Resolving Emulsion Or Dispersion Patents (Class 204/563)
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Patent number: 11002409Abstract: A gas and liquid separation system could be said to have a passage with an inlet connected to receive a mixed gas and liquid flow. An air separation tube extends into the passage at a location downstream of where the inlet is connected with an upstream tube end upstream in the passage relative to a downstream tube end. The upstream tube end provides an obstruction to the mixed gas and liquid flow, to cause separation of the gas from the mixed gas and liquid flow. A liquid tube is connected to the passage at a location downstream of the air separation tube.Type: GrantFiled: January 7, 2019Date of Patent: May 11, 2021Assignee: Hamilton Sundstrand CorporationInventors: Matthew Allen Slayter, Jeff A. Brown
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Patent number: 10786757Abstract: Certain embodiments may generally relate to systems and methods for developing and improving compact electrocoalescers for in-line dehydration of water-in-oil dispersions. A compact electrocoalescer may include a casing, and a plurality of bare or insulated conical-shaped electrodes housed in the casing. The electrodes may include a metal mesh structure. The electrodes may also be truncated at the apex, and alternatively connected to a power supply and ground. The electrodes may further be stacked in a manner such that at least one electrode is at least partially nested within at least another electrode.Type: GrantFiled: November 17, 2017Date of Patent: September 29, 2020Assignees: QATAR UNIVERSITY, UNIVERSITY OF LEEDSInventors: Aboubakr M. Abdullah, Vincenzino Vivacqua, Mohammed J. Al-Marri, Barry Azzopardi, Bijan Kermani, Ali Hassanpour, Buddhika Hewakandamby, Mojtaba Ghadiri
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Patent number: 10537900Abstract: An electrocyclonic particle collector (EPC) for removing particulate matter from a gas includes an EPC gas inlet, an EPC gas outlet, and an EPC gas flow path between the EPC gas inlet and the EPC gas outlet. A first section is downstream of the EPC gas inlet and includes a first cyclonic particle collector in the gas flow path for cyclonically removing particles from the gas. A second section is in series with the first section and includes a rotational flow chamber in the gas flow path, and at least a first electrode in the gas flow path for facilitating electrostatic removal of particles from the gas stream in the rotational flow chamber.Type: GrantFiled: January 12, 2016Date of Patent: January 21, 2020Assignee: TECH MACVERT INC.Inventors: Mark Lefsrud, Yves Roy, Jennifer Ashfield, Luc Roy
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Patent number: 10100263Abstract: Decreasing the water content of an organic phase can often be desirable, but low water levels can be difficult to achieve at high fluxes when the water is present in an emulsified form, such as in a water-in-oil emulsion. Processes for de-emulsifying a fluid stream containing emulsified water, such as water-in-crude oil emulsions, include introduction of the fluid stream into a vessel that defines a coalescence zone. The vessel is configured to provide for simultaneous application of a centrifugal force and an electric field to the fluid stream within the coalescence zone. The simultaneous application of the centrifugal force and the electric field to the fluid stream provides for the coalescence of a portion of the emulsified water into a bulk aqueous phase. A biphasic mixture comprising continuous phases of the organic component and the bulk aqueous phase is formed within the coalescence zone and subsequently removed from the vessel.Type: GrantFiled: October 5, 2015Date of Patent: October 16, 2018Assignee: SHELL OIL COMPANYInventors: Robert Paul Adamski, Gregory Kent Bethke, Gautan Chandrakanth Kini, Santhosh Kumar Shankar
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Patent number: 9795972Abstract: A high temperature high pressure electrostatic treater and method of use are described for removing water from heavy crude oil. The electrostatic treater is comprised of a vessel with a wet bitumen inlet and water outlet in the upper portion of the vessel, a dry bitumen outlet in the lower portion of the vessel, a plurality of electrodes on an electrically isolating support inside the vessel, an entrance bushing, and an interface control to regulate the flow of water through the water outlet. The water outlet is located above the dry bitumen outlet. The electrostatic treater and method reduce the amount of diluent needed to process the heavy crude when compared to the prior art.Type: GrantFiled: August 7, 2012Date of Patent: October 24, 2017Assignee: Cameron International CorporationInventors: Gary W. Sams, Everett Kamandala Minga
