Abstract: A method of creating a network of fractures in a reservoir is provided. The method includes designing a desired fracture network system, and determining required in situ stresses to create the desired fracture network within the reservoir. The method further includes designing a layout of wells to alter the in situ stresses within the stress field, and then injecting a fracturing fluid under pressure into the reservoir to create an initial set of fractures within the reservoir. The method also includes monitoring the in situ stresses within the stress field, and modifying the in situ stresses within the stress field. The method then includes injecting a fracturing fluid under pressure into the reservoir in order to expand upon the initial set of fractures and to create the network of fractures. A method for producing hydrocarbons from a subsurface formation is also provided herein, wherein a fracture network is created from a single, deviated wellbore production.

Abstract: The present techniques provide methods and systems for fracturing reservoirs without directly treating them. For example, an embodiment provides a method for fracturing a subterranean formation. The method includes causing a volumetric decrease in a zone proximate to the subterranean formation so as to apply a mechanical stress to the subterranean formation.

Abstract: The components of surfactant-laden fluids, such as those used in hydrocarbon recovery operations such as for stimulation, e.g. hydraulic fracturing, may be re-used and re-cycled into components for subsequent use in a wide range of similar or different operational fluids. In particular, aqueous fluids gelled with viscoelastic surfactants and having components therein to pseudo-crosslink the elongated VES micelles and for internal breaking may be separated into its component parts by relatively inexpensive methods such as filtration. One filtration method includes contacting the surfactant-containing fluid with a particle pack having particulate additives therein which filter out or extract fine solids from the fluid. In an alternate embodiment the surfactant-laden fluid is a nano- and/or micro-emulsion wellbore cleanup fluid.

Abstract: Disclosed herein are an acid emulsion fluid for use in sealing target portions of a hydrocarbon producing formation penetrated by a wellbore and the method of use thereof for fluid loss control.

Abstract: A method of preventing phase separation of a viscoelastic surfactant fluid or diverting agent due to ferric ions during matrix acidizing of an oil well which involves the injection of both citric acid and acetic acid which prevents the separation of the viscoelastic diverting agent/acid with ferric ions which avoids damage to well productivity and/or injectivity.

Abstract: A method of fracturing a subterranean formation comprising at least in part shale formation, comprises providing a carrier fluid; providing a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 microns and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.75; combining the carrier fluid and the particulate blend into a fracturing slurry; fracturing the formation with the fracturing slurry to create at least a fracture; and removing the second amount of particulates from the fracture.

Abstract: A composition and method are disclosed. The composition includes a carrier fluid and a solids mixture combined to form a slurry, wherein the solids mixture comprises a plurality of volume-averaged particle size distribution (PSD) modes, wherein a first PSD mode comprises solids having a volume-average median size at least three times larger than the volume-average median size of a second PSD mode such that a packed volume fraction of the solids mixture exceeds 0.75, and wherein the solids mixture comprises a degradable material and includes a reactive solid. The method includes circulating the slurry through a wellbore to form a pack in a fracture and/or a screen-wellbore annulus; degrading the degradable material to increase porosity and permeability of the pack; and producing a reservoir fluid through the permeable pack.

Abstract: Provided is a method and composition for the in-situ generation of synthetic sweet spots in tight-gas formations. The composition can include nitrogen generating compounds, which upon activation, react to generate heat and nitrogen gas.

Abstract: Disclosed herein are methods for extracting a kerogen-based product from subsurface shale formations. The methods utilize in-situ reaction of kerogen involving liquid phase chemistry at ambient temperatures at pressures for the subsurface shale formation. These methods rely on chemically modifying the shale-bound kerogen to render it mobile using metal particulate catalysts. In the methods disclosed herein a fluid comprising metal is provided to the subsurface shale formation comprising kerogen in an inorganic matrix. A reducing agent is provided to the subsurface shale formation. The kerogen is converted by contacting the kerogen with a metal particulate catalyst formed from the metal; and a mobile kerogen-based product is formed. At least a portion of the mobile kerogen-based product is recovered. The kerogen-derived product can be upgraded to provide commercial products.

Abstract: A method for producing nitrogen for injection into an enhanced oil recovery operation wherein the nitrogen is produced in an air separation device and the oxygen stream produced is not discarded but recovered and employed with or without an additional air gas stream for feeding to a partial oxidation unit/autothermal reformer and shift conversion to produce carbon dioxide and hydrogen. The carbon dioxide can additionally be used for injection into an enhanced oil recovery operation and the hydrogen can be used as a fuel for a gas turbine driven closed cycle power plant for providing energy to the air separation device.

