Including Fracturing Or Attacking Formation Patents (Class 166/271)
  • Publication number: 20080164026
    Abstract: Multiple formations are isolated in the wellbore and fractured and gravel packed together. The bottom hole assembly can have a series of screens that are separated with packers in between and above and below the screen stack. The assembly is positioned where needed in the borehole and the topmost and lowermost packers (if used) are set. The bottom of the interval can alternatively be the hole bottom. With multiple intervals isolated a fracturing operation can take place for the entire isolated interval that can encompass multiple producing zones. The interval can also be gravel packed in a single operation. After the gravel pack of the interval, packers that are on the bottom hole assembly between screens that are aligned with perforations for different zones can be set into the gravel pack and get an effective seal against the casing to isolate the various producing zones from each other.
    Type: Application
    Filed: January 4, 2007
    Publication date: July 10, 2008
    Inventor: Michael H. Johnson
  • Publication number: 20080149389
    Abstract: A method of using the Earth mantle substance for hydrogen production. Area of application is production of cheap and efficient energy resources, in particular, a fuel for internal-combustion engine. The substance of invention is an exploration of continental and oceanic rifting areas, supported by abnormal mantle diapers with the mantle substance fingers outlet into the Earth's crust. The mantle substance wells drilling with help of turbodrills. A reaction cavity can be formed by injection and production wells linkage and/or production wells reaming after the well inlet into the mantle substance. The water is supplied into the injection well, and hydrogen gas, produced in reaction of water with intermetallic compounds, contained in the mantle substance, is brought to the surface by the production well.
    Type: Application
    Filed: December 24, 2003
    Publication date: June 26, 2008
    Inventor: Vladimir Nikolaevich Larin
  • Publication number: 20080087426
    Abstract: A method for lowering the temperature of a portion of a subsurface formation is provided. Preferably, the formation is an oil shale formation. The method includes the step of injecting a cooling fluid under pressure into a wellbore, with the wellbore having been completed at or below a depth of the subsurface formation. The wellbore has an elongated tubular member for receiving the cooling fluid and for conveying it downhole to the subsurface formation. The wellbore also has an expansion valve in fluid communication with the tubular member through which the cooling fluid flows. The method then includes the steps of injecting a cooling fluid under pressure into the wellbore, and expanding the cooling fluid across the first expansion valve. In this way, the temperature of the cooling fluid is reduced. The temperature of the surrounding formation is likewise reduced through thermal conduction and convection.
    Type: Application
    Filed: October 10, 2007
    Publication date: April 17, 2008
    Inventor: Robert D. Kaminsky
  • Publication number: 20080080994
    Abstract: A fluid end for a reciprocating pump is provided that includes a base material less subject to abrasion, corrosion, erosion and/or wet fatigue than conventional fluid end materials such as carbon steel, and a reinforcing composite material for adding stress resistance and reduced weight to the fluid end.
    Type: Application
    Filed: September 24, 2007
    Publication date: April 3, 2008
    Inventors: Philippe Gambier, Jean-Louis Pessin
  • Patent number: 7228908
    Abstract: The present invention is directed to a method of increasing hydrocarbon production in an existing well in a hydrocarbon reservoir. The method includes the steps of forming a substantially horizontal transverse fractured wellbore that intersects the existing well and injecting a fluid remote from the existing well so as to form a fluid front that sweeps the hydrocarbons into the horizontal transverse fractured wellbore. Successive fractures can be sealed to control propagation of the fluid front and delay infiltration of the fluid into the production.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: June 12, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Loyd E. East, Jr., Leldon M. Farabee, John M. Warren, Jr.
