Entraining Or Incorporating Treating Material In Flowing Earth Fluid Patents (Class 166/310)
  • Patent number: 6059034
    Abstract: A subterranean formation is treated by injecting a blend of fracture proppant material and deformable particulate material into the formation. The deformable particulate material may combine with the fracture proppant material to increase fracture conductivity, reduce fines generation, and/or reduce proppant flowback. The fracture proppant material may be a material such as sand, and the deformable particulate material may be a material such as polystyrene divinylbenzene beads.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: May 9, 2000
    Assignee: BJ Services Company
    Inventors: Allan R. Rickards, Harold D. Brannon, Philip J. Rae, Gino A. DiLullo, Christopher J. Stephenson
  • Patent number: 6056058
    Abstract: An apparatus, and related methods, for automatically releasing sticks of various materials into oil and gas wells. The apparatus has an enclosed magazine which has several chambers for the sticks. The magazine rotates on a shaft when a sprocket on the shaft is engaged by a rod moving from an extended to a retracted position. The rod movement is actuated by a double acting cylinder which is powered by well gas. When rotated the magazine positions the next chamber above a bottom exit port which is aligned with the well, causing the stick to be released into the well. During the stick loading process, only a single valve need be opened to enable the sticks to be loaded into the stick chambers. The magazine is rotated by hand after each stick is loaded.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: May 2, 2000
    Inventor: Leonel Gonzalez
  • Patent number: 6035933
    Abstract: A process for the thermo-hydraulic control of gas hydrates in subsea production and injection wells as well as pipelines which transport liquid or gaseous hydrocarbons is described, the process making use of a Nitrogen Generating System foamed or in solution. The control may signify the prevention of the formation of the gas hydrates or the dissolution of the gas hydrate plug already formed. Under conditions of use designed for the prevention of the formation of gas hydrates the SGN fluid prevents the thermal conditions leading to the gas hydrate plugs. Under conditions of use designed to dissolve the already formed gas hydrate plugs, the SGN fluid alters the thermo-hydraulic conditions which favor the gas hydrate plugs, so that they are dissolved and return to the water+gas phase.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: March 14, 2000
    Assignee: Petroleo Brasileiro S.A.-Petrobras
    Inventors: Carlos Nagib Khalil, Nelson De Oliveira Rocha, Lucia Cristina Ferreira Leite
  • Patent number: 6028233
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is claimed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble polymers having N-vinyl amide or N-allyl amide units. Specific examples of such copolymers include, N-vinyl-N-methylacetamide (VIMA) copolymerized with acryloylpyrrolidine (APYD) or acryloylpiperidine (APID), and more preferably, VIMA copolymerized with N-substituted methacrylamides, such as N-isopropylmethacrylamide (iPMAM) and methacryloylpyrrolidine (MAPYD) to produce inhibitors for practicing the claimed method.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: February 22, 2000
    Assignee: Exxon Production Research Company
    Inventors: Karla Schall Colle, Christine Ann Costello, Enock Berluche, Russell Harlan Oelfke, Larry Dalton Talley
  • Patent number: 6028234
    Abstract: The present invention provides a process for continuously producing clathrate hydrate. This process includes comprising the steps of:(a) pressurizing a hydrate-forming gas to an elevated pressure and cooling the hydrate-forming gas below the gas-water-hydrate equilibrium point at the elevated pressure;(b) cooling liquid water below the gas-water-hydrate equilibrium temperature for the elevated pressure;(c) charging hydrate-forming gas at the elevated pressure into a reaction zone which contains a movable surface;(d) atomizing water in the reaction zone in contact with the hydrate-forming gas to form gas hydrates in the reaction;(e) depositing the gas hydrates on the movable surface; and(f) collecting the gas hydrates from the movable surface.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: February 22, 2000
    Assignee: Mobil Oil Corporation
    Inventors: Robert Frederick Heinemann, David Da-Teh Huang, Jinping Long, Roland Bernard Saeger
  • Patent number: 6021847
