Electrolytic Coating Is Oxygen-containing (e.g., Chromate, Silicate, Oxide Formed By Anodizing, Etc.) Patents (Class 205/199)
  • Patent number: 6660931
    Abstract: A substrate for a solar cell is provided which comprises a support having a metal surface and a zinc oxide film formed on the metal surface and having a water content of 7.5×10−3 mol/cm3 or less, preferably 4.0×10−4 mol/cm3 or more. Thereby, the increase of series resistance and the generation of shunt are prevented and the efficiency such as Jsc and the chemical stability are improved, thus obtaining a solar cell with a zinc oxide film having optimal overall characteristics.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: December 9, 2003
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noboru Toyama, Yuichi Sonoda, Yusuke Miyamoto
  • Patent number: 6585877
    Abstract: An object of the invention is to provide a surface-treated copper foil capable of consistently attaining a percent loss of peel strength in resistance against hydrochloric acid degradation of 10% or less as measured on a copper pattern prepared from the copper foil and having a line width of 0.2 mm, by bringing out the maximum effect of the silane coupling agent employed in brass-plated anti-corrosive copper foil. The Another object is to impart excellent moisture resistance to the surface-treated copper foil.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: July 1, 2003
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Masakazu Mitsuhashi, Takashi Kataoka, Naotomi Takahashi
  • Patent number: 6579437
    Abstract: An object of the invention is to provide a surface-treated copper foil capable of consistently attaining a percent loss in peel strength against hydrochloric acid degradation of 10% or less as measured on a copper pattern prepared from the copper foil and having a line width of 0.2 mm, by bringing out the maximum effect of the silane coupling agent employed in zinc-plated or zinc-alloy-plated anti-corrosive copper foil. Another object is to impart excellent moisture resistance, heat resistance, and long-term storage stability to the surface-treated copper foil.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: June 17, 2003
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Masakazu Mitsuhashi, Takashi Kataoka, Naotomi Takahashi
  • Publication number: 20030052012
    Abstract: A housing made of a magnesium material is colored by a non-painting process. In this process, an anode oxide film is grown on the surface of the housing by subjecting the housing to anodization. The anode oxide film is colored without a paint being applied to the surface of the film.
    Type: Application
    Filed: August 30, 2002
    Publication date: March 20, 2003
    Applicant: FUJITSU LIMITED
    Inventors: Yasuo Naganuma, Masami Tsutsumi
  • Patent number: 6475565
    Abstract: The invention relates to a process for producing a clothing wire which is suitable for fitting to an opening-cylinder base body, wherein a raw wire which is customarily used to produce clothing wire is processed on end to form a wire coil, in which the teeth of the wire are perpendicular to the coil axis and which has a diameter which corresponds to the diameter of the opening-cylinder base body or differs by at most ±5% from the diameter of the opening-cylinder base body, and the wire coil is pushed loosely onto a support device and, together with this device, is introduced into an electroplating unit, the process steps which are customarily used for the chemical deburring of a raw wire and the nickel-diamond coating of a clothed opening cylinder taking place in the electroplating unit, and the clothing wire being removed from the electroplating unit.
    Type: Grant
    Filed: October 26, 2000
    Date of Patent: November 5, 2002
    Assignee: Elektroschmelzwerk Kempten GmbH
    Inventors: Jörg Lukschandel, Manfred Menge, Jürgen Meyer
  • Patent number: 6471848
    Abstract: This invention provides an electrodeposition apparatus, comprising at least one electrodeposition vessel for supplying a current between a substrate and an electrode in an electrodeposition bath to form an oxide film or the substrate and a rinsing means for rinsing the substrate after passing the electrodeposition tank with water, wherein a humidifying means for preventing drying of at least the film forming surface of the substrate is provided along the transporting path of the substrate at least at the exit side of the electrodeposition vessel and an oxide film forming method. Thus a uniform oxide film without unevenness can be formed on the substrate.
    Type: Grant
    Filed: February 12, 1999
    Date of Patent: October 29, 2002
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kozo Arao, Noboru Toyama, Yuichi Sonoda, Yusuke Miyamoto
  • Publication number: 20020139687
    Abstract: A device for producing electrical discharges in an aqueous medium which comprises a first electrode and a second electrode comprised of a superalloy having a cobalt content of greater than 8% by weight or optionally a nickel content of greater than 8% by weight. A high electrical voltage is applied to the electrodes to produce a voltage discharge into the medium that creates a pressure wave in the medium. The electrodes of the device exhibit high thermal shock resistance during discharge thereby reducing tip burnout.