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Patent number: 9410092Abstract: The improved methods relate to desalting hydrocarbon feeds using a separator with a stacked disk centrifuge to separate an emulsified oil and water rag layer. This method is effective for desalting heavy, high ionic, and non-traditional crude oils.Type: GrantFiled: November 22, 2013Date of Patent: August 9, 2016Assignee: Phillips 66 CompanyInventor: Scott D. Love
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Patent number: 9284496Abstract: The improved system relates to desalting hydrocarbon feeds using a separator with a stacked disk centrifuge to separate an emulsified oil and water rag layer. This system is effective for desalting heavy, high ionic, and non-traditional crude oils.Type: GrantFiled: November 22, 2013Date of Patent: March 15, 2016Assignee: Phillips 66 CompanyInventor: Scott D. Love
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Patent number: 9233329Abstract: Methods and separator suitable for separating a gas from a liquid within a gas-liquid mixture. The separator includes a tank having a sidewall and oppositely-disposed endwalls that enclose an interior of the tank. An inlet to the tank directs a gas-liquid mixture against the sidewall of the tank within a first primary separation section to impart a circumferential flow direction to the mixture along the sidewall and initiate separation of a gas and liquid from the mixture. A reservoir located in a lower region of the tank collects the liquid separated from the mixture. A passage within a second primary separation section receives the gas separated from the gas-liquid mixture through an entrance thereof located in an upper region of the tank, and the passage directs flow of the gas into a secondary separation section, from which the gas exits the tank through an outlet.Type: GrantFiled: March 5, 2014Date of Patent: January 12, 2016Assignee: Vanair Manufacturing, Inc.Inventors: Mark A. Firnhaber, Garrett M. Griggs, Todd Allen Zeigner, Eugene A. Tibbs, Sr.
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Patent number: 9200938Abstract: The present invention provides an apparatus for producing micro liquid drops through fine channels which can produce a large amount of micro liquid drops at low costs in an efficient manner. The apparatus for producing micro liquid drops according to the present invention includes a fine channel substrate and a holder for holding the fine channel substrate.Type: GrantFiled: July 13, 2011Date of Patent: December 1, 2015Assignee: Toyota Institute of TechnologyInventor: Takasi Nisisako
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Publication number: 20140360880Abstract: Embodiments discussed herein relate to systems and methods for separating two or more phases of an emulsion or other mixture. The methods include providing the mixture with a net and unipolar charge (e.g., such that adjacent droplets therein acquire net and unipolar charges), thereby enhancing coalescence of like-phase droplets therein and producing, or enhancing the production of, two or more consolidated phases; and collecting the two or more consolidated phases.Type: ApplicationFiled: April 16, 2014Publication date: December 11, 2014Applicant: Massachusetts Institute of TechnologyInventors: Seyed Reza Mahmoudi, Kripa K. Varanasi
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Patent number: 8815068Abstract: The present invention relates to crude oil-water separation processes, specifically desalting in a petroleum refinery. More particularly, the present invention relates to a method and system for increase coalescence rates of water drops in a desalter.Type: GrantFiled: October 17, 2011Date of Patent: August 26, 2014Assignee: Phillips 66 CompanyInventor: Samartha G. Anekal
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Patent number: 8778159Abstract: A method of separating oil and water in a flow-stream through a gravity settling vessel (10) in which the flow-stream (12) separates into a lower water layer (22) and an upper oil layer (26), includes feeding an off-take stream (34) of the oil layer and/or an emulsion layer (20) that forms between the oil layer and the water layer through a compact electrostatic coalescer (CEC) (38) that has electrically isolated electrodes. The CEC coalesces water droplets in the off-take stream, and the coalesced off-take stream is then returned to the settling vessel. An associated separator apparatus for comprises: a gravity settling vessel (10); a CEC (38) including electrically isolated electrodes; a coalescer feed line (34) configured to provide an off-take stream of an oil phase and/or an emulsion layer from the settling vessel to the CEC; and a return line (40) from the CEC for returning the off-take stream to the settling vessel.Type: GrantFiled: September 9, 2005Date of Patent: July 15, 2014Assignee: Marks & ClerkInventors: Jon Liverud, Arne Myrvang Gulbraar, Simon Davies