    Abstract: The invention relates to a method of reducing an amount of a waste component present in a hydrocarbon fluid produced from an earth formation via a wellbore formed in the earth formation, the hydrocarbon fluid flowing in a stream of fluid through the wellbore. The method includes the steps of: a) inducing at least part of the amount of the waste component to move into a second fluid present in the stream of fluid as the stream flows through the wellbore; and b) separating the second fluid with the at least part of the amount of the waste component included therein, from the hydrocarbon fluid.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: February 8, 2000
    Assignee: Shell Oil Company
    Inventors: Phaidon Daskopoulos, Alexander Michiel Mollinger, Paul Dirk Schilte, Robert Gerard Smeenk, Paulus Henricus Joannes Verbeek, Marinus Hendricus Wilhelmus Verbruggen
  • Patent number: 6019903
    Abstract: A corrosive acid sulfate geothermal brine is mixed with a near neutral, bicarbonate geothermal brine containing above about 300 ppm silica to produce a relatively benign mixed brine of pH from about 4.5 to about 6.5 having reduced corrosivity as compared to the acid sulfate brine and a reduced tendency as compared to the near neutral, bicarbonate brine for depositing silica in equipment during brine processing.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: February 1, 2000
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 5965031
    Abstract: Sulfurous acid and/or sulfurous acid precursors, such as sulfur dioxide, are introduced into a hydrogen sulfide-containing geothermal brine or fluid prior to extracting energy from the resulting mixture by, e.g., passing the mixture through a flash vessel or a heat exchanger. The introduction of the sulfurous acid or its precursors into the geothermal brine or fluid inhibits scale formation and/or removes previously formed scale during processing of the brine or fluid.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: October 12, 1999
    Assignee: Union Oil Company of California
    Inventors: Kevin R. Kitz, Darrell L. Gallup
  • Patent number: 5960878
    Abstract: The present invention provides methods of protecting ferrous metal well tubular goods and the like disposed in a well bore penetrating a subterranean formation from corrosion. The method basically includes the steps of introducing a liquid or solution of a tackifying compound having ferrous metal corrosion inhibition properties into the well bore whereby the tackifying compound is coated onto the tubular goods thereby providing extended corrosion protection to the tubular goods. Thereafter, formation fluids are produced from the subterranean formation.
    Type: Grant
    Filed: February 10, 1998
    Date of Patent: October 5, 1999
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, James R. Stanford, Jimmie D. Weaver
  • Patent number: 5924490
    Abstract: A well treatment tool is installed along the sucker rod string of a well, within the surrounding production tube string. The tool provides for the distribution of a treatment fluid (solvent, etc.) within the fluid being pumped or flowing from the well. The tool receives treatment fluid through the hollow sucker rod string, and distributes the fluid through a valve which is set at a predetermined pressure. When the treatment fluid pumped down the sucker rod string from the surface exceeds the predetermined opening pressure of the valve, the treatment fluid is distributed into the production tube string through one or more passages in the tool. The present tool may be used simultaneously with well production, with fluid (oil, etc.) rising up the production tube string, carrying the treatment fluid therewith. The treatment fluid is thus distributed throughout the local fluid processing system, including pipelines from the well, any initial treatment operations, and any storage tanks.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: July 20, 1999
    Inventor: Roger K. Stone
  • Patent number: 5900516
    Abstract: A method for inhibiting the formation and/or agglomeration of clathrate hydrates in a petroleum fluid stream containing water is disclosed. The disclosed method uses predetermined inhibitors having a guest group, a polymer backbone, and an anchor group positioned between the guest group and the polymer backbone. The inhibitor predetermination method comprises selection of the polymer backbone, anchor group and guest group using several types of criteria. The polymer backbone should produce a substantially water soluble polymer in combination with the anchor group and the guest group. The anchor group should be a hydrophilic moiety with between one and four hydrogen bonding atoms. The guest group should be either a hydrophobic or amphiphilic moiety with a carbon atom to heteroatom ratio greater than or equal to about two to one and an average van der Waals diameter between about 3.8 angstroms and about 8.6 angstroms.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: May 4, 1999
