Abstract: An overhead stream from the quench system in a process for purifying acrylonitrile is condensed and recycled directly to the quench system as part of the quench liquid. The stream can be condensed in a column or in a partial condenser.

Abstract: A distillation unit (10) employs a rotary heat exchanger (32) forming a multiplicity of evaporation chambers (56) into which a liquid to be purified is sprayed for evaporation. Spray arms (58) spray at a steady rate into all of the evaporation chambers (56) simultaneously but not at a rate that is adequate to maintain the wetting required for efficient transfer of heat to the liquid. A scanning sprayer (140) supplements this steady spray with spray from nozzles (142 and 144) into only a few of the evaporation chambers at a time, visiting all of them cyclically. The overall rate of spray from the two sources thus combined to spray the chamber cyclically maintains proper wetting even though on average it is lower than the rate that would be required of a constant-rate spray into all of the evaporation chambers.

Abstract: A continuous process and apparatus is provided for treating an impure liquid to produce purified liquid. The process includes electrically activating a thermoelectric module (24) to provide a first module heated surface (26) and a module cooler surface (28); feeding the impure liquid to the first module heated surface (26) to produce vapor of the liquid; and transferring the vapor to the module cooler surface (28), to effect heat transfer to the module cooler surface (28). The process further includes (a) directing a first portion of the vapor adjacent to or onto the module cooler surface (28) to effect heat transfer to the module cooler surface to produce a first condensed liquid; (b) directing a second portion of the vapor to condenser means (18) having a second cooler surface (46) remote from the module cooler surface (28) to effect heat transfer to the second cooler surface (46) to produce a second condensed liquid; and (c) collecting the first and second condensed liquids.

Abstract: This invention relates to a process for the purification of phenols in a feedstock containing phenols and neutral oils and/or tar bases. The process includes liquid-liquid extraction of feedstock using a solvent and a counter-solvent, and separating the resulting solvent and counter-solvent layers. Phenols are then recovered from the separated solvent layer, and counter-solvent is recovered form the counter-solvent layer. The process also includes at least one of the following additions steps i) subjecting the separated solvent layer to distillation at atmospheric pressure; ii) subjecting the separated solvent layer to distillation, recovering an organic phase from the overheads product of the distillation step and recycling it to the liquid-liquid extraction step; and iii) recovering solvent from the counter-solvent layer.

Abstract: A distillation unit (10) employs a rotary heat exchanger (32) forming a multiplicity of evaporation chambers (56) into which a liquid to be purified is sprayed for evaporation. Spray arms (58) spray at a steady rate into all of the evaporation chambers (56) simultaneously but not at a rate that is adequate to maintain the wetting required for efficient transfer of heat to the liquid. A scanning sprayer (140) supplements this steady spray with spray from nozzles (142 and 144) into only a few of the evaporation chambers at a time, visiting all of them cyclically. The overall rate of spray from the two sources thus combined to spray the chamber cyclically maintains proper wetting even though on average it is lower than the rate that would be required of a constant-rate spray into all of the evaporation chambers.

Abstract: The present invention relates to a device for a distiller adapted to distil solvents for recovery of pure solvent from impure solvent, the solvent (2) being used for washing away residues of paint from spray guns. The distiller (1) includes an outer container (5) with a boiling chamber (8) which at the top has an opening (9) which can be tightly closed by a cover (10) and a flexible inner container (13) is provided in the boiling chamber (8), the flexible inner container (13) containing impure solvent to be distilled. A pipe means (20) is placed beside the flexible inner container (13) in order to allow solvent steam (7a), which is generated by boiling solvent in a lower space (19) beneath the flexible inner container (13), to pass from the lower space (19) into an upper space (16) having an outlet (17) and located above the flexible inner container (13) for preventing the solvent steam (7a) from lifting the flexible inner container (13) in the boiling chamber (8).

Abstract: There are disclosed an apparatus and a process for purification of an acrylic acid family.