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Patent number: 8673154Abstract: Described herein are systems, methods, and apparatuses for aggregating microorganism in an aqueous suspension. In particular, are systems, methods, and apparatuses that apply an electrical field to an aqueous suspension comprising microorganisms as the aqueous suspension follows a flow path to cause aggregation of the microorganisms. The electrical field may be continuous or pulsed. In some embodiments, the flow path for the aqueous suspension may vary. In some embodiments, the cross-sectional area of the electrical field may be tuned.Type: GrantFiled: May 22, 2013Date of Patent: March 18, 2014Assignee: Heliae Development, LLCInventors: Justin S. Kniep, Aniket Kale
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Patent number: 8591714Abstract: An apparatus for separating water from a water-in-oil mixture having an elongated inlet vessel with a lower outlet end and an upper inlet end, the length thereof being a multiple of the largest vessel cross-sectional dimension. A separation vessel having an oil outlet and a divergent water outlet has an inlet passageway in communication with the inlet vessel lower outlet end. At least one electrode is positioned within the inlet vessel by which a mixture flowing therethrough is subjected to an electric field.Type: GrantFiled: March 14, 2008Date of Patent: November 26, 2013Assignee: National Tank CompanyInventors: Gary W. Sams, Harry G. Wallace, David L. Taggart, David R. Manen
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Patent number: 8574417Abstract: The invention relates to a method for two-step separation of water, salt and particles from a hydraulic fluid by the use of a control unit. The hydraulic fluid is carried into a return oil tank with an electrostatic coalescer provided with a high-voltage transformer with direct current to two electric grids whose electrostatic field gathers water into drops which settle into a collecting tank. The hydraulic fluid is circulated to a filter module for removing any remaining water, salt and particles in filter elements connected in parallel, having hygroscopic cellulose fibers which swell until saturation, the swelling being measured by a sensor measuring the degree of saturation, alternatively conductivity.Type: GrantFiled: August 7, 2009Date of Patent: November 5, 2013Assignee: Tool-Tech ASInventor: Egil Eriksen
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Patent number: 8173006Abstract: An electrolyzed water production apparatus and method safely and simply produce electrolyzed water having a sterilizing action, having a physiologically neutral pH value, and, in addition, simultaneously with strong acidic electrolyzed water and strong alkaline electrolyzed water depending upon the structure. The electrolyzed water production apparatus has an electrolyzer tank with an end that receives or stores raw water, and a power supply. The interior portion of the electrolyzer tank is partitioned by a plurality of diaphragms into a plurality of regions. An anode and a cathode (constituting an electrode pair) are positioned on either side of the diaphragm. In a certain region of the electrolyzer tank, an anode and a cathode are arranged so as to face each other without a diaphragm sandwiched between them. When raw water for electrolysis is electrolyzed, electrolyzed water having a desired pH of a neutral range is produced during electrolysis.Type: GrantFiled: September 30, 2010Date of Patent: May 8, 2012Assignee: Osaka Electro-Communication UniversityInventors: Koichi Umimoto, Shunji Nagata
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Patent number: 7749459Abstract: A device, located in a vessel having an inlet and at least one outlet, through which a mixture of fluids flows, for promoting electrostatic coalescence of a first conductive fluid emulsified in a second fluid. The device includes a number of tubular electrostatic coalescer elements extending in the flow direction which are arranged in a matrix arranged over the cross sectional area of the vessel, and an applicator operative to apply an electrical field to the fluids flowing through the coalescer elements.Type: GrantFiled: November 6, 2002Date of Patent: July 6, 2010Assignee: Aibel ASInventors: PÃ¥l Jahre Nilsen, Gorm Sande, Wojciech Piasecki
