Abstract: Methods for decarboxylating carbohydrate acids in a divided electrochemical cell are disclosed using a cation membrane. The improved methods are more cost-efficient and environmentally friendly than conventional methods.
Abstract: Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.
Type:
Grant
Filed:
December 14, 2006
Date of Patent:
December 13, 2011
Assignee:
Ceramatec, Inc.
Inventors:
Ashok V. Joshi, Shekar Balagopal, Justin Pendelton
Abstract: Methods for the production of erythrose and/or erythritol are provided herein. Preferably, the method of producing erythritol includes the step of electrolytic decarboxylation of a ribonic acid or arabinonic acid reactant to produce erythrose and the step of electrolytic reduction or erythrose to produce erythritol. Optionally, the reactant can be obtained from a suitable hexose sugar, such as allose, altrose, glucose, fructose or mannose.
Type:
Application
Filed:
June 3, 2011
Publication date:
November 10, 2011
Inventors:
Jonathan A. Stapley, J. David Genders, Daniel M. Atherton, Peter M. Kendall
Abstract: Disclosed are processes of making solutions of metal alcoholates in their corresponding alcohols using an electrolytic process. In one embodiment, sodium methylate in methanol is made from methanol and sodium hydroxide solution. The sodium hydroxide solution is placed in the anolyte compartment and the methanol is placed in the catholyte compartment, and the two compartments are separated by a ceramic membrane that selectively transports sodium under the influence of current. In preferred embodiments, the process is cost-effective and not environmentally harmful.
Abstract: Methods for the production of erythrose and/or erythritol are provided herein. Preferably, the methods include the step of electrolytic decarboxylation of a ribonic acid or arabinonic acid reactant to produce erythrose. Optionally, the reactant can be obtained from a suitable hexose sugar, such as allose, altrose, glucose, fructose or mannose. The erythrose product can be hydrogenated to produce erythritol.
Type:
Grant
Filed:
July 7, 2006
Date of Patent:
June 7, 2011
Assignee:
Dynamic Food Ingredients Corporation
Inventors:
Jonathan A. Stapley, J. David Genders, Daniel M. Atherton, Peter M. Kendall
Abstract: Disclosed are processes of making solutions of metal alcoholates in their corresponding alcohols using an electrolytic process. In a preferred embodiment, sodium methylate in methanol is made from methanol and sodium hydroxide solution. The sodium hydroxide solution is placed in the anolyte compartment and the methanol is placed in the catholyte compartment, and the two compartments are separated by a ceramic membrane that selectively transports sodium under the influence of current. In preferred embodiments, the process is cost-effective and not environmentally harmful.
Abstract: Disclosed are processes of making solutions of alkali alkoxides in their corresponding alcohols using an electrolytic process. In one embodiment, sodium methoxide in methanol is made from methanol and aqueous sodium hydroxide solution, where the aqueous sodium hydroxide solution is present in the anolyte compartment and a solution of sodium methoxide in methanol is present in the catholyte compartment, the two compartments are separated by a ceramic membrane that selectively transports sodium ions under the influence of an electric potential, and wherein the composition of the solution of sodium methoxide in methanol in the catholyte compartment of the electrolytic cell comprises between at least about 2% by weight sodium methoxide and at most about 20% by weight sodium methoxide.
Type:
Grant
Filed:
June 9, 2006
Date of Patent:
November 2, 2010
Assignee:
Ceramatec, Inc.
Inventors:
Shekar Balagopal, Justin Pendleton, Robin Richards
Abstract: Methods for the production of erythrose and/or erythritol are provided herein. Preferably, the methods include the step of electrolytic decarboxylation of a ribonic acid or arabinonic acid reactant to produce erythrose. Optionally, the reactant can be obtained from a suitable hexose sugar, such as allose, altrose, glucose, fructose or mannose. The erythrose product can be hydrogenated to produce erythritol.
Type:
Application
Filed:
July 7, 2006
Publication date:
August 9, 2007
Inventors:
Jonathan A. Stapley, J. David Genders, Daniel M. Atherton, Peter M. Kendall
Abstract: A beverage container for a carbonated beverage includes a floating hollow insert (1) comprising an upper moulding (2) and a lower moulding (3) defining a chamber for containing gas, a first one-way duck-bill type valve (4) integrally formed with the upper moulding (2) at the bottom of a down pipe (6) and arranged to allow gas to enter the chamber and a second duckbill valve (5) integrally formed with the lower moulding (3) and arranged to allow gas to exit the chamber and be jetted into the beverage upon opening the beverage container.