  • Patent number: 7205264
    Abstract: Fluids comprising an aqueous acid, synthetic polymer, metal crosslinking agent and lactic acid or a salt thereof have particular applicability in fracturing subterranean formations of an oil or gas well. The lactic acid acts as a delaying agent. As a result, crosslinking of the synthetic polymer and metal crosslinking agent typically occurs at a temperature of 100° F. or higher.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: April 17, 2007
    Assignee: BJ Services Company
    Inventor: Joel Lynn Boles
  • Patent number: 7134492
    Abstract: Hydraulic fracture dimensions and, optionally, fracture closure pressure and time are determined by adding particulate matter that discharges to create an acoustic signal to the proppant, allowing the particulate matter to discharge, and detecting the acoustic signal with geophones or accelerometers. The particulate matter may be spheres or fibers. The discharge may be explosion, implosion, detonation, or rapid combustion or ignition. The discharge may be triggered by fracture closure or by chemical reaction.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: November 14, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Dean Willberg, Jean Desroches, Kamal Babour, Kais Gzara, Christian Besson
  • Patent number: 7069990
    Abstract: A process for enhanced oil recovery from an extraction operation comprises the steps of selection of an appropriate hydrocarbon bearing stratum; providing at least one production well and one injection well; and injecting into the target stratum a slurry formed from sand, viscous liquids or oily sludge, which is delivered at or near formation fracture pressures. Monitoring of bottom hole pressure is carried out, to permit delivery of the slurried wastes in a series of injection episodes, in which the length of the episodes and interinjection periods is determined by maintaining the bottom hole pressure within a preselected range. The position and spread of the slurried wastes within the target stratum may be monitored through the use of additional monitoring steps.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: July 4, 2006
    Assignee: Terralog Technologies, Inc.
    Inventor: Roman Bilak
  • Patent number: 7066257
    Abstract: A method for treating lean and rich zones of a hydrocarbon containing formation is provided. In one embodiment, heat from one or more heaters may be provided to at least a portion of the formation. Heat may be allowed to transfer from the one or more heaters to a first part of the formation. In certain embodiments, the heat from the one or more heaters may pyrolyze at least some hydrocarbons within the first part of the formation. The method may include producing a mixture through a second part of the formation. In same embodiments, the produced mixture may include at least some pyrolyzed hydrocarbons from the first part of the formation. In an embodiment, the second part of the formation may have a higher permeability than the first part of the formation.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: June 27, 2006
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Eric Pierre de Rouffignac, Harold J. Vinegar
  • Patent number: 6915850
    Abstract: An oil shale formation may be treated using an in situ thermal process. Heat may be provided to a formation from one or more heat sources in the formation. Hydrocarbons within the formation may be pyrolyzed. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. In some embodiments, the formation may include a relatively impermeable portion and/or a relatively permeable portion.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: July 12, 2005
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric Pierre de Rouffignac, Scott Lee Wellington
  • Patent number: 6886633
    Abstract: Provided is a bore hole underreamer, intended in particular for oil drilling. The underreamer has a hollow body and at least two cylindrical bores. The bores are distributed over the circumference of the hollow body and each bore contains a cylindrical widening arm. Each arm has a bladed cutting end disposed on the outside of the body that slides between active and inactive positions. Another end of each arm is disposed inside the body and receives fluid pressure for pushing the arm into the active position. The underreamer includes a locking member for locking the arms in their inactive position when the locking member is immobilized in the body in a releasable fashion in a locking position. When released, the locking member leaves the locking position under a thrust from at least one of the arms subjected to the pressure capable of pushing the arm into its active position.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: May 3, 2005
    Assignee: Security DBS NV/SA
    Inventors: Philipp Fanuel, Jean-Pierre Lassoie, Stein Erik Moi, Clint Smith
  • Publication number: 20040206497
    Abstract: The present invention provides a method for enhancing the production of hydrocarbons from a subterranean formation. A hydrocarbon bearing formation, surrounding a well bore, is fractured with a fracturing fluid to create one or more fractures in the formation. The formation includes a higher permeability zone and a lower permeability zone with the fractures extending across both the higher and lower permeability zones. The lower permeability zone may contain a substantially higher concentration of hydrocarbons, oil and gas, than does the higher permeability zone which may generally be depleted of hydrocarbons. Proppant is then selectively positioned in the fractures using a carrier fluid with a majority of the proppant being positioned in the lower permeability zone. The fracture is allowed to close about the proppant to create at least one high conductivity channel in the lower permeability zone.