Abstract: A three step method of using a non-acidic stimulation fluid in high temperature sandstone formation is provided. The method consists of using a preflush brine, a non-acidic stimulation fluid, and an overflush brine.

Abstract: A formation treatment system includes an annulus spanning member having one or more openings therein. A tubular having one or more ports therein in fluid communication with the one or more openings. A sleeve capable of isolating or communicating the one or more ports with an ID of the tubular. A method for effecting precision formation treatment is included.

Abstract: Methods of hydraulically fracturing subterranean coal seams and formations resulting in improved permeability to stimulate Coalbed Methane. In one method, the coal seam is fractured using a proppant-containing fracturing fluid in alternating stages with an aqueous base solution that etches the fracture faces of the coal thereby creating channels for fluid flow. In another method, the coal seam is fractured using a fracturing fluid without propping agents in alternating stages with an aqueous oxidizing solution that is pumped at a pressure sufficient to maintain the fractures in an open position thereby etching the fracture faces to create channels for fluid flow. In yet another embodiment, the aqueous oxidizing agent solution is pumped into the formation at a pressure sufficient to create fractures therein and simultaneously etch the faces of the open fractures to thereby form channels in the faces for increased fluid flow.

Abstract: An anchor tool having a housing, a one-way restrictor device in fluid communication with the housing, and a stabilizer affixed to the housing. The one-way restrictor device is configured to allow restricted flow in a first direction, and to allow flow in a second direction.

Abstract: A method is disclosed for in-situ upgrading bitumen or heavy oils during thermal recovery operations. In one embodiment, steam injection for thermal recovery of bitumen in a dolomitic or limestone reservoir matrix material can be carried out at a higher temperature, a higher pressure, a longer dwell time or a combination of all three to allow the mobilized bitumen to remain in contact with the catalytic materials in the dolomitic or limestone reservoir matrix material for longer times at higher temperatures and pressures. In another embodiment, catalytic materials such as for example, oxides or carbonates of calcium, magnesium, potassium, nickel and/or iron can be injected into the reservoir along with steam to further enhance catalytic activity during the heating, mobilization and recovery phases of a thermal recovery operation.

Abstract: In an aspect, method for stimulating fluid flow in a wellbore is provided, the method including placing a fluid jetting valve in a tubular, conveying the tubular in a wellbore with the fluid jetting valve in a closed position and changing a pressure within the tubular to move the fluid jetting valve to an open position. In addition, the method includes directing a stimulation fluid through the open fluid jetting valve into a wall of the wellbore and moving the fluid jetting valve to a permanently closed position via a passive control device.

Abstract: An apparatus and method for selectively delivering a fluid to a targeted area through the use of vortices that are experiencing Taylor-Couette flow. Rotation of the outer surface of a body of the apparatus causes fluid within the annular area between a wellbore and the outer surface to form opposing vortices, which can then be used to selectively deliver the fluid to the targeted area, such as areas of low permeability of a reservoir, in order to improve flow characteristics of a producing area.

Abstract: A bottom-to-surface connection installation of at least two undersea pipes (10a, 10b) resting on the sea bottom, the installation comprising: 1) a first hybrid tower comprising: a) a vertical riser (1a) anchored (3a) to a first base and connected to a said undersea pipe (10a) resting on the sea bottom and having its top end connected to a first sub-surface float (2a); and b) a first connection pipe (4a) preferably a flexible pipe, providing the connection between a floating support (11) and the top end of said riser; and 2) at least one second rigid pipe (1b) rising from the sea bottom on which it rests (10b) or from a second undersea pipe resting on the sea bottom to which its bottom end is connected, said bottom end not being anchored at said first base, up to the sub-surface where its top end is connected to a second float (2b) situated substantially at the same depth as said first float (2a) and fastened to said first float at least respectively a flexible second connection pipe (2b) providing its c

Abstract: Methods and systems are provided for favorably altering the chemomechanical properties of subterranean formations using treatment fluids comprising surfactants and halide salts. Methods for treating formations comprise the steps of introducing a chemomechanical treatment fluid into the formation and allowing the treatment fluid to interact with the formation to alter its petrochemical properties in various ways. Depending on the application, the chemomechanical treatment fluid may comprise a base fluid, a halide salt and an amphoteric or nonamphoteric surfactant where the surfactant is dissolved in the base fluid at a concentration below its critical micelle concentration. Applications of use involving the chemomechanical treatment fluids include treatment operations, secondary recovery operations, drilling operations, and any other operation that would benefit from the formation property modifications described herein.

