Separation Of Vapors And Liquid Products Patents (Class 208/100)
  • Patent number: 6004453
    Abstract: A process for hydrocracking a heavy hydrocarbon oil feedstock, a substantial portion of which boils above 524.degree. C. is described which includes the steps of: (a) passing a slurry feed of a mixture of heavy hydrocarbon oil feedstock and from about 0.01-4.0% by weight (based on fresh feedstock) of coke-inhibiting additive particles upwardly through a confined vertical hydrocracking zone, the hydrocracking zone being maintained at a temperature between about 350.degree. and 600.degree. C. a pressure of at least 3.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: December 21, 1999
    Assignee: Petro-Canada
    Inventors: N. Kelly Benham, Barry B. Pruden, Michel Roy
  • Patent number: 5980698
    Abstract: A method for vacuum distillation includes separation of a liquid product delivered to a reservoir under vacuum into a vapour-gaseous phase and at least one liquid fraction, withdrawal of the vapour-gaseous phase from the reservoir using a vacuum-creating device, and subsequent separation of the vapour-gaseous phase into gas and a liquid phase by condensing performed directly in the vacumm-creating device. A portion of the liquid phase is used as a fluid working medium in the vacuum-creating device.An equipment for vacuum distillation includes a reservoir under vacuum conditions equipped with mains and a vacuum-creating device, which has an ejector, a separator and a pump, interconnected by mains.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 9, 1999
    Assignee: Valery Grigorievich Tsegelsky
    Inventors: Alexandr Alexeevich Abrosimov, Alexandr Mikhailovich Kochemasov, Ivan Alexandrovich Kochergin, Valery Grigorievich Tsegelsky
  • Patent number: 5980730
    Abstract: A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: November 9, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Frederic Morel, Thierry Chapus, Stephane Kressman, Jean-Luc Duplan, Alain Billon, Gerard Heinrich
  • Patent number: 5954942
    Abstract: A process for thermally and catalytically upgrading a heavy feed in a single riser reactor FCC unit is disclosed. A heavy feed is cracked in the base of the riser at higher than normal cracking temperatures for at least 1.0 seconds of vapor residence time, then quenched. Quenching with large amounts of quench, preferably downstream of the mid point of the riser, increases conversion as compared to use of the same amount of quench within one second. Small amounts of quench, near the riser outlet, crack heavy feed roughly as well as large amounts of quench, near the base of the riser. High velocity, atomizing quench nozzles reduce riser pressure and/or catalyst slip in downstream portions of the riser, further increasing gasoline selectivity and reducing coke yields.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: September 21, 1999
    Assignee: Mobil Oil Corporation
    Inventors: Peter M. Adornato, Amos A. Avidan, David L. Johnson
  • Patent number: 5932090
    Abstract: The process for the conversion of heavy crude oils or distillation residues to distillates comprises the following steps:mixing the heavy crude oil or distillation residue with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreating reactor introducing hydrogen or a mixture of hydrogen and H.sub.2 S;sending the stream containing the hydrotreating reaction product and the catalyst in slurry phase to a distillation zone where the most volatile fractions are separated;sending the high-boiling fraction obtained in the distillation step to a deasphaltation step obtaining two streams, one consisting of deasphalted oil (DAO), the other consisting of asphaltenes, catalyst in slurry phase, possibly coke and rich in metals coming from the initial charge;recycling at least 60%, preferably at least 80% of the stream consisting of asphaltenes, catalyst in slurry phase, optionally coke and rich in metals, to the hydrotreatment zone.
    Type: Grant
    Filed: May 1, 1996
    Date of Patent: August 3, 1999
    Assignee: Snamprogetti S.p.A.