    Type: Application
    Filed: April 16, 2003
    Publication date: October 21, 2004
    Applicant: Chevron U.S.A. Inc.
    Inventors: Manuel E. Gonzalez, Joseph H. Schmidt
  • Patent number: 6776235
    Abstract: This invention relates generally to the art of hydraulic fracturing in subterranean formations and more particularly to a method and means for optimizing fracture conductivity. According to the present invention, the well productivity is increased by sequentially injecting into the wellbore alternate stages of fracturing fluids having a contrast in their ability to transport propping agents to improve proppant placement, or having a contrast in the amount of transported propping agents.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: August 17, 2004
    Assignee: Schlumberger Technology Corporation
    Inventor: Kevin England
  • Publication number: 20040094301
    Abstract: The invention concerns an aqueous viscoelastic fluid for use in the recovery of hydrocarbons. According to the invention, the aqueous viscoelastic fluid comprises a monomer, a dimer or an oligomer of a viscoelastic surfactant able to form a viscoelastic gel under downhole conditions, said surfactant comprising a hydrophobic tail and a hydrophilic head, and being of the following formulae: R—X—Y—Z where R is the hydrophobic tail of the surfactant, Z is the hydrophilic head of the surfactant, said hydrophilic head being charged, X is a stabilising group and Y chain is a linear, saturated or unsaturated, hydrocarbon chain of 1, 2 or 3 carbon atoms or a branched, saturated or unsaturated hydrocarbon chain wherein the main chain is of 1, 2 or 3 carbon atoms, possibly incorporating an aromatic ring.
    Type: Application
    Filed: December 11, 2003
    Publication date: May 20, 2004
    Inventors: Trevor Hughes, Timothy Gareth John Jones, Gary John Tustin, Jian Zhou
  • Patent number: 6722437
    Abstract: A technique for stimulating production of fluids from a subterranean formation. The technique utilizes a tubular member disposed within a wellbore. The tubular member comprises transverse openings that facilitate a formation fracturing process. Subsequent to fracturing, a completion element may be deployed within the tubular element. In some applications, the completion element is an expandable element.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: April 20, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Claude Vercaemer, Peter Allan Goode
  • Patent number: 6638896
    Abstract: The Invention relates to fluids and techniques to optimize/enhance the production of hydrocarbon from subterranean formations (e.g., “completion fluids”), in particular, fluids and techniques are. disclosed and claimed which remove wellbore damage and near-wellbore damage in the form of coating formed from drilling and production-related operations (“filtercake”); the techniques can be applied either by themselves or in conjunction with other completion operations, such as gravel packing; preferred embodiments are chelating agent and enzyme systems in a viscoelastic surfactant (VES) matrix.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: October 28, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Raymond J. Tibbles, Mehmet Parlar, Frank F. Chang, Diankui Fu, Jonathan Mark Davison, Elizabeth W. A. Morris, Antje M. Wierenga, Palathinkara S. Vinod
  • Patent number: 6502633
    Abstract: The remediation treatment creates environmentally neutral species from hydrocarbon contaminants. For soils having a low porosity, fissures are created in the site by, for example, fluid, i.e., hydraulic or pneumatic, fracturing. A catalyst is injected into the site and is permitted to diffuse through the site. An oxidizing agent is then introduced into the site to release a free radical in a Fenton-type reaction. The compounds react to release a free radical, which acts upon the contaminants to form environmentally neutral species. Diffusion of both compounds is aided by turbulence induced in the groundwater. A pH-adjusting compound is added to optimize reaction conditions. Reaction vapors are collected above ground, filtered, and vented to the atmosphere, reducing the chance for gas pressure buildup and possibly dangerous, potentially explosive conditions.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: January 7, 2003
    Inventors: Kent Cooper, James Carey, Robert J. Crim
  • Patent number: 6488087
    Abstract: A field development system and associated methods provide a main wellbore intersecting a formation and having fractures extending outwardly from the main wellbore into the formation. Multiple additional wellbores, spaced apart from the main wellbore and without associated additional production facilities, intersect the fractures and provide auxiliary drainage of the formation into the main wellbore via the fractures extending outwardly therefrom.
