Abstract: The present invention provides a well treatment fluid for use in a well, the well treatment fluid comprising water; an amine-based polymer; an polysaccharide-based polymer; and an oxidizing agent that is capable of at least partially oxidizing at least the polysaccharide-based polymer. The present invention also provides a method of treating a subterranean formation penetrated by a wellbore, the method comprising the steps of: (a) forming a well treatment fluid comprising water; an amine-based polymer; a polysaccharide-based polymer; and an oxidizing agent that is capable of at least partially oxidizing at least a portion of the polysaccharide-based polymer; and (b) contacting the well treatment fluid with the subterranean formation.

Abstract: A method for evaluating the permeability and formation damage in the porous rock around a well bore. This method relates to the use of a single string coiled tubing and a down hole assembly which includes a microcontroller, an electrically operable fluid control valve and electrically operable pressure sensing devices which allow for real time pressure transient analysis techniques before, during and after formation stimulation treatments.

Abstract: A reciprocating pump vent-dump and methods of use for utilization in the hydrocarbon industry. The device is preferably used with barrel pumps although it may be used with tubing pumps. The device is positioned at the bottom of the wellbore immediately above the stinger and immediately below above the standing valve and comprises a sliding piston within an outer housing. The device may be opened pulling upwards on the pump drive mechanism thereby allowing fluid within the production tubing to drain back into the formation as long as the pump drive mechanism is held up. The device closes when the pump is returned to normal operation. The method of spotting chemicals requires a pre-measured quantity of chemicals at the surface which is sucked into the tubing string when the valve is opened followed by a pre-measured quantity of make-up fluid which is drawn into the well thereby placing the chemicals at the required point.

Abstract: A formation treatment tool assembly is conveyed within a well casing by a tubing string and has a housing defining treatment fluid supply and discharge passages and a fluid injection port through which treatment fluid is directed from the supply passage into a packer isolated casing interval and a fluid inlet port permitting flow from the isolated casing interval to the fluid discharge passage. Spaced straddle packer elements of the tool are energized to establish sealing engagement with the well casing and define an isolated casing interval and are de-energized to retract from sealing engagement with the well casing and permit tubing conveyance. A dump valve connected with the tool housing is opened to permit flow of treatment fluid from the isolated casing interval through the treatment fluid discharge passage and is closed to confine treatment fluid to the isolated casing interval.

Abstract: Methods and compositions useful for sand control and/or hydraulic fracturing of subterranean formations that utilize relatively lightweight and/or substantially neutrally buoyant particles as particulate sand control or proppant material. Particles that may be employed include particulates of naturally-occurring materials that may be optionally strengthened or hardened by exposure to a modifying agent. Effectiveness of a modifying agent may be optionally enhanced by facilitating interaction between a modifying agent and one or more components present in a naturally occurring material by using enhancing agents and/or by using conditions that enhance interaction.

Abstract: A well treatment tool is installed along the sucker rod string of a well, within the surrounding production tube string. The tool provides for the distribution of a treatment fluid (solvent, etc.) within the fluid being pumped or flowing from the well. The tool receives treatment fluid through the hollow sucker rod string, and distributes the fluid through a valve which is set at a predetermined pressure. When the treatment fluid pumped down the sucker rod string from the surface exceeds the predetermined opening pressure of the valve, the treatment fluid is distributed into the production tube string through one or more passages in the tool. The present tool may be used simultaneously with well production, with fluid (oil, etc.) rising up the production tube string, carrying the treatment fluid therewith. The treatment fluid is thus distributed throughout the local fluid processing system, including pipelines from the well, any initial treatment operations, and any storage tanks.

Abstract: A tubing string assembly and a method are disclosed for fluid treatment of a wellbore. The tubing string assembly includes substantially pressure holding closures spaced along the tubing string, which each close at least one port through the tubing string wall. The closures are openable by a sleeve drivable through the tubing string inner bore.

