Inorganic Salt Containing Oxygen In The Anion Patents (Class 203/33)
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Patent number: 10035745Abstract: A method of purifying crude sevoflurane comprising (i) providing crude sevoflurane and an aqueous base to a first centrifugal separator, wherein the crude sevoflurane comprises sevoflurane and hexafluoroisopropanol; (ii) mixing the crude sevoflurane and the aqueous base in the first centrifugal separator; and (iii) separating the sevoflurane from the aqueous base in the first centrifugal separator, thereby purifying the crude sevoflurane.Type: GrantFiled: July 30, 2016Date of Patent: July 31, 2018Assignees: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE SAInventors: Yongxian Zeng, Hong-Chang Lee, Linas Kudzma
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Patent number: 9427705Abstract: The method of solvent recovery includes using a plurality of solvent recovery units to recover solvent from a dilute solution. The solvent recovery units can include a plurality of reverse osmosis or forward osmosis membrane systems arranged in series. For reverse osmosis, at least some of the concentrate in a last reverse osmosis unit of the series is recycled back to the permeate of that unit to provide a mixed permeate. The mixed permeate is then passed successively to the permeate side of each preceding reverse osmosis unit in the series. For forward osmosis, a draw solution is passed sequentially from the permeate side of each unit to the permeate side of the preceding unit. The draw solution may be prepared by concentrating part of the concentrate stream by evaporation and recycling it back as a draw solution.Type: GrantFiled: November 4, 2015Date of Patent: August 30, 2016Inventor: Basel Abusharkh
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Patent number: 8921088Abstract: The present invention includes a method for harvesting or separating one or more biological cells from an aqueous feed, a stream, a suspension, or any combinations thereof by providing the aqueous feed, the stream, or the suspension comprising the one or more biological cells in a tank or a vessel; providing one or more ion-exchange resins, wherein the ion-exchange resin is an anion-exchange resin; contacting the anion-exchange resin with the aqueous feed; binding the one or more biological cells to the anion-exchange resin; releasing or eluting the bound one or more biological cells by changing the pH; and collecting the released one or more biological cells to obtain a concentrated slurry or suspension of the one or more biological cells.Type: GrantFiled: October 3, 2012Date of Patent: December 30, 2014Assignee: Board of Regents, The University of Texas SystemInventors: Martin Poenie, Jessica Jones
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Patent number: 8741109Abstract: A method for purifying a crude acetone raw material containing low molecular weight impurities using two columns is disclosed. Crude acetone raw material is fed into a first column; adding an alkaline reagent and an oxidative agent into the first column to form high molecular weight impurities; removing a top fraction from the first column by distillation to form bottom fraction containing an acetone mixture containing high molecular weight impurities; feeding the bottom fraction containing the acetone mixture obtained to a second rectification column at a charge point on the column; adding an alkaline reagent to the second column above the charge point of the bottom fraction fed; and separating a purified acetone from the high molecular weight impurities and removing the purified acetone as a top fraction by distillation in the second column, wherein the second rectification column is operated at atmospheric pressure.Type: GrantFiled: December 8, 2009Date of Patent: June 3, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Mark Erik Nelson, Andrey Yurievich Sokolov, Ilya Yurievich Krupenko, Valery Yurievich Aristovich
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Patent number: 8592609Abstract: Processes for producing lactide from lactic acid oligomers are described herein. The processes generally include heating a lactic acid oligomer in the presence of a catalyst at a temperature of between 150° C. and 300° C. under a pressure of less than 0.01 MPa to form a lactide; distilling the lactide; and condensing and recovering the lactide, wherein the catalyst is a metal salt of the phosphite anion PO33? in which the metal is selected from the group consisting of tin, aluminum, zinc, titanium and zirconium.Type: GrantFiled: December 19, 2008Date of Patent: November 26, 2013Assignee: Futerro S.A.Inventors: Philippe Coszach, Pierre-Antoine Mariage
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Publication number: 20110155557Abstract: Processes for producing lactide from lactic acid oligomers are described herein. The processes generally include heating a lactic acid oligomer in the presence of a catalyst at a temperature of between 150° C. and 300° C. under a pressure of less than 0.01 MPa to form a lactide; distilling the lactide; and condensing and recovering the lactide, wherein the catalyst is a metal salt of the phosphite anion PO33? in which the metal is selected from the group consisting of tin, aluminum, zinc, titanium and zirconium.Type: ApplicationFiled: December 19, 2008Publication date: June 30, 2011Applicant: FUTERRO S.A.Inventors: Philippe Coszach, Pierre-Antoine Mariage