    Type: Grant
    Filed: March 13, 2001
    Date of Patent: December 3, 2002
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James R. Longbottom, Tommie A. Freeman
  • Patent number: 6412559
    Abstract: A process for recovering methane from a coal bed and/or sequestering a fluid more strongly adsorbing than methane (“SAG”) in a coal bed involves fracturing an injection well and cyclically injecting SAG with intervening shut-in periods. Even though the absolute permeability of the coal bed decreases with continued SAG sorption, the SAG injectivity, surprisingly and unexpectedly, increases while injecting SAG at pressures greater than reservoir pressure, but less than fracture pressure or fracture extension pressure. The increased injectivity is thought to be due to a reduction in near-well flow resistance.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: July 2, 2002
    Assignee: Alberta Research Council Inc.
    Inventors: William Daniel Gunter, Matthew John Mavor, David Hin-Sum Law
  • Publication number: 20010045280
    Abstract: A field development system and associated methods provide for cost effective development of a field by minimizing the number of required production facilities and preventing damage to wellbores due to drilling lateral wellbores therefrom. In a described embodiment, a field development system includes a main wellbore intersecting a formation and having fractures extending outwardly into the formation. Multiple additional wellbores intersect the fractures to thereby improve drainage of the formation without the need of drilling lateral wellbores from the main wellbore and without the need of providing additional production facilities for the additional wellbores.
    Type: Application
    Filed: March 13, 2001
    Publication date: November 29, 2001
    Inventors: James R. Longbottom, Tommie A. Freeman
  • Patent number: 6318464
    Abstract: An improved method for the recovery of hydrocarbons from a hydrocarbon deposit comprising the steps of introducing a diluent gas along a predominantly horizontal injection well drilled at the base of a hydrocarbon deposit; creating an initial communication path with a predominantly horizontal production well spaced laterally apart from the injection well; gradually enriching the diluent gas with a hydrocarbon solvent to produce a hydrocarbon solvent vapor which is saturated at reservoir conditions; continuously circulating the diluent gas and the saturated hydrocarbon solvent vapor through the hydrocarbon deposit; and producing mobilized hydrocarbons from the hydrocarbon deposit.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: November 20, 2001
    Assignee: Vapex Technologies International, Inc.
    Inventor: Igor J. Mokrys
  • Patent number: 6149344
    Abstract: Acid gas is liquified by compression and cooling, mixed with water under pressure and flowed into a disposal well.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: November 21, 2000
    Assignee: Master Corporation
    Inventor: Frank H. Eaton
  • Patent number: 6138755
    Abstract: In a method for enhancing the compatibility of a zinc-brine completion fluid with a fracturing fluid, test samples of selected completion fluids are combined with test samples of selected fracturing fluids to form an admixture. The parameters of incompatibility between the completion fluid and the fracturing fluid are analyzed and identified. The parameters or indicia of incompatibility identified can be precipitation, emulsification and/or an increase in viscosity. The zinc brine completion fluid is then blended with additives to remove these parameters of incompatibility. The additives can be selected from a group comprising hydrochloric acid, hydrobromic acid, acetate salts, citrate salts, and surfactants. At the well site, the altered zinc brine completion fluid is pumped in to displace drilling fluids in the wellbore before pumping in fracturing fluid. Additional altered brine completion can follow the fracturing fluid into the wellbore.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: October 31, 2000
    Assignee: Tetra Technologies, Inc.
    Inventor: Rosa Swartwout
  • Patent number: 6140277
    Abstract: The Invention relates to novel fluids and techniques to optimize/enhance the production of hydrocarbon from subterranean formations (e.g., "completion fluids"), in particular, fluids and techniques are disclosed and claimed which remove wellbore damage and near-wellbore damage in the form of coating formed from drilling and production-related operations ("filtercake"); the techniques can be applied either by themselves or in conjunction with other completion operations, such as gravel packing; preferred embodiments are chelating agent and enzyme systems in a viscoelastic surfactant (VES) matrix.