Abstract: The chemical injection system (10) is provided for controlling the distribution of chemical fluid from a supply conduit (12) into an individual petroleum well at an adjustable rate. The system includes a remotely operated two position control valve (14) connected to the supply conduit, and cylinder (30) having a cylinder bore (31) with first input-output port (34), and a second input-output port (36). The fluid barrier (50, 150, 250, 251) is provided within the cylinder bore, such that chemical fluid flows from the supply conduit through the control valve to one end of the cylinder bore and forces the barrier to displace a fixed volume of fluid. Each operation of the directional control valve reverses travel direction of the barrier within the cylinder bore and injects another fixed quantity of fluid into the well.

Abstract: Gelatin capsules containing oil field chemicals, preferably weighted with a heavy metal compound, are made more stable under certain conditions by the incorporation of a strong chelating agent. The microcapsules can provide an extended treatment period since many materials that would damage the microcapsules are controlled by the chelating agent.

Abstract: Improved mud additive compositions are provided which are especially formulated to control hole enlargement due to salt bed erosion during drilling, and to assist in solubilization of deposited salt during well operations. The compositions include a first ingredient such as sodium or potassium ferrocyanide and mixtures thereof, and a second ingredient such as the a phosphonic acid, alkali or alkaline earth metal phosphonic acid salts, or mixtures thereof. The first ingredient is generally present at a level of from about 50-95% by weight in the particulate, dilutable form of the invention, whereas the second ingredient is present at a level of from about 5-50% by weight. The compositions hereof may be added to drilling mud during drilling operations or to fresh water for removing salt depositions.

Abstract: A petroleum well having a well casing, a production tubing, a source of time-varying current, a downhole chemical injection device, and a downhole induction choke. The casing extends within a wellbore of the well. The tubing extends within the casing. The current source is located at the surface. The current source is electrically connected to, and adapted to output a time-varying current into, the tubing and/or the casing, which act as electrical conductors for providing downhole power and/or communications. The injection device having a communications and control module, a chemical container, and an electrically controllable chemical injector. The communications and control module is electrically connected to the tubing and/or the casing. The chemical injector is electrically connected to the communications and control module, and is in fluid communication with the chemical container. The downhole induction choke is located about a portion of the tubing and/or the casing.

Abstract: The invention provides a method for the treatment of a hydrocarbon well which method comprises administering down said well polymeric particles impregnated with a well treatment chemical or precursor or generator thereof (e.g. a scale inhibitor), said particles having a pore volume of at least 20%, and being prepared by a process which comprises preparing in a first step an aqueous dispersion of polymer particles containing from 0.

Abstract: A scale dissolver fluid for dissolving scale in a subterranean hydrocarbon-bearing formation comprises an effective amount of a scale dissolver formulation and an effective amount of a surfactant for controlling the viscosity of the fluid. In use, formation hydrocarbons act on the surfactant to reduce the viscosity of the fluid so that the fluid selectively invades a hydrocarbon-bearing zone of the formation.

Abstract: An electric submersible pumping system provides for the production of fluids from a well and for limiting the amount of sediment accumulation in the well. The apparatus includes an electric submersible pumping system lowered into a well on a production tubing. The electric submersible system includes an electric submersible pump having an intake at or near a lower end thereof. A seal is connected to the intake and a motor is connected to a lower end of the seal. The apparatus further includes an auxiliary pump having an auxiliary pump discharge at an upper end thereof and an auxiliary pump intake at a lower end thereof. The auxiliary pump is connected to the motor. The system is lowered into the well so that it is positioned below the perforations in a well which communicate a producing formation with the interior of the well. The auxiliary pump intake will receive fluid along with sediments that may be produced by the formation.

