Conductive Material Applied To Substrate By Painting, Spraying, Or Immersion (e.g., Electroless Plating, Etc.) Patents (Class 205/163)
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Patent number: 12108540Abstract: A ceramic substrate manufacturing method is provided in which a copper sheet is etched and then bonded to a ceramic substrate, so that the ceramic substrate has reduced to overall processing time and improved reliability and product lifespan. The ceramic substrate manufacturing method includes the steps of: etching a copper sheet so as to prepare a metal substrate; etching a ceramic substrate so as to prepare a unit ceramic substrate; assembling the metal substrate and the unit ceramic substrate; bonding the metal substrate and the unit ceramic substrate so as to form a stack; partially printing a metal paste on the surface of the stack; and sintering the metal paste.Type: GrantFiled: May 14, 2020Date of Patent: October 1, 2024Assignee: AMOSENSE CO., LTDInventors: Kyung Whan Woo, Ji Hyung Lee
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Patent number: 11005235Abstract: A method for manufacturing a surge absorbing device is provided. The method includes providing an elongate ceramic tube having a hollow space defined therein and having open and opposite first and second end; forming a first plating layer and a second plating layer on the first end and the second end, respectively; placing a surge absorbing element within the hollow space within the ceramic tube; disposing first and second brazing rings on the first plating layer and the second plating layer, respectively; disposing first and second sealing electrodes on the first and second brazing rings respectively; and melting the first and second brazing rings in an inert gas atmosphere to attach the first and second sealing electrodes onto the first plating layer and the second plating layer, respectively.Type: GrantFiled: August 10, 2016Date of Patent: May 11, 2021Assignees: AJOU UNIVERSITY INDUSTRY-ACADEMIC COOPERATION FOUNDATION, SMART ELECTRONICS INC.Inventors: Chang-Koo Kim, Hae-Min Lee, Doo Won Kang, Hyun Chang Kim
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Patent number: 9694562Abstract: Coated articles and methods for applying coatings are described. The article may include a base material and a coating comprising silver formed thereon. In some embodiments, the coating comprises a silver-based alloy, such as a silver-tungsten alloy. The coating may, in some instances, include at least two layers. For example, the coating may include a first layer comprising a silver-based alloy and a second layer comprising a precious metal. The coating can exhibit desirable properties and characteristics such as durability (e.g., wear), hardness, corrosion resistance, and high conductivity, which may be beneficial, for example, in electrical and/or electronic applications. In some cases, the coating may be applied using an electrodeposition process.Type: GrantFiled: March 12, 2010Date of Patent: July 4, 2017Assignee: Xtalic CorporationInventors: Nazila Dadvand, Christopher A. Schuh, Alan C. Lund, Jonathan C. Trenkle, John Cahalen
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Patent number: 8881353Abstract: Provided is a method of producing a piezoelectric/electrorestrictive film type device including a vibrating laminate obtained by laminating electrode films and piezoelectric/electrorestrictive films on a substrate containing a cavity. The method of producing the vibrating laminate includes: producing the substrate with a cavity, forming the first photoresist film on first principal surface of substrate, irradiating substrate from the second principal surface side of the substrate, transferring the plane shape of the cavity to the first photoresist film, developing and removing the first photoresist film formed in the region where the shape of cavity was formed, forming a lowermost electrode film by plating, and forming additional films other than the lowermost electrode film constituting the vibrating laminate.Type: GrantFiled: September 6, 2010Date of Patent: November 11, 2014Assignee: NGK Insulators, Ltd.Inventors: Hideki Shimizu, Mutsumi Kitagawa
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Patent number: 8840769Abstract: A catalyst precursor resin composition includes an organic polymer resin; a fluorinated-organic complex of silver ion; a monomer having multifunctional ethylene-unsaturated bonds; a photoinitiator; and an organic solvent. The metallic pattern is formed by forming catalyst pattern on a base using the catalyst precursor resin composition reducing the formed catalyst pattern, and electroless plating the reduced catalyst pattern. In the case of forming metallic pattern using the catalyst precursor resin composition, a compatibility of catalyst is good enough not to make precipitation, chemical resistance and adhesive force of the formed catalyst layer are good, catalyst loss is reduced during wet process such as development or plating process, depositing speed is improved, and thus a metallic pattern having good homogeneous and micro pattern property may be formed after electroless plating.Type: GrantFiled: July 23, 2013Date of Patent: September 23, 2014Assignee: LG Chem, Ltd.Inventors: Min Kyoun Kim, Min Jin Ko, Sang Chul Lee, Jeong Im Roh