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Patent number: 7311807Abstract: A process for the separation of dichlorobenzene mixtures containing m- and p-dichlorobenzene in which: (i) the mixture is as an extracting agent contacted with a phosphoric ester of the general formula (I) as an extracting agent in which R1, R2 and R3 are identical or different and represent an aliphatic or cycloaliphatic alkyl or alkenyl radical and R1, R2, and R3 together contain at least 3C-atom and not more than 12 C-atoms, or a mixture of different phosphoric esters (I) of formula or is contacted with a phosphine oxide of the general formula (II) as an extracting agent in which R1, R2 and R3 are identical or different and represent an aliphatic or cycloaliphatic alkyl or alkenyl radical or hydrogen, and R1, R2 and R3 together contain at least 3 C-atoms and not more than 12 C-atoms, or a mixture of different phosphine oxides of formula (II) or a mixture of said phosphoric esters of formula (I) and phosphine oxides of formula (II), and subsequently (ii) the components of the mixture areType: GrantFiled: November 4, 2003Date of Patent: December 25, 2007Assignee: Lanxess Deutschland GmbHInventors: Gültekin Erdem, Morris Leckebusch, Günter Olf, Kay-Jochen Rinck, Günter Zühlke
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Patent number: 6962967Abstract: The subject invention provides polyurethane foam and a method of purifying polyether polyols of non-volatile impurities for use in forming the polyurethane foam. The method includes the step of providing a crude polyether polyol having a non-volatile impurity present therein. The crude polyether polyol is contacted with an adsorbent selected from at least one of activated carbon, diatomaceous earth, charcoal, attapulgite, and clay to remove the impurity and filtered to form a purified polyether polyol. The filtering of the crude polyether polyol is carried out through a filter media that is used both in a pre-filtering step prior to adding the adsorbent and the filtering step to remove the adsorbent to reduce losses of the purified polyether polyol because of its high viscosity. The purified polyether polyol is then used to form a polyurethane foam having improved stability.Type: GrantFiled: March 31, 2004Date of Patent: November 8, 2005Assignee: BASF CorporationInventors: David D. Peters, Jon S. Speier, Alexander Gershanovich
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Patent number: 6685802Abstract: This invention relates to a continuous process and an apparatus (1) for removing dissolved and undissolved solids and/or high boiling point liquid contaminants from a mixture of miscible liquids (9). A recycle liquor stream (6) is fed at high velocity through a heat exchanger having a single flow path (12) and the heat added by the heat exchanger is sufficient to vaporize the feed stream (2) when the recycle liquor and feed stream are mixed upon delivery to the separation vessel (3).Type: GrantFiled: July 2, 2001Date of Patent: February 3, 2004Inventor: Craig Nazzer
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Publication number: 20030089591Abstract: A process for fractionating an amine-containing mixture which comprises one or more amines, water, low-boilers and optionally high-boilers, having the steps (i) to (v):Type: ApplicationFiled: October 17, 2002Publication date: May 15, 2003Inventors: Andreas Wolfert, Heinz Rutter, Stefan Rittinger, Mark Wehinger, Aurelie Alemany, Willi Schmidt
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Publication number: 20030089592Abstract: A process for fractionating an amine-containing mixture which comprises one or more amines, water, low-boilers and high-boilers, having the steps (i) to (iv):Type: ApplicationFiled: October 17, 2002Publication date: May 15, 2003Inventors: Andreas Wolfert, Heinz Rutter, Stefan Rittinger, Mark Wehinger, Aurelie Alemany, Willi Schmidt
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Patent number: 6387224Abstract: A process for the separation by distillation of a mixture of 1,4-butanediol and at least one 4-hydroxybutyraldehyde, its cyclic hemiacetal and its cyclic full acetals with at least one further alcohol by carrying out the distillation in the presence of an alkaline compound. The mixture to be separated preferably contains a cyclic full acetal of 4-hydroxybutyraldehyde with a further alcohol which has a lower boiling point than butanediol and also the further alcohol in free form. The process is particularly suitable for the separation by distillation of mixtures formed in the hydrogenation of maleic acid derivatives.Type: GrantFiled: August 29, 2000Date of Patent: May 14, 2002Assignee: BASF AktiengesellschaftInventors: Rolf Pinkos, Rolf Fischer, Shelue Liang