Abstract: A stick launcher and method for launching soap sticks into a gas or oil well. The stick launcher comprises a containment vessel adapted to house the soap sticks, the containment vessel comprising a contiguous wall and a top and a bottom. A turret-style separator is positioned within the containment vessel, the separator comprising blades, and adapted to contain the soap sticks between the blades of the turret-styled separator and the contiguous wall of the containment vessel. A ball valve is positioned adjacent the bottom of the containment vessel, the ball valve, when in open position, adapted to be in fluid communication with a well bore and the containment vessel. A rotating assembly, when set in motion by an actuator, is used to rotate the separator and simultaneously open or close the ball valve.

Abstract: Compositions and methods for the inhibition of salt formation in oil and gas wells are disclosed. In particular, nitrilotriacetamide and its salts are effective at treating existing salt formations, and in inhibiting formation of new deposits.

Abstract: A well treatment tool is installed along the sucker rod string of a well, within the surrounding production tube string. The tool provides for the distribution of a treatment fluid (solvent, etc.) within the fluid being pumped or flowing from the well. The tool receives treatment fluid through the hollow sucker rod string, and distributes the fluid through a valve which is set at a predetermined pressure. When the treatment fluid pumped down the sucker rod string from the surface exceeds the predetermined opening pressure of the valve, the treatment fluid is distributed into the production tube string through one or more passages in the tool. The present tool may be used simultaneously with well production, with fluid (oil, etc.) rising up the production tube string, carrying the treatment fluid therewith. The treatment fluid is thus distributed throughout the local fluid processing system, including pipelines from the well, any initial treatment operations, and any storage tanks.

Abstract: A tubing string assembly is disclosed for fluid treatment of a wellbore. The tubing string can be used for staged wellbore fluid treatment where a selected segment of the wellbore is treated, while other segments are sealed off. The tubing string can also be used where a ported tubing string is required to be run in in a pressure tight condition and later is needed to be in an open-port condition.

Abstract: A microemulsion comprising (i) an oil phase, (ii) an aqueous phase comprising an aqueous solution of a water soluble oil field or gas field production chemical or an aqueous dispersion of a water dispersible oil field or gas field production chemical and (iii) at least one surfactant, wherein the aqueous phase is distributed in the oil phase in the form of droplets having a diameter in the range 1 to 1000 mn or in the form of microdominans having at least one dimension of length, breath or thickness in the range 1 to 1000 nm.

Abstract: An apparatus and method for progressively treating an interval of a wellbore (32) is disclosed. The apparatus comprises a sand control screen (138) that is eccentrically positioned within the wellbore (32) and a fluid delivery tubular (140) that is disposed within the wellbore (32) adjacent to the sand control screen (138). During a treatment process when a treatment fluid is pumped into the fluid delivery tubular (140), the fluid delivery tubular (140) progressively allows the treatment fluid to exit from the interior of the fluid delivery tubular (140) to the exterior of the fluid delivery tubular (140) from a first end (46) of the interval (48) to a second end (44) of the interval (48) to progressively treat the interval (48) of the wellbore (32).

Abstract: An additive for inhibiting the formation of gas hydrates in connection with hydrocarbon production and transportation comprising the water-soluble polymers comprising structural elements of the formula wherein each R is independently H or C1-C5-alkyl; X is H, an alkaline or earth alkaline metal or a quaternary ammonium group; R1 is H or C1-C18-alkyl; and R2 is C1-C18-alkyl; and wherein the alkyl groups represented by R1 and R2 optionally carry a hydroxy or amino substituent; and, optionally, a minor proportion of structural elements of the formula  wherein R, R1, R2 and X may have the meaning as above, and Alk is a C1-C5-alkylene chain.

Abstract: An oil well capsule to reduce the paraffin and asphaltene which accumulate on the walls of the pipes which are used to bring the oil up from underground deposits, and a method of using said oil well capsule. An oil well capsule having a shell encapsulating a chemically active mass wherein said chemically active mass consists essentially of alkaline or alkaline earth metal.