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Patent number: 8656858Abstract: A device and a method for chemically or electrolytically treating work pieces (1) are proposed in an effort to avoid irregular contours of finest conductive structures, pads and lands as well as bridges (shorts) on the one side or breaks on printed circuit boards on the other side. The device comprises processing tanks (2) for the treating of work pieces and a conveyor system for the transport thereof. The conveyor system comprises at least one transport carriage (18), at least one holding element (14, 25) and at least one connection means (12, 13, 35) between the transport carriage(s) and the holding element(s). The processing tanks adjoined with a clean room zone (3). The work pieces are conveyed through the clean room zone using the conveyor system.Type: GrantFiled: June 30, 2005Date of Patent: February 25, 2014Assignee: Atotech Deutschland GmbHInventor: Reinhard Schneider
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Publication number: 20140048420Abstract: A method for fabricating one-dimensional metallic nanostructures comprises steps: sputtering a conductive film on a flexible substrate to form a conductive substrate; placing the conductive substrate in an electrolytic solution, and undertaking electrochemical deposition to form one-dimensional metallic nanostructures corresponding to the conductive film on the conductive substrate. The method fabricates high-surface-area one-dimensional metallic nanostructures on a flexible substrate, exempted from the high price of the photolithographic method, the complicated process of the hard template method, the varied characteristic and non-uniform coating of the seed-mediated growth method.Type: ApplicationFiled: October 25, 2012Publication date: February 20, 2014Applicant: NATIONAL CHIAO TUNG UNIVERSITYInventors: Yu-Liang CHEN, Nai-Ying CHIEN, Hsin-Tien CHIU, Chi-Young LEE
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Patent number: 8448842Abstract: An advanced copper bonding with ceramic substrate technology includes the steps of (1) forming a copper film of thickness <1 ?m on a ceramic substrate by sputtering deposition under 1.33×10?3 torr and 150° C., (2) plating a copper layer of thickness 10˜50 ?m at room temperature, and (3) bonding a copper foil to the ceramic substrate by diffusion bonding under environments of high temperature, vacuum, and negative pressure inertia gas or H2 partial pressure.Type: GrantFiled: December 22, 2011Date of Patent: May 28, 2013Assignee: Vaclong Vacuum Technology Co., Ltd.Inventor: Rong-Fu Wu
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Patent number: 8389123Abstract: A material for forming electroless plate comprising a non-conductive base material and a catalyst adhering layer provided on the non-conductive base material is constituted so that the catalyst adhering layer should comprise a hydrophilic (meth)acrylic resin constituted with a hydrophilic monomer and a hydrophobic monomer and containing the hydrophobic monomer at a ratio of 50 to 90 mol %. This material for forming electroless plate shows favorable catalyst adhering property, and shows no delamination of the catalyst adhering layer from the non-conductive base material, no dissolution of the catalyst adhering layer into a plating solution, and no discoloration of plate layer during the catalyst adhering step, development step and other steps.Type: GrantFiled: February 1, 2008Date of Patent: March 5, 2013Assignees: Kimoto Co., Ltd., Japan Surface Treatment Institute Co., Ltd.Inventors: Tetsuji Ohta, Keiko Kitamura, Mitsuhiro Watanabe
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Patent number: 8323463Abstract: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.Type: GrantFiled: December 15, 2010Date of Patent: December 4, 2012Assignee: Praxair Technology, Inc.Inventors: Gervase Maxwell Christie, Jamie Robyn Wilson, Bart Antonie van Hassel
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Patent number: 8206828Abstract: A material for electroless plating shows good adhesion for a catalyst and does not cause delamination of a catalyst adhering layer from a non-conductive base material in a catalyst adhering step, development step or other step. In a material for electroless plating, having a catalyst adhering layer on a non-conductive base material, the catalyst adhering layer is formed from a hydrophilic and/or water-soluble resin containing hydroxyl group, and a curable layer formed from a resin having hydroxyl group and an isocyanate type compound is provided between the base material and the catalyst adhering layer. The catalyst adhering layer is preferably formed while isocyanate groups of the isocyanate type compound in the curable layer remain.Type: GrantFiled: March 12, 2007Date of Patent: June 26, 2012Assignees: Kimoto Co., Ltd., Japan Surface Treatment Institute Co., Ltd.Inventors: Tetsuji Ohta, Mitsuhiro Watanabe
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Patent number: 8182594Abstract: An electroless nickel plating liquid capable of forming an underbarrier metal for metal bumps or solder bumps by electroless nickel plating with a uniform film thickness on silicon wafers composed of multiple IC chips contains a water-soluble nickel salt, a reducing agent, a complexing agent, and a pH buffer, wherein_lead ion is contained at 0.01-1 ppm, cobalt ion is contained at 0.01-1 ppm, and a sulfur compound is contained at 0.01-1 ppm.Type: GrantFiled: September 26, 2006Date of Patent: May 22, 2012Assignee: Nippon Mining & Metals Co., Ltd.Inventors: Eiji Hino, Masashi Kumagai
