Including Heat By Burning Of Product Patents (Class 201/15)
  • Patent number: 6746497
    Abstract: A waste is dry-distilled in a gasification furnace and generated combustible gas is combusted in a combustion furnace. A temperature in the combustion furnace is set to be substantially constant at a first preset temperature or more. When the temperature in the combustion furnace is greater than the first preset temperature by combustion of other fuels, the combustible gas is introduced. When the temperature in the combustion furnace reaches a second preset temperature or more by the combustion of only the combustible gas, the combustion of the other fuels is finished. When the temperature in the combustion furnace falls below a third preset temperature the combustion of the other fuels is resumed. When the temperature in the gasification furnace falls below a fourth preset temperature, the combustion of the other fuels is finished.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 8, 2004
    Assignee: Kinsei Sangyo Co., Ltd.
    Inventor: Masamoto Kaneko
  • Publication number: 20020134659
    Abstract: The invention provides a method and apparatus for decreasing gas flow rates in a sole flue gas system for a coke oven during at least an initial coking operation after charging a coking oven with coal. The method includes providing a duct system between a first coke oven having a first coking chamber and a second coke oven having a second coking chamber to direct at least a portion of gas from a gas space in first coking chamber to the second coke oven thereby reducing a gas flow rate in the first sole flue gas system of the first coke oven. Reduction in sole flue gas flow rates has a beneficial effect on product throughput, the life of the coke oven and environmental control of volatile emissions from coke ovens.
    Type: Application
    Filed: February 14, 2001
    Publication date: September 26, 2002
    Inventor: Richard W. Westbrook
  • Patent number: 6168688
    Abstract: A method and apparatus is provided for the thermolysis of solid waste within an enclosed thermolysis chamber in the absence of free oxygen which produces a thermolysis off-gas. The thermolysis off-gas is removed from the thermolysis chamber and injected into a cyclone where it is washed with water and cooled. The washed and cooled thermolysis off-gas is divided into two portions. One portion of the washed thermolysis off-gas is further cooled in a heat exchanger and then injected into a burner and combusted, while the remaining portion of the washed thermolysis off-gas is passed into indirect heat exchange with the hot off-gas resulting from the combustion of the other portion of the thermolysis off-gas in the burner and recycled back into the enclosed thermolysis chamber. This in-situ recycling of hot thermolysis off-gas helps prevent the creation of hot spots in the thermolysis chamber and the possibility of an explosive reaction between oxygen and hydrogen.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: January 2, 2001
    Assignee: Societe Francaise de Thermolyse
    Inventors: Guy Clot, Jean Roure
  • Patent number: 5928476
    Abstract: A coke oven door for closing the open end of an elongated coking chamber of a nonrecovery coke oven, including process air vents extending through the door at a level above a coal charge to be coked, has a structural frame on its outer surface including an elongated manifold extending across the door adjacent its bottom with a plurality of inlet openings in the manifold, and a tubular duct system connecting the manifold to the process air inlets whereby reduced pressure in the oven will draw air through the process air inlets and the duct system to thereby draw emissions from the area at the base of the door into the oven for incineration.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: July 27, 1999
    Assignee: Sun Coal Company
    Inventor: Jerry C. Daniels
  • Patent number: 5846385
    Abstract: The invention provide a process for energy recovering through waste classification and calcination and an apparatus therefor, comprises crushing and sorting various types of wastes and by means of a series of classification, calcination and recovering treatments, recovering and reusing efficiently fuel oil, fuel gas and residues as well as electric power and heat required for the apparatus in the self-supplying feedback system of the invention, and additionally, lowering successfully the possibility of secondary pollution from wastes disposal.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: December 8, 1998
    Inventor: Szu Jeng Chien
  • Patent number: 5843303
    Abstract: A residuum oil solvent extraction process is improved by using direct fired convection heaters for heating the asphaltene, the solvent-deasphalted oil phase, the deasphalted oil and the stripping steam, instead of hot oil heat exchangers. The convection heaters are fired using recirculated flue gas so that the hot flue gas supplied to the convection heaters has a temperature between 800.degree. F. and 1400.degree. F.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: December 1, 1998
    Assignee: The M. W. Kellogg Company
    Inventor: Ram Ganeshan
  • Patent number: 5789636
    Abstract: The invention concerns a process for recovering synthetic raw materials and fluid fuel components from used or waste plastics in accordance with patent application P 43 11 034,7. At least a partial flow of the depolymer produced according to this process is subjected, together with coal, to a coking process, fed to a thermal utilization system or introduced as a reducing agent into a blast furnace process. The depolymer can be used as an additive for bitumen and bituminous products.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: August 4, 1998
    Assignee: Veba Oel AG
    Inventors: Rolf Holighaus, Klaus Niemann, Claus Strecker
  • Patent number: 5783046
    Abstract: An improved process and apparatus for the destructive distillation or pyrolysis of rubber, such as used rubber tires, to produce liquid and gaseous hydrocarbons and a solid carbonaceous char. A heat transfer gas circulating in a circulation loop is used to cool the hot char produced in the distillation chamber of a distillation oven, the circulation loop having some means for removing the heat transferred to the heat transfer gas from the hot char. In one embodiment, two distillation ovens are operated in off-set, batchwise distillation cycles. The distillation cycles in the two ovens are coordinated so that a fresh charge of rubber feed is introduced into the distillation chamber of one of the ovens as the distillation of rubber in the other oven is concluded.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 21, 1998
    Assignee: Gentech, Inc.