    Type: Application
    Filed: March 15, 2002
    Publication date: October 3, 2002
    Inventors: Norbert Brill, Rudiger Bolze, Stefan Regenscheit, Frank Schock, Erwin Simnacher, Karl-Heinz Restle
  • Patent number: 6346184
    Abstract: The present invention provides a method of producing a zinc oxide thin film in which a current is passed between a conductive substrate immersed in an aqueous solution containing at least zinc ions and carboxylic acid ions, and an electrode as an anode immersed in the aqueous solution to form a zinc oxide thin film on the conductive substrate. This method stabilizes formation of the zinc oxide thin film and improves adhesion between the thin film and the substrate.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: February 12, 2002
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masafumi Sano, Yuichi Sonoda
  • Publication number: 20010053452
    Abstract: A non-aqueous electrolyte comprises an organic solvent and a solute, and also has an electrolytic conductivity that is greater than or equal to 1 mS/cm but less than or equal to 100 mS/cm. This solute preferably includes at least one of a carboxylate and a salt of inorganic oxoacid. In addition, the non-aqueous electrolyte preferably comprises water in a proportion of 1 to 10 wt %. In an MIM nonlinear element (20), an insulated film (24) is formed by anodic oxidation using the above non-aqueous electrolyte. In addition, the insulated film comprises at least one of carbon atoms and atoms of families 3 to 7 that were originally the central atoms of the salt of inorganic oxoacid, and has a relative permittivity of 10 to 25. With this MIM nonlinear element, the capacitance is sufficiently small, the steepness of the voltage-current characteristic is sufficiently large, and also the resistance is sufficiently uniform over a wide range of voltages.
    Type: Application
    Filed: September 15, 1998
    Publication date: December 20, 2001
    Inventors: TAKASHI INOUE, TAKEYOSHI USHIKI, TAKUMI SEKI, MAKOTO UE, FUMIKAZU MIZUTANI, SACHIE TAKEUCHI
  • Patent number: 6322687
    Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a mineral containing coating or film upon a metallic or conductive surface.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: November 27, 2001
    Assignee: Elisha Technologies Co LLC
    Inventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie
  • Patent number: 6312581
    Abstract: A process for fabricating a silica-based optical device on a silicon substrate is disclosed. The device has a cladding formed in a silicon substrate. The device also has an active region, and that active region is formed on the cladding. The cladding is fabricated by forming a region of porous silicon in the silicon substrate. The porous silicon is then oxidized and densified. After densification, the active region of the device is formed on the cladding.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: November 6, 2001
    Assignee: Agere Systems Optoelectronics Guardian Corp.
    Inventors: Allan James Bruce, Alexei Glebov, Joseph Shmulovich, Ya-Hong Xie
  • Patent number: 6280597
    Abstract: The known flourinated layer has usually a thickness of from 1000 to 3000 angstroms. After the forced oxidation of metal, the forcibly oxidized surface is flourinated. As a result of the preceding forcing oxidation, a 1 &mgr;m or more thick fluorinated layer is formed on the surface of the metal.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: August 28, 2001
    Assignee: Showa Denko K.K.
    Inventors: Kunio Kashiwada, Takanori Kodama, Hiroyasu Taguchi, Satoshi Hirano
  • Patent number: 6153080
    Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a mineral containing coating or film upon a metallic or conductive surface.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: November 28, 2000
    Assignee: Elisha Technologies Co LLC
    Inventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie
  • Patent number: 6106689
    Abstract: A process for forming a zinc oxide film including immersing an electroconductive substrate having a surface including a plurality of linear projections in an aqueous solution containing at least nitrate ions and zinc ions to form a zinc oxide film on the electroconductive substrate by a liquid-phase deposition. The plurality of linear projections may preferably provide an uneven surface which has a center-line average surface roughness Ra(X) of 15-300 nm when scanned in a direction parallel to the linear projections, a center line average surface roughness Ra(Y) of 20-600 nm when scanned in a direction perpendicular to the linear projections, and an Ra(X)/Ra(Y) ratio of at most 0.8. The thus formed zinc oxide film is provided with an uneven surface suitable for an optical-confinement layer of a photo-electricity generating device excellent in photoelectric performances.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: August 22, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventor: Jinsho Matsuyama
  • Patent number: 6077411