    Assignee: Exxon Production Research Company
    Inventors: Larry Dalton Talley, Russell Harlan Oelfke
  • Patent number: 5893416
    Abstract: Corrosion, scale-formation, or other deleterious processes are inhibited in an oil well by installing within the oil well (10) fluid-permeable elements, such as tubular filters (20), which comprises a suppressing material. Each filter (20) comprises two tubular filter screens (24) between which is a bed (26) of particles comprising suitable inhibitor material. The particles might for example be porous ceramic spheres impregnated with the inhibitor material. The inhibitor material gradually dissolves in the well fluids during operation, and may for example inhibit corrosion and/or scale formation.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: April 13, 1999
    Assignee: AEA Technology plc
    Inventor: Peter Arne Read
  • Patent number: 5891262
    Abstract: An on-line, thermo-chemical process for the dewaxing of oil export pipelines with the aid of a Nitrogen Generating System is described, wherein the treating fluid to be employed as dewaxing fluid comprises: a) a solution of nitrogen salts activated by emulsified acetic acid and designed to yield nitrogen and heat, and b) a solvent, which is the petroleum oil being produced. The dewaxing treatment is effected at the same time as the petroleum oil is produced, this leading to great savings in costs and energy.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: April 6, 1999
    Assignee: Petroleo Brasileiro S.A.-Petrobras
    Inventors: Carlos Nagib Khalil, Lucia Cristina Ferreira Leite, Nelson De Oliveira Rocha
  • Patent number: 5880319
    Abstract: Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Additional additives include alkoxy compounds, and particularly those comprising ethoxy and or propoxy polymer blocks. Further additives include alcohols and oxazoline polymers which are preferably used in combination with polymers having lactam rings. Additives are useful in controlling clathrate hydrates in highly saline aqueous liquids.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: March 9, 1999
    Assignee: Colorado School of Mines
    Inventor: Earle Dendy Sloan, Jr.
  • Patent number: 5874660
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitor used for practicing the method is selected from the family of substantially water soluble copolymers formed from N-methyl-N-vinylacetamide (VIMA) and one of three comonomers, vinylpyrrolidone (VP), vinylpiperidone (VPip), or vinylcaprolactam (VCap). VIMA/VCap is the preferred copolymer. These copolymers may be used alone or in combination with each other or other hydrate inhibitors. Preferably, a solvent, such as water, brine, alcohol, or mixtures thereof, is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: February 23, 1999
    Assignee: Exxon Production Research Company
    Inventors: Karla Schall Colle, Russell Harlan Oelfke, Malcolm A. Kelland
  • Patent number: 5858245
    Abstract: A method for controlling fouling of a production or reinjection well, a flashing vessel or a heat-exchange surface exposed to a high-enthalpy geothermal brine that forms metal/silicon-containing scale comprises the addition of a metal complexing agent to the brine to form a fluid mixture containing a soluble metal/silicon component complex that inhibits the amount of scale formation when the temperature of the fluid mixture is reduced. The addition of a preferred metal complexing agent such as forms of EDTA, citric acid or acetic acid maintains dissolved aluminum species in the brine and inhibits the formation of aluminum silicate precipitate.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: January 12, 1999
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 5853048
    Abstract: The present invention provides a method of treating a wellbore penetrating a subterranean formation with a treatment fluid whereby fine particulate flowback is reduced or prevented. The method includes the steps of providing a fluid suspension including a mixture of a particulate coated with a tackifying compound, pumping the suspension into a subterranean formation and depositing the mixture within the formation whereby the tackifying compound retards movement of at least a portion of any fine particulate within the formation upon flow of fluids from the subterranean formation through the wellbore. Alternatively, the tackifying compound may be introduced into a subterranean formation in a diluent containing solution to deposit upon previously introduced particulates to retard movement of such particulates and any fines subject to flow with production of fluids from the subterranean formation.