Abstract: A multi-gradient system for drilling a well bore from a surface location into a seabed includes an injector for injecting buoyant substantially incompressible articles into a column of drilling fluid associated with the well bore. Preferably, the substantially incompressible articles comprises hollow substantially spherical bodies.

Abstract: The present invention presents an improved method and apparatus for liquid entrainment by a two-phase flow system. The present invention provides an apparatus that recovers liquids by entrainment without experiencing deadhead conditions, choking or dry recovery due to fluctuations in the elevation of the liquid level. The apparatus provides self-regulated two-phase recovery of gas and liquid by construction design, thus eliminating the need for manual adjustments or electronically controlled devices. The enhanced venturi effects of the present invention enhance liquid lift while maintaining the gas recovery point above the liquid at all times to eliminate deadhead conditions.

Abstract: A well treatment tool is installed along the sucker rod string of a well, within the surrounding production tube string. The tool provides for the distribution of a treatment fluid (solvent, etc.) within the fluid being pumped or flowing from the well. The tool receives treatment fluid through the hollow sucker rod string, and distributes the fluid through a valve which is set at a predetermined pressure. When the treatment fluid pumped down the sucker rod string from the surface exceeds the predetermined opening pressure of the valve, the treatment fluid is distributed into the production tube string through one or more passages in the tool. The present tool may be used simultaneously with well production, with fluid (oil, etc.) rising up the production tube string, carrying the treatment fluid therewith. The treatment fluid is thus distributed throughout the local fluid processing system, including pipelines from the well, any initial treatment operations, and any storage tanks.

Abstract: A process for recovery of hydrocarbons in a production fluid from an underground reservoir of said hydrocarbons, the process comprising of: (a) injecting a viscosity reducing solvent of a fraction of said hydrocarbons into said reservoir at a pressure in the reservoir of above a liquid/vapor phase change pressure of a fraction of said solvent; said pressure in said reservoir also being sufficient to cause geomechanical formation dilation or pore fluid compression, and then, (b) allowing said solvent to mix with said hydrocarbons under pore dilation conditions, and then, (c) reducing the pressure in said reservoir to below said liquid/vapor phase change pressure of at least said fraction of said solvent thereby evincing solvent gas drive of said fraction of said hydrocarbons from said reservoir; and then, (d) repeating steps (a) to (c) as required.

Abstract: A stick launcher and method for launching soap sticks into a gas or oil well. The stick launcher comprises a containment vessel adapted to house the soap sticks, the containment vessel comprising a contiguous wall and a top and a bottom. A turret-style separator is positioned within the containment vessel, the separator comprising blades, and adapted to contain the soap sticks between the blades of the turret-styled separator and the contiguous wall of the containment vessel. A ball valve is positioned adjacent the bottom of the containment vessel, the ball valve, when in open position, adapted to be in fluid communication with a well bore and the containment vessel. A rotating assembly, when set in motion by an actuator, is used to rotate the separator and simultaneously open or close the ball valve.

Abstract: An automatic chemical stick loader apparatus for gas wells, including a storage and dispensing cabinet at ground level, for sequentially feeding sticks therefrom, a launch tube for sequentially receiving sticks and elevating them to the top of a well head, and a stick loader atop the well for receiving a stick from the launch tube, dropping the stick into a chamber, pressure isolating the chamber and pressure equalizing it with well pressure, and dropping the stick into the well. The apparatus is controlled by an electronic controller which may be solar powered. The apparatus is operated by well gas, the pressure thereof being regulated down to 20 psi or so.