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Patent number: 8105763Abstract: A method is provided that enables the formation of multiple level plated products with large plating depth. A negative photoresist composition comprising (a) an alkali-soluble resin, (b) an acid generator, and (c) other components is used, and a plated product is formed by (A) a step of forming a layer of this negative photoresist composition, and then either heating or not heating, before conducting exposure; (B) a step of repeating the step (A) so that the step is performed a total of 2 or more times, thereby superimposing layers of the negative photoresist, and subsequently developing all of these layers simultaneously to form a multilayer resist pattern; and (C) a step of conducting plating treatment within this multilayer resist pattern.Type: GrantFiled: May 10, 2005Date of Patent: January 31, 2012Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Yasuo Masuda, Yasushi Washio, Koji Saito
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Patent number: 7794578Abstract: A plating bath, able to form a resistance layer with a uniform thickness distribution on the roughened surface of a conductive base, including nickel ions and sulfamic acid or its salt as essential components and at least one of phosphoric acid, phosphorous acid, hypophosphorous acid, and salts of the same; a conductive base having a thin resistance layer with a stable resistance, and a resistance circuit board material using the same.Type: GrantFiled: November 24, 2003Date of Patent: September 14, 2010Assignee: The Furukawa Electric Co., Ltd.Inventors: Akira Matsuda, Yuuji Suzuki, Hideo Otsuka, Yuuki Kikuchi, Sadao Matsumoto
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Patent number: 7682774Abstract: Disclosed is a resin composition which comprises a catalyst precursor for electroless plating to form an electromagnetic wave shielding layer. The resin composition comprises an organic polymer resin, a polyfunctional monomer having an ethylenically unsaturated bond, a photoinitiator, a silver organic complex precursor as a catalyst precursor, and an organic solvent. Further disclosed are methods for forming metal patterns using the resin composition and metal patterns formed by the methods. The methods comprise forming a pattern, reducing the pattern, and electroless plating the reduced pattern. A patterned layer of the catalyst formed using the resin composition is highly adhesive, a loss of the catalyst during a wet process is substantially prevented, and an increase in plating rate leads to the formation of a uniform, fine metal pattern after electroless plating. Electromagnetic wave shielding materials comprising the metal pattern can be used in the formation of films for shielding electromagnetic waves.Type: GrantFiled: April 13, 2007Date of Patent: March 23, 2010Assignee: LG Chem, Ltd.Inventors: Min Kyoun Kim, Min Jin Ko, Bum Gyu Choi, Sang Chul Lee, Jeong Im Roh
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Patent number: 7560049Abstract: A method of manufacturing a device, comprising printing an aqueous solution or dispersion comprising an electronically functional substance, for example a conducting polymer such as PEDOT-PSS, and a surface tension reducing agent onto predetermined portions of a hydrophobic surface, for example formed by a ferroelectric polymer layer. The conducting polymer can form conductive tracks on either side of the ferroelectric layer to form a memory device.Type: GrantFiled: December 11, 2006Date of Patent: July 14, 2009Assignee: Seiko Epson CorporationInventors: Christopher Newsome, Daping Chu
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Patent number: 7384532Abstract: A process that can be uniformly employed for electroplating a wide variety of different non-conductive substrates, including those that are non-platable or difficult-to-plate using conventional electroless and electrolytic plating techniques involves application of a platable coating composition to the substrate prior to plating. The platable coating composition is cured to render the substrate more receptive to conventional plating techniques. In one embodiment, the process utilizes an epoxy resin system that upon being cured is receptive to electroless plating and electrolytic plating techniques that are the same or similar to those conventionally employed for electroplating ABS and/or PC/ABS substrates.Type: GrantFiled: November 16, 2004Date of Patent: June 10, 2008Assignee: Lacks Enterprises, Inc.Inventors: Dennis R. Parsons, II, Ling Hao, Daniel W. Irvine
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Publication number: 20070257235Abstract: A conductive coating composition and a method for producing coating layer using the same are disclosed. The conductive coating composition is capable of forming an antistatic coating layer on the protective film surface of display device. The conductive coating composition includes: 1 to 30 wt % of polyethylene dioxythiophene aqueous-dispersed solution; 5 to 15 wt % of water-soluble binder resin; 0.2 to 10 wt % of melamine resin; 6 to 40 wt % of alcohol solvent; 5 to 30 wt % of organic solvent selected from the group consisting of dimethyl sulfoxide, propyleneglycol methylether, N-methylpyrrolidone, ethyl-3-ethoxypropionate, propyleneglycol monomethyletheracetate, butylcarbitol and the mixtures thereof; and 10 to 50 wt % of water. The method for producing the conductive coating layer includes the steps of coating the conductive coating composition on a substrate; and drying the coating composition.Type: ApplicationFiled: March 8, 2007Publication date: November 8, 2007Inventors: Jong-Dai Park, Jong-Chul Shin, Ho-Kyu Lee