    Type: Grant
    Filed: April 21, 1998
    Date of Patent: December 29, 1998
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jim D. Weaver, James R. Stanford, Philip D. Nguyen, Bobby K. Bowles, Steven F. Wilson, Brahmadeo Dewprashad, Mark A. Parker
  • Patent number: 5848644
    Abstract: The invention concerns a process for reducing the tendency of hydrates in a fluid comprising at least water, a gas and a paraffin oil to agglomerate, by addition of a mixture of at least two organosoluble additives, namely at least one polyisobutene-polyethyleneglycol block copolymer and at least one copolymer of an alkyl (meth)acrylate and a nitrogen-containing monomer. These organosoluble copolymers are generally introduced at an overall concentration of 0.05% to 5% by weight with respect to the water present in the medium.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: December 15, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Marie Velly, Anne-Sophie Delion, Jean-Pierre Durand
  • Patent number: 5837145
    Abstract: A method for treating cyanide contaminated water is disclosed. This method generally involves passing the contaminated water through a bed containing elemental iron, to form a precipitate by a reaction between the iron and any of various cyanide species which exist in the water. The method can be applied either above ground or in situ in the subsurface environment.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: November 17, 1998
    Assignee: Aluminum Company of America
    Inventors: David A. Dzombak, Rajat S. Ghosh, Richard G. Luthy
  • Patent number: 5817898
    Abstract: A process is described for retarding or inhibiting the growth and/or aggregation of hydrates in production effluents comprising water and a gas under thermodynamic conditions in which hydrates can form, characterized in that a low concentration (0.05% to 5% by weight with respect to the water) of water-soluble copolymer containing hydrophobic groups is incorporated into the effluent.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: October 6, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Anne Sophie Delion, Jean Pierre Durand, Patrick Gateau, Marie Velly
  • Patent number: 5813455
    Abstract: An apparatus and method for automatically dispensing chemical sticks into a well bore is provided. In the preferred form, the apparatus is for dispensing soap sticks to unload an oil/gas producing well of fluid, e.g., salt water, built-up therein. The apparatus is a tubular receptacle with an upper storage section and a lower receiving chamber with sticks stacked end-to-end in the storage section and fed, as by gravity feed, to the receiving chamber after a stick is dispensed therefrom. An operating mechanism controls dispensing so that a stick is dispensed based on a predetermined timing sequence or when a predetermined well condition is reached. A preferred soap stick for use in the apparatus includes a water-soluble, flexible, resilient sheath encasing the stick body tightly therein.
    Type: Grant
    Filed: March 11, 1997
    Date of Patent: September 29, 1998
    Assignee: Amoco Coporation
    Inventors: Gary V. Pratt, Ronald F. Sloan
  • Patent number: 5789635
    Abstract: The invention concerns a process for inhibiting or retarding hydrate formation, growth and/or agglomeration in a fluid comprising water and gases, by addition of a hydrosoluble copolymer which does not contain a heterocycle but contains at least one sulphonate group.The copolymer is generally introduced at a concentration of 0.05% to 5% by weight with respect to the quantity of water in the medium.The copolymer can also be mixed with an alcohol (monoalcohol or polyol). In this case, the proportions are generally 0.5% to 20% by weight of alcohol with respect to the water content, for 0.05% to 3% by weight of copolymer with respect to the quantity of water content of the medium.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: August 4, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Durand, Anne Sinquin, Marie Velly
  • Patent number: 5783524
    Abstract: Glycine-N,N-diacetic acid derivatives and their alkali metal, akaline earth metal, ammonium and substituted ammonium salts, used as completing agents for alkaline earth metal and heavy metal ions in the production and transport of petroleum and natural gas.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: July 21, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Greindl, Wilhelmus Slotman
  • Patent number: 5758725
    Abstract: A method and device for increasing oil and gas recovery include connecting an oil and gas flow enhancing stick to a weighted plunger to speed the decent of the stick to the bottom of a well, which optionally includes a retrieving member to retrieve the plunger from the well.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: June 2, 1998
    Inventor: Foy Streetman
  • Patent number: 5755972
