Abstract: Embodiments of the invention relate to a method of treating a subterranean formation comprising shale comprising forming a fluid comprising potassium acetate, and introducing the fluid to a surface of the subterranean formation comprising shale, wherein geomechanical weakening of the formation is lower than if the formation were not in contact with the fluid. Embodiments of the invention relate to a method of treating a subterranean formation comprising shale, comprising forming a fluid comprising potassium chloride and ammonium acetate; and introducing the fluid to a surface of the subterranean formation comprising shale, wherein geomechanical weakening of the formation is lower than if the formation were not in contact with the fluid.

Abstract: A cross-linking system for hydratable polymers for using is formation fracturing applications is disclosed along with methods for using same, where the cross-linking system includes a reaction product of a transition metal alkoxide or alkanolate and a borate or borate generating reagent.

Abstract: Non-spherical particulates are useful in the stimulation of subterranean formations. A proppant pack composed of the non-spherical particulates exhibits greater porosity than a corresponding proppant pack composed of spherical particulates. Non-spherical particulates which are hollow and non-porous may further be at least partially filled with a chemical treatment agent including water-soluble or oil-soluble chemical treatment agents.

Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.

Abstract: A method of making a proppant is provided, wherein the method includes the steps of: (a) forming a particulate comprising: (i) a binder; and (ii) a filler; and (b) sintering the particulate to form a sintered proppant, wherein the sintered proppant comprises: (i) at least 20 wt % of alkaline earth oxide equivalent; and (ii) at least 20 wt % of silicon dioxide equivalent. A method of treating (e.g., fracturing) a subterranean formation is provided, the method including the steps of: (a) suspending the sintered proppant in a treatment fluid; and (b) introducing the sintered proppant into the subterranean formation. The sintered proppant is made with a raw material selected from the group consisting of: unhydrated cement, hydrated cement (e.g., construction cement or concrete waste), kiln dust, fly ash, limestone, lime, talc, olivine, dolomite, clay that contains a substantial concentration of alkaline earth oxide equivalent, and any combination thereof in any proportion.

Abstract: Provided are methods that include a method comprising: placing a clean fluid comprising proppant particulates into a portion of a fracture in a subterranean formation, and depositing one or more of the proppant particulates into the fracture to form a partial monolayer. In another aspect, the invention provides methods that include placing a degradable fluid loss additive comprising collagen into a subterranean formation.

Abstract: An ultra strong, hollow sintered, impervious, metallic shell for use in structural applications including proppants for hydraulic fracturing. The shell is made of a maraging steel, low alloy steel, or stainless steel with a crush strength of about 3,000 psi or greater and a density of about 0.6 g/cm3 to about 2.5 g/cm3.

Abstract: In one aspect, the invention relates to a method for “tagging” proppants so that they can be tracked and monitored in a downhole environment, based on the use of composite proppant compositions containing dispersed fillers whose electromagnetic properties change at a detectable level under a mechanical stress such as the closure stress of a fracture. In another aspect, the invention relates to composite proppant compositions containing dispersed fillers whose electromagnetic properties change under a mechanical stress such as the closure stress of a fracture. The currently preferred embodiments use substantially spherical thermoset nanocomposite particles where the matrix comprises a terpolymer of styrene, ethylvinylbenzene and divinylbenzene, a PZT alloy manifesting a strong piezoelectric effect or Terfenol-D manifesting giant magnetostrictive behavior is incorporated to provide the ability to track in a downhole environment, and carbon black particles possessing a length that is less than 0.

Abstract: A method for “tagging” proppants so that they can be tracked and monitored in a downhole environment, based on the use of composite proppant compositions comprising a particulate substrate coated by a material whose electromagnetic properties change at a detectable level under a mechanical stress such as the closure stress of a fracture. In another aspect, the invention relates to composite proppant compositions comprising coatings whose electromagnetic properties change under a mechanical stress such as the closure stress of a fracture. The substantially spherical composite proppants may comprise a thermoset nanocomposite particulate substrate where the matrix material comprises a terpolymer of styrene, ethylvinylbenzene and divinylbenzene, and carbon black particles possessing a length that is less than 0.

Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.

Abstract: A method is given for treating a wellbore in a subterranean formation by hydraulic fracturing, slickwater fracturing, gravel packing, and the like, by using plate-like materials as some or all of the proppant or gravel. The plate-like materials are particularly useful in complex fracture systems, for example in shales. They may be used as from about 20 to about 100% of the proppant. Relative to conventional proppants, plate-like proppants demonstrate (a) enhanced crush resistance of the proppant due to better stress distribution among proppant particles, (b) diminished proppant embedment into formation fracture faces due to the greater contact surface area of proppant particles with the formation, (c) better proppant transport due to lower proppant settling rates, (d) deeper penetration into branched and fine fracture networks, and (e) enhanced proppant flowback control. Preferred plate-like proppants are layered rocks and minerals; most preferred is mica.

Abstract: The present invention relates to glass-ceramic proppants which can be used to prop open subterranean formation fractions, as well as other uses. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the glass-ceramic proppants.

Abstract: The present invention relates to a proppant for the hydraulic fracturing of oil or gas wells, which consists of a mixture of from 10 to 95% by weight of a spherical proppant and from 5 to 90% by weight of an angular material, the percentages being based on the total weight of the mixture. The proppant obtained according to the present invention is useful for eliminating or decreasing the “flow-back” phenomenon in operations in oil or gas wells.

Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.

Abstract: Non-spherical particulates are useful in the stimulation of subterranean formations. A proppant pack composed of the non-spherical particulates exhibits greater porosity than a corresponding proppant pack composed of spherical particulates. Non-spherical particulates which are hollow and non-porous may further be at least partially filled with a chemical treatment agent including water-soluble or oil-soluble chemical treatment agents.

Abstract: The invention is directed to systems and methods for forming and using proppant particles having desirable attributes.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising dissymmetric bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions comprising polycationic quaternary ammonium compounds that comprise dissymmetric bis-quaternary compounds. In yet another aspect, the present technology provides polycationic quaternary ammonium compounds comprising a carboxylate functional polycationic quaternary ammonium compound. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C.

Abstract: Methods and compositions are provided that relate to well bore treatments that comprise swellable particles. An embodiment includes a method that comprises introducing a fluid comprising a dual oil/water-swellable particle into a subterranean formation. Another embodiment includes a method of cementing that comprises: introducing a cement composition comprising cement, water, and a dual oil/water-swellable particle into a space between a pipe string and a subterranean formation; and allowing the cement composition to set in the space. Another embodiment includes a well treatment composition comprising a dual oil/water-swellable particle.

Abstract: A proppant consists of a core part and shell of a material different from the material of the core part. The shell comprises a soft material attached rigidly to the core part in such a way that the total surface area of the points where the shell and the core part are joined is less than the surface area of the core part.

Abstract: Lightweight polyamide particulates may be used in treatment of subterranean formations, including hydraulic fracturing and sand control methods, such as gravel packing. The polyamide particulates typically have an apparent specific gravity (ASG) between from about 1.05 to about 2.0 and are stable at temperatures up to 500° C. The polyamide particulates may be used in combination with a filler which further serves to increase the strength and temperature stability of the resulting composite. Fracture conductivity may be increased by the placement of the low density polyamide particulates as a partial monolayer.

Abstract: A proppant material is provided that is in the form of generally rigid, elastic plate-like particles having a maximum to minimum dimension ratio of more than about 5. The proppant may be formed from a corrosion resistant material or having a corrosion resistant material formed thereon. The plate-like particles may be substantially non-deformable and may be formed from stainless steel or carbon steel provided with a corrosion resistant coating. The particles may have a thickness of from about 100 to about 300 ?m and may be in the form of a grating. A method of hydraulic fracturing in a formation penetrated by a wellbore is also provided wherein proppant material in the form of generally rigid, elastic plate-like particles having a maximum to minimum dimension ratio of more than about 5 are introduced into the wellbore. The particles may be formed from a corrosion resistant material or having a corrosion resistant material formed thereon.