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Patent number: 7255782Abstract: A process of providing a pattern of a metal on a non-conductive substrate to create loop antennae for wireless articles and for creating circuitry for smart cards, such as phone cards is provided. The method comprises the steps of catalyzing the non-conductive substrate by applying a catalytic ink, reducing a source of catalytic metal ions in the catalytic ink to its associated metal, depositing electroless metal on the pattern of catalytic ink on the surface of the substrate; and plating electrolytic metal on the electroless metal layer to produce the desired pattern of metal on the non-conductive substrate. The catalytic ink typically comprises one or more solvents, a source of catalytic metal ions, a crosslinking agent, one or more copolymers, a polyurethane polymer, and, optionally, one or more fillers.Type: GrantFiled: April 30, 2004Date of Patent: August 14, 2007Inventor: Kenneth Crouse
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Patent number: 7128820Abstract: A composition and process for electroplating a conductive metal layer onto the surface of a non-conductive material is disclosed. The composition and process utilizes an obvious dispersion traditional carbon black particles and highly conductive carbon black particles. The mixture of carbon blacks provides optimum dispersion and electroplating properties.Type: GrantFiled: March 11, 2004Date of Patent: October 31, 2006Inventor: Hyunjung Lee
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Patent number: 7005192Abstract: A ceramic electronic component having a ceramic member into which no plating intrudes, and a method of producing the ceramic electronic component by which the ceramic electronic component can be easily produced are provided. The ceramic electronic component contains a ceramic member, and terminal electrodes formed on both of end-faces of the ceramic member. Each terminal electrode comprises an external electrode, and a plating coat formed thereon. To produce the ceramic electronic component, the ceramic member having the external electrodes are dipped into a water-repelling agent, dried, and plated. The water-repelling agent contains a functional group which is readily adsorbed to the external electrodes and a hydrophobic functional group.Type: GrantFiled: March 26, 2002Date of Patent: February 28, 2006Assignee: Murata Manufacturing Co., Ltd.Inventors: Yukio Sanada, Yoshinori Saito
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Patent number: 6899829Abstract: A conductive polymer colloidal composition that selectively forms a coating on a non-conductive surface. The conductive polymer colloidal composition is composed of a polymer and a sulfonate dopant. The conductive polymer colloidal composition may also contain conductive colloidal particles such as conductive carbon or metal salt particles, oxidants, stabilizers, and preservatives. The conductive polymer colloidal composition may be employed to selectively coat the non-conductive parts of printed wiring boards such that a uniform metal layer can be deposited on the conductive polymer coat. In addition to a uniform metal layer being formed over the conductive polymer, adhesion between the metal layer and the printed wiring board is improved.Type: GrantFiled: November 30, 2001Date of Patent: May 31, 2005Assignee: Shipley Company, L.L.C.Inventors: James G. Shelnut, Wade Sonnenberg, Patrick J. Houle
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Publication number: 20040159554Abstract: A light-transmitting electromagnetic wave-shielding material includes a hydrophilic transparent resin layer laminated on a transparent substrate. An electroless plating layer is laminated on the hydrophilic transparent resin layer in a pattern, and a black pattern section is formed on the hydrophilic transparent resin layer under the electroless plating layer. Therefore, a black electroplating layer is formed to cover the electroless plating layer laminated in a pattern.Type: ApplicationFiled: February 13, 2004Publication date: August 19, 2004Inventors: Shuzo Okumura, Masahiro Nishida, Tatsuo Ishibashi
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Publication number: 20040076707Abstract: In a die for molding a honeycomb structure, in which a coating layer is formed on a die base so that slits with a particular width are provided, the slits are provided so as to have a width of 30 to 200 &mgr;m by forming the coating layer by a substrate layer with a thickness of 10 to 100 &mgr;m and a surface layer with a thickness of 1 to 30 &mgr;m. Further, the substrate layer is formed by a metal layer containing no oxide.Type: ApplicationFiled: July 3, 2003Publication date: April 22, 2004Inventors: Keiji Matsumoto, Haremi Ito, Shinji Murahata
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Publication number: 20030173226Abstract: A method is disclosed for the metallization of optical fibers with improved adhesion while using a shorter process cycle.Type: ApplicationFiled: January 21, 2003Publication date: September 18, 2003Inventor: John Grunwald
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Publication number: 20030155250Abstract: The invention relates to a method for the treatment of work pieces with a palladium colloid solution by bringing the work pieces into contact with the colloid solution, palladium being recovered after the use of the colloid solution. This is achieved by separating palladium colloid particles from the colloid liquid by means of a molecular filter. With this method it is easy to continuously and largely completely separate palladium from the spent processing solutions without investing large amounts of chemicals, energy and time. The spent processing solution may especially be worked up after separation of the part of the solution containing palladium such that palladium can be recovered completely and be reused for further processing.Type: ApplicationFiled: April 21, 2003Publication date: August 21, 2003Inventors: Hermann Middeke, Mariola Brandes, Brigitte Dyrbusch