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Patent number: 5653853Abstract: A process by which iodine compounds contained in crude acetic anhydride or a mixture of crude acetic anhydride and crude acetic acid can be converted into methyl iodide having a low boiling point and which can be separated by distillation and efficiently removed by the combination of the conversion step with the heat treatment step and distillation step. The process includes the steps of heat-treating the crude acetic anhydride or the mixture of crude acetic anhydride and crude acetic acid in the presence of methanol and/or methyl acetate in a treatment tank and distilling the heat-treated crude acetic anhydride or the heat-treated mixture of crude acetic anhydride and crude acetic acid, in the presence of an alkali metal salt and/or an alkaline earth metal salt if necessary.Type: GrantFiled: June 3, 1996Date of Patent: August 5, 1997Assignee: Daicel Chemical Industries, Ltd.Inventors: Masahiro Kagotani, Yasuo Tsuji
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Patent number: 5595634Abstract: A process for treating C.sub.3 to C.sub.12 petroleum fractions, such as a light cracked naphtha to be used as an etherification feed stock in which H.sub.2 S is removed by distillation of at least the C.sub.3 fraction and mercaptans and diolefins are removed simultaneously in a distillation column reactor using a dual catalyst bed. The mercaptans and H.sub.2 S are reacted with the diolefins in the presence of a reduced nickel catalyst to form sulfides which are higher boiling than the portion of the feed which is fractionated to an upper hydrogenation catalyst bed of palladium for hydrogenating diolefins and acetylenes. The higher boiling sulfides are removed as bottoms along with heavier materials. Any diolefins not converted to sulfides and acetylenes are selectively hydrogenated to mono-olefins in the presence of a palladium oxide catalyst in an upper bed, producing overheads, substantially free of sulfur compounds, diolefins and acetylenes.Type: GrantFiled: July 10, 1995Date of Patent: January 21, 1997Assignee: Chemical Research & Licensing CompanyInventors: Dennis Hearn, Gary R. Gildert, Hugh M. Putman
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Patent number: 5522971Abstract: Pure, substantially neutral, low-volatile organic compounds including reactive double bonds are advantageously isolated from a liquid feedstock which contains said compounds in combination with acidic reaction components or auxiliary materials by (i) adding to the feedstock, as neutralizing agents, finely powdered oxides, carbonates and/or hydroxides of the alkali metals and/or alkaline earth metals; (ii) adding, at the same time as the addition of the neutralizing agents or thereafter, a limited amount of water to the mixture of feedstock and neutralizing agents; (iii) mechanically mixing the liquid and solid mixture thus formed for at least a few minutes; (iv) distilling off water from the hot reaction mixture under reduced pressure; and (v) removal from the liquid product of the solid phase now present. Pure products which even without distillation exhibit low residual acid values in combination with low color values result.Type: GrantFiled: June 7, 1994Date of Patent: June 4, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Ritter, Stefanie Ortanderl
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Patent number: 5489366Abstract: A distillation method for the purification of crude propylene oxide containing contaminating quantities of water and methanol by partially purifying the crude propylene oxide in a plural stage distillation zone to provide a vaporized overhead distillate propylene oxide fraction containing a minor contaminating amount of vaporized water, andpassing the propylene oxide vapor fraction through a drying chamber containing a porous hygroscopic solid absorbent to selectively absorb water vapor onto the absorbent,and liquefying and recovering the thus-dehydrated purified propylene oxide.Type: GrantFiled: March 28, 1994Date of Patent: February 6, 1996Assignee: Texaco Chemical Inc.Inventor: Huibert S. Jongenburger
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Patent number: 5395486Abstract: Dehydrated compositions are obtained by: combining a hydrous composition, e.g., a hydrous electrolyte salt, with inert fluorochemical liquid; heating the resulting mixture in a vessel to volatilize water and inert fluorochemical liquid therein until the water content of the mixture is reduced to a desired level; optionally treating the resulting dehydrated mixture with another chemical material, e.g., a polar organic solvent; and optionally subjecting the dehydrated mixture or the treated dehydrated mixture to further treatment, e.g., separation of the mixture. Liquid electrolytes suitable for use in battery applications can be prepared by this method.Type: GrantFiled: October 19, 1993Date of Patent: March 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Michael E. Killian, John C. Stone
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Patent number: 5344528Abstract: Phenol plant waste water containing small amounts of phenol and sodium sulfate is successfully distilled through the addition of recovered sodium sulfate to enhance the volatility of the phenol relative to water; at least a portion of the sodium sulfate is recycled, while a significant portion of the phenol can be returned to the phenol plant for recovery.Type: GrantFiled: August 4, 1993Date of Patent: September 6, 1994Assignee: Aristech Chemical CorporationInventors: Thomas H. Bossler, Donald Glassman, Michael C. Grebinoski, Howard H. Morgan, Jr., Jennifer L. Voss