Abstract: Pumpable multiple phase compositions for carrying agents and components downhole and controllably releasing them by breaking the suspensions are described. The multiple phase composition may have an external or third phase, which in turn has a first pumpable emulsion internally. The first pumpable emulsion has a second phase containing a first phase which bears the agent to be controllably released. The entire pumpable multiple phase composition may thus be an oil phase-in-aqueous phase-in-oil phase emulsion, or an aqueous phase-in-oil phase-in-aqueous phase emulsion. The agent may be released by one or more of a variety of mechanisms. For example, a water-soluble shale stabilizer could be delivered downhole in an aqueous phase-in-oil phase-in-aqueous phase multiple phase emulsion by injecting the multiple phase composition into a water-based drilling fluid, and then the suspension broken by rotary bit nozzles under high shear stress to release the shale stabilizer at the drilling zone.

Abstract: An automatic chemical stick loader apparatus for gas wells, including a storage and dispensing cabinet at ground level, for sequentially feeding sticks therefrom, a launch tube for sequentially receiving sticks and elevating them to the top of a well head, and a stick loader atop the well for receiving a stick from the launch tube, dropping the stick into a chamber, pressure isolating the chamber and pressure equalizing it with well pressure, and dropping the stick into the well. The apparatus is controlled by an electronic controller which may be solar powered. The apparatus is operated by well gas, the pressure thereof being regulated down to 20 psi or so.

Abstract: A method for delivering encapsulated materials to a subsurface environment, for the treatment of the subsurface environment, has the steps of: (a) loading the lumen of hollow microtubules with an active agent selected for treating the subsurface environment, where the hollow microtubules are compatible with the subsurface environment; and (b) administering the hollow microtubules to the subsurface environment, permitting the controlled release of the active agent into the subsurface environment. This method may be practiced using a slurry of hollow microtubules, where the lumen of these microtubules is loaded with an agent for the treatment of petroleum well environments, and where these loaded microtubules are dispersed in a liquid phase carrier selected from aqueous carriers, non-aqueous carriers, and emulsions of aqueous and non-aqueous materials. This method may also be practiced using a pill made of a consolidated mass of tubules loaded with one or more active agents, typically bound with a binder.

Abstract: A method for remediating aquifers and groundwater contaminated, for example, by toxic halogenated organic compounds, certain inorganic compounds, and oxidized heavy metals and radionuclides, using the introduction of an innocuous oil, preferably an edible, food grade oil such as soybean oil, formulated into a microemulsion preferably by mixing with a natural food-grade emulsifier (such as lecithin) and water.

Abstract: The present invention provides compositions of oil-soluble inhibitors suitable for use in inhibiting oil field scale formation. The compositions comprise an acid form of a known scale inhibitor and a tertiary alkyl primary amine. These compositions possess advantages over conventional compositions used for inhibiting oil field scale.

Abstract: An additive for inhibiting the formation of gas hydrates in connection with hydrocarbon production and transportation comprising the water-soluble polymers comprising structural elements of the formula wherein each R is independently H or C1-C5-alkyl; X is H, an alkaline or earth alkaline metal or a quaternary ammonium group; R1 is H or C1-C18-alkyl; and R2 is C1-C18-alkyl; and wherein the alkyl groups represented by R1 and R2 optionally carry a hydroxy or amino substituent; and, optionally, a minor proportion of structural elements of the formula wherein R, R1, R2 and X may have the meaning as above, and Alk is a C1-C5-alkylene chain.

Abstract: A process and system which integrates on-site heavy oil or bitumen upgrading and energy recovery for steam production with steam-assisted gravity drainage (SAGD) production of the heavy oil or bitumen. The heavy oil or bitumen produced by SAGD is flashed to remove the gas oil fraction, and the residue is solvent deasphalted to obtain deasphalted oil, which is mixed with the gas oil fraction to form a pumpable synthetic crude. The synthetic crude has an improvement of 4-5 degrees of API and lower in sulfur, nitrogen and metal compounds. The synthetic crude is not only more valuable than the heavy oil or bitumen, but also has substantial economic advantage of reducing the diluent requirement since it has lower viscosity than the heavy oil or bitumen. The asphaltenes, following an optional pelletizing and/or slurrying step, are used as a fuel for combustion in boilers near the steam injection wells for injection into the heavy oil or bitumen reservoir.

