In Combination With Additional Organic Material (e.g., Alkyls, Carbon Chains) Patents (Class 166/403)
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Patent number: 11268017Abstract: Reservoir stimulation treatment diversion methods, systems, and compositions. One method includes identifying a reservoir requiring liquid stimulation treatment in a lesser-permeability portion of the reservoir. The method includes identifying a greater-permeability portion of the reservoir, the greater-permeability portion of the reservoir having a greater permeability than the lesser-permeability portion. The method also includes disposing a gas in the greater-permeability portion of the reservoir; injecting a liquid stimulation treatment into the reservoir, and allowing the gas in the greater-permeability portion of the reservoir to divert the liquid stimulation treatment into the lesser-permeability portion to stimulate fluid production from the lesser-permeability portion of the reservoir.Type: GrantFiled: March 12, 2020Date of Patent: March 8, 2022Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: Ayman Al-Nakhli, Mohamed Ahmed Nasr Eldin Mahmoud
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Patent number: 11142681Abstract: Methods to optimize solvent use in solvent-dominated processes for recovery of hydrocarbons. Methods include injecting a solvent composition into a reservoir at a pressure above a liquid/vapor phase change of the solvent composition; injecting a chaser into the reservoir at a pressure above the liquid/vapor phase change of the solvent composition; allowing the solvent composition to mix with hydrocarbons in the reservoir and at least partially dissolve into the hydrocarbons to produce a solvent/hydrocarbon mixture; reducing the pressure in the reservoir below the liquid/vapor phase change pressure of the solvent composition thereby flowing at least a fraction of the solvent/hydrocarbon mixture from the reservoir; and repeating these steps as required.Type: GrantFiled: June 8, 2018Date of Patent: October 12, 2021Assignee: ExxonMobil Upstream Research CompanyInventors: Jianlin Wang, Weidong Guo, Lu Dong, Chen Fang, Mathew D. Suitor
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Patent number: 10745281Abstract: The present disclosure relates to the field of oilfield chemistry, in particular to a composition for multi-component composite intercalation, a method of preparing a graphite system and a method of profile control and water shutoff.Type: GrantFiled: February 24, 2020Date of Patent: August 18, 2020Assignees: China University of Petroleum (East China), China University of Geosciences (Beijing), Northwest Oilfield Branch, China Petroleum & Chemical Co., Ltd.Inventors: Guang Zhao, Caili Dai, Yahui Lv, Jiawei Liu, Sen Wang, Ning Sun, Qing You, Guangjie Hu, Long He, Liang Li
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Patent number: 10648305Abstract: The present disclosure relates to the recovery of oil from an underground hydrocarbon reservoir, and more particularly to systems and methods for carbonated water flooding of an underground reservoir for enhanced oil recovery.Type: GrantFiled: June 11, 2018Date of Patent: May 12, 2020Assignee: Saudi Arabian Oil CompanyInventors: Subhash Chandrabose Ayirala, Ali Abdallah Al-Yousef, Sultan Al-Enezi, Ahmed Al-Eidan
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Patent number: 9328302Abstract: Compositions and methods for reducing the formation of hydrates within subsea or over-land pipeline systems. The compositions and methods include the use of organic salt solutions, such as an acetate salt solution, to precondition, treat, and/or dewater the pipeline systems, or employ the use of the organic salt solutions during other pre-commissioning operations. An effective concentration of an organic salt solution acts to reduce hydrates and/or inhibit hydrate formation within the pipeline systems.Type: GrantFiled: October 11, 2011Date of Patent: May 3, 2016Assignee: BAKER HUGHES INCORPORATEDInventors: Gregory E. Casey, Angel Hoover, Andrew J. Barden
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Patent number: 9150776Abstract: A hydrocarbon from a subterranean formation can be recovered by contacting the hydrocarbon with water or steam and one or more additives. The hydrocarbon can be selected from heavy or light crude oil, bitumen, an oil sand ore, a tar sand ore, and combinations thereof. The additive can be, for example, an aromatic hydrocarbon. The water or steam and the additive can be injected into the subterranean formation. Compositions or mixtures include hydrocarbons, water or steam, and additives.Type: GrantFiled: June 13, 2011Date of Patent: October 6, 2015Assignee: Nalco CompanyInventor: Kimberly Jantunen Cross