    Abstract: A method for inhibiting barium sulfate precipitation in low pH aqueous fluids of underground petroleum-bearing formations by adding to such systems an effective amount of low molecular weight water-soluble polymer containing 5-35 weight percent sulfonic acid monomer units and 65-95 weight percent carboxylic acid monomer units, is provided. Polymer compositions based on 10-15 weight percent 2-acrylamido-2-methyl-1-propanesulfonic acid, 15-65 weight percent acrylic acid and 25-70 weight percent maleic acid are particularly preferred for use at very low pH conditions, e.g., 5.5 or less in the presence of high sulfate ion and barium ion concentrations.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: May 26, 1998
    Assignee: Rohm and Haas Company
    Inventors: William Mathis Hann, Susan Tabb Robertson, Barry Weinstein
  • Patent number: 5744709
    Abstract: This invention relates generally to methods of measuring interfacial areas, and more specifically to flow-based methods for measuring the area of the interfaces between two immiscible fluids. The immiscible fluids of interest are various oils and gases that do not have significant solubility, and thus form a distinct fluid phase and exist as agglomerations of varying sizes of blobs or ganglia when added to aqueous solutions. Our invention permits the measurement of such fluid-fluid interface areas for two immiscible fluids present in flow systems. The flow-based method involves the introduction of an interfacial tracer chemical into the flow system in one of two modes: (1) step input, and (2) pulse input. The tracer is soluble to appreciable extent in only one of the two fluids, designated as the carrier fluid phase.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: April 28, 1998
    Assignee: University of Florida
    Inventors: Kanaka Prasad Saripalli, P. S. C. Rao, Michael D. Annable, Kirk Hatfield
  • Patent number: 5655601
    Abstract: A method for inhibiting scale formation in an oil or gas well is provided. Specifically, the method is a novel "squeeze" application. The squeeze comprises injecting three solutions into the oil or gas well: (1) the preflush solution, (2) the pill solution, and (3) the overflush solution. After the injection of the three solutions, the well is shut-in for about 24 to about 48 hours. The squeeze application is useful regardless of whether the mechanism for inhibitor fixation is adsorption or precipitation.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: August 12, 1997
    Assignee: Gas Research Institute
    Inventors: John E. Oddo, Amy T. Kan, Shiliang He, Anthony J. Gerbino, Mason Tomson
  • Patent number: 5656172
    Abstract: Sulfur-containing acid is produced at a geothermal energy source from hydrogen sulfide produced as part of a geothermal process and introduced into aqueous liquid brine to lower the pH of the liquid brine. The lowered pH of the brine inhibits silica, metal sulfide and/or calcite formation on the surfaces of geothermal energy processing equipment or in subterranean formations in which the brine is injected.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: August 12, 1997
    Assignee: Union Oil Company of California
    Inventors: Kevin R. Kitz, Darrell L. Gallup
  • Patent number: 5653288
    Abstract: Methods and apparatuses for removing contaminants. At least one injection well is drilled through the vadose zone to a depth below the water table defining the upper boundary of the aquifer. A plurality of venting wells or venting laterals are established to a depth above the water table sufficient to discourage fouling by contaminated water or condensate, and oxygenated substances are injected under pressure through the injection wells. Additional biochemical cleansing may occur at ground level prior to venting of contaminated air. Microbes natural to the contaminated site may be extracted, analyzed, fermented, and reintroduced to enhance biodegradation, and nutrients, food, or both, may be supplied to the microbial population to sustain high levels of degradation activity. Relatively pure liquid contaminant may be separated from other fluids, such as water.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: August 5, 1997
    Inventors: Jeffery F. Billings, Gale K. Billings
  • Patent number: 5639925
    Abstract: Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: June 17, 1997
    Assignee: Colorado School of Mines
    Inventors: Earle Dendy Sloan, Jr., Richard Lee Christiansen, Joseph P. Lederhos, Jin Ping Long, Vaithilingam Panchalingam, Yahe Du, Amadeu Kun Wan Sum
  • Patent number: 5622920
    Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: April 22, 1997
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
  • Patent number: 5600044