    Inventors: Mario Marchionna, Alberto DelBianco, Nicoletta Panariti
  • Patent number: 5904836
    Abstract: High-vacuum oil refinery systems and process are disclosed in this invention. The systems and process enables to carry out vaporization and distillation of oils under the condition of 1-10.sup.-4 Torr of high vacuum and at the temperature of not higher than 360.degree. C. and thereby removing possibility of thermal cracking while heating to be vaporized and easily produces high quality oil. The vaporized gases are centrifugally separated and liquefied by specific gravity using high-vacuum gas specific gravity centrifugal separators and thereby producing high purity oil of uniform quality. The process also carries out vaporization and distillation of the oil at the temperature of not higher than 360.degree. C. so that the process prevents vaporization of sulfur components of the oil, but simply drains the sulfur components along with the concentrated sludge oil and thereby distilling and desulfurizing the crude or heavy oil at the same time without using expensive conventional desulfurizing process.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: May 18, 1999
    Assignee: Dae Sung Lee
    Inventors: Dae Sung Lee, Ho Keun Shin
  • Patent number: 5885444
    Abstract: A process for thermally cracking waste motor oil into a diesel fuel product is provided. The thermal cracking process uses low temperature cracking temperatures from 625.degree. F. to 725.degree. F. with ambient pressure to generate a column distilled fraction of diesel fuel mixed with light ends, the light ends being flashed off to produce a high quality #2 diesel fuel. The process further provides for removal from the cracking vessel an additional product stream which, when filtered, is suitable for use as a #3 fuel oil and that can be further blended with a bunker oil to yield a #5 fuel product.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: March 23, 1999
    Assignee: Green Oasis Environmental, Inc.
    Inventors: Robert W. Wansbrough, Calvin E. Moore, Jr., William D. Carraway
  • Patent number: 5840582
    Abstract: In a first embodiment of the invention, a method for determining the hydrogen-to-carbon ratio of a liquid hydrocarbon fraction is presented. A sample of the liquid fraction is subjected to an ultra-violet absorption analysis. The results of the analysis correlate directly to the hydrogen-to-carbon ratio of the hydrocarbon fraction and, with a knowledge of this correlation, the hydrogen-to-carbon ratio of the sample under analysis may be determined. Another embodiment provides a method for monitoring the performance of a process for the preparation of olefins by the thermal cracking of a hydrocarbon feedstock. A liquid fraction is recovered from the product of the thermal cracking and subjected to an ultra-violet absorption analysis. The result of the analysis correlates directly to the hydrogen-to-carbon ratio of the product, which in turn correlates to the cracking severity being applied in the thermal cracking process.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 24, 1998
    Assignee: Shell Oil Company
    Inventor: Danny Yuk-Kwan Ngan
  • Patent number: 5770043
    Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing process step between the catalytic cracking reaction steps in order to maximize olefins production, mid-distillate quality and naphtha octane level in the cracked products. Preferably, a first cracked hydrocarbon product is obtained from a first cracking stage and separated into a mid-distillate and gas oil containing fraction having an initial boiling point of at least 300.degree. F., the distillate and gas oil containing fraction is hydroprocessed, and a naphtha fraction and a gas oil containing bottoms fraction of the hydroprocessed material are cracked in a second cracking stage.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: June 23, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
  • Patent number: 5770044
    Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing step between the catalytic cracking reaction steps in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, the hydroprocessing step is included between the reaction stages, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: June 23, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
  • Patent number: 5755955
    Abstract: A process for hydrocracking a heavy hydrocarbon oil feedstock, a substantial portion of which boils above 524.degree. C. is described which includes the steps of: (a) passing a slurry feed of a mixture of heavy hydrocarbon oil feedstock and from about 0.01-4.0% by weight (based on fresh feedstock) of coke-inhibiting additive particles upwardly through a confined vertical hydrocracking zone, the hydrocracking zone being maintained at a temperature between about 350.degree. and 600.degree. C. a pressure of at least 3.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: May 26, 1998
    Assignee: Petro-Canada
    Inventors: N. Kelly Benham, Barry B. Pruden, Michel Roy
  • Patent number: 5750052
    Abstract: Methods for controlling foam in hydrocarbon liquids within hydrocracking unit separator systems utilizing alkylphenolformaldehyde resin alkoxylates with a propylene oxide/ethylene oxide block copolymer having a molecular weight of from about 2000 to 6000 and having from about 20% to about 80% ethoxylation or an alkylarylsulfonic acid or alkylarylsulfonic acid amine salt to said hydrocarbon liquid.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: May 12, 1998
    Assignee: BetzDearborn Inc.