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Patent number: 8991491Abstract: The present invention relates to producing oil from an oil-bearing geological formation using a selection process. The process includes selecting a treatment option such as carbon dioxide flooding for enhancing oil recovery from a geological formation in a remote location. Various characteristic properties such as a physical or chemical property of the oil or rock may be used in the selection process and the carbon dioxide may be captured from a combustion process.Type: GrantFiled: March 11, 2011Date of Patent: March 31, 2015Assignees: Siemens Energy, Inc., Chevron U.S.A. Inc.Inventors: David Kalinowski, Steven Higgens
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Patent number: 8967283Abstract: A system and method for cracking, hydrogenating and extracting oil from underground deposits includes a gasifier, an injection well and a production well. The gasifier creates high pressure, high temperature syngas. The pressurized syngas flows through an injection well into a deposit of oil under the ground to crack and hydrogenate the oil to produce upgraded oil with a reduced density and viscosity. The production well of the system receives the reduced density and viscosity oil, transports it above the ground where it may be further separated into a portion that may be sold and a portion that can be gasified in the gasifier.Type: GrantFiled: September 19, 2011Date of Patent: March 3, 2015Assignee: Syagd Inc.Inventors: Jose J. P. Lourenco, John Gordon Murphy
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Patent number: 8869890Abstract: A method and system for processing produced fluids from a subterranean reservoir is disclosed. The system comprises: (a) a separator for separating produced fluids from a subterranean reservoir into associated gases, water and crude oil, (b) a membrane which receives at least a portion of the associated gases containing the hydrogen sulfide and separates the gas into a permeate stream enriched in hydrogen sulfide and carbon dioxide and a retentate stream depleted in hydrogen sulfide and carbon dioxide; (c) an amine unit for removing carbon dioxide and hydrogen sulfide from the retentate stream; and (d) a sour gas injection unit for injecting at the permeate stream in an underground formation.Type: GrantFiled: December 20, 2011Date of Patent: October 28, 2014Assignee: Chevron U.S.A. Inc.Inventors: Daniel Chinn, Jen Kai Chen, James Ong, Minquan Cheng, Oluwasijibomi O. Okeowo
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Patent number: 8800671Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: August 12, 2014Inventor: Donald Leo Stinson
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Patent number: 8752623Abstract: In solvent-dominated recovery processes for recovering In situ oil, including bitumen, the produced fluid stream includes oil and solvent. The solvent is preferably recovered and reinjected into the reservoir. In previously described methods, solvent is removed from the oil/solvent mixture. In the present method, the oil/solvent mixture is first separated into a heavier stream and a lighter stream from which solvent is independently removed.Type: GrantFiled: January 10, 2011Date of Patent: June 17, 2014Assignee: ExxonMobil Upstream Research CompanyInventors: Eric B. Sirota, Owen J. Hehmeyer
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Patent number: 8701788Abstract: The invention relates to methods for extracting an organics component from subsurface shale formations comprising kerogen and an extractible organics component in an inorganic matrix. Among other factors, these processes are based on the discovery that to more easily access the kerogen in oil shale, it is helpful to first remove the extractible organics component from the subsurface shale formation. The methods utilize a hydrocarbon solvent to at least partially solubilize the extractible organics component. The extractible organics component can be isolated and upgraded to produce useful products. The processes are more environmentally benign, more economical, and more efficient in producing commercial products and in providing access to kerogen.Type: GrantFiled: December 22, 2011Date of Patent: April 22, 2014Assignee: Chevron U.S.A. Inc.Inventor: Marcus O. Wigand
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Patent number: 8695718Abstract: Embodiments of the present disclosure include dispersion compositions having a nonionic surfactant for use in enhanced petroleum recovery, and methods of using the dispersion compositions in petroleum recovery processes. For the various embodiments, the nonionic surfactant of the dispersion composition promotes the formation of a dispersion from carbon dioxide and water.Type: GrantFiled: August 19, 2009Date of Patent: April 15, 2014Assignee: Dow Global Technologies LLCInventors: Aaron W. Sanders, Keith P. Johnston, Quoc Nguyen, Stephanie Adkins, Xi Chen, Ed G. Rightor