    Abstract: An apparatus for forming a zinc oxide film on a sheet substrate including a tank containing an aqueous electrolytic solution containing at least nitrate ions and zinc ions, conveyer means for continuously feeding and conveying an elongated electroconductive sheet substrate having two major surfaces in a direction while dipping a lengthwise portion of the sheet substrate in the electrolytic solution, a counter electrode immersed in the electrolytic solution so as to be opposite to the lengthwise portion of the sheet substrate, and a power supply disposed so as to pass a current between the sheet substrate and the counter electrode, wherein the conveyer means include a plurality of rollers and an endless belt wound about the rollers so as to have a conveyer surface contacting and covering one of the major surfaces of the lengthwise portion of the sheet substrate dipped in the electrolytic solution while moving together with the sheet substrate.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: June 20, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventor: Tetsuro Nakamura
  • Patent number: 6045677
    Abstract: A microchannel plate and method of manufacturing same is provided. The microchannel plate includes a plate consisting of an anodized material and a plurality of channels which are formed during the anodization of the material and extend between the two sides of the plate. Electrodes are also disposed on each side of the plate for generating an electrical field within the channels. Preferably, the material is alumina and the channels are activated such that the channel walls are conductive and highly secondary emissive.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: April 4, 2000
    Assignee: NanoSciences Corporation
    Inventors: Charles P. Beetz, Jr., Robert W. Boerstler, John Steinbeck, David R. Winn
  • Patent number: 5961809
    Abstract: A process for improving the adherence of paint applied after thin-film anodization is characterized in that the anodized metal surfaces are brought into contact with an aqueous solution containing one or more of the following components: (a) 200 to 2000 ppm of a homopolymer or copolymer of acrylic acid, methacrylic acid, and/or their esters; (b) 200 to 3000 ppm of a poly(vinyl phenol) compound in which at part of the phenol rings carry an alkylamino substituent; (c) 200 to 3000 ppm of hexafluorotitanic acid, hexafluorozirconic acid, and/or their anions.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: October 5, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolf-Achim Roland, Andreas Nowak
  • Patent number: 5948234
    Abstract: Acid-doped, polyaniline-based polymers are formed into fibers, films, and coatings with a solvent of at least one bicyclic terpene. Such a solvent system is characterized by a drying temperature of less than 150.degree. C. and a relatively low toxicity.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: September 7, 1999
    Assignee: Kemet Electronics Corporation
    Inventors: John T. Kinard, Brian J. Melody, Philip M. Lessner
  • Patent number: 5891269
    Abstract: A process for sealing anodized metals without using any heavy metals comprises a first step in which the anodized metal is contacted for a period of between 3 and 30 minutes (for an anodized layer thickness of 20 .mu.m) with an aqueous solution which has a temperature from 15.degree. to 35.degree. C. and a pH between 5.0 and 6.5 and contains from 0.1 to 3 g/l of lithium ions and from 0.1 to 5 g/l of fluoride ions and a second step in which the anodized metal is contacted for a period from 5 to 30 minutes (for an anodized layer thickness of 20 .mu.m) with water or an aqueous solution of substances which prevent the formation of a sealing coating, the solution having a pH from 5.5 to 8.5 and a temperature from 80.degree. to 100.degree. C.
    Type: Grant
    Filed: January 7, 1998
    Date of Patent: April 6, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Torsten Koerner, Josef Kresse, Juergen Lindener, Wolf-Achim Roland
  • Patent number: 5685968
    Abstract: In a ceramic substrate with a thin-film capacitor, having a ceramic substrate a lower electrode layer formed on the ceramic substrate, a dielectric layer formed on the lower electrode layer and made of an oxide of a material constituting the lower electrode layer, and an upper electrode layer formed on the dielectric layer, a plating layer is provided between the ceramic base and the lower electrode layer to serve as a basis for the lower electrode layer.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: November 11, 1997
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Toshitaka Hayakawa, Shinobu Yoshida, Toshikatsu Takada
  • Patent number: 5487825
    Abstract: A method of producing composite oxide ceramic fluorine polymer layers on articles of aluminum, magnesium, titanium or their alloys, particularly of light metal components, includes introducing particles of fluorine polymers into the capillary system of an oxide ceramic layer. The particles have a particle size which at least in one dimension is smaller than the diameter of the capillaries. The article is then subjected to alternating pressure conditions.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: January 30, 1996
    Assignee: Electro Chemical Engineering GmbH