    Inventors: Paul R. Hart, Michael A. Dion
  • Patent number: 5693191
    Abstract: A process is provided for the recovery of hydrogen chloride in anhydrous form from a dry (containing less than about 500 parts per million by weight of water) mixture of hydrogen chloride with one or more non-condensable gases and which may also contain components heavier than hydrogen chloride, which process comprises distilling the mixture to produce an overheads stream containing the non-condensable gases and about 95 percent or more by weight of the hydrogen chloride in the mixture and a bottoms stream containing about 95 percent or greater by weight of all components heavier than hydrogen chloride, and compressing and refrigerating the overheads stream whereby a selected proportion of the hydrogen chloride in the overheads stream is produced in a liquid anhydrous form containing less than about 50 parts per million by weight of water.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: December 2, 1997
    Assignee: The Dow Chemical Company
    Inventors: Katherine A. Pividal, Tom C. Tsai
  • Patent number: 5689032
    Abstract: A process and apparatus for separating a hydrocarbon gas into fractions containing predominant portions of hydrogen, methane, and C.sub.2 and heavier components, where the methane and lighter components are separated from the feed gas under non-cryogenic conditions to produce a hydrogen-rich fraction, a first fraction rich in C.sub.2 and heavier components and a hydrocarbon-rich fraction, the hydrocarbon-rich fraction then being separated under cryogenic conditions into a second fraction rich in C.sub.2 and heavier components and a methane-rich fraction.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: November 18, 1997
    Assignee: Krause/Pasadyn, a Partnership
    Inventors: William A. Krause, Ronald C. Pasadyn
  • Patent number: 5681450
    Abstract: A cyclone and process for fluidized catalytic cracking of heavy oils is disclosed. Gas and entrained solids are added around a clean gas outlet tube in a cyclone body. Solids and some gas are withdrawn via a solids outlet and discharged into a catch chamber. Some of the gas discharged with the solids into the catch chamber is returned to the interior of the cyclone body via an opening in the cyclone. Chaotic reflux of gas back into the cyclone via the solids outlet is eliminated. The device may be used as an FCC regenerator third stage separator or to improve other gas/solid separations.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 28, 1997
    Inventors: Girish K. Chitnis, Stephen J. McGovern, Klaus W. Schatz
  • Patent number: 5647972
    Abstract: A method of processing a cracked gas feedstream containing hydrogen and C.sub.1 to C.sub.6 and heavier hydrocarbons is described using a relatively low pressure as compared to conventional cryogenic separation processes. At pressures below 27 bars, the feedstream is dried and cooled in a series of steps to initially separate out essentially all of the C.sub.6 and heavier hydrocarbons forming a vapor stream containing the hydrogen, the C.sub.1 to C.sub.3 hydrocarbons and at least some of the C.sub.4 and C.sub.5 hydrocarbons. The C.sub.4 and C.sub.5 components act as an absorption liquid to lower the light ends partial pressure permitting the condensation of C.sub.2 and C.sub.3 components at higher temperature levels and permitting the operation at lower pressures. The vapor stream is then further cooled and separated in another series of steps and processed in a demethanizer column in a manner to provide a high pressure hydrogen and methane overhead product and a high recovery of C.sub.2 and C.sub.
    Type: Grant
    Filed: January 5, 1995
    Date of Patent: July 15, 1997
    Assignee: ABB Lummus Global Inc.
    Inventors: Steven I. Kantorowicz, Stephen J. Stanley, David M. Wadsworth, Rene C. L. Warner
  • Patent number: 5632867
    Abstract: In a solvent recovery plant including a recovery or distillation tower from which solvent product is recovered overhead, an isothermal separator, preferably a cyclone, is used to separate liquid phase contaminant (i.e. oil in a lubricating oil extraction process) in overhead product and to feed the separated liquid to the recovery tower as reflux. In addition, a portion of the feed to the tower can be branched off and mixed with the overhead product to bring its temperature down to close to the dew point of the solvent vapor. In this way, flooding of the uppermost tower trays and distillation of oil overhead can be overcome.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: May 27, 1997
    Assignee: Exxon Research and Engineering Company
    Inventors: Michael B. Davis, John J. Dugan, James D. Eagan, Adrianus Welmers
  • Patent number: 5620589
    Abstract: Acidic halides, especially chlorides, in two phase (vapor and hydrocarbon liquid) reactor effluent are separated and at least the halides in the vapor fraction neutralized in a vapor/liquid separator with an alkaline neutralization medium such as an alumina treater impregnated with NaOH. The treater may remove halides from both the vapor and liquid phase within the separator.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: April 15, 1997
    Assignee: Mobil Oil Corporation
    Inventor: Tsoung Y. Yan
  • Patent number: 5582711
    Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing step between the catalytic cracking reaction steps in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, the hydroprocessing step is included between the reaction stages, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: December 10, 1996
    Assignee: Exxon Research and Engineering Company
    Inventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
  • Patent number: 5453177
    Abstract: An integrated three-column process for recovering hydrocarbon distillate products from a hydroprocessing or hydrocracking reactor effluent stream and a hydrocarbon distillate product recovery train are disclosed. According to the present recovery process, an effluent stream from the cracking reactor is cooled and separated into light and heavy phase streams. The heavy phase stream is depressurized and stripped of light end components in a steam stripping column. The light phase stream is further cooled to separate a liquid stream which is combined with the light ends from the stripper and fed to a debutanizer. A C.sub.4 -rich light end stream taken overhead from the debutanizer is condensed to produce LPG product stream(s). A C.sub.4 -lean heavy end stream removed from the bottoms of the debutanizer is combined with a heavy end bottoms stream from the stripper and fed to a fractionator for fractionation into product distillate streams such as light and heavy naphtha, jet fuel, diesel oil, and the like.
