset well are provided in a subterranean reservoir containing heavy oil. Fluid communication is established across the span of formation extending between the pair of wells. Steam-assisted gravity drainage (“SAGD”) is then practised by injecting steam through the injection well and producing heated oil and steam condensate through the production well, which is operated under steam trap control. Cyclic steam stimulation is practised at the offset well. The steam chamber developed at the offset well tends to grow toward the steam chamber of the SAGD pair, thereby accelerating development of communication between the SAGD pair and the offset well. This process is continued until fluid communication is established between the injection well and the offset well.Type: GrantFiled: July 22, 1999Date of Patent: July 10, 2001Assignee: Alberta Oil Sands Technology and Research AuthorityInventors: Ted Cyr, Roy Coates, Marcel Polikar
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Patent number: 6244341Abstract: A cyclic or “huff and puff” enhanced oil recovery process utilizes purified nitrogen gas as the injection gas. The purified nitrogen gas is preferably generated near the well site by the use of a membrane separator. The resulting purified nitrogen gas comprises at least about 90% by volume nitrogen with the remaining gas mixture fraction being primarily oxygen. The producing well is shut in. The gas mixture is injected down through the well into the formation. The well is then shut in allowing the gas mixture to soak into the formation for a predetermined period of time of at least 7 days and in some cases as much as 180 days or more. Then the well is placed on production and additional hydrocarbons are produced back from the same well into which the nitrogen gas was injected.Type: GrantFiled: July 20, 1999Date of Patent: June 12, 2001Assignee: Nitrogen Oil Recovery Systems LLCInventor: Bernard J. Miller
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Patent number: 6244338Abstract: A method of stimulating coalbed methane production by injecting gas into a producer and subsequently placing the producer back on production is described. A decrease in water production may also result. The increase in gas production and decrease in water production may result from: (1) the displacement of water from the producer by gas; (2) the establishment of a mobile gas saturation at an extended distance into the coalbed, extending outward from the producer; and (3) the reduction in coalbed methane partial pressure between the coal matrix and the coal's cleat system.Type: GrantFiled: June 23, 1999Date of Patent: June 12, 2001Assignee: The University of Wyoming Research Corp.,Inventor: Charles G. Mones
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Patent number: 6234183Abstract: A method and composition for removing deposits of heavy hydrocarbonaceous materials and finely divided inorganic particulate matter from wellbore and flowline surfaces using a composition containing an alkyl polyglycoside, an ethoxylated alcohol, a caustic and an alkyl alcohol.Type: GrantFiled: July 10, 2000Date of Patent: May 22, 2001Assignee: Atlantic Richfield CompanyInventors: Albert F. Chan, William Mark Bohon, David J. Blumer, Kieu T. Ly
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Patent number: 6230814Abstract: A method for producing hydrocarbons from a subterranean formation comprises injecting steam and an additive into the formation. The additive has at least one nonaqueous fluid, which is selected so that the evaporation temperature of the additive is within about ±150° C. of the steam temperature at the operating pressure. Suitable additives include C1 to C25 hydrocarbons, and combinations thereof. At least a portion of the additive condenses in the formation. The mobility of the hydrocarbons is greater than that obtained using steam alone under substantially similar formation conditions.Type: GrantFiled: October 14, 1999Date of Patent: May 15, 2001Assignee: Alberta Oil Sands Technology and Research AuthorityInventors: Tawfik Noaman Nasr, Ezra Eddy Isaacs
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Patent number: 6227296Abstract: This invention provides a method for reducing the water saturation in the near-well region. Along with various well treatment possibilities, one application of this invention increases the injectivity rate of a substantially nonaqueous fluid into a subterranean formation. The preferred embodiment uses this invention to increase the injectivity of solvent gas into an oil-bearing formation for enhancing the amount and/or rate of oil recovery from the formation. The method includes injecting a second fluid into the near-well region of the injection well to displace at least a portion of the water from that region. Displacement of the water and subsequent displacement of the secondary fluid allow maximum injectivity for the primary solvent being injected for oil recovery.Type: GrantFiled: October 25, 1999Date of Patent: May 8, 2001Assignee: ExxonMobil Upstream Research CompanyInventors: Todd R. Reppert, W. Keith Idol