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a N-substituted acrylamide having two nitrogen substituent groups, R.sub.1 and R.sub.2, where R.sub.1 is a hydrocarbon group having from one to ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof, and R.sub.2 is a hydrogen atom or a hydrocarbon group having from one to ten carbon atoms selected from the group consisting of carbon, nitrogen, oxygen, and sulfur; alternatively, R.sub.1 and R.sub.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: February 4, 1997
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Christine A. Costello, Russell H. Oelfke, Larry D. Talley, John M. Longo, Enoch Berluche
  • Patent number: 5590716
    Abstract: A method of inhibiting corrosion on metal surfaces and downhole equipment and above surface separation equipment from a mixture of brine and crude oil extracted from underground formations. The method comprises the injection on a periodic basis of an effective amount of an oxime compound having the formula: ##STR1## in which R.sub.1 and R.sub.2 are the same or different and are selected from hydrogen, lower alkyl groups of one to eight carbons or aryl groups. In addition to functioning as a corrosion inhibitor for the metal surfaces in contact with the mixture, the oxime compound is less susceptible to neutralization by contact with acidic species, and is less likely to emulsify the brine and crude oil mixture brought to the surface.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: January 7, 1997
    Assignee: Drew Chemical Corporation
    Inventor: William D. Mansfield
  • Patent number: 5583273
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a cyclic imino ether. Such polymers may be ring closed cyclic imino ether ("CIE") polymers, ring opened CIE polymers, or combinations thereof. Some examples of ring opened CIE polymers include various N-acyl polyalkyleneimines produced by cationic polymerization, such as N-acyl substituted polyethyleneimine, N-acyl substituted polypropyleneimine, N-acyl substituted polybutyleneimine, N-acyl substituted polypentyleneimine and copolymers thereof.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: December 10, 1996
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Russell H. Oelfke
  • Patent number: 5544705
    Abstract: A method for injecting fluid, such as an accelerator, into a wellbore comprises storing the fluid in a reservoir, locating the reservoir downhole in the wellbore, and then transferring the fluid from the reservoir into the wellbore. More particularly, one embodiment of the method comprises storing the fluid in a reservoir in a plug, pumping the plug down casing in a wellbore, and transferring the fluid at the bottom of the wellbore via a venturi effect. Another embodiment of the method comprises storing the fluid in a reservoir integrated into the wall of a portion of casing, setting the casing in the wellbore, and then transferring the fluid via a venturi effect from the reservoir into the annulus defined between the casing and the wellbore.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: August 13, 1996
    Assignee: Atlantic Richfield Company
    Inventors: Richard R. Jones, William N. Wilson
  • Patent number: 5531895
    Abstract: The environment in a porous area, such as in an aquifer in controlled to promote the growth of indigenous microorganisms as well as introduced microorganisms. Nutrients and other growth-promoting chemicals are added to cause the organisms to grow and produce a biofilm that retards fluid movement. Tubes are inserted into the target area, and fluids containing nutrients and other chemical are circulated through the porous area, the paths of circulation defining the areas of growth of microorganisms to produce a barrier, referred to as a biowall. After the biowall has served its purpose, it can be dispersed by injecting chemicals to stop growth and/or to kill the microorganisms.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: July 2, 1996
    Inventors: George Alford, D. Roy Cullimore, Al T. Mikell
  • Patent number: 5509760
    Abstract: A remediation method for decontamination of soil and groundwater that puts maximum remediation stress on the entire area and volume of contamination. This results in site restoration in days and weeks. The target contaminants are organic compounds such as hydrocarbon constituents associated with diesel fuel, gasoline, kerosene, solvents and creosote. Cleanup concentrations to non-detectable levels can be achieved when properly implemented. Positive pressure is used to push an uncontaminated gas throughout the entire contaminated area/volume. When contacting the contaminated area, volume and media, this gas becomes a carrier gas, stripping the contaminants and carrying them to ground level where they can be collected and treated or dissipated to the atmosphere. The method incorporates air entry points (vertical, horizontal, or directional) installed to a depth below the contamination, combined with a predetermined air entry point spacing (depth/spacing ratio).