Abstract: A fluid containing a viscous hyposaline aqueous solution of first and second cationic polymers that include quatemized ammonium groups, wherein the first cationic polymer includes a hydrophilic base polymer structure and the second cationic polymer includes a lipophilic base polymer Also disclosed is a method of introducing the viscous fluid into an initial first interval of a subterranean formation, and diverting with the viscous fluid a treating fluid from the initial first interval to an initial second interval.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A process that includes pumping a first wellbore fluid comprising an oxidative degradable polymer into a wellbore through a subterranean formation; pumping a second wellbore fluid comprising a pH-activated oxidative breaker into the wellbore; pumping a third wellbore fluid comprising a delayed acid source into the wellbore; and allowing the delayed acid source to acidify at least a portion of the wellbore to a pH of less than 7 so as to activate the pH-activated oxidative breaker at the lower pH and degrade the oxidative degradable polymers is disclosed.

Abstract: The instant disclosure is directed to a method of enhancing adsorption of a salt inhibitor onto a wellbore region, wherein the method comprises preconditioning the wellbore region, emplacing the salt inhibitor into the wellbore region, and shutting in the wellbore region for a period of time to at least initiate adsorption of the salt inhibitor onto the wellbore region. The salt inhibitor comprises an at least partially water soluble compound comprising a Group 3 to Group 15 metal and/or an at least partially water soluble compound having any one of the formulae: wherein X is O or S; and R1, R2, R3, R4, and when present, R5 and/or R6 each independently comprise an organic or an inorganic functional group.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: A method to improve the effectiveness of MEOR or bioremediation processes. In this method toxic chemicals accumulated in subterranean sites adjacent to the water injection wells are either dispersed or removed prior to introduction of microbial inocula for enhanced microbial oil recovery or bioremediation of these sites.

Abstract: An acid treatment composition is provided including an alkyl sarcosinate as corrosion inhibitor and an optional corrosion inhibitor intensifier in an acidic solution. Methods for treating wells with these acid treatment compositions are also provided that help control corrosion of the alloy surfaces used in the wells during the acid treatment.

Abstract: A method of selectively blocking fractures in a subterranean formation by injecting a diversion agent into the well is disclosed. According to one embodiment, the method comprises injecting a diversion agent into a subterranean formation to form an alkaline-earth carbonate precipitate from decomposition of a carbonyl compound, wherein the diversion agent includes the carbonyl compound and an alkaline-earth halide salt.

Abstract: Methods for treating a subterranean formation can comprise introducing a treatment fluid comprising dicarboxymethyl glutamic acid (GLDA) or a salt thereof into a subterranean formation, and at least partially removing an iron-containing material in the subterranean formation using the GLDA. Treatment fluids used in the methods may have a pH equal to or greater than about 2.

Abstract: Methods for treating a subterranean formation can comprise introducing a treatment fluid comprising dicarboxymethyl glutamic acid (GLDA) or a salt thereof into a subterranean formation comprising a carbonate mineral, and at least partially dissolving the carbonate mineral in the subterranean formation using the GLDA. Treatment fluids containing GLDA or a salt thereof may be used to increase the permeability of a subterranean formation.

Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.

Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.

Abstract: Crosslinkable-polymer compositions that comprise a chitosan-based compound and a phenol source, and associated methods, are provided. Various methods of use are also provided. In one embodiment, the methods comprise providing a crosslinkable-polymer composition comprising an aqueous fluid, a chitosan-based compound, a chitosan-reacting polymer, and a phenol source; introducing the crosslinkable-polymer composition into the portion of the subterranean formation; and allowing the crosslinkable-polymer composition to form a crosslinked gel in the portion of the subterranean formation.

Abstract: Alkanesulfonic acid microcapsules and the use thereof as an additive for acidizing applications in carbonatic rock formations, especially for increasing the permeability of underground carbonatic mineral oil- and/or natural gas-bearing and/or hydrothermal rock formations and for dissolving carbonatic and/or carbonate-containing impurities in the production of mineral oil and/or natural gas or geothermal power generation are described. Additionally described is an acidic formulation comprising the inventive microcapsules and the use thereof for the aforementioned purpose, and a corresponding process.