    Type: Grant
    Filed: December 31, 1998
    Date of Patent: October 31, 2000
    Assignee: Schlumberger Technology Corporation
    Inventors: Raymond J. Tibbles, Mehmet Parlar, Frank F. Chang, Diankui Fu, Jonathan Mark Davison, Elizabeth W. A. Morris, Antje M. Wierenga, Palathinkara S. Vinod
  • Patent number: 6119776
    Abstract: Methods of stimulating and producing multiple stratified hydrocarbon reservoirs having numerous separate reservoir compartments are provided. The methods basically comprise the steps of drilling a first well bore into a lower part of the reservoir having a horizontal portion which intersects a previously drilled second well bore therein. At least one fracture is formed extending into two or more reservoir compartments from the horizontal portion of the third well bore for conducted hydrocarbons in the reservoir into the horizontal portion of the first well bore from where the hydrocarbons flow into the second well bore and are withdrawn.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: September 19, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Stephen A. Graham, Raymond L. Brown, David S. Stegemeier
  • Patent number: 6095244
    Abstract: Methods of stimulating and producing multiple stratified hydrocarbon reservoirs having numerous separate reservoir compartments are provided. The methods basically comprise the steps of drilling a first well bore into a lower part of the reservoir having a horizontal portion which intersects a previously drilled second well bore therein. At least one fracture is formed extending into two or more reservoir compartments from the horizontal portion of the first well bore for conducted hydrocarbons in the reservoir into the horizontal portion of the first well bore from where the hydrocarbons flow into the second well bore and are withdrawn.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: August 1, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Stephen A. Graham, Raymond L. Brown, David S. Stegemeier
  • Patent number: 6030048
    Abstract: An in-situ reactor with hydrologic cells is provided to facilitate recovery of metals such as gold from rocks, or purification of salts such as potium or magnesium chloride formed by evaporation of brines, by injecting into a source aquifer a fluid, which flows through and reacts with the solids or host rock within the in-situ reactor and then flows into a sink aquifer, from it is drained or pumped out via an exhaust borehole into a plant or a facility for further chemical treatment.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: February 29, 2000
    Assignee: Tarim Associates for Scientific Mineral and Oil Exploration AG.
    Inventor: Kenneth J. Hsu
  • Patent number: 5967233
    Abstract: A method for increasing the production of methane from a subterranean carbonaceous formation by chemically stimulating the formation of additional free surface area or cleats in the organic constituents of the formation and by causing inorganically adsorbed methane to be released from contained clay-minerals to increase the rate of methane desorption from the formation by injecting an aqueous oxidizing solution containing at least one oxidant into the formation, and thereafter producing methane from the formation at an increased rate. Suitable oxidants include peroxide, ozone, oxygen, chlorine dioxide, sodium hypochloride, water soluble salts of hypochlorous acid, perchlorate, chlorate, persulfate, perborate, percarbonate, permanganate, nitrate and combinations thereof.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: October 19, 1999
    Assignee: Vastar Resources, Inc.
    Inventors: Walter C. Riese, Stephen V. Bross
  • Patent number: 5964290
    Abstract: A method for increasing the production of methane from a subterranean coal formation by chemically stimulating the formation of cleats in the formation to increase the rate of methane production from the formation by injecting an aqueous oxidant solution into the formation to stimulate the formation of cleats in the formation; and thereafter producing methane from the formation at an increased rate. Suitable oxidants include chlorine dioxide, metallic salts of perchlorate, chlorate, persulfate, perborate, percarbonate, permanganate, nitrate and combinations thereof.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: October 12, 1999
    Assignee: Vastar Resources, Inc.
    Inventors: Walter C. Riese, Stephen V. Bross
  • Patent number: 5944104
    Abstract: A method for increasing the methane recovery from a subterranean carbonaceous formation by chemically stimulating the formation of cleats and increasing the surface area in the carbonaceous formation by injecting a gaseous oxidant into the carbonaceous formation to stimulate the formation of cleats in and increase the surface area of carbonaceous material in the carbonaceous formation; and thereafter producing methane from the carbonaceous formation at an increased rate. The gaseous oxidant may be ozone, oxygen or combinations thereof.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: August 31, 1999
    Assignee: Vastar Resources, Inc.