    Inventor: Virgil J. Flanigan
  • Patent number: 5639353
    Abstract: An apparatus for the carbonization of materials, such as coal, comprising an elongated coking retort defined by an annulus which constitutes the coking chamber within which the coal is carbonized indirectly by conduction. In order to provide an efficient mechanism for transferring thermal energy to the coal by conduction, highly conductive tiles equipped with flues and adapted to transport hot flue gas makes up the walls of the annulus within which the coal is carbonized. The raw gas (discharged from carbonization) and the cooled flue gas (discharged from the flues) are collected and separately treated to prevent polluting emissions.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: June 17, 1997
    Inventor: Albert Calderon
  • Patent number: 5607556
    Abstract: This invention discloses a new method for the production of coke from coals. In the present invention, coke is continuously produced by heating a moving charge of coal inside the annular space between two tubes. The coking chamber, which includes a large tube and a smaller tube, is force-fed with a coal such as a metallurgical coal. The coal is bi-directionally heated along a controlled temperature gradient between the outer wall of the small tube and the inner wall of the large tube. The coal is transformed to coke as it travels through the annulus of the coking chamber. Coke is discharged from the chamber at the end opposite to which it was charged and is cooled before being exposed to the atmosphere. Gases generated during the coking process are collected and treated. All of these operations are accomplished in a closed system to prevent pollution.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: March 4, 1997
    Inventor: Albert Calderon
  • Patent number: 5449439
    Abstract: Combustible off-gas(es) produced by the process of pyrolysis are superheated; and a pressurized gaseous mixture including oxygen, normally compressed air, is preheated; before, and by, a burning of the combustible off-gas(es) produced by process of pyrolysis in the presence of stoichiometric oxygen. The burning transpires in a large number of relatively small burner cups having bulbously-shaped and exhaust-constricted combustion chambers. The burner cups are both individually, and collectively, adjustable in their uptake of combustible gases by adjusting the flow of compressed air. The combustion in each burner cup is very complete and efficient nonetheless to having increased area contact with the chamber wall, and nonetheless to the rapidly and turbulent flow of gases, because everything contributing to or touching the combustion reaction is optimally hot, and because the shape of the burner cups holds the combustion optimally long.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: September 12, 1995
    Inventor: Ronald Heald
  • Patent number: 5318671
    Abstract: A method of controlling operation of a nonrecovery coke oven battery including a plurality of elongated coke ovens constructed in side-by-side relation with each oven having a separate system of sole flues beneath each end connected to the crown of the oven by measuring the temperature in the oven and regulating the draft to the oven in response to the measured oven temperature and by measuring the temperature in the sole flue systems beneath each oven and adjusting the draft to one of the sole flue systems only in response to differences in temperature in the two sole flue systems.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: June 7, 1994
    Assignee: Sun Coal Company
    Inventor: Charles W. Pruitt
  • Patent number: 5302254
    Abstract: A plant for treating industrial and/or urban waste includes a stage for drying of the waste, followed by a stage for effecting thermolysis of the dried waste and a stage for effecting recovery of the solids and gases resulting from the thermolysis. Thermolysis of the waste is effected in a reactor by indirect heat exchange with combustion gases and drying gases for drying of the waste are subsequently treated to remove vapor materials and then recycled to a gas generator for generating the drying gases. Additionally the plant includes a stage for effecting dechlorination of the solids resulting from the thermolysis by washing the solids with an aqueous liquid, as well as a stage of separating the wash solids and the resulting wash liquid.