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Publication number: 20030155248Abstract: An inexpensive process for depositing an electrically conductive material on selected surfaces of a dielectric substrate may be advantageously employed in the manufacture of printed wiring boards having high quality, high density, fine-line circuitry, thereby allowing miniaturization of electronic components and/or increased interconnect capacity. The process may also be used for providing conductive pathways between opposite sides of a dielectric substrate and in decorative metallization applications.Type: ApplicationFiled: February 21, 2002Publication date: August 21, 2003Inventors: David A. Dalman, Petar R. Dvornic
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Patent number: 6468593Abstract: Provided is a method of plating a non-conductive product comprising the steps of: forming a coating film on a surface of the non-conductive product with a conductive paint having the following composition of solid ingredients: (a) a resin vehicle in 20 to 80 weight %, and (b) a conductive whisker in 80 to 20 weight %; and executing electroless plating on a surface of the coating film. Also provided are products produced by this method.Type: GrantFiled: November 25, 1998Date of Patent: October 22, 2002Assignees: Kanto Kasei Co., Ltd., Tanabe Chemical Industry Co., Ltd.Inventors: Tsutomu Iizawa, Takuya Ishida, Tamotsu Murayama, Takayuki Yagi
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Publication number: 20020150840Abstract: A stamper-forming electrode material contains Cu as its main ingredient and at least one other element, preferably Ag and/or Ti. It is preferred that the Ag content be 10.0 wt % or less and that the Ti content be 5.0 wt % or less. A stamper-forming thin film is made of this stamper-forming electrode material, whereby its corrosion resistance is improved to suppress damage to itself, and a high-quality stamper can hence be formed.Type: ApplicationFiled: February 4, 2002Publication date: October 17, 2002Applicant: PIONEER CORPORATIONInventors: Masahiro Katsumura, Tetsuya Iida, Nobuhiro Oda, Takashi Ueno
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Publication number: 20020117400Abstract: After forming first catalyst cores on the surfaces of adhesive layers of an insulating substrate, a plating resist is patterned. The insulating substrate is treated with an aqueous solution containing an anionic surfactant. Then, the insulating substrate is soaked successively in a palladium—tin mixed colloid catalyst solution and an accelerator solution, whereby second catalyst cores are formed on the surface of the adhesive layer not covered with the plating resist. Thereafter, conductive circuits are formed by electroless copper plating. Due to the anionic surfactant, adsorption of the palladium—tin mixed colloid catalyst to the plating resist is suppressed, and the first catalyst cores promote the formation of second catalyst cores. By setting the concentration of the first catalyst cores to 4×10−8 atomic mol/cm2 or less, a fine conductive circuit with a line width/line space of 50 &mgr;m or less having a high electrical insulating property between circuit lines can be formed.Type: ApplicationFiled: February 20, 2002Publication date: August 29, 2002Applicant: NEC CORPORATIONInventor: Sinichi Hotta
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Publication number: 20020108863Abstract: A method and apparatus for selectively removing oxygen from a gas stream containing NOx and oxygen by contacting the gas stream with an electrochemical cell made from an electrode consisting of La1-XMXFeO3, (where M is selected from the group consisting of Sr, Ba, Ca, and combinations thereof, and X is between 0.05 and 0.5), a solid oxide electrolyte and a counter electrode, wherein the La1-XMXFeO3 electrode is on one side of a solid oxide electrolyte, and a counter electrode is on the opposite side of the solid oxide electrolyte, and applying a voltage to the electrochemical cell. The apparatus is preferably employed in a two chambered NOX sensor utilizing solid electrolyte electrochemical cells, wherein an electrochemical cell capable of catalyzing oxygen reduction without catalyzing NOX decomposition is formed as integral to the first chamber.Type: ApplicationFiled: December 14, 2000Publication date: August 15, 2002Inventors: Olga A. Marina, Craig F. Habeger
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Patent number: 6432291Abstract: A method of simultaneously electroplating both sides of a dual-sided circuit board substrate having electrically connected, multi-trace circuit patterns formed on both sides of the substrate, without requiring formation and at least partial removal of electrically conductive tie bars and associated extensions, comprises steps of simultaneously electrically contacting each feature of a first one of the circuit patterns with a multi-fingered electrical contactor, and applying an electrical potential to the contactor to effect simultaneous electroplating on the circuit patterns on both sides of the substrate. According to an embodiment of the invention, the multi-fingered contactor comprises an array of electrically conductive wires, rods, or filaments extending from one surface of a metal plate. The invention finds particular utility in the fabrication of ball grid array (BGA) semiconductor device packages.Type: GrantFiled: August 18, 2000Date of Patent: August 13, 2002Assignee: Advanced Micro Devices, Inc.Inventors: Valerie Vivares, Robert Newman, Edwin R. Fontecha