Abstract: A substance and method for treating a subterranean formation using hydraulic fracturing. A non-metallic, substantially deformable, proppant particle is “elastically flexible” or “plastically compressible” and adapted for use at concentrations which will substantially create a partial monolayer.

Abstract: A proppant composition comprises a non-radioactive, detectable tracer at least partially embedded in a ceramic composition. The composition may be prepared by agglomerating granules of the ceramic material and granules of the non-radioactive, detectable material to produce the particle by compression. Backflow of proppants in a fractured subterranean formation into which a plurality of particles of the proppant composition have been introduced may be tracked by analyzing a sample of the backflow by detecting for presence of the tracer in the sample.

Abstract: An increase in effective propped lengths is evidenced in hydraulic fracturing treatments by the use of ultra lightweight (ULW) proppants. The ULW proppants have a density less than or equal to 2.45 g/cc and may be used as a mixture in a first proppant stage wherein at least one of the proppants is a ULW proppant. Alternatively, sequential proppant stages may be introduced into the formation wherein at least one of the proppant stages contain a ULW proppant and where at least one of the following conditions prevails: (i.) the density differential between the first proppant stage and the second proppant stage is greater than or equal to 0.2 g/cc; (ii.) both the first proppant stage and the second proppant stage contain a ULW proppant; (iii.) the rate of injection of the second proppant stage into the fracture is different from the rate of injection of the first proppant stage; or (iv.) the particle size of the second proppant stage is different from the particle size of the first proppant stage.

Abstract: The invention is related to the field of oil and gas industry, particularly, to the methods of oil or gas formation fracture using proppants, i.e. to the technologies of making fracture cracks, and may be used for underground formations processing, particularly for oil formation fractures. In the method of oil formation fracture including high-rate fluid injection into the formation and addition of a proppant into the fluid, polydicyclopentadiene material is used as the proppant. The method enables ensuring a lower friction during the proppant injection into the well retaining the cracks permeability due to the specific density of the proppant close to 1, its high thermal stability and high crushing strength.

Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.

Abstract: Method of treating a hydrocarbon-bearing formation having brine and treated hydrocarbon-bearing formations. The method includes contacting a hydrocarbon-bearing formation with a composition comprising solvent and a polymer. The polymer comprises divalent units represented by formula: (formula I); and a plurality of alkyleneoxy groups. In some embodiments, the solvent at least one of solubilizes or displaces the brine in the formation. In some embodiments, the solvent includes at least one of a polyol or polyol ether independently having from 2 to 25 carbon atoms and at least one of water, a monohydroxy alcohol, an ether, or a ketone, wherein the monohydroxy alcohol, the ether, and the ketone each independently have up to 4 carbon atoms. Hydrocarbon-bearing formations and proppants treated with the polymer are also disclosed.

Abstract: The invention provides a proppant for treating a subterranean formation penetrated by a wellbore, wherein a typical specimen of the proppant has a non-globular and non-fibrous shape. The invention also provides a method for stimulating a subterranean formation penetrated by a wellbore, the method comprising the steps of forming the treatment fluid and introducing the treatment fluid through the wellbore and into the subterranean formation at a sufficient pressure to fracture the formation.

Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.

Abstract: The invention provides a method of forming a gelled liquid hydrocarbon treatment fluid, comprising: combining a liquid hydrocarbon, a phosphoric acid ester and a pre-mixed solution comprising water, ferrous ion (Fe2+) and an amine; and forming the gelled liquid hydrocarbon treatment fluid. A method of treating a portion of a subterranean formation is also disclosed and comprises: providing a gelled liquid hydrocarbon treatment fluid, by combining a liquid hydrocarbon, a phosphoric acid ester and a pre-mixed solution comprising water, ferrous ion and an amine, and treating the portion of the subterranean formation with the gelled liquid hydrocarbon treatment fluid.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions that comprise polycationic quaternary ammonium compounds comprising bis-quaternary compounds. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C. when the amount of the one or polycationic quaternary compounds is less than about 10% by weight based on the total weight of the composition.

Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.