    Type: Grant
    Filed: July 9, 1992
    Date of Patent: April 12, 1994
    Assignee: Institut Francais Du Petrole
    Inventors: Gerard Martin, Robert Gaulard
  • Patent number: 5279712
    Abstract: A process for the pyrolysis of carbonation materials such as wood which comprises directly or indirectly heating the carbonaceous material with flue gases. When carbonization commences the direct heating is stopped while indirect heating continues until carbonization is complete. There is also described an application for effecting the process.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: January 18, 1994
    Assignee: Pasco Nominees Pty Limited
    Inventor: Anthony Constantine
  • Patent number: 5114542
    Abstract: A sole flue nonrecovery coking oven battery includes a plurality of elongated coking ovens constructed in side-by-side relation with common sidewalls downcomers connecting the ovens through the sidewalls to the sole flues, uptakes connecting the sole flues through the sidewalls to an elongated tunnel extending transversely of the battery and a single stack connected to the elongated tunnel applying a draft to all ovens in the battery through the downcomers, sole flues and uptakes, and an improved draft control system includes an adjustable draft regulating valve for controlling the flow of gas from the uptakes beneath each oven to the common tunnel. An adjustable damper type stack draft valve is also provided for opening and closing the stack to vary the draft applied to the stack to the battery.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: May 19, 1992
    Assignee: Jewell Coal and Coke Company
    Inventors: James H. Childress, Steve E. Newberry, Charles W. Pruitt
  • Patent number: 5085738
    Abstract: An apparatus for the thermal conversion and recovery of organic waste materials includes an oxygen-free chamber filled with molten lead and a method of use of the apparatus. The chamber is elongate and inclined so that organic material introduced in a lower portion of the chamber migrates through the molten lead to a higher portion of the chamber due to the organic material having a specific gravity less than that of lead. As the organic material migrates through the molten lead, the material is thermally converted to gaseous and vapor hydrocarbons that are captured in a condenser. The gaseous hydrocarbons are utilized to heat the lead in the chamber and the vapor is condensed to liquid hydrocarbons in the condenser. Residual solids flow to a reservoir connected to the chamber. Light carbon black is drawn into a receiver by a vacuum line located near the top of the reservoir and all other residual solids flow over a reservoir wall.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: February 4, 1992
    Inventors: Windel L. Harris, James R. Donnohue
  • Patent number: 4744969
    Abstract: The present invention relates to the coproduction of a combustible feed gas stream useable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid. The process includes heating coal in the presence of an oxygen-lean atmosphere under partial coal gasifying conditions to produce a solid carbonaceous char and a crude coal-gas stream. Sulfur-containing compounds are removed from the coal gas stream and converted to solid sulfur-containing materials. The solid sulfur-containing materials are combined with the solid carbonaceous char and gypsum to form a feed mixture. The non-gypsum portion of the feed mixture contains sufficient reducing potential to release substantially all of the sulfur in the gypsum as gaseous compounds of sulfur in a +4 or lower oxidation state. The feed mixture is heated under reducing conditions to produce a sulfur-containing second gas stream and a solid sintered product.
    Type: Grant
    Filed: December 10, 1986
    Date of Patent: May 17, 1988
    Assignee: Florida Institute of Phosphate Research
    Inventors: Jerome H. Marten, Timothy J. Kendron
  • Patent number: 4683030
    Abstract: Briquettes made from bituminous or sub-bituminous coal or peat are produced by grinding the coal, mixing it with a binder and compacting the mixture. They are then carbonized in a continuous process in a shaft oven. The coal may be predried and the finished briquettes may be preheated, with a subsequent drying and hardening. The carbonization is effected in two stages in an indirectly heated shaft oven, with the evolved gas being taken off about at the mid-height of the oven shaft, processed, and used for heating in the second, high-temperature stage. The flue gases from this high-temperature stage are used for heating in the first stage and for preheating. The second or high-temperature stage is followed by a cooling stage where the gases evolved in the second stage, and mainly comprising hydrogen are used and circulated. The evolved gas in excess is continuously removed from the cooling circuit.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: July 28, 1987
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4650546
    Abstract: Slugs (4) of products dehydrated by compression are thrust into the tube (11) up to the hearth (15). The hot gases from the hearth passing round the tube (11) heat it up in order to release the gases and carbonize the solids which burn in the form of coke in the bottom (16) of the hearth. Household refuse may thus be eliminated not only without expense but with recovery of energy from it.