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Patent number: 8622127Abstract: Methods for improving the quality of hydrocarbon fluids produced by in situ pyrolysis or mobilization of organic-rich rock, such as oil shale, coal, or heavy oil. The methods involve reducing the content of olefins, which can lead to precipitation and sludge formation in pipelines and during storage of produced oils. The olefin content is reduced by arranging wells and controlling well pressures such that hydrocarbon fluids generated in situ are caused to pass through and contact pyrolyzed zones in which coke has been left. This contacting chemically hydrogenates a portion of the olefins in the pyrolysis oil by reducing the hydrogen content of the coke.Type: GrantFiled: June 17, 2011Date of Patent: January 7, 2014Assignee: ExxonMobil Upstream Research CompanyInventor: Robert D. Kaminsky
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Patent number: 8614578Abstract: The present disclosure relates to determining the attenuation of an electromagnetic signal passing through a conductive material. An antenna is provided and placed in relatively close proximity to the conductive material. An alternating current is passed through the antenna and the impedance of the antenna is measured. The attenuation is determined using the measured impedance. A single frequency measurement may be made, or multiple measurements using different frequencies may be made. Grouped parameters based on properties of the material and the frequency of the current are used to relate the coil impedance to the attenuation. A current frequency for which the ratio of the antenna's resistive part of the impedance to the angular frequency of the current is substantially insensitive to at least one of the parameters is preferred.Type: GrantFiled: December 18, 2009Date of Patent: December 24, 2013Assignee: Schlumberger Technology CorporationInventors: Guozhong Gao, H. Frank Morrison, Hong Zhang, Richard A. Rosthal, David Alumbaugh, Cyrille Levesque
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Patent number: 8544555Abstract: A system and method for cracking, hydrogenating and extracting oil from underground deposits is presented. A method includes injecting syngas into the oil deposit for processing the oil to produce upgraded oil with a reduced density and viscosity. A natural catalytic bed of the oil deposit is utilized to aid a rate of processing the oil into upgraded oil. The upgraded oil with reduced density and viscosity is extracted from the underground oil deposit by transporting the upgraded oil aboveground.Type: GrantFiled: September 19, 2011Date of Patent: October 1, 2013Assignee: Agosto Corporation Ltd.Inventors: Jose J. P. Lourenco, John Gordon Murphy
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Patent number: 8511384Abstract: A method for producing oil and/or gas comprising a method for producing oil from an underground formation comprising injecting an enhanced oil recovery formulation and a gas into a first well in the formation; forming a mixture comprising the enhanced oil recovery formulation and the oil in the formation; forming a gas cap with the injected gas; forcing the formulation and oil mixture towards a second well in the formation; and producing the formulation and oil mixture from the second well.Type: GrantFiled: July 18, 2008Date of Patent: August 20, 2013Assignee: Shell Oil CompanyInventor: Raul Valdez
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Patent number: 8459368Abstract: A system comprising a carbon disulfide formulation storage; a mechanism for releasing at least a portion of the carbon disulfide formulation into a formation; and a mechanism for creating a pulse in the carbon disulfide formulation in the formation.Type: GrantFiled: April 25, 2007Date of Patent: June 11, 2013Assignee: Shell Oil CompanyInventors: Ayca Sivrikoz, William E. Hickman
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Patent number: 8403069Abstract: A method for enhanced oil recovery contacts a gas and an alkylene carbonate with a subterranean formation. The gas may be selected from any gas that is suitable for injection into a subterranean formation and has properties that allow for enhanced recovery of petroleum from a subterranean formation. The alkylene carbonate may be cyclic, straight chained, or combinations thereof.Type: GrantFiled: January 15, 2009Date of Patent: March 26, 2013Assignee: Huntsman Petrochemical LLCInventors: David C. Lewis, Luis C. Salazar, James R. Machac, Jr.
