Abstract: According to one embodiment, a photochemical reaction system comprises a CO2 production unit, a CO2 absorption unit, and a CO2 reduction unit. The CO2 reduction unit comprises a laminated body and an ion transfer pathway. The laminated body comprises an oxidation catalyst layer producing O2 and H+ by oxidizing H2O, a reduction catalyst layer producing carbon compounds by reducing CO2 absorbed by the CO2 absorption unit, and a semiconductor layer formed between the oxidation catalyst layer and the reduction catalyst layer and develops charge separation with light energy. The ion transfer pathways make ions move between the oxidation catalyst layer side and the reduction catalyst layer side.

Abstract: A water treatment system including: a flow regulation control system configured to combine oxo-anion-contaminated water with a reduction-promoting agent, a hole scavenger, or both; a reactor fluidically coupled to the flow regulation control system; a first set of system control probes configured to monitor the concentration of oxygen and oxo-anion in the contaminated water; a second set of system control probes configured to monitor concentration of the oxo-anion and reduction products of the oxo-anion in treated effluent from the reactor; and a controller configured to control the flow regulation control system, thereby controlling the flow rate of the contaminated water and the at least one of the reduction-promoting agent and the hole scavenger to the reactor based at least in part on the concentration of oxo-anion and the reduction products of the oxo-anion in the treated effluent.

Abstract: Methods, kits, cartridges and compounds related to generating chlorine dioxide by exposing ClO2? to at least one of a manganese porphyrin catalyst or a manganese porphyrazine catalyst are described. Methods, kits, cartridges and compounds related to decomposed cyanide ions and hydrogen cyanide for water decontamination.

Abstract: Known methods for hydrothermal carbonization are very time intensive, as the carbonization reaction only proceeds gradually in the biomass used therefor. This is because of the different reaction conditions prevailing in different parts of the biomass. These also cause an inhomogeneous reaction product. To accelerate the method and to improve the result, the biomass is swirled inside the available reaction space with the aid of blower nozzles, which blow in the steam at a high speed so that the biomass is swirled. This ensures that the carbonization reaction can proceed uniformly and promptly after the biomass is introduced.

Abstract: Provided is a purification method for efficiently reducing an undesirable organic compound or compound in (E)-1-chloro-3,3,3-trifluoropropene and thereby obtaining (E)-1-chloro-3,3,3-trifluoropropene with high purity. The purification method of OF-1233E according to the present invention is characterized by bringing a composition containing OF-1233E and at least one organic compound selected from the group consisting of HCFC-142 isomers, HCFC-244fa, HFC-245fa, OF-1234E, OF-1234Z and OF-1233Z into contact with a solid adsorbent.

Abstract: Provided in this invention is a process for producing chemically functionalized nano graphene materials, known as nano graphene platelets (NGPs), graphene nano sheets, or graphene nano ribbons. Subsequently, a polymer can be grafted to a functional group of the resulting functionalized graphene. In one preferred embodiment, the process comprises a step of mixing a starting nano graphene material having edges and two primary graphene surfaces, an azide or bi-radical compound, and an organic solvent in a reactor, and allowing a chemical reaction between the nano graphene material and the azide compound to proceed at a temperature for a length of time sufficient to produce the functionalized nano graphene material.

Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.

Abstract: The invention relates to a method for producing hexachlorodisilane or Ge2CI6, which is characterized in that, in a gas containing SiCI4 or GeCI4, a) a non-thermal plasma is generated by means of an alternating voltage of the frequency f, and wherein at least one electromagnetic pulse having the repetition rate g is coupled into the plasma, the voltage component of which pulse has an edge steepness in the rising edge of 10 V ns-1 to 1 kV ns-1 and a pulse width b of 500 ns to 100 ?s, wherein a liquid phase is obtained, and b) pure hexachlorodisilane or Ge2Cl6 is obtained from the liquid phase.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.

Abstract: A method of producing HCl from H2 and Cl2 is provided. In some embodiments, the method comprises at least one photochemical chamber placed in fluid communication with at least one source of H2 and at least one source of Cl2. In some embodiments, the photochemical chamber effects the formation of HCl through the use of at least one source of ultraviolet radiation contained therein. In some embodiments, the HCl product may be captured and used as a gas. In some embodiments, the HCl product may be absorbed into water to form an aqueous HCl solution.

Abstract: A method of producing [18F]F2 from [18F] fluoride through a plasma induced scrambling procedure is provided. The present invention also provides an apparatus for preparing [18F]F2 from [18F] fluoride in a plasma induced scrambling procedure. Kit claims for preparing [18F]F2 from [18F] fluoride in a plasma induced scrambling procedure as well as method of use and use of claims for preparing [18F]F2 from [18F] fluoride through a plasma induced scrambling procedure are also provided.