Abstract: A process for the enhanced recovery and operation of hydrogen cyanide (HCN)/heads column obtained from the reactor effluent of an ammoxidation reaction of propane, propylene or isobutylene by reducing the polymer formation above the feed tray in the heads tower.

Abstract: A process for preparing a salt-free aqueous hydroxylamine solution by reacting an aqueous solution of a hydroxylammonium salt with a base to give a mixture and separating from said mixture by distillation a salt-free aqueous hydroxylamine solution, comprises using as a base an aqueous solution of a mixture of NaOH and KOH in a molar ratio Na+:K+ in the range from 70:30 to 95:5 and with a total concentration of Na+ and K+ in the range from 0.1 to 10 m/m % based on the total amount of the mixture.

Abstract: The invention relates to a method for producing a highly pure, aqueous hydroxylamine solution by distilling an aqueous solution, devoid of salt, of a hydroxyl ammonium salt in a plate column comprising at least two mechanical plates. Said method is characterised in that packing bodies are arranged between at least two plates of the plate column over the cross-section of said column.

Abstract: The present invention is directed to a solar powered distillation system and method. The solar powered still may have an impermeable nonporous membrane that may be extruded, molded, vacuum formed or sprayed-on. The membrane may be installed in a lightweight basin as a liner. Further, the membrane may have a plurality of fluid reservoirs and an overflow trough. In a preferred embodiment, the membrane material may be an opaque water grade non-toxic odorless, tasteless silicone, TPE, TPR, TPO, or EPDM. In one variation, the solar still basin casing may be molded or vacuum formed and made of ABS, polycarbonates, fiberglass and/or polybutylene. The solar still may further include legs made of PVC or similar pipe materials that are coupled to the still basin with a coupling. The still may include a gasket or seal compressed by a metal and rubber seal stripping to couple a sheet of glass to the still basin.

Abstract: A perforated tray without downcomer in accordance with the present invention satisfies following conditions: (a) The hole has a diameter of 10 mm to 25 mm. (b) Two adjacent holes are spaced by a distance of 1.2 d to 3 d, measured between the two centers. (c) The tray thickness is 2 mm to 8 mm. (d) The opening ratio is 10% to 30%. A perforated tray tower without downcomer fitted with two or more such perforated trays without downcomer in accordance with the present invention satisfies following conditions: (g) Perforated trays are spaced by a distance of 0.1 D to 0.5 D (D denotes the tower diameter). (h) The levelness of each perforated tray is 8 mm or less. (i) If a plurality of perforated trays are used at the same stage, the two most closely located holes that respectively belong to adjacent perforated trays are spaced by a distance of 50 mm to 150 mm, measured between the two centers.

Abstract: A simultaneous system for the distillation and elevation of water on top of the water table itself, which drastically reduces the effects of scaling and corrosion, which, driven by thermo solar energy in an autonomous operation allows for the transportation and generation of electrical power.

Abstract: Toluene diisocyanate is recovered from a crude distillation feed comprising less than 2% by weight of phosgene by

Abstract: Separations processes and apparati capable of purifying thermally sensitive materials at high capacity. An apparatus having a rectification section and a stripping section with the stripping section having a stripping tray with 5 to 50% open area, a pressure drop from 0.02 psi to 0.2 psi and a tray efficiency during operation of the column which is equal to or greater than 20%.

Abstract: By using a dephlegmator which conducts distillation concurrently with heat exchange within at least one distillation column, or a portion of one distillation column, of a distillation cascade, the quantity of liquid holdup within the distillation apparatus is reduced and the start-up time is shortened. Consequently, the operational costs associated with startup are reduced, and productivity is improved markedly.

Abstract: A process for obtaining pure 1,3-butadiene from crude 1,3-butadiene by distillation is carried out in a dividing wall column in which a dividing wall is located in the longitudinal direction of the column to form an upper common column region, a lower common column region, a feed section and an offtake section.