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Patent number: 6220352Abstract: A process for restoring the injectivity or productivity of a well penetrating a subterranean formation by injecting a micelle treating fluid into the subterranean formation via the well with the micelle treating fluid containing a 2% potassium chloride water solution and a mutual solvent containing alcohol, aromatic hydrocarbon and an alkyl or alkylaryl polyoxyalkylene phosphate ester surfactant, thereafter displacing the micelle treating fluid into the formation by injecting a gas into the well and contacting accumulated asphaltene precipitate and a low-gravity, high-viscosity, asphaltene-based crude in the subterranean formation with the micelle treating fluid to disperse the accumulation of asphaltene and to reduce the viscosity of the low-gravity, high-viscosity, asphaltene-based crude.Type: GrantFiled: September 21, 1998Date of Patent: April 24, 2001Assignee: ETechMMInventor: William B. Walton
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Patent number: 6148913Abstract: This invention is a process and a formulation for minimising the squeezing and shut-in operations needed to inhibit scale in a production well using the precipitation squeeze method by injecting into an oil-bearing rock formation a water-miscible formulation comprising: (a) a water-miscible surfactant which is in liquid form, (b) a solution of water-soluble metal salt comprising a multivalent cation and (c) a solution of a water-miscible scale-inhibiting compound comprising an anionic component capable of forming a scale-inhibiting precipitate in situ in the presence of the cations in (b) upon injection into the rock formation, wherein the surfactant is a glycol ether and the minimum ion concentration of the scale inhibiting compound (c) is 50 ppm based on the total weight of the formulation.Type: GrantFiled: August 4, 1998Date of Patent: November 21, 2000Assignee: BP Chemicals LimitedInventor: Ian Ralph Collins
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Patent number: 6129148Abstract: Method for reducing the viscosity of clogging hydrocarbons in an oil well. The method utilizes a tube type heat exchanger enabling heated gases to pass through feed water coils to heat the water to a predetermined temperature and at a pressure which prevents any flashing or phase change of the feed water within the heat exchanger. From the heat exchanger the heated feed water passes through a conduit which empties into the oil well. The well is open to atmosphere so that the feed water undergoes a phase change or flashing when it is introduced into the oil well. The resulting combined steam and hot water reduce the viscosity of the hydrocarbons sufficiently to facilitate their flow out of the oil well.Type: GrantFiled: September 21, 1999Date of Patent: October 10, 2000Inventor: Thomas Meeks
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Patent number: 6119778Abstract: A method is disclosed for recovering methane from a solid carbonaceous subterranean formation having a production well in fluid communication with the formation and an injection well in fluid communication with the formation. In the method an oxygen-depleted effluent, produced by a cryogenic separator is injected into the formation through the injection well. A first methane-containing gaseous mixture is recovered from the formation through the production well-during at least a portion of the time the oxygen-depleted effluent is being injected into the formation. The first methane-containing gaseous mixture has a first methane-desorbing gas volume percent. The injection of oxygen-depleted effluent is ceased and thereafter a second methane-containing gaseous mixture is recovered from the formation which has a second methane-desorbing gas volume percent which is less than the first methane-desorbing gas volume percent.Type: GrantFiled: October 21, 1996Date of Patent: September 19, 2000Assignee: BP Amoco CorporationInventors: John P. Seidle, Dan Yee, Rajen Puri
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Patent number: 6050335Abstract: A system for in-situ production of bitumen comprises a steam injection well system which comprises a number of lateral sections that traverse the bitumen bearing formation partly above a basal water transition and/or thief zone such that a tip of each lateral section protrudes from the bitumen bearing formation into the basal water transition and/or thief zone.Type: GrantFiled: October 26, 1998Date of Patent: April 18, 2000Assignee: Shell Oil CompanyInventor: Leslie James Parsons
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Patent number: 6039116Abstract: A method and apparatus for operating a well which has a wellbore which passes into both an oil and gas production zone and a gas injection zone. An oil and gas stream is produced from the production zone through the wellbore to the surface where gas is separated from the oil. After production is shut-in, gas is mixed with a carrier fluid at the surface to form a dense mixture which, in turn, is flowed down the same wellbore and through a downhole auger separator wherein a portion of the gas is separated from the mixture. The separated gas is injected into the injection zone with the remainder of the mixture being returned to the surface. At the conclusion of the injection cycle, the well is returned to production and, if desired, the process is repeated.Type: GrantFiled: May 5, 1998Date of Patent: March 21, 2000Assignee: Atlantic Richfield CompanyInventors: Mark D. Stevenson, Jerry L. Brady