    Inventors: Walter C. Riese, Stephen V. Bross
  • Patent number: 5865248
    Abstract: A method for increasing the permeability to methane of a subterranean coal formation by chemically stimulating the coal formation by injecting a gaseous oxidant into the coal formation and thereafter producing methane from the coal formation at an increased rate. The gaseous oxidant is ozone, oxygen or combinations thereof. The completion of wells penetrating a subterranean coal formation is facilitated by injecting a gaseous oxidant into the coal formation surrounding the well prior to forming a cavity in the coal formation around the well.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: February 2, 1999
    Assignee: Vastar Resources, Inc.
    Inventors: Walter C. Riese, Stephen V. Bross
  • Patent number: 5783524
    Abstract: Glycine-N,N-diacetic acid derivatives and their alkali metal, akaline earth metal, ammonium and substituted ammonium salts, used as completing agents for alkaline earth metal and heavy metal ions in the production and transport of petroleum and natural gas.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: July 21, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Greindl, Wilhelmus Slotman
  • Patent number: 5675088
    Abstract: An apparatus for measuring in situ stresses surrounding an active earthquake fault and forecasting shallow earthquakes includes a network of monitoring stations, each operating a respective borehole assembly for measuring in situ lateral stresses. The monitoring stations are arrayed along a recognized fault plane and arranged to straddle the fault plane, so that lateral stress readings may be obtained throughout the ground media surrounding the fault zone. All of the monitoring stations communicate with a central data-gathering facility, so that real-time analysis of changes in lateral stress orientation and magnitude surrounding the fault zone may be undertaken, and the results used to forecast forthcoming seismic events. Each borehole probe assembly includes a trio of single fracture expansion probes operated periodically, reiteratively, and automatically to expand against the borehole wall and determine the principal maximum and minimum lateral stress vectors in the underground media.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: October 7, 1997
    Inventor: Shosei Serata
  • Patent number: 5669444
    Abstract: A method for increasing the production of methane from a subterranean coal formation by chemically stimulating the formation of cleats in the coal formation in order to facilitate removal of formation water, and increase the rate of methane production from the coal formation is disclosed. The method comprises injecting an aqueous oxidant solution into the coal formations to stimulate the formation of cleats in the coal formation; and thereafter producing methane from the coal formations at an increased rate. The aqueous oxidant solution comprises hypochlorite, metallic salts of hypochlorous acid, hydrogen peroxide, ozone, oxygen and combinations thereof.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: September 23, 1997
    Assignee: Vastar Resources, Inc.
    Inventors: Walter C. Riese, Stephen V. Bross
  • Patent number: 5593248
    Abstract: The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: January 14, 1997
    Assignee: The Regents of the University of California
    Inventors: Edward J. Kansa, Ananda M. Wijesinghe, Brian E. Viani
  • Patent number: 5576485
    Abstract: A method and apparatus for measuring ambient stress states and material properties in underground media includes a borehole probe having a cylindrical tube formed of soft, elastic polymer material secured about a central mandrel. An upper end cap assembly removably secures the probe to a service module to provide high pressure hydraulic fluid and sensor connections. A distal end cap seals the tube to the mandrel, so that hydraulic pressure causes diametrical expansion of the tube. The end cap includes an annular seal formed of elastic polymer material and helical springs that are embedded therein in the circumferential direction. The interiors of the helical springs are filled with steel pins or balls to prevent deformation of the springs. High strength fibers are bonded in the outer surfaces of the annular seal and oriented longitudinally to permit radial expansion of the seal assembly without hydraulic leakage or extrusion of the soft polymer of the cylindrical tube.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: November 19, 1996
    Inventor: Shosei Serata
  • Patent number: 5484231
    Abstract: A process for obtaining decomposition products from a slurry of municipal waste by use of a geothermal reservoir. The process comprises placing the slurry of municipal waste into a geothermal reservoir; sealing the opening of the geothermal reservoir; and retorting the municipal waste slurry in the geothermal reservoir for a time sufficient to liberate methane, ammonia, urea, nitrites, nitrates, and phosphates from said slurry. Thereafter, the liberated products are removed from the geothermal reservoir and separated.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: January 16, 1996
    Assignee: Mobil Oil Corporation
    Inventors: William L. Cannan, Alfred R. Jennings, Jr.