    Type: Grant
    Filed: February 12, 1982
    Date of Patent: March 17, 1987
    Inventor: Gwenole J. Le Jeune
  • Patent number: 4476789
    Abstract: The present invention provides a charcoal producing apparatus comprising a combustion chamber, a heating chamber, first passage means interconnecting the combustion chamber and a discharge flue and second passage means interconnecting the heating chamber with the combustion chamber the second passage means being open to the atmosphere and having means for closing it off from the atmosphere. The invention also provides a method for the production of charcoal.
    Type: Grant
    Filed: August 31, 1982
    Date of Patent: October 16, 1984
    Inventor: Anthony Constantine
  • Patent number: 4473622
    Abstract: The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly.
    Type: Grant
    Filed: December 27, 1982
    Date of Patent: September 25, 1984
    Inventors: Paul J. Chludzinski, Philip Dantowitz, James F. McElroy
  • Patent number: 4419185
    Abstract: A process and system for continuously pyrolyzing organic feedstock produces a solid carbonaceous residue of controlled volatility, in a manner that is highly energy efficient. The value of the gaseous product and of the pyrolytic oil produced are also optimized.
    Type: Grant
    Filed: July 16, 1981
    Date of Patent: December 6, 1983
    Assignee: American Carbons, Inc.
    Inventors: Mack D. Bowen, Kenneth R. Purdy
  • Patent number: 4396487
    Abstract: The production of oil by retorting shale and other hydrocarbonaceous and lignocellulosic solid materials is facilitated by retorting in the presence of steam and acetic acid.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: August 2, 1983
    Assignee: Georgia Oil & Gas Company
    Inventor: Louis Strumskis
  • Patent number: 4384923
    Abstract: The invention relates to a process for the hygienization of carbonation sludges. For this purpose, these are mixed with wastes having a high calorific value and containing organic substances and are decomposed by pyrolysis, in the absence of air, at a temperature from 200.degree. C. to 800.degree. C., preferably 250.degree. C. to 720.degree. C.The fuel gases obtained in the decomposition by pyrolysis can be utilized for external heating of the thermal reactor, autothermic operation, that is to say self-sustaining operation, becoming possible when wastes of high calorific value are added to the carbonation sludge in such a quantity that the calorific value of the waste mixture is more than 1,000 kcal/kg.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: May 24, 1983
    Assignee: Deutsche Kommunal-Anlagen Miete GmbH
    Inventor: Klaus Hillekamp
  • Patent number: 4347119
    Abstract: A horizontal retorting apparatus and method designed to pyrolyze tar sands and oil shale, which are often found together in naturally occurring deposits. The retort is based on a horizontal retorting tube defining a horizontal retort zone having an upstream and a downstream end. Inlet means are provided for introducing the combined tar sands and oil shale into the upstream end of the retort. A screw conveyor horizontally conveys tar sands and oil shale from the upstream end of the retort zone to the downstream end of the retort zone while simultaneously mixing the tar sands and oil shale to insure full release of product gases. A firebox defining a heating zone surrounds the horizontal retort is provided for heating the tar sands and oil shale to pyrolysis temperatures. Spent shale and tar sands residue are passed horizontally beneath the retort tube with any carbonaceous residue thereon being combusted to provide a portion of the heat necessary for pyrolysis.