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Patent number: 6035933Abstract: A process for the thermo-hydraulic control of gas hydrates in subsea production and injection wells as well as pipelines which transport liquid or gaseous hydrocarbons is described, the process making use of a Nitrogen Generating System foamed or in solution. The control may signify the prevention of the formation of the gas hydrates or the dissolution of the gas hydrate plug already formed. Under conditions of use designed for the prevention of the formation of gas hydrates the SGN fluid prevents the thermal conditions leading to the gas hydrate plugs. Under conditions of use designed to dissolve the already formed gas hydrate plugs, the SGN fluid alters the thermo-hydraulic conditions which favor the gas hydrate plugs, so that they are dissolved and return to the water+gas phase.Type: GrantFiled: December 19, 1997Date of Patent: March 14, 2000Assignee: Petroleo Brasileiro S.A.-PetrobrasInventors: Carlos Nagib Khalil, Nelson De Oliveira Rocha, Lucia Cristina Ferreira Leite
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Patent number: 5996692Abstract: A method and composition for removing deposits of heavy hydrocarbonaceous materials and finely divided inorganic particulate matter from wellbore and flowline surfaces using a composition containing an alkyl polyglycoside, an ethoxylated alcohol, a caustic and an alkyl alcohol.Type: GrantFiled: February 13, 1998Date of Patent: December 7, 1999Assignee: Atlantic Richfield CompanyInventors: Albert F. Chan, William Mark Bohon, David J. Blumer, Kieu T. Ly
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Patent number: 5967233Abstract: A method for increasing the production of methane from a subterranean carbonaceous formation by chemically stimulating the formation of additional free surface area or cleats in the organic constituents of the formation and by causing inorganically adsorbed methane to be released from contained clay-minerals to increase the rate of methane desorption from the formation by injecting an aqueous oxidizing solution containing at least one oxidant into the formation, and thereafter producing methane from the formation at an increased rate. Suitable oxidants include peroxide, ozone, oxygen, chlorine dioxide, sodium hypochloride, water soluble salts of hypochlorous acid, perchlorate, chlorate, persulfate, perborate, percarbonate, permanganate, nitrate and combinations thereof.Type: GrantFiled: September 22, 1997Date of Patent: October 19, 1999Assignee: Vastar Resources, Inc.Inventors: Walter C. Riese, Stephen V. Bross
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Patent number: 5964290Abstract: A method for increasing the production of methane from a subterranean coal formation by chemically stimulating the formation of cleats in the formation to increase the rate of methane production from the formation by injecting an aqueous oxidant solution into the formation to stimulate the formation of cleats in the formation; and thereafter producing methane from the formation at an increased rate. Suitable oxidants include chlorine dioxide, metallic salts of perchlorate, chlorate, persulfate, perborate, percarbonate, permanganate, nitrate and combinations thereof.Type: GrantFiled: September 22, 1997Date of Patent: October 12, 1999Assignee: Vastar Resources, Inc.Inventors: Walter C. Riese, Stephen V. Bross
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Patent number: 5944104Abstract: A method for increasing the methane recovery from a subterranean carbonaceous formation by chemically stimulating the formation of cleats and increasing the surface area in the carbonaceous formation by injecting a gaseous oxidant into the carbonaceous formation to stimulate the formation of cleats in and increase the surface area of carbonaceous material in the carbonaceous formation; and thereafter producing methane from the carbonaceous formation at an increased rate. The gaseous oxidant may be ozone, oxygen or combinations thereof.Type: GrantFiled: October 16, 1997Date of Patent: August 31, 1999Assignee: Vastar Resources, Inc.Inventors: Walter C. Riese, Stephen V. Bross
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Patent number: 5942469Abstract: A composition for and an improved process of, enhancing petroleum recovery from a petroleum reservoir by injecting said composition into the reservoir through a wellbore are provided. The aqueous composition is derived from a concentrate which includes a defoaming agent, a demulsifying agent, and optionally a stabilizing agent suitable for stabilizing the concentrate as an aqueous emulsion. In one embodiment, the defoaming agent is dispersed in carrier solvent and the concentrate further includes an emulsifying agent suitable for emulsifying the carrier solvent in water. The composition is preferably injected at a high pumping rate directly into the formation through the tubing-casing annulus and allowed to permeate into the reservoir surrounding the wellbore before oil production commences. The composition and method are particularly suited for used in conjunction with steam injection oil recovery techniques.Type: GrantFiled: June 5, 1996Date of Patent: August 24, 1999Assignee: Chevron U.S.A. Inc.Inventors: Max S. Juprasert, Bruce W. Davis