  • Patent number: 5452763
    Abstract: The present apparatus and method utilizes a downhole electrolysis process implemented by means of an elongated gas generating apparatus containing an array of cascaded electrolysis cells distributed along all or part of the borehole length to be fractured. In one use of the present invention in a deep or a shallow drilled borehole, an electrical current delivered downhole converts an appropriate electrolyte to a stoichiometric mixture of combustible gases, such as, oxygen and hydrogen, which is ignited when sufficient gases have been collected to achieve the desired explosive force in the area surrounding the drilled borehole. In another use of the present invention, the gases are not ignited but rather at least one of the generated gases are delivered by pressure into the area surrounding the drilled borehole to enhance environmental remediation processes.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: September 26, 1995
    Assignee: Southwest Research Institute
    Inventor: Thomas E. Owen
  • Patent number: 5411086
    Abstract: A method for enhanced oil recovery from a low permeability diatomaceous reservoir by imbibition is described. In this method, oil is displaced from a single injection well, or series of injection wells into a single producer or series of producing wells by a combination of applied fluid pressure, plus "enhanced imbibition." Enhanced imbibition is accomplished by adding chemical additives to the injection fluid so that rock in the tight reservoir has a stronger affinity for the water present therein, thus releasing oil from the rock.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: May 2, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Christopher Burcham, Robert E. Fast, Anthony S. Murer, Paul S. Northrop
  • Patent number: 5407009
    Abstract: A method for the recovery of hydrocarbons from a hydrocarbon deposit overlying an aquifer, including injecting a hydrocarbon solvent in the vapour phase into the aquifer to mobilize hydrocarbons in the hydrocarbon deposit; and producing mobilized hydrocarbons from the hydrocarbon deposit. Mobilized hydrocarbons are produced from the aquifer, and the hydrocarbon solvent is injected along one or more predominantly horizontal injection wells in the aquifer that are spaced from and alternate with the production well or wells. The hydrocarbon solvent is a hydrocarbon solvent selected from the group consisting of ethane, propane, butane.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: April 18, 1995
    Assignee: University Technologies International Inc.
    Inventors: Roger M. Butler, Igor J. Mokrys
  • Patent number: 5400856
    Abstract: Methods are provided for overpressured perforating and fracturing of a subsurface formation in a substantially deviated well. A perforating gun is run into the well and is pushed through the deviated portion thereof on a coiled tubing string. The coiled tubing string contains an internal supporting pressure which is high enough to prevent collapse of the coiled tubing string prior to perforation of the well and which is low enough to avoid rupturing the coiled tubing string. After the perforations are formed and the fractures are initiated, the supporting gas pressure in the coiled tubing string is bled off to the atmosphere and the coiled tubing string and perforating gun are retrieved.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: March 28, 1995
    Assignee: Atlantic Richfield Company
    Inventor: Joseph H. Schmidt
  • Patent number: 5396957
    Abstract: Expandable casing portions are provided, such as casing slip joints or expansion joints, on opposite sides of a fracture initiation location to accommodate casing and formation movement during fracturing of a well. The fracture initiation location provided by forming openings through the well casing and then forming fan-shaped slots in the formation surrounding the casing. These fan-shaped slots circumscribe an angle about the axis of the casing substantially greater than the angle circumscribed by the opening itself through which the slot was formed. These techniques are particularly applicable to fracturing of horizontal wells, but are also useful on vertical wells. The expansion joints formed as tubular members having alternating inner and outer annular grooves. In another embodiment, the expansion joints formed by tubular members defining alternating inner and outer spiral grooves therein.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: March 14, 1995
    Assignee: Halliburton Company
    Inventors: Jim B. Surjaatmadja, Timothy W. Helton, Danny G. Porter
  • Patent number: 5392854