Abstract: High energy reaction of halogen-containing carbon, boron, silicon and nitrogen compounds, with base component comprising at least one atom selected from Groups IA to VIA, transition metals, lanthanides and actinides of the Periodic Table of the Elements, excluding aluminum and aluminum oxide.

Abstract: The invention relates generally to chemical reactions and processes, and in particular to a method for enhancing the rate of a chemical reaction and to apparatus for carrying out the method. The invention more particularly relates to methods and apparatus which utilize microwave and ultrasonic energy to enhance chemical reaction rates; and in specific instances, the invention relates to methods, processes and apparatus for the synthesis of biodiesel fuels. The methods, processes and apparatus of the invention are useful for the synthesis of biodiesel fuels; and also useful for production of reaction products of esterification and/or transesterification reactions including fatty acid alkyl esters.

Abstract: A method of producing HCl from H2 and Cl2 is provided. In some embodiments, the method comprises at least one photochemical chamber placed in fluid communication with at least one source of H2 and at least one source of Cl2. In some embodiments, the photochemical chamber effects the formation of HCl through the use of at least one source of ultraviolet radiation contained therein. In some embodiments, the HCl product may be captured and used as a gas. In some embodiments, the HCl product may be absorbed into water to form an aqueous HCl solution.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.

Abstract: Methods and compositions to a clathrate that includes chlorine dioxide (ClO2) are provided. Clathrates trap gaseous chlorine dioxide to provide a dry solid material that is stable and easy to use and handle. Stable formulations of gaseous chlorine dioxide are useful as disinfectants.

Abstract: The invention consequently relates, in one aspect, to a process for obtaining a hydrofluoroalkane comprising at least two carbon atoms, which is purified of unsaturated organic impurities, according to which the hydrofluoroalkane containing organic impurities including (chloro)fluoro olefins is subjected to at least one purification treatment with bromine or BrCl, preferably in the presence of, an initiator. The process is suitable, for example, to purify 1,1,1,2-tetrafluoroethane. A further aspect concerns the application of LEDs or OLEDs to support chemical reactions of the gas-gas, liquid-liquid or gas-liquid type, and a respective reactor.

Abstract: Methods and compositions to produce chlorine dioxide by reacting one or more reactants under the presence of polarized ultraviolet radiation, an electromagnetic field (EMF), successive chambers, and coiled configurations are disclosed. Polarized ultraviolet radiation and EMF favor the formation of chlorine dioxide and reduces the reversible reactions.

Abstract: The present application provides Ag/AgCl based reference electrodes having an extended lifetime that are suitable for use in long term amperometric sensors. Electrochemical sensors equipped with reference electrodes described herein demonstrate considerable stability and extended lifetime in a variety of conditions.

Abstract: A transportable gas sterilization unit having a chamber, a disposable gas generator utilizing chlorine dioxide as a sterilant, chemical quencher and a detector and a method of using the unit and to generate chlorine dioxide for medical instrument sterilization or disinfection. A two photon, photo-activated chlorine dioxide system and coatings utilizing chlorine dioxide as at least one sterilant material, and methods for coating medical instruments with the photo activated chlorine dioxide system.

Abstract: Process for the production of hydrogen by the thermochemical route from water, based on the chlorine/cerium cycle, in which, according to a first reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; ??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; ??(B) 2CeCl3+4H2O=2CeO2+6HCl+H2; ??(C) or in which, according to a second reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; ??(A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; ??(B) 2CeCl3+2H2O=2CeOCl+4HCl; ??(B?) 2CeOCl+2H2O=2CeO2+2HCl+H2; ??(C?) and in which the reaction (B) for the chlorination of cerium oxide is carried out in the liquid phase, the cerium chloride passing into solution.

Abstract: The present invention provides a system for continuously and efficiently producing low concentrations of aqueous chlorine dioxide from a dilute continuous feed stream of aqueous chlorite.

Abstract: Element halides are prepared in high yield by contacting an element or compound thereof and carbon or a carbon source with a gas stream containing a halogen or halogen compound in the gaseous state, and heating by means of an alternating magnetic field.

Abstract: An electrolytic cell combined into a unitary structure with a liquid circulation fitting, which purifies water by electrode plates inside the cell when an aqueous solution is present. The unitary structure replaces the existing water return fitting. This integrated structure is well suited for use in pools, tubs, spas, fountains or similar large liquid containers. The production of halogen inside the structure is not required to coincide with the cycle of the existing pool filtration system. Rather, the electrodes receive a continuous supply of low level power and the halogen produced inside the structure is disbursed back into the body of water through the fitting using an integrated, dedicated circulation pump, special channels in the surface and a check valve to insure one directional flow from the pool pump and natural convection. Using fresh water drawn from the vessel, halogen is then disbursed back into the vessel with the water at a location different from where the fresh water was drawn.