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Patent number: 5340445Abstract: Diaminodiphenyl-compounds of the structure selected from: ##STR1## wherein R.sub.1 and R.sub.2 can be: H, --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7, --C.sub.4 H.sub.9 or ##STR2## Y can be: C(CH.sub.3).sub.2, ##STR3## n=0; 1. are purified by distilling the crude product obtained under vacuum in one step, in the presence of one or more alkaline bases.Type: GrantFiled: June 11, 1992Date of Patent: August 23, 1994Assignee: Bromine Compounds Ltd.Inventors: Joshua Hermolin, Hugo Keselman, Jacob Oren
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Patent number: 5306398Abstract: Waste acetic acid, which is contaminated by nitrogen compounds and also by hardly hydrolyzable halogen compounds, is purified by adding a complex-forming metal or one of the compounds thereof and a basic compound. The resultant mixture is kept at a temperature between 25.degree. and 118.degree. C. over a period of time of 1 to 6 hours. Finally, purified acetic acid is removed from the mixture by distilling.Type: GrantFiled: November 19, 1992Date of Patent: April 26, 1994Assignee: Hoechst AktiengesellschaftInventors: Andreas Seidel, Alfred Hauser, Erhard Jagers
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Patent number: 5158651Abstract: A process for removing inorganic compounds from glycol recovery still bottoms resulting from the manufacture of poly(ethylene terephthalate), the novel process using a small amount of phosphoric acid to precipitate the antimony and then removing the titanium dioxide and antimony compound by a centrifuge. The novel process for removing the inorganic compounds from the recovery polyester bottoms includes the steps of distilling ethylene glycol from the spent glycol until the remaining bottoms have a solids concentration from about 15% to about 45%; adding phosphoric acid to the bottoms to form an antimony compound and removing the antimony and titanium precipitates from the bottoms by a centrifuge.Type: GrantFiled: June 11, 1990Date of Patent: October 27, 1992Assignee: Hoechst Celanese CorporationInventor: Marvin L. Doerr
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Patent number: 5124004Abstract: A method of distillation employing a heat pump (which may be driven by a compressor) using a vapor stream from within the distillation system as a heat source and a liquid stream from within the distillation system as a heat sink. The selection of heat-source vapors and heat-sink liquid is such that at least one is withdrawn from the phase-contracting region of the distillation system. The return of streams withdrawn from the phase-contacting region of the distillation system to the distillation system is such that at least one of the streams is returned at a temperature different from that of the point from which it was withdrawn, and all withdrawn streams are returned in manner such that a stream removed as vapor is returned at a point with a temperature at most that at the point it was withdrawn, and a stream removed as liquid is returned at a point with a temperature at least that at which it was withdrawn.Type: GrantFiled: February 6, 1990Date of Patent: June 23, 1992Assignee: Trustees of Dartmouth CollegeInventors: Hans E. Grethlein, Lee R. Lynd
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Patent number: 5104491Abstract: Crude pentachloronitrobenzene containing hexachlorobenzene and small amounts of acids is treated in the molten state or in a mixture solution of nitrobenzene or chloronitrobenzenes with an inorganic basic substance and then subjected to a distillation under reduced pressure.Type: GrantFiled: March 12, 1991Date of Patent: April 14, 1992Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Mitsumasa Umemoto, Ryuichi Mita, Yoshitsugu Kono, Hiroshi Maeda
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Patent number: 5094720Abstract: A method is disclosed for enhancing the purification of citral by fractional distillation by inhibiting the formation of isocitrals from isomerization of citral during the distillation process. The method involves reducing the pH of a mixture containing citral to inhibit the formation of isocitrals from citral upon heating, such as in distillation. Lowering the pH below 7 reduces formation of isocitrals, but a pH of about 4 to 5 is especially preferred. Most preferably, this pH adjustment is accomplished by addition of an acid with a pKa between about 4 and 5.Type: GrantFiled: October 18, 1990Date of Patent: March 10, 1992Assignee: Union Camp CorporationInventor: David E. Sasser
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Patent number: 5091057Abstract: A process for obtaining a substantially dry alcohol from a mixture comprising alcohol and water in a non-azeotropic amount by utilizing at least a portion of the alcohol in the mixture as the stripping medium.Type: GrantFiled: July 20, 1990Date of Patent: February 25, 1992Assignee: Ethyl CorporationInventor: Wayne D. Jensen