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Patent number: 7520985Abstract: An electrically energized device for coalescing a first conductive fluid emulsified in a second fluid. A tube member has at least one fluid inlet and at least one fluid outlet. The tube member defines a flow channel for an emulsion of the first and second fluid from its inlet side to its outlet side and includes at least one electrically insulating wall portion. An interacting pair of a first and a second electrode is separated from the first and second fluid by at least one insulating wall portion of the tube member. The electrodes are supplied with a voltage for the purpose of subjecting the first and second fluid flowing through the flow channel to an electrostatic field. At least one passive center electrode is made of a conducting material and is arranged in the channel and electrically insulated from the first and second electrode.Type: GrantFiled: April 30, 2002Date of Patent: April 21, 2009Assignee: Aibel ASInventors: PÃ¥l Jahre Nilsen, Gorm Sande, Wojciech Piasecki
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Patent number: 7462274Abstract: A separating system for separating a fluid mixture incorporates a smart surface having reversibly switchable properties. A voltage is selectively applied to the smart surface to attract or repel constituents of a fluid mixture, such as oil and water produced from a hydrocarbon well. The smart surface can be used in a conditioner to increase droplet size prior to entering a conventional separator, or the smart surface and other elements of the invention can be incorporated into an otherwise conventional separator to enhance separation. In a related aspect, a concentration sensor incorporating smart surfaces senses concentration of the fluid mixture's constituents.Type: GrantFiled: July 1, 2004Date of Patent: December 9, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Syed Hamid, Beegamudre N. Murali, Harry D. Smith, Jr.
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Publication number: 20080116072Abstract: A method of separating oil and water in a flow-stream through a gravity settling vessel (10) in which the flow-stream (12) separates into a lower water layer (22) and an upper oil layer (26), includes feeding an off-take stream (34) of the oil layer and/or an emulsion layer (20) that forms between the oil layer and the water layer through a compact electrostatic coalescer (CEC) (38) that has electrically isolated electrodes. The CEC coalesces water droplets in the off-take stream, and the coalesced off-take stream is then returned to the settling vessel. An associated separator apparatus for comprises: a gravity settling vessel (10); a CEC (38) including electrically isolated electrodes; a coalescer feed line (34) configured to provide an off-take stream of an oil phase and/or an emulsion layer from the settling vessel to the CEC; and a return line (40) from the CEC for returning the off-take stream to the settling vessel.Type: ApplicationFiled: September 9, 2005Publication date: May 22, 2008Applicant: Aker Kvaerner Process Systems A.S.Inventors: Jon Liverud, Arne Myrvang Gulbraar, Simon Davies
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Patent number: 7008536Abstract: The invention includes a method for dewatering and/or desalting a water-in-oil emulsion comprising introducing a plurality of streams of the emulsion into the electrostatic field under opposed flow whereby the water coalescence is enhanced. The invention also includes an improved electrostatic apparatus for dewatering and/or desalting a water-in-oil emulsion comprising a plurality of horizontally directed nozzles positioned to introduce a plurality of streams of the emulsion into the electrostatic field under opposed flow conditions.Type: GrantFiled: April 25, 2003Date of Patent: March 7, 2006Assignee: ExxonMobil Research and Engineering Co.Inventors: Ramesh Varadaraj, Rutton D. Patel, Ramesh R. Hemrajani, Salvatore J. Rossetti, David W. Savage
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Patent number: 6730205Abstract: A method and apparatus for the treatment of fluid columns uses an air-cooled electromagnetic field generator to prevent the deposition and accumulation of contaminants within conduits and on equipment utilized in the transportation, delivery and processing of the fluid columns. The instant invention may be utilized to accelerate the separation of oil and water and increase the efficiency of such separation apparatus.Type: GrantFiled: January 3, 2002Date of Patent: May 4, 2004Inventor: Herbert W. Holland
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Publication number: 20030150731Abstract: A subsea well fluid processing system has a subsea well fluid separator for separating heavier and lighter components of well fluid flowing from a subsea well and directing the lighter components to flow to a surface processing facility. A choke is located downstream of the separator for limiting the flow rate of well fluid from the subsea well. The separator has a cylindrical chamber having a length at least ten times its diameter. A coalescing unit having a plurality of tubes to which an electrical potential is applied is located in the chamber to cause water droplets in the well fluid flowing through the tubes to coalesce into larger droplets. A dielectrophoresis unit having a pair of undulating sheets spaced close to each other is also located in the chamber. The sheets of the dielectrophoresis unit are supplied with an electrical potential to force the water droplets in the well fluid into predetermined passage portions between the sheets to form high water content sections of liquid.Type: ApplicationFiled: February 7, 2003Publication date: August 14, 2003Inventors: Jarle Michaelsen, Paal J. Nilsen