    Type: Grant
    Filed: November 21, 1980
    Date of Patent: August 31, 1982
    Inventor: Delbert D. Thomas
  • Patent number: 4344820
    Abstract: A plurality of sole flue-heated, non-recovery coke ovens constructed in side-by-side relation in a battery have their chimney uptake outlets connected to a common combustion tunnel extending longitudinally of and above the battery and connected to stacks at spaced intervals along its length. Each oven has a bypass flue directly connecting the top of its coking chamber to the combustion tunnel, and a normally closed valve in each bypass is operable to selectively connect the coking chamber to the tunnel to permit charging gases to be drawn from the chambers to be burned in the tunnel and stack. The bypass valve is closed during coking so that the partially burned gases from the crown of the coking chambers are led through downcomers in the oven walls to the sole flues where a controlled amount of combustion air can be admitted to promote the continued burning process and provide maximum heat in the sole flues.
    Type: Grant
    Filed: December 19, 1980
    Date of Patent: August 17, 1982
    Assignee: Elk River Resources, Inc.
    Inventor: Buster R. Thompson
  • Patent number: 4317800
    Abstract: A process for reducing environmental pollution resulting from disposal of waste containing halogenated hydrocarbons by simultaneous treatment with used metal and/or metal scrap at elevated temperatures. The halogenated hydrocarbons are pyrolyzed and the resulting hydrogen halide containing gas is brought into contact with the used metal and/or metal scrap at elevated temperatures so as to form metal halogenides that are volatile under the conditions applied. The volatile metal halogenides are largely separated from the gaseous mixture formed, and at least part of the remaining gaseous mixture and/or hydrocarbon residue is used as fuel to maintain the required temperature. The waste feed compositions and process conditions can be chosen to effect separation between various metals by selective halogenation and condensation, and substantially all of the hydrogen halide can be tied up and recovered as metal halogenides.
    Type: Grant
    Filed: September 15, 1980
    Date of Patent: March 2, 1982
    Assignee: Esmil B.V.
    Inventors: Wijtze Sloterdijk, Gerrit Dapper, Cornelis A. Verbraak, Willem Kirchner
  • Patent number: 4305788
    Abstract: The process for the production of molded metallurgical coke from dried coal or fine coal mixtures with a low swelling index particularly highly volatile fine coal comprises mixing normal washed fine coal or fine coal mixtures of a grain size of from 0 to 10 mm and a swelling index of not more than 5 with a binder, pressing the mixture into briquettes, oxidizing the briquettes in a continuous material flow stream, and coking the oxidized briquettes continuously in an oven chamber by supplying indirectly and exhausting the coke oven gases with a temperature of 300.degree. to 1200.degree. C.
    Type: Grant
    Filed: March 28, 1980
    Date of Patent: December 15, 1981
    Assignee: Firma Carl Still GmbH & Co KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Klaus Urbye
  • Patent number: 4276120
    Abstract: A process and apparatus are disclosed for purification of petroleum coke to produce an economical low sulfur product suitable for electrode production. Finely ground green coke is treated on an enclosed circular grate apparatus and subjected to sequential treatments in which hot gases are passed through a deep permeable bed of coke on the grate in a series of separate treating zones including a preheat zone, a heating and calcining zone, a desulfurizing zone in which hydrogen rich gas is passed through the heated bed, a reduction gas generation zone in which hydrocarbon and steam pass through hot coke to form hydrogen, and a cooling zone.Adequate temperatures for calcination and desulfurization are achieved and the proper heating rate is obtained without overheating the metal parts of the hearth by use of radiant and hot gas heating means in the calcining zone and in the desulfurizing zone and by introducing the air and/or fuel gas near the bottom of the coke bed.
    Type: Grant
    Filed: July 10, 1979
    Date of Patent: June 30, 1981
    Assignee: Davy Inc.
    Inventor: Irvin H. Lutz
  • Patent number: 4235676
    Abstract: An elongated tube is maintained at a temperature of about 1100.degree. F. throughout its length. Organic waste material such as shredded rubber automobile tires or industrial plastic waste or residential trash which preferably has metal and inorganic matter removed therefrom, is moved through the tube at a uniform rate of speed in the absence of air and/or oxygen, with the material being churned or tumbled as by means of a screw conveyor. The vapors and gases which are produced and/or liberated within the tube are quickly removed therefrom by means of a vacuum of from about four inches to about six inches of mercury, with the vapors being condensed and the gases separated therefrom. The char or residue which is a black, powdery, carbon-type material is also recovered.
    Type: Grant
    Filed: September 16, 1977
    Date of Patent: November 25, 1980
    Assignee: Deco Industries, Inc.