Abstract: A method for removing dissolved solids, particularly salts, from water. An apparatus for performing the inventive method is disclosed. The aqueous solution to be treated, for example sea water, is atomized using special non-pneumatic nozzles, and sprayed into an evaporation chamber through which air, heated by waste heat, is blown. The micro-droplets undergo rapid evaporation in the chamber, resulting in the separation of the salt solids from the vapor phase of the water. The mixture of suspended solids and water vapor is filtered to remove and collect the salts, and the water vapor is condensed to collect the salt-free water.

Abstract: A method for vaporizing a liquid in a microwave evaporator (19) by slowly evaporating the liquid from a liquid phase to a vapor phase below the boiling point of the liquid; and applying an effective amount of microwave generated by magnetron (21) to maintain the slow evaporation of the liquid to produce a purified liquid. The amount of liquid in the evaporator is monitored by a level transmitter (13) and controlled by a combination of controller (14) and control valves (12) and (16).

Abstract: A modular apparatus for fractional distillation and other forms of vapor-liquid contacting is presented. The apparatus performs cocurrent contacting of vapor and liquid in a number of identical structural units which are placed in horizontal layers in a column or other enclosure. The structural units, or modules, are horizontally spaced apart in each layer to provide spaces for the downcomers from the modules of the next higher layer. The downcomers deliver the liquid to one of two inclined contacting channels, with the contacting channels discharging the vapor and liquid into separation chambers at the top of the module. Vapor flows upward from the separation chambers to the contacting channel of the next higher module and liquid flows down through a single central downcomer to the next lower contacting channel.

Abstract: Identified herein are inhibitors which may be added to the boiling pot portion of a distillation apparatus prior to or during the distillation of an alkylene carbonate. The inhibitors retard the occurrence of undesirable reactions of the alkylene carbonate with itself and impurities present in the pot, and hence greatly reduce or minimize the formation of undesirable by-products which otherwise tend to reduce overall yields of alkylene carbonate recovered by the distillation process. Higher distillation temperatures at higher pressures over the prior art are possible without attendant losses of significant amounts of recovered alkylene carbonate, which confers heretofore unseen flexibility in alkylene carbonate distillation.

Abstract: The invention refers to a simultaneous system for the distillation and elevation of water on top of the water table itself, which driven by thermo solar energy allows in an autonomous operation the generation of electrical power through transportation and free fall of water.

Abstract: Improved HETP is obtained in the operation of a distillation column containing trays with a packing of a porous container containing a particulate material intimately associated with a resilient component having at least 50 volume % open space, preferably at least 70 volume % positioned on the trays compared to the trays without the packing. The packing may contain a catalytic particulate material and the distillation may involve reaction and distillation of the reaction products. The particulate material may also be inert and the distillation of the conventional type to separate components in the distillation mixture without reaction.

Abstract: The present invention concerns a process for providing tertiary amine products which are color-stable, and have a greatly reduced tendency to take on color during their storage. According to the invention, an ethyleneamine derivative is added to the distillation pot prior to or during the distillation of the tertiary amine product. Preferably, the ethyleneamine derivative has a higher boiling point than the desired tertiary amine product so as to preclude the ethyleneamine from distilling over with the tertiary amine.

Abstract: In distillation of a polymerizable compound such as (meth)acrylic acid or a liquid containing such a polymerizable compound with use of a distillation column equipped with a reboiler, (a) a vertical multi-tube reboiler whose outlet nozzle inside diameter (D1) is 0.2 to 1 time its reboiler shell inside diameter (D2) is used as the reboiler, (b) an outlet of an outlet nozzle of the reboiler to a gas-phase section of the distillation column is provided at a position such that a distance L from the top tubesheet of the reboiler to the lower end of the outlet of the outlet nozzle satisfies L=(0.4 to 3)×D1, and (c) a liquid level in the distillation column is maintained in a range such that a height H of the liquid level from the top tubesheet of the reboiler satisfies H=(0.1 to 0.8)×L.

Abstract: Process for the purification of toluenediisocyanate from a crude distillation feed comprising toluenediisocyanate, an organic solvent and less than 2% by weight phosgene by separating the crude distillation feed in a dividing-wall distillation column into at least four product fractions P1-P4.

