With Group Vi Metal Or Metal Oxide (i.e., Cr, Mo, W, Po, Or Oxide Thereof) Patents (Class 208/111.3)
  • Patent number: 6267874
    Abstract: The present invention relates to a hydrotreating catalyst composed of a carrier having a Brønsted acid content of at least 50 &mgr;mol/g such as a silica-alumina carrier or a silica-alumina-third component carrier, in which the silica is dispersed to high degree and a Brønsted acid content is at least 50 &mgr;mol/g, and at least one active component (A) selected from the elements of Group 8 of the Periodic Table and at least one active component (B) selected from the elements of Group 6 of the Periodic Table, supported on said carrier. The present invention also relates to a method for hydrotreating hydrocarbon oils using the same. The hydrotreating catalyst of the present invention provides excellent tolerance to the inhibiting effect of hydrogen sulfide, high desulfurization activity, and exhibits notable effects for deep desulfurization of hydrocarbon oils containing high contents of sulfur, in particular gas oil fractions containing difficult-to-remove sulfur compounds.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: July 31, 2001
    Assignee: TonenGeneral Sekiyu K.K.
    Inventors: Masahiko Iijima, Yoshinobu Okayasu
  • Patent number: 6251261
    Abstract: The invention relates to a hydrocracking catalyst that comprises at least one oxide-type amorphous or poorly crystallized matrix, at least one element of group VB, preferably niobium, and at least one clay that is selected from the group that is formed by the 2:1 dioctahedral phyllosilicates and the 2:1 trioctahedral phyllosilicates, optionally at least one element that is selected from among the elements of group VIB and group VIII, optionally at least one element that is selected from the group that is formed by P, B, Si, and optionally at least one element of group VIIA. The invention also relates to the use of this catalyst in hydrocracking of feedstocks that contain hydrocarbon.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: June 26, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Slavik Kasztelan, Eric Benazzi, Nathalie Marchal-George
  • Patent number: 6238550
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks. More particularly, the new SAPOs have a high silica:alumina ratio, and may be prepared from single phase synthesis solutions or from microemulsions containing surfactants.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: May 29, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Karl G. Strohmaier, David E. W. Vaughan, William J. Murphy, Ian A. Cody, Sandra J. Linek
  • Patent number: 6231750
    Abstract: The invention provides a hydrocracking catalyst comprising at least one mineral matrix, at least one beta zeolite, at least one group VB element or at least one mixed sulphide phase comprising sulphur, optionally at least one group VIB or group VIII element, optionally at least one element selected from the group formed by silicon, boron or phosphorous, and optionally at least one group VIIA element.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: May 15, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Slavik Kasztelan, Eric Benazzi, Nathalie Marchal-George
  • Patent number: 6203695
    Abstract: A process for hydrotreating a hydrocarbon feed, comprising subjecting said feed to hydrotreating conditions in the presence of a catalyst comprising an essentially alumina-based extruded support, essentially constituted by a plurality of juxtaposed agglomerates, optionally at least one catalytic metal or a compound of a catalytic metal from group VIB (group 6 of the new periodic table notation) and/or optionally, at least one catalytic metal or a compound of a catalytic metal from group VIII (group 8, 9 and 10 of the new periodic table notation), in which the sum S of the group VIB and VIII metals, expressed as the oxides, is 0% to 50% by weight, and wherein each of these agglomerates is partly in the form of packs of flakes and partly in the form of needles, said needles being uniformly dispersed both about the packs of flakes and between the flakes, in which the alumina agglomerates are obtained by forming a starting alumina originating from rapid dehydration of hydrargillite and in which the amount of alum
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: March 20, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Virginie Harle, Slavik Kazstelan, Frédéric Morel, Stéphane Kressmann, Philippe Courty
  • Patent number: 6174429
    Abstract: The invention relates to a hydrocracking catalyst that contains at least one metal of group VIB, and/or at least one metal of group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA (fluorine), and a zeolite Y that is not fully dealuminificated, with a crystalline parameter that is greater than 2,438 nm, an overall SiO2/Al2O3 ratio that is less than 8, and a framework SiO2/Al2O3 ratio that is less than 21 and greater than the overall SiO2/Al2O3 ratio. The invention also relates to a process for hydrocracking with this catalyst, in particular at low pressure of 7.5 to 11 MPa.
    Type: Grant
    Filed: October 20, 1998
    Date of Patent: January 16, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Nathalie George-Marchal, Samuel Mignard, Slavik Kasztelan
  • Patent number: 6171475
    Abstract: A method for converting a polymer or oligomer derived from an ethylenically unsaturated monomer into alkanes or into a hydrocarbon fraction or a lower oligomer fraction by controlled hydrocracking, wherein the polymer or oligomer is exposed to a catalyst based on a metal hydride or an organometallic complex supported on a mineral carrier, the complex having at least one hydrocarbon ligand and optionally at least one hydride ligand, and the resulting mixture is reacted with hydrogen to cause catalytic hydrocracking of the polymer or oligomer. The polymer or oligomer is broken down into reclaimable products with a lower molecular weight for use, e.g., in the field of polymers, particularly controlled molecular weight polymers, fuels or lubricants.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: January 9, 2001
    Assignee: CPE-Lyon-FCR
    Inventors: V{acute over (e)}ronique Dufaud, Jean-Marie Basset
  • Patent number: 6171474
    Abstract: Useful for example, for the hydrocracking of hydrocarbons is a catalyst comprising a matrix, at least one Y zeolite which is dealuminated and has a lattice parameter in the range 2.424 nm to 2.455 nm, a global SiO2/Al2O3 mole ratio is more than 8, the quantity of alkaline-earth metal cations or alkali metal cations and/or rare earth metal cations is such that the atomic ratio (n×Mn+)/Al is less than 0.8, the specific surface area, determined using the BET method, is more than 400 m2/g, and the water adsorption capacity is more than 6% by weight for P/P0 =0.2 at 25° C., said catalyst also comprising silicon deposited on the catalyst.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: January 9, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Slavik Kasztelan, Nathalie George-Marchal, Eric Benazzi