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Patent number: 6426290Abstract: A method of electroplating both sides of a dual-sided circuit board substrate having electrically connected, multi-trace circuit patterns formed on both sides of the substrate, without requiring formation and at least partial removal of electrically conductive tie bars, comprises steps of covering and electrically contacting a first one of the circuit patterns with a first layer of electrically conductive material, applying an electrical potential to the first layer of electrically conductive material to effect electroplating on the second one of the circuit patterns, removing the first layer of electrically conductive material, covering and electrically contacting the second one of the circuit patterns with a second layer of electrically conductive material, applying an electrical potential to the second layer of electrically conductive material to effect electroplating on the first one of the circuit patterns, and removing the second layer of electrically conductive material.Type: GrantFiled: August 18, 2000Date of Patent: July 30, 2002Assignee: Advanced Micro Devices, Inc.Inventors: Valerie Vivares, Robert Newman, Edwin R. Fontecha
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Patent number: 6406607Abstract: An inkjet printer nozzle plate having a non-wetting surface of uniform thickness and an orifice wall of tapered contour, and method of making the nozzle plate. In the method a metal masking layer is deposited on a glass substrate, the masking layer having an opening therethrough for passage of light only through the opening. Next, a negative photoresist layer is deposited on the masking layer, the negative photoresist layer being capable of photochemically reacting with the light. A light source passes light through the substrate, so that the light also passes only through the opening in the form of a tapered light cone. This tapered light cone will define the tapered contour of a nozzle plate orifice wall to be formed. The negative photoresist layer photochemically reacts with the light only in the light cone to define a light-exposed region of hardened negative photoresist.Type: GrantFiled: November 10, 2000Date of Patent: June 18, 2002Assignee: Eastman Kodak CompanyInventors: Jeffrey I. Hirsh, Edwin A. Mycek, Larry L. Lapa
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Patent number: 6358390Abstract: A method for forming an electrode on a surface of an electronic device formed of a ceramic material is disclosed. The method comprises the steps of: adjusting a polarity of a surface charge by immersing the electronic device in a solution containing a cationic or an anionic surfactant; depositing an electroconductive material on the surface of the electronic device by contacting the electronic device with an electroconductive solution containing the electroconductive material having a polarity opposite to the adjusted polarity of the surface charge; and performing electrolytic plating using the electroconductive material deposited on the surface of the electronic device as an underlying metal film.Type: GrantFiled: September 28, 2000Date of Patent: March 19, 2002Assignee: Murata Manufacturing Co., Ltd.Inventors: Yasushi Yoshida, Tatsuo Kunishi
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Patent number: 6350365Abstract: A method of producing a multilayer circuit board comprising a core substrate and a plurality of layers of wiring lines on both sides of the core substrate with an insulation layer being interposed therebetween; the layers of wiring lines on both sides being interconnected by conducting members provided on the inside walls of through holes going through the core substrate, and the interposed insulation layer. The method further comprising, wiring lines with an upper layer of wiring lines wherein the conducting member on the inside wall of the through hole and the via are formed in separate steps. The method can provide a multilayer circuit board which can advantageously be used to mount a chip or device thereon having an increased number of electrodes or terminals.Type: GrantFiled: August 9, 2000Date of Patent: February 26, 2002Assignee: Shinko Electric Industries Co., LTDInventors: Toshinori Koyama, Noritaka Katagiri
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Patent number: 6348142Abstract: A method of electroplating circuit board substrate having a high density, multi-trace circuit pattern formed on at least one major surface of an insulative substrate, without requiring formation and at least partial removal of a large plurality of electrically conductive tie bars contacting each of the circuit traces for supplying electroplating potential/current, comprises providing the at least one major surface with a single tie bar having at least a pair of laterally extending arms in simultaneous electrical contact with an end of each trace. Portions of the tie bar extension arms are selectively removed after completion of electroplating, e.g., by laser drilling or plasma etching, to electrically separate each of the circuit traces from the tie bar. According to an embodiment of the invention, electroplating is simultaneously performed on a dual-sided substrate including electrically interconnected circuit patterns formed on opposite sides thereof.Type: GrantFiled: August 7, 2000Date of Patent: February 19, 2002Assignee: Advanced Micro Devices, Inc.Inventors: Valerie Vivares, Edwin R. Fontecha
