Abstract: Organic solid wastes represented by the general chemical formula C.sub.X H.sub.Y O.sub.Z are reacted with steam at elevated temperatures to produce H.sub.2 and CO.sub.2. The overall process is represented by the reactionC.sub.X H.sub.Y O.sub.Z + 2(X-Z/2)H.sub.2 O.fwdarw..sup..delta.XCO.sub.2 + [(Y/2) + 2(X-Z/2)] H.sub.2 . (1)reaction (1) is endothermic and requires heat. This heat is supplied by a tower top solar furnace; alternatively, some of the solid wastes can be burned to supply heat for the reaction. The hydrogen produced by reaction (1) can be used as a fuel or a chemical feedstock. Alternatively, methanol can be produced by the commercial processCO.sub.2 + 3H.sub.2 .fwdarw. CH.sub.3 OH + H.sub.2 O . (2)since reaction (1) is endothermic, the system represents a method for storing heat energy from an external source in a chemical fuel produced from solid wastes.

Abstract: A method and apparatus for gasifying coal wherein the gasification takes place in a spout fluid bed at a pressure of about 10 to 30 atmospheres and a temperature of about 1800.degree. to 2200.degree.F and wherein the configuration of the apparatus and the manner of introduction of gases for combustion and fluidization is such that agglomerated ash can be withdrawn from the bottom of the apparatus and gas containing very low dust loading is produced. The gasification reaction is self-sustaining through the burning of a stoichiometric amount of coal with air in the lower part of the apparatus to form the spout within the fluid bed. The method and apparatus are particularly suitable for gasifying coarse coal particles.

Abstract: An improved material fluidizing apparatus having a series of communicating reaction chambers separated by a concavo-concave foraminous member having a plurality of spaced frusto-conical openings through which a mixture of gases and solids can flow. This apparatus is useful for sustaining fluidization in a recirculating flooded dense bed, particularly under conditions of high temperature.

Abstract: A continuous process is described whereby particulate woody materials are carbonized in a fluidized bed to form solid and gaseous fuel. The process includes injecting particulate woody materials, on a continuous basis, into a fluidized bed of previously carbonized material. Off-gas from carbonization with entrained charcoal fines is continuously removed from above the bed, and coarse charcoal is continuously removed from the surface of the bed. If desired, a high ash, coarse fraction may also be continuously removed from immediately above the bed grid. The off-gas and entrained fine charcoal are separated in a cyclone system, and the charcoal fines with the coarse charcoal fraction from the bed surface are collected for use as solid fuel. Off-gas from the separator may be scrubbed, if desired, or utilized directly as an enriched gaseous fuel.

Abstract: Heat from spent shale combustion is removed from shale ash and combustion gases by direct contact thereof with raw shale particles wherein the fine raw shale particles not easily separable from the shale ash are removed prior to contact of the raw shale with the shale ash and combustion gases.

Abstract: Fine-grained coke is produced by the degasification of fine-grained coal by a process which includes the following steps:A. mixing the coal to be degasified with recirculated, heated, fine-grained coke in a mixing zone;B. withdrawing gases and vapors produced by degasification from the top portion of an intermediate zone located below the mixing zone and subjecting same to a mechanical dust collection followed by fractional condensation;C. recovering a dust-containing, highboiling tar fraction and recycling same to the mixing zone;D. mixing said tar fraction with recirculated hot coke prior to mixing with coal to be degasified; andE. completely cracking said tar fraction by matching the temperature at which the tar fraction is separated, the rate at which the tar fraction is recycled, and the temperature and quantity of the recirculated hot coke.

Abstract: In a fluidized bed process for the gasification of coal or similar carbonaceous solids wherein char particles are withdrawn from a fluidized bed reaction vessel, transported to a second vessel, and later returned to the initial vessel, char particles of high ash content are separated from particles to be returned to the fluidized bed reaction vessel by injecting a dense phase stream of char particles including particles of both high and low ash content into a vertically moving gas stream having a velocity sufficient to transport relatively light particles of low ash content upwardly into the fluidized bed reaction vessel but insufficient to suspend relatively dense particles of high ash content, collecting the high ash content particles which are not entrained by the gas stream, and periodically withdrawing the collected particles from the system.

Abstract: An aqueous coal slurry is preheated, subjected to partial oxidation and vaporization by injection of high pressure oxygen and is introduced into a top section of a hydrogasifier in direct contact with hot methane-containing effluent gases where vaporization of the slurry is completed. The resulting solids are reacted in the hydrogasifier and the combined gases and vapors are withdrawn and subjected to purification and methanation to provide pipeline gas. The amount of oxygen injected into the slurry is controlled to provide the proper thermal balance whereby all of the water in the slurry can be evaporated in contact with the hot effluent gases from the hydrogasifier.

Abstract: Fluidized bed technique for oxidizing normally agglomerative bituminous coal is disclosed. One high rank bituminous coal is prepared for activation by grinding, briquetting and crushing to the 3/4 inch to 4 mesh size. Thereafter, the coal particles are fluidized in an oxygen containing atmosphere at from about 400.degree.F. to 700.degree.F. Water is preferably added during oxidation, controlling the oxidation temperature. In this manner, coal particles are rendered non-agglomerative which, when thereafter subjected to carbonization and activation, yields superior activated carbon.

Abstract: An oxidizing gas is injected through a nozzle into a bed of carbonaceous particles in a downward direction at an angle of declination at least as great as the angle of repose of the bed particles and at a gas inlet velocity of about 50 to 500 feet per second to supply the gas needed to fluidize the bed of carbonaceous particles.