    Type: Grant
    Filed: January 27, 1994
    Date of Patent: September 26, 1995
    Assignee: The M. W. Kellogg Company
    Inventors: Kenneth W. Goebel, Michael G. Hunter
  • Patent number: 5414172
    Abstract: A process for upgrading low octane naphthas to produce gasoline products with low levels of benzene and aromatics while retaining a high pool octane uses a paraffinic naphtha reformer feed which is dehexanized to provide a C.sub.7 + fraction which is fed to the reformer and a C.sub.6 fraction which is fed together with the C.sub.6 fraction from the reformer effluent to a catalytic upgrading step where the low octane components from the naphtha and the benzene from the reformate are converted to a low benzene, high octane gasoline by alkylation of the benzene and other aromatics present in the reformate. The process has the advantage that benzene make in the reformer is reduced by the partial by-passing of the C.sub.6 benzene precursors around the reformer; in addition, improved benzene alkylation results from the presence of additional light olefins generated by the cracking of paraffins from the paraffinic naphtha. the reaction is preferably carried out in a turbulent fluidized bed reaction zone.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: May 9, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Arthur A. Chin, Nick A. Collins, Mohsen N. Harandi, Robert T. Thomson, Robert A. Ware
  • Patent number: 5358627
    Abstract: High quality lubricating oil base stocks are produced from crude oils that contain significant concentrations of aromatic compounds in their higher boiling fractions. First, the crude is fractionated. After the residua fraction has been deasphalted, it is combined with the gas oil fraction. The resultant combined fraction is hydrocracked. The hydrocrackate is separated into a light fraction and a heavy fraction. The heavy fraction is hydrodewaxed, then hydrofinished. The hydrofinished product is combined with the light fraction and distilled into products including middle distillate fuel products and lubricating oil base stocks. The lubricating oil base stocks have high VI.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: October 25, 1994
    Assignee: Union Oil Company of California
    Inventors: David E. Mears, Michael G. Hunter
  • Patent number: 5347061
    Abstract: A process is disclosed for upgrading reformate and/or light FCC gasoline by substantially reducing the amount of benzene in the gasoline product while simultaneously reducing the gasoline ASTM distillation End Point. The process comprises the fractionation of reformate to recover that fraction, C.sub.7 -C.sub.8 hydrocarbons, directly useful in gasoline without further conversion. A heavy bottom fraction comprising C.sub.9 + aromatic and non-aromatic hydrocarbons is recovered and a C.sub.6 fraction rich in benzene. The total C.sub.6 fraction and a portion of the C.sub.9 + fraction are converted by alkylation, transalkylation and cracking in contact with acidic metallosilicate catalyst particles to gasoline boiling range materials rich in alkylaromatics. Following debutanization or depentanization of the conversion product, the fraction containing unconverted benzene is recycled to the reformate fractionator.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: September 13, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Mohsen N. Harandi, Hartley Owen, Paul H. Schipper
  • Patent number: 5338436
    Abstract: There is provided a process for dewaxing a hydrocarbon feedstock, wherein the effluent from a dewaxing reaction zone is passed over an oligomerization catalyst under conditions sufficient to oligomerize olefins in this effluent. The temperature of the oligomerization reaction is less than the temperature of the dewaxing reaction.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: August 16, 1994
    Assignee: Mobil Oil Corp.