    Inventors: Peter Kurze, Hans-Jurgen Kletke
  • Patent number: 5470636
    Abstract: A magnetic recording medium having a substrate made of aluminum or aluminum alloy and an anodic-oxide film, e.g., alumite film, formed by effecting the anodic oxidation process, wherein the surface of the alumite film has protruding portions formed in addition to micro-irregularities which are formed in response to the cell-pore structure of the alumite film and height of the protruding portions is higher than that of the micro-irregularity, and density of the protruding portions is ranging from 10.sup.2 to 10.sup.7 per one square millimeter, these protruding portions are formed by processing the alumite film in the fluorine-contained solution (e.g., hydrofluoric acid) or in solution containing one of the acid (HCl), base (NaOH) and strong-acid salt ((NH.sub.4)SO.sub.4), Cr film and magnetic film are sequentially formed on the alumite film by the sputtering process.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: November 28, 1995
    Assignee: Yamaha Corporation
    Inventors: Yukio Wakui, Yoshiki Nishitani, Kenichi Miyazawa
  • Patent number: 5395510
    Abstract: A blackened steel strip having improved blackness is produced in an efficient manner by anodizing a zinc alloy-plated steel strip in a solution containing 5 to 100 g/l of ClO.sub.3.sup.- and 10 to 300 g/l of SO.sub.4.sup.2- at pH 0.5 to 2.5 at a temperature of 30.degree. to 75.degree. C. and with a quantity of electricity of 10 to 300 C/dm.sup.2, and forming an acrylic resin chromate layer on the anodized steel strip to a thickness of 0.3 to 2.5 .mu.m. The solution may contain 5 to 100 g/l in total of at least one co-additive selected from Cl.sup.-, NO.sub.3.sup.-, H.sub.2 O.sub.2, Ni.sup.2+, Co.sup.2+, Fe.sup.2+, and Mn.sup.2+. The acrylic resin chromate layer contains 2 to 10 parts by weight of in the form of a chromate Cr per 100 parts by weight of acrylic resin.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: March 7, 1995
    Assignee: Kawasaki Steel Corporation
    Inventors: Katsuhei Kikuchi, Sachiko Suzuki, Nobuo Totsuka, Takao Kurisu, Keizo Okuno, Yoshihiro Naruse
  • Patent number: 5298149
    Abstract: A copolyester film was laminated onto a steel sheet, this sheet having double layers consisting of a lower layer of metallic chromium and an upper layer of hydrated chromium oxide on a tin plated steel sheet in which 5 to 40% of the surface of the steel sheet is covered with plated tin and the remainder of the steel surface is exposed and the space between plated tin particles is 0.5 to 50 .mu.m, and a method for production of this copolyester resin film laminated steel sheet which comprises: (a) electroplating with tin under restricted conditions, (b) formation of said double layer on the plated tin and exposed steel surface and (c) lamination of the copolyester resin film at a temperature above the melting temperature of tin.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: March 29, 1994
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Hiroaki Kawamura, Masatoki Ishida, Atsuo Tanaka, Terunori Fujimoto, Tsuneo Inui, Yoshikazu Kondo
  • Patent number: 5135262
    Abstract: Color change devices which are capable of undergoing a color change on bending. The devices comprise a flexible substrate having a color generating metal (e.g. a valve metal such as Ta or Nb) at at least one surface and an intimately contacting optically thin anodic film covering the color generating metal and generating a visible color by light interference and absorption effects. The thin anodic film is produced by anodizing the color generating metal in the presence of an adhesion-reducing agent (e.g. a fluoride) for weakening the normally tenacious bond between the anodic film and the metal. Devices of this kind capable of being activated by bending, as well as by separation of the constituent layers, are produced by carrying out the anodization step in the presence of a particular concentration of the adhesion reducing agent from a narrow range (e.g. 40-350 ppm of fluoride).
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: August 4, 1992
    Assignee: Alcan International Limited
    Inventors: Gary J. Smith, Robert A. Innes
  • Patent number: 5078845
    Abstract: A process for preparing an electrode foil for use in aluminum electrolytic capacitors is disclosed which comprises the steps of: subjecting an aluminum base foil to a first anodic treatment in an aqueous solution of oxalic acid or sulfuric acid; subjecting the base foil so treated to a second anodic treatment in an aqueous solution of boric acid or adipic acid; and immersing the base foil so treated into an aqueous solution containing phosphoric acid or a salt thereof. Also disclosed is an electrode foil prepared by this process, which comprises an aluminum base foil, an anodic oxide film disposed on the base foil, and a porous oxide film disposed on the anodic oxide film, wherein phosphate ions are adsorbed on the surface of the porous oxide film.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: January 7, 1992
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiromu Kunugihara, Hiroshi Takahashi, Ryoichi Shimatani, Nobuyoshi Kanzaki