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Patent number: 6599949Abstract: The invention is directed towards a chemical demulsifier formulation comprising an alkyl aromatic sulfonic acid additive with at least 16 carbon atom alkyl group and at least two 6 carbon-ring aromatic group and a co-additive selected from the group consisting of dipropylene monobutyl ether, aromatic naphtha, isoparaffinic solvent, cycloparaffinic solvent, aromatic solvent, diethylene glycol monobutyl ether, benzyl alcohol and mixtures thereof and a process for demulsification and desalting crude oil using the demulsifier formulation.Type: GrantFiled: October 1, 2002Date of Patent: July 29, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Cornelius Hendrick Brons
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Patent number: 6489368Abstract: The invention is directed towards a chemical demulsifier formulation comprising an alkyl aromatic sulfonic acid additive with at least 16 carbon atom alkyl group and at least two 6 carbon-ring aromatic group and a co-additive selected from the group consisting of dipropylene monobutyl ether, isoparaffinic solvent, cycloparaffinic solvent, diethylene glycol monobutyl ether, benzyl alcohol, and mixtures thereof.Type: GrantFiled: March 9, 2001Date of Patent: December 3, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Cornelius Hendrick Brons
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Patent number: 6171465Abstract: A longitudinally horizontal pressure vessel desalts a fluid mixture of oil, an emulsion of oil globules encapsulated in salt water casings, gas and/or free water. A vertical wall splits the vessel into a double length flow path extending from an inlet to separate outlets for discharging the gas, the free water and the oil. A plurality of vertical baffles at intervals between the inlet and the outlets are divided along horizontal lines into a lowermost perforated zone for passing free water, a lower central zone for blocking passage of the emulsion, an upper central perforated zone for stripping the salt water casing from the oil globules and for passing oil and an uppermost open zone for passing gas. The line dividing the lower and upper central zones of each baffle are higher than the corresponding line of each preceding baffle along the flow path extending from the inlet to the outlets.Type: GrantFiled: September 21, 1999Date of Patent: January 9, 2001Inventor: Bill E. Compton
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Patent number: 6136174Abstract: A compact device for coalescing finely dispersed droplets of a conductive fluid emulsified in a stream of nonconductive fluid by the use of a high intensity electric field acting on the emulsion as it flows through a narrow flow gap under non-laminar flow conditions. The emulsion is introduced into the top of a vertically mounted cylindrical vessel or shell, and flows through one or more narrow, annular flow gaps formed between one or more electrodes, or an internal wall of the device. The broken emulsion is discharged from the bottom of the vessel, after having a short residence time in the high-intensity electrostatic field. The flow of the emulsion in the one or all of the narrow, annular flow gaps is non-laminar to provide substantially smaller equipment size, even with emulsions having high water content therein.Type: GrantFiled: June 3, 1998Date of Patent: October 24, 2000Assignees: Kvaerner Process Systems, Den Norske Stats Olejeselskap A.S.Inventors: J. Patrick Berry, Stewart J. Mulvey, Adrian G. Bailey, Martin T. Thew, Trevor J. Williams, Nicholas J. Wayth, Olav Urdahl
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Patent number: 6136178Abstract: Wastewater containing a surfactant and an oil content that has been emulsified by the action of the surfactant can be freed of the oil content by a method including feeding the wastewater into the anode compartment, for electrolysis, of a diaphragm electrolyzer having an anode and a cathode provided in the anode compartment and a cathode compartment, respectively, which are spaced apart by a porous diaphragm and which are supplied with a dc voltage between the anode and the cathode, passing part of the electrolyzed wastewater through the diaphragm so that it enters the cathode compartment, discharging the influent from the cathode compartment, discharging the remainder of the electrolyzed wastewater from the anode compartment and introducing the same into the intermediate portion of a gas-liquid separator, withdrawing part of the influent from the top of the gas-liquid separator and introducing the same into a layer packed with an adhering material, where it is brought into contact with the adhering material,Type: GrantFiled: November 18, 1998Date of Patent: October 24, 2000Assignee: Ebara CorporationInventors: Qingquan Su, Michihiro Noda