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Patent number: 5871048Abstract: A method is provided for automatically determining an optimum gas injection rate for a gas-lifted oil well. The optimum gas-lift slope for the oil well is initially provided and stored in the memory of a programmable logic controller. A lift gas is injected into the well at an initial gas injection rate to displace a liquid at an initial liquid production rate from the well. The initial liquid production rate and initial gas injection rate are stored in the memory. Thereafter, the lift gas is injected into the well at a first incremental gas injection rate differing from the initial gas injection rate by a first incremental value. Additional liquid is displaced from the well at a first incremental liquid production rate and the first incremental liquid production rate and first incremental gas injection rate are stored in the memory. The first incremental slope is determined from the stored data points and compared to the optimum gas-lift slope.Type: GrantFiled: March 26, 1997Date of Patent: February 16, 1999Assignee: Chevron U.S.A. Inc.Inventors: Timothy J. Tokar, Brian E. Smith
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Patent number: 5865248Abstract: A method for increasing the permeability to methane of a subterranean coal formation by chemically stimulating the coal formation by injecting a gaseous oxidant into the coal formation and thereafter producing methane from the coal formation at an increased rate. The gaseous oxidant is ozone, oxygen or combinations thereof. The completion of wells penetrating a subterranean coal formation is facilitated by injecting a gaseous oxidant into the coal formation surrounding the well prior to forming a cavity in the coal formation around the well.Type: GrantFiled: April 30, 1997Date of Patent: February 2, 1999Assignee: Vastar Resources, Inc.Inventors: Walter C. Riese, Stephen V. Bross
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Patent number: 5860475Abstract: A thermal oil recovery process is disclosed for use in a heavy oil reservoir having a plurality of laterally separated, generally vertical wells whose use have left the reservoir characterized by a heated depletion zone, a channel, voidage, or mobility and communication. The process includes the steps of: drilling a well having a horizontal section and an opening therein that is located laterally between at least two of the vertical wells and at a depth within the lower part of the reservoir; injecting a steam through the two vertical wells to establish thermal communication with said horizontal well; and using the combination of steam drive and gravity drainage to recover oil from the reservoir through the horizontal well.Type: GrantFiled: December 8, 1994Date of Patent: January 19, 1999Assignee: Amoco CorporationInventors: Godwin Ejiogu, Paul R. Sander, William J. McCaffrey
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Patent number: 5803171Abstract: A method of producing hydrocarbons from a subterranean formation.Type: GrantFiled: July 26, 1996Date of Patent: September 8, 1998Assignee: Amoco CorporationInventors: William J. McCaffery, Grant W. Boyd, Andrew J. Fox, Wayne P. Kraus, Bryan D. Weir
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Patent number: 5769165Abstract: A method for increasing the production of methane from a subterranean coal formation penetrated by an injection well and a production well by producing methane from the coal formation via the production well; passing a portion of the methane to a synthesis gas generation zone wherein at least a portion of the methane is reacted with an oxygen-containing gas to produce a mixture of carbon monoxide and hydrogen; passing a major portion of the mixture to a hydrocarbon synthesis zone wherein the carbon monoxide and hydrogen are reacted to produce heavier hydrocarbons and a tail gas comprising nitrogen and carbon dioxide; separating a major portion of the tail gas from the hydrocarbons and recovering the hydrocarbons as a product stream; injecting at least a portion of the tail gas into the coal formation through the injection well. The methane may be obtained from a single well or a plurality of wells operated to produce the methane by a huff and puff process.Type: GrantFiled: January 31, 1996Date of Patent: June 23, 1998Assignee: Vastar Resources Inc.Inventors: Stephen V. Bross, Vu P. Dinh