    Inventor: Mohsen N. Harandi
  • Patent number: 5332492
    Abstract: A process for recovering hydrogen-rich gases and increasing the recovery of liquid hydrocarbon products from a hydrocarbon conversion zone effluent is improved by a particular arrangement of a refrigeration zone, a pressure swing adsorption (PSA) zone, and up to two separation zones. The admixing of at least a portion of the tail gas from the PSA zone with a hydrogen-rich gas stream recovered from a first vapor-liquid separation zone results in significantly improved hydrocarbon recoveries and the production of a high purity hydrogen product. The process is especially beneficial in the integration of the catalytic reforming process with vapor hydrogen consuming processes such as catalytic hydrocracking in a petroleum refinery.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: July 26, 1994
    Assignee: UOP
    Inventors: Richard T. Maurer, Michael J. Mitariten, Roger J. Weigand, Michael Whysall
  • Patent number: 5326927
    Abstract: In a process for the recovery of a polymerizable useful fraction, consisting of styrene, methylstyrenes, vinyltoluenes, indene, methylindenes and fractions whose boiling points are between styrene and methylindenes, from the crack gases of a steam cracker, the sidestream of the crack gas column is divided, by means of a distillation unit, into the useful fraction and into fractions which are recycled to the crack gas column.
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: July 5, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Stabel, Gerd Wunsch, Helmut Woerz, Andreas Fried, Ruediger Kotkamp
  • Patent number: 5310478
    Abstract: A method of producing hydrocarbon diluent from heavy crude oil, comprises pre-heating the crude oil to produce a heated crude oil, separating in a separator vessel by flashing the heated crude oil to produce a first vapor fraction and a first liquid fraction, thermally cracking in a cracking unit at least a portion of the first liquid fraction to produce a first liquid effluent, quenching the first liquid effluent, introducing at least a portion of the quenched first liquid effluent into a separator, condensing the first vapor fraction, and separating in a separator vessel the condensed vapor fraction to produce the hydrocarbon diluent and gas.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: May 10, 1994
    Inventor: Malcolm T. McCants
  • Patent number: 5302282
    Abstract: A process for the production of high quality lube oil blending stock from atmospheric fractionation residue and waste lubricants by means of contacting the waste lubricant with a hot hydrogen-rich gaseous stream to increase the temperature of this feed stream to vaporize at least a portion of the distillable hydrocarbonaceous compounds thereby producing a distillable hydrocarbonaceous stream which is immediately hydrogenated in an integrated hydrogenation zone. The vaporization of the waste oil is also conducted in the presence of an asphalt residue which is produced in the integrated process. The resulting effluent from the integrated hydrogenation zone provides at least one high quality lube oil blending stock stream.
    Type: Grant
    Filed: March 5, 1992
    Date of Patent: April 12, 1994
    Assignee: UOP
    Inventors: Tom N. Kalnes, Steven P. Lankton, Robert B. James, Jr.
  • Patent number: 5298151
    Abstract: In ebullated bed hydroprocessing of a distillate hydrocarbon feedstock, it has been found that high pressure and low pressure heat exchange can be separated. Both the high pressure heat exchange and the fired heater fuel consumption are reduced. A control system provides for a constant distillate feedstock temperature in cooperation with heat integration.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: March 29, 1994
    Assignee: Texaco Inc.
    Inventors: Robert M. Steinberg, Jacquelyn G. Niccum, John C. Strickland
  • Patent number: 5292976
    Abstract: A staged process has been discovered for the selective conversion of paraffins in naphtha to aromatics and conversion of naphthenes in naphtha to olefins. In a first stage, n-paraffins in naphtha are converted to aromatics over modified non acidic zeolite catalyst particles with a low conversion of naphthenes in the feedstream. The effluent from the first stage is cascaded to a second stage reactor containing acidic zeolite catalyst wherein naphthenes are converted to light olefins. Advantageously, the process of the invention results in a reduction in the production of light C.sub.1 -C.sub.4 paraffins compared to the prior art. The preferred catalyst for the first stage is a platinum modified zeolite containing tin.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: March 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Ralph M. Dessau, Mohsen N. Harandi
  • Patent number: 5244565
    Abstract: A process for the production of distillate hydrocarbon from atmospheric fractionation residue and waste lubricants by means of contacting the waste lubricant with a hot hydrogen-rich gaseous stream to increase the temperature of this feed stream to vaporize at least a portion of the distillable hydrocarbonaceous compounds thereby producing a distillable hydrocarbonaceous stream which is immediately hydrogenated in an integrated hydrogenation zone. The vaporization of the waste oil is also conducted in the presence of a vacuum fractionation residue which is produced in the integrated process. The resulting effluent from the integrated hydrogenation zone and a distillable hydrocarbon stream recovered from the atmospheric fraction residue is catalytically converted to produce lower molecular weight hydrocarbon compounds.