    Inventor: R. William Chambers
  • Patent number: 4203804
    Abstract: A fluidized bed reactor for the pyrolysis of pieces of rubber or the like, especially old tires the reactor comprising a container at the lower part of which there is discharge device for non-volatile pyrolysis products; gas blowing nozzles arranged in a zone above the discharge device for supplying a fluidizing gas and for producing a fluidized bed from material such as sand or alumina added to the reactor; preferably a heating device, especially one comprising heating tubes extending across the container; a gas outlet disposed in the zone above the fluidized bed; and supply means for conveying pieces of material to be pyrolized to the container; this apparatus is characterized by the fact that the gas blowing nozzles are arranged to direct the gas downwardly, that at least one group of nozzles are arranged in a common horizontal plane, and that the material supply device is such that its dimensions are comparable with the cross-sectional surface of the fluidized bed.
    Type: Grant
    Filed: December 22, 1977
    Date of Patent: May 20, 1980
    Assignee: Carl Robert Eckelmann AG
    Inventors: Jorg Janning, Walter Kaminsky, Hansjorg Sinn, Stanislav Tysarcyk
  • Patent number: 4176010
    Abstract: Green petroleum coke is indirectly dried, then calcined in a cylindric rotary kiln and indirectly cooled utilizing a one-way gas flow in the system. Most of the dust in the vapor from the drying step is directly burned in a steam boiler whose off-gases are used to heat the dryer. Any residual dust in the gas is collected in an electro-filter. This dust together with dust which settles out from the dryer and the kiln is collected and added in controlled amounts to the dried coke before calcining. Hydrocarbons expelled during calcining are partially burned off with a stream of secondary air introduced at the coke exit end of the kiln. Most of the remaining hydrocarbons are burned off before they leave the coke inlet end of the kiln. The calcined coke product contains 0.1% by weight of hydrocarbons. The final off-gas from the process has a residual dust content of less than 100 mg/nm.sup.3.
    Type: Grant
    Filed: July 18, 1977
    Date of Patent: November 27, 1979
    Assignee: Wintershall Aktiengesellschaft
    Inventors: Max Dudek, Otto Tieke
  • Patent number: 4169767
    Abstract: A process for calcining green coke containing water and combustible volatile matter and obtained by a delayed coking process in three or more stages of heating furnaces which are connected in series, and the control of the temperature and the adjustment of the atmosphere in the respective furnaces can be independently carried out, which process comprises carrying out, in respective furnaces in the indicated order, the steps of:(a) evaporating the water contained in the green coke, and drying and pre-heating the coke;(b) distilling off and burning the volatile matter from the dried coke; and(c) heating and calcining the coke from the step (b).Because each furnace can be controlled independently from the other furnaces in the above described process, it is possible to produce high-grade coke without process difficulties such as the loss of the coke by combustion and the formation of coke ring.
    Type: Grant
    Filed: March 24, 1978
    Date of Patent: October 2, 1979
    Assignee: Koa Oil Company, Limited
    Inventors: Kosaku Noguchi, Nobuyuki Komi
  • Patent number: 4124450
    Abstract: An increased coking rate of a coal charge in a non-recovery coke oven is achieved without polluting emissions by decreasing the supply of primary air fed into the coke oven chamber throughout the coking period while controlling the amount of heated secondary air for combustion of the effluent in downcomers to maintain the temperature therein between 1200.degree. F and 2400.degree. F and to maintain a temperature in the range of 1800.degree. F to 2700.degree. F in heating flues by further combustion of the effluent discharged thereto from the downcomers. Coking proceeds from the top, bottom and sides of the coal charge. The effluent from the sole heating flue is incinerated within a checker-filled ignition chamber maintained at a temperature of at least 1600.degree. F. The incinerated gases are drawn into a stack at a negative draft pressure of between 0.15 and 0.17 inch water gage.
    Type: Grant
    Filed: April 18, 1977
    Date of Patent: November 7, 1978
    Assignee: Pennsylvania Coke Technology, Inc.