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Patent number: 6344309Abstract: A metal pattern is prepared by applying a polysilane composition comprising a polysilane, a carbon functional silane, and a solvent onto a substrate to form a patterned coating of the polysilane composition, attaching catalytic metal nuclei to the patterned coating, and immersing the substrate in an electroless plating bath for thereby chemically depositing a metal film on the patterned coating.Type: GrantFiled: October 22, 1999Date of Patent: February 5, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Motoo Fukushima, Kunio Ito, Shigeru Mori
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Publication number: 20010052467Abstract: The present invention relates to a method and apparatus of fabricating electromagnetic coil vanes. The method involves photolithographically exposing high resolution, dense wire patterns in a flash coat of copper, on both sides of a ceramic vane substrate. The substrate can be pre-drilled with a through hole to connect the two copper coil patterns. Additional copper is then deposited on both high resolution patterns and in the through hole by plating until the desired thickness is obtained. A firing operation is then performed that eutectically bonds the copper to the ceramic.Type: ApplicationFiled: December 23, 1999Publication date: December 20, 2001Inventor: DAVID J. PINCKNEY
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Patent number: 6274241Abstract: To provide a substrate enclosed in a uniform nucleation layer, a substrate is nucleated with a noble metal salt where the noble metal salt is chemically bound to the substrate, and a method is described for binding a noble metal salt chemically to a substrate. To provide a metal plated powder, a powder is nucleated with a noble metal salt and the nucleation is coated with a metal layer. A method is also provided for nucleating the powder surface with a noble metal salt in such a manner that it is chemically bound to the substrate and then metal plated by a conventional electroless method.Type: GrantFiled: June 14, 1999Date of Patent: August 14, 2001Assignee: Robert Bosch GmbHInventors: Lothar Weber, Thomas Brinz, Ulrich Eisele, Dorothee Kling
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Patent number: 6251252Abstract: The present invention provides a simple, reproducible electroless process for metalizing a non-hermetic optical fiber. The process of the present invention provides the optical fiber with a metalization layer suitable for solder bonding the optical fibers to other surfaces. The silica surface of the optical fiber is sensitized with a stannous fluoride solution, catalyzed with a catalyzing solution of stannous chloride and hydrochloric acid, and activated with an activator solution comprising palladium chloride. The sensitizing, catalyzing and activating steps are performed under ambient condition. Then nickel is plated on the silica surface through electroless plating and electrolytic plating. Finally, a gold layer is plated on the nickel layer. The process produces good adhesion properties and reliable optical fiber attachment for various applications.Type: GrantFiled: August 25, 1999Date of Patent: June 26, 2001Assignee: Lucent Technologies Inc.Inventor: Meijiao Sara Chen
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Patent number: 6120670Abstract: There is provided a method of fabricating a multi-layered printed wiring board, including the steps of (a) forming a multi-layered substrate with a hole which will make a blind via-hole, (b) plating the multi-layered substrate, (c) forming an internal layer circuit pattern and an external layer circuit pattern, (d) laying one multi-layered substrate on another, (e) forming a product of the step (d) with a through-hole, (f) covering surfaces of a product of the step (e) including an inner wall surface of the through-hole with an electrically conductive film, (g) forming a resist in an area other than the through-hole, (h) plating the inner wall surface of the through-hole, (i) removing the resist, and (j) removing the electrically conductive film formed on the surfaces of the product of the step (e).Type: GrantFiled: January 26, 1998Date of Patent: September 19, 2000Assignee: NEC CorporationInventor: Shigeki Nakajima
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Patent number: 6113772Abstract: According to the present invention there is provided a method for making lithographic printing plates or a printing cylinder including the steps of applying image-wise a solution of ions of an oleophilic metal with an ink jet on a hydrophilic metallic base and reducing said ions by electroplating in order to obtain an oleophilic metal image.Type: GrantFiled: February 22, 1999Date of Patent: September 5, 2000Assignee: Agfa-Gevaert, N.V.Inventor: Ludo Van Rompuy
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Patent number: 6039859Abstract: The invention relates to a conductive dispersions used for diverse purposes such a base for electroplating nonconductors. The dispersion are characterized by use of a stabilizing quantity of a stabilizer having repeating alylkene oxide groups and a hydrophilic--lipophilic balance in excess of 12. It has been found that the stabilizers utilized in the subject compositions does result in a significant loss of conductivity in coatings formed from the dispersion.Type: GrantFiled: May 20, 1998Date of Patent: March 21, 2000Assignee: Shipley Company, L.L.C.Inventors: Wade Sonnenberg, Patrick J. Houle, Thong B. Luong, James G. Shelnut, Gordon Fisher