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Patent number: 6120678Abstract: Improved performance in the phase separation of aqueous brines from hydrocarbons within an electrostatic desalter operation is obtained by the addition to the crude oil emulsions entering the desalter of an effective asphaltene dispersing amount of an alkyl phenol-formaldehyde liquid resin polymer, optionally in the presence of a lipophilic/hydrophilic vinylic polymer. The preferred resin is a nonyl phenol-formaldehyde resin having a molecular weight of from 1,000-20,000, and the preferred vinylic polymer is a copolymer of lauryl (meth)acrylate and hydroxyethyl (meth)acrylate. Best results from the electrostatic desalter are obtained when also using a demulsifier chemical treatment along with the asphaltene dispersing treatments. Desalter efficiency is increased and desalter brine effluent quality is greatly increased.Type: GrantFiled: October 5, 1993Date of Patent: September 19, 2000Assignee: Nalco Chemical CompanyInventors: William K. Stephenson, Joe Scott Walker, Bordan W. Krupay, Sheraldean A. Wolsey-Iverson
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Patent number: 6110352Abstract: Wastewater containing a surfactant and an oil content that has been emulsified by the action of the surfactant can be freed of the oil content by a method including feeding the wastewater into the anode compartment, for electrolysis, of a diaphragm electrolyzer having an anode and a cathode provided in the anode compartment and a cathode compartment, respectively, which are spaced apart by a porous diaphragm and which are supplied with a dc voltage between the anode and the cathode, passing part of the electrolyzed wastewater through the diaphragm so that it enters the cathode compartment, discharging the influent from the cathode compartment, discharging the remainder of the electrolyzed wastewater from the anode compartment and introducing the same into the intermediate portion of a gas-liquid separator, withdrawing part of the influent from the top of the gas-liquid separator and introducing the same into a layer packed with an adhering material, where it is brought into contact with the adhering material,Type: GrantFiled: November 18, 1998Date of Patent: August 29, 2000Assignee: Ebara CorporationInventors: Qingquan Su, Hiroaki Sato, Michihiro Noda
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Patent number: 6093307Abstract: Wastewater containing a surfactant and an oil content that has been emulsified by the action of the surfactant can be freed of the oil content by a method to including feeding the wastewater into the anode compartment, for electrolysis, of a diaphragm electrolyzer having an anode and a cathode provided in the anode compartment and a cathode compartment, respectively, which are spaced apart by a porous diaphragm and which are supplied with a dc voltage between said anode and cathode, passing part of the electrolyzed wastewater through the diaphragm so that it enters the cathode compartment, discharging the influent from the cathode compartment, discharging the remainder of said electrolyzed wastewater from the anode compartment and introducing the same into the intermediate portion of a gas-liquid separator, withdrawing part of the influent from the top of the gas-liquid separator and introducing the same into a layer packed with an adhering material, where it is brought into contact with the adhering materialType: GrantFiled: November 18, 1998Date of Patent: July 25, 2000Assignee: Ebara CorporationInventors: Qingquan Su, Hiroaki Sato, Michihiro Noda
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Patent number: 6036840Abstract: A method and a reactor for electrochemical conversion of a material (21) being insoluble in a fluid into a material being soluble in the fluid, which method comprises that a flow of the fluid is passed to a reaction zone which comprises an internal circuit consisting of: one or more working electrodes (12), one or more counter-electrodes (13), and one or more ion-selective electrolytes (11), and which internal circuit is applied with an electrical voltage difference sufficient for the electrochemical processes; and use thereof for removal of soot particles from flue gasses and removal of oil in waste water.Type: GrantFiled: November 19, 1998Date of Patent: March 14, 2000Assignee: Dinex A/SInventor: Henrik Christensen