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Publication number: 20120261142Abstract: A system and method for cracking, hydrogenating and extracting oil from underground deposits is presented. A system includes injecting syngas into a oil deposit to crack and hydrogenate the oil to produce upgraded oil with a reduced density and viscosity. An acid is created to increase the geological matrix within the oil deposit to allow an increase volume of upgraded oil to flow through the geological matrix. For example, condensing the syngas in the oil deposit produces condensed syngas and this can be combined with combining carbon dioxide with the condensed syngas to produce carbonic acid. The upgraded oil with reduced density and viscosity is extracted from the underground deposit to transport the upgraded oil aboveground.Type: ApplicationFiled: September 19, 2011Publication date: October 18, 2012Applicant: AGOSTO CORPORATION LTD.Inventors: Jose J.P. Lourenco, John Gordon Murphy
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Publication number: 20120125644Abstract: A method for enhancing hydrocarbon recovery in low permeability reservoirs comprises first providing a subterranean reservoir comprising one or more hydrocarbons and water therewithin and a wellbore in fluid communication with the subterranean reservoir. Next, a substantially anhydrous composition is injected into the reservoir through the wellbore. The substantially anhydrous composition comprises carbon dioxide and one or more surfactants. The composition is suitable to form a foam upon contact with the water within the reservoir. The method often results in reduced wellbore corrosion and hydrate formation, reduced reservoir fingering, and enhanced carbon dioxide sweep efficiency over conventional methods.Type: ApplicationFiled: November 24, 2010Publication date: May 24, 2012Applicant: Chevron U.S.A. Inc.Inventor: Dengen ZHOU
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Patent number: 7931083Abstract: A method and system for producing steam for extraction of heavy bitumen including the steps of mixing carbon or hydrocarbon fuel. The fuel is crude oil, vacuum residue, asphaltin, petcoke or coal. The oxidation gas includes oxygen, oxygen enriched air or air-combustion of the mixture under high pressure and high temperature. The fuel is mixed with low quality contaminated water containing organics and inorganics. The liquid phase transferred to a gas phase includes steam and carbon dioxide, wherein solids are separated from the gas phase. The gas phase is mixed with saturated water to scrub the remaining solids and produce saturated steam. The solid rich water is recycled back for combustion. The saturated steam super-heated dry steam and gas mixture is send to an enhanced oil recovery facility for injection into an underground reservoir.Type: GrantFiled: April 7, 2010Date of Patent: April 26, 2011Assignee: EX-TAR Technologies Inc.Inventor: Maoz Betzer Tsilevich
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Publication number: 20100170683Abstract: A method of introducing a propellant gas into the ground is described, wherein a trace gas that can be analysed above the ground or the earth's surface is added to said propellant gas. According to the invention hydrogen is used as the trace gas, whereby the proportion of the trace gas hydrogen in the propellant gas/trace gas mixture is a maximum of 10% by vol., preferably a maximum of 5% by vol.Type: ApplicationFiled: December 18, 2009Publication date: July 8, 2010Inventor: Michael HEISEL
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Publication number: 20100163255Abstract: A method for treating a wellbore in a hydrogen sulfide-containing formation that includes injecting a first slug in the wellbore, the first slug comprising: at least one of primary amine and ammonia; and a base fluid; injecting a second slug in the wellbore, the second slug comprising: a triazine scavenger; and a base fluid; and allowing the triazine scavenger to react with the hydrogen sulfide is disclosed.Type: ApplicationFiled: April 1, 2008Publication date: July 1, 2010Applicant: M-I LLCInventors: Robert L. Horton, Randy Stoker, Paul Davis