    Inventor: James E. MacDonald
  • Patent number: 4123332
    Abstract: Process and apparatus for treating a comminuted solid carbonizable material, such as comminuted municipal waste; sawdust, granulated coal, shredded tires and the like wherein the material is caused to be pyrolyzed in a horizontally disposed elongated reaction zone essentially free of any oxygen containing gases at ambient pressure and at a temperature of from 400.degree. C. to 900.degree. C. The material is passed through the reaction zone by paddle-like impellers mounted on a shaft while being subject to an indirect heat transfer relationship via a burning air fuel mixture spirally swirling within a heating zone about the reaction zone and the mixture being withdrawn from a lower portion of the heating zone. During pyrolysis, the material is chemically changed into valuable gaseous, liquid and solid products.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: October 31, 1978
    Assignee: Energy Recovery Research Group, Inc.
    Inventor: Franz Rotter
  • Patent number: 4122036
    Abstract: A method of pyrolyzing sewage sludge to transform the same into activated carbon, with the combustible pyrogas and volatile liquids included therewith that arise from the pyrolysis operation being burned to sustain the transformation operation. A first portion of the hot activated carbon resulting from the operation is mixed with the wet sewage sludge to provide a dry sludge mixture that is subsequently subjected to the pyrolyzing operation. Water vapor that discharges as the hot activated carbon is mixed with the wet sewage sludge is heated by the burning of the pyrogas and transformed to steam. The resulting steam is in contact with the dry mixture during the pyrolyzing operation, and as a result the dry mixture is transformed to activated carbon. A second portion of the resulting activated carbon is separated from the first portion thereof, with this second portion being available for use apart from the method.
    Type: Grant
    Filed: January 7, 1977
    Date of Patent: October 24, 1978
    Assignee: Waterfront N.V.
    Inventor: Frederick Michael Lewis
  • Patent number: 4115202
    Abstract: The coke forms are produced in four stages, each constituted by a respective oven chamber, and in which the briquets are, respectively, preheated, dehydrated or dried, carbonized and cooled. Hot gas circuits are provided, in which the hot gas is composed substantially of burnt lean gas of the carbonization, and, for each stage, the hot gases are recirculated in a separate respective circuit. In the preheating, dehydrating and carbonization stages, the hot gases are heated and produced, or supplemented, in a respective separate combustion chamber with the recirculating hot gas in the carbonization stage being supplemented with cooled lean gas from this stage. The recirculating hot gases are dedusted separately in a dust settling chamber in which their flow velocity is reduced to approximately 0.2 to 2.0 m/sec, with the dust being collected.
    Type: Grant
    Filed: September 15, 1977
    Date of Patent: September 19, 1978
    Assignees: Firma Carl Still, Rheinische Braunkohlenwerke Aktiengesellschaft
    Inventors: Kurt Lorenz, Horst Dungs, Peter Speich, Roman Kurtz
  • Patent number: 4058205
    Abstract: A process and apparatus for decomposing kerogen and recovering oil, high BTU gas and energy for the process wherein a crushed oil shale is fed to a rotary preheater (300.degree. to 350.degree. F.) hence into a rotary retort (850.degree.-1050.degree. F.) where the kerogen is decomposed and the oil evaporated, removed and condensed. From the retort the crushed shale goes to a hopper where any residual oil is stripped out by super heated steam leaving a char on the crushed shale. The stripped shale is fed into a furnace wherein the char is burned to provide heat for the process. To supplement the char and provide enough BTU's for the process, it is necessary to add a small amount of coal to the feed to the process. The hot gases from the furnace first pass into contact with the rotary retort and hence indirectly heat the oil shale in the retort. The hot furnace gases (or a portion thereof) then pass into direct contact with the crushd oil shale feed in the preheater.
    Type: Grant
    Filed: October 17, 1975
    Date of Patent: November 15, 1977
    Inventor: Thomas G. Reed, Jr.
  • Patent number: 4052265
    Abstract: Organic and pseudo-organic materials such as waste materials, for example, are processed in a converter system and decomposed into various usable and reusable forms. Inorganic metals and salts are treated likewise in the same converter system and processed into various usable and reusable forms. While being carried by a conveyor through a controlled atmosphere treatment chamber, virtually free from combustion supporting air or other oxidizing agents, the feed material is caused to progressively thermally break down into its more basic constituents which flow out of the material treatment chamber in a continuous liquid and gaseous vapor stream. Negative pressure is applied upstream from the material treatment chamber to lead the liquid and gaseous vapor stream through successive processing stages of collection containers, condensers and gas scrubbers. The variable negative pressure is sufficient to maintain the pressure in the material treatment chamber within a range of slightly above ambient pressure.