Abstract: Methods are providing, including methods comprising providing a liner disposed within a well bore that penetrates a subterranean formation, such that the well bore comprises an annular space between the exterior surface of the liner and the well bore wall; providing a jetting tool disposed within the liner; introducing a stimulation fluid to a treatment interval of the well bore via the jetting tool, such that the stimulation fluid is introduced with sufficient pressure to create or enhance a plurality of perforations in the liner in the treatment interval; introducing a proppant slurry comprising a plurality of resin-coated particulates to the treatment interval of the well bore; and allowing the resin-coated particulates to fill at least a portion of the liner in the treatment interval and at least a portion of the annular space in the treatment interval.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In one aspect, the present technology provides polycationic quaternary ammonium compounds that comprise bis-quaternary compound. The bis-quaternary compounds of the present technology can be symmetric or dissymmetric. In another aspect, the present technology provides viscoelastic well bore treatment fluids comprising water, and at least one polycationic quaternary ammonium compound that comprises a bis-quaternary compound. In another aspect, the present technology provides polycationic carboxylates. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or 110° C.

Abstract: A substance and method for treating a subterranean formation using hydraulic fracturing. A non-metallic, substantially deformable, proppant particle is “elastically flexible” or “plastically compressible” and adapted for use at concentrations which will substantially create a partial monolayer.

Abstract: A method of fracturing using deformable proppants minimizes proppant pack damage, without compromising the fracturing fluid's proppant transport properties during pumping, by use of deformable proppants. Selection of proppant is dependent upon the mechanical properties of the formation rock. The strength of the deformable proppant is dependent upon the modulus of the formation rock being treated such that the proppant is capable of providing, at the very least, a minimum level of conductivity in in-situ stress environments. The maximum elastic modulus of the deformable proppant is less than the minimum modulus of the formation rock which is being treated. The method is particularly applicable in fracturing operations of subterranean reservoirs such as those comprised primarily of coal, chalk, limestone, dolomite, shale, siltstone, diatomite, etc.

Abstract: Methods and compositions useful for subterranean formation treatments, such as hydraulic fracturing treatments and sand control that include porous materials. Such porous materials may be selectively configured porous material particles manufactured and/or treated with selected glazing materials, coating materials and/or penetrating materials to have desired strength and/or apparent density to fit particular downhole conditions for well treating such as hydraulic fracturing treatments and sand control treatments. Porous materials may also be employed in selected combinations to optimize fracture or sand control performance, and/or may be employed as relatively lightweight materials in liquid carbon dioxide-based well treatment systems.

Abstract: The disclosed invention relates to a process of using molten salt ion exchange to treat particles such as spherically shaped soda-lime-silica glass particles. The treated particles may be used as proppants in hydrofractured oil and natural gas wells.

Abstract: Methods and compositions useful for subterranean formation treatments, such as hydraulic fracturing treatments and sand control that include porous materials. Such porous materials may be selectively configured porous material particles manufactured and/or treated with selected glazing materials, coating materials and/or penetrating materials to have desired strength and/or apparent density to fit particular downhole conditions for well treating such as hydraulic fracturing treatments and sand control treatments. Porous materials may also be employed in selected combinations to optimize fracture or sand control performance, and/or may be employed as relatively lightweight materials in liquid carbon dioxide-based well treatment systems.

Abstract: Elimination of sand entrainment and a significant increase in hydrodynamic permeability of the sand pack in an area near the wellbore are achieved through the use of a sand and/or proppant, and proppant material mixture at the final stage of the fracture filling process, where individual particles of the proppant material have at least one shape of plates, lattices, hollow bars, inside-hollow tubes with a closed impermeable cavity or cavities, toroidal particles, elongated particles in the form of ovals, pellets or plates, cylinders with a closed impermeable cavity or cavities, or blocks with a comb multi-channel structure with throughout channels of the ellipse or polygon cross-section.

Abstract: An adaptive cementitious composite composition, comprising: a coarse particulate material such as sand or proppant; a series of other particulate or fibrous materials; and a carrier fluid; the sand and other particulate materials being present as a series of coarse, medium and fine particle sizes in ratios selected to provide an optimized packing volume fraction; wherein the sand or proppant is coated with a resin and at least one of the other particulate or fibrous materials is a material that can be modified when placed at a downhole location.