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Patent number: 7707013Abstract: A method for estimating minimum miscibility enrichment (MME) for an injectant used in gas flooding of a reservoir at a given operating pressure comprising performing a plurality of slim tube simulations for the reservoir, determining minimum miscibility pressure (MMP) for a plurality of injected gases, creating a plot of recovery factor (RF) vs. 1?(MMP?P)/MMP wherein P is the operating pressure of the reservoir having at least one of the plurality of injected gases, wherein 1?(MMP?P)/MMP is a dimensionless pressure, wherein the plot has a y-intercept and slope, obtaining a recovery factor equation RF=i+s(1?(MMP?P)/MMP) wherein i is the y-intercept and s is the slope, determining a value for i, determining a value for s and calculating the recovery factor.Type: GrantFiled: December 4, 2006Date of Patent: April 27, 2010Assignee: Shell Oil CompanyInventors: Ŕaul Valdez, Peter Harold Doe, Tak Siang Kho
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Patent number: 7699104Abstract: A process for producing steam for extracting heavy bitumen includes the steps of mixing carbon or hydrocarbon fuel, the fuel being crude oil, vacuum residue, Asphaltin, or coke with an oxidation gas, the gas being oxygen, oxygen enriched air or air-combusting the mixture under high pressure and high temperature and mixing low quality contaminated water containing organics and inorganic with the combusted mixture so as to control combustion temperature and to generate steam. The liquid phase is transferred to a gas phase so as to contain steam and carbon dioxide. The solids are separated from the gas phase. The super heated dry steam and gas mixture is ejected into an underground reservoir.Type: GrantFiled: May 23, 2007Date of Patent: April 20, 2010Inventor: Maoz Betzer Tsilevich
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Patent number: 7694736Abstract: A method and system for producing steam for extraction of heavy bitumen including the steps of mixing carbon or hydrocarbon fuel. The fuel is crude oil, vacuum residue, asphaltin, petcoke or coal. The oxidation gas includes oxygen, oxygen enriched air or air-combustion of the mixture under high pressure and high temperature. The fuel is mixed with low quality contaminated water containing organics and inorganics. The liquid phase transferred to a gas phase includes steam and carbon dioxide, wherein solids are separated from the gas phase. The gas phase is mixed with saturated water to scrub the remaining solids and produce saturated steam. The solid rich water is recycled back for combustion. The saturated steam super-heated dry steam and gas mixture is send to an enhanced oil recovery facility for injection into an underground reservoir.Type: GrantFiled: May 12, 2008Date of Patent: April 13, 2010Inventor: Maoz Betzer Tsilevich
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Publication number: 20080283254Abstract: A method for increasing oil recovery from an oil reservoir in which method surplus gas streams from a plant for synthesis of higher hydrocarbons from natural gas is injected into the reservoir, is described. The surplus streams from the plant is the tailgas from the synthesis and optionally nitrogen from an air separation unit which delivers oxygen or oxygen enriched air to the plant for synthesis of higher hydrocarbons.Type: ApplicationFiled: May 16, 2008Publication date: November 20, 2008Applicants: STATOIL ASA, PetroSA (The Petroleum Oil & Gas Corporation of SA (Pty) Ltd)Inventors: Gareth David Huntley Shaw, Ola Olsvik, Erling Rytter, Jostein Sogge, Jan Age Stensen
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Patent number: 7261159Abstract: A method for perforating a wellbore comprises placing a perforating device in a cased wellbore that passes through a subterranean formation. The perforating device comprises at least one explosive perforating charge that can be detonated in order to perforate the casing and allow the formation fluids to enter the wellbore. A perforating fluid is placed in the wellbore between the perforating device and the casing. The ratio of the critical temperature of the perforating fluid in ° K and the temperature of the subterranean formation adjacent to the casing in ° K is between about 1.0-1.3. When the at least one explosive charge in the perforating device is detonated, at least one perforation is formed in the casing, and at least a portion of the perforating fluid is forced into the subterranean formation.Type: GrantFiled: June 14, 2005Date of Patent: August 28, 2007Assignee: Schlumberger Technology CorporationInventor: Philip Kneisl
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Patent number: 7036585Abstract: The invention concerns an aqueous viscoelastic fluid for use in the recovery of hydrocarbons. According to the invention this fluid comprises a first viscoelastic surfactant and a second surfactant able to decompose under downhole conditions to release a compound itself able to reduce the viscosity of the aqueous viscoelastic fluid.Type: GrantFiled: February 13, 2002Date of Patent: May 2, 2006Assignee: Schlumberger Technology CorporationInventors: Jian Zhou, Trevor Hughes