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Patent number: 5091058Abstract: Method of preparing para-cumylphenol including reacting an excess of phenol with alpha-methylstyrene by the slow addition of alpha-methylstyrene to a 50% to 200% molar excess of phenol at a temperature from about 80.degree. C. to about 90.degree. C. in the presence of an acid catalyst and thereafter maintaining the temperature at about 95.degree. to about 100.degree. C. to obtain a crude cumylphenol reaction product containing acid derived from the catalyst, and distilling the reaction product in the presence of an amount of base sufficient to neutralize the acid therein.Type: GrantFiled: January 25, 1991Date of Patent: February 25, 1992Assignee: Aristech Chemical CorporationInventor: William R. Davie
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Patent number: 5047580Abstract: The purpose of the process of the present invention is to remove excess sulfuric acid from a mixture of paraffin-sulfonic acids free or substantially free, from paraffins.In order to remove said sulfuric acid, according to the process of the present invention, the paraffin-sulfonic acid mixture is mixed with one or more halogenated solvent(s), possibly in mixture with sulfuric acid to form a two phase mixture consisting of an organic phase containing paraffin-sulfonic acids dissolved therein and an aqueous phase substantially containing sulfuric acid. The organic phase is then treated with sulfuric acid and the organic phase and aqueous phase are then separated and the organic phase is submitted to evaporation, for the removal of the halogenated solvent(s), and with the concentrated paraffin-sulfonic acids being obtained.Type: GrantFiled: March 22, 1990Date of Patent: September 10, 1991Assignees: Eniricerche S.p.A., Enichem Augusta S.p.A.Inventors: Lucio Faggian, Enrico Borgarello, Cosimo Franco, Gerardo Carrillo
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Patent number: 4994150Abstract: The present invention provides a process to recover esters of mercapto acids from solutions containing water by mixing an extraction mixture comprising cycloalkane, arene, and an aqueous inorganic salt solution with an ester of mercapto acid and water solution followed by separating and distilling the resultant organic phase to recover the ester of mercapto acid.Type: GrantFiled: August 24, 1989Date of Patent: February 19, 1991Assignee: Phillips Petroleum CompanyInventor: James E. Shaw
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Patent number: 4964957Abstract: A process for preventing the substantial decomposition of an alkyl sulfide compound at high temperatures comprising combining a non-reactive basic compound with the alkyl sulfide compound prior to subjecting the resultant mixture to the high temperatures.Type: GrantFiled: December 6, 1988Date of Patent: October 23, 1990Assignee: Phillips Petroleum CompanyInventors: James E. Shaw, John S. Roberts
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Patent number: 4963232Abstract: Provided by this invention is a process for producing a purified hydrazine hydrate having a low total organic carbon concentration and which involves:a first step which includes distilling an aqueous solution of hydrazine hydrate in the presence of at least one salt selected from the group consisting of chloride, sulfate, phosphate and carbonate of (a) the metals of Group Ia and IIa of the Periodic Table of the Elements, (b) ammonium or (c) hydrazinium to concentrate the aqueous solution of hydrazine hydrate by distilling water and the majority of the total organic carbon constituents off and separating the resultant concentrate as a bottom product, anda second step which includes distilling the resultant concentrate to recover a purified aqueous solution of hydrazine hydrate as a top product and separating an aqueous solution of the above salt as a bottom product.Type: GrantFiled: May 22, 1989Date of Patent: October 16, 1990Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yasuhisa Kuriyama, Shuuzabu Sakaguchi, Toshiaki Kohzaki, Syoichi Nito
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Patent number: 4961826Abstract: A method of distillation employing a heat pump (which may be driven by a compressor) using a vapor stream from within the distillation system as a heat source and a liquid stream from within the distillation system as a heat sink. The selection of heat-source vapors and heat-sink liquid is such that at least one is withdrawn from the phase-contacting region of the distillation system. The return of streams withdrawn from the phase-contacting region of the distillation system to the distillation system is such that at least one of the streams is returned at a temperature different from that of the point from which it was withdrawn, and all withdrawn streams are returned in manner such that a stream removed as vapor is returned at a point with a temperature at most that at the point it was withdrawn, and a stream removed as liquid is returned at a point with a temperature at least that at which it was withdrawn.Type: GrantFiled: August 19, 1986Date of Patent: October 9, 1990Assignee: Trustees of Dartmouth CollegeInventors: Hans E. Grethlein, Lee H. Lynd