Abstract: A well treatment composition is formed from a fluid mixture of a viscoelastic surfactant and a liquid carrier fluid. The fluid mixture has rheological properties wherein the mixture exhibits shear-thickening behavior when the shear rate is increased from a first shear rate to a second higher shear rate. The fluid mixture may further include a shear activation additive that interacts with the viscoelastic surfactant to facilitate the shear-thickening behavior. The method is accomplished by introducing the fluid mixture into a wellbore formed in a subterranean formation. In certain applications, the fluid mixture may be recycled by bringing the fluid mixture to the surface and reintroducing the fluid into the same or a different wellbore.

Abstract: Methods of using nanohybrid-stabilized emulsions in a well are provided. The methods include the steps of: (a) forming an emulsion comprising: (i) a nanohybrid; (ii) water or an aqueous solution; and (iii) a water-immiscible liquid; (b) introducing a well fluid comprising the emulsion into a well; and (c) after the step of introducing, modifying the nanohybrid to break the emulsion in the well. The methods can be used in various applications, such as in drilling, completion, or intervention operations.

Abstract: Nanoparticles are added to a fluid containing a wetting agent and the fluid is pumped down a well to enhance wetting of solid surfaces in and around the well before pumping an acid solution down the well. After acid is pumped, a fluid containing nanoparticles and wetting agent is again pumped down the well, leading to improved flow capacity of the well.

Abstract: The productivity of hydrocarbons from hydrocarbon-bearing calcareous or siliceous formations is enhanced by contacting the formation with a well treatment composition which contains a hydrofluoric acid source, a boron containing compound and a phosphonate acid, ester or salt thereof.

Abstract: Surfactant based viscoelastic fluids for enhancing the productivity of a hydrocarbon-bearing formations have particular applicability in acid fracturing of subterranean formations surrounding oil and gas wells. The viscoelastic fluid contains an organic acid, an inorganic monovalent salt and a quaternary ammonium aromatic salt and water. The fluid may further be foamed or energized.

Abstract: Methods that include a method comprising: providing a treatment fluid comprising an aqueous base fluid and a relative permeability modifier, wherein the relative permeability comprises a water-soluble polymer having hydrophobic or hydrophilic modification; introducing the treatment fluid into an interval of a well bore penetrating the subterranean formation; creating one or more perforations through a hydrajetting tool in the interval of the well bore, wherein the perforations extend from the well bore and into the subterranean formation; and allowing the treatment fluid to contact a portion of the subterranean formation.

Abstract: A method for well treatment by forming a temporary plug in a fracture, a perforation, a wellbore, or more than one of these locations, in a well penetrating a subterranean formation is provided, in which the method of well treatment includes: injecting a slurry comprising a degradable material, allowing the degradable material to form a plug in a perforation, a fracture, or a wellbore in a well penetrating a formation; performing a downhole operation; and allowing the degradable material to degrade after a selected time such that the plug disappears.

Abstract: A process for retorting and extracting sub-surface hydrocarbons. The process comprises drilling an energy delivery well extending from the surface to a location proximate a bottom of the hydrocarbons. The hydrocarbons are heated from the bottom to form a retort, the retort extending along a portion of the energy delivery well. A vapor tube is extended to a location proximate the retort, the vapor tube having an entrance corresponding to the region of the retort along the energy delivery well that is nearest the surface exit.

Abstract: A method to enhance oil recovery from a subterranean reservoir, the reservoir being accessible via a production well. The method includes injecting a surfactant solution that includes surfactants into the production well. The surfactant solution selected to increase an oil-to-water ratio of oil recovery from a porous matrix portion of the reservoir. The method also includes injecting a well-servicing volumetric solution into the production well to perform a second well treatment process. The second well treatment process is selected from the group consisting of a scale inhibition squeeze process, a well acidizing process, a chemical process to reduce water production rate, an acid fracturing process, and a hydraulic fracturing process. In the method, the surfactant solution and the second well treatment solution are injected into the production well within less than about six months of one another.

Abstract: A method and apparatus for fracturing a formation containing a wellbore comprising the steps of (a) injecting a gel into the wellbore; (b) permitting the gel to increase in viscosity and (c) fracturing the formation in the vicinity of the gel.

Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a cleavable viscoelastic surfactant and a hydrophobically-modified polymer, wherein the cleavable surfactant comprises a head group and a hydrophobic tail of at least 18 carbon atoms connected through a degradable acetal, amide, ether or ester bond and wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.