    Abstract: A process to recover oil is provided wherein an oil containing subterranean formation is heated by conductive heat transfer. The high temperature levels of this process result in high recoveries of initial oil in place, and recovery of the oil within a short time period. This process is particularly applicable to diatomite formations that have low permeabilities.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: February 28, 1995
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric P. De Rouffignac, Carlos A. Glandt, Thomas Mikus, Mark A. Beckemeier
  • Patent number: 5388643
    Abstract: A method is disclosed for using a pressure swing adsorption separator system to provide an oxygen-depleted gaseous effluent for injecting into a suitable solid carbonaceous subterranean formation, such as a coalbed, to enhance the recovery of methane from the formation.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: February 14, 1995
    Assignee: Amoco Corporation
    Inventors: Dan Yee, Rajen Puri
  • Patent number: 5388645
    Abstract: Processes are disclosed for separating an oxygen-containing gas into oxygen-enriched and oxygen-depleted streams. The oxygen-depleted stream is injected into a methane-containing solid carbonaceous subterranean formation to produce a methane-containing gaseous mixture. The oxygen-enriched stream is reacted with a stream containing an oxidizable material which can be the methane-containing mixture.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: February 14, 1995
    Assignee: Amoco Corporation
    Inventors: Rajen Puri, Paul T. Pendergraft
  • Patent number: 5388642
    Abstract: A method of recovering methane from a solid carbonaceous subterranean formation having a production well in fluid communication with the formation and an injection well in fluid communication with the formation, comprising the steps of passing a gaseous fluid containing at least 60 volume percent nitrogen and at least 15 volume percent oxygen through a membrane separator to produce an oxygen-depleted effluent, pressurizing the oxygen-depleted effluent to a pressure above a reservoir pressure of the solid carbonaceous subterranean formation, injecting the oxygen-depleted effluent into the formation through the injection well, and recovering a fluid comprising methane through the production well.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: February 14, 1995
    Assignee: Amoco Corporation
    Inventors: Rajen Puri, Dan Yee
  • Patent number: 5388646
    Abstract: An injection well has become plugged with an accumulation of undesirable material that is causing the wellhead pressure required to effect a selected minimum flow rate of injection fluid into the formation to have increased to a maximum value. The method of this invention provides a process for treating the plugged formation to remove the accumulated undesirable material. The process requires a plurality of treatment cycles, and in each cycle injection fluid flows into the wellhead for a first time interval while injecting treatment chemical into the flowing injection fluid during a second time interval, with the first time interval being much longer than the second time interval. The well is acidized after a multiplicity of cycles and returned to operation.
    Type: Grant
    Filed: October 1, 1993
    Date of Patent: February 14, 1995
    Inventor: Clifford J. Hensley
  • Patent number: 5375660
    Abstract: Minerals in a subterranean formation are dissolved by treating them in the presence of an organic acid with a fluoride-containing compound having a concentration in the range of from 0.007 N to 0.05 N. The hydrogen ion concentration can be less than 0.02 N, preferably less than 0.004 N. The fluoride-containing compound can be hydrofluoric acid. Alternatively, the minerals can be treated by applying alternating stages of a solution of fluoride salt, such as ammonium fluoride or ammonium bifluoride, and an organic acid, such as acetic acid. The treatment can be done in a formation at a temperature of at least 350.degree. F.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: December 27, 1994
    Assignee: Chevron Research and Technology Company
    Inventor: C. Dean Wehunt
  • Patent number: RE39077
    Abstract: Acid gas is liquified by compression and cooling, mixed with water under pressure and flowed into a disposal well.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: April 25, 2006
    Assignee: Master Corporation
    Inventor: Frank H. Eaton
  • Patent number: RE39244
    Abstract: Acid gas is liquified by compression and cooling, mixed with water under pressure and flowed into a disposal well.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: August 22, 2006
    Assignee: Master Corporation
    Inventor: Frank H. Eaton