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Patent number: 4915794Abstract: This invention relates to a process for producing an olefin product having an enhanced alpha olefin content from an olefin feedstock containing internal olefins or a mixture of internal and alpha olefins which includes:(a) contacting the feedstock with an anthracene and a double-bond isomerization catalyst at a temperature ranging from about 150.degree. to about 275.degree. C. to form an olefin adduct with anthracene,(b) separating the adduct from the product of step (a),(c) heating the separated adduct at a temperature ranging from about 250.degree. to about 400.degree. C. to produce anthracene and an olefin product enhanced in alpha olefin content over the alpha olefin content of the feedstock, and(d) separating anthracene from the product of step (c) to produce the product enhanced in alpha olefin.Linear olefins are a preferred feedstock.Type: GrantFiled: October 27, 1988Date of Patent: April 10, 1990Assignee: Shell Oil CompanyInventors: Lynn H. Slaugh, Howard L. Fong
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Patent number: 4898644Abstract: A process for removing volatile acids from aqueous solutions which involves steam stripping a volatile acid from an aqueous solution and contacting the vaporized acid with a reactable cation to form a salt of the acid. A preferred embodiment of apparatus comprises an elongated distillation column having therein a plurality of zones or stages wherein the volatile acid in the aqueous feed stream is vaporized by steam and then the vaporized acid is carried by the steam into a salt formation zone or stage to react with a reactable cation to form a salt of the acid.Type: GrantFiled: May 2, 1988Date of Patent: February 6, 1990Assignee: QO Chemicals, Inc.Inventor: Wendell E. Van Horn
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Patent number: 4765869Abstract: A continuous process is described for the production of a substantially acid free dialkyl maleate, for example diethyl maleate, from a feed stream containing a major amount of dialkyl maleate and a minor amount of the corresponding monoalkyl maleate. This comprises continuously distilling the feed stream in a primary distillation zone, which can comprise a single distillation column or a series of distillation columns connected in series, so as to give (i) a bottom fraction containing monoalkyl maleate and dialkyl maleate in admixture, (ii) a vaporous fraction comprising alkanol, and (iii) an intermediate fraction that is substantially free from alkanol and comprises a major proportion of diethyl maleate and a minor proportion of maleic anhydride. The intermediate fraction (iii) is redistilled in a secondary distillation zone to yield (i) an overhead fraction containing maleic anhydride and (ii) a bottom fraction containing substantially acid free dialkyl maleate.Type: GrantFiled: July 31, 1987Date of Patent: August 23, 1988Assignee: Davy McKee (London) LimitedInventors: Norman Harris, Colin Rathmell, Keith Turner, John Scarlett
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Patent number: 4755262Abstract: This invention relates to a method for the purification of glycidyl acrylate or glycidyl methacrylate. Specifically, the invention effects the purification by using a residual catalyst-inactivating additive and consequently produces highly purified glycidyl acrylate or glycidyl methacrylate containing substantially no epichlorohydrin and having a low chlorine content.Type: GrantFiled: October 26, 1987Date of Patent: July 5, 1988Assignee: Osaka Yuki Kagaku Kogyo Kabushiki KaishaInventors: Mitsumasa Matsunaga, Yukio Tanaka, Akio Tani, Shigeaki Matsumoto
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Patent number: 4716244Abstract: If the transesterification of esters of formula II ##STR1## with alcohols of formula III A--OH).sub.m is catalysed by treatment with catalytic amounts of an organic or inorganic zinc salt and the resultant melt is subsequently distilled in a short-time distillation apparatus under specific conditions, then compounds of the formula ##STR2## are obtained in virtually quantitative yield, in which formulae I, II and III n is a number from 0 to 2, m is 1 or 2, A is a radical derived from an m-valent aliphatic alcohol, which radical contains 2 to 18 carbon atoms, B is methyl or tert-butyl and R is methyl or ethyl. The products thus obtained contain no troublesome by-products and do not have to be additionally purified.Type: GrantFiled: April 21, 1986Date of Patent: December 29, 1987Assignee: Ciba-Geigy CorporationInventor: Ivan Orban
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Patent number: 4548701Abstract: A method for recovery of extraction solvent from a dissolved solute wherein halogen gas evolution and halogen compound retention in the solute are minimized comprises heating a solution of a halogenated organic solvent and the extracted solute in the presence of an ammonium, Group I metal or Group II metal salt of an acid of carbon number 1 to 6, such as ammonium bicarbonate, ammonium carbonate, ammonium formate, sodium carbonate, sodium formate, or calcium formate, to recover the solvent and the solute.Type: GrantFiled: December 19, 1983Date of Patent: October 22, 1985Assignee: Amoco CorporationInventor: William F. Wolff