Abstract: An apparatus for the desalination or purification of water includes a non-solid vessel (3) having a bottom defining an opening, the vessel (3) capable of being partially submerged below the surface of a body of water, a pan (5) located within the vessel (3), the pan (5) being flexibly connected to the inner wall of the vessel (3) and being located beneath the surface of the water (13), a lens fixably connected to the top of the vessel (3), wherein the lens is focused beneath the surface of the water (13) and above the surface of the pan (5) a device for varying the orientation of the vessel (3) in accordance with the location of the sun, and a device for condensing steam generated in the non-solid vessel (3), whereby steam generated in the non-solid vessel (3) is condensed outside of the non-solid vessel (3).

Abstract: A process is described for preventing plugging of distillation equipment when the distillable liquid comprises a mixture of different liquids containing a dissolved substance tending to precipitate from the distillate. An adjuvant is provided to the mixture to be distilled, which adjuvant forms a composition with the dissolved substance that, if isolated, melts at a lower temperature than the distillation temperature.

Abstract: The present invention provides a column treating method by use of a distillation column and so on, which method enables to effectively remove solid impurities such as precipitates and polymers contained or produced in a treating fluid, and to thereby stably operate the column treatment. Solid impurities in a treating fluid can be removed by carrying out: step (a) of drawing out the treating fluid from a drawing out outlet (16) at the column bottom of the treatment column (10) outside the treatment column (10), step (b) of removing solid impurities from the treating fluid, drawn out in step (a), by a strainer (40), and step (c) of returning the treating fluid, from which the solid impurities are removed in step (b), to a returning inlet (18) of the treatment column, with advancing physical and/or chemical treatment of the treating fluid in the treatment column (10).

Abstract: A mechanical water still (10) includes an impervious dome-like upper surface (12) and a membrane base (14) that is coupled (26) to the impervious dome-like structure (12) to form, when inflated, a chamber (20). The membrane base (14) supports a water pervaporation process therethrough. A water collection well (16) has an opening into which water droplets condensed from the water pervaporation process collect. The water collection well (16) is sited within the membrane base (14) and generally extends outwardly and downwardly from the membrane base (14), as shown in FIG. 1. In use, a contaminated water source (24) is brought into, ideally, complete contact with the membrane base (14), with the water collection well (16) arranged both to act as a heat sink into the water source (24) and to provide stability to the water still (10) when floating and immersed in the water source (24).

Abstract: A water purification system and method for residential or commercial application having a first support structure coupled to a water supply having a first heat source of sufficient magnitude to change the water into steam, thus abandoning any insoluble material dispersed within the liquid. The steam is further heated in a second support structure to form a substantially gaseous vapor and exposed to a second heat source of sufficient magnitude to super-heat the vapor to a temperature capable of destroying most, if not all living matter. Preferably, the second heat source is an electrical field of sufficient voltage to increase the temperature of the vapor in excess of 2000° F. The super-heated vapor is then allowed to condense to form potable water. This system may be powered by a standard 120 volt outlet found in the home.

Abstract: A distillation apparatus is provided with a distillation tower, a reboiler, a bottom outflow pipe for drawing a liquid from the bottom of the distillation tower, and a pot provided between the bottom of the distillation tower and the bottom outflow pipe. A part of the drawn liquid is discharged to the outside of the distillation apparatus while the rest is flowed to the reboiler. The pot has a cross-sectional area smaller than a cross-sectional area of the distillation tower and larger than a cross-sectional area of the bottom outflow pipe.