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: April 23, 1996
    Assignee: Integrated Environmental Solutions, Inc.
    Inventors: Fred E. Schriefer, Robert Bass, Stephen G. McMahon
  • Patent number: 5491269
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a cyclic imino ether. Some examples of such inhibitors include various N-acyl polyalkyleneimines, such as N-acyl substituted polyethyleneimine, N-acyl substituted polypropyleneimine, N-acyl substituted polybutyleneimine, N-acyl substituted polypentyleneimine and copolymers thereof. Also, such N-acyl substituted polyalkyleneimines can be used in various ratios with other substantially water soluble polymers and copolymers. Preferably, a solvent such as water, brine, alcohol, or mixtures thereof is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: February 13, 1996
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Russell H. Oelfke
  • Patent number: 5432292
    Abstract: Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.
    Type: Grant
    Filed: June 24, 1993
    Date of Patent: July 11, 1995
    Assignee: Colorado School of Mines
    Inventor: Earle D. Sloan, Jr.
  • Patent number: 5431222
    Abstract: A system for improving production of crude oil from an underground reservoir by the injection of treatment fluids includes a well casing, a production tube located within said well casing and defining therewith an annular space for receiving treatment fluids, a packer located within said annular space for isolating said annular space from a reservoir, a pump disposed in said production tube and having an inlet valve for receiving fluids to be pumped and a mixing shoe for mixing treatment fluids from said annular space with crude oil from said reservoir so as to form a substantially homogeneous mixture of said oil and said fluids in said production tube below said inlet valve of said pump.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: July 11, 1995
    Assignee: Corpoven, S.A.
    Inventor: Asdrubal Bustamante
  • Patent number: 5420370
    Abstract: Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: May 30, 1995
    Assignee: Colorado School of Mines
    Inventor: Earle D. Sloan, Jr.
  • Patent number: 5413718
    Abstract: Geothermal brines are extracted from the earth, flashed and the remaining liquids are injected back into the earth. Although it would be advantageous for resource maintenance to inject the same amount of liquid as extracted, addition of liquid causes massive system upsets that prevent such addition. River or other similar surface waters can now be added to the brine stream created when extracting power from a geothermal source, after adding a crystal structure modifier to the brine stream. In operations where the brine stream is returned to the earth, the weight rate of the brine injected into the earth is brought to at least 90% what it was when extracted from the ground.
    Type: Grant
    Filed: September 30, 1993
    Date of Patent: May 9, 1995
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, John L. Featherstone
  • Patent number: 5403493
    Abstract: An aqueous scale inhibitor product is corrosive to the elongated feed lines of a geothermal well due to the length of such feed lines, extended residence time of the product therein, and/or the elevated internal temperatures reached therein, and such corrosivity of aqueous scale inhibitor products is reduced when the scale inhibitor actives are no more than about 10 weight percent of the aqueous solution, when the pH of such aqueous solution is raised to the range of from about 5.5, or 8, to about 12, when carbohydrazide is added to such product, and by combinations of such factors.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: April 4, 1995
    Assignee: Nalco Chemical Company
    Inventors: Richard J. Mouche, Eugene B. Smyk
  • Patent number: 5396958
    Abstract: Improved mud additive compositions are provided which are especially formulated to control hole enlargement due to salt bed erosion during drilling, and to assist in solubilization of deposited salt during well operations. The compositions include a first ingredient such as sodium or potassium ferrocyanide and mixtures thereof, and a second ingredient such as the trisodium salt of nitrilotriacetic acid and alkali metal citrates. The first ingredient is generally present at a level of from about 50-95% by weight in the particulate, dilutable form of the invention, whereas the second ingredient is present at a level of from about 5-50% by weight. The compositions hereof may be added to drilling mud during drilling operations or to fresh water for removing salt depositions.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: March 14, 1995
    Assignee: Jacam Chemical Partners, Ltd.