    Type: Grant
    Filed: December 26, 1991
    Date of Patent: September 14, 1993
    Assignee: UOP
    Inventors: Steven P. Lankton, Tom N. Kalnes, Robert B. James, Jr.
  • Patent number: 5238555
    Abstract: A process for recovering hydrogen-rich gases and increasing the recovery of liquid hydrocarbon products from a hydrocarbon conversion zone effluent is improved by a particular arrangement of two refrigeration zones and an absorption vessel.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: August 24, 1993
    Assignee: UOP
    Inventors: Scott W. Pappas, Donald E. Felch
  • Patent number: 5178751
    Abstract: A process for recovering hydrogen-rich gases and increasing the recovery of liquid hydrocarbon products from a hydrocarbon conversion zone effluent is improved by a particular arrangement of a refrigeration zone and two separation zones.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: January 12, 1993
    Assignee: UOP
    Inventor: Scott W. Pappas
  • Patent number: 5164070
    Abstract: The recovery of distillate products from a hydrocracking process includes passing the liquid-phase portion of the reaction zone effluent into a stripping column. A naphtha sidecut stream is recovered off the stripping column and combined with the net overhead liquid of the column. These combined streams are then combined with the naphtha recovered from the primary product recovery column. This minimizes the hydrogen sulfide present in the total naphtha product.
    Type: Grant
    Filed: March 6, 1991
    Date of Patent: November 17, 1992
    Assignee: UOP
    Inventor: William H. Munro
  • Patent number: 5152883
    Abstract: Process for producing gasolines having improved RON and MON which consists in subjecting the LCO, HCO and CLO obtained by catalytic cracking of a heavy hydrocarbon feedstock, to a hydrogenation treatment and subjecting the obtained products to a new catalytic cracking and then recovering hydrocarbons boiling in the range of gasolines.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: October 6, 1992
    Assignee: Fina Research S.A.
    Inventors: Michel Melin, Jacques F. Grootjans
  • Patent number: 5143595
    Abstract: A process for the preparation of a base oil and middle distillate which is stable to oxidation and low temperature from a mineral oil fraction having a boiling range above 350.degree. C., by, in a first step, converting the mineral oil fraction on a hydrocracking catalyst under hydrocracking conditions to an extent of from 20 to 80% by weight into fractions which boil below 360.degree. C., separating the reactor effluent, if necessary, into liquid and gas phases in a high-pressure separator, treating the entire reactor effluent or only the liquid phase, directly or after removal of the fractions boiling below 360.degree. C. by distillation, in a second step with hydrogen at from 200.degree. to 450.degree. C.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: September 1, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Thomas, Roland Spahl, Thomas Anstock, Ansgar Eisenbeis, Wolfgang Schmid
  • Patent number: 5139647
    Abstract: The present invention relates to a hydrocracking and isomerization process for preparing low pour point middle distillate hydrocarbons and lube oil from a hydrocarbonaceous feedstock boiling above about 600.degree. F. by contacting the feedstock with a catalyst containing an intermediate pore size silicoaluminophosphate molecular sieve and a hydrogenation component.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: August 18, 1992
    Assignee: Chevron Research and Technology Company
    Inventor: Stephen J. Miller
  • Patent number: 5120426
    Abstract: An improved hydrocracking process, in a process for conversion of components of a heavy hydrocarbon feed to lighter, more valuable products, wherein the feed comprises foulant, the process comprising: (a.) contacting the feed with hydrogen, in the presence of a hydrocracking catalyst, at an elevated temperature and pressure in a hydrocracker, to produce a hydrocracker effluent comprising foulant; (b.) cooling and depressurizing the hydrocracker effluent to form a cooled, depressurized hydrocracker effluent comprising foulant; (c.) separating the cooled, depressurized hydrocracker effluent into the products of the conversion and an unconverted portion of the hydrocracker effluent which comprises foulant; and (d.) recycling, as effluent recycle to the hydrocracker, the unconverted portion of the hydrocracker effluent to the hydrocracker, wherein the concentration of foulant in the hydrocracker effluent is increased; the improvement comprising: (i.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: June 9, 1992
    Assignee: Atlantic Richfield Company
    Inventors: Mark R. Johnston, Donald J. Gatza, Mark J. Woodward
  • Patent number: 5120427
    Abstract: Potential problems associated with the formation of polynuclear aromatic compounds during hydrocracking of residual oils are eliminated by operating at high conversion rates with a high hydrogen concentration followed by a unique separation method. The feed to the final product recovery column is preferably highly vaporized before or within the column. All of the net bottoms stream of the product recovery column, which is equal to less than 5 vol. percent of the feed, is withdrawn from the process. Only PNA free distillate is recycled.