Abstract: A distillation apparatus includes a column body; a partition for dividing the interior of the column body; a first distillation section composed of an enriching section and an exhaust section; a second distillation section composed of an enriching section formed above an upper end of the first distillation section, and an exhaust section located adjacent to the enriching section of the first distillation section; a third distillation section composed of an enriching section located adjacent to the exhaust section of the first distillation section, and an exhaust section formed below a lower end of the first distillation section; a condenser; a negative pressure generation system for generating a negative pressure to thereby withdraw vent gas; a gas cooler for cooling the vent gas; a first discharge system disposed at the side of the column body and adapted to discharge liquid rich in a medium-boiling-point component formed from a high-melting-point material; and a second discharge system disposed at the botto

Abstract: A desalinization process and apparatus utilizing a humidity chamber having a saltwater structure; a cooling water structure and a salt-free water collection structure. Saltwater having a first temperature and cooling water having a second temperature are introduced into the humidity chamber. The temperature difference between the saltwater and the water running through the water coil create a temperature gradient causing salt-free water to distill from the saltwater. The salt-free water is then collected.

Abstract: One or more water distillation chambers are provided wherein water containing salt or other impurities enters an upper inlet at a chamber and flows down a solar heated evaporative surface. The evaporative surface may be the interior of a pipe or the surface of a bottom sheet enclosed by a cover. In this way, the steam produced in the process will be constrained and be guided into a steam drum. The steam drum interior has cooling tubes whereby vapor entering the steam drum will be condensed into fresh water and collected for use. The cover may be heated to limit the amount of vapor condensing back into water before entering the steam drum. Multiple evaporation chambers and steam collection stages limit the distance water vapor must travel before entering a steam drum of a given stage, thereby minimizing the loss of water vapor through re-condensation before the vapor enters the steam drum.

Abstract: The method and system of the present invention is designed to minimize exergy consumption consistent with a given level of product purity. For example, in a distillation system, the design employs a plurality of thermostatted trays which are maintained at a sequence of temperatures specified by finding the optimal control for an irreversible thermodynamic process. The specified temperatures at each tray are achieved with the help of a tandem heat pump which works over the range of required temperatures and which delivers the specified heat demands.

Abstract: A dividing-wall column having a dividing wall which is essentially disposed along the long direction of the column is proposed, which divides the column interior into a feed part, a take off part, an upper shared column part and a lower shared column part, with feed in whole or in part in the vaporous state of a mixture to be separated between the upper region of the feed part and the lower region of the feed part and/or side stream take off in whole or in part in the vaporous state between the upper region of the take off part and the lower region of the take off part, where if feed is in whole or in part in the vaporous state the cross-sectional area of the upper region of the feed part is increased by plane-parallel displacement of the dividing wall toward the upper region of the take off part, and/or if the side stream take off is in whole or in part in the vaporous state, the cross-sectional area of the lower region of the take off part is increased by displacement of the dividing wall toward the lower r

Abstract: Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Salt water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas to form positive buoyant hydrate. The hydrate rises and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths. In preferred embodiments, the input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth.

Abstract: A combination reflux/distillation apparatus is provided having interchangeable reflux and distillation columns, a segmented collection trough and an integrated indirect heating provision. The apparatus is uniquely adapted for refluxing and distilling small quantities of materials without the losses attendant to larger apparatus.

Abstract: A repairable short-path still is manufactured by forming the still body containing the cooling jacket and the vacuum adapter with two ring seals.

Abstract: Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Salt (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas to form either positively buoyant or negatively buoyant (assisted buoyancy) hydrate. The hydrate rises or is carried upward and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths. In preferred embodiments, the input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth.

Abstract: The present invention, a SOLAR DESALINATION PLANT is a water desalinating plant utilizing solar energy. It comprises of an airtight housing chamber covered with a transparent dome at its top and a transparent wall constructed over a source of saline or murky water. The chamber stands in the water and the water covers entire bottom portion inside the chamber. The surface of the water inside the chamber is covered with black floats. There is an horizontal channel in the form of an open duct above the surface of the water all around fixed to the wall inside the chamber. The channel slightly slopes down into an outlet pipe and a transparent U-tube connecting to a transparent collecting tank. A suction pump is connected between the collecting tank and a storage tank through a valve. The storage tank is also connected to the collecting tank through another valve. The transparent dome allows the sun's rays to pass through into the chamber to heat the black floats.