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Patent number: 6027862Abstract: A description is given of a method of providing an adhesive silver layer on a glass substrate, in which method the glass surface is activated, whereafter a first silver layer is provided from an electroless silver bath and reinforced by means of a second silver layer which is electrodeposited thereon from a cyanide-free bath comprising ammonia as the complexing agent for silver ions. The method can very suitably be used for silver-plating glass plates, as used in thin gas-discharge displays or thin electron displays, for example selection plates or control plates.Type: GrantFiled: November 19, 1997Date of Patent: February 22, 2000Assignee: U.S. Philips CorporationInventors: Martin H. Blees, Antonius A. M. Van Weert
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Patent number: 5961808Abstract: The present invention relates to an alloy film resistor containing mainly nickel and phosphorus having an excellent fuse function and a method for producing the alloy film resistor. After the conductivity is given to the surface of an electrical insulating substrate such as ceramics by sequentially performing an etching treatment, an activating treatment and an electroless plating treatment to the electrical insulating substrate, an alloy film containing mainly nickel and phosphorus is formed by not an electroless plating process but an electrolytic plating process. By adopting the electrolytic plating process, a film thickness of the formed alloy film of the middle part on the surface of the insulating substrate is thinner than that of the alloy film of the corner or ridge parts on the surface of the insulating substrate, and the thin part of the film thickness serves as a suitable fusing start part when applying an overload.Type: GrantFiled: November 6, 1998Date of Patent: October 5, 1999Assignee: Kiyokawa Mekki Kougyo Co., Ltd.Inventor: Tadashi Kiyokawa
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Patent number: 5938912Abstract: A method of providing a decorative metal pattern on an electrically non-conductive substrate, such as a glass or plastic substrate, which includes applying a mixture of a heat fusible material, such as glass or plastic, with a metal having a particle size less than about 500 mesh constituting at least 50% of the mixture, to the substrate in the desired pattern, heating the so-applied mixture until the heat fusible material fuses and bonds to the substrate, cleaning the substrate with the pattern thereon, and electroplating the pattern with the desired finish metal. In one method in which the mixture includes glass, a negative resist is adhesively secured to the substrate and the mixture is applied. The resist disintegrates upon heating. In another method, used when the substrate is plastic, a mixture of plastic and metal in paste form is applied to the substrate by silk screening or pad printing to form the pattern.Type: GrantFiled: April 23, 1996Date of Patent: August 17, 1999Inventor: Peter C. Jaeger
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Patent number: 5863407Abstract: The present invention relates to an alloy film resistor containing mainly nickel and phosphorus having an excellent fuse function and a method for producing the alloy film resistor. After the conductivity is given to the surface of an electrical insulating substrate such as ceramics by sequentially performing an etching treatment, an activating treatment and an electroless plating treatment to the electrical insulating substrate, an alloy film containing mainly nickel and phosphorus is formed by not an electroless plating process but an electrolytic plating process. By adopting the electrolytic plating process, a film thickness of the formed alloy film of the middle part on the surface of the insulating substrate is thinner than that of the alloy film of the corner or ridge parts on the surface of the insulating substrate, and the thin part of the film thickness serves as a suitable fusing start part when applying an overload.Type: GrantFiled: March 4, 1997Date of Patent: January 26, 1999Assignee: Kiyokawa Mekki Kougyo Co., Ltd.Inventor: Tadashi Kiyokawa
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Patent number: 5858198Abstract: A process for electroplating a metal clad substrate by coating the substrate with a coating of carbonaceous particles. The coating of particles is applied to the substrate from an aqueous dispersion and then the coating is saturated with an etchant for the metal cladding on the substrate to undercut the carbonaceous coating and facilitate its removal from areas where plating is undesired.Type: GrantFiled: September 8, 1997Date of Patent: January 12, 1999Assignee: Shipley Company, L.L.C.Inventors: Steven M. Florio, Jeffrey P. Burress, Carl J. Colangelo, Edward C. Couble, Mark J. Kapeckas
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Patent number: RE37765Abstract: Described herein is an improved process for electroplating a conductive metal layer to the surface of a nonconductive material comprising pretreating the material with a carbon black dispersion followed by a graphite dispersion before the electroplating step.Type: GrantFiled: February 22, 1999Date of Patent: June 25, 2002Assignee: MacDermid, IncorporatedInventors: Catherine M. Randolph, Barry F. Nelsen