    Type: Grant
    Filed: January 12, 1976
    Date of Patent: October 4, 1977
    Inventor: Klaus M. Kemp
  • Patent number: 4052266
    Abstract: The vapor emissions from process exhausts, containing one or more contaminants of the solid, liquid and gaseous types, are delivered to the inlet of a firebox which, in one embodiment, has a cylindrical side wall and a tangentially arranged oxidizing air-fuel burner. The hot gas outlet of the firebox is so arranged that the hot gases of combustion are retained within the firebox a sufficient length of time to insure substantially complete combustion of combustibles within the firebox. The portions of the firebox which are contacted by the gases of combustion are of a material or combination of materials having a surface capable of being heated to a temperature exceeding the ignition temperature of the air-fuel mixture of the burner and of combustible materials from the process, and an external mass capable of insulating said surface against external cooling below said ignition temperature.
    Type: Grant
    Filed: May 11, 1973
    Date of Patent: October 4, 1977
    Inventor: Joseph W. Griffith
  • Patent number: 4045299
    Abstract: A burner for oil or gas is controlled by a thermocouple to maintain a predetermined minimum operating temperature within ignition chambers employed to incinerate partially-burned distillation products conducted from the space above a coal charge in a coke oven. Passageways in the side walls of the coke oven conduct the partially-burned distillation products from the space above the coal charge into sole heating flues located below the oven floor from where such distillation products are conducted into the ignition chambers. A stack is connected to the ignition chambers by a conduit which includes a recuperator used to reduce the temperature of the burned gases and provides a heated secondary air supply. This air supply is fed by separate pipes including control valves into one of the ignition chambers and into the passageways in the side walls of the coke oven. The stack includes a gas washer and a fan used to control the draw on the ignition chambers as well as the coke oven.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: August 30, 1977
    Assignee: Pennsylvania Coke Technology, Inc.
    Inventor: James E. MacDonald
  • Patent number: 4002534
    Abstract: Lump fuels are continuously coked at a high temperature above 750.degree. C in a shaft oven with direct heating by a hot scavenging gas which is produced by a partial combustion of the coking gas and conducted through the shaft oven in a countercurrent to the lump fuel. A reactive carbonaceous material is added to the hot scavenging gas before it enters the high-temperature coking zone and reacts with the gasifying agents (carbon dioxide and water) contained therein before it is introduced into the shaft oven.
    Type: Grant
    Filed: July 23, 1974
    Date of Patent: January 11, 1977
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Roland Rammler, Paul Lange
  • Patent number: 3966560
    Abstract: In the calcination of petroleum coke in a rotary kiln, procedure wherein air is controllably supplied internally of the kiln to burn the removed volatiles, as by selection or adjustment of the amount of such air and of the speed of coke travel down the kiln, so that all or nearly all of the heat for calcining the coke is provided by such combustion, and so that a suitably high temperature is reached for effective calcination at an efficiently large feed rate of coke, a special feature being to maintain a significantly long travel time of the coke from a region of intense calcining activity to the product discharge end of the kiln. High production rates, of coke calcined well and uniformly, are economically attained, with ease of control and with unusual stability of kiln operation.
    Type: Grant
    Filed: May 6, 1974
    Date of Patent: June 29, 1976
    Assignee: Alcan Research and Development Limited
    Inventors: Frank John Farago, Raman Radha Sood, David Michael Stokes
  • Patent number: 3966561
    Abstract: Carbonization of coal in travelling grate furnace with hot gas inlets below the grate. A refractory screen is provided above the grate to provide a flame propagation base for the volatile gases withdrawn from the coal on the grate. The combustion zone above the refractory screen provides radiant heat to vaporize volatiles present in the coal on the grate.The coal to be treated may be in the form of briquettes or an extruded slab. When an extruded slab of slurried coal is used the thermal shock on first entering the carbonization chamber results in the formation of carbon granules.
    Type: Grant
    Filed: September 23, 1974
    Date of Patent: June 29, 1976
    Assignee: International Oils Exploration N.L.
    Inventor: David William Hinkley