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Patent number: 6959767Abstract: A method of injection of a higher density fluid into the top of the annulus of a well while lower density fluid is withdrawn from the top of the annulus of the well, wherein the higher density fluid has a composition such that it will drop through the lower density fluid without dispersing therein, thus flowing into the deeper reaches of the annulus and not short circuiting through the top of the annulus to the point from which the lower density fluid is intended to be withdrawn.Type: GrantFiled: September 12, 2003Date of Patent: November 1, 2005Assignee: M-I LLCInventors: Robert L. Horton, John W. Powell, William E. Foxenberg, David Kippie
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Patent number: 6806234Abstract: Compounds of the formula H(CH2)zCOO—[C2H4O]xCyH2y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H4O]3C6H7.Type: GrantFiled: August 19, 2002Date of Patent: October 19, 2004Assignee: Clearwater International, LLCInventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
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Patent number: 6662872Abstract: Steam is injected into the reservoir, heats the reservoir to mobilize and recover at least a fraction of reservoir hydrocarbons, forming a steam chamber in the reservoir. The steam is continuously injected into the reservoir to mobilize and recover reservoir hydrocarbons therefrom until at least one of (i) an upper surface of the chamber has progressed vertically to a position that is approximately 25 percent to 75 percent the distance from the bottom of the injection well to the top of the reservoir, and (ii) the recovery rate of the hydrocarbons is approximately 25 percent to 75 percent of the peak predicted recovery rate using steam-assisted gravity drainage. A viscosity-reducing hydrocarbon solvent is injected into the reservoir, the solvent being capable of existing in vapor form in the chamber and being just below the solvent's saturation pressure in the chamber, mobilizing and recovering additional hydrocarbons from the reservoir.Type: GrantFiled: November 7, 2001Date of Patent: December 16, 2003Assignee: ExxonMobil Upstream Research CompanyInventors: A. M. Harold Gutek, Brian Harschnitz, Ronald D. Myers, Tadahiro Okazawa
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Patent number: 6543535Abstract: A process is disclosed for stimulating the activity of microbial consortia in a subterranean formation to convert hydrocarbons to methane, which can be produced. Fluid and rock of the formation are analyzed. The presence of microbial consortia is determined and a characterization made (preferably genetic) of at least one microorganism of the consortia, at least one being a methanogenic microorganism. The characterization is compared with at least one known characterization derived from a known microorganism having one or more known physiological and ecological characteristics. This information, together with the information obtained from the analysis of the fluid and rock, is used to determine an ecological environment that promotes in situ microbial degradation of formation hydrocarbons and promotes microbial generation of methane by at least one methanogenic microorganism of the consortia. This information is then used as the basis for modifying the formation environment to produce methane.Type: GrantFiled: February 20, 2001Date of Patent: April 8, 2003Assignee: ExxonMobil Upstream Research CompanyInventors: David R. Converse, Stephen M. Hinton, Glenn B. Hieshima, Robert S. Barnum, Mohankumar R. Sowlay
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Patent number: 6439308Abstract: A foam drive method for enhancing oil recovery efficiently is initiated by injecting into a subterranean oil-bearing formation, an aqueous polymer solution as a preceding-slug. This is followed by periodically injecting simultaneously or alternately a non-condensible gas and an aqueous solution of foaming composition to form a combined foam under ground or periodically injecting the combined foam formed beforehand by the gas and said aqueous solution above ground. The aqueous solution of foaming composition comprises an alkali, a surfactant and a polymer. Thereafter, an aqueous polymer solution used as a protecting-slug is injected into the formation; followed by continuing water-flooding.Type: GrantFiled: December 5, 2000Date of Patent: August 27, 2002Assignee: Da Qing Petroleum Administration BureauInventor: Demin Wang