    Type: Grant
    Filed: October 8, 1990
    Date of Patent: June 9, 1992
    Assignee: UOP
    Inventors: Laurence O. Stine, Mark E. Reno, William H. Munro, Simon J. Hamper
  • Patent number: 5110446
    Abstract: The present invention provides a process for decreasing the energy consumption of a catalytic cracking process product recovery section while improving gasoline yield by integrating multistage vapor compression and product recovery with deacidification and conversion of C.sub.2 -C.sub.4 aliphatics to C.sub.5 + normally liquid hydrocarbons.
    Type: Grant
    Filed: September 7, 1990
    Date of Patent: May 5, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Mohsen N. Harandi, Hartley Owen
  • Patent number: 5082551
    Abstract: A hydroconversion effluent separation process is provided.The effluent from the hydroconversion zone is passed to a hot high pressure separation zone. The gas phase from that zone is then passed to a cold high pressure separation zone while the liquid hydrocarbon bottoms is passed to a hot low pressure separation zone. The gas phase is partially condensed in the cold high pressure separation zone to obtain a hydrogen-rich gas and a liquid hydrocarbon bottoms. A portion of the hydrogen-rich gas is recycled to the hydroconversion zone. A second portion is sent to a hydrogen purification step, most preferably by membrane separation, and the purified gas is recycled to the hydroconversion zone. The overhead from the hot low pressure separation is fed to a cold low pressure separation zone. The gas phase from the cold low pressure separation zone is recycled to the hydroconversion zone. Preferably, two cold low pressure separation zones are utilized in the process.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: January 21, 1992
    Assignee: Chevron Research and Technology Company
    Inventors: Bruce E. Reynolds, Donald A. Bea, Robert W. Bachtel
  • Patent number: 5080776
    Abstract: A two-stage method is provided for converting diamondoid-containing wash oils to gasoline comprising a first hydrocracking stage and a second reforming stage. In the most preferred embodiment, process conditions are controlled to effect a substantially hydrogen-balanced conversion of diamondoid-containing solvent to a motor gasoline blending component.
    Type: Grant
    Filed: June 14, 1990
    Date of Patent: January 14, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Randall D. Partridge, D. Duayne Whitehurst
  • Patent number: 5080777
    Abstract: For upgrading heavy slurry oil containing catalyst fines from a catalytic cracking operation, the viscosity of the slurry oil is lowered in a hydrovisbreaking process step. In a preferred embodiment an admixture of the fines containing slurry oil and a metal containing resid oil fraction, resulting from a crude distillation, is passed through the hydrovisbreaker. The hydrovisbreaker effluent is separated into higher and lower boiling fractions with the lower boiling fraction preferably passed through a cracking unit so as to covert the lower boiling fraction to lower molecular weight hydrocarbon products.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: January 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Paul A. Aegerter, Jr., Jerald A. Howell, Edward L. Sughrue, II, Kelly G. Knopp
  • Patent number: 5076910
    Abstract: A method for removing particulate solids, such as catalyst fines, from a hot slurry oil having a gravity of 5.degree. API to 15.degree. API, an atmospheric pressure initial boiling point of from about 500.degree. F. to about 750.degree. F. and an atmospheric pressure end point of less than 1,000.degree. F. which entails mixing a preselected amount of the slurry oil with a preselected amount of a hot vacuum reduced crude oil having equilibrium flash vaporization characteristics such that when the mixture is subjected to a selected temperature in a vacuum tower maintained at a vacuum of from about 1.0 mm Hg to about 10.0 mm Hg, at least 85 volume percent of the slurry oil will be flashed overhead and not more than about 15% of the vacuum reduced crude oil will be flashed overhead, and the particulate solids will remain in the liquid bottoms.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: December 31, 1991
    Assignee: Phillips Petroleum Company
    Inventor: John B. Rush
  • Patent number: 5074989
    Abstract: This invention relates to a process for the separation of fine catalyst particles from a hydrocarbon feedstock coming from a catalytic cracking unit by filtration through mineral barriers and a filtration loop.The process consists of filtering the feedstock through mineral barriers that are resistant to heat and have a porosity adapted to the minimum diameter of the particles to be retained. The porosity is generally between 0.1 and 100 microns.