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Patent number: 5725054Abstract: A method for recovering oil from a subterranean formation penetrated by a well is provided, comprising the steps of injecting via the well a gas mixture into the formation, the gas mixture comprising carbon dioxide and a gas selected from the group consisting of methane, nitrogen, or mixtures thereof; wherein the gas mixture is injected in an amount sufficient to establish in the vicinity of the well a zone of oil in contact with the gas mixture; and wherein the carbon dioxide comprises about 5 percent to about 50 percent by volume at reservoir conditions of the gas mixture; shutting in the well for a predetermined period of time; and producing the well and recovering the residual oil from the formation.Type: GrantFiled: August 21, 1996Date of Patent: March 10, 1998Assignee: Board of Supervisors of Louisiana State University and Agricultural & Mechanical CollegeInventors: Sara Shayegi, Philip A. Schenewerk, Joanne M. Wolcott
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Patent number: 5713416Abstract: The present invention provides methods of decomposing gas hydrates in subsea or subterranean wells, the equipment associated with the wells and in subterranean reservoirs containing gas hydrates. The methods basically comprise the steps of combining an acidic liquid with a basic liquid which chemically react exothermically to form a hot salt solution, contacting the gas hydrates with the hot salt solution to decompose at least a portion of the gas hydrates whereby natural gas and water are released therefrom and recovering the released natural gas, water and salt solution.Type: GrantFiled: October 2, 1996Date of Patent: February 3, 1998Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, James E. Griffith
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Patent number: 5669444Abstract: A method for increasing the production of methane from a subterranean coal formation by chemically stimulating the formation of cleats in the coal formation in order to facilitate removal of formation water, and increase the rate of methane production from the coal formation is disclosed. The method comprises injecting an aqueous oxidant solution into the coal formations to stimulate the formation of cleats in the coal formation; and thereafter producing methane from the coal formations at an increased rate. The aqueous oxidant solution comprises hypochlorite, metallic salts of hypochlorous acid, hydrogen peroxide, ozone, oxygen and combinations thereof.Type: GrantFiled: January 31, 1996Date of Patent: September 23, 1997Assignee: Vastar Resources, Inc.Inventors: Walter C. Riese, Stephen V. Bross
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Patent number: 5626191Abstract: A well arrangement is used wherein the production wells are generally horizontal, positioned low in the reservoir and arranged generally perpendicularly to a laterally extending combustion front. The combustion front is propagated by a row of vertical air injection wells completed high in the reservoir. The open production wells function to cause the combustion front to advance along their lengths. The process is characterized by a generally upright combustion front having good vertical and lateral sweep.Type: GrantFiled: June 23, 1995Date of Patent: May 6, 1997Assignee: Petroleum Recovery InstituteInventors: Malcolm Greaves, Alexandru T. Turta
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Patent number: 5607016Abstract: A method for the recovery of hydrocarbons from a reservoir of hydrocarbons including injecting a hydrocarbon solvent into the reservoir along with a displacement gas to mobilize hydrocarbons in the reservoir of hydrocarbons; and producing mobilized hydrocarbons from the reservoir of hydrocarbons. The hydrocarbon solvent is injected along one or more predominantly horizontal injection wells in the aquifer that are spaced from the production well or wells. The hydrocarbon solvent is a hydrocarbon solvent selected from the group consisting of ethane, propane, butane.Type: GrantFiled: April 14, 1995Date of Patent: March 4, 1997Inventor: Roger M. Butler
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Patent number: 5601144Abstract: A multi-point recovery system for recovering fluid from a plurality of wells, including a pumping apparatus which connects a suction pump sequentially to different wells or groups of wells. The apparatus includes a row of ports in a surface above which a carriage moves on wheels to connect the suction pump to different ports or groups of ports in turn. Hoses are inserted into each well and connect to the ports. The hoses have a high point near the well providing a gravity trap to prevent recovered fluid from running back into the well. The wells may be sealed at the top to allow pumping of soil air.Type: GrantFiled: July 24, 1995Date of Patent: February 11, 1997Assignee: Geo & Hydro International Pty. Ltd.Inventor: Ben Keet