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Patent number: 4433194Abstract: Solvents which may be used as mediums for the polymerization of olefinic hydrocarbons to form polymers useful as membranes in a gas separation process require purification to remove any impurities which will effect the aforesaid polymerization. Purification of these solvents such as cyclohexane may be effected by treating the solvent with titanium tetrachloride, contacting the solution with an adsorbent such as silica gel and thereafter distilling the solvent in the presence of a purification agent such as an alkaline metal aluminum hydride or borohydride.Type: GrantFiled: May 6, 1983Date of Patent: February 21, 1984Assignee: UOP Inc.Inventors: Ted Symon, Dusan J. Engel
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Patent number: 4404063Abstract: A method for the separation of indole by distilling an indole-containing reaction fluid obtained by the reaction of aniline with ethylene glycol or by the reaction of N-(.beta.-hydroxyethyl)aniline, which comprises bringing the reaction fluid into contact with a basic substance prior to and/or during the distillation. This method can prevent the deterioration of indole during the distillation procedure.Type: GrantFiled: September 24, 1982Date of Patent: September 13, 1983Assignee: Mitsui Toatsu Chemicals, Inc.Inventor: Tadatoshi Honda
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Patent number: 4401516Abstract: Acetamidoethylene is isolated from acetamidoethylene-containing mixtures by distillation with enhanced efficiency when a high-boiling liquid, especially glycerol, is added to the mixtures prior to or during said distillation. This invention is particularly effective at separating acetamidoethylene from mixtures additionally containing acetamide, especially preparation products.Type: GrantFiled: November 24, 1981Date of Patent: August 30, 1983Assignee: Dynapol Shareholders Liquidating TrustInventor: David P. Matzinger
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Patent number: 4400241Abstract: A novel composition, and extraction process for the dehydration of a hydrated aliphatic, monohydric alcohol to produce a fuel grade alcohol. A select group of alkali-metal and alkaline-earth metal salts are added to and dissolved within a low volatility polyhydric alcohol to form a solution, or solvent extractant, and said solvent extractant contacted and dissolved within said aliphatic, monohydric hydrated alcohol, the solvent extractant distilled, condensed, and a dehydrated fuel grade aliphatic monohydric fuel grade alcohol recovered.Type: GrantFiled: July 20, 1981Date of Patent: August 23, 1983Assignee: ImprotecInventors: David G. Braithwaite, Thomas Cheavens, Jason M. Voyce
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Patent number: 4384924Abstract: A method of separating acids or bases from vapors which are conveyed along with distillation vapors during concentration of a solution, comprising, passing said distillation vapors containing an acid or base, while being maintained at their existing pressure and temperature, through a salt solution which boils at said temperature and pressure, wherein, if an acid is to be removed from the distillation vapors, the salt solution contains a salt having an anion corresponding to that of the acid while being supplied with a base in an amount required to neutralize the acid, the cation of the base proportion corresponding to that of the salt, while, if a base is to be removed from the distillation vapors, the salt solution contains a salt having a cation corresponding to that of the base while being supplied with an acid in an amount required to neutralize the base in the distillation vapors, the anion of the acid corresponding to that of the salt so that salts are formed during neutralization which correspond to tType: GrantFiled: July 14, 1980Date of Patent: May 24, 1983Inventor: Matthias Thoma
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Patent number: 4381222Abstract: A process for the distillative separation of tertiary alkyl hydroperoxides of the formulaR--OOHwhereinR is a tertiary alkyl group with 4 to 6 carbon atoms from the corresponding di-tertiary alkyl peroxides resulting during their preparation, which process comprises neutralizing the reaction mixture resulting during the preparation of the tertiary alkyl hydroperoxide, subjecting same to vacuum distillation in the presence of water at a temperature of less than about 45.degree. C. and recovering the purified tertiary alkyl hydroperoxide as a bottoms product.Type: GrantFiled: October 27, 1981Date of Patent: April 26, 1983Assignee: Peroxide-Chemie GmbHInventors: Gottfried Brossmann, Fritz Diem
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Patent number: 4360407Abstract: The distillative separation of a mixture of glycerine and glycerine-based acetal or ketal transesterification products is aided by addition of a borate ester-forming compound to the mixture prior to distillation.Type: GrantFiled: March 22, 1982Date of Patent: November 23, 1982Assignee: The Dow Chemical CompanyInventor: Robert L. Reierson