Abstract: Composite proppant particles each of which comprises a plurality of microbubbles and a resin binder are disclosed. Also disclosed are a method of using such composite proppant particles to prop fractures in wells formed in underground formations.

Abstract: A composition and method are disclosed. The composition includes a carrier fluid and a solids mixture combined to form a slurry, wherein the solids mixture comprises a plurality of volume-averaged particle size distribution (PSD) modes, wherein a first PSD mode comprises solids having a volume-average median size at least three times larger than the volume-average median size of a second PSD mode such that a packed volume fraction of the solids mixture exceeds 0.75, and wherein the solids mixture comprises a degradable material and includes a reactive solid. The method includes circulating the slurry through a wellbore to form a pack in a fracture and/or a screen-wellbore annulus; degrading the degradable material to increase porosity and permeability of the pack; and producing a reservoir fluid through the permeable pack.

Abstract: A method of treating a subterranean formation penetrated by a wellbore is carried out by forming a treatment fluid comprising an aqueous carrier fluid and a solid-form polyimide homopolymer or copolymer capable of hydrolyzing to form polycarboxylates and/or polycarboxylic acids. The treatment fluid is introduced into the formation through the wellbore. In another method, a treatment fluid comprising an aqueous carrier fluid, a solid-form polysuccinimide homopolymer or copolymer and at least one of a viscosifying agent, proppant and an acid capable of dissolving materials of the formation is formed. This is introduced into the formation through the wellbore. A method of treating a sandstone-containing formation penetrated by a wellbore may also be carried out by forming a treatment fluid comprising an aqueous solution containing a hydrogen fluoride source, ammonium hydroxide and at least one of a polyimide and a polycarboxylate, which is introduced into the formation through the wellbore.

Abstract: Method of treating proppant particles present in a fractured subterranean geological formation comprising hydrocarbons in-situ with fluorinated silane.

Abstract: Sintered, spherical composite pellets or particles comprising alumina fines, at least one of clay and bauxite and optionally a sintering aid, are described, along with a process for their manufacture. The use of such pellets in hydraulic fracturing of subterranean formations and in grinding is also described.

Abstract: Methods comprising: providing a consolidating agent emulsion composition that comprises an aqueous fluid, a surfactant, and a consolidating agent; and coating at least a plurality of particulates with the consolidating agent emulsion to produce a plurality of consolidating agent emulsion coated particulates. Methods comprising: providing a treatment fluid comprising a consolidating agent emulsion comprising an aqueous fluid, an amine surfactant, and a consolidating agent; and introducing the treatment fluid into a subterranean formation. Methods comprising the steps of: coating a plurality of particulates with a consolidating agent emulsion to produce consolidating agent emulsion coated particulates; providing a treatment fluid comprising an aqueous fluid, a surfactant, and a consolidating agent; introducing the treatment fluid into a subterranean formation.

Abstract: This invention refers to the oil and gas production industry and can be employed to enhance the productivity of wells by preventing the closure of fractures through application of proppant granular material during the formation fracturing operation.

Abstract: A resin coated proppant slurry and a method for preparing a slurry is provided where the resin coated proppant particles are rendered less dense by attaching stable micro-bubbles to the surface of the resin coated proppants. A collector or frother may be added to enhance the number or stability of bubbles attached to the proppants. This method and composition finds use in many industries, especially in oil field applications.

Abstract: The invention relates to methods to stimulate formation production when oil recovering. Reducing cost and simplifying the manufacture of the propping material to prevent proppant carrying-over were achieved owing to the injection of the hydraulic fracturing liquid with a propping agent containing a propping material as randomly cut particles of the polymers reworked and being in irregular shapes with the maximum-to minimum size ratio more than 5. A propping material should be a material being resistant to hydraulic fracturing liquid, oil, gas condensate and oil-containing liquids, and salt water in the range of temperatures 40 to 140° C., plastic within pressure range of 7 atm to 700 atm, and having Young's modulus within 100 MPa to 20000 MPa. The propping material thickness can be within 10 to 500 micrometers. The propping material can be of flake-like, lamellar, and chip-like shapes or their mixture. The propping material content of the propping agent should be 0.