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Publication number: 20020066566Abstract: A method and apparatus are disclosed in which alkane-utilizing bacteria are used to reduce fouling of injection and recovery wells. Fouling materials such as combinations of bacteria and metal oxides that would otherwise clog the wells are prevented from depositing on the wells. In a preferred embodiment, a butane substrate and an oxygen-containing gas are injected near a well inlet or outlet to stimulate the growth of butane-utilizing bacteria which are effective at reducing or eliminating fouling of the well.Type: ApplicationFiled: June 11, 2001Publication date: June 6, 2002Inventor: Felix Anthony Perriello
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Patent number: 6244346Abstract: A method and apparatus are disclosed in which alkane-utilizing bacteria are used to reduce fouling of injection and recovery wells. Fouling materials such as combinations of bacteria and metal oxides that would otherwise clog the wells are prevented from depositing on the wells. In a preferred embodiment, a butane substrate and an oxygen-containing gas are injected near a well inlet or outlet to stimulate the growth of butane-utilizing bacteria which are effective at reducing or eliminating fouling of the well.Type: GrantFiled: April 16, 1999Date of Patent: June 12, 2001Assignee: Global BioSciences, Inc.Inventor: Felix Anthony Perriello
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Patent number: 6152234Abstract: A method for strengthening a subterranean formation by injecting an aqueous gellable composition containing a cross-inkable polymer into the subterranean formation through a wellbore to increase the strength of the subterranean formation while retaining the ability of the subterranean formation to produce fluids.Type: GrantFiled: June 10, 1998Date of Patent: November 28, 2000Assignee: Atlantic Richfield CompanyInventors: Daniel P. Newhouse, Gangerico G. Ramos
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Patent number: 6105672Abstract: Enhanced (WAG type) oil recovery process in an underground reservoir uses forced injection, through one or more wells, alternately of fluid slugs and gas slugs, and recovery, through one or more production wells, of petroleum fluids displaced by the wetting fluid and the gas injected. The process includes dissolving a pressurized gas in the liquid of certain slugs and, after injection, relieving the pressure prevailing in the reservoir so as to generate gas bubbles by nucleation in the smallest pores, which has the effect of driving the oil away from the less permeable zones into the more permeable zones (with large pores or with fractures) where the oil is swept by the gas slugs injected later on. Implementation of the process considerably increases the oil recovery ratio that is usually reached with WAG type processes.Type: GrantFiled: June 17, 1998Date of Patent: August 22, 2000Assignee: Institut Francais du PetroleInventors: Christian Deruyter, Jean-Claude Moulu
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Patent number: 5950727Abstract: A process for mitigating the effects of gas migration through channels in a cement sheath in a hydrocarbon production well by injecting a mixture of a carrier fluid with a dissolved polmer into the sheath and dropping the polymer out of solution to form polymers to plug the channels. The process utilizes the phase transition parameters of the mixture coupled with well conditions and/or injection parameters to cause the polymer to drop out of solution within the gas migration channels. The mixture can be injected through well perforations in the producing zone or perforations made in the wellbore adjacent the gas migration zone or directly into the cement sheath at the wellhead.Type: GrantFiled: August 14, 1997Date of Patent: September 14, 1999Inventor: Cyrus A. Irani
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Patent number: 5632336Abstract: A method is provided for increasing the rate of injection of flooding fluids into injection wells. A slug of polar solvent or a mixture of polar solvent and non-aqueous flooding fluid is injected into the injection well to displace aqueous and hydrocarbon liquids in the rock surrounding the injection well. Thereafter, the solvent is removed from the vicinity of the injection well by flooding fluid. The process may be repeated following each time water is injected into the injection well.Type: GrantFiled: July 28, 1994Date of Patent: May 27, 1997Assignee: Texaco Inc.Inventors: Phillip K. Notz, John Prieditis, James F. Stevens