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Patent number: 5861089Abstract: A process for separating an emulsion into separate and easily recoverable phases. The process comprises exposing an emulsion comprising a discontinuous phase and a non-conducting continuous phase to an electric field thereby effecting coalescence of the discontinuous phase into droplets of a size for effective gravitation from the continuous phase, where the discontinuous phase and the continuous phase have different dielectric constants and densities and at least one of the phases comprise a silicon containing compound or a silicon containing polymer. The present process is especially useful for separating emulsions where the discontinuous phase is an aqueous acid solution and the continuous phase is diorganopolysiloxane.Type: GrantFiled: November 12, 1996Date of Patent: January 19, 1999Assignee: Dow Corning CorporationInventors: Christopher Darren Gatti, Charles Alan Hall, Roland Lee Halm
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Patent number: 5746907Abstract: A method is provided to remove metals from a residual oil containing an initial amount of a selected metal, the method comprising the steps of:providing a vessel for exposing the residual oil to a DC electric field having a strength of about one kV/inch or greater,passing the residual oils through the vessel whereby at least ten percent by weight of the initial amount of the selected metal is removed by attraction to an electrode; andpassing the residual oil that has been passed through the vessel over a hydrodemetalization catalyst in the presence of hydrogen. Metal containing particles and other toluene insoluble organic and inorganic solids are effectively removed from residual oil streams by treatment with a DC electrical field prior to hydrodemetalization resulting in significant increases in useful lives for downstream hydrodemetalization catalyst.Type: GrantFiled: February 20, 1996Date of Patent: May 5, 1998Assignee: Shell Oil CompanyInventors: Antonius Franziskus Heinrich Wielers, Vitold Raimond Kruka
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Patent number: 5714048Abstract: An apparatus and method for combining the effects of centrifugal force and electrostatic coalescence of water droplets in an integral containment vessel to de-emulsify water in oil type emulsions, without utilizing chemicals or applying heat to reduce the viscosity of the emulsion.Type: GrantFiled: March 1, 1996Date of Patent: February 3, 1998Inventor: Jerry M. Edmondson
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Patent number: 5643431Abstract: A method of augmenting the coalescence of water in an emulsion having a heavier water component that is relatively electrically conductive and a lighter oil component that is relatively non-conductive, including the steps of tangentially injecting the emulsion into the interior of a cylindrical vessel and tangentially withdrawing the emulsion from the vessel interior to cause the emulsion to flow circumferentially within the vessel to thereby impart centrifugal force on the emulsion to create a first area within the vessel adjacent the vessel sidewall in which the heavier water component of the emulsion is maintained and a second area within the vessel interior towards which the lighter oil component migrates and imposing an electrical potential on a concentrically positioned electrode within the vessel interior and thereby on the areas within the vessel having the circumferentially flowing emulsion to cause at least a portion of the water component of the emulsion to coalescence, the lighter, relatively non-Type: GrantFiled: February 8, 1996Date of Patent: July 1, 1997Assignee: National Tank CompanyInventors: Gary W. Sams, Floyd L. Prestridge, Merle B. Inman
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Patent number: 5575896Abstract: A method and apparatus for augmenting the coalescence of water in a water-in-oil emulsion. The apparatus includes a tubular vessel having a cylindrical side wall and opposed ends. A tangential inlet in the cylindrical side wall is adjacent one of the vessel ends. A tubular electrode having an external diameter less than the internal diameter of the vessel extends concentrically within the vessel from the one end less than the entire length of the vessel. An elongated electrode extends axially and concentrically within the tubular electrode from the one end. An outlet is provided in the one end between the tubular electrode and the elongated electrode. The inlet and outlet serve to cause fluid to initially flow through the vessel in a circumferential path outside the tubular electrode and thereafter axially through the tubular electrode to the outlet. An electrical potential is applied between the electrodes and the vessel.Type: GrantFiled: January 31, 1995Date of Patent: November 19, 1996Assignee: National Tank CompanyInventors: Gary W. Sams, Floyd L. Prestridge, Merle B. Inman, Dennis K. Manning