Abstract: An apparatus for injecting a treatment chemical into an oil well produced using a subsurface pump, preferably a subsurface rotary pump, is described. Crude oil is pumped upward from a subsurface oil production zone through a central production pipe in the well. A small portion of produced fluid is diverted through a by-pass line interconnecting the production pipe and the annular space of the well between the production pipe and the well casing. A venturi nozzle comprising a throat of reduced diameter is mounted in the by-pass pipe. A suction pipe interconnects a chemical storage container containing a treatment chemical with the nozzle throat. Under the action of the venturi nozzle a suction pressure is created in the nozzle throat whereby the treatment chemical is drawn through the suction pipe and mixes with the fluid in the by-pass line thereby delivering the chemical to the well annulus.

Abstract: A subterranean formation is treated by injecting a blend of fracture proppant material and deformable particulate material into the formation. The deformable particulate material may combine with the fracture proppant material to increase fracture conductivity, reduce fines generation, and/or reduce proppant flowback. The fracture proppant material may be a material such as sand, and the deformable particulate material may be a material such as polystyrene divinylbenzene beads.

Abstract: Characterization of organic contaminants in subsurface formation is performed by methods for detecting the presence of nonaqueous phase liquid in a subsurface formation, and for determining the composition and for determining the volume of nonaqueous phase liquids. Generally the methods comprise introducing one or more partitioning tracers and one or more non-partitioning tracers at one or more injection points located in the subsurface formation and measuring separation between the one or more partitioning tracers and the one or more non-partitioning tracers from one or more sampling points located in the subsurface formation to determine presence, composition and/or volume of nonaqueous phase liquid in the subsurface formation. In addition, the methods can be used to assess the performance of an attempted remediation.

Abstract: A chemical additive element or “soap stick” dispensing apparatus, particularly adapted for use in dispensing soap sticks into gas wells, includes an elongated tubular soap stick magazine member and a manual and gravity actuated flapper type check valve operable to hold a soap stick in the magazine member but operable in response to pressure equalization across the valve to open under the weight of the soap stick to dispense the soap stick into a wellbore. A bypass conduit is connected across the check valve and the magazine member and includes a remotely controllable or timer controlled motor operated valve operable to conduct wellbore pressure gas to a magazine chamber to equalize pressure across the check valve so as to allow the soap stick to be dispensed into the wellbore.

Abstract: The invention is the method of treating of a well, a formation, or both, with the solids, liquids, or apparatuses, by 1) encasing the solids, liquids, or apparatuses in a water-soluble shell, 2) conveying the encased solids, liquids, or gases to the predetermined location in the well, and then 3) allowing the water-soluble shell to dissolve in the aqueous phase in the wellbore. The shell is preferably made of water-soluble polymers such as collagen, a crosslinking agent such as zolidine, optionally a hydrophobic compound such as a processed oil, and water used in processing. Other modifying or conditioning compounds, for example glycerin and other polymeric additives, may be incorporated to extend the strength or temperature range of the shell. The shell encases a variety of solids, liquids, or combinations thereof, where the solids or liquids are useful in the treatment of the well or of the producing formation.

Abstract: A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of N-acyldehydroalanine derivatives which are esters or amides of N-acyldehydroalanine.

Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well and pipeline fluids and slowly release treatment ingredients over time, depending on the downhole and pipeline conditions. The composites include a nonylphenol ethoxylate having at least about 50 moles of ethylene oxide per mole of nonylphenol and a fatty acid amide having from 14-20 carbon atoms. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof. In one embodiment, the composites are spherical in shape and are passed through pipelines for maintenance and treatment of the pipelines.