Abstract: A perforated tray without downcomer having only a small deviation between the opening ratio based on the diameter of a column and the actual opening ratio and a perforated tray column without downcomer formed by disposing such perforated trays without downcomer are provided. The perforated trays without downcomer are characterized by having a ratio of (A)/(B) in the range of 1.1-1.5, wherein A denotes the opening ratio found from the standard pitch between centers of holes and (B) denotes the opening ratio based on the diameter of a column.

Abstract: Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Saline (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas or liquid to form either positively buoyant (also assisted buoyancy) or negatively buoyant hydrate. The hydrate rises or sinks or is carried into a lower pressure area and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths, and input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth.

Abstract: A solar cell floats over a body of saline water. A submerged fresh water collection system underlies the cell. A partial vacuum is created in the solar cell for drawing water vapor from the cell to the collection system. Water vapor is condensed in a condenser disposed between the cell and the collection system. Heat generated by the condensation of water vapor is utilized to heat the salt water, which rises upwardly to replace the salt water vaporized in the cell.

Abstract: High-purity benzyl benzoate is recovered by distilling the residue remaining after removal of unreacted toluene and benzoic acid from a reaction mixture produced by the oxidation of toluene by molecular oxygen in the presence of a metal catalyst thereby separating a fraction of benzyl benzoate containing 80 wt % or more benzyl benzoate, 10 wt % or less benzoic acid and 10 wt % or less fluorenone, and purifying the fraction of benzyl benzoate by crystallization such as recrystallization. According to this process, it is possible to recover high-purity benzyl benzoate by a simple operation at low cost from the by-product formed in the manufacture of benzoic acid.

Abstract: A process comprising electrically activating a thermoelectric module (24) to provide a first module heated surface (26) and a module cooler surface (28); feeding the impure liquid to the first module heated (26) surface to produce vapour of the liquid; and transferring the vapour to the module cooler surface (28) to effect heath transfer to the module cooler surface (28), the improvement comprising (a) directing a first portion of the vapour adjacent to or onto the module cooler surface (28) to effect heat transfer to the module cooler surface to produce a first condensed liquid (b) directing a second portion of the vapour to condenser means (18) comprising a second cooler surface (46) remote from the module cooler surface (28) to effect heat transfer to the second cooler surface (46) to produce a second condensed liquid; and (c) collecting the first and second condensed liquids; wherein the condensation means is such as to accept the balance of the latent heat contained in the vapour produced by the first mo

Abstract: Mass transfer process, in which, in at least two contact stages, and at least two liquid or gaseous phases are brought into contact with one another, at least one component being transferred between the phases and the phases moving countercurrently. The flow through at least one of the contact stages is batchwise for one phase and continuous for another phase. The phases flow through contact stages which are formed by trays in a column, which trays are opened periodically so that the phase which flows through the column in a batchwise manner flows to the next tray.

Abstract: A modular solvent recovery device (30) includes an enclosure (34) mounted to a frame (32) to enclose a tank (70) having a solvent section (72) and a waste fluid section (73), a still (40) in which waste photopolymer fluid is distilled by application of heat and vacuum pressure to the waste photopolymer fluid to distill a solvent from the waste photopolymer fluid and reduce the waste photopolymer fluid to a coalescing concentrated residue, and a flash-point-increasing agent delivery system (95) to supply a flash-point-increasing agent to the concentrated residue in an amount sufficient to raise the flash point temperature of the coalescing concentrated residue to a predetermined temperature. The still has a manhole device (46) comprising a pivotally and telescopically mounted closure (47) having wheels (51) rotatably mounted thereto and tracks (52) mounted to the still to engage the wheels and raise the closure vertically above a manhole (42) of the still upon pivotal movement of the closure.

Abstract: A distillation procedure is provided for the separation of impurities from organic materials such as glycols and glycol ethers whereby a liquid stripping component is interfaced into a distillation column with or below the organic material introduction, heat being provided by a reboiler, the stripping component and impurities being removed overhead.