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Patent number: 5566756Abstract: A method for treating a mixture of gaseous fluids within a solid carbonaceous subterranean formation. In some embodiments, the invention provides for the disposal of a strongly adsorbing gaseous fluid within the formation. In other embodiments, the invention provides a means for fractionating a mixture of gaseous fluids within the formation. In still other embodiments, the invention provides for the recovery of a raffinate from the formation which is enriched in relatively weaker adsorbing gaseous fluids. In still other embodiments, the invention provides for the recovery of methane from the formation.Type: GrantFiled: August 7, 1995Date of Patent: October 22, 1996Assignee: Amoco CorporationInventors: Joseph J. Chaback, Dan Yee, Richard F. Volz, Jr., John P. Seidle, Rajen Puri
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Patent number: 5566755Abstract: A method is disclosed for recovering methane from a solid carbonaceous subterranean formation having a production well in fluid communication with the formation and an injection well in fluid communication with the formation. In the method an oxygen-depleted effluent, produced by a cryogenic separator is injected into the formation through the injection well. A first methane-containing gaseous mixture is recovered from the formation through the production well during at least a portion of the time the oxygen-depleted effluent is being injected into the formation. The first methane-containing gaseous mixture has a first methane-desorbing gas volume percent. The injection of oxygen-depleted effluent is ceased and thereafter a second methane-containing gaseous mixture is recovered from the formation which has a second methane-desorbing gas volume percent which is less than the first methane-desorbing gas volume percent.Type: GrantFiled: February 13, 1995Date of Patent: October 22, 1996Assignee: Amoco CorporationInventors: John P. Seidle, Dan Yee, Rajen Puri
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Patent number: 5547022Abstract: A composition for, and an improved process of, enhancing petroleum recovery from a petroleum reservoir by injecting said composition into the reservoir through a wellbore are provided. The aqueous composition is derived from a concentrate which includes a defoaming agent, a demulsifying agent, and optionally a stabilizing agent suitable for stabilizing the concentrate as an aqueous emulsion. In one embodiment, the defoaming agent is dispersed in carrier solvent and the concentrate further includes an emulsifying agent suitable for emulsifying the carrier solvent in water. The composition is preferably injected at a high pumping rate directly into the formation through the tubing-casing annulus and allowed to permeate into the reservoir surrounding the wellbore before oil production commences. The composition and method are particularly suited for used in conjunction with steam injection oil recovery techniques.Type: GrantFiled: May 3, 1995Date of Patent: August 20, 1996Assignee: Chevron U.S.A. Inc.Inventors: Max S. Juprasert, Bruce W. Davis
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Patent number: 5542474Abstract: The invention is a foam method for improving conformance during a steam flood or carbon dioxide flood in a subterranean, oil-containing formation penetrated by at least one injection well and at least one production well. In a steam flood oil recovery process, sweep efficiency is improved by injecting steam until steam breakthrough occurs at the production well after which a mixture of steam, a noncondensible gas, and an aqueous surfactant-polypeptide solution is injected into the formation. The aqueous surfactant-polypeptide solution forms a stable foam with the formation oil at formation conditions that reduce the permeability of the highly permeable steam swept zones thereby diverting the steam to other portions of the formation containing unswept oil. The polypeptide is used as a partial substitute for the surfactant to improve the cost of the foam-forming mixture without reducing its effectiveness in increasing sweep efficiency.Type: GrantFiled: December 4, 1995Date of Patent: August 6, 1996Assignee: Mobil Oil CorporationInventors: Nizar F. Djabbarah, Ralph V. Garling, David T. Hand, Jennifer Macfadyen
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Patent number: 5513705Abstract: The invention is a foam method for improving conformance during a steam flood or carbon dioxide flood in a subterranean, oil-containing formation penetrated by at least one injection well and at least one production well. In a steam flood oil recovery process, sweep efficiency is improved by injecting steam until steam breakthrough occurs at the production well after which a mixture of steam, a noncondensible gas, and an aqueous surfactant-polypeptide solution is injected into the formation. The aqueous surfactant-polypeptide solution forms a stable foam with the formation oil at formation conditions that reduce the permeability of the highly permeable steam swept zones thereby diverting the steam to other portions of the formation containing unswept oil. The polypeptide is used as a partial substitute for the surfactant to improve the cost of the foam-forming mixture without reducing its effectiveness in increasing sweep efficiency.Type: GrantFiled: May 10, 1995Date of Patent: May 7, 1996Assignee: Mobil Oil CorporationInventors: Nizar F. Djabbarah, Ralph V. Garling, David T. Hand, Jennifer Macfadyen