    Type: Grant
    Filed: January 11, 1991
    Date of Patent: December 24, 1991
    Assignee: Compagnie de Raffinage et de Distribution Total France
    Inventors: Jean B. Sigaud, Jean Rossarie
  • Patent number: 5073249
    Abstract: A process and apparatus for fluidized catalytic cracking of heavy oils is disclosed. The long transfer line connecting the catalytic cracking reactor to the main fractionator is modified to include a cooling means, such as a quench drum or a heat exchanger. Cooling hot cracked products from the FCC reactor upstream of the main fractionator prevents thermal cracking in the transfer line, improves yields, and permits higher catalytic cracking reactor temperatures.
    Type: Grant
    Filed: November 21, 1989
    Date of Patent: December 17, 1991
    Assignee: Mobil Oil Corporation
    Inventor: Hartley Owen
  • Patent number: 5055175
    Abstract: Heavy crude oil emulsions are converted to lighter essentially sulphur-free and nitrogen-free hydrocarbons by Group VI B or Group VIII B metal compounds or complexes along with carbon monoxide, hydrogen or mixtures of carbon monoxide and hydrogen, and broken without the necessity for prior emulsion treatment and separation.
    Type: Grant
    Filed: July 14, 1989
    Date of Patent: October 8, 1991
    Assignee: University of Waterloo
    Inventors: Flora T. T. Ng, Sophia K. Tsakiri
  • Patent number: 5049258
    Abstract: A process is disclosed for reprocessing contaminated oils, such as used crankcase oil from automobile engines, by thermal treatment, such as visbreaking, in the presence of other hydrocarbon feedstocks, followed by fractional distillation for the recovery of a gasoline fraction, a carboxylic acid fraction, a gas oil fraction containing chlorinated hydrocarbons and a high boiling bottoms fraction. The gas oil fraction is subjected to catalytic hydrocracking with the simultaneous destruction of chlorinated hydrocarbons. The resulting hydrocracked oils, after separation of hydrogen chloride, are free from chlorine compounds and other contaminants.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: September 17, 1991
    Assignee: RWE-Entsorgung Aktiengesellschaft
    Inventors: Karl H. Keim, Peter Seifried, Hartmut Hammer, Ralf Wehn
  • Patent number: 5045175
    Abstract: A hydrotreating process uses a separation section that reduces the loss of C.sub.4 and higher hydrocarbons through the use of a low hydrogen to hydrocarbon ratio in the reactor and the adsorptive removal of a majority of hydrogen sulfide from a liquid phase hydrotreater effluent. Sulfurous hydrocarbon feed is admixed with hydrogen to maintain a hydrogen to hydrocarbon ratio of less than 50 SCFB. The hydrogen and hydrocarbons are passed through a hydrotreater reactor to convert sulfur compounds to H.sub.2 S. The hydrotreater effluent is cooled and after flashing of any excess hydrogen or light ends the cooled effluent is contacted with an adsorbent material for the removal of H.sub.2 S. A hydrotreated hydrocarbon product is withdrawn from the adsorption section. The low hydrogen to hydrocarbon ratio permits the process to be used without the recycle of hydrogen thereby eliminating the need for separators and compressors that were formly used to recycle hydrogen to the hydrotreater.
    Type: Grant
    Filed: October 22, 1990
    Date of Patent: September 3, 1991
    Assignee: UOP
    Inventors: Robert S. Haizmann, Andrew S. Zarchy, Martin F. Symoniak
  • Patent number: 5021143
    Abstract: The invention relates to a process for hydrocarbon fractionation and extraction making it possible to obtain a petrol with an improved octane number and a kerosene with an improved smoke point.According to the invention a charge with a final boiling point of at least 220.degree. C. is fractionated into three fractions:a light petrol containing less than 10% aromatics and boiling points at 25.degree. to 80.degree. C.,a medium petrol (80.degree. C. and at the most 150.degree. C.), whose end point is determined by a nitrogen content below 50 ppm,a heavy petrol with an end point equal to or below 220.degree. C.,be a selective liquid solvent aromatics are then extracted from the heavy petrol producing a refined product which is poured into the kerosene pool or diesel fuel,the solvent is regenerated by reextraction using light petrol so as to produce an aromatics-enriched petrol fraction with an improved octane number.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: June 4, 1991
    Assignee: Institut Francais du Petrole
    Inventors: Sigismond Franckowiak, Paul Mikitenko, Pierre Baumgartner, Georges Cohen