Abstract: A system for in-situ generation of fluorine radicals and/or fluorine-containing interhalogen compounds XFn (wherein X is Cl, Br, or I, and n is an odd integer). Such system comprises a fluorine source, a halogen source for supplying halogen species other than fluorine, a chamber for mixing fluorine with halogen species other than fluorine, and an energy source to supply energy to such chamber to facilitate reaction between fluorine and the halogen species other than fluorine. The chamber may be a semiconductor processing chamber, wherein the in situ generated fluorine radicals and/or fluorine-containing interhalogens are employed for cleaning the processing chamber.

Abstract: A method for processing substances to be degraded is provided. The method includes a decomposing step in which a mixed gas containing chlorine and the substances to be degraded is irradiated with light to decompose the substances to be degraded, a contact step in which gas generated through the decomposing step is contacted with an alkaline solution to trap chlorine contained in the gas generated through the decomposing step in the alkaline solution, and a reusing step in which the alkaline solution containing the chlorine as a source of generating the chlorine is used again in the decomposing step.

Abstract: There is provided a method of treating a substance to be degraded comprising the steps of: degrading the substance to produce a degraded product; contacting the product obtained in the degrading step with a liquid; and entrapping a component of the product not trapped by the liquid in a medium by contacting the component with the medium. Also, the apparatus for conducting the method is provided.

Abstract: According to the present invention, provided are a method whereby a sterilization/deodorization gas is supplied by irradiating a stabilized chlorine dioxide gel or liquid with ultraviolet radiation, and a sterilization/deodorization gas supply apparatus which comprises: a chemical container used to hold a chemical gel or liquid which is used for sterilization and deodorization, and as an insecticide or an insectifuge; an ultraviolet radiation unit for projecting ultraviolet radiation onto the chemical and for generating a dispersed gas; and a gas discharge unit for extracting from the chemical container gas elements that are to be dispersed by the ultraviolet radiation unit. With this arrangement, a chlorine dioxide gas that can effectively perform sterilization and deodorization can be easily and safely stored, handled and supplemented by employing the chemical reactive propagative effects of ultraviolet radiation.

Abstract: A photochemical process for removing or minimizing the concentration of PCDD or PCDF compounds within an industrial gas stream. The process includes the direct photolysis of PCDD or PCDF compounds. Light within a particular spectral range is irradiated into the gas stream and is absorbed by the PCDD and PCDF compounds in the presence of a hydrogen donor and this results in producing a lower chlorinated PCDD or PCDF compound form. In addition, the gas stream may be treated by removing particular matter therefrom and thereafter subjected to the above-described irradiation. Further, as another optional step, the gas stream may be irradiated with the specific purpose of targeting PCDD and PCDF precursor compounds. In this case, the irradiation is absorbed the precursor compounds causing them to be chemically modified to different chemical compounds that do not participate in chemical reactions that result in the formation of PCDD and PCDF compounds.

Abstract: In accordance with the present invention, a catalyst is described which comprises at least one metal selected from the group consisting of copper, zinc, iron, tungsten, molybdenum, and chromium distributed over a catalyst support comprising a material containing at least one of silicon, titanium, zirconium, magnesium, aluminum, and activated carbon. The catalyst is used to remove phosgene from a contaminated gas stream and/or reduce or eliminate phosgene from an effluent of a previously treated gas stream. At least one metal in the catalyst of the present invention is preferably present in an amount from about 0.001 wt % to about 15 wt %. When more than one metal is present, the combined metals preferably do not exceed 20 wt %. Catalysts in accordance with the present invention may be used as Photocatalysts. Processes for using the catalysts and Photocatalysts of the present invention are also described.

Abstract: The invention relates to a method for decomposing bromate ions contained in a liquid. The method includes the sequential steps of bringing the liquid into contact with a photocatalyst; and irradiating the photocatalyst with a light ray having an energy that is not lower than that of a band gap of the photocatalyst, thereby generating a photocatalytic reaction to decompose the bromate ions. The invention further relates to an apparatus for decomposing bromate ions contained in a liquid. The apparatus includes a first section for generating therein a photocatalytic reaction to decompose the bromate ions; a photocatalyst adapted to be brought into contact with the liquid in the first section; and a light source for irradiating the photoacatalyst with the light ray such that the photocatalytic reaction is generated in the first section when the photocatalyst is in contact with the liquid.

Abstract: Compounds containing a primary amino group are converted into compounds containing a fluorine atom in place of the amino group by reaction of the amino compound with hydrogen fluoride and a nitrosating reagent under the influence of ultrasound or microwaves.

Abstract: A process comprises passing a contaminated gaseous stream through a photocatalytic stage and, thereafter, through a catalytic stage.