Abstract: The present invention provides a method of treating a subterranean formation with a particulate laden fluid whereby particulate flowback is reduced or prevented while also providing a controlled release of a treatment chemical within the formation. The method includes the steps of providing a fluid suspension including a mixture of a particulate, a tackifying compound and a treatment chemical, pumping the suspension into a subterranean formation and depositing the mixture within the formation whereby the tackifying compound retards movement of at least a portion of the particulate within the formation upon flow of fluids from the subterranean formation and said tackifying compound retards release of at least a portion.

Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well and pipeline fluids and slowly release treatment ingredients over time, depending on the downhole and pipeline conditions. The composites include a compound selected from the group consisting of nonylphenol ethoxylates having at least about 50 moles of ethylene oxide per mole of nonylphenol, fatty acid amides having from 14-20 carbon atoms, and mixtures thereof. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof.

Abstract: A composition is provided herein for preventing or retarding the formation of gas hydrates or for reducing the tendency of gas hydrates to agglomerate, during the transport of a fluid comprising water and a hydrocarbon, through a conduit. The composition is a homopolymer of vinyl caprolactam having the low molecular weight in the range of 500 to 2500, or copolymers or terpolymers thereof, and a polyoxyalkylenediamine or a polyoxyarylenediamine. Such homopolymers, copolymers and terpolymers, preferably are made and applied in the defined solvent, which, most preferably, is a glycol ether such as 2-butoxyethanol.

Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well fluids and slowly release treatment ingredients over time, depending on the downhole conditions. The composites include a nonylphenol ethoxylate having at least about 50 moles of ethylene oxide per mole of nonylphenol and a fatty acid amide having from 16-20 carbon atoms. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof.

Abstract: An aqueous composition containing an amine oxide surfactant, and preferably containing an amine oxide surfactant and enzymes, is added to crude oil, preferably by injecting the composition into the oil well, or adding the composition to pipelines or tankage containing the oil. An acid can also be used in conjunction with the composition. The composition acts to remove hydrocarbon contamination, from the well bore and mechanical components and further serves to break up the oil/water/sludge emulsion being delivered from the well head to facilitate separation of the oil. When used with an acid, the composition increases the effectiveness of the acid in removing inorganic contamination.

Abstract: A process for slowing the growth and/or agglomeration of hydrates in a fluid comprising water and gases by adding at least one essentially water-soluble polyoxyalkylene glycol macromer or at least one essentially water-soluble polymer containing a single macromer or a plurality of different macromer units of polyoxyalkylene glycol or a mixture of essentially water-soluble macromers and/or polymacromers. It is also possible to both retard the formation of hydrates and to substantially slow their growth and limit their agglomeration during crystallization by combining polyoxyalkylene glycol macromer type structures with kinetic additive type structures which are known to inhibit hydrate formation.

Abstract: The present invention provides improved methods of drying pipelines containing water which are to transport hydrate forming gaseous fluids. The methods basically comprise flowing a liquid which forms an azeotrope mixture with water into contact with water in a pipeline, the amount of the azeotropic liquid being sufficient to form an azeotrope mixture with the water whereby as the mixture is evaporated in the pipeline, the water concentration in the remaining mixture does not reach that concentration which will form hydrates with the hydrate forming gaseous fluid.

Abstract: A method of inhibiting or retarding formation of hydrates from water and a lower alkane, such as methane or ethane, involves adding additives which comprise (i) a corrosion inhibitor and (ii) a salt which is of formula [R.sup.1 (R.sup.2)XR.sup.3 ].sup.+ Y.sup.-, wherein each of R.sup.1, R.sup.2 and R.sup.3 is bonded directly to X, each of R.sup.1 and R.sup.2, which may be the same or different is an alkyl group of at least 4 carbons, X is S, NR.sup.4 or PR.sup.4, wherein each of R.sup.3 and R.sup.4 which may be the same or different represents hydrogen or an organic group, with the proviso that at least one of R.sup.3 and R.sup.4 is an organic group of at least 4 carbons, and Y is an anion, the additives being added in an amount effective to inhibit or retard hydrate formation, to a medium susceptible to hydrate formation.