    Inventor: Najib H. Zaid
  • Patent number: 5388644
    Abstract: A method of reducing, preferably preventing, precipitation of asphalt from crude oil. In one aspect, crude oil is contacted in the borehole with at least one N,N-dialkylamide of a fatty acid having 8 to 22 carbon atoms. In an second aspect, precipitation is reduced during miscible flooding in an EOR process by adding to the flooding solvent at least one N,N-dialkylamide of a fatty acid having 8 to 22 carbon atoms.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: February 14, 1995
    Assignee: Buckman Laboratories International, Inc.
    Inventor: Julian Romocki
  • Patent number: 5360065
    Abstract: A copolymer of sodium vinyl sulfonate and polyalkylene glycol mono- or di-methacrylate and a process for inhibiting scale deposition, particularly inorganic sulfate such as barium sulfate. An aqueous fluid present in or produced from a subterranean formation is contacted with an aqueous solution having the copolymer dissolved therein. The aqueous fluid has an acidic pH and the copolymer has a molecular weight of from about 2,000 to about 30,000.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: November 1, 1994
    Assignee: Marathon Oil Company
    Inventor: David O. Falk
  • Patent number: 5351756
    Abstract: A process for the treatment or processing and transportation of a natural gas from a gas well to a reception and treatment or processing terminal comprises, in a zone in the producing well, contacting the natural gas and a recycled liquid phase containing water and at least one anti-hydrate additive and/or at least one anti-corrosion additive, both of which being at least partly miscible with water and which vaporize in the pure state or as an azeotrope. The resultant additive-containing gaseous phase is cooled to form an uncondensed and a condensate. The condensate containing substantially all of the additive is separated from the uncondensed gas and is recycled to the contact zone in the producing well.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: October 4, 1994
    Assignee: Institut Francais du Petrole
    Inventors: Ari Minkkinen, Joseph Larue
  • Patent number: 5263541
    Abstract: A method for inhibiting inorganic sulfate scale growth in an aqueous fluid present within or produced from a subterranean formation is performed by contacting the aqueous fluid in situ with a scale inhibitor composition containing two homopolymers in solution within an aqueous liquid medium. The first homopolymer is a polyvinyl sulfonate and the second homopolymer is a polyacrylic acid. The weight ratio of the first homopolymer to second homopolymer is preferably at least about 1:1 and the aqueous fluid being contacted by the composition typically contains a relatively high concentration of precursor ions of inorganic sulfate scale, including scale-forming inorganic cations and scale-forming sulfate anions.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: November 23, 1993
    Inventors: Richard T. Barthorpe, Frank L. Dormish
  • Patent number: 5246074
    Abstract: An apparatus is provided for continually adding chemicals to a producing oil and gas well. A mixing chamber is provided having an inlet and an outlet. A subassembly is provided for diverting a flow of production fluid from the well and directing the flow of production fluid to the inlet of the mixing chamber. A subassembly is provided for admitting an amount of chemical into the mixing chamber. The fluid mixture of the production fluid and the chemical is exhausted from the mixing chambers through the outlet. A flow control system is provided, in fluid communication with the outlet of the mixing chamber, for permitting only a predetermined flow rate of the fluid mixture to exit from the mixing chamber. An adjustment control is provided for adjusting the flow rate of the fluid mixture through the mixing chamber to selectively increase and decrease the predetermined flow rate. An exhaust system is provided for conveying the fluid mixture from the outlet, through the flow control, and into the well.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: September 21, 1993
    Assignee: Baker Hughes Incorporated
    Inventor: Robert N. Ayres
  • Patent number: 5244878
    Abstract: A process for delaying the formation and/or reducing the agglomeration tendency of hydrates in conditions under which a hydrate may be formed, these hydrates being formed from water and gas.The process according to the invention wherein, in particular, an additive comprising at least one amphiphilic compound chosen from the group of esters of polyols and substituted or unsubstituted carboxylic acids is used.Application of the process according to the invention to processes using gases and water, which form hydrates between them, in particular in the petroleum or gas industry.
    Type: Grant
    Filed: July 10, 1991
    Date of Patent: September 14, 1993
    Assignee: Institut Francais du Petrole
    Inventors: Andre Sugier, Paul Bourgmayer, Jean-Pierre Durand