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Patent number: 4358360Abstract: Halogenated hydrocarbon and uncontaminated water is recovered from a stream of process water contaminated with halogenated hydrocarbon and hydrogen halide. The process water is neutralized and then distilled to obtain a first fraction containing halogenated hydrocarbon and water and a second fraction containing uncontaminated water. The first fraction is allowed to settle into layers of halogenated hydrocarbon and water which are then removed.The contaminated stream may be obtained from a process for the solvent dewaxing of a petroleum fraction.Type: GrantFiled: July 16, 1980Date of Patent: November 9, 1982Assignee: British Petroleum Company LimitedInventor: Ferdinand Richter
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Patent number: 4349417Abstract: Ethylene oxide and water are reacted in a reactor and the reaction product is subjected to distillation in a plurality of distillation columns, in the first columns water and components having a boiling point below that of monoethylene glycol and higher ethylene glycols, if any, being distilled off. To obtain extremely pure monoethylene glycol alkali metal compounds are added at a point between the reactor and the monoethylene glycol distillation column in an amount to adjust the pH of the product entering the latter column to a value of from 7 to 10. The monoethylene glycol obtained in this manner is especially pure and has very low UV absorption values. It is, therefore, especially suitable for the manufacture of polyester fibers.Type: GrantFiled: January 9, 1981Date of Patent: September 14, 1982Assignee: Hoechst AktiengesellschaftInventors: Siegfried Rebsdat, Sigmund Mayer, Josef Alfranseder, Iwo Schaffelhofer
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Patent number: 4311597Abstract: A method of removing ammonia from a wastewater containing free and fixed ammonia said process comprising the steps of: distilling the wastewater to remove the free ammonia; treating the distilled wastewater with soda ash to decompose the fixed ammonia; and distilling the treated wastewater to remove the decomposed ammonia.An apparatus for removing ammonia from a wastewater containing free and fixed ammonia comprising: an ammonia still for removing free and fixed ammonia; a source of soda ash solution; and means for feeding the soda ash solution from said soda ash source to the ammonia still to decompose the fixed ammonia.Type: GrantFiled: February 21, 1979Date of Patent: January 19, 1982Assignees: Republic Steel Corporation, The Hanna Furnace CorporationInventor: Aniruddha Bhattacharyya
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Patent number: 4306943Abstract: Crude liquid polyether-polyols containing an alkaline catalyst are purified by the steps of:neutralizing said crude liquid polyether-polyol with a mineral acid having a dissociation constant of greater than 10.sup.-3 at 25.degree. C.distilling off water from said liquid, and filtering the same. The improvement resides in the step of adding a hydrate of a metal salt of said mineral acid to the liquid polyether-polyol at a stage before the distillation step for promoting the crystal growth of a salt formed from said alkaline catalyst by the neutralization.Type: GrantFiled: March 12, 1981Date of Patent: December 22, 1981Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Shigeo Mori, Takeshi Fujita
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Patent number: 4304639Abstract: A process for the purification of olefine oxides by subjecting a mixture containing the olefine oxides to distillation in a distillation column in the presence of a small amount of water in order to obtain olefine oxide as the distillate. A fraction of the down-flow liquid is withdrawn from the column and the withdrawn fraction is subjected to decantation, so as to separate off an aqueous phase which is discarded, and an organic phase. The organic phase is returned to the column at a point located below the withdrawal point.Type: GrantFiled: April 7, 1980Date of Patent: December 8, 1981Assignee: Propylox (Societe Anonyme)Inventors: Nicolas Hardy, Teddy Durieux
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Patent number: 4271013Abstract: A method for removing biodegradable compounds selected from the group comprising: phenolics, free and fixed ammonia compounds, thiosulfates, cyanides, thiocyanates, sulfides and the like from a feed wastewater. The method comprises the steps of treating the feed wastewater by adding soda ash thereto; and further treating the wastewater by means of an activated sludge treatment in a sludge reactor to reduce the level of biodegradable compounds in the wastewater.A method for removing biodegradable compounds selected from the group comprising phenolics, free and fixed ammonia compounds, thiosulfates, cyanides, thiocyanates, sulfides and mixtures thereof from a feed wastewater comprising the steps of: treating the feed wastewater with an inorganic carbon source; and further treating the wastewater by means of a single-stage activated sludge treatment in a sludge reactor to reduce the level of said biodegradable compounds in the wastewater.Type: GrantFiled: April 24, 1979Date of Patent: June 2, 1981Assignees: Republic Steel Corporation, The Hanna Furnace CorporationInventor: Aniruddha Bhattacharyya